Past Year Papers AIEEE 2007

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    1 (1) 2 (2) 3 (2) 4 (4) 5 (4) 6 (3) 7 (3) 8 (2) 9 (2) 10 (4)

    11 (4) 12 (2) 13 (3) 14 (4) 15 (4) 16 (1) 17 (2) 18 (4) 19 (1) 20 (4)

    21 (3) 22 (3) 23 (2) 24 (3) 25 (4) 26 (1) 27 (1) 28 (2) 29 (3) 30 (4)

    31 (1) 32 (1) 33 (1) 34 (3) 35 (1) 36 (3) 37 (4) 38 (4) 39 (1) 40 (1)

    41 (4) 42 (3) 43 (3) 44 (1) 45 (4) 46 (4) 47 (1) 48 (1) 49 (1) 50 (4)

    51 (3) 52 (4) 53 (2) 54 (4) 55 (3) 56 (4) 57 (3) 58 (2) 59 (4) 60 (3)

    61 (2) 62 (3) 63 (2) 64 (2) 65 (4) 66 (4) 67 (1) 68 (1) 69 (1) 70 (3)

    71 (3) 72 (4) 73 (1) 74 (3) 75 (4) 76 (3) 77 (3) 78 (3) 79 (1) 80 (4)

    81 (4) 82 (2) 83 (4) 84 (3) 85 (4) 86 (3) 87 (4) 88 (2) 89 (1) 90 (3)

    91 (4) 92 (3) 93 (2) 94 (1,2) 95 (3) 96 (1) 97 (2) 98 (2) 99 (4) 100 (4)

    101 (1) 102 (2) 103 (3) 104 (2) 105 (4) 106 (3) 107 (3) 108 (4) 109 (1) 110 (4)

    111 (3) 112 (1) 113 (3) 114 (1) 115 (3) 116 (4) 117 (1) 118 (1) 119 (3) 120 (1)

    PHYSICS

    1. x=(210-2) cos t

    Here,a=210-2 m = 2 cm

    At t = 0, x = 2 cm, i.e., the object is at positive extreme, so to acquire maximum speed (ie.,

    to

    reach mean position) it takes1

    th4

    of time period.

    Required timeT

    4=

    where2

    T

    = =

    T = 2s

    So, required timeT 2

    0.5s4 4

    = = =

    2. For given circuit current is lagging the voltage by2

    , so circuit is purely inductive and there

    is no power consumption in circuit. The work done by battery is stored as magnetic energy in

    the inductor.

    3.1r 2i 2 j= +

    ( ) ( )2 21 1r r 2 2 2= = + =

    2r 2i 0j= +

    2 2r r 2 = =

    AIEEE 2007 SOLUTION

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    Potential at point A is

    3 6

    A

    0 1 0

    1q 1 10 10V

    4 r 4 2

    = =

    Potential at pointBis3 6

    B

    0 2 0

    1 q 1 10 10V

    4 r 4 2

    = =

    VA

    VB

    = 0

    4. Required ratioEnergystoredincapacitor

    Work doenby thebattery=

    2

    2

    1CV

    2Ce

    = where C = Capacitance of capacitor,

    V = Potential difference

    e = emf of battery

    ( )2

    2

    1Ce

    2 V eCe

    = =

    1

    2=

    5. Rise of current in L-R circuit is given by

    ( )t/0I I 1 e =

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    Where0

    E 5I 1A

    R 5= = =

    Now,L 10

    2sR 5

    = = =

    After 2s, ie, at t = 2s

    RiseofcurrentI=(1e-1)A

    6. Uniformcurrentisowing.Currentenclosedinthe1st amperean path is

    2 2

    1 1

    2 2

    I r Ir

    R R

    =

    2

    0 0 1 0 1

    2 2

    1

    current .Ir IrB

    path 2 r R 2 R

    = = =

    Magnetic induction at a distance 02

    2

    .Ir

    2 r

    =

    1 1 2

    2 2

    2

    a.2a

    B r r 2 1B R a

    = = =

    7. There is no current inside the pipe and hence Amperes law can not be applied. So, the

    magneticeldatanypointinsidethepipe=0

    8. Bindingenergy

    ( )2

    nucleus nucleonsBE M M c= ( )2

    0 p nM 8M 9M c= [nucleons=protons+neutrons= p n8M 9M+ ]9. rayemissiontakesplaceduetodeexcitationofthenucleus.Thereforeduring-ray emission,

    there is no change in the proton and neutron number.

