P1097, Phosphoric Acid, 85 Percent, FCCPhosphoric Acid 7664-38-2 85-88 Water 7732-18-5 12-15 4. FIRST AID MEASURES First aid measures General Advice: National Capital Poison Center

Not appropriate for regulatory submission. Please visit www.spectrumchemical.com or contact Tech Services for the most up‐to‐date information contained in this information package.

Spectrum Chemical Mfg Corp 769 Jersey Avenue New Brunswick, NJ 08901 Phone 732.214.1300

Ver4.05 18.December.2019

Scientific Documentation P1097, Phosphoric Acid, 85 Percent, FCC

Dear Customer,

Thank you for your interest in Spectrum’s quality products and services.

Spectrum has been proudly serving the scientific community for over 45 years. It is our mission to manufacture and distribute fine chemicals and laboratory products with Quality and delivery you can count on every time.

To accomplish our mission, Spectrum utilizes our sourcing leverage and supplier qualification expertise in offering one of the industry’s most comprehensive line of fine chemical products under one brand, in packaging configurations designed to meet your research and production requirements. Our product grades include: USP, NF, BP, EP, JP, FCC, ACS, KSA, Reagent grade, as well as DEA controlled substances. We operate facilities in the United States on the East Coast, West Coast, as well as in Shanghai, China in order to provide the best logistical support for our customers.

At Spectrum, Quality is priority number one. Suppliers with the best qualifications are preferred and we employ full-functioning in-house analytical laboratories at each of our facilities. Our facilities and systems are USFDA registered and ISO certified. We frequently host customer audits and cherish opportunities for improvements. Quality is engrained into our culture. Quality is priority number one.

In the following pages, we have designed and prepared documented scientific information to aid you in your initial qualification or your continual use of our products. Please do not hesitate to contact us if further information or the most up-to-date documentation is desired from any of the covered areas.

We appreciate your business and we look forward to hearing from you.

Sincerely,

Michael Dang Director, Quality Systems & GMP [email protected]

8 Dec

P1097, Phosphoric Acid, 85 Percent, FCC

Table of Contents

Product Specification

Safety Data Sheet (SDS)

Certification of Quality Management System (QMS)

Certification of current Good Manufacturing Practices (cGMP)

Product BSE/TSE Statement

Product Allergen Statement

Product Certificate of Analysis Sample(s)

General Label Information – Sample Label

General Lot Numbering System Guidance

Stability – Shelf Life Guidance

Halal Certificate

Specification for Phosphoric Acid, 85 Percent, FCC(P1097)

Item Number P1097

Item Phosphoric Acid, 85 Percent, FCC

CAS Number 7664-38-2

Molecular Formula H3PO4

Molecular Weight 98.00

MDL Number

Synonyms Orthophosphoric Acid

Test SpecificationMin Max

ASSAY 85.0 %

ARSENIC (As) 3 mg/kg

CADMIUM (Cd) 3 mg/kg

FLUORIDE 10 mg/kg

LEAD (Pb) 3 mg/kg

IDENTIFICATION POSITIVE FOR PHOSPHATE

CERTIFIED HALAL

EXPIRATION DATE

DATE OF MANUFACTURE

APPEARANCE

SAFETY DATA SHEETPreparation Date: 05/29/2015 Revision Date: 06/20/2018 Revision Number: G2

1. IDENTIFICATIONProduct identifier

Product code: P1097Product Name: PHOSPHORIC ACID, 85 PERCENT, FCC

Other means of identificationSynonyms: Orthophosphoric acid, 85%CAS #: 7664-38-2RTECS # TB6300000CI#: Not available

Recommended use of the chemical and restrictions on useRecommended use: Acidifying agent.Uses advised against No information available

Supplier: Spectrum Chemical Mfg. Corp14422 South San Pedro St.Gardena, CA 90248(310) 516-8000

Order Online At: https://www.spectrumchemical.comEmergency telephone number Chemtrec 1-800-424-9300Contact Person: Martin LaBenz (West Coast)Contact Person: Ibad Tirmiz (East Coast)

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous according to the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Considered a dangerous substance or mixture according to the Globally Harmonized System (GHS)

Acute toxicity - Oral Category 4Skin corrosion/irritation Category 1Serious eye damage/eye irritation Category 1

Label elements

Corrosive to metals Category 1

Danger

Hazard statementsHarmful if swallowedCauses severe skin burns and eye damageMay be corrosive to metals

Product code: P1097 Product name: PHOSPHORIC ACID,85 PERCENT, FCC

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Hazards not otherwise classified (HNOC)Not Applicable

Other hazards Not available

Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handlingDo not eat, drink or smoke when using this productDo not breathe dust/fume/gas/mist/vapors/sprayWear protective gloves/protective clothing/eye protection/face protectionKeep only in original container

Precautionary Statements - ResponseImmediately call a POISON CENTER or doctor/physicianAbsorb spillage to prevent material damageIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerWash contaminated clothing before reuseIF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER ordoctor/physician.IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellRinse mouthDo NOT induce vomiting

Precautionary Statements - StorageStore locked upStore in corrosive resistant/ .? container with a resistant inner liner

Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Weight %Phosphoric Acid 7664-38-2 85-88

Water 7732-18-5 12-15

4. FIRST AID MEASURES

First aid measures

General Advice: National Capital Poison Center in the United States can provide assistance if youhave a poison emergency and need to talk to a poison specialist. Call


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1-800-222-1222.

