Page 1/7 Material Safety Data Sheet - b2bcomposites.com · Page 1/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 10/31/2007 Reviewed on 10/31/2007 DR ... NBR ·

Page 1/7

Material Safety Data Sheetacc. to ISO/DIS 11014

Printing date 10/31/2007 Reviewed on 10/31/2007

DR

* 1 Identification of substance

· Product details

· Trade name: SP 8682 Resin RAL7035· Application of the substance / the preparation Epoxy coating

· Manufacturer/Supplier:GURIT (UK) Ltd. GURIT (Canada)Inc.St. CROSS BUSINESS PARK 555 boulevard PoirierNEWPORT I.O.W. Magog QCPO30 5WU J1X 7L1UNITED KINGDOM CanadaTEL:+44(0)1983 828000 T: +1 819 847 2182FAX:+44(0)1983 828100 F: +1 819 847 2572Transport Emergency +44(0)2392 241208

· Information department: Product safety department.· Emergency information: Contact as above

* 2 Composition/Data on components

· Chemical characterization· Description: Mixture of the substances listed below with nonhazardous additions.· Dangerous components:30499-70-8 1,2,3trimethylolpropanetriglycidylether 50-100%64742-95-6 Solvent naphtha (petroleum), light arom. < 0.5%

* 3 Hazards identification

· Hazard description:

Xi Irritant

· Information pertaining to particular dangers for ma n and environment:The product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version.Irritating to eyes and skin.May cause sensitization by skin contact.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentContains epoxy constituents. See information supplied by the manufacturer.

· Classification system:The classification was made according to the latest editions of international substances lists, and expandedupon from company and literature data.

· NFPA ratings (scale 0 - 4)

11

0Health = 1Fire = 1Reactivity = 0

(Contd. on page 2) USA

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Trade name: SP 8682 Resin RAL7035

(Contd. of page 1)

DR

· HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

1

1

0

Health = 1Fire = 1Reactivity = 0

* 4 First aid measures

· General information: Immediately remove any clothing soiled by the product.· After inhalation:Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact:Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

· After swallowing:Do not induce vomiting; immediately call for medical help.A person vomiting while lying on their back should be turned onto their side.Administer medicinal carbonRinse out mouth and then drink plenty of water.

* 5 Fire fighting measures

· Suitable extinguishing agents:Water hazeFoamFire-extinguishing powderCarbon dioxide

· For safety reasons unsuitable extinguishing agents: Water with full jet· Special hazards caused by the material, its product s of combustion or resulting gases:Formation of toxic gases is possible during heating or in case of fire.

· Protective equipment:Mount respiratory protective device.Wear fully protective suit.

· Additional informationCollect contaminated fire fighting water separately. It must not enter the sewage system.

* 6 Accidental release measures

· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.

7 Handling and storage

· Handling:· Information for safe handling: Ensure good ventilation/exhaustion at the workplace.· Information about protection against explosions and fires: No special measures required.


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(Contd. of page 2)

DR

· Storage:· Requirements to be met by storerooms and receptacle s: No special requirements.· Information about storage in one common storage fac ility: Not required.· Further information about storage conditions: Keep receptacle tightly sealed.

* 8 Exposure controls and personal protection

· Additional information about design of technical sy stems: No further data; see item 7.

· Components with limit values that require monitorin g at the workplace:The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.

· Additional information: The lists that were valid during the creation were used as basis.

· Personal protective equipment:· General protective and hygienic measures:Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothing.Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.

· Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation.· Protection of hands:

Protective gloves

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior tothe application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.

· For the permanent contact of a maximum of 15 minute s gloves made of the following materials aresuitable:Nitrile rubber, NBR

· As protection from splashes gloves made of the foll owing materials are suitable: Nitrile rubber, NBR· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

9 Physical and chemical properties

· General Information

Form: FluidColor: Light greyOdor: Mild


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(Contd. of page 3)

DR

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 336°C (637°F)

· Flash point: 101°C (214°F)

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Vapor pressure at 20°C (68°F): 0.1 hPa (0 mm Hg)

· Density at 20°C (68°F): 1.400 g/cm3

· Solubility in / Miscibility withWater: Not miscible or difficult to mix.