    10. For Vi0, the diode is forward biased and circuit would be as shown in Figure (3) and V

    0=

    ViHence, the option (4) is correct.

    11. Energy of a photon E = h .(i)

    Also E = pc ..(ii)

    where p is the momentum of a photon

    From (i) and (ii), we get

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    hh pc p

    c

    = =

    12. We know that,dx

    v dt=

    dx = v dt

    integrating,tx

    0 0

    dx vdt=

    ( )t

    2 3t2

    0 0

    0 0

    gt ftx v gt ft dt v t

    2 3

    = + + = + +

    2 3

    0

    gt ftx v t c

    2 3

    = + + + where c is the constant of integration.

    Byquestion,x=0att= 0

    0

    g f0 v 0 0 0 c

    2 3 = + + + c = 0

    2 3

    0

    gt ftx v t

    2 3 = + +

    At t = 1,0

    g fx v

    2 3= + +

    13. By perpendicular axes theorem, M.I. about perpendicular axis passes through centre of

    lamina.

    ( )2 22 2 2z

    M a aa b 2al M M

    12 12 12

    ++= = =

    Byperpendicularaxestheorem,

    AC BD zI I I+ =

    2z

    AC

    I MaI

    2 12 = =

    Bythesametheorem2

    zEF

    I MaI

    2 12= = .

    IAC

    = IEF.

    14.0

    x x cos t4

    =

    Acceleration,2

    2

    d xa

    dt=

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    2

    0x cos t

    4

    =

    2

    0

    3

    x cos t 4

    = +

    So, A = 2x0

    and3

    4

    =

    15. Asshowninthegure,theresultantelectriceldsbeforeandafterinterchangingthecharges

    will have the same magnitude but opposite directions.

    Also, the potential will be same in both cases as it is a scalar quantity.

    16.1

    2

    T , half life ofY

    X = , mean life of Y

    X Y

    ln2 1=

    X Yln2 =

    X Y >

    X Yt t

    X 0 Y 0A A e ; A A e = =

    X will decay faster than Y.

    17. For Carnot engine using as refrigerator

    12

    2

    TW Q 1

    T

    =

    It is given1

    10 =

    2

    1

    T1

    T =

    2

    1

    T 9

    T 10 =

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    2 210

    10 Q 1 Q 90 J9

    = =

    18. Si and Ge are semiconductors but C is an insulator. Also, the conductivity of Si and Ge is more

    than C because the valence electrons of Si, Ge and C lie in third, fourth and second orbit

    respectively.

    19. When E

    and B

    areperpendicularandvelocityhasnochangesthenqE=qvBie.,E

    vB

    = .

    The two forces oppose each other if v is along2

    E BE B i.e.,v

    B

    =

    As E

    and B

    are perpendicular to each other

    2 2

    E B EB sin 90 E

    BB B

    = =

    For historic and standard experimentslikeThomsonse/mvalue,ifvisgivenonlyasE/B,

    it would have been better from the pedagogic view, although the answer is numerically

    correct.

    20. V V V

    E i j kx y z

    =

    x 2

    V d 20E

    x dx x 4

    = =

    ( )2

    2

    40x

    x 4

    =

    x

    10E at x 4 m V / m

    9 = =

    and is along positive x direction.

    21. Wehavetondthefrequencyofemittedphotons.Foremissionofphotonsthetransitionmust

    take place from a higher energy level to a lower energy level which are given only in option

    (2) and (3).