Skin Contact: Wash off immediately with soap and plenty of water. Continue flushing with plenty of waterfor at least 15 minutes. Immediate medical attention is required. Call a physician or PoisonControl Centre immediately.

Eye Contact: Flush eyes with water for 15 minutes. Immediate medical attention is required. Call aphysician immediately.

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, giveoxygen. WARNING! It may be hazardous to the person providing aid to givemouth-to-mouth resuscitation when the inhaled or ingested material is toxic, infectious orcorrosive. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled thesubstance; induce artificial respiration with the aid of a pocket mask equipped with aone-way valve or other proper respiratory medical device. Get medical attention.

Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Immediate medical attention is required. Call a physician or PoisonControl Center immediately.

Most important symptoms and effects, both acute and delayed

Symptoms Severe skin and eye irritation or burnsSkin contact may result in redness, pain, inflammation, itching, scalingInflammation of the eye is characterized by redness, watering and itchingHarmful if swallowedCoughing and wheezingChoking sensationDyspnea (Shortness of breath and difficulty breathing)

Indication of any immediate medical attention and special treatment needed

Notes to Physician: Treat symptomatically.

Protection of first-aidersFirst-Aid Providers: Avoid exposure to blood or body fluids. Wear gloves and other necessary protective clothing. Dispose ofcontaminated clothing and equipment as bio-hazardous waste.

5. FIRE-FIGHTING MEASURES

Extinguishing Media Suitable Extinguishing Media: The product is not flammable. If it is involved in a fire,

extinguish the fire using an agent suitable for the type ofsurrounding fire.

Unsuitable Extinguishing Media: No information available.

Specific hazards arising from the chemical

Hazardous Combustion Products: Phosphorus oxides

Hazardous Combustion Products: No information available.

Specific hazards: Contact with metals may evolve flammable hydrogen gas.Formation of flammable gases with aldehydes, cyanides,mercaptins, and sulfides.

Special Protective Actions for Firefighters

Specific Methods: No information available.


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Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear

7. HANDLING AND STORAGE

Precautions for safe handling

Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Keep away from incompatible materials.

Safe Handling AdviceWear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spraymist. Do not ingest. Handle in accordance with good industrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities

Technical Measures/Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the originalcontainer. May corrode metallic surfaces. Do not store in uncoated metallic containers. Store away fromincompatible materials. Store in a segregated and approved area.

Incompatible Materials:Oxidizing agentsCombustible materialsMetalsAlkalisBases

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters

National occupational exposure limits

United States

Components CAS-No. OSHA NIOSH ACGIH AIHA WEELPhosphoric Acid 7664-38-2 1 mg/m3 TWA 1 mg/m3 TWA

3 mg/m3 STEL3 mg/m3 STEL1 mg/m3 TWA

None

Water 7732-18-5 None None None None

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions: Keep people away from and upwind of spill/leak. Ensure adequate ventilation. Do not touchdamaged containers or spilled material unless wearing appropriate protective clothing.Avoid contact with skin, eyes and clothing. Use personal protective equipment.

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains.Prevent entry into waterways, sewers, basements or confined areas.

Methods and material for containment and cleaning up

Methods for containment Stop leak if you can do it without risk.

Methods for cleaning up


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Neutralize with Sodium carbonate or Sodium bicarbonate. Dilute with water.Absorb spill with inert material (e.g. vermiculite, dry sand or earth), then place in asuitable chemical waste container. Clean contaminated surface thoroughly.

Canada

Components CAS-No. Canada - Alberta Canada - BritishColumbia

Canada - Ontario Canada - Quebec

Phosphoric Acid 7664-38-2 1 mg/m3 TWA3 mg/m3 STEL

1 mg/m3 TWA3 mg/m3 STEL

1 mg/m3 TWA3 mg/m3 STEL

1 mg/m3 TWAEV3 mg/m3 STEV

Water 7732-18-5 None None None None

Australia and Mexico

Components CAS-No. Australia MexicoPhosphoric Acid 7664-38-2 3 mg/m3 STEL

1 mg/m3 TWA1 mg/m3 TWA3 mg/m3 STEL

Water 7732-18-5 None None

Appropriate engineering controls

Engineering measures to reduce exposure: Provide exhaust ventilation or other engineering controls tokeep the airborne concentrations of vapors and mist belowtheir respective threshold limit value.