· Solvent content:Organic solvents: 0.6 %Water: 0.0 %

* 10 Stability and reactivity

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Dangerous reactions No dangerous reactions known.· Dangerous products of decomposition: Danger of toxic pyrolysis products.

11 Toxicological information

· Acute toxicity:· Primary irritant effect:· on the skin: Irritant to skin and mucous membranes.· on the eye: Irritating effect.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:The product shows the following dangers according to internally approved calculation methods forpreparations:Irritant

* 12 Ecological information

· General notes:Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow product to reach ground water, water course or sewage system.

* 13 Disposal considerations

· Product:· Recommendation:Must not be disposed of together with household garbage. Do not allow product to reach sewage system.


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(Contd. of page 4)

DR

· Uncleaned packagings:· Recommendation:Packagings that cannot be cleansed are to be disposed of in the same manner as the product.

* 14 Transport information

· DOT regulations:· Hazard class: -

· Land transport ADR/RID (cross-border):· ADR/RID class: -

· Maritime transport IMDG:· IMDG Class: - · Marine pollutant: No

· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: -

· Transport/Additional information: Not classified as hazardous for transport.

* 15 Regulations

· Sara· Section 355 (extremely hazardous substances):None of the ingredient is listed.

· Section 313 (Specific toxic chemical listings):None of the ingredients is listed.

· TSCA (Toxic Substances Control Act):13463-67-7 titanium dioxide14807-96-6 Talc (Mg3H2(SiO3)4)7631-86-9 silicon dioxide, chemically prepared

64742-95-6 Solvent naphtha (petroleum), light arom.471-34-1 calcium carbonate108-65-6 2-methoxy-1-methylethyl acetate

1345-25-1 iron oxide· Proposition 65· Chemicals known to cause cancer:None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for females:None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for males:None of the ingredients is listed.

· Chemicals known to cause developmental toxicity:None of the ingredients is listed.

· Cancerogenity categories· EPA (Environmental Protection Agency)None of the ingredients is listed.


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(Contd. of page 5)

DR

· IARC (International Agency for Research on Cancer)13463-67-7 titanium dioxide 3 14807-96-6 Talc (Mg3H2(SiO3)4) 3

· NTP (National Toxicology Program)None of the ingredients is listed.

· TLV (Threshold Limit Value established by ACGIH)13463-67-7 titanium dioxide A414807-96-6 Talc (Mg3H2(SiO3)4) A4

· MAK (German Maximum Workplace Concentration)None of the ingredients is listed.

· NIOSH-Ca (National Institute for Occupational Safet y and Health)13463-67-7 titanium dioxide

· OSHA-Ca (Occupational Safety & Health Administratio n)None of the ingredients is listed.

· Product related hazard informations:The product has been classified and marked in accordance with directives on hazardous materials.

· Hazard symbols:Xi Irritant

· Hazard-determining components of labelling:Trimethylolpropanetriglycidylether

· Risk phrases:Irritating to eyes and skin.May cause sensitization by skin contact.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

· Safety phrases:Do not breathe gas/fumes/vapour/spray.Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of soap and waterWear suitable gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/Safety data sheets

· Special labeling of certain preparations:Contains epoxy constituents. See information supplied by the manufacturer.

· National regulations:

· Technical instructions (air):Class Share in %

II 0.4III 0.2

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.

· Department issuing MSDS: Environment protection department.(Contd. on page 7)

USA

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(Contd. of page 6)

DR

· Contact:SIMON RHODESHARALD BEHMER

· * Data compared to the previous version altered. USA

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DR


· Product details

· Trade name: SP 7856 HARDENER· Application of the substance / the preparation Epoxy curing agent




· Chemical characterization:· CAS No. Description68889-71-4 3(4), 8(9)-BIS(AMINOETHYL)-TRYCYCL0(5,2,1,02,6)-DECANE

· Identification number(s) -

· Chemical characterization· Description: Mixture of the substances listed below with nonhazardous additions.



