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Paleomagnetism and Geochemistry of Tertiary Intrusions and Flows Associated with the Kootznahoo Formation near Kake, Southeast Alaska, and Implications for the Alexander Terrane Jordan Epstein Department of Geology, Carleton College, Northfield, MN USA March 10, 2010

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Page 1: Paleomagnetism and Geochemistry of Tertiary Intrusions and

           Paleomagnetism and Geochemistry of Tertiary Intrusions and Flows Associated with the Kootznahoo Formation near Kake, Southeast Alaska, and Implications for the Alexander Terrane 

 

 Jordan Epstein 

Department of Geology, Carleton College, Northfield, MN USA 

March 10, 2010

Page 2: Paleomagnetism and Geochemistry of Tertiary Intrusions and

TABLE OF CONTENTS:

INTRODUCTION 1

GEOLOGIC SETTING 1

PETROGRAPHY 2

METHODS OF GEOCHEMICAL ANALYSIS 4

MAJOR-ELEMENT CHEMISTRY 6

TRACE-ELEMENT CHEMISTRY 11

IMPLICATIONS OF GEOCHEMISTRY FOR PALEOMAGNETISM 15

PALEOMAGNETIC METHODS AND RESULTS 15

ANALYSIS OF DIRECTIONS 16

DISCUSSION OF REMNANT MAGNETISM 18

TECTONIC IMPLICATIONS 22

KEKU ISLETS 25

HARE ISLANDS AND HOUND ISLAND OVERPRINT 26

POINT CAMDEN GABBRO AND CLARK ISLAND 27

DISCUSSION OF THE REGROUPING OF THE HAEUSLLER ET AL. (1992) DATA 28

CONCLUSION 31

ACKNOWLEDGEMENTS 31

REFERENCES 32

Page 3: Paleomagnetism and Geochemistry of Tertiary Intrusions and

ABSTRACT

Major and trace element geochemistry of basaltic sills, dikes, and flows from 16

sites associated with the Paleogene-Neogene Kootznahoo Formation near Kake, Alaska

plot in either "within-plate" or "ocean-floor" fields on the Ti-Zr-Y diagram of Pearce and

Cann (1973), suggesting at least two basalts with distinct histories. The mean in-situ

characteristic remnant magnetism (ChRM) of 49 cores from 8 sites with MAD <7.0° and

α95 <10° is D =331.3° ± 7.07°, I = 66.5° ± 3.1, α95=3.1, k = 43.95. Applying a structural

correction based on the local strike and dip of the Kootznahoo Formation, the mean

corrected direction for all sites is D = 339.0° ± 10.7°, I =76° ± 2.4°, α95 = 2.4°, k = 70.75,

which suggests a moderate 20.6° ± 9.8° of vertical axis counterclockwise rotation and no

displacement when compared with a North American pole at ~23 Ma, the approximate

crystallization age of the gabbros and basalts (Haeussler et al., 1992). However, close

inspection of the paleomagnetic results from this study combined with previously

published paleomagnetic data from Haeussler et al. (1992) show systematic regional

differences in directions that suggest local tilting and vertical-axis rotations vary across

the region from no vertical axis rotation up to 46.3° ± 8.3° counterclockwise rotation at

some locations. This suggests Neogene deformation in the Alexander terrane east of the

Queen Charlotte and Clarence Strait faults could be locally significant and should be

considered when determining paleomagnetic directions for older rocks in the region.

Keywords: southeast Alaska, paleomagnetism, Alexander terrane, Tertiary tilt and

counterclockwise rotation

Page 4: Paleomagnetism and Geochemistry of Tertiary Intrusions and

INTRODUCTION

Shallower than expected paleomagnetic directions from the Coast Plutonic

Complex have been interpreted to indicate large-scale northward transport of the

Wrangellia Composite Terrane of about 4000 km from its present-day location (Beck,

1976, 1981; Irving et al. 1985, 1996), and this interpretation has been coined the Baja BC

hypothesis (Irving et al., 1985, Cowan et al., 1996). However, Butler et al. (1989, 2006)

note that this challenges the conventional view of the Cretaceous North American

paleogeography, and instead suggest that these directions indicate tilting of the Coast

Plutonic Complex about 30° to the southwest. Resolution of this controversy is important

for the understanding of the tectonic history of the North American Cordillera in

particular, and on convergent boundaries in general. Whether systematic post-mid-

Cretaceous tilting and rotation of crustal blocks has occurred in the region is central to

disentangling the Baja British Columbia hypothesis (Cowan et al., 1996).

This study focuses on the geochemistry and paleomagnetism of sills, dikes, and

volcanic flows associated with the Tertiary Kootznahoo Formation near Kake, Alaska.

These observations document heterogeneous crustal rotation and tilting of the Alexander

terrane post late-Paleogene, and suggest a complex local response to Tertiary deformation

in Southeast Alaska.

GEOLOGIC SETTING

The Kootznahoo Formation is a nonmarine to marginal marine clastic unit that

crops out in Southeastern Alaska, most notably in the Zarembo-Kuiu Islands region

(Dickinson, 1979; Brew et al., 1984) and on Admiralty Island (Lathram et al, 1965). The

formation consists mostly of arkosic conglomerate, sandstone, and rare shale and is

1

Page 5: Paleomagnetism and Geochemistry of Tertiary Intrusions and

intruded by gabbroic sills and dikes ranging up from one to hundreds of meters in

thickness. At Port Camden beach, the Kootznahoo Formation grades into volcaniclastic

rocks, where at least three distinct flows of three meters in thickness are recognized,

separated by hundreds of meters of the clastic Kootznahoo Formation.

Muffler (1967) suggests the sills associated with the Kootznahoo Formation have

a ‘gentle’ dip and are up to 500 meters thick, and groups the gabbro on Hamilton Island,

Kuiu Island, and Big John Bay together, with a suggested age of Miocene-Oligocene

(Gehrels and Berg, 1992). Muffler (1967) also notes that the large gabbroic sills crop out

roughly parallel with the Kootznahoo Formation, and that some samples have a magmatic

foliation that is roughly parallel with the trend of the dip. On the basis of its inferred age

and geographic location, Brew and Morrel (1983) consider these large sills to be the

northernmost intrusions of the Kuiu-Etolin volcanic-plutonic belt. Heaussler et al. (1992)

dated the intrusion at Point Hamilton using Ar40/Ar39, and obtained a 23 Ma age.

PETROGRAPHY

Thin-section analysis of 20 sites (Fig. 1) indicates two types of intrusions and

volcanism: (1) a common basaltic type, which is quartz poor, and contains

orthopyroxene, clinopyroxene, and plagioclase with rare olivine and biotite, and (2) a

relatively more rare rhyolitic type, which contains significant quartz, plagioclase and

horneblende, which is consistent with descriptions by Gehrels and Berg (1992). Evidence

of alteration is present at almost all sites, with the presence of serpentine, chlorite,

sericite, calcite and quartz veins, which Brew et al. (1984) attribute to deuteric altering.