Individual protection measures, such as personal protective equipment

Personal Protective Equipment

Eye protection: Face-shield

Skin and body protection: Chemical resistant protective suitGlovesBoots

Respiratory protection: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.

Hygiene measures: Avoid contact with skin, eyes and clothing. When using, do not eat, drink orsmoke. Wash hands before breaks and immediately after handling the product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state:Liquid

Appearance:Syrupy. Viscous.

Color:Clear. Colorless.

Odor:Odorless.

TasteAcid.

Formula:H3PO4

Molecular/Formula weight:98.00

Flammability:No information available

Flashpoint (°C/°F):No information available.

Flash Point Tested according to:Not available

Autoignition Temperature (°C/°F):No information available

Lower Explosion Limit (%):No information available

Upper Explosion Limit (%):No information available

Melting point/range(°C/°F):21°C/ 69.8°F

Decomposition temperature(°C/°F):No information available

Boiling point/range(°C/°F):158°C/ 316°F

Bulk density:No information available

Density (g/cm3):No information available

Specific gravity:1.685

pH:No information available

Vapor pressure @ 20°C (kPa):0.3


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10. STABILITY AND REACTIVITYReactivityReactive with oxidizing agents, combustible materials, metals, alkalisEvolves flammable hydrogen gas on contact with metalsIncompatible with sodium tetrahydroborate producing a violent exothermic reaction.Heat generated with: alcohols, glycols,aldehydes, amides, amines, azo-compounds, carbamates, caustics, esters, ketones, phenols and cresols, organophosphates,epoxides, combustible materials, unsaturated halides, organic peroxides.Formation of flammable gases, with aldehydes, cyanides,mercaptins, and sulfides.Formation of toxic fumes with cyanides, fluorides, halogenated organics, sulfides, and organicperoxides.Do not mix with solutions containing bleach or ammonia.Incompatible with nitromethane, chlorides + staiinless steel.

Chemical stability

Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: Hazardous polymerization does not occur

Conditions to avoid: Incompatible materials.

Incompatible Materials: Oxidizing agentsCombustible materialsMetalsAlkalisBases

Hazardous decompositionproducts:

Phosphorus oxides.

Other InformationCorrosivity: Extremely corrosive in presence of copper

Extremely corrosive in the presence of stainless steel (316)Extremely corrosive in the presence of stainless steel (304)Highly corrosive in presence of aluminumNon-corrosive in the presence of glass

Special Remarks on Corrosivity: Minor corrosive effect on bronze Severe corrosive effect on brass Corrosive toferrous metals and alloys

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Principal Routes of Exposure:Skin. Eyes. Inhalation. Ingestion.

Acute Toxicity

Evaporation rate:No information available

Vapor density:3.4

VOC content (g/L):No information available

Odor threshold (ppm):No information available

Partition coefficient(n-octanol/water):No information available

Viscosity:No information available

Miscibility:No information available

Solubility:Easily soluble in hot waterSoluble in cold water


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Component Information

Phosphoric AcidCAS-No. 7664-38-2

LD50/oral/rat = 1530 mg/kg Oral LD50 RatLD50/oral/mouse = No information availableLD50/dermal/rabbit = 2730 mg/kg Dermal LD50 Rabbit; 2740 mg/kg Dermal LD50 RabbitLD50/dermal/rat = No information availableLC50/inhalation/rat = >850 mg/m3 Inhalation LC50 Rat 1 hLC50/inhalation/mouse = No information availableOther LD50 or LC50information = No information available

WaterCAS-No. 7732-18-5

LD50/oral/rat = > 90 mL/kg Oral LD50 RatLD50/oral/mouse = No information availableLD50/dermal/rabbit = No information availableLD50/dermal/rat = No information availableLC50/inhalation/rat = No information availableLC50/inhalation/mouse = No information availableOther LD50 or LC50information = No information available

Product Information

LD50/oral/rat =VALUE- Acute Tox Oral = No information available

LD50/oral/mouse =Value - Acute Tox Oral = No information available

LD50/dermal/rabbitVALUE-Acute Tox Dermal = No information available

LD50/dermal/ratVALUE -Acute Tox Dermal = No information available

LC50/inhalation/ratVALUE-Vapor = No information availableVALUE-Gas = No information availableVALUE-Dust/Mist = No information available

LC50/Inhalation/mouseVALUE-Vapor = No information availableVALUE - Gas = No information availableVALUE - Dust/Mist = No information available

Symptoms

Skin Contact: Corrosive. Contact causes severe skin irritation and possible burns. May affectbehavior (somonlence or excitment) if absorbed through skin.

