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Organic Particle Production from the Bubbler and Sea Sweep
During CalNex 2010 Amanda Frossard, Lynn Russell,
Scripps Institution of Oceanography, UC San DiegoWilliam Keene, John Maben,
Department of Environmental Science, University of VirginiaTimothy Bates, and Patricia Quinn
Pacific Marine Environmental Laboratory, NOAA
January 12, 2011 - CalNex Data Meeting
Overview• Comparison of marine organic particle
composition from the UVa Bubbler, Sea Sweep, and Ambient Marine Factor
Overview• Comparison of marine organic particle
composition from the UVa Bubbler, Sea Sweep, and Ambient Marine Factor
Methods
• Fourier transform Infrared (FTIR) spectroscopy of filter samples to get overall organic mass and functional groups
• Scanning transmission x-ray microscopy near edge absorption fine structure (STXM-NEXAFS) to get morphology and composition of single particles impacted on sample windows
Nascent Marine Aerosol from Bubbling Ambient Sea Water
Marine Aerosol Production: Bubbler
Vacuum Pump
Bubbler Outlet
1 pair of Teflon filters
Sampled at 80% RHNo diameter size cut“Bulk aerosol”
sub and super micrcon
Organic Composition: Bubbler
Organic Composition:
Bubbler
Northern CA
Southern CA
Bubbling CharacteristicsFine Coarse Jets
Morning
Afternoon
Night
3.43.2 1.7 1.94.2 2.6
Southern CANorthern CASan Francisco Bay
frit typeflow (lpm)
= phenol
Marine Aerosol Production: Sea Sweep
Organic Aerosol Sampling: Sea Sweep and Ambient
Mass Flow Meter and ControllerTotal: 16.8 lpm
Vacuum Pump
PM1 Cyclone
2 pairs of Teflon filters
Dried to 55% RH
Organic Composition: Sea SweepNorthern CA
Southern CA
Single Particle Sea SweepParticle Map
Hawkins et al. 2010
High C
Low C
Single Particle Sea SweepParticle Map
Hawkins et al. 2010
High C
Low C
Organic Composition: Ambient
Ambient Marine Aerosol
Russell et al. 2010
Marine FactorAlcohol: 62%Acid: 9%Alkane: 20%Amine: 9%
Makes up on average 13% of total OM
Similar to marine insoluble organicstandards
Ambient Marine Aerosol
• Marine Factor fraction of OM
Single Particle Ambient MarineParticle Map
Hawkins et al. 2010
High C
Low C
Summary
• Sea sweep, bubbler, and ambient marine factor show similar organic functional group composition
• Single particles from the Sea Sweep and clean marine samples have particle morphologies and absorption spectra similar to other observed marine particle
Thanks!
Acknowledgements:• Scientists and crew of R/V Atlantis• Crew at the LBNL Beamline • PMEL Atlantis Group• Russell Group• PNNL Group and Dan Czizco