Page 1 of 48 SAFETY DATA SHEET - Brownells...Suitable extinguishing media Alcohol foam, carbon dioxide (CO2), dry chemical, foam, or water fog. Unsuitable extinguishing media Do not

SAFETY DATA SHEET

1. Identification

Product identifier ACRAGLAS (R) HARDENER, 7/8 OZ. (2-GUN ACRAGLAS KIT)

Other means of identification

Product code 081-003-002 (HARDENER)

Recommended use Adhesive (epoxy hardener component).

Recommended restrictions Not available.

Manufacturer/Importer/Supplier/Distributor information

Manufacturer

BROWNELLS, INC.

Address 200 South Front Street

Company name

Website

Telephone (641) 623-5401

Emergency phonenumber

INFOTRAC Registrant #79335

24 hour Emergency Number, Domestic: (800) 457-4280

24 hour Emergency Number, Foreign: +1(352) 323-3500

E-mail

United States

www.brownells.com

Not available.

Montezuma, Iowa 50171

2. Hazard(s) identification

Not available.Physical hazards

Category 3Acute toxicity, oralHealth hazards

Category 3Acute toxicity, dermal

Category 2Acute toxicity, inhalation

Category 1Skin corrosion/irritation

Category 1Serious eye damage/eye irritation

Category 1Sensitization, skin

Category 2Germ cell mutagenicity

Category 1Specific target organ toxicity, repeatedexposure

Category 3Hazardous to the aquatic environment, acutehazard

Environmental hazards

Category 3Hazardous to the aquatic environment,long-term hazard

Not available.OSHA defined hazards

Label elements

Signal word Not available.

Hazard statement Causes severe skin burns and eye damage. Causes damage to organs through prolonged orrepeated exposure.

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Material name: ACRAGLAS (R) HARDENER, 7/8 OZ. (2-GUN ACRAGLAS KIT)

1353 Version #: 02 Revision date: 02-10-2015 Issue date: 01-27-2015

SDS US

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Precautionary statement

Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly afterhandling. Do not eat, drink or smoke when using this product. Use only outdoors or in awell-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoidrelease to the environment. Wear protective gloves/protective clothing/eye protection/faceprotection. Observe good industrial hygiene practices.

Response IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Take off immediately allcontaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keepat rest in a position comfortable for breathing. If in eyes: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed orconcerned: Get medical advice/attention. Immediately call a poison center/doctor. If skin irritationor rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Ifswallowed, do NOT induce vomiting. Give victim water or milk. Never give anything by mouth to avictim who is unconscious or is having convulsions. Call a physician or poison control centerimmediately.

Storage Store away from incompatible materials. Store indoors in a cool, dry place at an ambienttemperature. Keep containers closed when not in use. Keep out of reach of children.

Disposal Dispose of in accordance with current, applicable local, state, and federal regulations.

Hazard(s) not otherwise classified (HNOC)

Not available.

Hazard(s) not otherwiseclassified (HNOC)

Not available.

Supplemental information 80% of the mixture consists of component(s) of unknown acute hazards to the aquaticenvironment.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

ProprietaryFORMALDEHYDE POLYMER WITHPHENOL

50 - < 80

108-95-2PHENOL 10 - < 20

Other components below reportable levels 5 - < 10

112-24-3TRIETHYLENE TETRAMINE 10 - < 20

#: This substance has workplace exposure limit(s).vPvB: very persistent and very bioaccumulative substance.PBT: persistent, bioaccumulative and toxic substance.*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician or poison control centerimmediately. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratorymedical device.

Skin contact Remove and isolate contaminated clothing and shoes. For contact with ambient temperaturematerial: Immediately wash off with plenty of soap and water. Wash clothing separately beforereuse. If skin irritation or rash occurs: Get medical advice/attention.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Call a physician or poison control center immediately.

Ingestion If swallowed, do NOT induce vomiting. Give victim water or milk. Call a physician or poison controlcenter immediately. Never give anything by mouth to a victim who is unconscious or is havingconvulsions.

Most importantsymptoms/effects, acute anddelayed

May cause severe irritation to the eyes and respiratory system. Irritating to the skin and digestivesystem. Contact with skin may cause itching, redness, rash and scaling. Causes burns to the skin,eyes, and digestive tract. Causes serious eye damage. Ingestion may cause abdominal pain,nausea, possible collapse, and kidney damage.

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Indication of immediatemedical attention and specialtreatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet (SDS) to the doctor in attendance. If you feelunwell, seek medical advice (show the label where possible).

5. Fire-fighting measures

Suitable extinguishing media Alcohol foam, carbon dioxide (CO2), dry chemical, foam, or water fog.

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising fromthe chemical

Closed containers may rupture or explode (due to pressure build-up) when exposed to extremeheat. During fire, gases hazardous to health may be formed.

Special protective equipmentand precautions forfirefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and NIOSH approved self-contained breathing apparatus (SCBA).

Fire fightingequipment/instructions

Move containers from fire area if you can do so without risk. Use water to cool exposed containers.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

Hazardous combustionproducts

Oxides of carbon. Irritating and/or toxic fumes and gases may be emitted upon the productsthermal decomposition or combustion.

6. Accidental release measures

Personal precautions,protective equipment andemergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ensureadequate ventilation. Wear appropriate protective equipment and clothing during clean-up. SeeSection 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers orspilled material unless wearing appropriate protective clothing.

Methods and materials forcontainment and cleaning up

Stop the flow of material, if this is without risk.

Clean up in accordance with all applicable regulations.

Large Spills: Absorb with inert absorbent such as clay. Sweep up and shovel into suitable containersfor disposal. Wash spill area with detergent solution or wipe with alcohol-soaked rags. Dispose of allwashings and contaminated items in accordance with waste regulations.

Small Spills: Absorb with inert absorbent such as clay. Sweep up and shovel into suitable containersfor disposal. Wash spill area with detergent solution or wipe with alcohol-soaked rags. Dispose of allwashings and contaminated items in accordance with waste regulations.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid discharge into drains, water courses or onto the ground. Keep off of soil. Prevent furtherleakage or spillage if safe to do so. Avoid release to the environment.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Observe good industrial hygiene practices. Do not breathedust/fume/gas/mist/vapors/spray. Use local ventilation if product is heated during use. Provideadequate ventilation. In case of inadequate ventilation, use respiratory protection. Avoid contactwith skin, eyes and clothing. Use personal protective equipment as required. See Section 8 of theSDS for Personal Protective Equipment. When using, do not eat, drink or smoke. Wash thoroughlyafter handling. Remove contaminated clothes and wash separately before reuse. Avoid release tothe environment.

Conditions for safe storage,including anyincompatibilities

Store indoors in a cool, dry place at an ambient temperature. Store away from incompatiblematerials. See Section 10 of the SDS for incompatible materials. Keep containers closed when notin use. Keep out of reach of children.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents Type

PEL 19 mg/m3PHENOL (CAS 108-95-2)

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5 ppm

US. ACGIH Threshold Limit Values


TWA 5 ppmPHENOL (CAS 108-95-2)

US. NIOSH: Pocket Guide to Chemical Hazards


Ceiling 60 mg/m3PHENOL (CAS 108-95-2)

15.6 ppm

TWA 19 mg/m3

5 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides


TWA 6 mg/m3TRIETHYLENE TETRAMINE(CAS 112-24-3)

1 ppm

Biological limit values

US. ACGIH. BEIs. Biological Exposure Indices

ValueComponents Determinant Specimen Sampling Time

250 mg/g Phenol withhydrolysis

Creatinine inurine

*PHENOL (CAS 108-95-2)

* - For sampling details, please see the source document.

Exposure guidelines

US - Tennessee OELs: Skin designation

PHENOL (CAS 108-95-2) Can be absorbed through the skin.



US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants


US. Minnesota Hazardous Substances List (Minn. Rules 5206.0400).

PHENOL (CAS 108-95-2) Skin designation applies.





US. Workplace Environmental Exposure Level (WEEL) Guides

TRIETHYLENE TETRAMINE (CAS 112-24-3) Can be absorbed through the skin.

Appropriate engineeringcontrols

Local exhaust as needed to control vapor or dust levels to below lowest component TLV. Provideeyewash station and safety shower.

Individual protection measures, such as personal protective equipment

Eye/face protection Avoid contact with eyes. Wear chemical goggles. Face-shield.

Skin protection

Hand protection Use nitrile, supported polyvinyl alcohol (PVA), or butyl rubber gloves.

Other Avoid contact with the skin. Normal work clothing (long sleeved shirts and long pants) isrecommended.