Eye Contact: Corrosive. Liquid or vapor causes severe eye irritation and can cause severe eyeburns leading to permanent corneal damage or chemical conjunctivtis.

Inhalation Causes irritation or possible burns of the respiratory tract and mucous membraneswith sore throat, coughing, shortness of breath and pulmonary edema. It may alsocause ulceration and perforation of the nasal septum.


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Ingestion Harmful if swallowed. Causes irritation of the digestive tract (mouth, throat(oropharyngeal mucosa), esophagus, stomach). Can cause corrosion (burns) andpermanent tissue destruction of digestive tract. Causes severe abdominal pain,nausea, vomiting (sometimes bloody), diarrhea (sometimes watery and bloody),gastrointestinal hemmorrhaging, hypotension, and shock. May affect behavior(seizures, coma) and urinary system (scanty urine), liver (hepatocellular damage,hepatic enzymes increased), blood (blood dyscrasia). May also cause aspirationpneumonitis, acute pulmonary edema, Hypocalcemia, Hyperphosphatemia orHypophosphatemia, Hypomagnesemia, and acidosis.

Aspiration hazard No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chronic Toxicity Skin: Prolonged or repeated skin contact may cause drying and cracking of theskin, which can lead to secondary infections or dermatitis, an allergicreaction.Ingestion: Prolonged or repeated ingestion will have similiar effects asacute ingestion. It may also affect the brain. Prolonged or repeated eye contactcan cause conjunctivitis. Repeated exposure may cause bronchitis to develop withcough, phlegm, and /or shortness of breath.

Sensitization: No information available.

Mutagenic Effects: No information available

Carcinogenic effects: Not considered carcinogenic.

Components CAS-No. IARC ACGIH -Carcinogens

NTP OSHA HCS -Carcinogens

Australia -Notifiable

CarcinogenicSubstances

Australia -Prohibited

CarcinogenicSubstances

Phosphoric Acid 7664-38-2 Not listed Not listed Not listed Not listed Not listed Not listedWater 7732-18-5 Not listed Not listed Not listed Not listed Not listed Not listed

ACGIH (American Conference of Governmental Industrial Hygienists)

IARC (International Agency for Research on Cancer)

NTP (National Toxicology Program)

OSHA (Occupational Safety and Health Administration of the US Department of Labor)

Reproductive toxicity No data is available

Reproductive Effects: No information availableDevelopmental Effects: No information availableTeratogenic Effects: No information available

Specific Target Organ Toxicity

STOT - single exposure No information available.STOT - repeated exposure No information available.Target Organs: Lungs. Respiratory system. Skin. Eyes.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Ecotoxicity effects: Aquatic environment.


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Phosphoric Acid - 7664-38-2Freshwater Fish Species Data: 3 - 3.5 mg/L LC50 Gambusia affinis 96 h 1Water Flea Data: 4.6 mg/L EC50 Daphnia magna 12 h

Persistence and degradability: No information available

Bioaccumulative potential: No information available.

Mobility: No information available.

13. DISPOSAL CONSIDERATIONS

Disposal Methods

Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.

Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal

Components CAS-No. RCRA - F SeriesWastes

RCRA - K SeriesWastes

RCRA - P SeriesWastes

RCRA - U SeriesWastes

Phosphoric Acid 7664-38-2 None None None NoneWater 7732-18-5 None None None None

14. TRANSPORT INFORMATION

DOTUN-No: UN1805Proper Shipping Name: Phosphoric acid solutionHazard Class: 8Subsidiary Class No information availablePacking group: IIIEmergency Response GuideNumber

154

Marine Pollutant No data availableDOT RQ (lbs): No information availableSpecial Provisions A7, IB3, N34, T4, TP1Symbol(s): [DOT]: (R5) - Identifies a material that is a hazardous substance that has a

reportable quantity (RQ) of 5000 pounds (2270 Kilograms).Description: UN1805, Phosphoric acid solution, 8, III

TDG (Canada)UN-No: UN1805Proper Shipping Name: Phosphoric acid, solutionHazard Class: 8Subsidiary Risk: No information availablePacking Group: IIIMarine Pollutant No Information availableDescription: UN1805, Phosphoric acid, solution, 8, III

ADRUN-No: UN1805Proper Shipping Name: Phosphoric acid, solutionHazard Class: 8Packing Group: III


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Subsidiary Risk: No information availableDescription: UN1805, Phosphoric acid, solution, 8, III

IMO / IMDGUN-No: UN1805Proper Shipping Name: Phosphoric acid solutionHazard Class: 8Subsidiary Risk: No information availablePacking Group: IIIMarine Pollutant No information availableEMS: F-ASpecial Provisions 223Description UN1805, Phosphoric acid solution, 8, III

RIDUN-No: UN1805Proper Shipping Name: Phosphoric acid, solutionHazard Class: 8Subsidiary Risk: No information availablePacking Group: IIIDescription: UN1805, Phosphoric acid, solution, 8, III