    Frequency is given by,2 2

    1 2

    1 1hv 13.6

    n n

    =

    For transition from n = 6 to n = 2

    1 2 2

    13.6 1 1 2 13.6v

    h 9 h6 2

    = =

    For transition from n = 2 to n = 1.

    2 2 2

    13.6 1 1 3 13.6v

    h 4 h2 1

    = =

    v2

    > v1

    Hence, option (3) is the correct answer.

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    22. Acceleration of the systemF

    am M

    =+

    Force on block of mass m = mamF

    m M

    =+

    .

    23. Power of a lens is reciprocal of its focal length.

    Power of combined lens is

    P = P1

    + P2

    =15+5=10D

    1 100f cm

    P 10 = =

    f=10 cm

    24. LetTbethetemperatureoftheinterface.Asthetwosectionsareinseries,therateofowof heat in them will be equal

    ( ) ( )1 1 2 21 2

    K A T T K A T T

    l l

    =

    where A is the area of cross-section.

    K1A(T

    1T)l

    2= K

    2A(TT

    2)l

    1

    K1T

    1l2k

    1Tl

    2= K

    2Tl

    1K

    2T

    2l1

    (K2l1

    + K1l2)T = K

    1T

    1l2

    + K2T

    2l1

    1 1 2 2 2 1 1 2 1 2 1 2

    2 1 1 2 1 2 2 1

    K T l K T l K l T K l TT

    K l K l K l K l

    + + = =

    + +

    25. 1 21 2

    0 0

    l lL 10log ; L 10log

    l l

    = =

    1 21 2

    0 0

    l lL L 10log 10log

    l l

    =

    1

    2

    lL 10log

    l

    =

    1

    2

    l20dB 10log

    l

    =

    2 1

    2

    l10

    l =

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    12

    ll

    100 =

    26. According to Mayers relation,

    p vR RC Cm 28

    = =

    27. Whenachargeparticleentersamagneticeldatadirectionperpendiculartothedirectionof

    motion, the path of the motion is circular. In circular motion the direction of velocity changes

    at every point (the magnitude remains constant). Therefore, the momentum will change

    ateverypoint.Butkineticenergywillremainconstantasitisgiven by 21

    mv2

    and v2 is the

    square of the magnitude of velocity which does not change.

    28. The eld at the same point at the same distance from the mutually perpendicular wires

    carrying current will be having the same magnitude but in perpendicular directions.

    2 2

    1 2B B B = +

    ( )

    12 20 21 2

    B l l2 d

    = +

    29. From Rt= R

    0(1 + t)

    5 = R0

    (1 + 50) .(i)

    and 6 = R0

    (1 + 100) . (ii)

    5 1 50

    6 1 100

    + =

    +

    1

    200 =

    Putting value of in Eq (i), we get

    0

    15 R 1 50

    200

    = +

    R0

    = 4

    30. The potential energy of a charged capacitor is given by2Q

    U2C

    =

    If a dielectric slab is inserted between the plates, the energy is given by

    2

    Q2KC

    , where K is the

    dielectric constant.

    Again, when the dielectric slab is removed slowly its energy increases to initial potential

    energy. Thus work done is zero.

    31. Since electronic charge (1.6 1019 C) is universal constant. It does not depend on g.

    Electronic charge on the moon = electronic charge on the earth

    electronicchargeonthemoon

    electronicchargeontheearth = 1

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    32. In this question distance of centre of mass of new disc from the centre of mass of remaining

    disc is R.

    Mass of remaining disc

    M 3MM

    4 4= =

    3M MR R 0

    4 4 + =

    1

    3 =

    33. The acceleration of a solid sphere of mass M, radius R and moment of inertia I rolling

    down (without slipping an inclined plane making an angle with the horizontal) is given by

    2 2

    2

    2

    gsin Ia ,whereI MK K

    MK1

    R

    = = =

    +

    2

    gsina

    I1

    MR

    =

    +

    34. Central forces passes through axis of rotation so torque is zero.

    If no external torque is acting on a particle, the angular momentum of a particle is

    constant.

