Printing date 04/17/2015

I J Jde11tijicatio11

Safety Data Sheet acc. to OSHA HCS

Page J/10

Reviewed 011 03/17/2015

· Product identifier

· Trade 11a111e: Cherry

· Article 1111mber: 36200

· Details of the s11pplier of the safety tlata sheet· S11pplier:Penco Products, Inc.1820 Stonehenge Dr.Greenville, NC 27858USA

· Phone number: 252-917-5287

· Emergency telephone 1111mber: INFOTRAC 800-535-5053

2 Hazard(s) ide11tijicatio11 ------------·-·---··-------------�

· Classification of the substance or 1nixture

Acute Toxicity - Oral: Catagory 4 Skin lrritation: Catagory 2

Sensitization - Skin: Catagory 1

Flammable Liquids: Catagory 4

· Label ele111e11ts· GHS label elementsThe product is classified and labeled according to the Globally Ha1111011ized System (GHS).

· Hazard pictog1·a111s

0-GHS07

. Signal H'Ord rvarning

· Hazard-deter111b1ing co111po11e11ts oflabeli11g:benzaldelzyde(R)-p-mentha-1, 8-dienemethyl salicylateCoianarin

· Hazard state111e11tsCombustible liquid.Hamiful if swallowed.Causes skin irritation.May cause an allergic skin reaction.

· Precautionary state111entsKeep a1vay fron1 jlan1es and hot stufaces. - No s111oking.Avoid breathing dust!]i1111e/gas/mist/vaporslspray

(Contd. on page 2) '------------------------------------------�us

Safety Data Sheet acc. to OSHA HCS

Page 2/10

Reviewed on 03/17/2015 Printing date 04/17/2015

Trade 11a111e: Cherry

Tf1ear protective gloves I eye protection I face protection. J,Vear protective gloves. Wash thoroughly after handling. Do not eat, drink or s1noke 1vhen using this product. Contan1inated 1vork clothing n1ust not be a/101ved out of the ,vorf...place. Specific treatment (see on this label). If sival/o,ved: Call a poison center/doctor if you feel un1vell. Wash contan1inated clothing before reuse. If skin irritation or rash occurs: Get nzedical advice/attention. Rinse nzouth. In case of fire: Use for extinction: C02, po1vder or 1,vater spray. If on skin: Wash with plenty of water. Take off contan1inated clothing and 1vash it before reuse. Store in a well-ventilated place. Keep cool.

(Contd. of page 1)

Dfapose of contents/container in accordance lvitlz local/regional/national/international regulations. · C/assificatio11 syste111:· NFPA ratings (scale O - 4)

Health = 1 Fire = 2 Reactivity = 0

· HMIS-ratings (scale O - 4)

HEAL TH I] Health = 1FIRE 0 Fire = 2 REACTIVITY@] Reactivity = 0

· Other hazards· Results of PBT and vPvB assess111e11t· PBT: Not applicable.· vPvB: Not applicable.

3 Compositio11/i11formatio11 011 i11gredie11ts

· Cl1e111ical clu1racterizatio11: Mixtures· Description: Ml'fture of the substances listed belolv 1vitlz nonhazardous additions.· Dangerous co111po11e11ts:

100-52-7 benzaldehyde <)> Acute Tox. 4, H302; Flam. Liq. 4, H227

140-Jl-4 benzyl acetate 104-87-0 p-tolualdehyde

<)> Skin lrrit. 2, H315; Flam. Liq. 4, H227101-84-8 diphenyl ether

5989-27-5 (R)-p-mentha-1,8-diene �· Fiaii,: .Liq.I .H226i ¢ski ii i,;.ii·2,H3I5;.Ski11 Sei;,:·i,HH7.

119-36-8 methyl salicylate � FTc,;,;: Liq. I H226,: <'.9Ac11iefox..{ H3()2;Eyeiri·ii.2A: j.j3j9··

(Contd. on page 3) �����������������������������������������-us-

Safety Data Sheet acc. to OSHA HCS

Page 3/10

Reviewed on 03/17/2015 Printing date 04/17/2015

Trade u11ne: Cherry1

(Contd. of page 2)

134-20-3 n1ethyl anthranilate <j) Skin lrrit. 2, H315; Eye lrrit. 2A, H319

77-83-8 Aldehyde C-/6�·Fiaii,· D',j.:.i: fi22if: 0 s1<;ii ii-i·1t. ·2.· iii y5;· Eyei,:i·ii: 2A .. iiiYf stoisEi. iii!3s··

91-64-5 Cozunarin<&, Acute Tax. 3, H301; <j) Skin Sens. 1, H317

4 First-aid measures . -·-·- ... -·"--·-··

· Description of first aid 111eas11res

· General i11for111atio11:

-------.