ICAOUN-No: UN1805Proper Shipping Name: Phosphoric acid, solutionHazard Class: 8Subsidiary Risk: No information availablePacking Group: IIIDescription: UN1805, Phosphoric acid, solution, 8, IIISpecial Provisions A3

IATAUN-No: UN1805Proper Shipping Name: Phosphoric acid, solutionHazard Class: 8Subsidiary Risk: No information availablePacking Group: IIIERG Code: 8LSpecial Provisions No information availableDescription: UN1805, Phosphoric acid, solution, 8, III

15. REGULATORY INFORMATION

International Inventories

Components CAS-No. U.S. TSCA KOREA KECL Philippines(PICCS)

Japan ENCS CHINA Australia(AICS)

EINECS-No.

Phosphoric Acid 7664-38-2 PresentACTIVE

PresentKE-27427

Present Present(1)-422

Present Present Present231-633-2

Water 7732-18-5 Present(ACTIVE)

PresentKE-35400

Present Not present Present Present Present231-791-2

U.S. Regulations

Phosphoric AcidMassachusetts RTK: PresentNew Jersey RTK Hazardous Substance List: 1516New Jersey - Discharge Prevention - List of Hazardous Substances: PresentPennsylvania RTK: Environmental hazard


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Pennsylvania RTK - Environmental Hazard List PresentMinnesota - Hazardous Substance List: PresentNew York Release Reporting - List of Hazardous Substances:5000 lb RQ100 lb RQLouisana Reportable Quantity List for Pollutants: ListedCalifornia Directors List of Hazardous Substances: PresentFDA - Food Additives Generally Recognized as Safe (GRAS): 21 CFR 182.1073

FDA - 21 CFR - Total Food Additives 133.123, 133.124, 133.129, 133.169, 133.173, 133.178, 133.179, 163.110, 163.111,163.112, 175.300, 177.2260, 178.1010, 178.3520, 182.1073, 73.275, 73.85

California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.

Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

Components CAS-No. Carcinogen Developmental Toxicity MaleReproductiveToxicity

FemaleReproductiveToxicity:

Phosphoric Acid 7664-38-2 Not Listed Not Listed Not Listed Not ListedWater 7732-18-5 Not Listed Not Listed Not Listed Not Listed

CERCLA/SARA

Components CAS-No. CERCLA -Hazardous

Substances andtheir Reportable

Quantities

Section 302ExtremelyHazardousSubstancesand TPQs

Section 302ExtremelyHazardous

Substances andRQs

Section 313 -Chemical Category

Section 313 -Reporting

de minimis

Phosphoric Acid 7664-38-2 5000 lb final RQ2270 kg final RQ

None None None None

Water 7732-18-5 None None None None None

U.S. TSCA

Components CAS-No. TSCA Section 5(a)2 - ChemicalsWith Significant New Use Rules(SNURS)

TSCA 8(d) -Health and SafetyReporting

Phosphoric Acid 7664-38-2 Not Applicable Not ApplicableWater 7732-18-5 Not Applicable Not Applicable

Canada

WHIMIS 2015 - GHS Classifications

WHMIS 2015 Hazard ClassificationInformation:

.

Component WHMIS 2015 Hazard ClassificationPhosphoric Acid 7664-38-2 ( 85-88 )

Corrosive to Metals - Category 1: H290 May be corrosive tometals. (potentially corrosive to metals; the supplier should becontacted for more information); Health Hazard Not OtherwiseClassified - Category 1: Causes severe damage to the respiratorytract; Skin corrosion/irritation - Category 1: H314 Causes severeskin burns and eye damage.; Serious Eye Damage/Eye Irritation -Category 1: H318 Causes serious eye damage.

Water 7732-18-5 ( 12-15 )

Not a dangerous product according to HPR classification criteria

Canada Hazardous Products Regulation This product has been classified according to the hazard criteria of the HPR (HazardousProducts Regulation) and the SDS contains all of the information required by the HPR


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WHMIS 1988 Hazard Class

E Corrosive material

Components WHMIS 1988Phosphoric Acid E including 5-35% in aqueous solution, 35%, aqueous

solution 35-80%, 85% or lessWater Uncontrolled product according to WHMIS classification

criteria

Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDScontains all of the information required by the CPR.

Components WHMIS Ingredient Disclosure List -Phosphoric Acid 1 %

Inventory

Components CAS-No. Canada (DSL) Canada (NDSL)Phosphoric Acid 7664-38-2 Present Not ListedWater 7732-18-5 Present Not Listed

Components CAS-No. CEPA Schedule I - Toxic SubstancesPhosphoric Acid 7664-38-2 Not listedWater 7732-18-5 Not listedComponents CAS-No. CEPA - 2010 Greenhouse Gases Subject

to Mandatory ReportingPhosphoric Acid 7664-38-2 Not listedWater 7732-18-5 Not listed

EU Classification

EU GHS - SV - CLP 1272/2008

Components CAS-No. EU GHS - SV - CLP (1272/2008)Phosphoric Acid 7664-38-2 Skin corrosion/irritation - Skin Corr.

