PC KAO 2007

8/9/2019 PC KAO 2007

1/29

8/9/2019 PC KAO 2007

2/29

8/9/2019 PC KAO 2007

3/29

T h e m issio n o f K ao C h em icals Eu ro p e, in lin e w ith th e m issio n

o f K ao Jap an , co n sists o f fu lfillin g m arket req u irem en ts a n d

custom er expectation s by m ean s of the develop m en t, p rod uction

an d m arketing of p rodu cts, ach ievin g a reaso n ab le level of profit

an d co n stan tly im p ro vin g its o w n co m p etitive p o sitio n an d

con tribu ting to the develop m ent of the p eop le w ho m ake up the

co m p an y, w ith in a fram ew o rk of fu ll resp ect fo r th e so cial an d

n atu ral en viro n m en t.

K a o ' s G e n e r a l M i s s i o n S t a t e m e n t

BRINGING NEW VALUE

TO CHEMICALS

8/9/2019 PC KAO 2007

4/29

Kao Corporation is a Japanese com pany with m ore than a century of

experience in the cosm etics and detergents m arket, having now adays m ore

than 30 affiliates w orldw ide.

Kao has been present in the surfactants m arket in Europe for m ore than 35

years now. In the year 2000 , at the gateway to the new m illennium , Kao's

Chem ical D ivision united their European production centres in a new head

office, Kao C hem icals Europe, in B arcelona, Spain.

Kao C hem icals Europe has been created to unite the efforts of the different

centres, in order to gain efficiency and strength in a m arket that is becom ing

m ore and m ore dem anding and com petitive.

W ith years of experience and the m ost advanced technology, Kao produces

and com m ercialises in Europe m ore than 400 different surfactants, which

can be applied in m any different fields.

In the developm ent and design stage, as w ell as in the m anufacturing

process of these surfactants, Kao is com m itted to health, safety and the

environm ent. In its corporate activities Kao continuously im proves and

im plem ents m easures that m inim ise the im pact on the environm ent and

ensure the safety and the health of its em ployees and the com m unity. Kao

is com m itted to Responsible Care.

The aim of this review is to describe the m ost relevant fam ilies of surfactants

com m ercialised by Kao Ch em icals Europe, and to point out the benefits

and advantages of each one considering their properties and final applications.

See below an overview of the interconnecting process steps that Kao uses

to produce these surfactants.

Introduct ion

Propoxylation

Ethoxylation

Esterification

Amidation

Glycerides

Fatty Acids

Fatty Alcohols

Fatty Amines

ANIONIC

NON-IONIC

CATIONIC

AMPHOTERIC

BLENDS

Oxidation

Sulfatation

Carboxylation

Quaternisation

Sulfonation

Blending

Table of Contents

TRADEMARK

Introduct ion 3

Main Surfactants :

EMAL (Sulfated derivatives) 4

ALFANOX (Sulfonated derivatives) 4

Co-Surfactants :

SUCC IDET (Disodium Laureth Sulfosuccinate) 5

AKYPO (Ether Carboxylat e derivat ives) 6

O XIDET (Amine Oxides) 9

BETADET (Betaines) 10

L EV E N O L (Glyceri ne Ester derivatives) 13

Thickeners:

AM IDET (Amide derivatives) 16

Condit ioners:

Q U A R TA M IN (Ammonium Chlori de Quats) 18

A M ID E T APA22 (Amido Amine) 18

T E TR A N Y L (TEA Esterquats) 18

K A L C O L (Fatty Alcohols) 21

Pearlizing Agents:

D A N O X (EGDS blends) 22

AKYPO SAL(EGDS blends) 22

Moistur izers:

LEVENO L (Glycerine Ester derivatives) 24

EM A N O N (PEG-7 Glyceryl Cocoate) 24

Solubi lizers - Emulsi f iers

AKYPO S O F T(Ether Carboxylat e derivat ives) 26

AKYPO R LM (Ether Carboxylic acids) 26

K A O P A N (Sorbitan derivatives) 27

FIN DET (Fatty Alcohol Ethoxylates) 27

APPLICATION

SHAMPOO

N orm al 29

Baby - Children 30

Anti-D andruff 31

2 in 1 32

H air G loss 34

HAIR CONDITIONER

N orm al - M ask 35

Transparent 38

Cold Process 38

Leave-on 39

BODY CLEANSERS

H and Liquid Soap 40

Face Cleanser 41

D erm oConcept 42

M oisturizing 44

SLES-Free 45

OTHERS

Body Care 46

Bath O il 47

W et W ipes 48

Shaving Foam 48

Hair Coloring - Temporary 49

Hair Coloring - Perm anent 50

CATEGORY

ANIONIC

CATIONIC

AMPHOTERIC

NON- IONIC

BLENDS

SPECIALITIES

2 3

8/9/2019 PC KAO 2007

5/29

An ionic surfactants are usually used as m ain surfactants in rinse-off products and

cleansers for personal hygiene, due to their relatively high effectiveness-cost ratio and

their unbeatable properties as foam ing agents. Am ong this range, sodium laureth

sulfate is the m ost used w orldw ide, due to its foam ing capacity and its ability to be

thickened even at low concentration.

Kao Chem icals Europe is one of the biggest producers of this surfactant worldw ide,

selling it under the trade nam e of EM AL 270D . This product achieves the highest

standards of quality, due to the com bination of natural raw m aterials, technology and

the experience conferred by m ore than 30 years of constant im provem ent in production.

It is very difficult to overcom e the application properties of the above m entioned surfactant,

but in som e especial cases, due to m arketing requirem ents, other m inor surfactants can

replace it and be used as m ain surfactant in rinse-off products. These are alkyl sulfates

(EM AL 30E, EM AL 40TE ) or- olefin sulfonates (ALFAN O X 46).

Another typical application of anionic surfactants is toothpaste. M any, though not all,

toothpastes contain sodium lauryl sulfate, in solid form , as foam ing agent. This product

is sold by Kao Chem icals Europe under trade nam es of EM AL 10N , EM AL 10 P-H D

and EM AL 10 G . They aid in rubbing dental plaque and food off of the teeth, they can

elim inate or m ask undesirable breath odours, and they can deliver active ingredients

such as fluoride to prevent tooth and gum disease.

E M A L / A L F A N O X

PROPERTIES

Foaming Power

Emulsifying Effect

Cleansing Effect

MAINAPPLICATION

M a i n s u r f a c t a n t s

600

400

200

0EMAL30E ALFANOX46 SUCCIDETNESEMAL40TE EMAL270D

Irritant II

500 < ZV < 600

Irritant I

400 < ZV < 500

Moderately

Irritant

200 < ZV < 400

Non Irritant

ZV < 200

Ze i n Va l u e (mg N / 100 mL )

AKYPOSOFT100 BVC

AKYPOFOAMRL 40

S K I N I R R I T A T I O N P O T E N T I A L : Z e i n T e s t 1% d r y ma t t e r so l u t i o n

ANIONICSURFACTANTS

4 5

A N I O N I C S U R F A C T A N T S R a n g e

Trademark CAS Number INCI NameAppearance % Active

at 20C Matter

ALFANOX 46 68439-57-6 Sodium C14-16O lefin Sulfonate Liquid 38

EMAL 10N 73296-89-6 Sodium Lauryl Sulfate N eedles 95 m in.

EMAL 10P-HD 73296-89-6 Sodium Lauryl Sulfate Pow der 95 m in.

EMAL 10G 73296-89-6 Sodium Lauryl Sulfate G ranules 95 m in.

EMAL 30E 73296-89-6 Sodium Lauryl Sulfate Liquid 30

EMAL 40TE 90583-18-9 TEA Lauryl Sulfate Liquid 40

EMAL 270D or

EMAL 270E68585-34-2 Sodium Laureth Sulfate Paste 70

EMAL 227E or

EMAL 228D68585-34-2 Sodium Laureth Sulfate Liquid 27

SUCCIDET NES or

SUCCIDET S 3 039354-45-5 Disodium Laureth Sulfosuccinate Liquid 31

S U C C I D E T

The disodium laureth sulfosuccinate is an anionic surfactant which can be u sed

as m ain surfactant, altho ugh it is typically used as co -surfactant in cosm etic

cleansers, m ainly due to its m ildness and the capacity to reduce the skin and eye

irritation potential of anionic surfactants. Kao produces it under the trade nam e

of SUC CID ET .

8/9/2019 PC KAO 2007

6/29

C o - s u r f a c t a n t s

A K Y P O

A different type of anionic surfactants is the ether carboxylic derivatives. AK YP O is

a tradem ark used to den om inate the alkyl ether carboxylic acids and their salts.

The products included in the range d iffer from each other in the degree of ethoxylation

and in the alkyl chain length. For cosm etic applications vegetable origin is in favour,

the alkyl chain being traditionally based on coconut (C12/14) becau se of the high

foam ing properties that are required in this application field. D ifferent ethoylation

degrees are available am ong the range of AKYPO .

The nam e of AKYPO RLM is used for the ether carboxylic derivatives in con centrated

acid form . AK YPO SO FT is used for the n eutralised form of these surfactants. The

abbreviation N Vat the end ind icates a sod ium salt, w hile the abbreviation BVC

indicates a high concentrated sodium salt alkyl ether carboxylate.

In the early 1970s the go od com patibility of alkyl ether carboxylates, used as co-

surfactants in sham poos, with all kind of surfactants including cationic type w as

described in the literature. A n explanation for this un usu al behaviour for anionic

surfactants is the form ation of a five-m em bered ring after deprotonation. Because

of this structure, alkyl ether carboxylates are com bining the prop erties of anionic and

no n-ionic surfactants an d are therefore called cryptoanionic.

The ethercarboxylic d erivatives w ith C 12/14 alkyl chain, from natural sources, are

characterised by their m ildness, their foam ing and their solubilizing ben efits, therefore

they are used as co-surfactants in cosm etic rinse-off products.