=

Syn1pton1s of poisoning n1ay even occur after several hours; therefore 1nedical observation for at least 48hours after the accident.

· After i11/zalatio11:Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Inunediately 1vash 1vith 1vater and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several nzinutes under running lvater.· After sJvallo1vi11g: Inunediately call a doctor.· Infor111atio11 for doctor:· Most b11portant sy111pto111s and effects, both acute and delayedNo further relevant infornzation available.

· I11dication of any b11111ediate 11,edical atte11tio11 a11d special treat111e11t ,reededNo fi1rther relevant info1711atio11 available.

[ 5Fire-fighting measures-"·--··-·-·------·--·--·�·�------

---·-

· Extinguishing 111edia· Suitable extinguislting agents:

C02, e.1:tinguishing po1vder or 1vater �pray. Fight largerfires lvith ,vat er spray or alcohol resistant foan1.· Special ltazards arising fro111 tlte substance or 111L"\:ture No fi1rther relevant infor,nation available.· Advice for firefighters· Protective equip111ent: No special n1easures required.

6 Accide11ta/ release measures

· Personal precautions, protective equip111e11t and e111erge11cy procedures Not required.· E11viro111ne11tal precautions:I1ifo1711 respective authorities in case of seepage into 1vater course or sewage systen1.Do not allolv to enter seivers/ su,face or ground lvater.

· Methods and 111aterial for co11tait1111e11t anti clea11i11g up:Absorb 1vith liquid-binding ,naterial (sand, diatomite, acid binders, universal binders, sa1vdust).Dispose conta,ninated ,naterial as lvaste according to iten1 13.Ensure adequate ventilation.

· Reference to otlter sectionsSee Section 7 for iliforn1ation on safe handling.See Section 8 for info1mation on personal protection equipn1ent.

(Contd. on page 4)

us-

Safety Data Sheetacc. to OSHA HCS

Page 4/10

Printing date 04/17/2015 Reviewed on 03/17/2015

I

Trade na111e: CherlJ'

(Contd. ofpnge 3)

See Section 13 for disposal i1ifomiation.

7 Ha11dli11g and storage � · Handling:· Preca11tio11s for safe ltandlingEnsure good ventilation/exlzaustion at the ivorAplace.Prevent fo11nation of aerosols.

· l11for111atio11 about protection against explosio11s and fires: No special n1easures required.

· Co11ditio11s for safe storage, i11c/11di11g any i11co111patibilities· Storage:· Require111e11ts to be 111et by storeroo111s and receptacles: No special requiren1ents. · /11for111atio11 about storage in one co111111011 storage facility: Not required. · Further infor111ation about storage co11tlitio11s: None. · Specific end use(s) No fitrther relevant info11natio11 available.

8 Exposure co11tro/s/perso11alprotectio11 ---· ·-····-�- .=::J

· Additional i11for111ation about desig11 of tec/znical syste111s: No fitrther data; see iten1 7.

· Controlpara111eters

· Co111po11e11ts 11Jith lilnit values that require 11u111itori11g at the ,µorkplace: 100-52-7 be11za/dehydeWEEL Short-ter,11 value: 4 pp111

Long-te1711 value: 2 ppm DSEN

140-11-4 be11zy/ acetateTLV Long-ter,n value: 61 ,ng/1113, JO pp111 101-84-8 diphe11yl etherPEL Long-ter,n value: 7 1ng/n13, 1 pp111 REL Long-te1111 value: 7 n1gln13, J ppn1 TLV Short-term value: 14 mglm', 2 ppm

Long-te1711 value: 7 1ng/n13, 1 ppn1 · Additio11a/ i11for111atio11: The lists that lVere valid during the creation 1vere used as basis.

· E�"'l:posure controls· Personal protective equip111e11t:· General protective and hygienic nieasures:Keep away Ji-om foodstuffs, beverages and feed.In1111ediately ren1ove all soiled and conta,ninated clothing.Wash hands before breaks and at the end of work.

· Breathing eq11ip111e11t:In case of brief exposure or lo1v pollution use respirato,y filter device. In case of intensive or longerexposure use respirato,y protective device that is independent of circulating air.