1B: H314 Causes severe skin burnsand eye damage. (C >= 25

%)015-011-00-6Skin corrosion/irritation - Skin Corr.1B: H314 Causes severe skin burnsand eye damage. (C >= 25 %); Skin

corrosion/irritation - Skin Irrit. 2: H315Causes skin irritation. (10 % <= C <25%); Serious Eye Damage/Eye Irritation- Eye Irrit. 2: H319 Causes serious eye

irritation. (10 % <= C <25%)015-011-00-6

Water 7732-18-5

EU - CLP (1272/2008)

R-phrase(s)R34 - Causes burns.

S -phrase(s)S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).S 1/2 - Keep locked up and out of the reach of children.

Components CAS-No. Classification ConcentrationLimits:

Safety Phrases

Phosphoric Acid 7664-38-2 C; R34 10%<=C<25% Xi; S(1/2) S26 S45


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R36/3825%<=C C; R34

Water 7732-18-5 No informationThe product is classified in accordance with Annex VI to Directive 67/548/EEC

Indication of danger:C - Corrosive.

16. OTHER INFORMATION

Preparation Date: 05/29/2015Revision Date: 06/20/2018Prepared by: Sonia Owen

Disclaimer: All chemicals may pose unknown hazards and should be used with caution. ThisSafety Data Sheet (SDS) applies only to the material as packaged. If this productis combined with other materials, deteriorates, or becomes contaminated, it maypose hazards not mentioned in this SDS. The physical properties reported in thisSDS are obtained from the literature and do not constitute product specifications.Information contained herein does not constitute a warranty, whether expressed orimplied, as to the safety, merchantability or fitness of the goods for a particularpurpose. Spectrum Chemicals & Laboratory Products, Inc. assumes noresponsibility for results obtained or for incidental or consequential damages,including lost profits, arising from the use of these data. No warranty againstinfringement of any patent, copyright or trademark is made or implied. It shall bethe user's responsibility to develop proper methods of handling and personalprotection based on the actual conditions of use. While this SDS is based ontechnical data judged to be reliable, Spectrum assumes no responsibility for thecompleteness or accuracy of the information contained herein.

End of Safety Data Sheet


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C O R P O R A T E H E A D Q U A R T E R S

769 Jersey Avenue

New Brunswick, NJ 08901

PHONE 732.214.1300

FAX 732.246.7132

A N I S O 90 0 1 :2 0 15 RE G IS T E RE D COM P A NY

W E S T C O A S T F A C I L I T Y

14422 South San Pedro Street

Gardena, California 90248

PHONE 310.516.8000

FAX 310.516.9843

w w w . s p e c t r u m c h e m i c a l . c o m

January 08, 2019

Certification of Compliance with current Good Manufacturing Practices

Dear Valued Customer:

Spectrum Chemical Mfg Corp certifies that our USP, NF, FCC, EP, BP, JP, and food grade products are produced, processed, packaged and held in compliance with current Good Manufacturing Practices (cGMP) in accordance with the applicable parts of 21 CFR, parts 210 and 211 and parts 110 and 111 of the Code of Federal Regulations, respectively.

Spectrum is an FDA registered and inspected Drug Establishment. Our United States Food and Drug Administration (USFDA) Registration numbers are as follows:

Spectrum Gardena, California: 2020632 Spectrum New Brunswick, New Jersey: 2246824

Thank you for your interest in Spectrum products. Please feel free to contact me at 310-516-8000, extension 5610 or via email at [email protected] I may be of further assistance.

Sincerely,

Michael Dang Director, Quality Systems & GMP Compliance

December 18, 2019

Certification of Compliance with current Good Manufacturing Practices

Dear Valued Customer:

Spectrum Chemical Mfg Corp certifies that the following product(s) is produced, processed, packaged and held in compliance with current Good Manufacturing Practices (cGMP) in accordance with the applicable parts of 21 CFR, parts 210 and 211 of the Code of Federal Regulations.