C Corrosive

· Information pertaining to particular dangers for ma n and environment:Harmful in contact with skin and if swallowed.Causes burns.May cause sensitization by skin contact.

· Classification system:· NFPA ratings (scale 0 - 4)

31

0Health = 3Fire = 1Reactivity = 0


HEALTH

FIRE

REACTIVITY

3

1

0


USA

(Contd. on page 2)

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Trade name: SP 7856 HARDENER

(Contd. of page 1)

DR


· General information:Immediately remove any clothing soiled by the product.Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48hours after the accident.

· After inhalation:Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· After swallowing:Do not induce vomiting; immediately call for medical help.Induce vomiting and call for medical help.Administer medicinal carbonRinse out mouth and then drink plenty of water.






* 6 Accidental release measures

· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.


· Handling:· Information for safe handling: Store in cool, dry place in tightly closed receptacles.· Information about protection against explosions and fires: No special measures required.

· Storage:· Requirements to be met by storerooms and receptacle s: No special requirements.· Information about storage in one common storage fac ility: Not required.· Further information about storage conditions: Keep receptacle tightly sealed.

USA

(Contd. on page 3)

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(Contd. of page 2)

DR

8 Exposure controls and personal protection

· Additional information about design of technical sy stems: No further data; see item 7.

· Components with limit values that require monitorin g at the workplace: Not required.· Additional information: The lists that were valid during the creation were used as basis.



Protective gloves







* 9 Physical and chemical properties


Form: FluidColor: OpaqueOdor: Amine-like

· Change in conditionMelting point/Melting range: -40°C (-40°F)Boiling point/Boiling range: 315°C (599°F)


· Danger of explosion: Product does not present an explosion hazard.

· Vapor pressure at 20°C (68°F): <0.01 mbar

· Density at 20°C (68°F): 1.04 g/cm3


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(Contd. of page 3)

DR

· Solubility in / Miscibility withWater: Not miscible or difficult to mix.

· pH-value at 20°C (68°F): 12.0· Water: 0.0 %

· Solids content: 1.0 %

* 10 Stability and reactivity

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Dangerous reactions No dangerous reactions known.· Dangerous products of decomposition: Danger of toxic pyrolysis products.


· Acute toxicity:· LD/LC50 values that are relevant for classification :68889-71-4 3(4), 8(9)-BIS(AMINOETHYL)-TRYCYCL0(5,2,1 ,02,6)-DECANEOral LD50 502 mg/kg (rat)Dermal LD50 500 mg/kg (rat)

· Primary irritant effect:· on the skin: Caustic effect on skin and mucous membranes.· on the eye: Strong caustic effect.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation ofesophagus and stomach.

* 12 Ecological information

· General notes:Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow product to reach ground water, water course or sewage system.

13 Disposal considerations



USA

(Contd. on page 5)

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(Contd. of page 4)

DR

14 Transport information

· DOT regulations:

· Hazard class: 8 · Identification number: UN2735· Packing group: II· Proper shipping name (technical name): POLYAMINES, LIQUID, CORROSIVE, N.O.S. (3(4), 8(9)-

BIS(AMINOETHYL)-TRYCYCL0(5,2,1,02,6)-DECANE)· Label 8

· Land transport ADR/RID (cross-border):

· ADR/RID class: 8 Corrosive substances· Danger code (Kemler): 80· UN-Number: 2735· Packaging group: II· Description of goods: 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. (3(4), 8(9)-

BIS(AMINOETHYL)-TRYCYCL0(5,2,1,02,6)-DECANE)

· Maritime transport IMDG:

· IMDG Class: 8 · UN Number: 2735· Label 8 · Packaging group: II· EMS Number: F-A,S-B· Marine pollutant: No· Propper shipping name: POLYAMINES, LIQUID, CORROSIVE, N.O.S. (3(4), 8(9)-


· Air transport ICAO-TI and IATA-DGR:

· ICAO/IATA Class: 8 · UN/ID Number: 2735· Label 8 · Packaging group: II· Propper shipping name: POLYAMINES, LIQUID, CORROSIVE, N.O.S. (3(4), 8(9)-


USA

(Contd. on page 6)

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(Contd. of page 5)

DR

* 15 Regulations

· Sara· Section 355 (extremely hazardous substances):Substance is not listed.

