Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010Date of issue: 04/09/2015 Revision date: : Version: 1.0

04/09/2015 EN (English US) 1/8

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifierProduct form : MixtureProduct name : Phthalic Anhydride StandardProduct code : AL0-130005Product group : Trade product

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified usesMain use category : Laboratory UseIndustrial/Professional use spec : Industrial

For professional use only

1.2.2. Uses advised againstNo additional information available

1.3. Details of the supplier of the safety data sheetPhenova6390 Joyce Dr. Suite 10080403 Golden, CO - United StatesT 1-866-942-2978 - F 1-866-283-0269info@phenova.com - www.phenova.com1.4. Emergency telephone numberEmergency number : ChemTel Assistance (US/Canada) 1-800-255-3924

ChemTel Assistance (International) +1 813-248-0585

SECTION 2: Hazards identification2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flam. Liq. 2 H225Eye Irrit. 2 H319Carc. 2 H351

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]Carc.Cat.3; R40F; R11Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effectsNo additional information available

2.2. Label elements

Labeling according to Regulation (EC) No. 1272/2008 [CLP]Hazard pictograms (CLP) :

GHS02 GHS07 GHS08

Signal word (CLP) : DangerHazardous ingredients : Methylene ChlorideHazard statements (CLP) : H225 - Highly flammable liquid and vapor

H319 - Causes serious eye irritationH351 - Suspected of causing cancer

Precautionary statements (CLP) : P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understood

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

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P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. NosmokingP233 - Keep container tightly closedP240 - Ground/bond container and receiving equipmentP241 - Use explosion-proof electrical/ventilating/lighting/… equipmentP264 - Wash ... thoroughly after handlingP280 - Wear protective gloves/protective clothing/eye protection/face protectionP303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water/showerP305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsingP308+P313 - IF exposed or concerned: Get medical advice/attentionP337+P313 - If eye irritation persists: Get medical advice/attentionP370+P378 - In case of fire: Use ... to extinguishP403+P235 - Store in a well-ventilated place. Keep coolP405 - Store locked upP501 - Dispose of contents/container to ...

EUH phrases : EUH208 - Contains phthalic anhydride(85-44-9). May produce an allergic reactionNo labeling applicable

2.3. Other hazardsNo additional information available

SECTION 3: Composition/information on ingredients3.1. SubstanceNot applicable

3.2. Mixture

Name Product identifier % Classification according toRegulation (EC) No.1272/2008 [CLP]

Methylene Chloride (CAS No) 75-09-2(EC no) 200-838-9(EC index no) 602-004-00-3

89.8 Carc. 2, H351

acetone (CAS No) 67-64-1(EC no) 200-662-2(EC index no) 606-001-00-8

10 Flam. Liq. 2, H225Eye Irrit. 2, H319STOT SE 3, H336

phthalic anhydride (CAS No) 85-44-9(EC no) 201-607-5(EC index no) 607-009-00-4

0.2 Acute Tox. 4 (Oral), H302STOT SE 3, H335Skin Irrit. 2, H315Eye Dam. 1, H318Resp. Sens. 1, H334Skin Sens. 1, H317

SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get

medical advice/attention.First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness

persist.First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayedNo additional information available

4.3. Indication of any immediate medical attention and special treatment neededNo additional information available

SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Use extinguishing media appropriate for surrounding fire.Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixtureFire hazard : Highly flammable liquid and vapor.Explosion hazard : May form flammable/explosive vapor-air mixture.

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

04/09/2015 EN (English US) 3/8

5.3. Advice for firefightersFirefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any

chemical fire. Prevent fire-fighting water from entering environment.Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnelEmergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency respondersProtective equipment : Equip cleanup crew with proper protection.Emergency procedures : Ventilate area.

6.2. Environmental precautionsPrevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning upMethods for cleaning up : Take up in absorbent material. Collect spillage.

6.4. Reference to other sectionsSee Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage7.1. Precautions for safe handlingAdditional hazards when processed : Handle empty containers with care because residual vapors are flammable.Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or

smoking and when leaving work. Provide good ventilation in process area to prevent formationof vapor. No open flames. No smoking. Use only non-sparking tools. Obtain special instructionsbefore use. Do not handle until all safety precautions have been read and understood.

Hygiene measures : Gently wash with plenty of soap and water. Remove/Take off immediately all contaminatedclothing. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond

container and receiving equipment.Storage conditions : Keep in fireproof place. Keep container tightly closed. Keep container tightly closed and in a

well-ventilated place. Keep away from any flames or sparking source.Incompatible materials : Direct sunlight. Heat sources.