Conspicuously, at site 09JDE10, virtually no evidence of alteration is present, suggesting

a lack of fluids during cooling. Because of the large variation in grain size and alteration

2

Page 6: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Admiralty Island Dike

PortageBay

Hamil tonBay

Big JohnBay

DavidsonBay

KadakeBay

KuiuIsland

KuiuIsland

KupreanofIsland

Kake Airport

Dak

anee

k Bay

Ro

ck

y P

a ss

Port Cam

de

n

Keku Strai t

Kupreanof Island

HoundIsland

HareIs lands

ClarkIs land

KekuIs lets

PointHamil ton

Hamil tonIs land

PointCamden

133°40’

56°55’

56°50’

56°45’

133°45’133°50’133°55’134°00’

0 3 km

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

Tmgb

MDc

MDc

MDc

Pp

Pp

Ksm

Tk

Tk

Ksm

Ksm

Pp

Pp

Qs

Tk

Tk

Tk

TkQTf

QTf

QTf

QTf

QTf

QTf

QTb

QTb

QTb

QTb

QTb

QTb

QTc

QTc

QTc

QTc

vRT

cRT

hRT

hRT

kRT

vRT

vRT

vRT

vRT

vRT

QTc

Qs

QTf

Geologic Map of the Keku Straight Area, Southeast Alaska.Modified from Muffler (1967) and Brew et al. (1984)

Surficial deposits (Quaternary): Alluvium, glaciofluvial deposits, and tidal mud flats.

Felsic volcanics (Quaternary and Tertiary): Grey to buff altered volcanic flows, tuff, or shallow intrusives with myrolitic cavities.

Basalt (Quaternary and Tertiary): Dark grey to black aphanitic basalt.

Hound Island volcanics (Triassic): Dark green to black basaltic pillow breccia and pillow lava with some interbedded limestone.

Hamilton limestone (Triassic): Dark grey thinly bedded limestone.

Qs

QTf

QTb

QTc

Tmgb

Tk

Ksm

Pp

MDc

vRT

ALASKA

MAP LOCATION

hRT

cRT

kRTVolcaniclastic deposits (Quaternary and Tertiary): Grey to buff conglomerate and lithic sandstone. Gradational contact with Tk.

Gabbro (Tertiary): Grey to black phaneritic gabbro with olivine and clinopyroxene.

Kootznahoo Formation (Tertiary): Grey to buff arkosic sandstone, conglomerate, and black shale. Coal, fossil leaves and wood present.

Turbidites (Early? Cretaceous): Rhythmically layered grey to black sandstone, siltstone, and mudstone with carbonate concretions.

Cornwallis limestone (Triassic): Grey medium to thick bedded oolitic limestone.

Keku volcanics (Triassic): Altered felsic flows and breccia, basalt, volcanoclastics and limestone.

Pybus Formation (Permian): White to light grey limestone, dolostone and chert.

Cannery Formation (Mississipian and Devonian): Dark grey to bluish green thinly bedded volcanic argillite and greywacke with chert.

Sample locationStrike and dip of bedding

09JDE01A&B

09JDE01

15

10

15

135

12

16

10

10

10

5

25

15

25 15

15

1510

20

1515

09JDE04

09JDE10A

09JDE11

09JDE07

09JDE13

09JDE12

14

12

20

20

15

15

09JDE02

09JDE03

09JDE05

09JDE09

09JDE14

09JDE15&1609JDE08

09JDE06

09JDE10BHE69

HE60

HE25&26

HE74HE75

HE76

HE77

HE73

HE71&72HE50&51

HE52HE53

HE21&22

HE24HE23

HE70HE68

HE67

HE58&59

HE20

HE55-57

HE17

HE19HE18 HE14HE13HE15

HE61HE63HE65

HE34&35HE32&33

HE31HE30

HE36HE37

HE39-41

HE42-45

HE46HE47

HE48HE49

HE85

HE78

HE83&84HE79-81

HE82

HE66

Hamilton Bay Dike

Admiralty Island Dike

Pt. & Port Camden Dikes

Pt. Camden SillPt. Camden Flow

Pt. Hamilton Sills + Dikes

Dellenite

Geochemistry Sites

Paleomagnetism Sites

QTb

Fig. 1

HorseshoeIs land

Recent dikesPt. Hamilton gabbroPort Camden flowPt. Camden gabbroLower Kuiu Is. overprintUpper Kuiu Is. overprintKeku Islets gabbroKeku Islets overprintHound Island overprintHare Islands gabbroHamilton Is. overprintUnknown component

3

Page 7: Paleomagnetism and Geochemistry of Tertiary Intrusions and

among sites, it is not possible to discern systematic differences in mineralogy between

sites based on petrographic observations alone.

Of the three rhyolitic samples, sites 09JDE05 and 09JDE09 contain large quartz

grains that appear sub-equant and hornblende, suggesting a magmatic origin, consistent

with Muffler’s (1967) field description of dellenite. Sample 09JDE09 contained

miarolitic cavities, with quartz grains clearly growing into the empty space, which

constrains emplacement to a shallow depth. Conversely, while 09JDE11 has what

appears to be some characteristics of a magmatic texture, including extremely large,

euhedral laths of plagioclase, the laths are surrounded by very small grains of quartz,

suggesting a mobilization and subsequent relatively rapid cooling of quartz. Sample

09JDE11 is sampled from the margin of the Point Camden gabbro, a sill hundreds of

meters thick, and such an interpretation is consistent with localized melting of quartz-

rich sandstone at the margin of a large sill. This high quartz-content margin is 3.5 meters

thick, which suggests either prolonged heating or extremely high temperatures at time of

intrusion.

METHODS OF GEOCHEMICAL ANALYSIS

Representative samples were collected from sixteen sites associated with the

Kootznahoo Formation: six mafic sills (Point Hamilton, Big John Bay, Point Camden,

Port Camden), six mafic dikes (Point Hamilton, Hamilton Bay, Point Camden, Port

Camden, Admiralty Island), two mafic flows (Port Camden), and two felsic flows or

intrusions (Davidson Point, Horseshoe Island) (Fig 1).

4

Page 8: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Samples were prepared and analyzed at Macalaster College using the procedure

of Vervoort et al. (2007). Their method, repeated verbatim, is as follows. “Samples were

crushed in a Bico-Braun jaw crusher, separated into two aliquots using a sample splitter,

and ground to fine powder (<75 μm) using a shatterbox with steel and tungsten carbide

(WC) bowls. The aliquot ground in WC was used for preparation of samples for major

element analyses, and the powders ground in the steel mill were used for trace element

and isotope analyses. The concentrations of major elements (SiO2, TiO2, Al2O3, Fe2O3,

MnO, MgO, CaO, Na2O, K2O, and P2O5) were determined by XRF from fused lithium

borate glass beads. Loss on Ignition (LOI) values were calculated from the percent

weight loss after ignition (1000° C for 1 hour) relative to the dried (105° C for 2 hours)

sample powders.

One gram of ignited rock powder was mixed with five grams of dried lithium

tetraborate/metaborate (12:22) flux, and 0.01 gram ammonium nitrate (NH3NO4). The

sample mixture was then fused in platinum alloy (95% Pt—5% Au) crucibles with two

drops 50% hydrobromic acid solution (HBr) using a Claisse® Fluxy. Fused samples were

cast in 32mm diameter platinum alloy molds which produced glass discs approximately

5mm thick.