· Section 313 (Specific toxic chemical listings):Substance is not listed.

· TSCA (Toxic Substances Control Act):Substance is listed.

· Proposition 65· Chemicals known to cause cancer:Substance is not listed.

· Chemicals known to cause reproductive toxicity for females:Substance is not listed.

· Chemicals known to cause reproductive toxicity for males:Substance is not listed.

· Chemicals known to cause developmental toxicity:Substance is not listed.

· Cancerogenity categories· EPA (Environmental Protection Agency)Substance is not listed.

· IARC (International Agency for Research on Cancer)7631-86-9 silicon dioxide, chemically prepared 3

· NTP (National Toxicology Program)Substance is not listed.

· TLV (Threshold Limit Value established by ACGIH)Substance is not listed.

· MAK (German Maximum Workplace Concentration)Substance is not listed.

· NIOSH-Ca (National Institute for Occupational Safet y and Health)Substance is not listed.

· OSHA-Ca (Occupational Safety & Health Administratio n)Substance is not listed.


· Hazard symbols:C Corrosive

· Risk phrases:Harmful in contact with skin and if swallowed.Causes burns.May cause sensitization by skin contact.

· Safety phrases:When using do not eat or drink.Do not breathe gas/fumes/vapour/spray.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.


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(Contd. of page 6)

DR

In case of accident or if you feel unwell, seek medical advice immediately.This material and its container must be disposed of as hazardous waste.




· Department issuing MSDS: Environment protection department.· Contact:SIMON RHODESHARALD BEHMER


Page 1/7



DR


· Product details

· Trade name: SP 7857 ACCELERATOR· Application of the substance / the preparation Epoxy curing agent




· Chemical characterization· Description: Mixture of the substances listed below with nonhazardous additions.· Dangerous components:10124-37-5 calcium nitrate, containing in the anhydrous state more than 16 per cent by weight of

nitrogen50-100%

64-17-5 ethanol 25-50%



Xi IrritantF Highly flammableO Oxidizing

· Information pertaining to particular dangers for ma n and environment:The product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version.Contact with combustible material may cause fire.Highly flammable.Irritating to eyes.

· Classification system:The classification was made according to the latest editions of international substances lists, and expandedupon from company and literature data.

· NFPA ratings (scale 0 - 4)

13

0OX


The substance possesses oxidizing properties.(Contd. on page 2)

USA

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Trade name: SP 7857 ACCELERATOR

(Contd. of page 1)

DR


HEALTH

FIRE

REACTIVITY

1

3

0



· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact:Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

· After swallowing:A person vomiting while lying on their back should be turned onto their side.Do not induce vomiting; immediately call for medical help.Rinse out mouth and then drink plenty of water.Administer medicinal carbon






6 Accidental release measures

· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection: Prevent seepage into sewage system, workpits and cellars.· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Ensure adequate ventilation.


· Handling:· Information for safe handling:Store in cool, dry place in tightly closed receptacles.Keep away from heat and direct sunlight.Ensure good ventilation/exhaustion at the workplace.Open and handle receptacle with care.


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(Contd. of page 2)

DR

· Information about protection against explosions and fires:Keep ignition sources away - Do not smoke.Protect against electrostatic charges.

· Storage:· Requirements to be met by storerooms and receptacle s: Store in a cool location.· Information about storage in one common storage fac ility: Not required.· Further information about storage conditions:Keep receptacle tightly sealed.Store in cool, dry conditions in well sealed receptacles.

* 8 Exposure controls and personal protection

· Additional information about design of technical sy stems: No further data; see item 7.· Components with limit values that require monitorin g at the workplace:64-17-5 ethanol (25-50%)ACGIH TLV

NIOSH RELOSHA PEL

1000 ppmA41900 mg/m³, 1000 ppm1900 mg/m³, 1000 ppm

· Additional information: The lists that were valid during the creation were used as basis.