Respiratory protection A NIOSH approved air purifying respirator with an organic vapor cartridge or canister may bepermissible under certain circumstances where airborne concentrations are expected to exceedexposure limits, inhalation effects occur, or if use is performed in poorly ventilated spaces.

Thermal hazards Not available.

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General hygieneconsiderations

Always observe good personal hygiene measures, such as washing after handling the material andbefore eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment toremove contaminants. When using, do not eat, drink or smoke. Keep away from food and drink. Donot get in eyes, on skin, or on clothing.

9. Physical and chemical properties

Appearance

Physical state Liquid.

Form Liquid.

Color Light amber.

Odor Acrid ammoniacal.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point andboiling range

446 °F (230 °C)

Flash point 275.0 °F (135.0 °C)

Evaporation rate Slower than n-Butyl Acetate.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit -upper (%)

Not available.

Explosive limit - lower(%)

Not available.

Explosive limit - upper(%)

Not available.

Vapor pressure Not available.

Vapor density Heavier than Air.

Relative density Not available.

Solubility(ies)

Solubility (water) Appreciable.

Partition coefficient(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Specific gravity 1.080

VOC (Weight %) 0 g/l Calculated.

10. Stability and reactivity

Reactivity Not available.

Chemical stability Product is stable, when stored indoors, inside a closed container, and at ambient conditions.

Possibility of hazardousreactions

Will not occur under normal conditions.

Conditions to avoid Contact with incompatible materials.

Incompatible materials Strong Lewis or mineral acids.

Hazardous decompositionproducts

Oxides of carbon. Irritating and/or toxic fumes and gases may be emitted upon the productsdecomposition.

11. Toxicological information

Information on likely routes of exposure

Inhalation Do not breathe dust/fume/gas/mist/vapors/spray. Severely irritating to respiratory system. Fatal ifinhaled. High mist, gas, dust, or vapor concentrations may be harmful if inhaled.

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Skin contact Avoid contact with the skin. Harmful in contact with skin. Contact cause irritation, swelling,redness, and scaling. Causes skin burns. May cause an allergic skin reaction. May be absorbedthrough the skin in harmful amounts.

Eye contact Avoid contact with eyes. Severely irritating to eyes. Causes eye burns. If not removed promptly,will injure eye tissue, which may result in permanent damage.

Ingestion Do not swallow or taste. May cause burns or irritation to the mouth, throat, and stomach withnausea, abdominal pain, nausea, and possible collapse. This product may be harmful or fatal ifswallowed. Kidney damage may occur through ingestion of significant amounts.

Symptoms related to thephysical, chemical andtoxicological characteristics

May cause severe irritation to the eyes and respiratory system. Irritating to the skin and digestivesystem. May cause an allergic skin reaction. Contact with skin may cause itching, redness, rashand scaling. Causes burns to the skin, eyes, and digestive tract. Causes serious eye damage.Ingestion may cause abdominal pain, nausea, possible collapse, and kidney damage.

Information on toxicological effects

Acute toxicity May cause severe irritation to the eyes and respiratory system. Irritating to the skin and digestivesystem. May cause an allergic skin reaction. Contact causes irritation with redness, scaling andswelling to the skin. Fatal if inhaled. Causes burns to the skin, eyes, and digestive tract. May causepermanent damage to the eyes. Ingestion may cause abdominal pain, nausea, possible collapse,and kidney damage.

Test ResultsComponents Species

PHENOL (CAS 108-95-2)

LD50 Rabbit

Dermal

Acute

850 mg/kg

Rat 669 mg/kg

LD50 Cat

Oral

0.1 g/kg

Dog 0.5 g/kg

Mouse 270 mg/kg

Rat 317 mg/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Causes severe burns to the skin. Causes skin irritation.

Serious eye damage/eyeirritation

Severely irritating, and may seriously damage eye tissue. Causes severe eye burns. May causepermanent damage to the eyes.

Respiratory or skin sensitization

Respiratory sensitization Not available.

Skin sensitization May cause an allergic skin reaction.

Germ cell mutagenicity Suspected of causing genetic defects.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of Carcinogenicity

PHENOL (CAS 108-95-2) 3 Not classifiable as to carcinogenicity to humans.

Reproductive toxicity Not available.

Specific target organ toxicity- single exposure

Not available.

Specific target organ toxicity- repeated exposure

Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard Not available.

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Chronic effects Preexisting pulmonary and dermatological disorders may be aggravated by exposure to hazardouscomponents. Prolonged inhalation may be harmful. May cause an allergic skin reaction May beharmful if absorbed through skin. Prolonged exposure may cause chronic effects.Triethylenetetramine (TETA) caused embryofetal toxicity and fetal malformations when fed topregnant rats. Similar effects were not seen in studies which this material was applied to the skinof rabbits, a more relevant route of industrial exposure. These effects are believed to be secondaryto copper deficiency, resulting from the chelating acitivty of the amine. Repeated or prolongedexposure to phenol via inhalation, ingestion, or skin absorpotion may cause damage to the liver,kidneys, pancreas, and spleen. Phenol is muagenic 'in virto." Repeated or prolonged overexposureto phenol may damage liver or kidney with dark urine, diarrhea, and localized external and/orinternal sores. Phenolic solutions may be absorbed rapidly through the skin and may causedamage to the pancreas, spleen, liver, kidneys, and edema of the lungs. Causes damage to organsthrough prolonged or repeated exposure.

12. Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.

Product Test ResultsSpecies

ACRAGLAS (R) HARDENER, 7/8 OZ. (2-GUN ACRAGLAS KIT)

Aquatic

EC50Crustacea 189 mg/l, 48 hoursDaphnia


LC50Fish 144 mg/l, 96 hoursFish

Persistence and degradability Not available.

Bioaccumulative potential Not available.

Mobility in soil Not available.

Other adverse effects Not available.

13. Disposal considerations

Disposal instructions Dispose of in accordance with current, applicable local, state, and federal regulations.

Waste from residues /unused products

Not available.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information

DOT

Not regulated as dangerous goods.

IATA


IMDG


Not available.Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

PHENOL (CAS 108-95-2) Listed.

SARA 304 Emergency release notification

PHENOL (CAS 108-95-2) 1000 LBS

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Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely hazardous substance

Chemical name CAS number Reportablequantity

Thresholdplanning quantity

Thresholdplanningquantity, lowervalue

Thresholdplanningquantity, uppervalue

PHENOL 108-95-2 1000 500 lbs 10000 lbs

SARA 311/312Hazardous chemical

No

SARA 313 (TRI reporting)

Chemical name CAS number % by wt.

PHENOL 108-95-2 10 - < 20

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List


Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act(SDWA)

Not regulated.

US state regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section11100)

Not listed.

US. Massachusetts RTK - Substance List


TRIETHYLENE TETRAMINE (CAS 112-24-3)

US. New Jersey Worker and Community Right-to-Know Act



US. Pennsylvania Worker and Community Right-to-Know Law



US. Rhode Island RTK


US. California Proposition 65

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain anychemicals currently listed as carcinogens or reproductive toxins.

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

NoAustralia Australian Inventory of Chemical Substances (AICS)

NoCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

NoChina Inventory of Existing Chemical Substances in China (IECSC)

NoEurope European Inventory of Existing Commercial Chemical Substances(EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

NoKorea Existing Chemicals List (ECL)

NoNew Zealand New Zealand Inventory

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NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

16. Other information, including date of preparation or last revision

Issue date 01-27-2015

Revision date 02-10-2015

Version # 02

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,information, and belief at the date of its publication. The information given is designed only asguidance for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.

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SAFETY DATA SHEET

1. Identification

Product identifier ACRAGLAS (R) RESIN, 2 OZ. (2-GUN ACRAGLAS KIT)


Product code 081-003-002 (RESIN)

Recommended use Adhesive (epoxy resin component).



Manufacturer

BROWNELLS, INC.


Company name

Website

Telephone (641) 623-5401





E-mail

United States

www.brownells.com

Not available.




Category 2Skin corrosion/irritationHealth hazards


Category 1Sensitization, skin

Category 1Reproductive toxicity

Category 1Hazardous to the aquatic environment, acutehazard


Category 2Hazardous to the aquatic environment,long-term hazard


Label elements


Hazard statement Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Maydamage fertility or the unborn child. Harmful to aquatic life with long lasting effects.


Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly afterhandling. Do not eat, drink or smoke when using this product. Contaminated work clothing shouldnot be allowed out of the workplace. Avoid release to the environment. Wear protectivegloves/protective clothing/eye protection/face protection. Use only with adequate ventilation.