Trace-element concentrations (Co, Ni, Zn, Ga, Ba, Rb, Sr, Y, Zr, Nb, Ce, Pb, Th,

and U) were determined from pressed powder pellets. Ten grams of rock powder were

combined with 15–20 drops of 2% polyvinyl alcohol (PVA). The mixture was then

placed in a 40mm diameter stainless steel die and formed into a 5mm thick pellet by

applying six tons pressure for 60 seconds in a manual press.

5

Page 9: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Major and trace-element concentrations were determined using a Philips PW-

2400 X-ray Fluorescence Spectrometer with a Rh-anode, end window X-ray tube, and

Philips Super-Q analytical software at Macalester College. Elemental concentrations

were determined by comparing X-ray intensities for each element in a sample unknown

with those from reference samples from the US Geological Survey” (Vervoort et al.,

2007).

MAJOR-ELEMENT CHEMISTRY

SiO2 content of samples ranges widely, from about 35 -75 weight percent (Table

1); however, analyses with weight percent lower than 45 should be treated with suspect,

as these samples tended to have extremely high loss on ignition (LOI), with some as high

as 14 weight percent. Comparison with geochemical analysis by Ford et al. (1996) of the

Admiralty Island volcanics had similarly high LOI but no quartz deficient samples, which

suggests a processing error on my part. Discounting these data, these rocks plot as either

basalt or rhyolite, as shown on the total alkali and silica (TAS) diagram (Fig. 2) (Lebas et

al., 1986). Discounting the sample from Admiralty Island and the chill margin at site

09JDE11, there is a SiO2 gap from about 48-75 weight percent. The lack of rocks of

intermediate composition makes determination of source material, fractional

crystallization, or crustal assimilation difficult; however, the Point Hamilton gabbro has

higher MgO and lower Na2O content than all other sites (Fig. 3); however, Na2O is highly

mobile so should be interpreted with care. Aside from this, the major-element chemistry

of basalts is largely homogenous across sites and samples, with the only exception that

dikes (regardless of location) having slightly higher TiO and lower Al2O3 content than

other sites (Fig. 3).

6

Page 10: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Major-element contents of the rhyolite samples 09JDE05 and 09JDE09 are nearly

identical, which were mapped by Brew et al. (1984) as dellenite and granite, respectively.

This suggests that the two are genetically related, and that the dellenite is simply the

extrusive equivalent of the granite. Comparison with the other “rhyolite” sample

09JDE11, the margin of the Point Camden sill, shows significantly lower SiO2 and a

distinct major element composition. This is consistent with the interpretation of localized

melting of a quartz-rich arkosic sandstone.

7

Page 11: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Tabl

e 1.

Maj

or-e

lemen

t che

mica

l com

posit

ion

(weig

ht p

erce

nt) o

f sam

ples

reno

rmal

ized

by

the

volat

ile fr

ee a

mou

ntEl

emen

t09

JDE0

1A09

JDE0

1B09

JDE0

209

JDE0

309

JDE0

409

JDE0

509

JDE0

709

JDE0

809

JDE0

909

JDE1

009

JDE1

0G09

JDE1

109

JDE1

409

JDE1

509

JDE1

609

JDE1

8Si

O2

46.4

946

.10

34.9

846

.43

46.5

975

.00

46.8

543

.81

73.8

648

.06

47.3

069

.17

44.0

541

.95

38.3

650

.22

TiO

21.

151.

053.

761.

321.

300.

111.

621.

520.

252.

151.

380.

432.

212.

241.

661.

89A

l 2O3

16.6

016

.83

15.1

516

.30

16.1

412

.61

16.1

618

.71

9.80

15.3

218

.09

14.0

314

.53

15.1

913

.98

14.9

1Fe

2O3

11.0

410

.98

16.4

811

.43

11.7

11.

568.

958.

555.

8413

.41

9.61

4.49

12.4

212

.32

10.5

99.

93M

nO0.

180.

220.

190.

180.

190.

010.

160.

180.

060.

220.

160.

080.

190.

200.

210.

18M

gO8.

619.

203.

298.

077.

950.

102.

365.

490.

015.

196.

400.

393.

613.

795.

083.

40C

aO11

.52

11.0

110

.36

10.7

811

.32

0.64

10.8

511

.20

0.11

9.39

10.1

51.

9812

.35

9.28

12.0

36.

44N

a 2O

2.50

2.26

2.95

2.57

2.79

4.34

3.61

3.90

5.48

3.41

3.96

4.62

3.09

3.43

3.09

3.59

K2O

0.21

0.37

0.86

0.69

0.21

5.32

0.59

0.32

4.53

0.71

0.45

4.07

0.62

0.32

0.73

0.98

P 2O

50.

100.

100.

600.

120.

110.

020.

220.

190.

000.

350.

160.

070.

360.

250.

370.

46LO

I1.

581.

8911

.38

2.11

1.68

0.29

8.63

6.13

0.07

1.79

2.34

0.68

6.56

11.0

213

.91

8.00

Sum

100.

0010

0.00

100.

0010

0.00

100.

0010

0.00

100.

0010

0.00

100.

0010

0.00

100.

0010

0.00

100.

0010

0.00

100.

0010

0.00

8

Page 12: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Picro-basalt

Basalt

Basalticandesite

AndesiteDacite

Rhyolite

Trachyte

TrachydaciteTrachy-andesite

Basaltictrachy-andesiteTrachy-

basalt

TephriteBasanite

Phono-Tephrite

Tephri-phonolite

Phonolite

Foidite

35 40 45 50 55 60 65 70 750

2

4

6

8

10

12

14

16

Na2O+K2O

SiO2

Hamilton Bay Dike

Admiralty Island Dike

Pt. & Port Camden Dikes

Pt. Camden SillPt. Camden Flow

Pt. Hamilton Sills + Dikes

Dellenite

Figure 2. Total alkali versus silica diagram, after Lebas et al. (1986). The Point Hamilton sills and dikes have significantly lower total alkali content than all other samples. There is a silica gapfrom 48 to 70 wt. percent, exlcuding the Admiralty Island dike.

9

Page 13: Paleomagnetism and Geochemistry of Tertiary Intrusions and

0

5

10

MgO

12

17

22

Al2O3

0.0

0.5

1

1.5

2.0TiO2

CaO

K O2 Na O2

6

4

2

30 75 30 75SiO2

15

0

Figure 3. Harker Diagrams for Majors. Point Hamilton sills and dikes have higher MgO and lower Na Othan all other samples. Dikes appear to have higher TiO and lower Al O . Sample 09JDE11 has lower silica and distinct major elment composition from the other rhyolites.