7.3. Specific end use(s)No additional information available

SECTION 8: Exposure controls/personal protection8.1. Control parametersNo additional information available

8.2. Exposure controlsAppropriate engineering controls : Either local exhaust or general room ventilation is usually required.Personal protective equipment : Avoid all unnecessary exposure. Gloves. Protective clothing. Protective goggles. Safety

glasses.

Hand protection : Wear chemically resistant protective gloves. Wear suitable gloves resistant to chemicalpenetration.

Eye protection : Chemical goggles or safety glasses. Safety glasses.Skin and body protection : Wear chemically protective gloves, lab coat or apron to prevent prolonged or repeated skin

contact.Respiratory protection : Wear appropriate mask.Other information : Do not eat, drink or smoke during use.

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

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SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical state : LiquidColor : Colorless.Odor : characteristic.pH : No data availableMelting point : No data availableFreezing point : No data availableBoiling point : No data availableFlash point : No data availableAuto-ignition temperature : No data availableDecomposition temperature : No data availableFlammability (solid, gas) : Highly flammable liquid and vaporRelative density : No data availableSolubility : No data availableExplosive properties : No data availableOxidizing properties : No data availableExplosion limits : No data available

9.2. Other informationNo additional information available

SECTION 10: Stability and reactivity10.1. ReactivityNo additional information available

10.2. Chemical stabilityHighly flammable liquid and vapor. May form flammable/explosive vapor-air mixture.

10.3. Possibility of hazardous reactionsNot established.

10.4. Conditions to avoidDirect sunlight. Extremely high or low temperatures. Open flame.

10.5. Incompatible materialsNo additional information available

10.6. Hazardous decomposition productsMay release flammable gases.

SECTION 11: Toxicological information11.1. Information on toxicological effectsAcute toxicity : Not classified

phthalic anhydride (85-44-9)LD50 oral rat 1530 mg/kg (Rat)LD50 dermal rabbit > 3160 mg/kg (Rabbit)

acetone (67-64-1)LD50 oral rat 5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value)LD50 dermal rabbit 20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >7426 mg/kg

bodyweight; Rabbit; Weight of evidence)LC50 inhalation rat (mg/l) 71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value)LC50 inhalation rat (ppm) 30000 ppm/4h (Rat; Experimental value)ATE CLP (oral) 5800.000 mg/kg body weightATE CLP (dermal) 20000.000 mg/kg body weightATE CLP (gases) 30000.000 ppmV/4hATE CLP (vapors) 71.000 mg/l/4hATE CLP (dust, mist) 71.000 mg/l/4h

Methylene Chloride (75-09-2)LD50 oral rat > 2000 mg/kg (Rat; Literature study)LD50 dermal rabbit > 2000 mg/kg (Rabbit; Literature study)

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

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Skin corrosion/irritation : Not classifiedBased on available data, the classification criteria are not met

Serious eye damage/irritation : Causes serious eye irritation.Based on available data, the classification criteria are not met

Respiratory or skin sensitization : Not classifiedBased on available data, the classification criteria are not met

Germ cell mutagenicity : Not classifiedBased on available data, the classification criteria are not met

Carcinogenicity : Suspected of causing cancer.May cause cancer

Reproductive toxicity : Not classifiedBased on available data, the classification criteria are not met

Specific target organ toxicity (single exposure) : Not classifiedBased on available data, the classification criteria are not met

Specific target organ toxicity (repeatedexposure)

: Not classifiedBased on available data, the classification criteria are not met

Aspiration hazard : Not classifiedBased on available data, the classification criteria are not met

Potential Adverse human health effects andsymptoms

: Based on available data, the classification criteria are not met.

SECTION 12: Ecological information12.1. Toxicity

phthalic anhydride (85-44-9)LC50 fish 2 56 mg/l (LC50; 96 h; Pisces)EC50 Daphnia 2 71 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna;

Fresh water)Threshold limit algae 1 >= 100 mg/l (NOEC; EU Method C.3; 72 h; Desmodesmus subspicatus; Static system; Fresh

water; Experimental value)Threshold limit algae 2 > 100 mg/l (EC50; EU Method C.3; 72 h; Desmodesmus subspicatus; Static system; Fresh

water; Experimental value)

acetone (67-64-1)LC50 fish 2 5540 mg/l (LC50; EU Method C.1; 96 h; Salmo gairdneri; Static system; Fresh water;

Experimental value)EC50 Daphnia 2 12600 mg/l (LC50; Other; 48 h; Daphnia magna; Static system; Fresh water; Experimental

value)

Methylene Chloride (75-09-2)LC50 fish 1 193 mg/l (LC50; 96 h; Pimephales promelas)EC50 Daphnia 1 168.2 mg/l (EC50; 48 h)