PROPERTIES

Mildness

Solubilizing Effect

Foam Stabilizing Effect

Compatibility

Cryptoanionic Character

CHEMICAL

STRUCTURE R-(OCH2CH2)n-OCH2-C

Na(+)

O

O(-)

6 7

MAINAPPLICATION

The newly developed alkyl ether carboxylate derivative is AK YP O FO AM RL 40. This

product m eets the m arket requirem ents of a good surfactant: high concen trated,

preservative free, m ildness, positive influen ce o n the viscosity and rapid foam ing

w ith good lathering. This relevant influen ce on the foam is even m ore outstand ing

when AKYPO FO AM RL 40 is com bined w ith SLES and am photeric surfactants.

M I O I - V a l u e

1% a.m. solution

CAPB1 AKYPORLM 45 AKYPOR LM 10 0 De cy l Gl uc os id e

M I L D N E S S : E y e s I r r i t a t i o n P o t e n t i a l R B C T e s t

30

25

20

15

10

5

0100 80 60 40 20 0

100% An ion ic Rat io An ionic / Co-Surfact an t % 100% Co-sur fact an t

F o a m V o l u m e ( m L )1% a.m. solution

CAPB 1 CAMA 1 Cocamide DEA SLES 1 AKYPOFOAM RL 40

F O A M I N G S P E E D

300

250

200

150

100

50

0

50 100 150 200 250 300 350 400 450 tim e (sec)

B r o o k f i e l d V i s c o s i t y ( L V T , 2 0 C , c P s )

15% a.m.; rat io SLES/ Co-surfactant 3/ 1

SLES SLES/AKYPOFOAM RL 40

T H I C K E N I N G E F F E C T

100000

10000

1000

1000.0 1.0 2.0 3.0 4.0 5.0

(1) CAPB: Cocamidopropy l Betaine

CAMA: Sodium Cocoamphoacetate

SLES: Sodium Laureth Sulf ate

% NaCl

8/9/2019 PC KAO 2007

7/29

A K Y P O S OF T R a n g e :

Trademark CAS Number INCI Name R nA pp ea ra nc e % A c ti ve

at 20C Matter

AKYPO FOAM RL 40 33939-64-9 Sodium Laureth-5 Carboxylate C12 4 Paste 60

AKYPO SOFT 45 NV 33939-64-9 Sodium Laureth-6 Carboxylate C12-14 5 Liquid 22

AKYPO SOFT 100 NV 33939-64-9 Sodium Laureth-11 Carboxylate C12-14 10 Liquid 22

AKYPO SOFT 70 BVC 33939-64-9 Sodium Laureth-8 Carboxylate C12-14 7 Paste 70

AKYPO SOFT 100 BVC 33939-64-9 Sodium Laureth-11 Carboxylate C12-14 10 Liquid 70

0.1% a.m .; 25C; 15GH; pH = 6 .5; t =30 sec.F O A M V O L U M E : R o s s M i l e s T e s t

Foam Vo l ume (mL )

Rat io SLES(1) / CAMA (1)/ AKYPOFOAM RL 40

3/0/1 3/1/0 3/0.75/0.25 3/0.5/0.5

200

180

160

140

120

100

80

60

40

200

A K Y P O R LM R a n g e :

Trademark CAS Number INCI Name R nA pp ea ra nc e % A c ti ve

at 20C Matter

AKYPO RLM 45 CA 27306-90-7 Laureth-6 Carboxylic Acid C12-14 4.5 Liquid 92

AKYPO RLM 45 N 27306-90-7 Sodium Laureth-6 Carboxylate C12-14 4.5 Paste 82

AKYPO RLM 70 2730 6-90 -7 Laureth-8 C arboxylic A cid C 12-14 7 Liquid 90

AKYPO RLM 100 27306-90-7 Laureth-11 Carboxylic Acid C12-14 10 Liquid 90

Am ine oxides have been well know n to surfactant chem ists for decades. These surfactants are

characterised by their versatility.

Am ine oxides are obtained by a reaction of a tertiary am ine w ith hydrogen peroxide. The sem i-

polar bond between the nitrogen and the oxygen is responsible for m uch of the uniqueness an d

functionality of am ine oxides.

Am ine oxides are non-ionic, but when the pH is low ered, the sem i-polar linkage becom es stronger and

the m olecule assum es a weak positive charge, becom ing a cationic surfactant with conditioning properties.

The Kao Chem icals Europe 's tradem ark for am ine oxides is O XIDET .

They are used as co-surfactants in foam ing cleansers, like sham poos or body gels. Com pared to typical

surfactants used in detergents like CAPB or cocam ide D EA, O XIDET L-75 provides h igher foam .

Mixt ures SLES / Co-surfactant (8.5/1.5, total a.m .: 10%)

20C; 20H F; 1% w/ v solu ti on

F O A M I N G A B I L I T Y : R o s s M i l e s T e s t

Foam Vo l ume (mL )

CAPB OXIDETL-75

250

200

150

100

50

0

5 sec. 5 min.

O X I D E T R a n g e :

Trademark CAS Number INCI NameA pp ea ra nc e % A ct iv e

Rat 20C Matter

OXIDET DM-20 1643-20-5 Lauram ine O xide Liquid 30 C12

OXIDET DMCLD 61788-90-7 Cocam ine O xide Liquid 30 Coconut

OXIDET L-75 68155-09-9 Cocamidopropylam ine Oxide Liquid 30 R'-CO: Coconut

8 9

MAINAPPLICATION

O X I D E T O X I D E T A K Y P O

PROPERTIES

Foam Booster

Thickener

Mild Surfactant

Emulsifier

OXIDETDM type OXIDETL-75

CH3

CH3

I

IR-N O

CH3

CH3

I

IR-CO-NH-(CH2)3-N O

CHEMICAL

STRUCTURE

8/9/2019 PC KAO 2007

8/29

B E T A D E T

Alm ost since their introduction on the m arket, am photeric surfactants have been

used in personal care products.

It is w ell know n that betaines show, in general m ildness, good pH stability, and

hard w ater tolerance. They increase the viscosity when com bined w ith anionic

surfactants, and act as foam boosters.

Kao Chem icals Europe's tradem ark for this group of surfactants is BETAD ET .

Cocam idopropyl betaine (CAP B) is by far the m ost used Betaine, not only due to

the low cost but also to its effectiveness.

PROPERTIES

Skin Compatible

Foam Booster

Thickening Agent

Detoxification Effect

Hard Water Tolerance

B r o o k f i e l d V i s c o s i t y ( 2 0 C , c P s )

10% a.m. SLES / 3% a.m.Co-surfactantT H I C KE N I N G E F F E C T

1000000

100000

10000

1000

100

100.0 1.0 2.0 3.0 4.0 5.0

CAPB BETADET SHR BETADET S-20 0% Co-surfactant

% N a C l

Besides the CAPB (BETAD ET H R and BETADET H R-50K), sulfobetaines or hydroxysultaines m ust be pointed out. H ydroxysultaines

are trialkyl am m onium com pounds sim ilar to alkylbetaines but having an alkylsulfonate group. These surfactants present added

advantages com pared to standard CA BP. Kao Chem icals Europe's tradem arks are BETA D ET S-20 and BETAD ET SHR.

Alm ost since their introdu ction on the m arket, am pho teric surfactants have been used in personal care products.

Thickeningimprovement

Foam booster

Vegetableand mineral raw

materials

Excellent stability atextreme pH and

cold temperatures

Preservative freeLime soap

dispersing agent

Compatible with Anionic, Cationic andNon-ionic surfactants

Very mild co-surfactants, which show detoxifying properties andespecially suitable for non-irritating and baby products

BETADETSH R&

BETADETS-20

10% a.m. SLES + 3% a.m . Co-surfactant

0.1% a. m. sol ut ion ; 25C ; 200 ppm Ca2+/ M g2+, 2/1

F OAM QUAL ITY : Bub b l in g M ethod

Dens i t y ( g /m L )

SLES CAPB BETADETS-20 BETADETSHR BETADETTHC-2

6.6

6.4

6.2

6.0

5.8

5.6

5.4

5.2

5.0

B E T A D E T R a n g e :


at 20C Matter

BETADET HR 61789-40-0 Cocam idopropyl Betaine Liquid 30

BETADET HR-50K 61789-40-0 Cocam idopropyl Betaine Liquid 40

BETADET S-20 13197-76-7 Lauryl H ydroxysultaine Liquid 38

BETADET SHR 68139-30-0 Cocam idopropyl Hydroxysultaine Liquid 44

BETADET THC-2 68650-39-5 Disodium Cocoam phodiacetate Viscous Liquid 40

10 11

CHEMICAL

STRUCTURE

CH3

CH3

R-N+-CH2-CH-CH2SO3-

OH

I

I I

R: C 12

CH3

CH3

R-CO-NH-(CH2)3-N+-CH2-CH-CH2SO3-

OH

I

I I

R-CO= Hydrogenated Coconut

BETADETS-20BETADETSHR

8/9/2019 PC KAO 2007

9/29

B E T A D E T

Foam Stabili ty in the presence of sebum; 10% a.m. SLES + 3% a.m. Co-surfactant

0.1% a.m. soluti on; 40C; 200 ppm Ca2+/ Mg2+, 2/1; 0.5% Sebum

F O A M V O L U M E : " F o a m i n g R e v e r s e S t i r r i n g M e t h o d "

200

180

160

140

120

100

80

60

40

20

0SLES (0.1%) CAPB BETADETS-20 BETADETSHR APG 1

Foam Vo lume (mL) 30 sec. 1 min. 3 min. 5 min.