Catalog Number Product Name P1097 Phosphoric Acid, 85 Percent, FCC

Spectrum is an FDA registered and inspected Drug Establishment. Our United States Food and Drug Administration (USFDA) Registration numbers are as follows:

Spectrum-Gardena, CA: 2020632 Spectrum-New Brunswick, NJ: 2246824

Thank you for your interest in Spectrum products. If we may be of further assistance, please feel free to contact the Quality Assurance department at 310-516-8000 or via email at [email protected]

Sincerely,

Oralia Chavez Quality Assurance Specialist

May 25, 2017 Re: Phosphoric Acid, 85 Percent, FCC- P1097 To Whom It May Concern: Thank you for your interest in Spectrum high quality chemicals. We at Spectrum Chemical Mfr. Corp. understand the concern regarding Bovine Spongiform Encephalopathy (BSE). Please be assured that the chemical Phosphoric Acid, 85 Percent, FCC- P1097 is BSE/TSE free. If you have any further questions, please contact Tech Services at (310) 516- 8000 Extension 5471, or by email at [email protected]. Sincerely, Darlene Dagdag-Lyudmirskiy Technical Services Spectrum Chemical Mfr. Corp. This document has been produced electronically and is valid without a signature

May 25, 2017 Re: Phosphoric Acid, 85 Percent, FCC- P1097 To Whom It May Concern: Thank you for your interest in Spectrum high quality chemicals. We at Spectrum Chemical Mfr. Corp. understand the concern regarding the presence of allergens in raw materials. Please be assured that the following chemical does not contain (Milk; Egg; Fish; Shellfish; Sulfur dioxide and sulfites at concentrations of more than 10 mg/kg or 10 mg/liter expressed as SO2; Lupin; Tree nuts; Mollusks; Wheat; Peanuts; Soy; Cereals containing Gluten; Celery; Mustard; Sesame Seed). Phosphoric Acid, 85 Percent, FCC- P1097

If you have any further questions, please contact Tech Services at (310) 516- 8000 Extension 5471, or by email at [email protected]. Sincerely, Darlene Dagdag-Lyudmirskiy Technical Services Spectrum Chemical Mfr. Corp. This document has been produced electronically and is valid without a signature

Certificate Of Analysis

Item Number P1097 Lot Number 1IH1295

Item Phosphoric Acid, 85 Percent, FCC

CAS Number 7664-38-2

Molecular Formula H3PO4 Molecular Weight 98.00

Test Specification Resultmin max

85.0 % 85.2 %

3 mg/kg < 0.2 mg/kg

3 mg/kg < 2 mg/kg

10 mg/kg < 5 mg/kg

3 mg/kg < 3 mg/kg

POSITIVE FORPHOSPHATE

POSITIVE FORPHOSPHATE

CERTIFIED HALAL

12-JUN-2021

13-JUN-2019

CLEARCOLORLESS

LIQUID

Spectrum Chemical Mfg Corp


Gardena 90248 CA

All pharmaceutical ingredients are tested using current edition of applicable pharmacopeia.

Read and understand label and SDS before handling any chemicals. All Spectrum's chemicals are for manufacturing, processing,repacking or research purposes by experienced personnel only. It is the customer's responsibility to provide adequate hazardousmaterial training and ensure that appropriate Personal Protective Equipment (PPE) is used before handling any chemical.

SPECTRUM CHEMICAL MFG. CORP. Gardena, CA 90248 • New Brunswick, NJ 08901

Chemical Emergency: (800)424-9300*49452p1097062233A0A*

DANGER• Causes severe skin burns and eye damage • Harmful if swallowed • May be corrosive to metals.• Do not eat, drink or smoke when using this product • Wear protective gloves, protective clothing, eye protection, face protection • Do not breathe mist or vapors • Wash face, hands and any exposed skin thoroughly after handling • Keep only in original container • Absorb spillage to prevent material damage.FIRST AID: Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting.

KEEP FROM CHILDREN

DOT: UN1805, Phosphoric acid solution, 8, PG III

W 9/E1GHS A Lot No. 062233

H3PO4 F.W. 98.00Components:

Phosphoric Acid ............................... CAS 7664-38-2Water ................................................ CAS 7732-18-5

Assay ........................................................... Min. 85.0%MAXIMUM LIMITS

Arsenic (As) ...................................................... 3 mg/kgCadmium .......................................................... 3 mg/kgFluoride ........................................................... 10 mg/kgLead .................................................................. 3 mg/kg

WARNING: This product contains a chemical known to the State of California to cause cancer.

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

www.SpectrumChemical.com

Exp.

Dat

e: 0

3-31

-202

5

P1097 4 LPhosphoric Acid

(Orthophosphoric Acid)85%F.C.C.

CAS 7664-38-2CAUTION: For manufacturing, processing or repacking. Read and understand the label and Safety Data Sheet (SDS) prior to use.

XxAa

Empirical Formula, Formula Weight and Technical Specifications Panel

Expiration Information

Lot Number

Kosher Certified by Kosher Supervision of America (KSA).

