1
ORGANIC ELECTRONICS Applied Petroleum Engineering-Upstream Lakshya , Shashank Pandey, Vedant Makwana Disadvantages of Traditional Electronics: 1. Lack Of Sustainability Prospects 2. High Manufacturing Costs 3. Complex Processing 4. Rigid Substrates 5. Small Usable Surface Areas Sustainability being the talk of the town and Moore's Lawsincreasing relevance evidently imply that the future is going to be ORGANIC ELECTRONICS . . . . What is Organic Electronics ? Organic electronics is the branch of Material Sciences which involves the use of conducting Organic Polymers and their small monomer molecules in designing electronic circuits. Most of these polymers and monomers are carbon based and hence this new technology is termed as Organic Electronics. Though it is also known as Plastic or Polymer Electronics in the Scientific fraternity. This is a modern revolutionary tech- nology involving the charge transfer complex formation properties of organic polymers. Materials for or- ganic electronics Semiconductor Materi- als Small molecules: Pentacene, Ru- brene Polymers: PEDOT:PSS, P3HT,PTAA, Conductive Materials Organic: PPy, PEDOT:PSS, PANI Inorganic: metals (Au, Ag), ox- ides (ITO, ATO) Dielectric Materials Polycarbonate, PMMA, PP, PVA, PET, Parylene X Properties Germanium Polythiophene Graphene Melting Point (K) 937 457 4900 Intrinsic Conductivity (1/ohm.cm) 0.02 0.3 10 6 Electron Mobility (cm 2 /Vs) 4500 350 15000 Hole Mobility (cm 2 /Vs) 3500 260 12000 Alpha-Oligofurans: The Future…. α-Oligofurans are a new class of organic compounds with long chains of as much as nine rings attached to one other. Oligofurans are highly fluorescent with a quantum yield of 58-74 % which is far more than contemporary LED materials. [2] They are stronger and more rigid than the sister class of compounds Oligothio- phenes and yet more soluble in suitable substrates thus is the best material known for flexible devices. The electronic coupling integral of oligofurans (H ab ) is 30-40% greater indicat- ing better conductivity than graphene. The high conductivity of oligofurans along with a higher HOMO-LUMO gap serves a great deal in its use as a replacement of semiconductors. The long chain of Oligofurans provide a large surface area at the nano level thus increasing Acknowledgements: Dr. Sanjeev Dubey, Dr. Sapna Jain– Department Of Chemistry, University Of Petroleum & Energy Studies Dr. Rajeev Gupta - Department Of Physics, University Of Petroleum & Energy Studies Literature Review 1.Graphene Nano Membrane. [1] 2.SWNT( Single walled Carbon Nano Tubes) [1] 3.Effieient and Integrated Electronic System [3] 4.Flexible mul-site biological probe [4] References: 1.A. Geim and K. Novoselov, 'The rise of graphene', Nat Mater , vol. 6, no. 3, pp. 183-191, 2007. 2.Vrhel, M.; Saber, E.; Trussell, H.J. "Color image generaon and display technologies", Signal Processing Magazine, IEEE, On page(s): 23 - 33 Volume: 22, Issue: 1, Jan. 2005 3.Yasufuku, S. "Electroconducve polymers and their applicaons", Electrical Insulaon Magazine, IEEE, On page(s): 14 - 24 Volume: 17, Issue: 5, Sept.-Oct. 2001 4.C. Liao and M. Zhang, Flexible Organic Electronics in Biology: Materials and Devices. Weinheim: WILEY-VCH Verlag GmbH & Co, 2015, pp. 542-547. 5.S. Sutar, E. Comfort and J. Lee, 'Graphene p-n juncons for electron-opcs devices', 71st Device Research Conference, 2013. Source : BERGGREN, M., NILSSON, D. AND ROBINSON, N. D. OLED Structure Source : GEIM, A. K. AND NOVOSELOV, K. S. Structure of Carbon NanoTubes Source : LIAO, C. AND ZHANG, M. Comparison of Properties of Element with respect to Graphene Source :SUTAR, S., COMFORT, E. AND LEE, J. U.[5]

Organic Electronics

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Page 1: Organic Electronics

ORGANIC ELECTRONICS

Applied Petroleum Engineering-Upstream

Lakshya , Shashank Pandey, Vedant Makwana

Disadvantages of Traditional Electronics: 1. Lack Of Sustainability Prospects

2. High Manufacturing Costs

3. Complex Processing

4. Rigid Substrates

5. Small Usable Surface Areas

Sustainability being the talk of the town and Moore's Laws’ increasing relevance evidently imply that the future is

going to be ORGANIC ELECTRONICS . . . .