12 13

MAINAPPLICATION

PROPERTIES

Ecological-No LabellingNeeded

No R or S Sentences

Non-irritant for the Skin

Non-irritant for the Eyes

Vegetable Origin

Preservative Free

APPLICATION

Body Cleansers

Liquid Hand Soaps

Shampoos

Facial Cleansers

Skin Care

LEVENOL H&B

Foam Booster

Thickener

Skin Emollient

N on-ionic surfactants have been used by the cosm etic industry for m any years and

for m any different applications. A fundam ental requirem ent for any cosm etic produ ct

is the need for high skin com patibility under norm al conditions of use. The addition

of a secondary surfactant in a cosm etic form ula to im prove the physico-chem ical and

toxicological properties of the m ain surfactant, as w ell as its final perform ance, is

alm ost an obligation. LEVEN O L , registered trade nam e of KAO for a new range of

non-ionic surfactants, m eet these dem and s.

Chem ically, LEVEN O L is a glycerine po lyoxyethylene ester. The different degrees of

ethoxylation and esterification provide a w ide range of products w ith m any different

application properties regarding foam ing and thickening ability, solubilization and

em ulsifying capability and m oisturising effect.

The LEVENO L range is characterised by its ecological and toxicological advantages

w hen com pared w ith other non-ionic surfactants. The surfactants included in the

LEVENO L range don't need any risk and safety phrase warnings on its label, even

at 100% concentration. This fact m akes them very suitable for environm entally friend ly

cosm etics, which therefore can achieve better classification according to the European

D irective o f Preparations (1999 /45/EC).

LEVENO L prod ucts are also included in the p ositive list of Bra M iljval (good

environm ental choice) in the N ordic cou ntries.

CHEMICAL STRUCTURE

CH2O(CH2CH2O)xRICHO(CH2CH2O)yR

ICH2O(CH2CH2O)zR

R = H or R'-CO(Coconut chain)x+y+z=2

Am ong all the surfactants included in the LEVEN O L range, the o ne w hich is

recom m ended as co-surfactant is LEVEN O L H & B .

LEVENO L H & B is a m ultifunctional raw m aterial for toiletries perform ing as a thickener,

foam booster, skin an d hair m oisturizer and also em ollient. It perform s as detoxifying

agent when com bined w ith anionic surfactants.

Besides these properties as co-surfactant in cleansers it can be also used as em ollient

and em ulsifier in leave-on or any skin care products.

LEVENO L C-201 is a good solubilizer for oils, perfum es, fragrances and som e silicones.

L E V E N O L

MAINAPPLICATION

Z e i n Va l u es (mg N / mL )

M I LDN ES S : S k i n I r r i t a t i o n P o t en t i a l " Z e i n T es t "

800

700

600

500

400

300

200

100

00 2 4 6 8 10 12

SDS (1) CAPB BETADET SHR BETADET S-20

Concentration (% dry matter)

Irritant II I

ZV > 600

Irritant II

500 < ZV < 600

Irritant I

400 < ZV < 500

Moderately Irritant

200 < ZV < 400

Non Irritant

ZV < 200

(1) APG: Decyl Glucos ide

SDS: Sodium Dodecyl Sulfate

8/9/2019 PC KAO 2007

10/29

L E V E N O L R a n g e

Trademark CAS Number INCI NameAppearance % Active Properties

at 20C Matter & Application

LEVENOLH&B 68201-46-7 Glycereth-2 Cocoate Liquid 100G ood Foam ing & Thickening

Skin Em ollient

LEVENOLC-301 68201-46-7 Glycereth-7 Cocoate Liquid 100M edium Foam ing

& T hickening

LEVENOLC-201 68201-46-7 Glycereth-17 Cocoate Liquid 100 Solubilizing Effect

SLES 10% a.m.

0.8% a.m . Solu t i on; 40 C; 20HF; 1% Spangl er Soi l

F O A M V O L U M E : " F o a m i n g R e v e r s e S t i r r i n g M e t h o d "

100

80

60

40

20

0

0.5 1.0 3.0 5.0

Foam Vo l ume (mL )

LEVENOLH&B Cocamide DEA Decyl Glucoside

L E V E N O L

20C ; 20H F

FO A MIN G Q U A LIT Y: B u bb l i ng Me t h o d

Dens i t y ( g /m L )

SLES ( 10% a .m. ) +2% a. m. LEVENOLH &B +2% a.m. Decyl Glucoside

14

12

10

8

6

4

2

0

T ime t o f o rm 2L o f f o am (m i n . )

t ime (m in . )

Broo kf i eld Vi scosi ty ( LVT, 20C, cPs)

10% a.m. SLES / 2% a.m. Co-surfactantT H I C K E N I N G E F F E C T

100000

10000

1000

1001.0 2.0 3.0 4.0 5.0 6.0 7.0

LEVENOL H&B Decy l Glucoside Cocam ide DEA S LES (1 0% a .m. )

% NaC l

2% a.m . SLES + 2% a.m. Co-sur f ac t an t ; 48 hours

% vs SLS i r r i t a t i on leve l

S K I N I R R I T A T I O N P O T E N T I A L : P a t c h T e s t

I r r i t a t i o n I n de x (% )

SLS SLES + Cocamide DEA + Decyl Glucoside + LEVENOLH&B WATER(reference)

100

80

60

40

20

0

14 15

3.0

2.5

2.0

1.5

1.0

0.5

0

t ime (m in . )

8/9/2019 PC KAO 2007

11/29

AMIDET N

R-CO-NH-(CH2CH2O)nH

T h i c k e n e r s

A M I D E T

The Kao C hem icals Europe's tradem ark for alkano lam ides an d their derivatives is

AM IDET .

In the cosm etic field, alkanolam ides are w ell known for their ability to greatly enh ance

the viscosity of aqueous so dium alkyl sulfate and alkyl ether sulfate solutions.

Alkanolam ides are also characterized by their excellent foam boosting and stabilizing

properties.

Cocam ide DEA (AM IDET B -112) has been the m ost used alkanolam ide for years,

as viscosity enh ancing agent and foam boo ster, due to its liquid appearance and its

goo d p rice-perform ance ratio.

Co ncerns over the safety of secondary alkanolam ides h ave led to a steady decline on

their use and new alternatives have been introduced in the m arket using D EA -free

concept. Cocam ide M EA (AM ID ET A-111-P) is one of the alternatives in spite of its

solid appearance and high m elting p oint.

In Kao Chem icals Europe range there are also different types o f ethoxylated

m onoethanolam ides, based o n different alkyl chain and ethoxylation degree, w hich

are used in a variety of applications as em ulsifiers and solubilizers.

The m ost uniquesurfactant that Kao Ch em icals Eu rope produces is AM ID ET N .

This product is based on rapeseed o il, a vegetable oil w ith high con tent of C18

un saturated fatty acid an d is therefore liquid.

AM IDET N is highly concentrated with strong solubilizing and em ulsifying properties,

especially for silicone derivatives, perfum es and vegetable oils. Co m pared to cocam ideD EA , it is a better thickener and foam booster, being also w ash active.

An other alkanolam ide d erivative is AM ID ET A 15, which is a m odified ether carboxylic

acid. Because its unbeatable thickening effect it becom es a very good gelling agent

in h air coloration products. M oreover it also im proves the co lour up-take and the

levelling effect on the h air surface.

AMIDET A 15

R-O-(CH2CH2O)n-CH2-CO-NH-CH2CH2OH

A M I D E T R a n g e :

Trademark CAS Number INCI NameAppearance % Dry

at 20C Matter

AMIDET A-111-P 68140-00-1 Cocam ide M EA Pellets 100

AMIDET B-112 68603-42-9 Cocam ide D EA Liquid 100

AMIDET N 85536-23-8 PEG -4 Rapeseedam ide Liquid 95

AMIDET A 15 10 7628-0 4-6 Trideceth-2 C arboxam ide M EA Liquid 95

AMIDET A/17 61791-08-0 PEG -5 Cocam ide Liquid 100

AMIDET A/26 61791-08-0 PEG -14 Cocam ide Liquid 100

16 17

MAINAPPLICATION

Broo kfi eld Vi scosit y (LVT, 20C, cPs)

8.5% a.m. SLES + 1.5% Non-Ioni cT H I C K E N I N G E F F E C T

100000

10000

1000

1002.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 % NaCl

AMIDET N Cocamide DEA 0% thickener

AMIDET N

Thickener

Foam Booster

Solubilizer

Emulsifier

Mildness

AMIDET A 15

Hair Dyes Application

Levelling Agent

Gelling effect

Colour Up-take

PROPERTIES

CHEMICALSTRUCTURE

R-CO: rapeseed oil n=3 R-CO: C13/C15 n=1.5

AMIDETN vs Cocamide DEA

0.1% a.m . ; rat io SLES / N on-I onic , 3/ 1; 37C ; 15GH ;

F OA M V OL UME : R o ss Mi l es Tes t

Foam Volume (mL)

t im e (m i n . ) 0 5 10 15

250

200

150

100

50

0

AMIDET N Cocamide DEA

8/9/2019 PC KAO 2007

12/29

C o n d i t i o n e r s

Q U A R T A M I N / T E T R A N Y L / A M I D E T

H air con dition ers are used to provide a variety of benefits to hair: they redu ce the

com bing force, enhance the gloss, confer sm oothn ess and anti-static prop erties an d

they im prove the m anageability of the hair.

The ability of the cation ic com poun ds to provide co nd itioning prop erties to hair is du e

both to the hyd roph obic nature of the alkyl chain as w ell as to the cation ic charge of

the p olar head.

Particularly w ell proven are cationic surfactants having a trim ethyl am m onium group .

Am on g these products, cetrim onium chloride (C TAC), containing a cetyl alkyl chain

(C16), is one of the m ost widely used. In K ao C hem icals Europe this produ ct com es in

three different concentrations, Q U AR TAM IN 60L at 50% , Q UA RTAM IN 60W 30 at

30% and QU ARTAMIN 60W 25 at 25% .

A sim ilar structure is that of behentrim on ium chloride (B TA C), w here the alkyl fatty

chain consists prim arily of a behen ic radical (C22). This com pou nd has been u sed m ore

and m ore over the last years, due to the excellent perform ance associated to the very

long alkyl chain. Kao C hem icals Europe p roduces the behen trim onium chloride un der

the trade nam e of Q U ARTAM IN AB and a m ixture w ith cetearyl alcoh ol, w hich is

QU ARTAM IN AB K. This concen trated pre-m ix for hair rinses application com es w ithout

any kind o f solvent.