Protective gloves







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(Contd. of page 3)

DR


9 Physical and chemical properties


Form: FluidColor: Light yellowOdor: Alcohol-like

· Change in conditionMelting point/Melting range: Undetermined.


· Ignition temperature: 425.0°C (797°F)

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapormixtures are possible.

· Explosion limits:Lower: 3.5 Vol %Upper: 15.0 Vol %

· Vapor pressure at 20°C (68°F): 59.0 mbar

· Density at 20°C (68°F): 1.185 g/cm3

· Solubility in / Miscibility withWater: Fully miscible.

· Solvent content:Organic solvents: 42.0 %Water: 0.0 %

10 Stability and reactivity

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Dangerous reactions Reacts with acids, alkalis and oxidizing agents.· Dangerous products of decomposition:Nitrogen oxides (NOx)Carbon monoxide and carbon dioxideDanger of toxic pyrolysis products.


· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: Irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:The product shows the following dangers according to internally approved calculation methods forpreparations:


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(Contd. of page 4)

DR

Irritant

12 Ecological information

· General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water

* 13 Disposal considerations



· Recommended cleansing agent: Water, if necessary with cleansing agents.

* 14 Transport information

· DOT regulations:

· Hazard class: 3 · Identification number: UN1993· Packing group: II· Proper shipping name (technical name): FLAMMABLE LIQUID, N.O.S. (ETHANOL)· Label 3

· Land transport ADR/RID (cross-border):

· ADR/RID class: 3 Flammable liquids· Danger code (Kemler): 33· UN-Number: 1993· Packaging group: II· Description of goods: 1993 FLAMMABLE LIQUID, N.O.S. (ETHANOL (ETHYL

ALCOHOL))

· Maritime transport IMDG:

· IMDG Class: 3 · UN Number: 1993· Label 3 · Packaging group: II


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(Contd. of page 5)

DR

· EMS Number: F-E,S-E· Marine pollutant: No· Propper shipping name: FLAMMABLE LIQUID, N.O.S. (ETHANOL (ETHYL ALCOHOL))

· Air transport ICAO-TI and IATA-DGR:

· ICAO/IATA Class: 3 · UN/ID Number: 1993· Label 3 · Packaging group: II· Propper shipping name: FLAMMABLE LIQUID, N.O.S. (ETHANOL)

* 15 Regulations

· Sara· Section 355 (extremely hazardous substances):None of the ingredient is listed.

· Section 313 (Specific toxic chemical listings):None of the ingredients is listed.

· TSCA (Toxic Substances Control Act):All ingredients are listed.

· Proposition 65· Chemicals known to cause cancer:None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for females:None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for males:None of the ingredients is listed.

· Chemicals known to cause developmental toxicity:64-17-5 ethanol

· Cancerogenity categories· EPA (Environmental Protection Agency)None of the ingredients is listed.

· IARC (International Agency for Research on Cancer)None of the ingredients is listed.

· NTP (National Toxicology Program)None of the ingredients is listed.

· TLV (Threshold Limit Value established by ACGIH)64-17-5 ethanol A4

· MAK (German Maximum Workplace Concentration)64-17-5 ethanol 5

· NIOSH-Ca (National Institute for Occupational Safet y and Health)None of the ingredients is listed.


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(Contd. of page 6)

DR

· OSHA-Ca (Occupational Safety & Health Administratio n)None of the ingredients is listed.


· Hazard symbols:Xi IrritantF Highly flammableO Oxidizing

· Risk phrases:Contact with combustible material may cause fire.Highly flammable.Irritating to eyes.

· Safety phrases:Keep container tightly closed and in a well-ventilated place.Keep away from sources of ignition - No smoking.Keep away from combustible material.Do not breathe gas/fumes/vapour/spray.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste.


· Technical instructions (air):Class Share in %

III 42.0



· Department issuing MSDS: Environment protection department.· Contact:SIMON RHODESHARALD BEHMER


Documents

Page 1/7 Material Safety Data Sheet - b2bcomposites.com · Page 1/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 10/31/2007 Reviewed on 10/31/2007 DR ... NBR ·