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Oxidation-Reduction. Dr. Ron Rusay Spring 2008. Oxidation-Reduction. Oxidation is the loss of electrons. Reduction is the gain of electrons. The reactions occur together. One does not occur without the other. - PowerPoint PPT Presentation
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© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Oxidation-ReductionOxidation-Reduction
Dr. Ron RusayDr. Ron Rusay
Spring 2008Spring 2008
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Oxidation-ReductionOxidation-Reduction
�OxidationOxidation is the loss of electrons. is the loss of electrons.�ReductionReduction is the gain of electrons. is the gain of electrons.�The reactions occur together. One does The reactions occur together. One does
not occur without the other.not occur without the other.�The terms are used relative to the The terms are used relative to the
change in the change in the oxidation stateoxidation state or or oxidation numberoxidation number of the reactant(s). of the reactant(s).
Oxidation Reduction ReactionsOxidation Reduction Reactions
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© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Oxidation StateOxidation State(Oxidation Number)(Oxidation Number)
QuickTime™ and aSorenson Video decompressorare needed to see this picture.
QUESTIONQUESTIONIn which of the following does nitrogen have an oxidation state of +4? 1) HNO3 2) NO2 3) N2O 4) NH4Cl 5) NaNO2
ANSWERANSWER 2
-
–
2O2
2) NO
Section 4.9 Oxidation Reduction Reactions(p. 154)
Oxygen almost always has an oxidation state of 2 when part of a compound. The exception is
when it is part of a peroxide. For example, hydrogen peroxide H . Then it has an oxidation state of –1.
Zinc
QUESTIONQUESTIONHow many of the following are oxidation-reduction reactions? NaOH + HCl → + NaCl H2O + 2Cu AgNO3 → 2 + (Ag Cu NO3)2 ( )Mg OH 2 → + MgO H2O N2 + 3H2 → 2NH3 1) 0 2) 1 3) 2 4) 3 5) 4
ANSWERANSWER
-
3) 2
Section 4.9 Oxidation Reduction Reactions(p. 154)
If an element is found on the reactant’s side, this is almost always a redox reaction, since an element usually becomes part of a compound during a chemical reaction.
Cu 2+ Cu (s)
H2 (g) 2 H +
0
0
+2 e-
- 2 e-
Use oxidation numbers to determine what is oxidized and what is reduced.
Number of electrons gained must equal the number of electrons lost.
- 2 e-
+2 e-
Refer to BalancingOxidation-Reduction Reactions
QUESTIONQUESTIONIn the reaction 2Cs(s) + Cl2(g) → 2 ( ), CsCl s Cl2 is 1) .the reducing agent 2) .the oxidizing agent 3) oxid .ized 4) .the electron donor 5) two of these
ANSWERANSWER
-
2) the oxidizing agent.
Section 4.9 Oxidation Reduction Reactions(p. 154)
Metals lose electrons, so they are oxidized, making the other reactant an oxidizing agent.
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Balancing Redox EquationsBalancing Redox Equationsin acidic solutionsin acidic solutions
1) Determine the oxidation numbers of atoms in both 1) Determine the oxidation numbers of atoms in both reactants and products.reactants and products.
2) Identify and select out those which change 2) Identify and select out those which change oxidation number (“redox” atoms) into separate oxidation number (“redox” atoms) into separate “half reactions”.“half reactions”.
3) Balance the “redox” atoms and charges (electron 3) Balance the “redox” atoms and charges (electron gain and loss must equal!).gain and loss must equal!).
4) In acidic reactions balance oxygen with water 4) In acidic reactions balance oxygen with water then hydrogen from water with acid proton(s).then hydrogen from water with acid proton(s).
1
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Balancing Redox EquationsBalancing Redox Equations
FeFe+2+2(aq)(aq)+ Cr+ Cr22OO77
2-2-(aq) (aq) +H+H++
(aq)(aq)---->---->
FeFe3+3+(aq)(aq) + Cr + Cr3+3+
(aq) (aq) + H+ H22OO(l) (l)
??
