5
ORGANIC PEROXIDES / High polymers

ORGANIC PEROXIDES / High polymers - seki-arkema.co.kr A global chemical company and France’s leading chemicals producer, Arkema is building the future of the chemical industry every

  • Upload
    others

  • View
    80

  • Download
    4

Embed Size (px)

Citation preview

ORGANIC PEROXIDES /

High polymers

2 3

Trade name ChemiCal sTruCTureassay (%)

molar weight (g/mol)

active oxygen

(%)Form Phlegmatizer

half-life temperature (°C)Flash-point

(°C)sadT*

(°C)

storage temperature (°C) Control temperature

(°C)

emergency temperature

(°C)10h00 1h00 1 min mini maxi

luPerOX® 610m50 50 288 2.80 Liquid Hydrocarbon 37a 54 91 61 15 -25 -15 -5 5

luPerOX® 610en50 50 288 2.80 Non frozen emulsion Water 37a 54 91 40 15 -25 -15 -10 0

luPerOX® 546m75 75 258 4.60 Liquid Hydrocarbon 46a 64 99 56 20 -30 -10 0 10

luPerOX® 10 97 244 6.30 Liquid 48a 66 102 65 15 -30 -10 -5 5

luPerOX® 10m75 75 244 4.90 Liquid Hydrocarbon 48a 66 102 63 20 -25 -10 0 10

luPerOX® 10en50 50 244 3.20 Non frozen emulsion Water 48a 66 102 45 15 -25 -10 -5 5

luPerOX® 223s 97 346 4.48 Liquid 49a 66 99 >38 15 -25 -15 -15 -5

luPerOX® 223m75 75 346 3.50 Liquid Hydrocarbon 49a 66 99 >55 5 -25 -15 -15 -5

luPerOX® 223en50 50 346 2.30 Non frozen emulsion Water 49a 66 99 39 5 -25 -15 -15 -5

luPerOX® 223en60 60 346 2.80 Non frozen emulsion Water 49a 66 99 28 5 -25 -20 -15 -5

luPerOX® 554m75 75 188 6.30 Liquid Hydrocarbon 55a 74 112 46 25 -30 -10 10 15

luPerOX® 11m75 75 174 6.90 Liquid Hydrocarbon 58a 76 116 48 20 -15 -5 0 10

luPerOX® 11m25 25 174 2.30 Liquid Hydrocarbon 58a 76 116 46 25** -20** -5** 10** 15**

luPerOX® 219m75 75 314 3.80 Liquid Hydrocarbon 61a 78 114 68 25 -10 -5 10 15

luPerOX® 219m37,5 37.5 314 1.90 Liquid Hydrocarbon 61a 78 114 50 10*** -20*** -10*** 0*** 5***

luPerOX® 219en50 50 314 2.50 Non frozen emulsion Water 61a 78 114 27 25 -15 -10 10 15

luPerOX® lP 99 398 3.98 Flakes 64a 81 117 - 49 -30 27 - 45

luPerOX® lPs40 40 398 1.60 Suspension Water 64a 81 117 - 49 5 20 - 45

luPerOX® deC 98 342 4.50 Flakes 65a 83 120 - 40 -30 15 30 35

luPerOX® a75 75 242 4.95 Fine granules Water 73b 92 131 - 65 5 30 - 60

luPerOX® a75FP 75 242 4.95 Fine powder Water 73b 92 131 - 65 5 30 - 60

luPerOX® 256 95 430 7.00 Liquid - 73d 91 129 52 40 -20 15 30 35

luPerOX® 575 95 230 6.60 Liquid - 75c 92 126 84 35 -15 10 20 25

luPerOX® 26 99 216 7.30 Liquid - 77c 95 130 84 35 -30 20 20 25

luPerOX® 26m30 30 216 2.20 Liquid Hydrocarbon 77c 95 130 49 40** -30** 10** 30** 35**

luPerOX® 80m50 50 160 5.00 Liquid Hydrocarbon 82d 102 146 47 30 5 10 15 20

luPerOX® V10 93 216 6.90 Liquid - 87f 105 143 59 60 -30 30 - 55

luPerOX® 531m60 60 288 6.60 Liquid Hydrocarbon 93c 112 150 69 >60 -20 30 - 55

3-hydroxy-1,1-dimethylbutylperoxyneodecanoate

tert-amyl peroxyneodecanoate

tert-butyl peroxyneodecanoate

di-2-ethylhexyl peroxydicarbonate

tert-amyl peroxypivalate

tert-butyl peroxypivalate

di-(3,5,5-trimethylhexanoyl)-peroxide

dilauroyl peroxide

didecanoyl peroxide

dibenzoyl peroxide

2,5-dimethyl-2,5-di(2-ethylhexanoyl peroxy)-hexane

tert-amyl peroxy-2-ethylhexanoate

tert-butyl peroxy-2-ethylhexanoate

tert-butyl peroxy isobutyrate

a: in trichloroethylene b: in benzene c: in dodecane d: in n-decane e: in ethylbenzene f: in cumene * Values refer to 25 kg packaging size ** Values refer to IBC container - 1000 liters *** Values refer to tank container - 20 m3