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Material name: ACRAGLAS (R) RESIN, 2 OZ. (2-GUN ACRAGLAS KIT)


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Response If on skin: Wash with plenty of soap and water. If in eyes: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed orconcerned: Get medical advice/attention. Specific treatment (see this label). If skin irritation orrash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.Take off contaminated clothing and wash before reuse. If inhaled: Remove to fresh air and keep atrest in a position comfortable for breathing. If swallowed, do NOT induce vomiting. Give victimwater or milk. Call a physician or poison control center immediately. Never give anything by mouthto a victim who is unconscious or is having convulsions.

Storage Store locked up. Store indoors in a cool, dry place at an ambient temperature away fromincompatible material. Keep containers closed when not in use. Keep out of reach of children.



Not available.


Not available.

Supplemental information % of the mixture consists of component(s) of unknown acute hazards to the aquatic environment.


Mixtures


25068-38-6BISPHENOL A - EPICHLOROHYDRINPOLYMER

50 - < 100


84-74-2DIBUTYL PHTHALATE 10 - < 20



Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.Oxygen or artificial respiration if needed. If experiencing respiratory symptoms call a POISONCENTER or doctor/physician. Do not use mouth-to-mouth method if victim inhaled the substance.Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or otherproper respiratory medical device.

Skin contact Remove and isolate contaminated clothing and shoes. Wash off immediately with soap and plentyof water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothingbefore reuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Ingestion If swallowed, do NOT induce vomiting. Give victim water or milk. Call a physician or poison controlcenter immediately. Never give anything by mouth to a victim who is unconscious or is havingconvulsions. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respirationwith the aid of a pocket mask equipped with a one-way valve or other proper respiratory medicaldevice.


Irritating to eyes, respiratory system and skin. May cause an allergic skin reaction. Dermatitis. Maycause nausea and vomiting.


Provide general supportive measures and treat symptomatically. Symptoms may be delayed. Incase of shortness of breath, give oxygen. Keep victim under observation. Keep victim warm.

General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware ofthe material(s) involved, and take precautions to protect themselves. Show this safety data sheet(SDS) to the doctor in attendance. Keep victim under observation. Keep victim warm.



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During fire, gases hazardous to health may be formed. Closed containers exposed to heat from firemay build pressure and explode.




Move containers from fire area if you can do so without risk. Use water to cool containers exposedto fire and heat. In case of fire and/or explosion do not breathe fumes.






Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Avoidbreathing dust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. In case of inadequateventilation wear respiratory protection. Wear appropriate protective equipment and clothing duringclean-up. See Section 8 of the SDS for Personal Protective Equipment. Do not touch damagedcontainers or spilled material unless wearing appropriate protective clothing.


Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.


Large Spills: Absorb with inert absorbent such as clay. Sweep up and shovel into suitable containersfor disposal. Clean surface thoroughly to remove residual contamination.

Small Spills: Absorb with inert absorbent such as clay. Sweep up and shovel into suitable containersfor disposal. Clean surface thoroughly to remove residual contamination.


Environmental precautions Avoid discharge into drains, water courses or onto the ground. Keep off of soil. Prevent furtherleakage or spillage if safe to do so. Avoid release to the environment.


Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Observe good industrial hygiene practices. Avoid prolonged exposure. Do notbreathe dust/fume/gas/mist/vapors/spray. Provide adequate ventilation. Use local ventilation ifproduct is heated during use. In case of insufficient ventilation, wear suitable respiratoryequipment. Should be handled in closed systems, if possible. Do not get in eyes, on skin, or onclothing. Wear appropriate personal protective equipment. See Section 8 of the SDS for PersonalProtective Equipment. Wash thoroughly after handling. Contaminated work clothing must not beallowed out of the workplace. Wash contaminated clothing before reuse. Avoid release to theenvironment.


Store locked up. Store indoors in a cool, dry place at an ambient temperature away fromincompatible material. See Section 10 of the SDS for incompatible materials. Keep container closedwhen not in use. Keep out of the reach of children.





PEL 5 mg/m3DIBUTYL PHTHALATE (CAS84-74-2)



TWA 5 mg/m3DIBUTYL PHTHALATE (CAS84-74-2)

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TWA 5 mg/m3DIBUTYL PHTHALATE (CAS84-74-2)

Biological limit values No biological exposure limits noted for the ingredient(s).


Local exhaust as needed to control vapor or dust levels to below lowest component TLV. Provideeyewash station and safety shower.


Eye/face protection Do not get in eyes. Wear chemical goggles. Face-shield.

Skin protection


Other Do not get this material in contact with skin. Normal work clothing (long sleeved shirts and longpants) is recommended.

Respiratory protection Do not breathe dust/fume/gas/mist/vapors/spray. A NIOSH approved air purifying respirator withan organic vapor cartridge or canister may be permissible under certain circumstances whereairborne concentrations are expected to exceed exposure limits, inhalation effects occur, or if use isperformed in poorly ventilated spaces.



Always observe good personal hygiene measures, such as washing after handling the material andbefore eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment toremove contaminants. Contaminated work clothing should not be allowed out of the workplace.When using, do not eat, drink or smoke. Do not get in eyes, on skin, or on clothing.


Appearance


Form Liquid.

Color Clear pale yellow.

Odor No appreciable.


pH Not available.



Not available.

Flash point > 248.0 °F (> 120.0 °C)




Flammability limit - lower(%)

Not available.


Not available.


Not available.


Not available.




Solubility(ies)

Solubility (water) Insoluble.


Not available.


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Other information




Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.




Incompatible materials Strong bases or oxidants. Strong Lewis or mineral acids. Reaction with amines and mercaptans inlarge amounts or under uncontrolled conditions releases considerable heat and may release acridfumes.





Inhalation Avoid breathing dust/fume/gas/mist/vapors/spray. Vapors and/or aerosols which may be formed atelevated temperatures and may be irritating to the respiratory tract.

Skin contact Avoid contact with the skin. Moderate skin irritation. May cause an allergic skin reaction. Frequentor prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

Eye contact Avoid contact with eyes. Causes serious eye irritation. Irritating, but will not permanently injureeye tissue.

Ingestion Do not swallow or taste. May cause nausea and vomiting. May be harmful if swallowed.


Irritating to eyes, respiratory system and skin. May cause an allergic skin reaction. Dermatitis. Maycause nausea and vomiting.


Acute toxicity May cause an allergic skin reaction. Irritating to eyes, respiratory system and skin. May causenausea and vomiting. Dermatitis.


DIBUTYL PHTHALATE (CAS 84-74-2)

LD50 Rabbit

Dermal

Acute

4200 mg/kg

LC50 Mouse

Inhalation

25 mg/l, 2 Hours

Rat 15.68 mg/l, 4 Hours

LD50 Guinea pig

Oral

10000 mg/kg

Mouse 4840 mg/kg

Rat 6300 mg/kg


Skin corrosion/irritation Causes skin irritation.


Causes serious eye irritation.



Skin sensitization May cause an allergic skin reaction. Frequent or prolonged contact may defat and dry the skin,leading to discomfort and dermatitis.

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SDS US

Page 14 of 48

Germ cell mutagenicity Not available.


Reproductive toxicity Possible reproductive hazard. May damage fertility or the unborn child. Potential embryo-fetaltoxicity and teratogenicity.


Not available.


Not available.


Chronic effects Preexisting dermatological conditions may be aggravated by exposure or contact. Prolongedinhalation may be harmful. May cause an allergic skin reaction


Ecotoxicity Very toxic to aquatic life with long lasting effects.

Persistence and degradability The product is not readily biodegradable (in test environment). No information regardingbiopersistence.

Bioaccumulative potential Moderate bioconcentration potential.






Not available.



DOT


IATA

UN3082UN number

Environmentally Hazardous Substance, Liquid, n.o.s. (Bisphenol-A Epoxy Resin)UN proper shipping name

9Class

Transport hazard class(es)

-Subsidiary risk

IIIPacking group

Yes.Environmental hazards

Not available.Special precautions foruser

Forbidden.Passenger and cargoaircraft

Other information

Forbidden.Cargo aircraft only

IMDG

UN3082UN number

Environmentally Hazardous Substance, Liquid, n.o.s. (Bisphenol-A Epoxy Resin), MARINEPOLLUTANT

UN proper shipping name

9Class


-Subsidiary risk

IIIPacking group

YesMarine pollutant


Not available.EmS


6 / 8



SDS US

Page 15 of 48


IATA; IMDG

Marine pollutant

General information IMDG Regulated Marine Pollutant.




Not regulated.


DIBUTYL PHTHALATE (CAS 84-74-2) Listed.


Not regulated.


Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


Not listed.


