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    ACKNOWLEDGEMENT

    Any achievement, be it scholastic or otherwise does not depend solely on the

    individual efforts but on the guidance, encouragement and cooperation of

    intellectuals, elders and friends. A number of personalities, in their own capacities

    have helped me in carrying out this seminar work. I would like to take this

    opportunity to thank them all.

    I would like to express my hearty gratitude to Mr Rajkumar

    Jain, Head of the Department of Electronics and Communication, P.E.S.C.E for

    providing permission and facilities to conduct the seminar in a systematic way

    I would like to express my hearty gratitude to Mr.Dilip Tiwari

    Asst.Professor, seminar coordinator, Department of Electronics and

    Communications, C.I.I.T.M. for her guidance, regular source of encouragement

    and assistance throughout this seminar.

    I express my sincere gratitude to Mr.Dilip Tiwari,

    Asst.Professor, seminar guide, Department of Electronics and Communications,

    P.E.S.C.E for inspiring and sincere guidance throughout the seminar.

    I am thankful to all the faculty members in the Department of

    Electronics and Communications, C.I.I.T.M. for their constant support.

    I would like to thank my parents and friends for their moral support.

    Thanks for being always there. Finally, I thankGod, for his blessings.

    Abhishek sanadaya

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    ABSTRACT

    The Batteries form a significant part of many electronic devices. Typical

    electrochemical batteries or cells convert chemical energy into electrical energy.

    Batteries based on the charging ability are classified into primary and secondary

    cells. Secondary cells are widely used because of their rechargeable nature.

    Presently, battery takes up a huge amount of space and contributes to a large

    part of the device's weight. There is strong recent interest in ultrathin, flexible, safe

    energy storage devices to meet the various design and power needs of modern

    gadgets. New research suggests that carbon nanotubes may eventually provide the

    best hope of implementing the flexible batteries which can shrink our gadgets even

    more.

    The paper batteries could meet the energy demands of the next generation

    gadgets. A paper battery is a flexible, ultra-thin energy storage and production

    device formed by combining carbon nanotubes with a conventional sheet of

    cellulose-based paper. A paper battery acts as both a high-energy battery and super

    capacitor, combining two components that are separate in traditional electronics.

    This combination allows the battery to provide both long-term, steady power

    production and bursts of energy. Non-toxic, flexible paper batteries have the

    potential to power the next generation of electronics, medical devices and hybrid

    vehicles, allowing for radical new designs and medical technologies.

    The various types of batteries followed by the operation principle,

    manufacturing and working of paper batteries are discussed in detail.

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    Table of Contents

    Chapter _______________ Page no

    1. Introduction to batteries..11.1Terminologies...2 1.2Principle of operation of cell....41.3Types of battery....5 1.4Recent developments....61.5Life of battery.......7 1.6

    Hazards.........8

    2. Paper Battery......9 3. Carbon nanotubes...12

    3.1Properties of carbon nanotubes14

    4. Fabrication of paper battery....15 5. Working of paper battery........18 6. Advantages of paper battery.......21 7. Limitations of paper battery...........22 8. Applications of paper battery.....22 9. Conclusion.....24

    References......25

    http://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_Principal_of_Operationhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_Principal_of_Operationhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.3.Categories_and_typeshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.3.Categories_and_typeshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.4._Recent_developmentshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.4._Recent_developmentshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.5._Life_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.5._Life_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.6._Hazards_relatedhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.6._Hazards_relatedhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.6._Hazards_relatedhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_3._Paper_batteryhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_4._Carbon_Nanotubeshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_5._Fabrication_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_6._Working_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_7._Applicationshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_8._Limitationshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_9._APPLICATIONShttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_9._Conclusionhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_11.Referenceshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_11.Referenceshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_9._Conclusionhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_9._APPLICATIONShttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_8._Limitationshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_7._Applicationshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_6._Working_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_5._Fabrication_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_4._Carbon_Nanotubeshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_3._Paper_batteryhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.6._Hazards_relatedhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.5._Life_ofhttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.4._Recent_developmentshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_2.3.Categories_and_typeshttp://c/Users/JITENDRA/Desktop/abhikhek%20ack.docx%23_Principal_of_Operation
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    List of Figures

    Figures Description

    Figure 1aSymbolic View of the Battery

    Figure 1b...Conventional Battery

    Figure 1.2..Principle Operation of Battery

    Figure 1.3a....Primary cell

    Figure 1.3b....Secondary cell

    Figure 1.4..USB cell

    Figure 1.5..Life of Battery

    Figure 1.6..Electronic Waste

    Figure 2.....Paper Battery

    Figure 2.1.Types of CNTs

    Figure 3.....Carbon nanotubes

    Figure 3.1..Relation b/w resistence vs. width

    Figure 3.2..Relation b/w resistivity vs. temp.