1,1-dimethyl propyl 1-methoxycyclohexylperoxide

1,1-di(tert-amyl peroxy)-cyclohexane

4 5

Trade name ChemiCal sTruCTureassay (%)

molar weight (g/mol)

active oxygen

(%)Form Phlegmatizer

half-life temperature (°C)Flash-point

(°C)sadT*

(°C)

storage temperature (°C) Control temperature

(°C)

emergency temperature

(°C)10h00 1h00 1 min mini maxi

luPerOX® 231m50 50 302 5.30 Liquid Hydrocarbon 96c 115 153 61 53 -25 30 - 45

luPerOX® 331m50 50 260 6.10 Liquid Hydrocarbon 97c 116 155 63 >60 -20 30 - 55

luPerOX® TaeC 95 260 5.80 Liquid - 98c 117 155 64 65 -30 30 - 60

luPerOX® TBeC 95 246 6.60 Liquid - 100c 121 166 104 65 -30 30 - 60

luPerOX® JWeB 50 50 965 3.38 Liquid Ethylbenzene 100e 119 159 22 70 -30 30 - 65

luPerOX® 570 96 244 6.30 Liquid - 100c 120 162 68 60 -20 30 - 55

luPerOX® 270 97 230 6.75 Liquid - 102b 123 165 97 60 -20 30 - 55

luPerOX® 270m30 30 230 2.10 Liquid Hydrocarbon 102b 123 165 48 55** -20** 25** - 50**

luPerOX® 7m50 50 132 6.10 Liquid Hydrocarbon 102d 123 166 38 85 -10 30 - 80

luPerOX® 520m50 50 262 6.10 Liquid Hydrocarbon 102c 124 161 46 64 -10 30 - 60

luPerOX® P 99 194 8.10 Liquid - 102d 124 171 107 60 8 30 - 55

luPerOX® 220m50 50 234 6.80 Liquid Hydrocarbon 107c 127 169 54 >70 0 30 - 65

luPerOX® 230 97 334 9.3 Liquid - 112c 129c 163c 64 67 -20 30 - 55

luPerOX® 533m65 65 320 6.50 Liquid Hydrocarbon 112b 132 173 68 >58 -20 30 - 50

1,1-di(tert-butylperoxy)-3,3,5-trimethylcyclohexane

1,1-di(tert-butylperoxy)-cyclohexane

OO-tert-amyl-O-(2-ethylhexyl)-monoperoxycarbonate

OO-tert-butyl-O-(2-ethylhexyl)-monoperoxycarbonate

Polyether poly(t-butyl)-peroxycarbonate

tert-amyl peroxy-3,5,5-trimethylhexanoate

tert-butyl peroxy-3,5,5-trimethylhexanoate

tert-butyl peroxyacetate

2,2-di(tert-amylperoxy)-butane

tert-butyl-peroxybenzoate

2,2-di(tert-butylperoxy)-butane

n-butyl-4,4-di(tert-butylperoxy)-valerate

ethyl 3,3-di(tert-amylperoxy)-butyrate

a: in trichloroethylene b: in benzene c: in dodecane d: in n-decane e: in ethylbenzene f: in cumene * Values refer to 25 kg packaging size ** Values refer to IBC container - 1000 liters *** Values refer to tank container - 20 m3

6 7

Trade name ChemiCal sTruCTureassay (%)

molar weight (g/mol)

active oxygen

(%)Form Phlegmatizer

half-life temperature (°C)Flash-point

(°C)sadT*

(°C)

storage temperature (°C) Control temperature

(°C)