Sample 9 has 9 wt. % Al2O3

10

5

2

3

4

0

SiO2

6

4

2

0

2

2 3

10

Page 14: Paleomagnetism and Geochemistry of Tertiary Intrusions and

TRACE-ELEMENT CHEMISTRY

Trace-element contents of basaltic samples (Table 2) show variation that appears

independent of SiO2 (Fig. 4). This suggests that the basalts are not related by fractional

crystallization, as it would be expected that incompatible elements be concentrated in

basalts of higher SiO2 content, and compatible elements concentration likewise be

reduced. However, because SiO2 content of reasonable analyses spans only 45-48 weight

percent, it is unlikely that any sign of fractionalization would be apparent. Trace-element

content of the rhyolitic samples (excluding 09JDE11) have extremely low concentrations

of the compatible elements Ni, Cr, and Sr, and high concentrations of the incompatible

elements Rb and Zr, as expected, although Ba concentration is more variable than

anticipated. The similarity between samples 09JDE05 and 09JDE09 supports the

conclusion that they are genetically related, and sample 09JDE09 has significantly higher

elevated levels of Zr, as expected of a plutonic rock.

It is not possible to distinguish between bimodal volcanism, fractionalization, or

assimilation from this data alone—however, given the paucity of rocks of intermediate

composition, I would favor bimodal volcanism as found throughout Southeast Alaska and

on the nearby Zarembo and Admiralty Islands (Lindline et al., 2004, Ford et al., 1996).

Finally, elevated trace element concentration in of La, Nb, Rb, and Zr in sample 09JDE11

11

Page 15: Paleomagnetism and Geochemistry of Tertiary Intrusions and

Tabl

e 2.

Trac

e ele

men

t con

tent

(in

parts

per

milli

on)

Elem

ent

09JD

E01A

09JD

E01B

09JD

E02

09JD

E03

09JD

E04

09JD

E05

09JD

E07

09JD

E08

09JD

E09

09JD

E10

09JD

E10G

09JD

E11

09JD

E14

09JD

E15

09JD

E16

09JD

E18

Ba10

726

267

761

510

570

544

722

137

719

201

990

365

328

456

4187

Ce11

1044

108

7129

2215

434

1864

4722

4440

Co53

5216

350

502

3348

136

324

4348

4728

Cr27

027

853

260

242

412

224

55

8019

83

105

6821

213

Cu42

5845

422

523

1119

619

206

2412

880

41Ga

1717

3119

1718

2119

3420

1922

2222

1918

La3

417

66

4015

1291

198

3720

1220

16N

b4

521

45

1910

997

169

2115

1214

16N

i11

111

959

8394

1231

135

1437

4015

3782

141

25Pb

bd7

bdbd

bd17

2bd

141

bd13

0bd

bdbd

Rb8

814

215

152

52

137

85

114

103

1219

Sc34

3341

3938

332

370

2926

638

2127

24Sr

234

255

525

262

224

6931

529

13

396

559

144

450

348

529

863

Th3

3bd

23

163

219

20

112

40

bdU

10

6bd

bd9

21

10bd

bd7

13

bdbd

V21

520

441

625

623

72

257

253

224

219

95

298

276

286

280

Y26

2349

3029

4632

2711

140

2054

4026

2331

Zn69

145

449

5281

3111

079

213

121

7286

132

107

8811

2Zr

8077

294

9990

158

171

125

943

206

113

355

219

151

164

238

12

Page 16: Paleomagnetism and Geochemistry of Tertiary Intrusions and

NiO

200

0 0

500

1000

Ba

Note Sample 18 has a Ba of4402 ppm

Cr

0

50

100Rb

0

100

200

300Zr

Note Sample 9 has a Zr of1006 ppm

0

500

1000

Sr

30 7530 75

400

0

300

200

100

300

100

150

200

400

500

SiO2 SiO2

Figure 4. Harker Diagrams for trace elements. Selected trace elements (in ppm) against silica (wt. percent.). Trace element concentration of basalts appears independent of silica. Rhyolites show high concentrationof Zr, Rb, and low concentrations of Ni, Cr, Sr.

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Zr Y*3

Ti/100

C

DA

B

Island-arc A B

Ocean-!oor B

Calc-alkali B C

Within-plate D

Alkali basalt

Tholeiitic basalt

0.00 0.05 0.10 0.150

1

2

3

4

TiO 2

Zr/(P 2O 5*104)

200 400

Figure 6. Tectonic discrimination plotsfor basalts with 12­20 wt. percent  CaO + MgO, after Pearce and Cann (1973). Note that the Point Hamilton sills and dikes plot exclusivley in theocean­floor basalt, while all other samples plot as within­plate or calc­alkaline basalts.

Figure 5. Alkali vs.Tholetic discrimination diagram for basalts, after Floyd and Winchester (1976).All basalts from the Keku Strait appear tholeitic.

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is consistent with the hypothesis of localized melting and incorporation of the nearby

poorly developed arkosic sandstone formation.

IMPLICATIONS OF GEOCHEMISTRY FOR PALEOMAGNETISM

The geochemistry of these samples suggests that there are at least two genetically

distinct basalts: the Point Hamilton gabbroic sill, and all other sites. While all basalts are

tholeitic (Fig. 5), the Point Hamilton sill has a geochemical signature consistent with

ocean floor basalts, while all other samples plot in the within-plate or calc-alkaline fields

(Fig. 6). In thin section, it is difficult to distinguish between basalts—thus, geochemically

and petrologically distinct basalts might easily be inferred to be identical based on

mineralogy alone. Reconnaissance of this area of Southeast Alaska has previously

grouped all sills and dikes together under the label “Tertiary Gabbros” (Muffler, 1967;

Brew et al., 1984; Gehrels and Berg, 1992). Geochemical evidence in this paper suggests

that at least some of these sills and dikes are distinct and that the assumption of a

homogenous “Tertiary Gabbro” be revisited. This further suggests that paleomagnetic

data from one location of intrusions cannot necessarily be applied to or averaged with

another without further geochemical or geochronological work demonstrating they have

related compositions or crystallized at the same time.

PALEOMAGNETIC METHODS AND RESULTS

Seventy-two paleomagnetic samples were collected from 12 sites of basaltic

dikes, sills, and volcanic flows exposed on shorelines of islands west of Kake in southeast

Alaska (Fig. 1). Six or more oriented samples were collected from each site. A portable

coring device was used to collect samples in the field, which were oriented using an

inclinometer and magnetic compass. At the Institute of Rock Magnetism at the University

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of Minnesota, a ten-step alternating field demagnetization was performed on each

sample. All measurements were made using a 2G three axis cryogenic magnetometer in a

shielded room. For 8 sites (49 cores), characteristic remnant magnetism (ChRM) was

easily isolated, and little evidence of thermal or chemical overprinting was present. The

magnetic mineralogy appears to be magnetite or titanomagnetite, based on the

coercivities of less than 100 mT for most samples, and in thin section visible equant and

euhedral to subeuhedral opaque grains are ubiquitous.