No


Chemical name CAS number % by wt.

DIBUTYL PHTHALATE 84-74-2 10 - < 20





Not regulated.


Not regulated.

7 / 8



SDS US

Page 16 of 48

US state regulations WARNING: This product contains a chemical known to the State of California to cause birth defectsor other reproductive harm.


Not listed.










WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductiveharm.

US - California Proposition 65 - CRT: Listed date/Developmental toxin

DIBUTYL PHTHALATE (CAS 84-74-2) Listed: December 2, 2005

US - California Proposition 65 - CRT: Listed date/Female reproductive toxin


US - California Proposition 65 - CRT: Listed date/Male reproductive toxin




YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)


YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial Chemical Substances(EINECS)


YesJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)






Version # 02

References ACGIHEPA: AQUIRE databaseNLM: Hazardous Substances Data BaseUS. IARC Monographs on Occupational Exposures to Chemical Agents


8 / 8



SDS US

Page 17 of 48

SAFETY DATA SHEET

1. Identification

Product identifier ACRAGLAS (R) RELEASE AGENT, 7/8 OZ. (2-GUN ACRAGLAS KIT)


Product code 081-003-002 (RELEASE AGENT)

Recommended use Coating: Prevents adhesive from adhering parts together.



Manufacturer

BROWNELLS, INC.


Company name

Website

Telephone (641) 623-5401





E-mail

United States

www.brownells.com

Not available.



Category 1Flammable liquidsPhysical hazards

Category 4Acute toxicity, oralHealth hazards


Category 3 narcotic effectsSpecific target organ toxicity, single exposure

Not available.Environmental hazards


Label elements


Hazard statement Not available.


Prevention Keep out of reach of children. Obtain special instructions before use. Do not handle until all safetyprecautions have been read and understood. Keep away from heat/sparks/open flames/hotsurfaces. - No smoking. Keep container tightly closed. Avoid breathingdust/fume/gas/mist/vapors/spray. Use explosion-proof electrical/ventilating/lighting equipment.Use only non-sparking tools. Take precautionary measures against static discharges. Do not eat,drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wearprotective gloves/protective clothing/eye protection/face protection.

Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinsecautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing. Call a physician or poison control center immediately. IF exposed or concerned:Get medical advice/attention. In case of fire: Use appropriate media for extinction. If on skin:Wash off immediately with soap and plenty of water. If swallowed: Do not induce vomiting. Nevergive anything by mouth to a victim who is unconscious or is having convulsions.

1 / 9

Material name: ACRAGLAS (R) RELEASE AGENT, 7/8 OZ. (2-GUN ACRAGLAS KIT)


SDS US

Page 18 of 48

Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protectfrom sunlight. Store indoors in a cool, dry place at an ambient temperature away fromincompatible material. Keep away from heat and sources of ignition Take precautionary measuresagainst static discharges. Keep out of reach of children.



Not available.


Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.

Supplemental information Not available.


Mixtures



71-23-8N-PROPYL ALCOHOL 20 - < 50



Inhalation If inhaled, remove to fresh air and keep at rest in a position comfortable for breathing. Oxygen orartificial respiration if needed. Get medical attention if symptoms persist. Do not usemouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid ofa pocket mask equipped with a one-way valve or other proper respiratory medical device.

Skin contact Take off immediately all contaminated clothing. Wash off immediately with soap and plenty ofwater. Get medical attention if symptoms occur. Wash contaminated clothing before reuse.

Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contactlenses. Continue rinsing. Get medical attention immediately.

Ingestion If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Nevergive anything by mouth to a victim who is unconscious or is having convulsions.


May cause drowsiness and dizziness. Drying and irritation of the nose, mucous membrane, and sorethroat may result from the inhalation of vapors. Liquid, aerosols and vapors of this product areirritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensationand/or a feeling like that of fine dust in the eyes. Irritating to eyes, respiratory system and skin.Preexisting pulmonary and dermatological disorders may be aggravated by exposure to hazardouscomponents. Possible burns to the skin.


Provide general supportive measures and treat symptomatically. If swallowed, gastric lavage isindicated. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim underobservation. Symptoms may be delayed. Thermal burns: Flush with water immediately. Whileflushing, remove clothes which do not adhere to affected area. Call an ambulance. Continueflushing during transport to hospital.

General information In case of shortness of breath, give oxygen. Keep victim under observation. Keep victim warm. IFexposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware ofthe material(s) involved, and take precautions to protect themselves. Show this safety data sheet(SDS) to the doctor in attendance.






Closed containers may rupture or explode (due to pressure build-up) when exposed to extremeheat. Vapors may form explosive mixtures with air. Vapors may travel considerable distance to asource of ignition and flash back. This product is a poor conductor of electricity and can becomeelectrostatically charged. To reduce potential for static discharge, use proper bonding andgrounding procedures. If sufficient charge is accumulated, ignition of flammable mixtures canoccur. Material will float and may ignite on surface of water.

2 / 9



SDS US

Page 19 of 48




Application of large quantities (flooding) of water instead of mist or spray preferred. Use water tocool containers exposed to fire and heat. In case of fire and/or explosion do not breathe fumes.Move containers from fire area if you can do so without risk.



Oxides of carbon. Oxygen-deficient environments may produce formaldehyde. Irritating and/ortoxic fumes and gases may be emitted upon the products thermal decomposition or combustion.

General fire hazards Extremely flammable liquid and vapor.



Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate allignition sources (no smoking, flares, sparks, or flames in immediate area). Use only non-sparkingtools. Take measures to prevent the build up of electrostatic charge. Avoid breathingdust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. Wear appropriate protectiveequipment and clothing during clean-up. See Section 8 of the SDS for Personal ProtectiveEquipment. Do not touch damaged containers or spilled material unless wearing appropriateprotective clothing.


Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.


Large Spills: Absorb with inert absorbent such as clay. Sweep up and shovel into suitable containersfor disposal. Wash spill area with detergent solution. Dispose of all washings and contaminateditems in accordance with waste regulations.

Small Spills: Absorb with inert absorbent such as clay. Sweep up and shovel into suitable containersfor disposal. Wash spill area with detergent solution. Dispose of all washings and contaminateditems in accordance with waste regulations.

Never return spills to original containers for re-use.

Environmental precautions Keep out of waterways, drains, ditches, and sewers. Keep off of soil.


Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Protectmaterial from direct sunlight. Use explosion-proof electrical/ventilating/lighting equipment. Usenon-sparking tools. Take precautionary measures against static discharges. Observe good industrialhygiene practices. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in awell-ventilated area. Do not get in eyes, on skin, or on clothing. Wear appropriate personalprotective equipment. See Section 8 of the SDS for Personal Protective Equipment. Washthoroughly after handling. Remove and wash contaminated clothing before re-use.


Store indoors in a cool, dry place at an ambient temperature away from incompatible material. SeeSection 10 of the SDS for incompatible materials. Protect against direct sunlight. Keep cool. Keep inan area equipped with sprinklers. Take precautionary measures against static discharge. Store in awell-ventilated place. Store locked up. Keep container tightly closed. Keep away from food, drinkand animal feedingstuffs. Keep out of the reach of children. Keep away from heat and sources ofignition. Keep out of the reach of children.





PEL 500 mg/m3N-PROPYL ALCOHOL (CAS71-23-8)

200 ppm



TWA 100 ppmN-PROPYL ALCOHOL (CAS71-23-8)

3 / 9



SDS US

Page 20 of 48



STEL 625 mg/m3N-PROPYL ALCOHOL (CAS71-23-8)

250 ppm

TWA 500 mg/m3

200 ppm


Exposure guidelines

US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants

N-PROPYL ALCOHOL (CAS 71-23-8) Can be absorbed through the skin.

US. Minnesota Hazardous Substances List (Minn. Rules 5206.0400).

N-PROPYL ALCOHOL (CAS 71-23-8) Skin designation applies.


N-PROPYL ALCOHOL (CAS 71-23-8) Can be absorbed through the skin.


Local exhaust as needed to control vapor or dust levels to below lowest component TLV. Provideexplosion proof ventilation for processing large quantities. Provide eyewash station and safetyshower.


Eye/face protection Avoid contact with eyes. Wear chemical goggles. Face-shield.

Skin protection








Appearance


Form Liquid.

Color Clear.

Odor Alcohol.


pH 6 - 8



Not available.

Flash point 71.6 °F (22.0 °C)





2.2


13.7


2.2

4 / 9



SDS US

Page 21 of 48


13.7




Solubility(ies)

Solubility (water) Complete.


Not available.