It is w ell know n that m ono alkyl com pounds p resent lim itations regarding to their eco-

toxicological properties. Kao Chem icals Europ e p roduces d ifferent en vironm entally

friend ly products, w hich are readily biodegradab le an d show also g ood properties on

aquatic toxicity.

Based on the long experience in do m estic softeners, Kao developed a special cosm etic

grade TEA -esterquat, based on oleic alkyl chain. This is TE TR AN YL CO -40.

A d ifferent esterquat produced by Kao Ch em icals Europe is based on C22 alkyl chain

and it is com m ercialised as a pure cationic surfactant, Q U AR TAM IN BTC 131, as w ell

as blended w ith cetyl alcoho l as a pre-m ix. This on e en ables the produ ction of cream

rinses just by dilution at 40C.

Trademark CAS Number INCI NameAppearance Active Matter

Solventa t 2 0 C ( Ca ti on ic , % )

QUARTAMIN60W25 112-02-7 Cetrim onium Chloride Liquid 25% W ater

QUARTAMIN60W30 112-02-7 Cetrim onium Chloride Liquid 30% W ater

QUARTAMIN60L 112-02-7 Cetrim onium Chloride Liquid 50%W ater

IPA

QUARTAMINTH-V 6 80 02-6 2-0 S teartrim o niu m C hlo ride Liqu id 50 %W ater

IPA

QUARTAMINAB 68607-24-9 Behentrim onium Chloride Pellets 85% IPA

QUARTAMINABK68607-24-9 + Behentrim onium Chloride

Pellets 35% N one67762-27-0 + Cetearyl Alcohol

QUARTAMINBTC 131 69537-38-8Behenoyl PG -Trim onium

Pasty 70%W ater

Chloride H exylene G lycol

QUARTAMINBTC 131 VC69537-38-8 Behenoyl PG-Trim onium

Pasty 30%W ater

36653-82-4 Chloride + Cetyl Alcohol H exylene G lycol

TETRANYL

CO-409409 5-35-9

D ioleoylethylLiquid 80% D PG

H ydroxyethylm onium M ethosulfate

AMIDETAPA22 60 270 -33-9 B ehenam idopropyl D im e thylam ine Pellets 10 0% N o ne

18 19

MAIN

APPLICATION

C A T I O N I C S U R F A C T A N T S R a n g e :

Ano ther class of pseudo-cation icsare am idoam ine d erivatives, which in acidic m edia present a net cationic charge and

perform as a cationic surfactant. AM ID ET AP A22, a C22 am idoam ine presents also goo d results on en vironm ental aspects

and also on effectiveness on com bing force and anti-static prop erties.

8/9/2019 PC KAO 2007

13/29

8/9/2019 PC KAO 2007

14/29

D A N O X / A K Y P O S A L

P e a r l i z i n g A g e n t s

D A N O X / A K Y P O S A L

Im age and appearance have always been very im portant and for cosm etic products even

m ore so.

Pearling agents are w idely used in cleansing cosm etic products to im prove their appearance.

By incorporating them a w hite product w ith a high shiny and brilliant app earance is

obtained.

The pearling effect gives an appearance of richness and luxury, which m akes cosm etic

products m ore attractive to consum ers. O ther reasons to use pearling agents is to hide

a hazy or slightly opaque appearance produced by the incorporation of poo rly soluble

additives.

D evelopm ent of pearling agents concentrates (PA C) is com plex and their final com position

is usually a result of a long R & D investigation and optim isation of the crystallisation

process.

M ainly, all the pearlescent concentrates found in the m arket are based on ethylene glycol

distearate (EG D S) and fatty am ides. The use of fatty am ides helps the form ation of crystals

of EG D S an d im proves the n acreous ap pearance. Recently, fatty am ides have been

abandoned due to increasing sensitivity in the m arket, and there is a trend towards m ilder

and m ore innocuous products.

Follow ing European trends in pearling agents, Kao Chem icals Europe developed D AN O X

BF-22 w ithou t alkanolam ides; the p reservative w as elim inated in D AN O X P-15 and our

m ost recent developm ent D AN O X PL-10, does not contain am ides, is preservative free,

highly concentrated and very m ild to the skin and eyes, m aintaining an excellent perform ance.Furtherm ore ingredients of the D AN O X PL-10 im prove skin and hair condition b y

increasing m oisture content.

Pearling agents concentrates (PAC) are usually added to the surfactant solution at the

end of the produ ction process at room tem perature, avoiding heating of the total solution

and the controlled crystallisation process. They save tim e and energy. Their com m on use

percentage is between 2 and 10% .

Am ong the range of Kao Chem icals Europe, AK YPO SAL 2010 S and DAN O X PAC-T are

very effective pearling agents with excellent price-perform ance ratio. Both products are based

on Cocam ide DEA. DA N O X P-15 is a very effective pearling additive, which can be used at

a very low percentage; it is based on Cocam ide M EA. D AN O X BF-22 is based on am photeric

and non-ionic surfactants therefore it is com patible with any type of surfactants. It is a very

effective pearling additive. It gives a fine silky gloss effect. Finally, D AN O X PL -10 is a new

pearling agent developed in accordance to the new m arket trends.

PROPERTIES

Pearling Effect

APPLICATION

P A C R a n g e

Trademark INCI Name % Active Matter

Sodium Laureth Sulfate

AKYPO SAL 2010 S Cocam ide DEA 36

G lycol D istearate


DANOX

PAC-TCocam ide DEA 36

G lycol D istearate

Cocam idopropyl Betaine

DANOX BF-22 Laureth-4 44

G lycol D istearate


DANOX P-15 Cocam ide M EA 40

G lycol D istearate


DANOX PL-10 G lycereth-2 Cocoate 52

G lycol D istearate

22 23

MAIN

APPLICATION

PAC as it is 3% PAC in a pink coloured water solution

8/9/2019 PC KAO 2007

15/29

M o i s t u r i z e r s

L E V E N O L / E M A N O N

Ingredients providing care ben efits for skin and hair in person al cleansing p rodu cts are

becom ing increasingly im portant. Form ulators of cosm etic products like to use com pon ents

that can provide better sensorial characteristics to these final clean sers. To m aintain the

right balance betw een em ollients and the surfactant base is im portant to achieve optim al

clean sing and lathering prop erties in rinse-off produ cts. In gen eral em ollients are used to

soften the skin.

The m ost used w ater soluble em ollient applied in hair and body sham poo s is the well-know n

ester, PEG -7 glyceryl cocoate, w hich K ao C hem icals Europe produces under the trade n am e

of EM ANO N H E.

An other w ater-soluble o il is P EG -6 caprylic/capric g lycerides, LEV EN O L N -242, wh ich is

used in bath prod ucts as re-greasing agen t, im parting a long-lasting skin feeling.

Besides the properties m entioned before of LEVEN O L H & B as co -surfactant, this non -

ionic surfactant also presents very nice properties regarding skin care. Co con ut oil has been

w idely used in co sm etics for years. Its sm all m olecular structure allow s for easy adso rption,

giving the skin a soft sm oo th texture. Coco nu t oil softens the skin, bu t protects against

dam age, prom otes healing and gives it a m ore healthy app earance and shine. The low degree

of ethoxylation in LE VEN O L H & B lead to an ester with sim ilar em ollient benefits to coco nut

oil, and w hich can be used in bo th aqu eous system s and in leave-on produ cts.

W ith LEVEN O L H & B used as co-surfactant, cosm etic form ulators can develop high quality

produ cts at low er cost, becau se there is no need for add ition al m oisturizers to b e added .

M O I S T U R I Z E R S R a n g e :


at 20C Matter

EMANON HE 68201-46-7 PEG -7 G lyceryl Cocoate Liquid 100

LEVENOL H&B 68201-46-7 G lycereth-2 Cocoate Liquid 100

LEVENOL N-242 308067-12-1 PEG-6 Caprylic/Capric Glycerides Liquid 100

FINDET LN/8750 61790-81-6 PEG -75 Lanolin Liquid 50

24 25

MAIN

APPLICATION

Re l a t i v e Conduc t a n ce

M O I S T U R I Z I N G E F F E C T : " l e a ve - o n " p r o d uc t

16

14

12

10

8

6

4

2

00 1 2 3 4 5

LEVENOLH&B EMANONHE LEVENOL N-242 Water

t i m e ( h )

S ho r t t r e a tm en t ( o n e a p p l i c a t i o n ) ;

20+-1C; 45+-5% RH

Moisturising Emulsion

Emollient 10.0%

Polysorbate 60 1.5%

Sorbitan Stearate 0.5%

Wat er Up t o 100%

Re l a t i v e Conduc t a n ce

M O I S T U R I Z I N G E F F E C T : " r in s e - o f f " p r o d uc t

1.1

1.0

0.9

0.8

0.7

0.6

0.5

t i m e ( h )

S ho r t t r e a tm en t ( o n e a p p l i c a t i o n ) ;

20+-1C; 45+-5% RH

10% LEVENOLH&B 5% LEVENOLH &B 10% Glycerine Water

0 1 2 3 4 5

Shower Gel

SLES 10.0 %

CAPB 3.0 %

Emol li en t 5 or 10 %

Water Up to 100%

8/9/2019 PC KAO 2007

16/29

S o l u b i l i z e r s & E m u l s i f i e r s

Follow ing the introduction of the 2 in 1concept in the early 90's, the use of silicones

and cationic polym ers, as w ell as the use of essential oils in personal cleansers, becam e

m ore and m ore extended. Bod y and h air cleansers are required to offer additional

properties such as a soft feel, enhanced shine or good com bing. The use of these

additives in clear aqueous form ulations such as gels, conditioners or sham poos, will

haze the solution and can eventually lead to separation. Esp ecially the silicones are

hardly em ulsified in w ater solutions such as sham poo s. To avoid haziness and prevent

separation , the use of a solubilizer is required. Surfactants usually used as solubilizers

have a high H LB and disperse clearly in w ater. They have to be u sed in the proper ratio

w ith the o il. This surfactant to oil ratio can range from 2:1 to higher, although the

optim um is based o n em pirical results.