    35. 2kF 15

    a 7.5m / sm 2

    = = =

    Now, 21

    ma kx2

    =

    212 7.5 10000 x2

    =

    x2=3 103

    x = 0.055 m

    x = 5.5 cm

    36. Let K be the K.E. at the highest point.

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    Then

    2

    x

    1K' mv

    2= (v

    y= 0 at highest point)

    ( )21 m ucos2

    =

    2 2 2 21 1

    mu cos K.cos K mu2 2

    = = =

    K = K.cos260 ( = 60)

    21 K

    K.2 4

    = =

    37. In Youngs double slit experiment intensity at a point is given by

    2

    0I I cos

    2

    =

    . (i)

    where = phase difference, l0

    = maximum intensity

    2

    0

    Icos

    I 2

    =

    Phase difference2

    pathdifference

    =

    2

    6

    =

    3

    = .(ii)

    Substitute eqn. (ii) in eqn. (i), we get

    2

    0

    Icos

    I 6

    =

    0

    I 3

    I 4 = .

    38. 1 2k k1

    f

    2 m

    +=

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    and 1 2k k1

    f ' .2 2f 2 m

    += =

    39. For path iaf, Q = 50 cal, W = 20 cal

    Byrstlawofthermodynamics

    U=QW=5020=30cal.

    For path ibf, Q = 36 cal, W = ? Byrstlawofthermodynamics,

    Q = U + W

    W=QU

    Since, the change in internal energy does not depend on the path, therefore U = 30 cal

    W=QU=3630=6cal.

    40. For a particle to execute simple harmonic motion its displacement at any time t is given by

    x(t) = a (cos t + )

    where, a = amplitude, = angular frequency, = phase constant.

    Let us choose = 0 x(t) = acost

    Velocity of a particledx

    v a sin tdt

    = =

    Kinetic energy of a particle is 21

    K mv2

    =

    2 2 21 ma sin t2

    =

    Average kinetic energy = 2 2 21

    ma sin t

    2

    < >

    2 2 21 m a sin t2

    = < >

    2 2 21 1 1m a sin2 2 2

    = < >=

    ( )221 ma 2 [ 2 ]4

    = =

    2 2 2ma=

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    CHEMISTRY

    41.2 2

    A B 2 AB+

    Ea(forward) = 180 kJ mol1

    Ea (backward) = 200 kJ mol

    1

    In the presence of catalyst :

    Ea(forward)=180100=80kJmol1

    Ea(backward)=200100=100kJmol1

    H = Ea(forward)E

    a(backward)

    =80100

    =20kJmol1

    42. Ecell

    = 0; when cell is completely discharged.

    2

    cell .cell 2

    Zn0.059E E log

    2 Cu

    +

    +

    =

    2

    2

    Zn0.0590 1.1 log

    2 Cu

    +

    +

    =

    2

    2

    Zn 2 1.1log 37.3

    0.059Cu

    +

    +

    = =

    2

    37.3

    2

    Zn10

    Cu

    +

    +

    =

    43. For acidic buffer,a

    ApH pK log

    HA

    = +

    When the acid is 50% ionised, [A] = [HA]

    pH = pKa

    + log1

    or pH = pKa

    Given pKa= 4.5

    pH = 4.5

    pOH=144.5=9.5

    44. 2A+B products

    [B]isdoubled,half-lifedidntchangehalf-lifeisindependentofchangeinconc.ofreactant

    First order

    Firstorderw.r.ttoB

    [A] is doubled, rate increased by two times

    First order w.r.t A

    Hence, net order of reaction = 1 + 1 = 2

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    unit for the rate constant = conc.(1n) t1

    = (mol. L1)1. s1

    = L. mol1 s1

    45. 4f orbital is nearer to nucleus as compared to 5f orbital therefore, shielding of 4f is more than

    5f.

    46. In 4-coordinate complexes Pt, the four ligands are arranged about the central 2-valent

    platinumioninasquareplanarconguration.

    47. The molecule, which is optically active, has chiral centre, is expected to rotate the plane of

    polarized light.