Auto-ignition temperature 773.6 °F (412 °C)



Other information





Chemical stability Solidification of product may occur upon prolonged exposure to heat.



Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials.

Incompatible materials May react with strong bases or oxidizing agents.


Oxides of carbon. Oxygen-deficient environments may produce formaldehyde. Irritating and/ortoxic fumes and gases may be emitted upon the products thermal decomposition or combustion.



Inhalation Do not breathe dust/fume/gas/mist/vapors/spray. Liquid aspirated into lungs may cause injury tothe lungs, kidney, or liver. Drying and irritation of the nose, mucous membrane, and sore throatmay result from the inhalation of vapors. Gas, vapor, mist, or dust concentrations may be harmfulif inhaled.

Skin contact Do not get this material in contact with skin. Prolonged skin contact may cause severe skinirritation and possible burns. Frequent or prolonged contact may defat and dry the skin, leading todiscomfort and dermatitis.

Eye contact Do not get this material in contact with eyes. Causes serious eye damage. If not promptlyremoved, contact may cause injury to eye tissue. Liquid, aerosols and vapors of this product areirritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensationand/or a feeling like that of fine dust in the eyes.

Ingestion Do not swallow or taste. Harmful if swallowed. Irritating to mouth, throat, and stomach withnausea.


May cause drowsiness and dizziness. Irritating to eyes, respiratory system and skin. Drying andirritation of the nose, mucous membrane, and sore throat may result from the inhalation of vapors.Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddeningand swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes.Irritating to mouth, throat and stomach, with nausea. Preexisting pulmonary and dermatologicaldisorders may be aggravated by exposure to hazardous components. Possible burns to the skin.


Acute toxicity Harmful if inhaled or swallowed. Causes serious eye damage. Possible burns to the skin. Irritatingto eyes, respiratory system and skin. May cause drowsiness or dizziness. Drying and irritation ofthe nose, mucous membrane, and sore throat may result from the inhalation of vapors. Liquid,aerosols and vapors of this product are irritating and can cause pain, tearing, reddening andswelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes.Irritating to mouth, throat and stomach, with nausea.

5 / 9



SDS US

Page 22 of 48


N-PROPYL ALCOHOL (CAS 71-23-8)

LD50 Mouse

Oral

Acute

6800 mg/kg

Rabbit 2.8 g/kg

Rat 1.87 g/kg


Skin corrosion/irritation Causes severe irritation and burns to the skin.


Irritating to eyes. Causes severe eye damage.



Skin sensitization Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.





May cause drowsiness and dizziness.


Not available.


Chronic effects Preexisting pulmonary and dermatological disorders may be aggravated by exposure to hazardouscomponents. Prolonged inhalation may be harmful. Prolonged skin contact may cause severe skinirritation and possible burns. Repeated absorption may cause disorder of central nervous system,liver, kidneys and blood. Prolonged exposure may cause chronic effects.


Ecotoxicity Not available.

Persistence and degradability Product is readily degradable.







Not available.



DOT

UN1274UN number

n-Propanol SolutionUN proper shipping name

3Class


-Subsidiary risk

IIPacking group

Read safety instructions, SDS and emergency procedures before handling.Special precautions foruser

150Packaging exceptions

202Packaging non bulk

242Packaging bulk

129ERG number

6 / 9



SDS US

Page 23 of 48

IATA

UN1274UN number


3Class


-Subsidiary risk

IIPacking group

No.Environmental hazards

3LERG Code


Allowed.Passenger and cargoaircraft

Other information

Allowed.Cargo aircraft only

IMDG

UN1993UN number


3Class


-Subsidiary risk

IIPacking group

No.Marine pollutant


F-E, S-DEmS



DOT

IATA; IMDG



CERCLA/SARA Hazardous Substances - Not applicable.

7 / 9



SDS US

Page 24 of 48


Not regulated.


N-PROPYL ALCOHOL (CAS 71-23-8) Listed.


Not regulated.


Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No


Not listed.


No


Not regulated.



Not regulated.


Not regulated.


Not regulated.

US state regulations

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not listed.








Not regulated.















8 / 9



SDS US

Page 25 of 48







Version # 02

References ACGIHACGIH Documentation of the Threshold Limit Values and Biological Exposure IndicesEPA: AQUIRE databaseHSDB® - Hazardous Substances Data BankIARC Monographs. Overall Evaluation of CarcinogenicityNational Toxicology Program (NTP) Report on CarcinogensNLM: Hazardous Substances Data BaseUS. IARC Monographs on Occupational Exposures to Chemical Agents


9 / 9



SDS US

Page 26 of 48

SAFETY DATA SHEET

1. Identification

Product identifier FIBERGLASS FLOC, 4.25 GRAMS (2-GUN ACRAGLAS KIT)


Product code 081-003-002 (FIBERGLASS)

Recommended use Strengthens stock and simplifies inletting.



Manufacturer

BROWNELLS, INC.


Company name

Website

Telephone (641) 623-5401





E-mail

United States

www.brownells.com

Not available.




Not available.Health hazards



Label elements

Not available.Hazard symbol


Hazard statement The mixture does not meet the criteria for classification.


Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Do not breathe dust. Use personal protective equipment as required. Washthoroughly after handling. Do not eat, drink or smoke when using this product. Observe goodindustrial hygiene practices. Minimize dust generation and accumulation. Provide appropriateexhaust ventilation at places where dust is formed. Do not get in eyes, on skin, or on clothing.Remove contaminated clothes and wash separately before reuse.

Response If exposed or concerned: Get medical advice/attention. If inhaled: Move to fresh air. If on skin:Wash off immediately with soap and plenty of cold water. If in eyes: Rinse cautiously with water atleast 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Ifswallowed: Rinse mouth thoroughly with water and have victim drink water to remove fibers fromthroat. Never give anything by mouth to a victim who is unconscious or is having convulsions. Calla physician if symptoms develop or persist.

Storage Store in a well-ventilated place. Store in tightly closed original container. Minimize dust generationand accumulation. Material should be kept dry. Keep out of reach of children.



Not available.


Not available.


1 / 7

Material name: FIBERGLASS FLOC, 4.25 GRAMS (2-GUN ACRAGLAS KIT)


SDS US

Page 27 of 48


Mixtures


65997-17-3FIBER GLASS (MADE FROMCONTINUOUS FILAMENT, NOTRESPIRABLE)

> 99

Not ApplicableSIZING < 1



Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Do not use mouth-to-mouthmethod if victim inhaled the substance. Induce artificial respiration with the aid of a pocket maskequipped with a one-way valve or other proper respiratory medical device.

Skin contact Remove and isolate contaminated clothing and shoes. Wash off immediately with soap and plentyof cold water. Do not wash with warm water, because warm water will open up the pores of skincausing the fibers to penetrate further. Get medical attention if irritation develops and persists.Wash clothing separately before reuse. Wash clothing separately before reuse. Do not scratch orrub affected areas. Do not use compressed air to remove fibers from skin. Fibers that havepenetrated the skin may be removed by applying and removing adhesive tape resulting in the fibersadhering to the tape and are removed from the skin.

Eye contact Do not rub eyes. Immediately flush eyes with eyelids open and use plenty of water for at least 15minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attentionif irritation develops or persists.

Ingestion Material is unlikely to be accidently ingested. If ingestion occurs, observe person for several days toensure intestinal blockage does not occur. Rinse mouth thoroughly with water and have victimdrink water to remove fibers from throat. If symptoms persist, get medical attention. Never giveanything by mouth to a victim who is unconscious or is having convulsions.


Irritating to eyes, respiratory system and skin. Mechanical irritation to the skin and eyes may resultfrom exposure to dust. Inhalation may cause sneezing, coughing and irritation to the nose andthroat. High exposure may cause congestion, chest tightness, and difficulty in breathing. Ingestionmay cause transient irritation to the throat and gastrointestinal tract. Exposure may temporallyworsen pre-existing respiratory and skin conditions.


Provide general supportive measures and treat symptomatically. Keep victim under observation.Keep victim warm. Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet (SDS) to the doctor in attendance. If you feelunwell, seek medical advice (show the label where possible).


Suitable extinguishing media Dry chemical. Foam. Carbon dioxide (CO2). Water fog.


Not available.


None known.




Move containers from fire area if you can do so without risk.



Carbon monoxide and carbon dioxide. Ammonia. Small quantities of other undeterminedcompounds may be released.

2 / 7



SDS US

Page 28 of 48



Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ensureadequate ventilation. Wear appropriate protective equipment and clothing during clean-up. SeeSection 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers orspilled material unless wearing appropriate protective clothing.


Material will settle out of air. Prevent spreading through covering material. Dike the spilled material,where this is possible.