O ne of the m ost effective solubilizers, useful to incorporate m any different type o f oils,

is PEG -40 hydrogenated castor oil, which K ao Chem icals Europe produces un der the

trade nam e of FIN D ET ARH /52. Besides this w ell know n surfactant, Kao Chem icals

Europe's product range also includes som e relevant surfactants that com bine com parable

solubilizing properties to the above m entioned product, together w ith som e additional

benefits as co-surfactants, such as foam ing ability, thickening effect or em olliency.

This is the case of som e products in the AK YPO , AM ID ET or LEVENO L fam ilies.

D etailed inform ation abo ut process-ability, com positions and ad ditional ben efits are

available upon request, as w ell as som e related publications.

S OL UB IL IZ ER S & CO- S UR F ACT ANT S R ange :


at 20C Matter

AKYPO RLM 70 33939-64-9 Laureth-8 Carboxylic A cid Liquid 90

AKYPO SOFT 70 BVC 33939-64-9 Sodium Laureth-8 Carboxylate P asty 72

AKYPO SOFT 100 BVC 339 39 -6 4-9 S od ium Lau reth -11 C arbo xylate Liqu id 72

LEVENOL C-201 68201-46-7 G lycereth-17 Cocoate Liquid 100

AMIDET A 1 5 10 76 28-0 4-6 Trideceth -2 C arbo xam id e M E A Liqu id 95

ADDITIONALPROPERTIES

Co-surfactant

Mildness

Vegetable Origin

26 27

As it is known, an em ulsion is a system of tw o or m ore im m iscible m aterials in w hich one m aterial or phase is dispersed as particles

in the other. Em ulsifying agents are required to redu ce the interfacial tension and stabilize these em ulsions. They m ay be anionic,

cationic, non-ionic or even am photeric surfactants in nature. To select the m ost convenient em ulsifier, the type of em ulsion to be

prepared has to be decided. The m ost com m on type in cosm etic produ cts today is oil-in-water (O /W ), in w hich water is the

continuous phase, resulting in a cooling effect, due to w ater evaporation, w hen it is applied d irectly to the skin. On the other hand,

w hen a water-in-oil (W /O ) em ulsion is used, the oil m akes con tact im m ediately with the skin, giving a m ore occlusive oily film and

less refreshing effect. This type of em ulsions is used in night cream s, m akeup rem overs, sunscreens, etc.

The H ydrophile-Lipophile system (H LB), developed by Griffin in 1949 , m akes the choice of the em ulsifier quite sim pler and system atic.

The H LB system is the ratio of oil-soluble and water-soluble portions of a m olecule, and it is m ainly used for non-ionic surfactants.

Kao Ch em icals Europe offers a group of sorbitan esters which are widely used as em ulsifiers, and w hich cover a wide H LB range.

This is the KA O PAN

fam ily.

Another im portant group of surfactants, w hich are m ostly used in the cosm etic field as em ulsifying agents are the fatty alcoh ol

ethoxylates. Kao Chem icals Europe produces them under the nam e of FIND ET . Alkyl chain length and ethoxylation degree are variable.

EM UL S I F I ER S & S OL UB I L IZ ER S R ange :

Trademark CAS Number INCI NameAppearance

HLBat 20C

KAOPAN SP-L10 68154-36-9 Sorbitan Laurate Liquid 8.6

KAOPAN SP-S10 1338-41-6 Sorbitan Stearate Solid-Pellets 4.7

KAOPAN SP-O10 1338-43-8 Sorbitan O leate Liquid 4.3

KAOPAN TW L120 9005-64-5 Polysorbate-20 Liquid 16.7

KAOPAN TW S120 9005-67-8 Polysorbate-60 Liquid 14.9

KAOPAN TW O120 9005-65-6 Polysorbate-80 Liquid 15.0

FINDET 1214N/23 68439-50-9 Laureth-11 & M yreth-11 Solid-Paste 14.3

FINDET 1618A/18 68439-49-6 Ceteareth-6 Solid 10.2

FINDET 1618A/35-P 68439-49-6 Ceteareth-23 Solid-Pellets 16.0

FINDET 1618A/72-P 68439-49-6 Ceteareth-60 Solid-Pellets 18.3

FINDET 1816/32-E 68920-66-1 O leth-20 & Ceteth-20 Solid 15.4

FINDET ARH/52 61788-85-0 PEG -40 H ydrogenated Castor O il Soft Paste 13.9

LEVENOL SR-152 180254-52-8 PEG -40 Sunflower G lycerides Liquid 13.2

MAIN

APPLICATION

8/9/2019 PC KAO 2007

17/29

F o r m u l a

C -024 C-073

Concentrated Mild

MAIN SURFACTANT

EMAL270D or 270E 23 ----

EMAL228D or 227E ---- 28.5

BETADETHR-50K 10 ----

CO-SURFACTANT BETADETHR ---- 10.0

AKYPOSOFT 100 NV ---- 11.5

THICKENER AMIDETB-112 1.0 ----

AMIDETN ---- 1.0

EMOLLIENT EMANONHE 0.8 ----

APPEARANCE MODIFIER DANOXP-15 3.0 ----

Preserv. / Fragr./ Dye(s) q.s. q.s.

OTHERSCi t r ic Acid / N aOH (di lu t ed) q.s. q.s.

N aCl q.s. 0.8

Deionized wat er Up t o 100% Up to 100%

Appearance Pear led Transparent

pH 6 .5 6.5

CHARACTERISTICS Viscosit y ( cPs, 20C) 8.000 2.500

D ry mat t er (%) 25.0 17.0

Cloud Point (C) ---- - 10

More detai ls about process are available upon request

PROCESS - GENERAL REMARKS:

- When EMAL270D (SLES at 70% concentrati on) is used, it is recommended to heat the water

up to around 45C before adding it.

- All t he other components are soluble in t he SLES solution.

- Add DANOXP-15 before viscosity adj ust in order to be sure about it s homogeneous incorporation.

N O R M A L S H A M P O O

For al l t he fami l y

26 2926

H a i r C a r e

B o d y C l e a n s e r s

O t h e r s

S h a m p o o

A p p l i c a t i o n s

8/9/2019 PC KAO 2007

18/29

B A B Y S H A M P O O

Keep your baby smi l ing

C-011 C-068 C-095 C-100

Without NaCl Pearled Regular Very Mild

MAIN SURFACTANT

EMAL270D or 270E ---- 12.0 ---- 12.0

EMAL228D or 227E 14.00 ---- 31.5 ----

BETADETS-20 13.0 7.5 9.0 7.0

CO-SURFACTANT LEVENOLH& B 2.0 2.0 2.0 2.0

AKYPOFOAM RL 40 ---- ---- ---- 1.5

KAOPANTW L120 1.0 ---- q.s. ----

THICKENER PEG-120 M ethyl Gl ucose Dioleate 0.6 ---- ---- ----

AMIDETN ---- 1.0 0.7 1.5

APPEARANCE MODIFIER DANOXPL-10 ---- 3.0 ---- ----

Preserv. / Fragr./ Dye(s) q.s. q.s. q.s. q.s.

OTHERSCitric Acid / NaOH (diluted) q.s. q.s. q.s. q.s.

NaCl ---- q.s. ---- ---

Deionized Water Up to 100% Up to 100% Up to 100% Up to 100%

Appearance Transparent Pearled Transparent Transparent

pH 6.5 6.5 6.5 6.5

Viscosity (cPs, 20C) 8.000 10.000 4.300 2.200 CHARACTERISTICSDry matter (%) 13.0 17.0 14.5 16.2

Cloud Point (C) - 4 ---- - 8 < - 10

Zein Test Non Irritant Non Irritant Non Irritant Non Irritant

More detail s about process are available up on request

F o r m u l a


- In t he case of ref. C-011, adjust t he final desired viscosity using PEG-120 Met hyl

Glucose Dioleate to in crease it or KAOPANTW L120 to decrease it .

30 31

A N T I D A N D R U F F S H A M P O O

Keep you hai r & scalp heal t hy

C-0 26 C-0 50 C-11 4

Zn -Pt Cl imbazo le P ir oc to ne Olam in e

EMAL270D or 270E 15.0 23.0 ----

MAIN SURFACTANT EMAL228D or 227E ---- ---- 25.0

EMAL40TE 6.0 ---- ----

BETADETHR-50K ---- 10.0 ----

CO-SURFACTANT BETADETHR 5.0 ---- ----

BETADETTHC-2 ---- ---- 5.0

AKYPO FOAM RL 40 ---- ---- 5.0

THICKENER AMIDETB-112 2.0 1.0 ----

Hydroxypropyl Cellulose 0.2 ---- ----

EMOLLIENT EMANONHE 0.8 0.8 ----

CONDITIONER TETRANYLCO-40 0.5 ---- ----

Zinc Pyrithione 1 act ive ---- ----

SPECIFIC ADDITIVE Climbazole ---- 0.5 ----

Piroctone Olamine ---- ---- 0.5

Salicylic Acid ---- ---- 0.3

TETRANYLU 0.5 ---- 1.0

APPEARANCE MODIFIER DANOXP-15 3.0 3.0 ---

Additives* q.s. q.s. q.s.

Preserv. / Fragr./ Dye(s) q.s. q.s. q.s.

OTHERS Citric Acid / NaOH (diluted) q.s. q.s. q.s.

NaCl < 1.0 q.s. q.s.