    One chiral centre optically active

    Two chiral centres, but plane of symmetry within molecule optically inactive

    48. Proteins have two types of secondary structures -helix and -plated sheet.

    49.

    HBr

    3 2 3 2 2CH CH CH CH CH CHBr =

    2HBr

    3 2CH CH CH CHBr

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    HBr

    3 2 3 3CH CH CH CH CHBr CH =

    50. This is carbylamine reaction.

    3 2 2 3

    2 5 2

    CH CH NH CHCl 3KOH

    C H NC 3KCl 3H o

    + +

    + +

    51.

    52.

    NO2groupwithdrawelectronfromthering,showsMeffectmakesringelectrondecient,

    thus, deactivates ring for electrophilic substitution.

    53. NO NO+

    NO Totale 14

    +

    =

    2 2 2 2 1 1 1 1 2

    x y z1s *1s 2s *2s 2p 2p 2p+ + =

    Diamagnetic

    Bondorder10 4

    32

    = =

    (NO) Total e = 15

    2 2 2 2 2 1 1 1 1

    z x y1s *1s 2s *2s 2p 2p 2p+ +

    1x y*2p 2p =

    Paramagnetic

    Bondorder10 5

    2.52

    = =

    Electron is taken away from non-bonding molecular orbital, thats why bond order increases.

    54. More the distance between nucleus and outer orbital, lesser will be force of attraction on

    them. Distance between nucleus and 5f orbital is more as compared to distance between 4f

    orbital and nucleus. So actinides exhibit more number of oxidation states in general than the

    lanthanides.

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    55. Let the mass of methane and oxygen be m gm. Mole fraction of oxygen,2o

    x

    mm 32 132

    m m 32 3m 3

    32 16

    = = =

    +

    Let the total pressure be P.

    Partial pressure of O2,

    2 2O OP P x=

    1 1P P

    3 3= =

    56. Solution is isotonic.

    C1RT = C

    2RT

    C1

    = C2

    Density of both the solutions are assumed to be equal to 1.0 g cm3

    molality = molarity 5.25%

    in 100 g 5.25 g of substance therefore, in 1000g 52.5 g of substance

    Hence,52.5 15

    M 60= ,

    M = molecular mass of the substance

    52.5 60M 210

    15

    = =

    57. Isotonic solution have same osmotic pressure.

    1 1 2 2C RT, C RT = =

    For isotonic solution 1

    = 2

    C1C

    2

    1.5 / 60 5.25 / M

    V V =

    [Where M = molecular weight of the substance]

    1.5 5.25

    60 M =

    M = 210.

    58. Let x = solubility

    3 3AgIO Ag IO+ +

    2

    sp 3K [Ag ][IO ] x x x+ = = =

    Given Ksp

    =1108

    8 4

    spx K 1 10 1.0 10 mol / lit = = =

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    =1.0104283g/lit

    41.0 10 283 100

    gm / 100ml1000

    =

    =2.83103 gm/100 ml

    59. Activity N

    n

    0

    N 1

    N 2

    =

    n1 1

    10 2

    =

    10 = 2n

    Taking log on both sides

    log 10 = n log 2

    1n 3.32

    0.301= =

    time=nhalf-life

    = 3.3230=99.6days.

    60. Chiral conformation will not have plane of symmetry. Since twisted boat does not have plane

    of symmetry it is chiral.

    61.

    Chair form is unsymmetrical and absence of any element of symmetry.