ANALYSIS OF DIRECTIONS

The demagnetization behavior for most of the samples in this study suggests one

stable component of magnetization for which a ChRM was isolated. The high coercivity

and stable component is typically well defined, and yields four primary directions of

magnetism. The first group of magnetizations is steeply dipping down (I = 67°) and

oriented north-northwest (D = 335°); the second, dipping moderately down (I = 55°) and

oriented northwest (D = 320°); the third dipping moderately down (I = 59°) and oriented

north (D=2°, and the fourth, dipping steeply down (I = 76°), and oriented north (D =7°)

(Fig. 7A-D). A fifth unstable magnetization was found at four sites for which no ChRM

could be confidently established (Fig. 7 E, F). All sites within this fifth group of

characteristic magnetizations displayed extremely low inclinations either up or down (I ≈

± 10°), and oriented either south or north (D ≈ 0° or 180°). These samples also had

extremely low coercivities, suggesting variations in magnetic mineralogy, range of

magnetic grain sizes, or lack of a strong magnetic field at time of cooling through the

blocking temperature (Haeussler et al., 1992). Regardless, these directions are not further

treated in this paper.

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NRM

5 101520

30

40

50

75100

N, Up

W

NRM5N, Up

E

1015

2030

40

50

NRM

510

1520

30 405075

N, Up

W

NRM

5

101520 30

40

N, Up

W

NRM

5

N, Up

E

1015

2030

A. B. C.

D. E. F.

Fig. 7. A-E. Orthogonal vector plots of alternating field demagnetization results. Filled symbols correspond to the horizontalvector component (declination), and open symbols correspond to the vertical component projected onto the plane of thefigure (inclination). Alternating field steps in mT. Plots show examples of A.) normal polarity Point Hamilton sill,B.) reverse polarity Port Camden flow, C.) Point Camden sill, D.) recent dike at Port Camden, E.) a lack of stablemagnetization. Note the extremely low coercivity and the loss of nearly all remnant magnetism in the smallstep from 15 to 20 mT. F.) is an equal area plot of the directions of 09JDE14, showing extremely shallow dips and both normal and reversed polarities within the same core. Such data is suggestive of a lack of a strong magnetic fieldat the time of cooling through the blocking temperature, possibly due to a transitioning pole. Such directions are not treatedfurther in this paper.

09JDE015E

09JDE014F

09JDE08D

09JDE11B09JDE4C

09JDE014F

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For individual samples, I calculated the orientation of the ChRM by a least

squares regression of the portion of the vector diagram that decays univectorally toward

the origin of the plot, using a weighted analysis and forcing through the origin. Between

3 and 10 points, with an average of 5.0 points, were used to define this straight-line

segment. No least squares regression reported in this paper had a maximum angular

deviation (MAD) of greater than 7.0°, and the average MAD was 1.81°. Site means were

calculated using Fisher statistics, and all sites had an α95 confidence interval of <10°, with

an average of 5.27°. The Fisher precision parameter k for all sites is greater than 50, with

an average of 218.6 and a maximum as high as 645. The coercivities of sites is quite

variable, with some samples losing >90% of their initial magnetization when exposed to

fields of 20 μT, while other sites displayed extremely high coercivities and showed

considerable remnant magnetization even after exposure to 100 μT.

DISCUSSION OF REMNANT MAGNETISM

Paleomagnetic data from the Keku Strait is organized by locality and presented in

Table 3 and Fig. 8. Magnetic directions are compared to the 20 Ma reference pole of

Hagstrum et al. (1987) at 87.4° N, 129.7° E, A95 = 3.0°, with expected direction of I =

73.5° ± 1.5°, D = 359.6° ± 5.9°. Using the Oligocene reference pole at 84.0° N, 168.0°,

A95 = 4.0° (Diehl, 1988), the expected Oligocene direction differs by only I = +1.5° and

D = +7°, so the choice of reference pole has largely negligible effect for paleomagnetic

comparison. Magnetic directions for individual sites are compared to expected values,

and values for inclination flattening (F ± ΔF) and rotation of declination (R ± ΔR) are

calculated using the methods of Beck (1980) and Demarest (1983). Site 09JDE15 is the

only site to record a magnetization direction within error of the expected direction; all

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Abbreviations as follows: M — inferred magnetization group, with: (red) Point Hamilton gabbro group, (orange) Point Camden gabbro, (yellow) Port Camden flows, and (green) recent dike; N — indicates the number of cores used out of the total collected; P — polarity, whether normal (n), reversed (r) or no good(ng); R — the vector length of the mean direction; α95 — indicates the 95% confidence interval; k — the Fisher precision parameter; I — Inclination; D — Declination; R — Rotation (positive for clockwise) as compared to the expected declination based on the 20 Ma North American pole of Hagstrum et al.(1987); F — Flattening, after Beck et al. (1981) and Demarest (1983); Bedding S & D— best estimate for strike and dip of the Kootznahoo Formation near site.

Group In-Situ Directions BeddingM Group N P r α95 k I D R ΔR F ΔF Variable

All Data 49/72 n/r 48.9 3.1 43.95 66.5 331.3 -28.3 7.8 7.0 2.9Port Camden Flows 19/19 n/r 18.8 3.9 75 62.7 313.3 -46.3 8.3 10.8 3.5Point Hamilton and Big John Bay 21/23 n 20.7 3.6 79 67.6 339.0 -20.6 8.9 5.9 3.2

Group Tilt-Corrected Directions BeddingM Group N P r α95 k I D R ΔR F ΔF Variable

All Data 49/72 n/r 48.9 2.4 75 76.9 339.0 -20.6 9.7 -3.4 2.4Port Camden Flow 19/19 n/r 18.8 3.6 90 74.3 314.9 -44.7 11.5 -0.8 3.2Point Hamilton and Big John Bay 21/23 n 20.7 2.9 118 78.5 353.6 -6.0 12.8 -5.0 2.8

Tilt-Corrected Point Camden sill Compared to Late Cretaceous Pole (Mcelhinney, 1979) BeddingM Site Latitude(°)Longitude(°)N P r α95 k I D R ΔR F ΔF S D

09JDE11 56.79 133.88 5/6 n 5 7.7 81 70.5 9.6 -24.6 19.8 4.3 6.4 80 12

Table 3Epstein (2009) data.Site In-Situ Directions BeddingM Site Latitude(°)Longitude(°)N P r α95 k I D R ΔR F ΔF S D

09JDE3+4 56.86 133.87 9/10 n 8.9 5.3 86 70.5 335.8 -23.8 13.6 3.1 4.5 47 1009JDE06 56.75 133.87 7/7 n 7 2.2 646 62.7 298.3 -61.3 6.1 10.8 2.3 49 1009JDE07 56.76 133.87 6/6 n 6 5.8 111 68.5 312 -47.6 13.7 5.0 4.9 49 1009JDE08 56.77 133.87 6/6 r 6 3.6 290 -55.4 148 -31.6 6.9 18.1 3.2 49 1509JDE10 56.80 133.86 0/6 ng09JDE11 56.79 133.88 5/6 n 5 7.7 81 59.0 2.5 2.9 12.9 14.5 6.3 80 1209JDE12 56.82 133.74 6/6 n 6 3.8 254 69.1 324.3 -35.3 9.9 4.4 3.4 75 1509JDE13 56.80 133.68 6/6 n 5.9 8.4 54 61.4 352.5 -7.1 14.9 12.1 6.9 47 1209JDE14 56.78 133.86 0/7 ng09JDE15 56.78 133.87 4/6 n/r 4 6.3 160 76 7.9 8.3 22.1 -2.5 5.3 49 1609JDE16 56.78 133.87 0/6 ng