Bar CodeGHS Hazard PictogramsWarning, Safety Data and Precautionary InformationProduct Catalog NumberItem Name, Form, Grade

Size/Quantity

Chemical Abstracts Service (CAS) Registry Number

Caution Information

DOT Shipping Information

Toll-Free 24-Hour Chemical Emergency Telephone Number

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A

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L

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YELLOW: Oxidizer

RED: Flammable

GREEN: General Storage

BLUE: Health Hazard

WHITE: Corrosive

Storage Color Band

This color-coded band indicates the hazard most likely to be posed by that material under storage conditions. The criteria used to assign band colors have been established by the Storage Code working group of the Society for Chemical Hazard Communication (SCHC). It is recommended that like colors be stored together, unless otherwise stated, based on the color codes indicated to the right. However, it is the responsibility of the customer to check with their local fire department for possible conflicts with our recommendations when storing hazardous chemicals.

O

Label Legend

M

N

The Spectrum label presents technical and safety information in an easily understood format. Our technical specialists stay abreast of the latest requirements of the Globally Harmonized System for Classification and Labelling of Chemicals (GHS), as well as the Occupational Safety and Health Administration (OSHA), the Food and Drug Administration (FDA) and other government regulatory agencies in order to ensure compliance, accuracy and concise hazard communication.

G

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Spectrum Chemical Mfg Corp

Corporate Headquarters: West Coast Facility:

769 Jersey Ave. 14422 S. San Pedro St.

New Brunswick, NJ 08901 Gardena, CA 90248

732.214.1300 310.516.8000

Label Information

F

KB

I

C O R P O R A T E H E A D Q U A R T E R S

769 Jersey Avenue

New Brunswick, NJ 08901

PHONE 732.214.1300

FAX 732.246.7132

A N I S O 90 0 1 :2 0 15 RE G IS T E RE D COM P A NY

W E S T C O A S T F A C I L I T Y


Gardena, California 90248

PHONE 310.516.8000

FAX 310.516.9843

w w w . s p e c t r u m c h e m i c a l . c o m

February 1, 2019 RE: Lot Numbering System Dear Valued Customer: This letter is to inform you of Spectrum Chemicals and Laboratory Products’ Lot Numbering System. The system is based on an alpha-numerical sequence which provides the month, year and location of production. The lot numbering system utilized until 2010 is a sequence of six characters, two letters followed by four numbers. The first letter represents the year, for example, Y denotes 2009 and Z denotes 2010. The second letter represents the month and site, for example, A-L denotes January through December at Spectrum’s Gardena, CA facility, while M-X denotes January through December at the New Brunswick, NJ facility. The following four numbers are sequentially assigned.

Example: ZI0928 = The 928th material produced in California in September 2010 The lot numbering system utilized for 2011 and forward, is a sequence of seven characters. The first character, a number, represents the production facility: 1 = Gardena, CA Facility 2 = New Brunswick, NJ Facility 3 = China Facility 4 = Pharmacy, NJ Facility The second character, a letter, represents the year. For example, A denotes 2011 and B denotes 2012. The third character, a letter, represents the month, with A denoting January and L denoting December. The following four numbers are sequentially assigned.

Example: 2AA0706 = The 706th material produced in New Jersey in January 2011 Thank you for your interest with Spectrum products. Please feel free to contact us at 310-516-8000 or via email at [email protected] if we may be of further assistance.

Sincerely,

Howard Lau, Quality Assurance Specialist

18.December.2019

Stability – Shelf Life Guidance Product Covered: P1097, Phosphoric Acid, 85 Percent, FCC

Spectrum Chemical’s manufacturing partner has assigned the following shelf life guidance for the product listed above. The product, P1097, Phosphoric Acid, 85 Percent, FCC, is assigned a 24 months retest date from date of manufacturing. The quality and integrity of the chemical depends on the handling and storage conditions. Please refer to the Safety Data Sheet for proper storage and handling procedures. Himanshu Patel Quality Control Manager

Corporate Headquarters 769 Jersey Avenue New Brunswick, NJ 08901-360

ProductName Product Code Halal-ID Product Certificate #

1. Phosphoric Acid, 85 Percent, FCC P1097 B94019 HC-19SPRV65

This is to certify that the following product(s) have been produced under the supervision of the Islamic Food and Nutrition Council of America(IFANCA).The production facility as well as component ingredients have been reviewed and approved. The product(s) are in compliance with the halal requirements underIslamic laws.

Date: June 18, 2019Document #: 11205.11209.II191033

Company Name & Address: Spectrum Laboratory Products, Inc. 755-769 Jersey Ave New Brunswick, New Jersey 08901 USA

Plant Name & Address: Spectrum Laboratory Products, Inc. 14422 South San Pedro Street Gardena, California 90248 USA

Muhammad Munir Chaudry, Ph.D.President

This Certificate is valid until August 31, 2020 and subject to renewal at that time.

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Documents

P1097, Phosphoric Acid, 85 Percent, FCCPhosphoric Acid 7664-38-2 85-88 Water 7732-18-5 12-15 4. FIRST AID MEASURES First aid measures General Advice: National Capital Poison Center