    62.2P l Mg

    3 2 3 2 EtherCH CH OH CH CH I

    A

    +

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    63. n = 3, l = 0 represents 3s orbital

    n = 3, l = 1 represents 3p orbital

    n = 3, l = 2 represents 3d orbital

    n = 4, l = 0 represents 4s orbital

    The order of increasing energy of the orbital is

    3s < 3p < 4s < 3d

    64. Hydrogen bond is strongest in HF due to higher electro negativity of F.

    65. 3(s) (aq) (aq) (aq) 2(g)

    2Al 6HCl 2Al 6Cl 3H+ + + +

    6 moles of HCl produces = 3 moles of H2

    =322.4 L of H2

    2

    3 22.4

    1moleofHClproduces 11.2L ofH2

    = =

    Since, 2 moles of Al produces 3 moles of H2=322.4LofH

    2

    1 mole of Al produces2

    3 22.433.6L ofH

    2

    = =

    66.( ) ( )24 4 2 4 42NH SO 2H O 2H SO 2NH OH

    Strongacid Weakbase

    + + + +

    (NH4)

    2SO

    4on hydrolysis produces strong acid H

    2SO

    4, which increases the acidity of the soil.

    67. In an isolated system where either mass or energy are not exchanged with surrounding for

    the spontaneous process, the change in entropy is positive.

    68. Isotopes are atoms of same element having same atomic number but different atomic masses.

    Neutron has atomic number 0 and atomic mass 1. So loss of neutron will generate isotope.

    69. According to Kohlrauschs law, the molar conductivity at innite dilution () for weak

    electrolyte, CH3COOH is

    3 3CH COOH CH COONa HCl NaCl

    = +

    So, for calculating the value of3CH COOH

    , value of NaCl should also be known.

    70. In aqueous solution, basicity order :

    Dimethylamine > methylamine > trimethylamine > aniline

    2 13

    71. When alkyl benzene are oxidized with alkaline KMnO4, the entire alkyl group is oxidized to

    COOHgroupregardlessoflengthofsidechain.

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    72.

    73. Diamagnetic species have no unpaired electrons

    2 2 2 2 2 2 2 2 2

    2 z x y x yO 1s , s , s , 2p , 2p , 2p , *2p , *2p 1

    74. Due to the inert pair effect (the reluctance of ns2 electrons of outermost shell to participate

    in bonding) the stability of M2+ ions (of group IV elements) increases as we go down the

    group.

    75. Br2reactswithhotandstrongNaOHtogiveNaBr,NaBrO3 and H2O.

    2 3 26NaOH 3Br 5NaBr NaBrO 3H O

    conc.andhot

    + + +

    76. Smaller the size and higher the charge more will be polarizing power of cation. So the correct

    order of polarizing power is K+ < Ca2+ < Mg2+

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    80. For G = HTS

    For a spontaneous process G < 0

    i.e., HTS < 0

    H < TS

    TS > H

    TS

    >

    i.e.,179.1 1000

    T160.2

    >

    T > 1117.9 K 1118 K.

    MATHEMATICS

    81. Since, each term is equal to the sum of the next two terms.

    n 1 n n 1ar ar ar + = +

    21 r r = +

    r2+r1=0

    5 1 5 1r r

    2 2

    =

    82. 1 1x 5

    sin cosec5 4 2

    + =

    1 1x 5

    sin cosec5 2 4

    =

    1 1x 4

    sin sin5 2 5

    =

    [sin-1 x + cos1 x = /2]

    1 1x 4

    sin cos ....(i)5 5

    =

    Let 14

    cos A5

    =

    4cosA

    5 =

    3sinA

    5 =

    13

    A sin5

    =

    1 14 3cos sin5 5

    =

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    504 AIEEE

    equation (i) become 1 1x 3

    sin sin5 5

    =

    x 3

    5 5 =

    x = 3

    83. Given n n 4 4 n n 5 55 6 4 5t t 0 C a ( b) C a ( b) 0 + = + = ( ) ( )(4 5n n 4 n n 54 5C a b C a b =

    a (n 4)! n 4

    b (n 5)!5 5

    = =

    84. Required number of ways 12 8 44 4 4

    C C C=

    12! 8!1

    8! 4! 4! 4!=

    ( )3

    12!

    4!=

    85.2x 1 xf(x) 4 cos 1 log(cosx)

    2

    = + +

    f(x)isdened ifx

    1 1 12

    and cos x > 0

    x0 2and x

    2 2 2

    < <

    0 x 4and x2 2