    Figure 4.....Fabrication Process

    Figure 4.1......Paper Battery

    Figure 4.2..Sechemetic of fabrication process

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    Figure 5.....working of paper battery

    Figure 5.1.Testing of paper battry

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    1. INTRODUCTION TO BATTERIES

    An electrical battery is one or more electrochemical cells that convert stored

    chemical energy into electrical energy. Since the invention of the first battery in

    1800 by Alessandro Volta, batteries have become a common power source for

    many household and industrial applications.

    Batteries are represented symbolically as

    Fig. 1a Symbolic view Fig. 1b conventional

    battery

    Electrons flow from the negative terminal towards the positive terminal.

    Based on the rechargeable nature batteries are classified as

    a. Non rechargeable or primary cellsb. Rechargeable or secondary cells

    Based on the size they are classified as

    a. Miniature batteriesb. Industrial batteries

    Based on nature of electrolyte

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    1.1.6 C - Used to signify a charge or discharge rate equal to the capacity ofa battery divided by 1 hour. Thus C for a 1600 mAh battery would be 1.6 A,

    C/5 for the same battery would be 320 mA and C/10 would be 160 mA.

    1.1.7 Capacity - The capacity of a battery is a measure of the amount ofenergy that it can deliver in a single discharge. Battery capacity is normally

    listed as amp-hours (or milli amp-hours) or as watt-hours.

    1.1.8 Cathode - Is an electrode that, in effect, oxidizes the anode or absorbsthe electrons. During discharge, the positive electrode of a voltaic cell is the

    cathode. When charging, that reverses and the negative electrode of the cell

    is the cathode.

    1.1.9 Cycle - One sequence of charge and discharge.

    1.1.10 Cycle Life - For rechargeable batteries, the total number ofcharge/discharge cycles the cell can sustain before its capacity is

    significantly reduced. End of life is usually considered to be reached when

    the cell or battery delivers only 80% of rated ampere- hour capacity.

    1.1.11 Electrochemical Couple - The system of active materials within a cellthat provides electrical energy storage through an electrochemical reaction.

    1.1.12 Electrode - An electrical conductor through which an electric currententers or leaves a conducting medium

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    1.1.13 Electrolyte - A chemical compound which, when fused or dissolved incertain solvents, usually water, will conduct an electric current.

    1.1.14 Internal Resistance - The resistance to the flow of an electric currentwithin the cell or battery.

    1.1.15 Open-Circuit Voltage - The difference in potential between theterminals of a cell when the circuit is open (i.e., a no-load condition).

    1.1.16 Voltage, cutoff - Voltage at the end of useful discharge. (See Voltage,end-point.)

    1.1.17 Voltage, end-point - Cell voltage below which the connectedequipment will not operate or below which operation is not recommended.

    1.2 Principal of Operation of cell

    A battery is a device that converts chemical energy directly to electricalenergy. It consists of a number of voltaic cells. Each voltaic cell consists of two

    half cells connected in series by a conductive electrolyte containing anions and

    cations. One half-cell includes electrolyte and the electrode to which anions

    (negatively charged ions) migrate, i.e., the anode or negative electrode. The other

    half-cell includes electrolyte and the electrode to which cations (positively charged

    ions) migrate, i.e., the cathode or positive electrode. In the redox reaction that

    powers the battery, cations are reduced (electrons are added) at the cathode, while

    anions are oxidized (electrons are removed) at the anode. The electrodes do not

    touch each other but are electrically connected by the electrolyte. Some cells use

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    two half-cells with different electrolytes. A separator between half cells allows

    ions to flow, but prevents mixing of the electrolytes.