Clean up in accordance with all applicable regulations. Avoid the generation of dusts duringclean-up.

Large Spills: Use dustless methods for cleanup. Collect dust using a vacuum cleaner equipped withHEPA filter. If not possible, moisten dust with water before it is collected with shovel, broom or thelike. Avoid dry sweeping.

Small Spills: Use dustless methods for cleanup. Collect dust using a vacuum cleaner equipped withHEPA filter. If not possible, moisten dust with water before it is collected with shovel, broom or thelike. Avoid dry sweeping.


Environmental precautions Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses oronto the ground.


Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Observe good industrial hygiene practices. Avoid prolonged exposure. Do notbreathe dust. Provide appropriate exhaust ventilation at places where dust is formed. Minimize dustgeneration and accumulation. Avoid contact with skin, eyes and clothing. Use personal protectiveequipment as required. See Section 8 of the SDS for Personal Protective Equipment. When using,do not eat, drink or smoke. Wash thoroughly after handling. Remove contaminated clothes andwash separately before reuse. Practice good housekeeping.


Store in tightly closed original container. Minimize dust generation and accumulation. Materialshould be kept dry. Store in a well-ventilated place. Keep out of the reach of children.




ValueComponents FormType

TWA 1 fibers/cm3 Fiber.FIBER GLASS (MADE FROMCONTINUOUS FILAMENT,NOT RESPIRABLE) (CAS65997-17-3)

5 mg/m3 Inhalable fraction.



TWA 3 fibers/cm3 Dust.FIBER GLASS (MADE FROMCONTINUOUS FILAMENT,NOT RESPIRABLE) (CAS65997-17-3)

3 fibers/cm3 Fiber.

5 mg/m3 Fiber, total

5 mg/m3 fibers, total dust



If material is ground, cut, or used in any operation which may generate dusts, use appropriate localexhaust ventilation to keep exposures below the recommended exposure limits. If engineeringmeasures are not sufficient to maintain concentrations of dust particulates below the OccupationalExposure Limit (OEL), suitable respiratory protection must be worn. Provide eyewash station andsafety shower.

3 / 7



SDS US

Page 29 of 48


Eye/face protection Avoid contact with eyes. Safety glasses with side-shields.

Skin protection

Hand protection Wear protective gloves.


Respiratory protection Wear a dust mask if dust is generated above exposure limits. Type N95 or better is recommended.





Appearance

Physical state Solid.

Form Powder or shredded fiber glass.

Color White to gray.

Odor None.


pH Not available.

Melting point/freezing point < 1472 °F (< 800 °C)


Not available.

Flash point Not available.

Evaporation rate Not available.




Not available.


Not available.


Not available.


Not available.


Vapor density Not available.


Solubility(ies)



Not available.




Other information

Specific gravity 2.55 - 2.58


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.



Hazardous polymerization does not occur.

4 / 7



SDS US

Page 30 of 48

Conditions to avoid Not available.

Incompatible materials Not available.


Carbon monoxide and carbon dioxide. Ammonia. Small quantities of other undeterminedcompounds may be released.



Inhalation Do not breathe dust. Prolonged inhalation may be harmful. May cause irritation to the respiratorytract. Inhalation may cause sneezing, coughing and irritation to the nose and throat. Highexposure may cause congestion, chest tightness, and difficulty in breathing.

Skin contact Avoid contact with the skin. Dust may cause mechanical irritation to skin. May be slightly irritatingto the skin.

Eye contact Avoid contact with eyes. Dust may cause mechanical irritation to eyes. May be slightly irritating tothe eyes.

Ingestion Exposure by ingestion is unlikely. Ingestion may cause transient irritation to the throat andgastrointestinal tract.


Irritating to eyes, respiratory system and skin. Mechanical irritation to the skin and eyes may resultfrom exposure to dust. Inhalation may cause sneezing, coughing and irritation to the nose andthroat. High exposure may cause congestion, chest tightness, and difficulty in breathing. Ingestionmay cause transient irritation to the throat and gastrointestinal tract. Exposure may temporallyworsen pre-existing respiratory and skin conditions.


Acute toxicity Mechanical irritation to the skin and eyes may result from exposure to dust. Inhalation may causesneezing, coughing and irritation to the nose and throat. High exposure may cause congestion,chest tightness, and difficulty in breathing. Ingestion may cause transient irritation to the throatand gastrointestinal tract.

Skin corrosion/irritation Dust may cause mechanical irritation to skin. May be slightly irritating to the skin.


Dust may cause mechanical irritation to the eyes May be slightly irritating to the eyes.



Skin sensitization Not available.


Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARCMonographs. Overall Evaluation of Carcinogenicity: FIBER GLASS (MADE FROM CONTINUOUSFILAMENT, NOT RESPIRABLE) (CAS 65997-17-3) Group 3 Not classifiable as to carcinogenicity tohumans.



Not available.


Not available.


Chronic effects Exposure may temporally worsen pre-existing respiratory and skin conditions.


Ecotoxicity This material in not expected to be harmful to fish, animals, or plants.








Not available.

5 / 7



SDS US

Page 31 of 48



DOT


IATA


IMDG




US federal regulations All components are on the U.S. EPA TSCA Inventory List.

CERCLA/SARA Hazardous Substances - Not applicable.This product is not known to be a "Hazardous Chemical" as defined by the OSHA HazardCommunication Standard, 29 CFR 1910.1200.


Not regulated.


Not listed.


Not regulated.


Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


Not listed.


No


Not regulated.



Not regulated.


Not regulated.


Not regulated.

US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material isnot known to contain any chemicals currently listed as carcinogens or reproductive toxins.


Not listed.


FIBER GLASS (MADE FROM CONTINUOUS FILAMENT, NOT RESPIRABLE) (CAS 65997-17-3)





6 / 7



SDS US

Page 32 of 48


Not regulated.




















Version # 02

References ACGIHACGIH Documentation of the Threshold Limit Values and Biological Exposure IndicesEPA: AQUIRE databaseHSDB® - Hazardous Substances Data BankIARC Monographs. Overall Evaluation of CarcinogenicityNational Toxicology Program (NTP) Report on CarcinogensNLM: Hazardous Substances Data BaseUS. IARC Monographs on Occupational Exposures to Chemical Agents


7 / 7



SDS US

Page 33 of 48

SAFETY DATA SHEET

1. Identification

Product identifier ACRAGLAS (R) DYE – BROWN (2 GUN ACRAGLAS KIT)


Product code 081-003-002 (BROWN DYE)

Recommended use Epoxy dye.



Manufacturer

BROWNELLS, INC.


Company name

Website

Telephone (641) 623-5401





E-mail

United States

www.brownells.com

Not available.




Category 2CarcinogenicityHealth hazards



Label elements


Hazard statement Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.


Prevention Keep out of reach of children. Obtain special instructions before use. Do not handle until all safetyprecautions have been read and understood. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Wash thoroughly afterhandling. Avoid release to the environment. Wear protective gloves/protective clothing/eyeprotection/face protection. Observe good industrial hygiene practices. Use only with adequateventilation. Wash contaminated clothing before reuse.

Response If on skin: Wash with plenty of soap and water. If exposed or concerned: Get medicaladvice/attention. If inhaled: Remove to fresh air if symptoms occur. If in eyes: Immediately flusheyes with plenty of water for at least 15 minutes. If swallowed, do NOT induce vomiting. Givevictim water or milk. Call a physician or poison control center immediately. Never give anything bymouth to a victim who is unconscious or is having convulsions.

Storage Store in a cool, dry place at an ambient temperature away from incompatible materials. Keep awayfrom heat, sparks and open flame. Store locked up. Store in well-ventilated place.



Not available.

1 / 8

Material name: ACRAGLAS (R) DYE – BROWN (2 GUN ACRAGLAS KIT)


SDS US

Page 34 of 48


Not available.

Supplemental information % of the mixture consists of component(s) of unknown long-term hazards to the aquaticenvironment.


Mixtures


Trade SecretEPOXY RESIN 20 - < 50

13463-67-7TITANIUM DIOXIDE 5 - < 10

Trade SecretALKYL GLYCIDYL ETHER 1 - < 5


1333-86-4CARBON BLACK 1 - < 5

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.


Inhalation Remove to fresh air if symptoms occur. If breathing is difficult, trained personnel should giveoxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratorymedical device. Get medical attention, if needed.

Skin contact Remove and isolate contaminated clothing and shoes. Wash off immediately with soap and plentyof water. If skin irritation or rash occurs: Get medical advice/attention. Get medical attention ifsymptoms occur. For minor skin contact, avoid spreading material on unaffected skin. Washclothing separately before reuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Get medical attention.