(Conld. on page 5)

us-

Printing date 04/17/2015

Trade 11a111e: Cher1y

· Protection of ha11ds:

8 Protective gloves

Safety Data Sheet acc. to OSHA HCS

Page 5/10

Reviewed on 03/17/2015

(Contd. ofpagc4)

The glove nzaterial has to be in1pern1eable and resistant to the product/ the substance/ the preparation. Due to n1issing tests no recon1n1endation to the glove n1aterial can be given for the product/ the preparation/ the che,nical n1l1:ture. Selection of the glove n1aterial on consideration of the penetration tin1es, rates of diffusion and the degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also onfi1rther n1arks ofquality and varies j,·0111 n1anufacturer to n1anufacturer. As the product is a preparation of severalsubstances, the resistance of the glove n1aterial can not be calculated in advance and has therefore to bechecked prior to the application.

· Penetration tbne of glove 111aterialThe e.,;:act break through tin1e has to be found out by the manufacturer of the protective gloves and has tobe obse11,ed.

· Eye protection: Goggles recon1n1ended during refilling.

@llysical and clle,;�ical properties

· l11for1natio11 011 basic physical anti clte111ical properties· General lnfor111atio11· Appearance:

For111:Color:

· Odor:· Odour titres/told:

· pH-value:

· Change i11 conditionMelting poi11t/A1elting range:Boiling poin'I/Boili11g range:

· Flash point:

· Fla111111ahility (solid, gaseous):

· lg11itio11 te111perature:

· Deco111positio11 te111perat11re:

· Auto igniting:

· Danger of explosion:

· Explosion lin,its:Lo1-ver:Upper:

· Vapor pressure:

· Density:

Liquid Colorless Characteristic Not deter111ined.

Not detennined.

Undete11ni11ed. 179 °C (354 °P)

67 °C (153 °P)

Not applicable.

190 °C (374 °P}

Not dete11nined.

Product is not selfigniting.

Not dete11nined.

1.4 Vol% 60.0 Vol%

Not dete11nined.

Not deter,nined.

(Contd. on page 6) '-�����������������������������������������us-

Safety Data Sheet acc. to OSHA HCS

Page 6/10

Printing date 04/17/2015 Reviewed on 03/17/2015

Trade 11a111e: Cherry

(Contd. ofpoge 5)

· Relative density Not dete1111ined. · J?apour density Not dete11nined. · Evaporation rate Not dete11nined.

· Solubility i11 / Miscibility withWater: Not n1iscible or difficult to 1nlt:.

· Partition coefficie11t (11-octa110V1-vater): Not detern1ined.

· Viscosiry:Dy11a111ic: Not detern1ined. J(iue111atic: Not dete1711fned.

· Solvent co11te11t:Organic solve11ts: 3.8% voe co11te11t: 3.8 i�

37.5 g/l I 0.31 /big/

Solids co11te11t: JO.I% · Other i11fo1·111atio11 No further relevant info1111atio11 available.

110 Stability and reactivity •

J.

-·--· ..

· Reactivity· Che111ical stability· Tlter111al deco111positio11 I co11ditio11s to be avoided:No decon1position if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions la1orvn.· Conditio11s to avoid No fi,rther relevant infor,nation available.· lnco111patible 111aterials: No fi1rther relevant inforn1ation available.· Hazar,lous deco111positio11 pro,lucts: No dangerous deconzposition products h1101v11.

[ 11 Toxicological iliformatio11 ·-·--·--

=:_:] -·· .

· J11for111atio11 011 toxicological effects· Acute toxicity:· LDILC50 values that are releva11t for c/assificatio11:I 00-52-7 be11zaltlehydeOral]LD50l I 300 mg/kg (rat)5989-27-5 (R)-p-111e11tha-J,8-tlie11eOra!ILD50 I 4400 mg/kg (rat)

· Primary irritant effect:· 011 t!te ski11: No irritant effect.· 011 the eye: No hritating effect.· Se11sitizatio11: Sensitization possible through skin contact.· Additio11al to.-..:icological i11for111atio11:The product shorvs the follorving dangers according to internally approved calculation 1nethods forpreparations:Harm/it!I11·itant

(Contd. on page 7)

,_ us

Printing date 04/17/2015

Trade 11a111e: Cherry

· Carci11oge11ic categories

Safety Data Sheet acc. to OSHA HCS

· IARC (l11ternati1111al Agency for Research 011 Cancer)

140-11-4 benzyl acetate

5989-27-5 (R)-p-mentha-1, 8-diene

91-64-5 Coun1ari11

· NTP (Natio11al Toxicology Program)

None of the ingredients is listed.

