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1 R C I s p r a Physical Characteristics of PM from 2- Stroke and 4-Stroke Motorcycle Engines G. Martini, P. Bonnel, C. Astorga-LLorens, A. Krasenbrink Institute of Environment and Sustainability European Commission – Joint Research Centre ISPRA (Italy) Vehicle Emissions Laboratory (VELA) - Institute for Environment and Sustainability

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1RC – Ispra

Physical Characteristics of PM from 2-Stroke and 4-Stroke Motorcycle Engines

G. Martini, P. Bonnel, C. Astorga-LLorens, A. KrasenbrinkInstitute of Environment and Sustainability

European Commission – Joint Research CentreISPRA (Italy)

Vehicle Emissions Laboratory (VELA) - Institute for Environment and Sustainability

2RC – Ispra

Background and objectives of the study:

• Background:– Amendment of the European Directive 97/24/EC– EURO3 stage for two and three-wheelers from 2006– Reduction of particulate emissions

• Main Objectives:– To evaluate particulate measurement techniques– To determine particulate mass emissions from 2-stroke engines– To assess particulate emissions for big four-stroke engines to

check if they diverge significantly from passenger cars with similar engine sizes

3RC – Ispra

Test Fleet:Motos Eng. (cc) 2S 4S Remarks

MT001-50 50 X Pre Euro1 Moped – No Cat MT002-50 50 X Direct Injection – No Cat MT003-50 50 X Conventional 2-stroke – With OxCat

MT004-125 125 X Carburetor MT005-125 125 X Controlled TWC MT006-200 200 X Carburetor MT007-500 500 X SAI MT008-1150 1150 X Controlled TWC MT009-1200 1200 X Controlled TWC

EFI = Electronic InjectionSAI = Secondary Air InjectionOC = Oxidation CatalystTWC= Three Way Catalyst

4RC – Ispra

Test Matrix:

Motos EURO2 EURO3 WMTC ECE47 ECE 40 6UDC 6UDC+EUDC (*)

MT001-50 X X X MT002-50 X X X X MT003-50 X X X

MT004-125 X X X MT005-125 X X MT006-200 X X MT007-500 X X X MT008-1150 X X MT009-1200 X X

(*) Worldwide Motorcycle Test Cycle

5RC – Ispra

Test Procedure: 1a. ECE 47 Test Cycle (Mopeds only)

0

10

20

30

40

50

0Time [s]

Spee

d [k

m/h

]

"COLD" PHASE "HOT" PHASE

6RC – Ispra

Test Procedure: 1b. EURO 2 Test Cycle

0

10

20

30

40

50

60

1 101 201 301 401 501 601 701 801 901 1001 1101Time [s]

Spee

d [k

m/h

]

SAMPLINGNO SAMPLING

Conditionning2 phases ECE15 (UDC) of 195 s = 390 skm 1.013*2 phases = 2.026 kmMax. Speed: 50 km/hAverage Speed: 19 km/h

Measurement4 phases ECE15 of 195 s = 780 skm 1.013*4 phases = 4.052 kmMax. Speed 50 km/hAverage Speed: 19 km/h

7RC – Ispra

Test Procedure: 1c. EURO 3 Test Cycle (<=150 cc)

0

10

20

30

40

50

60

1 101 201 301 401 501 601 701 801 901 1001 1101Time [s]

Spee

d [k

m/h

]

UDC Cycle - 6 phases ECE15 of 195 s = 1170 skm 1.013*6 phases= 6.078 kmMax. Speed: 50 km/hAverage Speed: 19 km/h

SAMPLING

8RC – Ispra

Test Procedure: 1d. EURO 3 Test Cycle (>150 cc)

0

10

20

30

40

50

60

70

80

90

100

110

120

130

1 101 201 301 401 501 601 701 801 901 1001 1101 1201 1301 1401 1501Time [s]

Spee

d [k

m/h

]

Part One Part Two

EUDC Cycle of 400 skm 6.955Max. Speed: 120 km/hAverage Speed: 62.6 km/h

UDC Cycle - 6 phases ECE15 of 195 s = 1170 skm 1.013*6 phases= 6.078 kmMax. Speed: 50 km/hAverage Speed: 19 km/h

SAMPLING

9RC – Ispra

Test Procedure: 2. Test Set-up

• Carried out at the JRC-VELA1 emissions test facility• Roller bench 48” suitable for testing small two wheelers • Conventional CVS system + dilution tunnel

10RC – Ispra

Particulate Emissions Characterisation:

• Measurement of particulate total mass– The legislative procedure prescribed for Diesel was used to

measure particulate total mass– In addition, a cyclone was used to avoid contaminating the

sampling system and the analysers with very large droplets of lubricant

• Particulate physical properties:– Number/size distribution (TSI – SMPS)– Mass/size distribution (LPI)

11RC – Ispra

Particulate physical properties:

• Number/size distribution (TSI – SMPS)– Constant speed (40 km/h)– Sampling: from dilution tunnel

• Mass/size distribution (Low Pressure Impactor)– 11+1 stages– Volume flow rate: 25 l/min– Measuring range: 0.0085 µm-16 µm– Constant speed (40 km/h) and ECE 47 cycle– Sampling: from dilution tunnel

12RC – Ispra

13RC – Ispra

Total Mass

14RC – Ispra

Particulate Emissions from Mopeds - Total MassECE 47 Cycle

0.000

0.025

0.050

0.075

0.100

0.125

0.150

0.175

0.200

0.225

MT001-M-50 MT002-M-50 MT003-M-50Motorcycle

Tota

l Mas

s, (g

/km

)

Cold Phase (1-2-3-4)Hot Phase (5-6-7-8)

Moped - 2-strokePre-Euro 1

Moped - 2 strokeDirect Injection

Moped - 2 strokeOxycat

15RC – Ispra

Particulate Emissions from Mopeds and Motorcycles - Total MassEuro 2 Cycle (ECE 40)

0.000

0.050

0.100

0.150

0.200

0.250

0.300

0.350

MT001-50 MT002-50 MT003-50 MT004-125 MT007-500Motorcycle

Tota

l Mas

s, (g

/km

)

Cold Phase (UDC 1-2)Hot Part (UDC 3-4-5-6)Complete Cycle

Moped - 2 strokePre-Euro 1

Moped - 2 strokeOxycatMoped - 2 stroke

Direct Injection

4-stroke motorcycles

16RC – Ispra

Particulate Emissions from Mopeds and Motorcycles - Total Mass (Filter)Complete Euro 3 Cycle (6 Urban Driving Cycles)

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

MT001-50 MT002-50 MT003-50 MT004-125 MT005-125 MT006-200 MT007-500Motorcycle

Tota

l Mas

s, (g

/km

)

0.20Moped - 2 strokePre-Euro 1

Moped - 2 strokeOxycat

Moped - 2 strokeDirect Injection

4-stroke Motorcycles

EURO4 Diesel Passenger cars = 0,025 g/km

17RC – Ispra

Mass/Size Distribution

18RC – Ispra

Particulate Emissions from Mopeds ECE 47 Cycle - Mass/Size Distribution (LPI 11 stages)

0.00E+00

2.00E-02

4.00E-02

6.00E-02

8.00E-02

1.00E-01

1.20E-01

10 100 1000 10000 100000

Aerodynamic Diameter (nm)

dM/d

LogD

(g/k

m)

MT001-M-50 (Min)

MT002-M-50 (Min)

MT003-M-50 (Min)

Diesel passenger car

Pre-Euro 1 Moped

Euro 1 - Oxycat

Euro 1 - Direct Inj.

19RC – Ispra

Mass/Size Distribution (LPI 11 stages) - Measurement Repeatibility ECE 47 (Cold Phase + Hot Phase)

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0.090

0.100

1 10 100 1000 10000 100000Aerodynamic Diameter (nm)

dM/d

LogD

, (g/

km)

MT001-M-50MT001-M-50MT002-M-50MT002-M-50MT003-M-50MT003-M-50

20RC – Ispra

Particulate Emissions from Mopeds - Total Mass - LPI vs Filter ECE 47 Cycle (Cold Phase + Hot Phase)

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0.160

0.180

0.200

MT001-M-50 MT002-M-50 MT003-M-50Aerodynamic Diameter (nm)

dM/d

LogD

, (g/

km)

FilterLPI

91%

75%

88%

21RC – Ispra

Particulate Emissions from Mopeds and Motorcycles Mass/Size Distribution (LPI 11 stages) - EURO2 (Cold+ Hot Phase) Cycle

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0.090

0.100

1 10 100 1000 10000 100000Aerodynamic Diameter (nm)

dM/d

LogD

, (g/

km)

MT001-M-50MT002-M-50MT003-M-50MT006-C2-200*

* 6 UDC_Euro 3 Cycle (no 40 s idling)

22RC – Ispra

MT007-C2-500 Mass/Size Distribution (LPI 11 stages) - WMTC 1-2-3

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

1 10 100 1000 10000 100000Aerodynamic Diameter (nm)

dM/d

LogD

, (g/

km)

WMTC 1_2_3

23RC – Ispra

Number/Size Distribution

24RC – Ispra

Number/Size Distribution - Constant Speed 20 km/hEngine Technology Effect

0

1E+13

2E+13

3E+13

4E+13

5E+13

6E+13

7E+13

10 100 1000Electrical Mobility Diameter (nm)

[dN/

dlog

Dp]

/km

MT001-M-50 (Day 1)MT002-M-50 (Day 1)MT003-M-50 (Day 1)

Moped - 2 strokesPre - Euro 1

Moped - 2 strokesEuro 1 - Direct Inj.

