npi.pdf

SpectrAA Report. 6:10 PM 3/26/2015 Page 1 of 12

AnalystDate StartedWorksheetCommentMethods Cr,Cu,Mg,Mn,Fe,Co,Ni,Pb,Ca,Al

M NPI A-E, M089 NIKEL ORE1:54 PM 3/2/2015

Computer name ANALIS-PC

Method: Cr (Flame)

Sample ID Conc mg/L %RSD Mean Abs

CAL ZERO 0.0000 16.8 0.0035

STANDARD 1 1.0000 0.5 0.0712

STANDARD 2 2.0000 0.4 0.1154

STANDARD 3 5.0000 0.8 0.1946

New Rational - Cal. Set 1

Cr mg/L

Abs

0.00

0.19

0.10

0.15

0.0000 5.00002.0000 3.0000 4.0000


Cr mg/L

Abs

0.00

0.19

0.10

0.15

0.0000 5.00002.0000 3.0000 4.0000

Curve Fit = New Rational

Characteristic Conc = 0.0612 mg/L

r = 0.9995

Calculated Conc = 0.0489 1.0459 1.9010 5.0835

Residuals = -0.0489 -0.0459 0.0990 -0.0835

Conc = A

------------------------------------------

(-0.95878 x A x A + 0.01362 x A + 0.07191)

BLK 0.1115 7.9 0.0080

GPS 2.4029 0.7 0.1351

IH 0.6288 1.1 0.0444

MRC OVER 0.0 0.8044

LIM OVER 0.0 0.5916

SAP 3.3777 0.7 0.1637

BLK <0.0060U 53.6 -0.0007

A 0.9659 0.2 0.0663

B OVER 0.0 0.3372

C OVER 0.0 0.1967

D 0.6708 1.4 0.0472

E 3.7389 0.8 0.1718

COMP 1.8422 0.0 0.2390

BLK 0.1633 7.7 0.0117

BLK 0.1712 6.0 0.0123

Method: Cu (Flame)


http://www.iceni.com/unlock-pro.htm


CAL ZERO 0.0000 30.2 -0.0003

STANDARD 1 1.0000 1.1 0.1286

STANDARD 2 3.0000 1.3 0.3712

STANDARD 3 5.0000 0.5 0.5888


Cu mg/L

Abs

0.00

0.59

0.20

0.40

0.0000 5.00002.0000 3.0000 4.0000


Cu mg/L

Abs

0.00

0.59

0.20

0.40

0.0000 5.00002.0000 3.0000 4.0000



r = 1.0000

Calculated Conc = -0.0020 1.0038 2.9913 5.0051

Residuals = 0.0020 -0.0038 0.0087 -0.0051

Conc = A

------------------------------------------

(-0.02871 x A x A - 0.00207 x A + 0.12881)

BLK <0.0030U >100 0.0000

GPS 0.0641 1.4 0.0083

IH 0.6580 1.9 0.0845

MRC 0.0593 1.5 0.0076

LIM 0.1513 1.1 0.0195

SAP 0.1014 1.6 0.0131

BLK <0.0030U 28.5 -0.0004

M089/1 0.1012 1.0 0.0130

1 0.1039 1.0 0.0134

2 0.1100 1.0 0.0142

2 0.1062 1.8 0.0137

3 0.1127 1.0 0.0145

3 0.1099 1.2 0.0142

4 0.1020 1.3 0.0131

4 0.1035 0.6 0.0133

5 0.1049 0.4 0.0135

5 0.1056 1.7 0.0136

6 0.1025 1.7 0.0132

6 0.1008 0.7 0.0130

7 0.1011 2.7 0.0130

7 0.1001 1.3 0.0129

8 0.1005 0.6 0.0129

8 0.1007 1.7 0.0130

9 0.0926 1.6 0.0119

9 0.0907 1.5 0.0117

10 0.0894 1.2 0.0115

10 0.0934 0.7 0.0120

GPS 0.0575 3.1 0.0074



IH 0.6595 0.5 0.0847

MRC 0.0564 1.0 0.0073

LIM 0.1510 0.5 0.0194

SAP 0.0995 0.6 0.0128

BLK <0.0030U 20.7 -0.0003

A 0.4912 0.1 0.0631

B 0.1915 1.0 0.0247

C 0.2189 1.2 0.0282

D 0.2213 0.7 0.0285

E 0.2706 1.5 0.0348

COMP 0.2985 1.7 0.1412

BLK <0.0030U 18.9 -0.0005

BLK <0.0030U 37.9 -0.0006

Method: Mg (Flame)