Site Tilt-Corrected Directions BeddingM Site Latitude(°)Longitude(°)N P r α95 k I D R ΔR F ΔF S D

09JDE3+4 56.86 133.87 9/10 n 8.9 4.5 119 78.6 356.5 -3.1 19.1 -5.0 3.9 47 1009JDE06 56.75 133.87 7/7 n 7 2.2 669 72.3 291.7 -67.9 7.4 1.2 2.3 49 1009JDE07 56.76 133.87 6/6 n 6 5.8 112 78.4 313.1 -46.5 24.6 -4.9 4.9 49 1009JDE08 56.77 133.87 6/6 r 6 3.4 327 -69.2 159.2 -20.4 9.0 4.3 3.1 49 1509JDE11 56.79 133.88 5/6 n 5 7.7 81 70.5 9.6 9.7 19.4 3.0 6.3 80 1209JDE12 56.82 133.74 6/6 n 6 3.8 258 80.3 339.1 -20.5 19.2 -6.8 3.4 75 1509JDE13 56.80 133.68 6/6 n 5.9 8.4 54 76.1 0.1 0.5 30.2 -2.6 6.9 47 12

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In-Situ Directions Tilt-Corrected Directions A. B.

C. D.

E. F.

G. H.

Port Camden Flows

Pt. Hamilton

Pt. Camden Sill

N N

N N

N N

N N

Fig 8.

A. In-situ directions for all cores. Black circles are normal and white reversved polarities. The red triangle is the calculated mean pole. The green square is the expected direction as compared to a Miocene pole. Comparison with the expected direction shows directions are 28.3° ± 7.8° counterclockwise and 7.0° ± 2.9° more shallow than expected.B. Tilt-corrected directions for all data. Comparisonwith the expected direction shows declinations are 20.6° ± 9.7°counterclockwise and inclination within error of expected.

All data

Sills & Dikes

Big John Bay

C. In-situ directions for cores converted to lower hemisphere. Yellow circles are individual cores, yellowtriangle is the mean, black circle is the α95 confidence interval.The green square is the expected direction as compared to a Miocene pole. Comparison with the expected direction shows mean is 46.3° ± 8.3° counterclockwise and 10.8° ± 3.5° more shallow than expected.D. Tilt-corrected directions. Comparison with the expected direction shows declinations are still44.7° ± 11.5°counterclockwise and inclination within error of expected.

E. In-situ directions for cores. Red circles are individualcores, red triangle is the mean, black circle is the α95confidence interval.The green square is the expected direction as compared to a Miocene pole. Comparison with the expected direction shows mean is 20.6° ± 8.9° counterclockwise and 5.9° ± 3.2° more shallow than expected.F. Tilt-corrected directions. Comparison with the expected direction shows directions are within error ofexpected.

G. In-situ directions for cores. Orange circles are individual cores, orange triangle is the mean, black circleis the α95 confidence interval.The green square is theexpected direction as compared to a Miocene pole, the blue as compared to a Cretceous pole. Comparison with the expected Miocene direction shows no declination discordance but inclination 14.5° ± 6.3° more shallow than expected.

H. Tilt-corrected directions. Comparison with the expected Miocene direction shows no discordance; comparison with a a late Cretaceous expected directionshows similar inclination but significant counterclockwise rotation of 24.6° ± 19.8° .

20

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other sites record shallower than expected inclinations, and declinations west of the

expected north. Because all sites are inferred to be Tertiary and the location of the

Alexander terrane is well constrained to its present day location by that time, significant

northward transport is not viable. All paleomagnetic discordance must therefore be due to

crustal block tilting or rotations.

Structural corrections are performed on all sites by rotating to horizontal based on

the local strike and dip of the Kootznahoo Formation. For the sills and dikes, inclination

changes are particularly sensitive to the dip amount, and to determine confidence

intervals at least an additional ± 2° should be added to reflect the uncertainty in the strike

and dip of the Kootznahoo Formation. By doing so, all structurally corrected dikes and

sills on Kupreanof Island fall within error of the expected paleomagnetic direction (Table

3, Fig. 8 F).

For the Port Camden flows sampled at sites 09JDE06, 09JDE07, and 09JDE08,

the average in-situ declination is about 45° west of expected, and inclination is 10° too

shallow. There are tens of meters of sedimentary and volcaniclastic sediments between

each flow, and site 09JDE08 is reversed, making it likely that a large amount of time is

represented between flows on an order greater than 105 years. This suggests that an

average of the sites’ directions provides an accurate measure of position and successfully

averages out measures of secular variation typical of directions sampled from individual

flows. Correcting the flows based on the bedding of the local Kootznahoo Formation

eliminates the inclination discordance, but still leaves the 45° counterclockwise

declination gap unresolved.

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Finally, one sill (09JDE16) intruded by dike 09JDE15 was sampled that yielded

unusual directions of magnetism. Three cores yielded the type 5 magnetism with

extremely low coercivity and low inclinations that are characteristic of a transitional pole.

However, the three other cores yielded directions of magnetization which all had reversed

polarities and independently had extremely low MAD, but gave paleomagnetic directions

that were completely inconsistent between cores. Notable at this site were what we

documented in the field to be flame or mullion structures and evidence of soft sediment

deformation. Given this field relationship, it is possible that the sill cooled past its

blocking temperature and then experienced rigid body flexure. This would scatter

otherwise consistent paleomagnetic directions and yield the discordant directions found.

TECTONIC IMPLICATIONS

Paleomagnetic results from this study, which suggest local tilting and vertical-axis

rotations up to 46.3 ± 8.3°, seem to be at odds with previously published paleomagnetic

data from Haeussler et al. (1992), who found insignificant evidence of Tertiary tilting or

counterclockwise rotation anywhere in the Keku Strait. However, close inspection of

their data reveals systematic differences in paleomagnetic directions based on locality,

and it appears only fortuitous that the disparate directions averaged to yield no directional

discordance. Parsing their data by location, data from both studies are consistent with

local tilting and heterogeneous vertical-axis rotations.

The directional data on Point Hamilton of sites 09JDE03&04 are consistent with

those from Haeussler et al. (1992), and are not statistically distinguishable from dikes

09JDE12 and 09JDE13. All sites, including all of the Haeussler et al. (1992) sites, have

paleomagnetic directions that differ from those expected of a Miocene pole, with

22

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inclinations too shallow by about 8° and declinations about 18° counterclockwise from

expected. Performing tilt-corrections based on the strike and dip of the local Kootznahoo

Formation yields directions within error of the expected early Miocene directions.

Haeussler et al. (1992) found a 23 Ma age for this sill, which constrains the occurrence of

tilt to the Neogene. This suggests most if not all of the current dip of the Kootznahoo

Formation can be attributed to this tilting. Furthermore, this suggests that the portion of

Kupreanof Island near Point Hamilton and Big John Bay deformed as a unit, and at least

in recent history represents a single crustal block.