    Fig. 1.2 principle operation

    Each half cell has an electromotive force (or emf), determined by its ability

    to drive electric current from the interior to the exterior of the cell. The voltage

    developed across a cell's terminals depends on the energy release of the chemical

    reactions of its electrodes and electrolyte. Alkaline and carbon-zinc cells have

    different chemistries but approximately the same emf of 1.5 volts. Likewise NiCd

    and NiMH cells have different chemistries, but approximately the same emf of 1.2

    volts. On the other hand the high electrochemical potential changes in the reactions

    of lithium compounds give lithium cells emf of 3 volts or more.

    1.3 Types of batteries

    Batteries are classified into two broad categories. Primary batteries

    irreversibly (within limits of practicality) transform chemical energy to electrical

    energy. When the initial supply of reactants is exhausted, energy cannot be readily

    restored to the battery by electrical means. Secondary batteries can be recharged.That is, they can have their chemical reactions reversed by supplying electrical

    energy to the cell, restoring their original composition.

    Primary batteries: This can produce current immediately on assembly.

    Disposable batteries are intended to be used once and discarded. These are most

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    commonly used in portable devices that have low current drain, are only used

    intermittently, or are used well away from an alternative power source, such as in

    alarm and communication circuits where other electric power is only intermittently

    available. Disposable primary cells cannot be reliably recharged, since the

    chemical reactions are not easily reversible and active materials may not return to

    their original forms. Battery manufacturers recommend against attempting

    recharging primary cells. Common types of disposable batteries include zinc-

    carbon batteries and alkaline batteries.

    Secondary batteries: These batteries must be charged before use. They are

    usually assembled with active materials in the discharged state. Rechargeable

    batteries or secondary cells can be recharged by applying electric current, which

    reverses the chemical reactions that occur during its use. Devices to supply the

    appropriate current are called chargers or rechargers.

    Fig. 1.3a Primary cell Fig. 1.3b Secondary cell

    1.4 Recent developments

    Recent developments include batteries with embedded functionality such as

    USBCELL, with a built-in charger and USB connector within the AA format,

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    enabling the battery to be charged by plugging into a USB port without a charger

    USB Cell is the brand of NiMH rechargeable battery produced by a company

    called Moixa Energy. The batteries include a USB connector to allow recharging

    using a powered USB port. The product range currently available is limited to a

    1300 mAh.

    Fig. 1.4 USB cell

    1.5 Life of battery

    Even if never taken out of the original package, disposable (or "primary")

    batteries can lose 8 to 20 percent of their original charge every year at a

    temperature of about 2030C. [54] This is known as the "self-discharge" rate andis due to non-current-producing "side" chemical reactions, which occur within the

    cell even if no load is applied to it. The rate of the side reactions is reduced if the

    batteries are stored at low temperature, although some batteries can be damaged by

    freezing. High or low temperatures may reduce battery performance. This will

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    affect the initial voltage of the battery. For an AA alkaline battery this initial

    voltage is approximately normally distributed around 1.6 volts.

    Rechargeable batteries self-discharge more rapidly than disposable alkaline

    batteries, especially nickel-based batteries a freshly charged NiCd loses 10% of itscharge in the first 24 hours, and thereafter discharges at a rate of about 10% a

    month. Most nickel-

    based batteries are partially discharged when purchased, and must be charged

    before first use.

    1.6 Hazards related to batteries

    1.6.1 ExplosionA battery explosion is caused by the misuse or malfunction of a battery, such as

    attempting to recharge a primary (non-rechargeable) battery, or short circuiting a

    battery.

    1.6.2 CorrosionMany battery chemicals are corrosive, poisonous, or both. If leakage occurs, either

    spontaneously or through accident, the chemicals released may be dangerous

    Fig 1.5 Life cycle

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    1.6.3 Environmental pollutionThe widespread use of batteries has created many environmental concerns, such as

    toxic metal pollution. Battery manufacture consumes resources and often involves

    hazardous chemicals. Used batteries also contribute to electronic waste.

    Americans purchase nearly three billion batteries annually, and about 179,000 tons

    of those end up in landfills across the country.

    1.6.4 IngestionSmall button/disk batteries can be swallowed by young children. While in the

    digestive tract the battery's electrical discharge can burn the tissues and can be

    serious enough to lead to death.