Ingestion Do not induce vomiting. Give victim a glass of water or milk. Never give anything by mouth to avictim who is unconscious or is having convulsions. Call a physician or poison control centerimmediately. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.Do not use mouth-to-mouth method if victim ingested the substance. Do not use mouth-to-mouthmethod if victim ingested the substance.


Dust or vapors may be slightly irritation to respiratory tract. Moderate skin irritation. May causeallergic skin reaction to the skin. Dermatitis. Causes serious eye irritation. May cause nausea andvomiting.


Provide general supportive measures and treat symptomatically. In case of shortness of breath,give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet (SDS) to the doctor in attendance. IF exposed orconcerned: Get medical advice/attention. In case of shortness of breath, give oxygen. Keep victimwarm. Keep victim under observation.


Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical. Foam. Water fog.




Closed containers may rupture or explode (due to pressure build-up) when exposed to extremeheat. Irritating and/or toxic gases or fumes may be generated by thermal decomposition orcombustion.




Move containers from fire area if you can do so without risk. Use water to cool exposed containers.Water runoff can cause environmental damage.



Oxides of carbon.

2 / 8



SDS US

Page 35 of 48



Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ensureadequate ventilation. Avoid inhalation of vapor, fumes, dust and/or mist from the spilled material.Avoid contact with skin, eyes, and clothes. Wear appropriate protective equipment and clothingduring clean-up. See Section 8 of the SDS for Personal Protective Equipment. Do not touchdamaged containers or spilled material unless wearing appropriate protective clothing.


ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Preventproduct from entering drains. Prevent entry into waterways, sewer, basements or confined areas.Cover with plastic sheet to prevent spreading.


Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product.Sweep up and shovel into suitable containers for disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.


Environmental precautions Avoid release to the environment. Avoid discharge into drains, water courses or onto the ground.Do not contaminate water. Keep off of soil.


Precautions for safe handling Do not handle until all safety precautions have been read and understood. Obtain specialinstructions before use. Do not handle, store or open near an open flame, sources of heat orsources of ignition. Protect material from direct sunlight. Avoid prolonged exposure. Do not use inareas without adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contactwith eyes, skin, and clothing. Wear personal protective equipment. See Section 8 of the SDS forPersonal Protective Equipment. Wash thoroughly after handling. Handle in accordance with goodindustrial hygiene and safety practice. Remove contaminated clothes and wash separately beforereuse. Avoid release to the environment.


Store indoors in a cool, dry place at an ambient temperature. Keep away from heat, sparks andopen flame. Store locked up. Store in a well-ventilated place. Store in a closed container away fromincompatible materials. See Section 10 of the SDS for incompatible materials. Keep away from food,drink and animal feedingstuffs. Keep out of the reach of children.



U.S. - OSHA


TWA 3.5 mg/m3CARBON BLACK (CAS1333-86-4)



PEL 3.5 mg/m3CARBON BLACK (CAS1333-86-4)

PEL 15 mg/m3 Total dust.TITANIUM DIOXIDE (CAS13463-67-7)



TWA 3 mg/m3 Inhalable fraction.CARBON BLACK (CAS1333-86-4)

TWA 10 mg/m3TITANIUM DIOXIDE (CAS13463-67-7)




3 / 8



SDS US

Page 36 of 48



Ensure adequate ventilation, especially in confined areas. An eye wash and safety shower must beavailable in the immediate work area.


Eye/face protection Avoid contact with eyes. Chemical goggles are recommended.

Skin protection






Always observe good personal hygiene measures, such as washing after handling the material andbefore eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment toremove contaminants. When using, do not eat, drink or smoke.


Appearance


Form Liquid.

Color Brown.

Odor Mild.


pH Not available.



Not available.

Flash point > 212.0 °F (> 100.0 °C)

Evaporation rate Slower than n-Butyl Acetate




Not available.


7.6


Not available.


Not available.


Vapor density Heavier than air.


Solubility(ies)



Not available.




Other information


VOC (Weight %) 0 g/l (Calculated).

4 / 8



SDS US

Page 37 of 48







Incompatible materials Strong Lewis or mineral acids. Strong bases or oxidants. Reaction with amines and mercaptans inlarge amounts or uncontrolled conditions releases considerable heat and may release acrid fumesor smoke.


Carbon oxides.



Inhalation Do not breathe dust. Dust or vapors may be slightly irritation to respiratory tract. Prolongedinhalation may be harmful. May cause cancer by inhalation.

Skin contact Avoid contact with the skin. Moderate skin irritation. This product may cause an allergic skinreaction. Frequent or prolonged contact may defat and dry the skin, leading to discomfort anddermatitis.

Eye contact Avoid contact with eyes. Causes serious eye irritation. Slightly irritating, but does not injure eyetissue.

Ingestion Do not ingest. May cause nausea and vomiting. Small amounts (a tablespoonful) swallowed duringnormal handling operations are not likely to cause injury; swallowing amounts larger than that maycause injury.


Dust or vapors may be slightly irritation to respiratory tract. Moderate skin irritation. May causeallergic skin reaction to the skin. Dermatitis. Causes serious eye irritation. May cause nausea andvomiting.


Acute toxicity Inhalation of vapors or dust may cause slight irritation to the respiratory tract. This substance maycause moderate skin irritation. May cause allergic skin reaction. Eye contact causes slight irritationwithout damage to eye tissue. May cause nausea and vomiting. Swallowing small amounts (atablespoonful) during normal use of product will not likely cause injury. Swallowing larger amountsmay cause injury.


CARBON BLACK (CAS 1333-86-4)

LD50 Rat

Oral

Acute

> 8000 mg/kg


Skin corrosion/irritation Irritating to skin.


Causes serious eye irritation.



Skin sensitization May cause an allergic skin reaction. Frequent or prolonged contact may defat and dry the skin,leading to discomfort and dermatitis.


Carcinogenicity Suspected of causing cancer.


CARBON BLACK (CAS 1333-86-4) 2B Possibly carcinogenic to humans.

TITANIUM DIOXIDE (CAS 13463-67-7) 2B Possibly carcinogenic to humans.



Not available.

5 / 8



SDS US

Page 38 of 48


Not available.


Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation maybe harmful. Prolonged exposure may cause chronic effects. Chronic exposure may causedermatitis. Preexisting dermatological disorders may be aggravated by exposure to hazardouscomponents.


Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.

Persistence and degradability The product is not readily biodegradable (in test environment).

Bioaccumulative potential The potential of bioconcentration is moderate.

Mobility in soil No data available.





Not available.



DOT


IATA

UN3082UN number

Environmentally Hazardous Substance, Liquid, n.o.s. (Bisphenol-A Epoxy Resin)UN proper shipping name

9Class


-Subsidiary risk

IIIPacking group

Yes.Environmental hazards


Forbidden.Passenger and cargoaircraft

Other information

Forbidden.Cargo aircraft only

IMDG

UN3082UN number

Environmentally Hazardous Substance, Liquid, n.o.s. (Bisphenol-A Epoxy Resin), MARINEPOLLUTANT

UN proper shipping name

9Class


-Subsidiary risk

IIIPacking group

YesMarine pollutant


Not available.EmS



6 / 8



SDS US

Page 39 of 48

IATA; IMDG

Marine pollutant

General information IMDG Regulated Marine Pollutant.


US federal regulations CERCLA/SARA Hazardous Substances - Not applicable.

All components are on the U.S. EPA TSCA Inventory List.This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200.


Not regulated.


Not listed.


Not regulated.


Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


Not listed.


No


Not regulated.



Not regulated.


Not regulated.


Not regulated.

US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer.

7 / 8



SDS US

Page 40 of 48


Not listed.



TITANIUM DIOXIDE (CAS 13463-67-7)








Not regulated.


WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

CARBON BLACK (CAS 1333-86-4) Listed: February 21, 2003

TITANIUM DIOXIDE (CAS 13463-67-7) Listed: September 2, 2011



NoAustralia Australian Inventory of Chemical Substances (AICS)

NoCanada Domestic Substances List (DSL)


NoChina Inventory of Existing Chemical Substances in China (IECSC)



NoJapan Inventory of Existing and New Chemical Substances (ENCS)



NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)






Version # 02

References ACGIHEPA: AQUIRE databaseNLM: Hazardous Substances Data BaseUS. IARC Monographs on Occupational Exposures to Chemical Agents


Revision Information Product and Company Identification: Alternate Trade Names

8 / 8



SDS US

Page 41 of 48

SAFETY DATA SHEET

1. Identification

Product identifier ACRAGLAS (R) DYE – BLACK (2-GUN ACRAGLAS KIT)


Product code 081-003-002 (BLACK DYE)

Recommended use Epoxy dye.