emergency temperature

(°C)10h00 1h00 1 min mini maxi

luPerOX® 233m50 50 292 5.50 Liquid Hydrocarbon 114c 134 175 60 80 / 30 - 75

luPerOX® dCP 99 270 5.80 Crystals - 117d 137 178 121 90 / 30 - 75

luPerOX® 101 95 290 10.50 Liquid 120c 140 181 58 82 10 30 - 75

luPerOX® 101PP7,5 7.5 290 0.80 Powder Polypropylene 120c 140 181 - >90 - 30 - 85

luPerOX® 101PP10 10 290 1.10 Powder Polypropylene 120c 140 181 - >90 - 30 - 85

luPerOX® 101PP20 20 290 2.20 Granules Polypropylene 120c 140 181 - >90 - 30 - 85

luPerOX® 101mO50 50 290 5.50 Liquid Hydrocarbon 120c 140 181 >60 >80 8 30 - 75

luPerOX® 101mO80 80 290 8.84 Liquid Hydrocarbon 120c 140 181 70 >80 8 30 - 75

luPerOX® 802PP40 40 338 3.80 Powder Polypropylene 119c 139 181 - 81 - 30 - 75

luPerOX® 802PP20 20 338 1.90 Powder Polypropylene 119c 139 181 - 81 - 30 - 75

luPerOX® 801 91 208 7.00 Liquid - 124c 144 185 82 84 16 30 - 75

luPerOX® dTa 95 174 8.70 Liquid - 123c 143 184 29 75 -30 30 - 70

luPerOX® di 99 146 10.80 Liquid - 129d 149 189 6 80 -30 30 - 75

luPerOX® di-s 99 146 10.80 Liquid - 129d 149 189 6 80 -30 30 - 75

luPerOX® dim50 50 146 5.50 Liquid Hydrocarbon 129d 149 189 10 80 -25 30 - 75

luPerOX® PmhP 54 172 5.00 Liquid Paramenthane 133b 160 218 70 55 -35 30 - 50

luPerOX® dh 50 194 4.20 Liquid Diisopropyl-benzene 150b 181 252 90 55 -30 30 - 50

luPerOX® 2,5-2,5 70 178 12.60 Powder - 154b 187 260 - 70 2 30 - 65

luPerOX® Cu80 80 152 8.40 Liquid Cumene 158b 190 260 79 80 -30 30 - 75

luPerOX® Cu88 88 152 9.30 Liquid Cumene 158b 190 260 94 70 -30 30 - 75

luPerOX® Tah85 85 104 13.00 liquid water 165 - - 38 > 58 0 30 - 50

luPerOX® TBh70X 70 90 12.40 liquid water 172b 200 260 38 81 0 30 - 75

ethyl 3,3-di(tert-butylperoxy)-butyrate

dicumyl peroxide

2,5-dimethyl-2,5-di(tert-butylperoxy)-hexane

di(tert-butylperoxyisopropyl)-benzene

tert-butyl cumyl peroxide

di-tert-amyl peroxide

di-tert-butyl peroxide

paramenthane hydroperoxide

diisopropylbenzene mono-hydroperoxide

2,5-dimethyl-2,5-di-hydroperoxyhexane

cumene hydroperoxide

tert-amyl hydroperoxide

tert-butyl hydroperoxide

a: in trichloroethylene b: in benzene c: in dodecane d: in n-decane e: in ethylbenzene f: in cumene * Values refer to 25 kg packaging size ** Values refer to IBC container - 1000 liters *** Values refer to tank container - 20 m3

420, rue d’Estienne d’Orves92705 Colombes Cedex – France

Tel.: 33 (0)1 49 00 80 80Fax: 33 (0)1 49 00 83 96

arkema.comluperox.com

The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constitute or imply any warranty, undertaking, express or implied commitment from our part. Our formal specifi cations defi ne the limit of our commitment. No liability whatsoever can be accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevant laws and/or regulations in force in the country or countries concerned.

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, ARKEMA expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specifi c product designated and may not be applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement.See MSDS for Health & Safety Considerations.

A global chemical company and France’s leading chemicals producer, Arkema is building the future of the chemical industry every day. Deploying a responsible, innovation-based approach, we produce state-of-the-art specialty chemicals that provide customers with practical solutions to such challenges as climate change, access to drinking water, the future of energy, fossil fuel preservation and the need for lighter materials. With operations in more than 40 countries, some 14,000 employees and 10 research centers, Arkema generates annual revenue of approximately 6.4 billion, and holds leadership positions in all its markets with a portfolio of internationally recognized brands.

Ark

ema

- A li

mite

d lia

bilit

y co

mpa

ny w

ith c

apita

l of 6

25 3

88 1

80 e

uros

- N

ante

rre C

ompa

ny a

nd C

omm

erci

al R

egist

ry N

o. 4

45,0

74,6

85DI

RCO

M 4

344E

/ 0

9.20

13 /

10

- ADD

I - P

hoto

s: A

rkem

a, T

hink

stock

- A

genc

y: VU

DU TO

IT

Production Facilities- Rio Claro, Brazil- El Chapo, Mexico- Crosby, TX, USA - Geneseo, NY, USA - Franklin, VA, USA- Gunzburg, Germany

- Spinetta, Italy- Changshu, China- Cuddalore, India- SEKI, Korea- YOSHITOMI, Japan

R&D Centers- Changshu, China- King of Prussia, PA, USA- Pierre-Bénite, France

Headquarter- Colombes, France

Production Facilities Production Facilities R&D Centers R&D Centers