    Fig 1.6 Electronic waste

    2. PAPER BATTERY

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    Energy has always been spotlighted. In the past few years a lot of inventions

    have been made in this particular field. The tiny nuclear batteries that can provide

    energy for 10 years, but they use radioactive elements and are quite expensive.

    Few years back some researchers from Stanford University started experiments

    concerning the ways in which a copier paper could be used as a battery source.

    After a long way of struggle they, recently, concluded that the idea was right. The

    batteries made from a plain copier paper could make for the future energy storage

    that is truly thin.

    The anatomy of paper battery is based on the use of Carbon Nanotubes tiny

    cylinders to collect electric charge. The paper is dipped in lithium containing

    solution. The nanotubes will act as electrodes allowing storage device to conduct

    electricity. Its astounding to know that all the components of a conventional

    battery are integrated in a single paper structure; hence the complete mechanism

    for a battery is minimized to a size of paper.

    One of the many reasons behind choosing the paper as a medium for battery

    is the well-designed structure of millions of interconnected fibers in it. These fiberscan hold on carbon nanotubes easily. Also a paper has the capability to bent or

    curl.

    You can fold it in different shapes and forms plus it as light as feather. Output

    voltage is modest but it could be increased if we use a stack of papers. Hence the

    voltage issues can be easily controlled without difficulty. Usage of paper as a

    battery will ultimately lead to weight diminution of batteries many times as

    compared to traditional batteries.

    It is said that the paper battery also has the capability of releasing the energy

    quickly. That makes it best utilization for devices that needs burst of energy,

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    mostly electric vehicles. Further, the medical uses are particularly attractive

    because they do not contain any toxic materials.

    Fig.2 Papper Battry

    A paper battery is a flexible, ultra-thin energy storage and production device

    formed by combining carbon nanotubes with a conventional sheet ofcellulosebased

    paper. A paper battery acts as both a highenergy battery and super capacitor,

    combining two discrete components that are separate in traditional electronics.

    Paper Battery= Paper (Cellulose) + Carbon Nanotubes

    Cellulose is a complex organic substance found in paper and pulp; not digestible

    by humans. A Carbon NanoTubes (CNT) is a very tiny cylinder formed from a

    single sheet of carbon atoms rolled into a tiny cylinder. These are stronger than

    steel and more conducting than the best semiconductors. They can be Single-

    walled or Multi-walled.

    Mayer-rod-coated on the paper substrate with an effective thickness of 10 _m. The

    wet PVDF functions as a glue to stick the double layer films on paper. Theconcentration of PVDF in N-methyl-2-pyrrolidone (NMP) was 10% by weight the

    double layer films were laminated on the paper while the PVDF/ NMP was still

    wet. During this process, a metal rod rolls over the films to remove air bubbles

    trapped between films and the paper separator. After laminatingLTO/CNT on one

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    side of the paper, thesame process was used to put LCO/CNTon the opposite side

    of the paper to complete the Li-ion battery fabrication. Figure 1d,e shows the

    scheme and a final deviceof the Li-ion paper battery prior to

    encapsulation and cell testing. Althougha paper-like membrane has been used as

    the separator for other energy storage systems including supercapacitors, it is the

    first demonstration of the use of commercial paper in Li-ion batteries, 12 where

    paper is used as both separator and mechanical support.

    Fig2.1 Types of CNTs

    3. CARBON NANOTUBES

    Carbon nanotubes (CNTs) are allotropes of carbon with a cylindrical

    nanostructure. Nanotubes have been constructed with length-to-diameter ratio of

    up to 132,000,000:1, significantly larger than any other material. These cylindrical

    carbon molecules have novel properties, making them potentially useful in many

    applications in nanotechnology, electronics, optics, and other fields of materials

    science, as well as potential uses in architectural fields.

    They may also have applications in the construction of body armor. They

    exhibit extraordinary strength and unique electrical properties, and are efficient

    thermal conductors.

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    Their name is derived from their size, since the diameter of a nanotube is on

    the order of a few nanometers (approximately 1/50,000th of the width of a human

    hair), while they can be up to 18 centimeters in length (as of 2010). Nanotubes are

    categorized as single-walled nanotubes (SWNTs) and multi-walled nanotubes

    (MWNTs).