Manufacturer

BROWNELLS, INC.


Company name

Website

Telephone (641) 623-5401





E-mail

United States

www.brownells.com

Not available.




Category 2ASerious eye damage/eye irritationHealth hazards

Category 2Carcinogenicity



Label elements

Signal word Warning

Hazard statement Causes mild skin irritation. Causes serious eye irritation. Causes damage to organs () throughprolonged or repeated exposure. Suspected of causing cancer. Toxic to aquatic life.


Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drinkor smoke when using this product. Wear protective gloves/protective clothing/eye protection/faceprotection. Keep out of reach of children. Avoid release to the environment.

Response If inhaled: Remove to fresh air if symptoms occur. If in eyes: Rinse cautiously with water forseveral minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin:Wash with plenty of soap and water. If eye or skin irritation occurs/persists: Get medicaladvice/attention. IF exposed or concerned: Get medical advice/attention. If swallowed, do NOTinduce vomiting. Give victim water or milk. Call a physician or poison control center immediately.Never give anything by mouth to a victim who is unconscious or is having convulsions.

Storage Store in a cool, dry place out of direct sunlight. Keep away from heat, sparks and open flame.Store in a well-ventilated place. Store in a closed container away from incompatible materials.Store locked up. Keep out of reach of children.


1 / 7

Material name: ACRAGLAS (R) DYE – BLACK (2-GUN ACRAGLAS KIT)

1626 Version #: 01 Issue date: 02-10-2015

SDS US

Page 42 of 48


Not available.


Not available.



Mixtures



1333-86-4CARBON BLACK 10 - < 20

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.


Inhalation Remove to fresh air if symptoms occur. Get medical attention if symptoms persist. Do not usemouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid ofa pocket mask equipped with a one-way valve or other proper respiratory medical device.

Skin contact Remove and isolate contaminated clothing and shoes. Wash off immediately with soap and plentyof water. Get medical attention if irritation develops or persists. For minor skin contact, avoidspreading material on unaffected skin. Wash contaminated clothing before reuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart. Removecontact lenses, if present and easy to do. Continue rinsing. Get medical attention.

Ingestion If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Never give anything bymouth to a victim who is unconscious or is having convulsions. Call a physician or poison controlcenter immediately. If vomiting occurs, keep head low so that stomach content doesn't get into thelungs.


Discomfort in the chest. Shortness of breath. Coughing. Irritant effects. Conjunctiva.


Provide general supportive measures and treat symptomatically. Keep victim warm and underobservation. Symptoms may be delayed.

General information If exposed or concerned: Get medical advice/attention. Keep victim warm and under observation.Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet (SDS) to the doctor in attendance.


Suitable extinguishing media Alcohol foam. Carbon dioxide (CO2). Dry chemical. Foam. Water fog.




Closed containers may rupture or explode (due to pressure build-up) when exposed to extremeheat. Irritating and/or toxic gases or fumes may be generated by thermal decomposition orcombustion.




Move containers from fire area if you can do so without risk. Use water to cool exposed containers.Water runoff can cause environmental damage.



Oxides of carbon.



Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ensureadequate ventilation. Avoid inhalation of vapor, fumes, dust and/or mist from the spilled material.Avoid contact with skin, eyes, and clothes. Wear appropriate protective equipment and clothingduring clean-up. See Section 8 of the SDS for Personal Protective Equipment. Do not touchdamaged containers or spilled material unless wearing appropriate protective clothing. Ensureadequate ventilation.

2 / 7



SDS US

Page 43 of 48


ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Preventproduct from entering drains. Prevent entry into waterways, sewer, basements or confined areas.Cover with plastic sheet to prevent spreading.


Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product.Sweep up and shovel into suitable containers for disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.


Environmental precautions Avoid release to the environment. Avoid discharge into drains, water courses or onto the ground.Do not contaminate water.


Precautions for safe handling Do not handle until all safety precautions have been read and understood. Do not handle, store oropen near an open flame, sources of heat or sources of ignition. Protect material from directsunlight. Observe good industrial hygiene practices. Avoid prolonged exposure. Do not use in areaswithout adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact witheyes, skin, and clothing. Wear personal protective equipment. See Section 8 of the SDS forPersonal Protective Equipment. Wash thoroughly after handling. Avoid release to the environment.


Store in a cool, dry place out of direct sunlight. Keep away from heat, sparks and open flame. Storein a well-ventilated place. Store in a closed container away from incompatible materials. SeeSection 10 of the SDS for incompatible materials. Store locked up. Keep out of the reach ofchildren. Keep away from food, drink and animal feedingstuffs.



U.S. - OSHA





PEL 3.5 mg/m3CARBON BLACK (CAS1333-86-4)



TWA 3 mg/m3 Inhalable fraction.CARBON BLACK (CAS1333-86-4)






Ensure adequate ventilation, especially in confined areas. An eye wash and safety shower must beavailable in the immediate work area.


Eye/face protection Do not get in eyes. Wear chemical goggles.

Skin protection




3 / 7



SDS US

Page 44 of 48

Thermal hazards Wear appropriate thermal protective clothing, when necessary.


Always observe good personal hygiene measures, such as washing after handling the material andbefore eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment toremove contaminants. When using, do not eat, drink or smoke.


Appearance


Form Liquid.

Color Black.

Odor Not available.


pH Not available.



Not available.

Flash point 212.0 °F (100.0 °C)

Evaporation rate Slower than n-Butyl Acetate




Not available.


Not available.


Not available.


Not available.


Vapor density Heavier than air


Solubility(ies)

Solubility (water) Negligible.


Not available.




Other information


VOC (Weight %) < 10 g/l (Calculated).






Conditions to avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatiblematerials.

Incompatible materials Strong bases or oxidants. Reaction with Isocyanates in large amounts or under uncontrolledconditions may produce extreme heat and acrid or noxious fumes.


Carbon oxides.

4 / 7



SDS US

Page 45 of 48



Inhalation Avoid breathing dust/fume/gas/mist/vapors/spray. Dust or vapors may be slightly irritation torespiratory tract. May cause cancer by inhalation.

Skin contact Avoid contact with the skin. Prolonged or repeated contact may cause irritation. Frequent orprolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

Eye contact Do not get this material in contact with eyes. Slightly irritating, but does not injure eye tissue.

Ingestion Do not ingest. May cause nausea and vomiting. Small amounts (a tablespoonful) swallowed duringnormal handling operations are not likely to cause injury; swallowing amounts larger than that maycause injury.


Discomfort in the chest. Shortness of breath Coughing. Irritant effects.


Acute toxicity Eye contact causes slight irritation without damage to eye tissue. Inhalation of vapors or dust maycause slight irritation to the respiratory tract. May cause nausea and vomiting. Swallowing smallamounts (a tablespoonful) during normal use of product will not likely cause injury. Swallowinglarger amounts may cause injury.



LD50 Rat

Oral

Acute

> 8000 mg/kg


Skin corrosion/irritation Causes skin irritation.


Slightly irritating to the eyes.



Skin sensitization Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.


Carcinogenicity Suspected of causing cancer.


CARBON BLACK (CAS 1333-86-4) 2B Possibly carcinogenic to humans.



Not available.


Not available.


Chronic effects Prolonged exposure may cause chronic effects. Causes damage to organs through prolonged orrepeated exposure. Conjunctiva.


Ecotoxicity Not available.







5 / 7



SDS US

Page 46 of 48


Not available.



DOT


IATA


IMDG




US federal regulations All components are on the U.S. EPA TSCA Inventory List.

CERCLA/SARA Hazardous Substances - Not applicable.This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200. This product is not known to be a "Hazardous Chemical" as defined by theOSHA Hazard Communication Standard, 29 CFR 1910.1200.


Not regulated.


Not listed.


Not regulated.


Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


Not listed.


No


Not regulated.



Not regulated.


Not regulated.


Not regulated.

US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer.


Not listed.





6 / 7



SDS US

Page 47 of 48




Not regulated.


WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

CARBON BLACK (CAS 1333-86-4) Listed: February 21, 2003

















Version # 01

References ACGIHEPA: AQUIRE databaseUS. IARC Monographs on Occupational Exposures to Chemical Agents


Revision Information Product and Company Identification: Alternate Trade Names

7 / 7



SDS US

Page 48 of 48

Documents

Page 1 of 48 SAFETY DATA SHEET - Brownells...Suitable extinguishing media Alcohol foam, carbon dioxide (CO2), dry chemical, foam, or water fog. Unsuitable extinguishing media Do not