Directional data from the basaltic flows of Port Camden beach, sites 09JDE06-08,

are distinct from all other sites and localities except for site HE66, a 100 m thick dike that

cuts through the Kootznahoo Formation across from Port Camden beach. Without

performing a tilt-correction, the data suggests ≈45° of counter-clockwise rotation and a

northward transport of 15° in the Neogene, which is untenable. Performing a tilt-

correction based on the local strike and dip of the Kootznahoo Formation yields a latitude

consistent with that expected, but still leaves the ≈45° of counterclockwise discordance

unresolved.

Without alternative, it appears likely this paleomagnetic discordance is due to

simple counterclockwise rotation about a vertical axis. If so, it is likely this rotation

represents deformation local only to Kuiu Island, as all other sites sampled in this study

do not require any vertical-axis rotation when compared with a Miocene pole. A

comparison of strike directions of the Kootznahoo Formation at Port Camden beach with

the average strike of the Kootznahoo Formation appears to support this conclusion of

variable rotation: while the average strike of the Kootznahoo Formation is 086° (Muffler,

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1967), the average strike of the sampled area of Port Camden beach is ≈050°, which

suggests a counterclockwise rotation of ≈36°, which is consistent with the rotation

calculated from the paleomagnetic data.

Because all other sites sampled in this study require a tilt-correction but not a

rotation correction, it seems likely that response to tectonic deformation is

heterogeneously accommodated in portions of the Kootznahoo Formation, with the

Kupreanof Island block experiencing tilt-only deformation and the Port Camden block

experiencing both tilt and counter-clockwise rotation.

However, additional complexity must be considered due to the directional data

from the Point Camden sill, including 09JDE11 (Fig. 8 G,H) and HE 67, 68, 70. In-situ

directions show declinations within error of the expected Miocene direction but

inclinations significantly too shallow. Structural correction based on the strike and dip of

the local Kootznahoo Formation corrects data from this study to within the expected

direction but leaves about ≈10° of inclination discordance in the Haeussler et al. (1992)

data. Because this sill is within two kilometers of the Port Camden flows, this suggests

that counterclockwise rotation is localized only to Port Camden flows, or possibly that

the Port Camden flows were extruded and rotated before emplacement of the sill, and

then both were tilted.

Alternatively, an arbitrary comparison of the sill with a Cretaceous pole

(Mcelhinney, 1979) shows insignificant inclination discordance but considerable

counterclockwise rotation 24.6 ± 19.8°, which is consistent with the vertical axis

counterclockwise rotation of the nearby Port Camden flows. Such an interpretation would

suggest crustal block tilting and rotation of the entire portion of the Point Camden

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Peninsula of Kuiu Island; however, this is contingent upon a late Cretaceous age for the

yet-undated Point Camden gabbro. Field relationships of this sill do not show conclusive

evidence of intrusion into the Kootznahoo Formation, and it is at least possible that the

sill could be Cretaceous in age. In the discussion of the Haeussler et al. (1992) data that

follows, I will make an argument for a late Cretaceous age for the sill.

The re-interpretation and regrouping of the data of Haeussler et al. (1992) satisfyingly

explains directional data of all the Tertiary data on Kupreanof Island, including the Point

Hamilton sills, and dikes and the Big John Bay dikes, and is consistent with directional

data from the Port Camden flows and Point Camden sill. However, a considerable

amount of the Haeussler et al. (1992) data with paleomagnetic directions significantly

different from those just considered are now left in need of explanation. I will now

address this data by locality and address their tectonic implications.

KEKU ISLETS

The paleomagnetic directional data from the gabbros on the Keku Islets are

significantly different from the ChRM of all other locations. However, the directions are

consistent with a thermal overprinting found elsewhere in the Keku Islets, including that

found in the Triassic Hound Island Volcanics and the Permian Pybus Formation that it

intrudes. Because Haeussler et al. (1992) compared the directions of the overprinting to

the average direction of all gabbro in the region and not the directions specific to the

Keku Islets, they considered it less likely that the overprinting was caused by these

gabbro, and instead favored a Cretaceous overprinting. Comparison of the directional

data from the gabbro on the Keku Islets with a Miocene pole suggests neglible

displacement but considerable clockwise rotation ≈34°. Considering Haeussler et al.’s

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(1992) suggestion that the overprinting might be Cretaceous in age, comparison with a

late Cretaceous pole of 72.3° N, 194.8° W, A95 = 3.7° (Mcelhinney, 1979) shows

directions are consistent within ±1° of the expected direction. Because the youngest rocks

this gabbro intrudes are Triassic, without further data it is at least possible that the gabbro

is Cretaceous in age. We are thus left with two alternatives: (1), the gabbro on Keku

straight is Tertiary in age, and it and the nearby Pybus Formation and Hound Island

volcanic on the Keku Islets have experienced significant ~34° clockwise rotation, or (2)

the gabbro is late Cretaceous in age, and has negligible rotation and displacement.

Resolution of either of these hypotheses requires further geochemical and geochronologic

study.

HARE ISLANDS AND HOUND ISLAND OVERPRINT

Directional data from Hare Islands are consistent with a component of thermal

overprinting of the Hound Island Triassic volcanics found on the north of Hound Island

(Haeussler et al., 1992). Haeussler et al. attribute this overprinting to the aggregate

Tertiary “Point Camden” gabbro principally by noticing that the most local outcrop of the

gabbro, the Hare Islands gabbro, has directions that match the overprint. However,

suggestion that this overprinting is Tertiary in age does not seem valid, as paleomagnetic

declinations on the Hare Islands are almost 100° counterclockwise from those expected

of a Tertiary intrusion. Its seems unlikely that the gabbro on Hare Islands has undergone

≈100° of counterclockwise rotation in the Neogene. However, performing a structural

correction on both the overprint of the Hound Island volcanic and the Hare Island gabbro

based on the local strike and dip of the Hound Island volcanics (~325/12), directional

data exactly matches that of the Keku Islets and of a late Cretaceous pole. Again, it could

26

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still be the case that the Keku Islets gabbro is Tertiary and requires a ~34° clockwise

rotation, but if so, it would suggest (1) a regional overprinting caused by the Keku Islet

gabbro, (2) differential tilting of the Hare and Hound Islands but not the Keku Islets

suggesting they are on different blocks, and (3) rotation of both ~34° clockwise, with

both blocks moving together. A Cretaceous age of overprint would not require this

rotation, nor require probable separate blocks first experiencing differential and then

synchronous deformation.

POINT CAMDEN GABBRO AND CLARK ISLAND

Directions from the Point Camden gabbro are consistent with a component of

thermal overprinting found in the Triassic Hound Island volcanics found on Kadake Bay

Point on Kuiu Island (Haeussler et al., 1992). Haeussler et al. (1992) compared this

overprint to the aggregate “Point Camden” gabbro, and finding discordance, suggested

that the overprinting was similar with that of the overprinting signature found at

Turnabout Island and Cape Bendal on Kupreanof Island, which are geographically the

sites farthest away from those on Point Kadake Bay. Using Ar40/Ar39 dating from

Turnabout Island in the Frederick Sound, they calculate an age of overprint to be 90-100

Ma, or late mid-Cretaceous. Grouping sites from the disparate locations together, they

also note that ‘all’ sites are of normal polarity, which they suggest is consistent with the

normal polarity Superchron in the mid-Cretaceous from 120-85 Ma.