12.2. Persistence and degradabilityPhthalic Anhydride StandardPersistence and degradability Not established.

phthalic anhydride (85-44-9)Persistence and degradability Readily biodegradable in water.Biochemical oxygen demand (BOD) 1.26 g O₂/g substanceThOD 1.51 g O₂/g substanceBOD (% of ThOD) 0.83

acetone (67-64-1)Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under

anaerobic conditions. No (test)data on mobility of the substance available.Biochemical oxygen demand (BOD) 1.43 g O₂/g substanceChemical oxygen demand (COD) 1.92 g O₂/g substanceThOD 2.20 g O₂/g substanceBOD (% of ThOD) 0.872 (20 days; Literature study)

Methylene Chloride (75-09-2)Persistence and degradability Not readily biodegradable in water. Biodegradable in the soil.

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

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12.3. Bioaccumulative potentialPhthalic Anhydride StandardBioaccumulative potential Not established.

phthalic anhydride (85-44-9)BCF fish 1 71.87 (BCF; 24 h; Gambusia affinis)BCF other aquatic organisms 2 39.46 (BCF; 24 h; Daphnia magna)Log Pow 1.6 (Experimental value; Other)Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

acetone (67-64-1)BCF fish 1 0.69 (BCF)BCF other aquatic organisms 1 3 (BCF; BCFWIN)Log Pow -0.24 (Test data)Bioaccumulative potential Not bioaccumulative.

Methylene Chloride (75-09-2)BCF fish 1 2 - 40 (BCF)Log Pow 1.25 (Experimental value)Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

12.4. Mobility in soil

acetone (67-64-1)Surface tension 0.0237 N/m

Methylene Chloride (75-09-2)Surface tension 0.028 N/m (20 °C)Ecology - soil May be harmful to plant growth, blooming and fruit formation.

12.5. Results of PBT and vPvB assessmentNo additional information available

12.6. Other adverse effectsAdditional information : Avoid release to the environment

SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.Additional information : Handle empty containers with care because residual vapors are flammable.Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport informationIn accordance with ADR / RID / IMDG / IATA / ADN14.1. UN numberUN-No. (ADR) : 1992UN-No.(IATA) : 1992

14.2. UN proper shipping nameProper Shipping Name (ADR) : FLAMMABLE LIQUID, TOXIC, N.O.S.Proper Shipping Name (IATA) : FLAMMABLE LIQUID, TOXIC, N.O.S.Transport document description (ADR) : UN 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), II, (D/E)

14.3. Packing group

Class (ADR) : 3Classification code (ADR) : FT1Class (IATA) : 3Subsidiary risks (ADR) : 6.1Hazard labels (ADR) : 3, 6.1

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

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Hazard labels (IATA) : 3, 6.1

14.4. Packing groupPacking group (ADR) : IIPacking group (IATA) : II14.5. Environmental hazardsOther information : No supplementary information available.

14.6. Special precautions for user

14.6.1. Overland transportHazard identification number (Kemler No.) : 336Classification code (ADR) : FT1Orange plates :

Special provision (ADR) : 274Transport category (ADR) : 2Tunnel restriction code (ADR) : D/ELimited quantities (ADR) : 1lExcepted quantities (ADR) : E2

14.6.2. Transport by seaNo additional information available

14.6.3. Air transportCAO packing instructions (IATA) : 364CAO max net quantity (IATA) : 60LPCA packing instructions (IATA) : 352PCA Limited quantities (IATA) : Y341PCA limited quantity max net quantity (IATA) : 1LPCA max net quantity (IATA) : 1LPCA Excepted quantities (IATA) : E2ERG code (IATA) : 3HP

14.6.4. Inland waterway transportCarriage prohibited (ADN) : No

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

Contains no substances with Annex XVII restrictionsContains no REACH candidate substanceContains no REACH Annex XIV substances.

15.1.2. National regulationsNo additional information available

15.2. Chemical safety assessmentNo chemical safety assessment has been carried out

SECTION 16: Other information

Phthalic Anhydride StandardSafety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

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Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THECOUNCIL of 16 December 2008 on classification, labeling and packaging of substances andmixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amendingRegulation (EC) No 1907/2006.

Other information : None.

PHV SDS EU

Copyright 2015 Phenova, Inc. License granted to make paper copies for internal use. The information contained in this Safety Data Sheet is based on our current knowledge. The informationcontained in this document should be used only as a guide for appropriate safety precautions and should not be considered to be all inclusive. Users should make their own investigation todetermine the suitability of the information for their particular purposes. The document does not represent any guarantee of the properties of the product. Phenova, Inc. shall not be held liable forany damage resulting from the handling or use of this product. Visit the Terms and Conditions of Sale link at www.phenova.com for additional terms and conditions of sale.