Deionized Water Up to 100% Up to 100% Up to 100%

Appearance Opaque/ pearled Transparent

pH 5.5 6.5 6.0

CHARACTERISTICS Viscosity (cPs, 20C) 5.000 8.000 4.000

Dry matter (%) 21.0 25.0 15.0

Cloud Point (C) ---- ---- - 6

F o r m u l a

More detail s about process are available upon request


- Ref. C-026 : solubilize Hydroxypropyl Cellulose into t he water avoiding lumps formation.

- Ref. C-050 : mi x Climbazol, AMID ETB-112 and EMANONHE, heating a little bit t o improve solubility.

8/9/2019 PC KAO 2007

19/29

Keep your hai r beaut y

C -0 66 C -0 72 C- 080 C - 09 3

Very Reg ula r Regu lar Af t e r

Mi l d Tr an spa ren t Pear l ed Per m

MAIN SURFACTANTEMAL270D or 270E ---- ---- 12.0 ----

EMAL228D or 227E 25.0 32.0 ---- 43.0

BETADETS-20 5.0 8.0 4.0 ----

BETADETHR ---- ---- 3.0 ---- CO-SURFACTANT

LEVENOLH& B 2.0 2.0 1.5 1.5

AKYPOSOFT 70 BVC 4.0 ---- ---- 2.0

THICKENER AMIDETN ---- ---- ---- 2.0

FOAM BOOSTER AMIDETA 15 1.0 ---- ---- ----

APPEARANCE MODIFIER DANOXPL-10 3.0 ---- 3.0 ----

QUARTAMINAB 0.5 ---- ---- ----

CONDITIONERAMIDETAPA22 ---- 0.5 ---- ----

TETRANYLCO-40 ---- ---- 0.5 ----

QUARTAMINBTC 131 ---- ---- ---- 0.2


OTHERSCitric Acid /NaOH (diluted) q.s. q.s. q.s. q.s.

NaCl (viscosity adjust) q.s. ---- 0.7 1.5


Appearance Pearled Transparent Pearled Transparent

pH 6.0 6.5 6.5 6.5

CHARACTERISTICS Viscosity (cPs, 20C) 9.000 3.700 10.500 4.000

Dry matter (%) 17.0 15.0 16.0 18.0

Cloud Point (C) ---- < - 10 ---- - 6

F o r m u l a


2 i n 1 S H A M P O O

Keep your hai r beaut y


- When EMAL270D (SLES at 70% concentr ation) is used, it is recommended

to heat t he water up to around 45C before adding it.

- All t he other component s are soluble in t he SLES soluti on wit h th e exception

of some of the condi t ioners, those which are sol id. I n th e case of

QUARTAMINAB, al l t he mixt ure has to be heated up t o 75C.

- In t he case of AMID ETAPA22 mix it wit h 10% of water and heat up to

65C. Sti r and add the blend t o the basic composition.

- In ref. C-093, mix AMIDETN, LEVENOLH&B and QUARTAMI NBTC

131 , heat u p to 50C, sti r unt i l clear and add t o the basic formula.

ADDITIVES:

- If hi gher conditioni ng effect or some specific benefits are desired, some other

addit ives can be added like: silicones , vitami ns, polymers, etc.

- To improve feeling while rinsing, our recomm endation i s to use SOFCARE

KG-101E at 0 .3%.

SOFCARE KG-101E

(Cation i c Polymer)

Hair Care Application

Foam speed &creaminess

Better feeling while rinsing

Improve detangling

Better comb-ability

Smooth hair feeling

Produced by Kao Corporation in Asia

32 33

8/9/2019 PC KAO 2007

20/29

H A I R R I N S E C O N D I T I O N E R

Condi t i on ing accord ing to your needs

34 35

H A I R G L O S S S H A M P O O

Im prove ha i r sh ine

F o r m u l a

C-067 C-078

Clear Clear

MAIN SURFACTANT EMAL227E or 228D 36.0 36.0

SOLUBILIZERAKYPOSOFT 100 BVC ---- 5.0

AKYPOSOFT 70 BVC 10 5.0

THICKENERAMIDETN 5.0 5.0

PEG-150 Distearate 0.5 ----

Guar Gum (1) 0.5 ----

CONDITIONERJojoba Oil 0.5 ----

Cyclomethicone (2) 0.5 0.5

QUARTAMINBTC 131 ---- 0.3


OTHERSCitric Acid / NaOH (diluted) q.s. q.s.

NaCl q.s. 3.0

Deionized Water Up to 100% Up to 100%

Appearance Transparent Transparent

pH 6.5 6.3

CHARACTERISTICS Viscosity (cPs, 20C) 5.000 4.000

Dry matter (%) 25.0 17.0

Cloud Point (C) - 4 - 4

(1) Hydroxypropyl Guar Hydroxypropyltrimoni um Chloride

(2) DC 245


C-067

A - Add guar gum to the water and reduce pH using citric acidto improve its incorporation. Continue adding EMAL227E.

B - Mix AKYPOSOFT 70 BVC, AMIDETN an d PEG-150Distearate at 60C.

B - Mix Jojoba oil and cyclomethicone. Stir t ill clear.

D - Add C over B.

E - Add D over A.

Continue with t he addition of t he rest of t he components.

C-078

A - Mix Jojoba oil and cyclomethicone. Stir t ill clear.

B - Mix QUARTAMINBTC 131 and AM IDETN at 75C. Stir til l clear.

C - Add B over A.

D - Add AKYPOSOFT 100 BVC.

E - Add AKYPOSOFT 70 BVC.

F - Mix EMAL228D with water.

G - Add F over E.

Continue with t he addition of t he rest of t he components.

C-054 C-056 C-053

N or ma l Ha ir Da ma ge d H air Ha ir Ma sk

CONDITIONER QUARTAMIN

AB K 4.5 6.0 9.0

CO-EMULSIFIER FINDET1618A/35-P 0.5 ---- 1.0

EXCEPARLHO/IPM ---- 0.5 2.0

EMOLLIENTLEVENOLH& B ---- 0.5 ---

Protein Derivative(1) ---- ---- 2.0

Glycerine ---- ---- 3.0

Additives q.s. q.s. q.s.

OTHERS Fragr./ Dye(s )/ Preserv. q.s. q.s. q.s.


F o r m u l a

Appearance White Emulsion

pH 3.5 - 4.5


Dry matter (%) 5.0 7.0 15.0

Cationic Active Matter(%) 1.5 2.0 3.0

More detai ls about process are availabl e upon request

(1) Hydroxypropyltrim onium Hydrolized Wheat Protein


- Heat wat er up to around 50C and add LEVENOLH&B,

FINDET1618A/35-P and glycerine.

- Continue heating ti ll 80C and add QUARTAMINABK

in f lakes and EXCEPARLHO /I PM . Keep stirring 30

minutes at 80C.

EXCEPARLHO/IPM

(Cetyl Octanoate / Isopropyl Myristate)

90 / 1 0

Emollient

Conditioner

Available upon request

8/9/2019 PC KAO 2007

21/29

Don ' t fo rge t the env i ronmen t

C- 074 C- 075 C - 076 C- 077

T hi n No r mal Da mag ed Ha ir

Ha ir H air Ha ir Mask

MAIN CONDITIONER AMIDETAPA22 1.1 1.7 2.2 3.2

NEUTRALIZER Lactic Acid (90%) 0.3 0.5 0.6 0.7

CONDITIONER & THICKENER KALCOL6850 2.2 3.3 4.4 7.0

Additives q.s. q.s. q.s. q.s.

OTHERS Fragr./ Dye(s )/ Preserv. q.s. q.s. q.s. q.s.

Deionized water Up to 100% Up to 100% Up to 100% Up to 100%

F o r m u l a


- Heat wat er up to around 75C. Add the lactic acid and then AMID ET

APA22 under stirring, avoiding air incorporation.

- Once the mi xture is clear add KALCOL6850 under stirring. Once the fatty

alcohol is completely melted keep stir ring at 75C for 30 minutes, unti l tot al

homogeneity.

- Start t he cooling process in a gradual slope (5C / 30 min.) .

- Perfume and preservative must be added at t emperat ure below 40C. Then

adjust the pH.


pH 3.5 - 4.5


Dry matter (%) 4.0 5.5 7.0 11.0

Cationic Active Matter(%) 1.3 2.0 2.5 5.5

36 37


- In order t o obtain hi gher viscosities with QU ARTAMINBTC 131 add it to

30% of the water at 6 0C. Once incorporated add fat ty alcohol and t he rest

of conditioners and emollients. After hom ogenization cool down to 40C

and then add t he rest of water and additi ves.

- In t he case of QUARTAMI NBTC 131 VC add it t o 50% of t he water at

40C. Once incorporated add the rest of condition ers and emolli ents. After

homogenization add the rest of wat er and additives.


addit ives can be added like: silicones , vitami ns, polymers, etc.

C-109 C-110 C-115

Normal Hair Dry Hair Normal Hair

Low temperature

QUARTAMIN

BTC 131 2.0 2.0 ---- CONDITIONER QUARTAMINBTC 131 VC ---- ---- 6.5

Quaternium-80 ---- 1.0 ----

CONDITIONER & THICKENER KALCOL6850 3.0 3.0 ----

EMOLLIENT LEVENOLH& B ---- ---- 0.5


OTHERS NaCl ---- 0.75 ----

Fragr./ Dye(s )/ Preserv. q.s. q.s. q.s.


F o r m u l a


pH 3.5 - 4.5


Dry matter (%) 4.5 5.75 4.0

Cationic Active Mat ter(%) 1.2 2.2 1.7


H A I R R I N S E C O N D I T I O N E R

8/9/2019 PC KAO 2007

22/29

L E A V E - O N H A I R C O N D I T I O N E RH A I R R I N S E C O N D I T I O N E R

C-060 C-008 C-007

Clear/Hot Clear/Cold Emulsion/Cold

QUARTAMINAB 1.0 ---- ----

MAIN CONDITIONER QUARTAMIN

60W25 5.0 10.0 ---- TETRANYLCO-40 ---- ---- 1.7

CO-EMULSIFIER & THICKENEROXIDETDMCLD 6.0 ---- ----

LEVENOLC-301 ---- ---- 0.5

THICKENER Hydroxyethyl Cellulose 1.2 1.0 1.0

STABILIZER Propylene Glycol ---- 2.0 2.0


Fragr./ Dye(s )/ Preserv. q.s. q.s. q.s.