Fe Fe 2+2+(aq)(aq)+ Cr+ Cr22OO77
2-2-(aq) (aq) +H+H++
(aq)(aq)---->---->
Fe Fe 3+3+(aq)(aq) + Cr + Cr 3+3+
(aq) (aq) + H+ H22OO(l)(l)
1
x x == ?? Cr Cr ; ; 2x+7(-2) 2x+7(-2) = = -2-2; ; x x = = +6+6
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Balancing Redox EquationsBalancing Redox Equations
Fe Fe 2+2+(aq)(aq) ---> Fe ---> Fe 3+3+
(aq)(aq)
CrCr22OO772-2-
(aq) (aq) + --> Cr + --> Cr 3+3+(aq) (aq)
CrCr = (= (6+6+))
1
66 (Fe (Fe 2+2+(aq)(aq) -e -e - - ---> Fe---> Fe3+3+
(aq)(aq)))
66 Fe Fe 2+2+(aq)(aq) ---> ---> 6 6 FeFe3+3+
(aq) (aq) + + 6 6 ee - -
CrCr22OO772-2-
(aq) (aq) + 6 e+ 6 e - - --> --> 2 2 CrCr3+3+(aq)(aq)
6 e6 e - -
-e-e - -
22
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Balancing Redox EquationsBalancing Redox Equations
66 Fe Fe2+2+(aq)(aq) ---> ---> 6 6 FeFe3+3+
(aq) (aq) + + 6 6 ee - -
CrCr22OO772-2-
(aq) (aq) + 6 e+ 6 e - - --> --> 2 2 CrCr3+3+(aq)(aq)
66 Fe Fe2+2+(aq)(aq)+ Cr+ Cr22OO77
2-2-(aq) (aq) + + ? ? 2nd 2nd HH++
(aq)(aq) ----> ---->
6 6 FeFe3+3+(aq) (aq) + + 2 2 CrCr3+3+
(aq)(aq)+ + ? ? 1st Oxygen 1st Oxygen HH22OO(l) (l)
1
OxygenOxygen == 7 7 2nd (Hydrogen)2nd (Hydrogen) == 1414
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Balancing Redox EquationsBalancing Redox Equations
Completely Balanced Equation:Completely Balanced Equation:
66 Fe Fe2+2+(aq)(aq)+ Cr+ Cr22OO77
2-2-(aq) (aq) + + 14 14 HH++
(aq)(aq) ----> ---->
6 6 FeFe3+3+(aq) (aq) + + 2 2 CrCr3+3+
(aq)(aq)+ + 77 HH22OO(l) (l)
1
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Balancing Redox EquationsBalancing Redox Equationsin basic solutionsin basic solutions
1) Determine oxidation numbers of atoms in 1) Determine oxidation numbers of atoms in Reactants and ProductsReactants and Products
2) Identify and select out those which change 2) Identify and select out those which change oxidation number into separate “half reactions”oxidation number into separate “half reactions”
3) Balance redox atoms and charges (electron gain 3) Balance redox atoms and charges (electron gain and loss must equal!)and loss must equal!)
4) In basic reactions balance the Oxygen with 4) In basic reactions balance the Oxygen with hydroxide then Hydrogen from hydroxide with hydroxide then Hydrogen from hydroxide with waterwater
1
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
MnOMnO2 (aq)2 (aq)+ ClO+ ClO331-1-
(aq) (aq) + OH + OH 1-1-aq) aq) ->->
MnOMnO441-1-
(aq) (aq)+ Cl + Cl 1-1-(aq) (aq) + H+ H22OO(l) (l)
MnMn4+4+ (MnO (MnO22) ---> Mn) ---> Mn7+7+ (MnO (MnO4 4 )) 1-1-
ClCl+5+5 (ClO(ClO3 3 )) 1-1-+ + 6 6 ee-- ---> Cl ---> Cl 1-1-
Balancing Redox EquationsBalancing Redox Equationsin basic solutionsin basic solutions
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Electronically Balanced Equation:Electronically Balanced Equation:
22 MnO MnO2 (aq)2 (aq)+ ClO+ ClO331-1-
(aq) (aq) + + 66 e e - - ---->---->
2 2 MnOMnO4 4 1-1- + + Cl Cl 1- 1- + + 6 6 ee--
Balancing Redox EquationsBalancing Redox Equationsin basic solutionsin basic solutions
© Copyright 2002-2008 R.J. Rusay© Copyright 2002-2008 R.J. Rusay
Completely Balanced Equation:Completely Balanced Equation:
22 MnO MnO2 (aq)2 (aq)+ ClO+ ClO331-1-
(aq) (aq) + + 22 OH OH 1- 1- (aq)(aq)---->---->
2 2 MnOMnO4 (aq)4 (aq)1-1- + + Cl Cl 1- 1-
(aq)(aq)+ + 1 1 HH22O O (l)(l)
99 O in productO in product
Balancing Redox EquationsBalancing Redox Equationsin basic solutionsin basic solutions
QUESTIONQUESTIONOxalate ion can be found in rhubarb and spinach (among other green leafy plants). The following unbalanced equation carried out in a basic solution, shows how MnO4
– could be used to analyze samples for oxalate.
MnO4– + C2O4
2– MnO2 + CO32– (basic solution)
When properly balanced, how many OH– are present?
1. 12. 23. 34. 4
ANSWERANSWERChoice 4 is correct. The redox equation could be balanced according to the steps for an acid solution, but then OH– must be added to neutralize the H+ ions. When done properly 4 OH– ions will be present in the basic equation.
Section 4.10: Balancing Oxidation–Reduction Equations