    In theory, metallic nanotubes can carry an electric current density of 4 109

    A/cm2 which is more than 1,000 times greater than metals such as copper, where

    for copper interconnects current densities are limited by electro migration.

    In paper batteries the nanotubes act as electrodes, allowing the storage

    devices to conduct electricity. The battery, which functions as both a lithium-ion

    battery and a super capacitor, can provide a long, steady power output comparable

    to a conventional battery, as well as a super capacitors quick burst of high energy

    and while a conventional battery contains a number of separate components, the

    paper battery integrates all of the battery components in a single structure, making

    it more energy efficient.

    Carbon nanotubes have been implemented in Nano electromechnical

    systems, including mechanical memory elements(NRAM being developed by

    Nantero Inc.)

    Fig 3. Carbon nanotubes

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    3.1 Properties of Carbon Nanotubes:

    Ratio of Width: Length: 1:107

    High tensile Strength (Greater than Steel).

    Low Mass density & High Packing Density.

    Very Light and Very Flexible.

    Very Good Electrical Conductivity (betterthan Silicon).

    Low resistance (~33 ohm per sq. inch).

    Output Open Circuit Voltage(O.C.V): 1.5-2.5 V (For a postage stamp sized)

    The O.C.V. of Paper Batteries is directly proportional to CNT concentration.

    Stacking the Paper and CNT layers multiplies the Output Voltage; Slicing the

    Paper and CNT layers divides the Output Voltage.

    Thickness: typically about 0.5-0.7mm.

    Nominal continuous current density: 0.1 mA/cm2/ active area.

    Nominal capacity: 2.5 to 5 mAh/cm2/ active area.

    Shelf life (RT): 3 years.

    Temperature operating range: -75C to +150C.

    No heavy metals (does not contain Hg, Pb, Cd, etc.)

    No safety events or over-heating in case of battery abuse or mechanical damage

    No safety limitations for shipment, packaging storage and disposal.

    Fig3.1 Variation of Resistance with Width of CNT

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    Fig3.2. Variation of Resistivity with Temperature

    4. FABRICATION OF PAPER BATTERY

    The materials required for the preparation of paper battery are

    a. Copier paperb. Carbon nano inkc. Oven

    The steps involved in the preparation of the paper battery are as follows

    Step 1: The copier paper is taken.

    Step 2: carbon Nano ink which is black in color is taken. Carbon nano ink is a

    solution of nano rods, surface adhesive agent and ionic salt solutions. Carbon nano

    ink is spread on one side of the paper.

    Step 3: the paper is kept inside the oven at 150C temperature. This evaporates the

    water content on the paper. The paper and the nano rods get attached to each other.

    Step 4: place the multi meter on the sides of the paper and we can see voltage drop

    is generated.

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    Fig 4. Fabrication process

    After drying the paper becomes flexible, light weight in nature. The paper is

    scratched and rolled to protect the nano rods on paper.

    Fig4.1 Paper Battry

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    Figure 4.2. (a) Schematic of fabrication process for free-standing LCO/CNT or LTO/CNT

    double layer thin films. The CNT film is doctor-bladed onto the SS substrate and dried. An

    LTO or LTO slurry is then doctor-blade-coated on top of CNT film and dried. The whole

    substrate is immersed into DI water, and the double layer of LTO/CNT or LCO/ CNT can

    be easily peeled off due to the poor adhesion of CNTs to the SS substrate.

    (b) (Left) 5 in. _ 5 in. LTO/CNT double layer film coated on SS substrate; (middle) the

    double layer film can be easily separated from the SS substrate in DI water; (right) the final

    free-standing film after drying.

    (c) Schematic of the lamination process: the freestanding film is laminated on paper with a

    rod and a thin layer of wet PVDF on paper.(d) Schematic of the final paper Li-ion battery device structure, with both LCO/CNT and

    LTO/CNT laminated on both sides of the paper substrate. The paper is used as both the

    separator and the substrate.

    (e) Picture of the Li-ion paper battery before encapsulation for measurement.