OTHERS NaOH (diluted) q.s. ---- q.s.

Triethanolamine ---- 0.5 ----


F o r m u l a


- The addition of Triethanol amin e to the water reduces the incorporati on tim e

of th e Hydroxyethyl Cellulose. The percentage of this polymer depends on the

desired f inal viscosity.

- QUARTAMI NAB is a solid i n pellet s and needs to be heat ed at ar ound 75C

and mixed with the other surfactan ts before being added to the water phase.


additi ves can be added like: silicones , vitam ins, polymers, etc.

Appearance Clear Gel White Emulsion

pH 3.5 - 4.5


Dry matter (%) 5.0 3.5 3.0

Cationic Active Matter(%) 2.0 2.5 1.5


38 39

Clear Gel - Cold Pr ocess Rinse is not n eeded

F o r m u l a

C -107 C-108

Clear Emulsion

MAIN CONDITIONER AMIDET

APA22 0.5 0.96

EMULSIFIER OXIDETDMCLD 1.0 ----

THICKENER & CONDITIONER SOFCAREKG-101E 0.1 ----

KALCOL6850 ---- 2.5

STABILIZER Glycerine 1.0 1.0

EMOLLIENT Isopropyl Myristate ---- 1.0

Additives q.s. q.s.

OTHERS Fragr./ Dye(s )/ Preserv. q.s. q.s.

Lact ic acid (diluted) q.s. q.s.

Deionized water Up to 100% Up to 100%

Appearance Clear Liquid Emulsion

pH 4.0 - 4.5 4.5-5.0

CHARACTERISTICS Viscosity (cPs, 20C) 7 7000

Dry matter (%) 3.0 5.8

Cationic Active Matter(%) 0.6 1.1


- AMIDETAPA22 is a solid i n pellet s and needs to be heat ed at

around 80C. It also needs to be neutralised with lactic acid, which

is added to wat er before addition of the amide.

- OXIDETDMCLD and KALCOL6850 are also added at 80C.

- SOFCAREKG-101E must be pre-dilut ed i n water. This solut ion is

obtained by 30 minut es stirring at 50C. The polymer solution is

added at room temperature.

- All other in gredients are added at room t emperature one by one.

ADDITIVES:

- If higher condit ioning effect

or some specifi c benefits are

desired, some other additi ves

can be added like: vitamins,

polymers. extract s, silicones,

etc.

8/9/2019 PC KAO 2007

23/29

40 41

H A N D L I Q U I D S O A P

C-081 C-119 CG-032

Mild Soap based Abrasive

EMAL270D or 270E 12.0 ---- ----

EMAL

228D or 227E---- ---- 27.0

MAIN SURFACTANT PRIOLYB-750D ---- 30.0 ----

AKYPOSOFT 100 BVC ---- ---- 4.5

AKYPOFOAM RL 40 ---- 8.0 ----

BETADETSH R 2.9 ---- ----

CO-SURFACTANT BETADETHR ---- ---- 5.0

LEVENOLH&B 2.0 ---- ----

THICKENER AMIDETN ---- 3.5 3.5

APPEARANCE MODIFIER DANOXPL-10 3.5 2.0 ----

Propylene Glycol ---- 1.5 ----

Walnutshell Powder ---- ---- 12.0

SPECIFIC ADDITIVE Bentonite ---- ---- 3.5

Titanium Dioxide ---- ---- 0.5



OTHERS Citric Acid / NaOH (diluted) q.s. q..s. q.s.

NaCl (viscosity adjust) 1.5 ---- 0.3

Deionized water Up to 100% Up to 100% Up to 100%

F o r m u l a


- Propylene Glycol is u sed t o reduce viscosity.

- To improve skin feeling, our recommendation

is to use SOFCAREKG-301P at 0.3-0.5 %.

Appearance Pearled Pearled Opaque

CHARACTERISTICSpH 6.3 6.9 6.5

Viscosity (cPs, 20C) 5.900 3.000 20.000

Dry matter (%) 15.5 27.0 31.5


H and Cleanser - Soapy Feel ing

F A C E C L E A N S E R

C-070 C-089 C-104

Foaming Make-up Remover Fresch & Clean

MAIN SURFACTANTEMAL228D or 227E 27.0 ---- ----

PRIOLYB-750D ---- ---- 30.0

CO-SURFACTANTBETADETS-20 5.0 ---- 3.0

LEVENOLH& B 2.0 ---- ----

Acrylic Polymer ---- 0.1 ----

THICKENER KALCOL6850 --- 0.3 ----

RHEODOLTW-IS399C ---- ---- 2.0

EMULSIFIER FINDET1214N/23 ---- 1.5 ----

Glyceryl Stearate ---- 3.0 ----

EMOLLIENT Mineral Oil ---- 10.0 ----

SOFCAREKG-301P(4% sol.) ---- ---- 5.0

MOISTURIZER Glycerine 6.0 2.5 ----

Dimethicone Copolyol ---- 1.0 ---- SPECIFIC ADDITIVETocopheryl Acetate ---- 0.5 ----


OTHERS Citric Acid / TEA (diluted) q.s. q.s. q.s.


F o r m u l a


- In t he case of Ref. C-070, viscosity can be controlled using

LEVENOL H&B.

- Process at 70C in t he case of Ref. C-089.

- In t he case of Ref. C-104 prepare a 4% solut ion of SOFCARE

KG-301P in water by stirrin g 30 min utes at 50C.

Appearance Transparent Emulsion Opaque

pH 5.5 7.2 6.0


Dry matter (%) 17.0 19.0 24.0

Cloud Point (C) - 8 ---- ----

Details about process are available upon r equest

M ild Cleanser - Make-up Remover

RHEODOLTW-IS399C

(PEG-160 Sorbitan Triisostearate)

Viscous paste to solid

Thickener

High viscosity at low dosage

Produced by Kao Corporation in Asia and

commercialised by Kao Chemicals Europe in Europe

RHEODOLTW-IS399C

(PEG-160 Sorbitan Triisostearate)

Viscous paste to solid

Thickener

High viscosity at low dosage


PRIOLYB-750D

(Phosphate esters blend)

Very mild co-surfactant

Easily rinsed-off


8/9/2019 PC KAO 2007

24/29

D E R M O B O D Y C L E A N S E R

C-017 C- 040 C- 044 C- 103

Regul ar Opaque Sp or t S port

MAIN SURFACTANTEMAL270D or 270E 14.0 ---- ---- 12.7

EMAL228D or 227E ---- 30.0 33.0 ----

BETADETTHC-2 ---- 5.0 ---- ----

CO-SURFACTANTBETADETHR 10.0 10.0 6.0 ----

BETADETHR-50K ---- ---- ---- 4.7

LEVENOLH& B 2.5 2.0 1.8 ----

THICKENER AMIDETB-112 ---- 1.7 ---- 2.0

EMOLLIENTEMANONHE ---- 0.7 ---- ----

LEVENOLN-242 ---- ---- ---- 1.0

APPEARANCE MODIFIER Opacifier ---- 0.7 0.5 0.5

SPECIFIC ADDITIVETETRANYLU ---- ---- 1.0 1.0

Triclosan ---- ---- 0.2 0.2


Preserv. / Fragr. / Dye(s) q.s. q.s. q.s. q.s.

OTHERS Citric Acid / NaOH (diluted) q.s. q.s. q.s. q.s.NaCl (viscosity adjust) q.s. q.s. q.s. q.s.


F o r m u l a


SOFCAREKG-301P

(Cationic Polymer)

Skin Care Application

- Body Shampoo

- Face Cleanser

- Hand Cleanser

Improves feeling of soap base cleansers

Improves skin conditioning

Slippery feeling during rinsing

Foam enhancer: rich and creamy foam



- When EMAL270D (SLES at 70% concentr ation) is used, it is recommended

to heat t he water up to around 45C before adding it.

- It is recommended to pre-dilute the opacifier in water and to avoid t he

excessive stir after being added to t he total formula, n ot t o damage the

part icle size.

ADDITIVES:


addit ives can be added like: vit ami ns, polymers, extr acts, silicones, etc.

- To im prove skin feeling, our recomm endation i s to use SOFCAREKG-301P

at 0.3% .It must pre-diluted in water. This solution is obtained by 30

minu tes stirr ing at 50C. The polymer solution i s added at room temperatu re.

42 43

Keep t he skin clean, fr esh and safe

Appearance Transparent Opaque Opaque

pH 6.0 6.5 6.0 6.0


Dry matter (%) 16.0 17.0 14.5 13.5

Cloud Point (C) - 8 ---- ---- ----

TETRANYL

U( Undecylenamidopropyltrimonium

Meth osulf ate )

Cationic Surfactant

Fungicide Effect

Skin &Hair application

Available upon request

8/9/2019 PC KAO 2007

25/29

44 45

M O I S T U R I Z I N G B O D Y C L E A N S E R

M ois tur i z i ng ef fect - M i l dness

C-096 C- 097 C-094 C-1 02

Regu lar Ex tr a Reg ula r Reg ula r

MAIN SURFACTANT EMAL227E or 228D 32.0 32.0 30.0 30.0

BETADETSH R ---- ---- 3.6 ----

BETADETHR 5.0 5.0 ---- ----

CO-SURFACTANTBETADETS-20 3.0 3.0 ---- 4.2

AKYPOSOFT 45 NV ---- ---- 10.0 ----

AKYPOSOFT 70 BVC 3.0 3.0 ---- ----

LEVENOLH& B 2.0 2.0 2.0 ----

THICKENER AMIDETN 1.0 1.0 2.0 2.0

EMOLLIENTSOFCAREKG-301P ---- 0.5 ---- ----

LEVENOLN-242 ---- ---- ---- 2.0

APPEARANCE MODIFIER DANOX PL-10 ---- 3.0 ---- ----



OTHERS Citric acid (diluted) (pH adjust) q.s. q..s. q.s. q.s.