· OSHA-Ca (Occ11patio11al Safety & Health Atl111i11istratio11)

None of the ingredients is listed.

I 12 Ecological i11formatio11-----

· Toxicity· Aquatic toxicity: No fitrther relevant info1711ation available.· Persistence and degradability No fitrther relevant infonnation available.· Behavior in e11viro11111e11tal syste111s:· Bioacc1111111/ative potential No further relevant inforn1ation available.· Mobiliry in soil No further relevant info1?11ation available.· Ecotoxical effects:· Remark: Toxic for fish· Additional ecological i11for111ation:· General notes:

Water hazard class 2 (Self-assessment): hazardous for waterDo not allo1v product to reach ground 1vater, 1vater course or seivage �ystenz.Danger to drinking 1vater if even sniall quantities leak into the ground.Also poisonous for fish and plankton in 1,vater bodies.Toxic for aquatic organis,ns

· Results of PBT a11d vPl,B assess111e11t· PBT: Not applicable.· vA•B: Not applicable.· Other adverse effects No fitrther relevant info11nation available.

� 3 Disposal co11sidera_t�o11s """""-

· JVaste treat111e11t 111etlzo1ls· Reco111111e11datio11:

Page 7/10

Reviewed 011 03/17/2015

(Contd. of page 6)

3

3

3

..

.

__ _J

Must not be disposed of together 1vith household garbage. Do not allo1v product to reach seivage systen1.

· U11clea11ed packagings:· Reco111111e11datio11: Disposal 1nust be niade according to official regulations.

I 14 Transport i11for111atio11

I· UN-N11111ber· DOT, IMDG, L4TA

- - ··- . J

I (Contd. on page 8)

us-

*

Page 8/10 Safety Data Sheet

acc. to OSHA HCS

Printing date 04/17/2015

Trade 11a111e: Cherry

· UN proper shipping 11a111e·DOT·IMDG,IATA

· Transport hazard class(es)

·DOT· Class

. - ..... ··------------------

·IMDG,L4TA

{,(lh;,,'\ /;

\?-/·'

· Class· Label

· Packi11g group· DOT, IMDG, L4TA

· E11vi,-011111eutal hazards:

· k/ari11e po/luta11t:

- ". "' -

· Special precautions for user· Danger code (Ke111/er):· EMS Number:

...... ........

Reviewed on 03/17/2015

(Contd. of page 7)

........ ......... . ·---------------····-·

Product contains environn1entally hazardous substances: diphenyl ether, (R)-p-mentha-1,8-diene No Warning: .A1iscellaneous dangerous substances and articles 90 F-A,S-A

· Transport i11 bulk accordi11g to Annex II ofMARPOL 73178 am/ the !BC Cotle Not applicable.

· Tra11sport/Additio11a/ i11for111atio11:

·DOT· Q11a11tit;1 /i111itatio11s On passenger aircraft/rail: I 00 L

On cargo aircraft only: 220 L

·IMDG· Limited qua11tities (LQ) 5L · Excepted qua11tities (EQ) Code: El

.lvfa.Yinnan net quantity per inner packaging: 30 nzl kfaxi111Zt111 net quantity per outer packaging: I 000 n1/

· UN "Model Reg11/atio11 ": UN3082, Environn1entally hazardous substances, liquid, 11.0.S., 9, III

-·--·

[ 15 R�gulatory i11formatio11 . .

· Safety, lzealt/z a111/ e,n,iro11111e11tal regulations/legislatio11 specific for t/ze substance or 111ixture·Sara· Sectio11 355 (extremely lwzardous substa11ces):None of the ingredients is listed

(Contd. on page 9)

us-

Printing date 04/17/2015

Trade 11a111e: Cher,y

Safety Data Sheet acc. to OSHA HCS

· Sectio11313 (Specific toxic che111ica/ /isti11gs):None of the ingredients is listed.

· TSCA (Toxic S11bsta11ces Co11trol Act):All ingredients are listed.

· Pmpositio11 65· Clze111ica/s k110,v11 to cause cancer:None of the ingredients is listed.

· Che111ica/s k110,v11 to cause reprotluctive toJ:icity for fe111ales:None of the ingredients is listed.