However, there are three reversals found in the Point Kadake Bay overprint and

all directions on Point Kadake have directions significantly different from those of

Turnabout Island and Cape Bendal at greater than 99.9% confidence. Indeed, four sites

from the Point Camden sill and Kadake Bay Point overprint (sites HE 54, 61, 63, 65)

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have reversed polarities, meaning they cannot be from the normal Cretaceous superchron

and not 120-85 Ma.

Keeping with the hypothesis of a Cretaceous overprint, I would like to instead

propose a later date for the overprint—namely, late Cretaceous. Revisiting the hypothesis

that the Point Camden gabbro may be of such an age, I apply the same structural

correction I performed on 09JDE11 based on the average strike and dip of the

Kootznahoo Formation on Kuiu Island to the rest of the Point Camden gabbro and all of

the overprint. Based on my preliminary analysis, such a correction yields directions D ~

10°, I ~ 62°, which is 10° clockwise of an expected Miocene pole but 24°

counterclockwise of a late Cretaceous pole. Furthermore, comparison of the mean strike

and dip of the Hound Island volcanics on Kuiu Island with those on Hound Island show

~45° of counterclockwise rotation. This suggests that a considerable portion of Kuiu

Island may have as a crustal block experienced Neogene tilting and significant

counterclockwise vertical axis rotation. While the large crustal block scenario is

appealing, I suggest radiometric dating of the Point Camden, Hare, Clark, and Keku

Islands gabbro in conjunction with dating of the Hound Island overprint and additional

paleomagnetic sampling, particularly on Kuiu Island, is in order. In particular, the

unresolved ~ 10° inclination discordance present in any scenario presented is

unsatisfying—and hopefully additional data will help resolve the discordance.

DISCUSSION OF REGROUPING OF THE HAEUSLLER ET AL. (1992) DATA

This section details the geochemical, petrographic, and paleomagnetic rationale

for the regrouping of the paleomagnetic data of Haeusller et al. (1992) from the aggregate

“Point Camden” gabbro based on locality.

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REGARDING COOLING RATES

Haeussler et al. (1992) found that for their samples from “Point Camden” gabbro,

typical laboratory unblocking temperatures were often small, between <40-50° C. They

suggest that if the rocks cool through this temperature range in a few thousand years or

less, then a single specimen or locality would not completely average secular variation

(Haeussler et al., 1992). While sills up to 500 m thick like the “Point Camden” gabbro

(Muffler, 1967) are not expected to cool this quickly, it is possible that hydrothermal

convection of meteoric groundwater through propagated crack systems might have

greatly expedited the cooling process (Dodson et al., 1978). If so, it is possible that the

gabbro cooled through the blocking temperatures of 580° to 500° in as few as 500 years,

making it likely that a particular locality or site would record secular variation and an

average of magnetic directions across disparate localities necessary to compute mean

VGP’s (Haeussler et al., 1992).

Cooling is not likely to be as rapid as Haussler et al. suggest for 3 reasons. First,

while petrographic analysis of most localities indicate significant hydrothermal alteration

as evidenced by the presence of chlorite, iddingsite, and serpentine, it is not possible to

determine if this alteration is primary or secondary. Furthermore, one site, 09JDE10,

shows no evidence of alteration in thin section, suggesting that rapid cooling by

circulating groundwater did not occur at that site.

Second, at three sites, 09JDE10, 09JDE14, 09JDE15, distinct (09JDE10 and

09JDE14 show similar geochemical signature and may be identical) dikes were sampled.

At two of these sites, 09JDE10 and 09JDE14, type 5 magnetizations were recorded,

suggesting transitional poles. At site 09JDE15, however, 6 cores were sampled across the

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width of the dike, with each core representing a different intrusion event. While two of

the cores yielded type-5 magnetizations typical of transitional poles, four magnetizations

consistent with an Oligocene-Miocene pole were recorded. Most notably, one of these

cores had a reversed polarity (the other three were normal), suggesting that there were at

least two distinct intrusion events, that they did not cause significant overprinting of

ChRM, and that magmatism persisted over a prolonged period of time representing at

least 105 years. Most importantly, the consistency of the magnetization directions of the

four cores, including both reversed and normal polarities, suggests that the intrusions

cooled slowly enough to average secular variation. The fact that these intrusions were on

average only five cm wide further suggests that directions from other sills and dikes in

the region, which varied from one to hundreds of meters thick, also cooled slowly enough

to average secular variation.

Finally, site 09JDE11 was sampled from the chill margin of the Point Camden

gabbro. Geochemical analysis indicated an incredibly high silica content (SiO2 ≈ 70%)

and elevated trace elements of La, Nb, Rb, and Zr, which suggests localized melting and

incorporation of the nearby clastic formation. Petrographic analysis supports this

interpretation, with extremely small quartz grains surrounding all other minerals,

including large euhedral lath plagioclase crystals that are clearly magmatic in origin. This

“chill margin” is 3.5 meters thick, and suggests elevated temperatures well above the

blocking temperature of 580° for prolonged periods of time, making rapid cooling in a

period of fewer than 500 years unlikely. Finally, I should add these elevated temperatures

make a hydrothermal cooling convection system unlikely, as groundwater is unable to aid

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in cooling until there is a solidified margin in which cracks can open to allow circulation

(Taylor, 1971).

For these reasons, the sills and dikes likely cooled slowly enough to average out

secular variation, and that any significant difference in magnetizations across sites must

be the result of geologic, structural, or paleomagnetic variation.

CONCLUSION

The recent tectonic history of the Keku Strait is decidedly complex. Directional

data found in this study provides evidence of Neogene regional tilting based on the strike

and dip of the Tertiary Kootznahoo Formation, and locally suggest up to 45° of

counterclockwise vertical-axis rotation. A re-evaluation of Hauessler et al. (1992)

supports the conclusion of Neogene tilting, and suggests that deformation in the

Alexander terrane is highly variable and locally significant. Such deformation should be

considered when determining paleomagnetic directions for older rocks in the region,

which have been used to constrain the location of the Alexander terrain in relation to the

Baja BC hypothesis. A final implication of the paleomagnetic results from this study is

that it is unlikely the Kootznahoo Formation had a significant primary dip, making it

unlikely that it was the type of alluvial fan that Loney (1964) suggests.

ACKNOWLEDGEMENTS

I gratefully acknowledge all the people who helped me pull this research

together—Michael Jackson, at the Institute of Rock Magnetism, for his help with

paleomagnetic work, Jeff Thole at Macalester for his assistance with laboratory

processing of majors and traces, Karl Wirth, also at Macalester, for insight into

geochemical analysis, and Tim White, Sue Karl, and Peter Haeussler, for laying down the

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groundwork that made this research possible. Special thanks goes Maria Princen, Alex

Gonzalez, and Cameron Davidson, who made excellent companions drilling in the field

and in review of this manuscript. Finally, I’d like to thank Sarah Crump, for her help with

paleomagnetic analysis, and Nate Evenson, for his invaluable openness to vetting of

ideas, and to the KECK Consortium, for funding of this project.

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