NaCl (viscosity adjust) q.s. q.s. q.s. q.s.

Deionized water Up to 100% Up to 100% Up to 100% Up to 100%

Appearance Transparent Pearled Transparent Transparent

pH 6.0 6.0 5.6 5.7


Dry matter (%) 16.0 18.0 17.5 17.0

Cloud Point (C) - 10 ---- - 10 < -8

F o r m u l a



- EMAL227E (SLES at 27% concentra ti on) is

easily soluble in water at room temperature.

- EMAL270D (SLES at 70% concentration) can

be also used. In that case, it is recommended to

heat the water up to around 45C before adding it.

ADDITIVES:

- If higher conditioning effect or some specific benefits are

desired, some other addi tives can be added like: vit ami ns,

polymers, extracts.

- To improve skin feeling, our recommendation is to use SOFCARE

KG-301P at 0.3-0.5 % as in the case of ref. C-097.

S L E S F R E E B O D Y C L E A N S E R

Keep Up-dated wi t h market t rends

C-101 C-105 C-106

ALFANOX46 ---- 27.0 12.2

MAIN SURFACTANT SUCCIDETNES ---- ---- 20.0

AKYPOFOAM RL 40 8.0 ---- ----

BETADETHR 17.0 ---- 5.0

CO-SURFACTANT BETADETS-20 ---- 10.5 ----

OXIDETL-75 ---- ---- 5.0

THICKENER AMIDETN 3.8 2.1 1.0

PEG-150 Pentaerythrityl Tetrastearate --- 1.5 1.5

EMOLLIENT EMANONHE ---- ---- 0.5

CONDITIONER QUARTAMINBTC 131 0.3 ---- ----


OTHERS Citric Acid / NaOH (diluted) q.s. q..s. q.s.


F o r m u l a


- Dissolve QUARTAMINBTC 131 in AM IDETN by stirring and heati ng up to 60C.

Appearance Transparent Transparent Transparent

pH 6.6 6.5 5.6


Dry matter (%) 15.0 21.5 17.5

Cloud Point (C) + 2 < - 10 < - 10


8/9/2019 PC KAO 2007

26/29

B O D Y C A R E

Take care of your body

B A T H O I L

Relax i n t he Spa - Wel lness

C-085 C-086 C-087

B ab y L oti on H and Cr ea m L ig ht Bo dy Mi lk

KAOPANSP-S10 1.0 ---- ----

EMULSIFIER KAOPANSP-O10 ---- 1.8 1.2

KAOPANTW O120 ---- 2.2 ----

CO-EMULSIFIER & MOISTURIZEREMANONHE 5.0 ---- ----

LEVENOLH&B 3.0 3.0 5.0

Stearic Acid 2.0 ---- ----

EMOLLIENT & OILVaseline Oil 10.0 26.0 ----

Cetyl Octanoate 1.0 7.0 8.0

Isopropyl Myristate ---- ---- 1.0

KALCOL6098 1.0 ---- ----

THICKENER KALCOL8098 1.0 ---- ----

Acrylic Polymer ---- 0.3 0.13


Citric acid (diluted) q.s. q.s. q.s.OTHERS

Triethanolamine ---- 0.6 0.23


F o r m u l a


- Process at 70C.

- Pre-dilute t he Acrylic Polymer in water before using it.

Appearance Emulsion

CHARACTERISTICSpH 5.4 7.6 7.0

Viscosity (cPs, 20C) 3.600 20.000 13.000

HLB 9.5 10.7 9.7

Details about process are available upon request

F o r m u l a

CG-015 CG-030

Foa mi ng O il 2- pha se s Foami ng Oil

AKYPORLM 45 4.0 ----

SOLUBILIZER AKYPO

RLM 100 4.0 ----

FINDETARH/52 ---- 5.0

CO-SOLUBILIZERFINDET1214N/16 15.0 ----

AMIDETN 15.0 ----

Mineral Oil 28.0 20.0

EMOLLIENT & OIL Jojoba Oil 28.0 ----

Tocopheryl Acetate 0.1 ----

MOISTURIZER Glycerine ---- 5.0

FOAMING COMPONENTEMAL270D ---- 13.0

BETADETHR-50K ---- 8.0


OTHERS NaOH (pH adjust) 1.0 q.s.

Deionized water ---- Up to 100%

Appearance Emulsion 2-phases

CHARACTERISTICS pH 7.5 5.5

Viscosity (cPs, 20C) 100 ----

Details about process are available upon r equest


- High content of fragrance is usually used to improve pleasance when bathing.

46 47

8/9/2019 PC KAO 2007

27/29

W E T W I P E S

Refresh & Clean - Very mi l d

F o r m u l a

C -015 C-057

Refreshing Cleansing

MAIN SURFACTANT LEVENOLH& B 2.0 4.5

CO-SURFACTANT QUARTAMIN60W25 0.2 ----

Ethyl Alcohol 15.0 ----

SPECIFIC ADDITIVE Propylene Glycol ---- 7.0

Camomille Extract ---- 2.0

Glycerine 3.0 ----


OTHERS NaOH (pH adjust) q.s. q.s.

Deionized water Up to 100% Up to 100%

CHARACTERISTICSAppearance Opaque

pH 5.5 5.5

S H A V I N G F O A M

On l y fo r h im

F o r m u l a

C-046

Aerosol

FOAMING SURFACTANT OXIDETDMCLD 3.0

BETADETHR-50K 1.0

EMOLLIENT & THICKENER LEVENOLH& B 0.5

KALCOL6098 0.5

Stearic Acid 7.5

SPECIFIC ADDITIVE Dimethicone Copolyol 1.0

Glycerine 3.0

Preserv. / Fragr./ Dye(s) q.s.

OTHERS Tri et hanolam ine (pH adjust ) 3.5

Deionized water Up to 100%

PROCESS - GENERALREMARKS:

- Process at 80C.

- Mi x 95% of this blend with

5% of propellant i n a can.

48 49

H A I R C O L O R I N G T E M P O R A R Y

F o r m u l a

C-113

Colour Cream

EMULSIFIER FINDET1618A/35-P 0.5

EMULSIFIER & CONDITIONER AMIDETAPA22 2.0

THICKENER KALCOL6098 4.0

NEUTRALIZER Lactic Acid (90%) 0.3

DYE(S) Ruby Red 5% 1.0

Lactic Acid (pH adjust) q.s.

OTHERS Fragrance / Preservative q.s.

Deionized Water Up to 100%

CHARACTERISTICSAppearance Viscous emulsion

pH 7.0

Viscosity (cPs, 20C) 25.000


- Heat t he water around 60C, add lactic acid and the fat ty phase together with the

emulsifiers melted. Cool down to 40C and add the dye soluti on. Adjust pH and add

the rest of additi ves.

- Ot her dyes can be used.

- This cream is applied directly to the hair obtaining a ni ce red brilliant colour.

On ly fo r a sho r t

8/9/2019 PC KAO 2007

28/29

H A I R C O L O R I N G O X I D A T I O N D Y E I N G

C-111 CG-027A CG-027B

Sem i p er manent Sem i p er manent Per manent

EMULSIFIER & REFATTING Oleic Acid 10.0 ---- ----

EMULSIFIER & CONSISTENCY Oleth-13 10.0 ---- ----

EMULSIFIER FINDET1618 A/35-P ---- 2.1 2.1

THICKENER KALCOL6850 ---- 11.2 11.2

THICKENING & LEVELLINGAMIDETAPA22 5.0 ---- ----

AMIDETA 15 ---- 5.0 5.0

ALKALIZER Monoethanolamine 7.5 q.s. ----

NH3 25% ---- ---- 10.0

SOLVENT Ethyl Alcohol 10.0 ---- ----

Sodium sulfite 0.5 ---- 0.5

STABILIZER Ascorbic acid 0.5 ---- ----

(antioxidant, chelat ing, etc.) EDTA-Na4 0.5 0.35 0.35

Resorcinol q.s. q.s. q.s.DYE PRECURSOR

Toluene-2,5-Diamine Sulfate q.s. q.s. q.s.


OTHERS Fragrance q.s. q.s. q.s.


For mu la CREAM BASE

Appearance Yellowish emulsion

CHARACTERISTICS pH (10%) 10.5 9.7 11.2

Viscosity (cPs, 20C) 2.500 39.000 4.500

50 51


- CREAM:Heat the water around 80C, add the emulsifiers and the AMI DET. Add

MEA and O leic acid. Cool down to 55C and add EtOH, stabillizers and dye Precursors.

Cool down to 40C and add the rest of addi tives.

- DEVELOPER:Heat t he water around 70C, add the fatt y phase together with the

emulsifiers melted. Cool down to 30-35C. Adjust pH and add t he rest of addit ives.

Mix 1 to 1

CREAM BASE / DEVELOPER

C -112 C-014

B l ea c hi ng E mu ls i on B l ea c hi ng E mu l si on

OXIDIZING AGENT H2O2 (50%) 12.0 12.0

EMULSIFIER FINDET1618 A/35-P ---- 0.5

FINDET1618 A/72-P ---- 1.1

EMULSIFIER & CONDITIONER QUARTAMINAB 4.0 ----

THICKENER KALCOL

6098 2.0 ---- KALCOL6870P ---- 3.4

HUMECTANT Glycerine 1.0 ----

Phosphoric acid (pH adjust) q.s. q.s.

OTHERS Fragrance q.s. q.s.

Deionized Water Up to 100% Up to 100%

Formula DEVELOPER

Appearance White emulsion White emulsion

CHARACTERISTICS pH 3.5 3.5

Viscosity (cPs, 20C) 375 1.500

Add co lou r to you r ha i r

8/9/2019 PC KAO 2007

29/29

N o t e s

Documents

PC KAO 2007