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Organic Chemistry Chapter 3. Alkenes and Alkynes. Nanoplasmonic Research Group. Unsaturated hydrocarbons: Alkenes & Alkynes. Degree of Unsaturati on from Molecular Formula. How to name it !!. Chemical Reactions. Nanoplasmonic Research Group. - PowerPoint PPT Presentation
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Alkenes and Alkynes
Nanoplasmonic Research Group
Organic Chem-istry
Chapter 3
Unsaturated hydrocarbons: Alkenes & Alkynes
Nanoplasmonic Research Group
Degree of Unsaturation from Molecular For-mula
How to name it !!
Chemical Reactions
Calculating the Degrees of Un-saturation from a Molecular Forumula: Isomers Matter!!!
• Degrees of Unsaturation ->Number of Rings and/or Multiple
Bonds• 1 Degrees of Unsaturation ->1 Ring or 1 Double Bond• 2 Degrees of Unsaturation ->2 Double Bonds, 2 Rings, 1 Ring + 1
Double Bonds, or 1 Triple Bond
Example: C6H10 (fully saturated would be C6H14)14 H – 10 H = 4 hydrogen atoms = 2 H2 (pairs of hydrogen atoms) = 2 degrees of unsatura-tion
• If molecular formular contains– Halogen (F, Cl, Br, I) – Add number of halogens to
number of hydrogen atoms -> C4H6Br2 is equivalent to C4H8, degrees of unsatura-
tion = 1– Oxygen – Ignore it -> C5H8O is equivalent to C5H8, degrees of unsatura-
tion = 2– Nitrogen – Subtract number of nitrogen atoms
from number of hydrogen atoms -> C5H9N is equivalent to C5H8, degrees of unsatura-
tion = 2
Naming AlkenesStraight-chain alkenes1. Find parent (longest chain containing
a double bond)2. Number the chain
3. Write the full name
Cycloalkenes
Start the end nearest the double bondIf double bonds are equidistant from both ends , start at the end with the nearest branch point
Place the number corresponding to the double bond before the parent name
Number so that the double bonds is between C1 and C2 and that the 1st substituent has the lowest number possible
Examples (alkenes)
Naming Alkynes1. Follow alkene rules, but use –yne as
suffix
2. If more than one triple bond is present, use –diyne, triyne,…
3. If both double and triple bonds are present- Use –enyne as suffix- Number from side with nearest multiple bond (either double or triple)- If a double and triple bond is equidistant, make the double bond the lower number
Examples (alkynes)