· Che111icals k1101v11 to cause reproductive toxicity for 111ales:None of the ingredients is listed

· Che111ica/s k1101v11 to cause develop111e11tal toxicity:None of the ingredients is listed

· Carci11oge11ic categories· EPA (E11l'iro11111elllal Protectio11 Age11cy)None of the ingredients is listed.

· TLV (Threshold Li111it Value established by ACGIH)140-11-41 benzyl acetate

· NIOSH-Ca (Natio11al J11stit11tefor Occ11patio11al Safety a11tl Health)None of the ingredients is listed.

· GHS label ele111e11ts

Page 9/10

Reviewed on 03/17/2015

(Contd. of page 8)

I IA4

T/ze product is classified and labeled according to the Globally Harmonized System (GHS).· Hazard pictogra111s

0 GHS07

· Sig11al 1vor1/ JVarning

· Hazard-deter111ining co111po11ents of labeli11g:benzaldehyde(R)-p-mentha-1. 8-dienemethyl salicylateCotanarin

· Hazard state1ne11tsCombustible liquid.Harmful if swallowed.Causes sldn irritation.May cause an allergic skin reaction.

· Precalltionary state111e11tsKeep away fro111 flan1es and hot szufaces. - No snioking.Avoid breathing dust/fi1me/gas/mistlvapors/sprayWear protective gloves I eye protection I face protection.Wear protective gloves.Wash thoroug/z/y after handling.

(Contd. on page 10) '-�����������������������������������������us

Page 10/10

Safety Data Sheet acc. to OSHA HCS

Reviewed on 03/17/2015 Printing date 04/17/2015

Trade 11a111e: Cherry

(Contd. of page 9)

Do not eat, drink or sn1oke when using this product. Contan1inated 1vork clothing nn1st not be al/01ved out of the 1vorkplace. Specific treatment (see on this label). If swallowed: Call a poison center/doctor if you feel unwell. Wash contan1inated clothing before reuse. If skin irritation or rash occurs: Get n1edical advice/attention. Rinse niouth. In case of fire: Use for e.x.tinction: C02, po1vder or 1vater spray. If on skin: Wash with plenty of water. Take off conta,ninated clothing and 1vash it before reuse. Store in a 1vell-ventilated place. Keep cool. Dispose of contents/container in accordance 1vith local/regional/national/international regulations.

· Cl,e111ica/ safety assess111e11t: A Clzeniical Safety Assessn1ent has not been carried out.

�-q Other i11form_a.h __ ·o_11 ___ _c_ __ _ I This inforn1ation is based on our present /a101vledge. Ho1veve1� this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrasesH226 Flammable liquid and vapor.H227 Combustible liquid.H301 Toxic if swallowed.H302 Hannfit! if swallowed.H3 l 5 Causes skin irritation.H3 l 7 May cause an allergic skin reaction.H3 l 9 Causes serious eye irritation.H335 May cause respirato1y i,1·itation.

· Date of preparatio11 /last revisio11 04/17/2015 I -· Abbreviations and acro11y111s:ADR: Accord europeen sur le transport des marcha11dises dangere11ses par Route (European Agreement concerning the!11ten1ational Carriage of Dangerous Goods by Road)llv!DG: International Afaritime Code for Dangerous GoodsDOT: US Department of Transportationr

IATA: International Ai Transport AssociationACGIH: American Conference ofGoven1mental Industrial lfygienistsE!NECS: European Inventory of £.:isling Commercial Chemical SubstancesELJNCS: European List of Notified Chemical SubstancesCAS: Chemical Abstracl,; Service (division of the American Chemical Society)NFPA: National Fire Protection Association (USA)11/l{IS: Hazardous Materials Identification System (USA)VOC: Volatile Organic Compounds (USA. EU)LC50: Lethal concentration. 50 percentLD50: Lethal dose, 50 percentFlam. Liq. 3: Flammable liquids, Hazard Catego1y 3Flam. Liq. 4: Flammable liquids, Hazard Category 4Acute Tox. 3: Acute toxicity, Hazard Category 3Acute Tox. 4: Acute toxicity, Jlazard Category 4Skin Irrit. 2: S/..'111 corrosion/irritation, Hazard Category 2Eye frrit. 2A: Serious eye damage/eye irritation, Hazard Catego,y 2ASkin Sens. 1: Sensitisation - Skill, Hazard Category 1STOT SE 3: Specific target organ toxicity - Single exposure, Ha:ard Category 3

· *

Data co111pared to tl,e previous versio11 altered.