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    5. WORKING OF PAPER BATTERY

    The battery produces electricity in the same way as the conventional lithium-

    ion batteries that power so many of today's gadgets, but all the components have

    been incorporated into a lightweight, flexible sheet of paper.

    The devices are formed by combining cellulose with an infusion of aligned

    carbon nanotubes. The carbon is what gives the batteries their black color.

    These tiny filaments act like the electrodes found in a traditional battery,

    conducting electricity when the paper comes into contact with an ionic liquid

    solution.

    Ionic liquids contain no water, which means that there is nothing to freeze or

    evaporate in extreme environmental conditions. As a result, paper batteries can

    function between -75 and 1500C.

    The paper is made conducting material by dipping in ink. The paper works

    as a conductive layer. Two sheets of paper kept facing inward act like parallel

    plates (high energy electrodes). It can store energy like a super capacitor and it can

    discharge bursts of energy because of large surface area of nano tubes.

    Fig.5 working of a paper battery

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    Chlorine ions flow from the positive electrode to the negative one, while

    electrons travel through the external circuit, providing current. The paper electrode

    stores charge while recharging in tens of seconds because ions flow through the

    thin electrode quickly. In contrast, lithium batteries take 20 minutes to recharge.

    The sheets can be rolled, twisted, folded, or cut into numerous shapes with no loss

    of integrity or efficiency, or stacked like printer paper to boost total output.

    The components are molecularly attached to each other: the carbon nanotube print

    is embedded in the paper, and the electrolyte is soaked into the paper batteries

    produce electrons through a chemical reaction between electrolyte and metal in the

    traditional battery. Chemical reaction in the paper battery is between electrolyte

    and carbon nanotubes.

    Electrons collect on the negative terminal of the battery and flow along a

    connected wire to the positive terminal Electrons must flow from the negative to

    the positive terminal for the chemical reaction to continue.

    Fig5.1 Paper battry

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    Figure 5.2 (a) Lighting a red LED with a Li-ion paper battery which is encapsulated with

    _10 _m PDMS.

    (b) Flexible Li-ion paper batteries light an LED device.

    (c) Galvanostatic charging/discharging curves of a laminated LTO_LCO paper batteries, a

    structure as in Figure 1d.

    (d) Self-discharge behavior of a full cell after being charged to 2.6 V. The initial drop is due

    to the IR drop after turning off the charging current. Inset: cycling performance of

    LTO_LCO full cells.

    (e) Comparison of our paper Li-ion battery with a polymer paper battery. The green arrow

    indicates the target of the paper battery.

    (f) Schematic for stacked cells separated by 10 _m plastic paper. An individual cell is made

    with laminated LTO/CNT and LCO/CNT on either side of a piece of Xerox paper. A small

    piece of Cu is connected on the LTO/CNT side and Al on the LCO/CNT side.

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    6. ADVANTAGES

    The flexible shape allows the paper battery to be used small or irregularly-shaped electronics:

    One of the unique features of the paper battery is that it can be bent to any such

    shape or design that the user might have in mind. The battery can easily squeeze

    into tight crevasses and can be cut multiple times without ruining the battery's life.

    For example if a battery is cut in half, each piece will function, however, each

    piece will only contain 1/2 the amount of original power. Conversely, placing two

    sheets of paper battery on top of one-another will double the power.

    The paper battery may replace conventional batteries completely:By layering sheets of this paper, the battery's voltage and current can be

    increased that many times. Since the main components of the paper battery are

    carbon nanotubes and cellulose, the body structure of the battery is very thin,

    "paper-thin". Thus to maximize even more power, the sheets of battery paper can

    be stacked on top of one another to give off tremendous power. This can allow thebattery to have a much higher amount of power for the same size of storage as a

    current battery and also be environmentally friendly at the same time.

    Supply power to an implanted pacemaker in the human body by using theelectrolytes in human blood:

    An improvement in the techniques used in the health field can be aided by the

    paper battery. Experiments have taken place showing that batteries can be

    energized by the electrolyte emitted from one's own blood or body sweat. This can

    conserve the usage of battery acid and rely on an environmental friendly

    mechanism of fueling battery cells with the help from our bodies.