Moped - 2 strokesEuro 1 - Oxycat

25RC – Ispra

Number/Size Distribution - Constant Speed: 40 km/hEngine Technology Effect

0

1E+13

2E+13

3E+13

4E+13

5E+13

6E+13

7E+13

8E+13

9E+13

10 100 1000

Electrical Mobility Diameter (nm)

[dN/

dlog

Dp]

/km

MT001-M-50 (Day 1)MT002-M-50 (Day 1)MT003-M-50 (Day 1)

Moped - 2 strokesEuro 1 - Direct Inj.

Moped - 2 strokesPre - Euro 1

Moped - 2 strokesEuro 1 - Oxycat

26RC – Ispra

MT001-M-50 (Pre Euro1 2-stroke Moped) SMPS Number/Size Distribution - Constant Speed: 20 km/h

5 consecutive scans

0.00E+00

1.00E+13

2.00E+13

3.00E+13

4.00E+13

5.00E+13

6.00E+13

7.00E+13

8.00E+13

1 10 100 1000Electrical Mobility Diameter (nm)

[dN

/dlo

g Dp

]/km

Scan 1Scan 2Scan 3Scan 4Scan 5

27RC – Ispra

MT002-M-50 (2-stroke Moped - 50 cc Direct Injection) Number/Size Distribution - Constant Speed: 40 km/h

5 consecutive scans

0.00E+005.00E+12

1.00E+131.50E+13

2.00E+132.50E+13

3.00E+133.50E+13

4.00E+134.50E+13

5.00E+13

1 10 100 1000Electrical Mobility Diameter (nm)

[dN

/dlo

g Dp

]/km

Scan 1Scan 2Scan 3Scan 4Scan 5

28RC – Ispra

MT001-M-50Number/Size Distribution - 20 km/h

Day to Day Repeatability Each curve is the average of 5 daily scans

0

1E+13

2E+13

3E+13

4E+13

5E+13

6E+13

7E+13

1 10 100 1000Electrical Mobility Diameter (nm

[dN

/dlo

g Dp

]/km

MT001-M-50 (Day 1)MT001-M-50 (Day 2)MT001-M-50 (Day 3)MT001-M-50 (Day 4)

29RC – Ispra

MT006-C2-200 (4 strokes) SMPS Number/Size Distribution - Constant Speed: 20 km/h

10 consecutive scans

0.00E+00

5.00E+11

1.00E+12

1.50E+12

2.00E+12

2.50E+12

3.00E+12

3.50E+12

4.00E+12

1 10 100 1000

Electrical Mobility Diameter (nm)

[dN

/dlo

g D

p]/k

m

Scan 1Scan 2Scan 3Scan 4Scan 5Scan 6Scan 7Scan 8Scan 9Scan 10

30RC – Ispra

MT006-C2-200 (4 strokes) SMPS Number/Size Distribution - Constant Speed: 40 km/h

4 consecutive scans

0.00E+00

1.00E+11

2.00E+11

3.00E+11

4.00E+11

5.00E+11

6.00E+11

7.00E+11

1 10 100 1000Electrical Mobility Diameter (nm)

[dN

/dlo

g D

p]/k

m

Scan 1Scan 2Scan 3Scan 4

31RC – Ispra

MT002-M-50 (2 strokes- Dir. inj) SMPS Number/Size Distribution - Constant Speed: 40 km/h

Effect of Thermodenuder - 6 consecutive scans

0.00E+00

2.00E+13

4.00E+13

6.00E+13

8.00E+13

1.00E+14

1.20E+14

1.40E+14

1.60E+14

1 10 100 1000

Electrical Mobility Diameter (nm)

[dN

/dlo

g D

p]/k

m Series1Series2Series3Series4Series5Series6

32RC – Ispra

Effect of Thermodenuder - MT002-M-50 (2 strokes - Injection) Number/Size Distribution - Constant Speed: 40 km/h

0

1E+12

2E+12

3E+12

4E+12

5E+12

6E+12

7E+12

8E+12

9E+12

1 10 100 1000Electrical Mobility Diameter (nm)

[dN

/dlo

g D

p]/k

m

Without ThermodenuderThermodenuder Switched OffThermodenuder Switched OnDilution air

33RC – Ispra

Conclusions:

• The engine technology has a huge effect on particulate emissionsfrom mopeds

• Pre-Euro1 conventional 2-stroke engines emit high masses and numbers of particulate matter.

• There is some potential to reduce these levels using 2-stroke engines with direct injection and/or catalytic converters technologies.

• All 4 stroke engines, even the less modern ones, emit masses of particulate matter comparable to those observed for gasoline passenger cars

• On going works now focusing on:• 1. Toxicity of PM (also for passenger cars), performing chemical

analysis of the PM emissions• 2. Limits of the instruments (Repeatability from test bench to test

bench, Detection limits)