What is Organic Electronics ?

Organic electronics is the branch of Material Sciences which

involves the use of conducting Organic Polymers and their

small monomer molecules in designing electronic circuits.

Most of these polymers and monomers are carbon based and

hence this new technology is termed as Organic Electronics.

Though it is also known as Plastic or Polymer Electronics in

the Scientific fraternity. This is a modern revolutionary tech-

nology involving the charge transfer complex formation

properties of organic polymers.

Materials for or-

ganic electronics

•Semiconductor Materi-

als

Small molecules: Pentacene, Ru-

brene

Polymers: PEDOT:PSS,

P3HT,PTAA,

•Conductive Materials

Organic: PPy, PEDOT:PSS, PANI

Inorganic: metals (Au, Ag), ox-

ides (ITO, ATO)

•Dielectric Materials

Polycarbonate, PMMA, PP, PVA,

PET, Parylene X

Properties Germanium Polythiophene Graphene

Melting

Point (K) 937 457 4900

Intrinsic

Conductivity

(1/ohm.cm)

0.02 0.3 106

Electron

Mobility

(cm2/Vs)

4500 350 15000

Hole

Mobility

(cm2/Vs)

3500 260 12000

Alpha-Oligofurans: The Future…. α-Oligofurans are a new class of organic compounds with long chains of as

much as nine rings attached to one other.

Oligofurans are highly fluorescent with a quantum yield of 58-74 % which is

far more than contemporary LED materials.[2]

They are stronger and more rigid than the sister class of compounds Oligothio-

phenes and yet more soluble in suitable substrates thus is the best material

known for flexible devices.

The electronic coupling integral of oligofurans (Hab) is 30-40% greater indicat-

ing better conductivity than graphene.

The high conductivity of oligofurans along with a higher HOMO-LUMO gap

serves a great deal in its use as a replacement of semiconductors.

The long chain of Oligofurans provide a large surface area at the nano level thus

increasing

Acknowledgements: Dr. Sanjeev Dubey, Dr. Sapna Jain– Department Of Chemistry, University Of Petroleum & Energy Studies

Dr. Rajeev Gupta - Department Of Physics, University Of Petroleum & Energy Studies

Literature Review 1.Graphene Nano Membrane.[1]

2.SWNT( Single walled Carbon Nano Tubes)[1]

3.Effieient and Integrated Electronic System[3]

4.Flexible multi-site biological probe[4]

References: 1.A. Geim and K. Novoselov, 'The rise of graphene', Nat Mater, vol. 6, no. 3, pp. 183-191, 2007.

2.Vrhel, M.; Saber, E.; Trussell, H.J. "Color image generation and display technologies", Signal Processing Magazine, IEEE, On page(s): 23 - 33 Volume: 22, Issue: 1, Jan. 2005

3.Yasufuku, S. "Electroconductive polymers and their applications", Electrical Insulation Magazine, IEEE, On page(s): 14 - 24 Volume: 17, Issue: 5, Sept.-Oct. 2001

4.C. Liao and M. Zhang, Flexible Organic Electronics in Biology: Materials and Devices. Weinheim: WILEY-VCH Verlag GmbH & Co, 2015, pp. 542-547.

5.S. Sutar, E. Comfort and J. Lee, 'Graphene p-n junctions for electron-optics devices', 71st Device Research Conference, 2013.

Source : BERGGREN, M., NILSSON, D. AND ROBINSON, N. D.

OLED Structure

Source : GEIM, A. K. AND NOVOSELOV, K. S.

Structure of Carbon NanoTubes

Source : LIAO, C. AND ZHANG, M.

Comparison of Properties of Element with respect

to Graphene

Source :SUTAR, S., COMFORT, E. AND LEE, J. U.[5]