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    The paper battery can be molded to take the shape of large objects, like a cardoor:

    As stated earlier, the key characteristics that make the paper battery very appealing

    are that it can be transformed into any shape or size, it can be cut multiple times

    without damaging it, and it can be fueled through various ways besides the typical

    harmful battery acid that is used in the current day battery.

    7. LIMITATIONS

    Presently, the devices are only a few inches across and they have to be

    scaled up to sheets of newspaper size to make it commercially viable.

    Carbon nanotubes are very expensive, and batteries with large enough power

    are unlikely to be cost effective.

    Cutting of trees leading to destroying of the nature.

    8. APPLICATIONS

    The paper-like quality of the battery combined with the structure of the nanotubes

    embedded within gives them their light weight and low cost, making them

    attractive for portable electronics, aircraft, automobiles, and toys (such as model

    aircraft), while their ability to use electrolytes in blood make them potentially

    useful for medical devices such as pacemakers. The medical uses are particularly

    attractive because they do not contain any toxic materials and can

    be biodegradable; a major drawback of chemical cells. However, Professor

    Sperling cautions that commercial applications may be a long way away, because

    nanotubes are still relatively expensive to fabricate. Currently they are making

    devices a few inches in size. In order to be commercially viable, they would like to

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    be able to make them newspaper size; a size which, taken all together, would be

    powerful enough to power a car.

    With the developing technologies and reducing cost of CNTs, the paper batteries

    will find applications in the following fields:

    1. In Electronics:

    in laptop batteries, mobile phones, handheld digital cameras: The weight of these

    devices can be significantly reduced by replacing the alkaline batteries with light-

    weight Paper Batteries, without compromising with the power requirement.

    Moreover, the electrical hazards related to recharging will be greatlyreduced.

    in calculators, wrist watch and other low drain devices.

    in wireless communication devices like speakers, mouse, keyboard ,Bluetooth

    headsets etc.

    in Enhanced Printed Circuit Board(PCB) wherein both the sides of the PCB can

    be used: one for the circuit and the other side (containing the components )would

    contain a layer of customized Paper Battery. This would eliminate heavy step-

    down transformers and the need of separate power supply unit for most electronic

    circuits.

    2. In Medical Sciences:

    in Pacemakers for the heart

    in Artificial tissues (using Carbon nanotubes)

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    in Cosmetics, Drug-delivery systems

    in Biosensors, such as Glucose meters, Sugar meters, etc.

    3. In Automobiles and Aircrafts:

    in Hybrid Car batteries

    in Long Air Flights reducing Refueling

    for Light weight guided missiles

    for powering electronic devices in Satellite programs

    9. CONCLUSION

    One of the major problems bugging the world now is Energy

    crisis. Every nation needs energy and everyone needs power. And this problem

    which disturbs the developed countries perturbs the developing countries like India

    to a much greater extent. Standing at a point in the present where there cant be a

    day without power, Paper Batteries can provide an altogether path-breaking

    solution to the same. Being Biodegradable, Light-weight and Nontoxic, flexible

    paper batteries have potential adaptability to power the next generation of

    electronics, medical devices and hybrid vehicles, allowing for radical new designs

    and medical technologies. But India still has got a long way to go if it has to be

    self-dependant for its energy solution. Literature reflects that Indian researchers

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    have got the scientific astuteness needed for such revolutionary work. But what

    hinders their path is the lack of facilities and funding. Of course, the horizon of

    inquisitiveness is indefinitely vast and this paper is just a single step towards this

    direction

    .

    We have discussed the various terminologies, principle of operation of a

    battery and recent developments related to it. The life of a battery is an important

    parameter which decides the area of application of the battery. Increased use of

    batteries gives rise to E-waste which poses great damage to our environment.

    In the year 2007 paper battery was manufactured. The technology is capable

    of replacing old bulky batteries. The paper batteries can further reduce the weight

    of the electronic gadgets.

    The adaptations to the paper battery technique in the future could allow for

    simply painting the nanotube ink and active materials onto surfaces such as walls.

    These surfaces can produce energy.

    REFERENCES

    Thin, Flexible Secondary Li-Ion Paper Batteries Liangbing Hu, Hui Wu,Fabio La Mantia, Yuan Yang, and Yi Cui

    Department of Materials Science and Engineering, Stanford University,

    Stanford, California 94305.

    David Linden Handbook of batteries