CAL ZERO 0.0000 >100 -0.0001

STANDARD 1 0.3000 0.2 0.3218

STANDARD 2 0.6000 0.8 0.6659

STANDARD 3 1.5000 0.4 1.3134


Mg mg/L

Abs

0.00

1.31

0.50

1.00

0.0000 1.50000.5000 1.0000


Mg mg/L

Abs

0.00

1.31

0.50

1.00

0.0000 1.50000.5000 1.0000



r = 0.9997

Calculated Conc = -0.0001 0.2916 0.6126 1.4931

Residuals = 0.0001 0.0084 -0.0126 0.0069

Conc = A

------------------------------------------

(-0.27364 x A x A + 0.22145 x A + 1.06078)

BLK <0.0003U 38.9 -0.0007

GPS 1.3963 1.0 1.2625

IH OVER 0.0 1.3914

MRC 0.3820 0.7 0.4223

LIM 0.4881 0.4 0.5373

SAP 1.1346 0.2 1.1030

BLK <0.0003U >100 -0.0006

M089/1 0.8486 0.2 0.8847

1 0.8291 0.4 0.8679

2 0.8424 0.8 0.8794

2 0.8358 0.7 0.8737



3 0.8724 1.9 0.9048

3 0.8717 1.2 0.9042

4 0.8159 0.6 0.8564

4 0.7617 1.3 0.8082

5 0.8857 0.8 0.9158

5 0.7582 1.5 0.8050

6 0.9073 1.0 0.9336

6 0.9996 1.7 1.0062

7 1.0579 0.9 1.0493

7 0.8496 1.3 0.8855

8 1.0104 1.3 1.0143

8 0.9243 1.2 0.9474

9 0.9766 0.5 0.9886

9 0.8451 1.0 0.8817

10 0.8636 0.4 0.8974

10 0.5854 1.4 0.6384

BLK <0.0003U 16.9 -0.0019

BLK <0.0003U 9.9 -0.0019

Method: Mn (Flame)


CAL ZERO 0.0000 >100 0.0001

STANDARD 1 1.0000 0.4 0.1883

STANDARD 2 2.0000 0.9 0.3712

STANDARD 3 5.0000 1.2 0.8254


Mn mg/L

Abs

0.00

0.83

0.40

0.60

0.0000 5.00002.0000 3.0000 4.0000


Mn mg/L

Abs

0.00

0.83

0.40

0.60

0.0000 5.00002.0000 3.0000 4.0000



r = 1.0000

Calculated Conc = 0.0007 0.9993 2.0011 4.9996

Residuals = -0.0007 0.0007 -0.0011 0.0004

Conc = A

------------------------------------------

(-0.04560 x A x A + 0.00959 x A + 0.18823)

BLK 0.0035 23.0 0.0007

GPS 3.9648 0.5 0.6871

IH 1.9821 1.0 0.3679

MRC OVER 0.0 1.3444

LIM OVER 0.0 1.4878

SAP OVER 0.0 1.1126



BLK <0.0020U 43.3 -0.0008

A 0.3859 1.5 0.0728

B 2.3939 0.3 0.4396

C 2.5886 0.6 0.4726

D 0.1483 0.7 0.0279

E 3.7977 0.4 0.6629

COMP 2.8541 0.7 0.1807

BLK <0.0020U 46.9 -0.0003

BLK <0.0020U >100 -0.0002

Method: Fe (Flame)


CAL ZERO 0.0000 >100 -0.0001

STANDARD 1 1.0000 1.3 0.0807

STANDARD 2 2.0000 0.9 0.1693

STANDARD 3 5.0000 1.0 0.3831


Fe mg/L

Abs

0.00

0.38

0.10

0.20

0.30

0.0000 5.00002.0000 3.0000 4.0000


Fe mg/L

Abs

0.00

0.38

0.10

0.20

0.30

0.0000 5.00002.0000 3.0000 4.0000



r = 1.0000

Calculated Conc = -0.0018 0.9774 2.0301 4.9894

Residuals = 0.0018 0.0226 -0.0301 0.0106

Conc = A

------------------------------------------

(-0.13459 x A x A + 0.04348 x A + 0.07989)

BLK <0.0060U >100 0.0002

GPS 0.7596 0.2 0.0623

IH 0.2638 4.6 0.0213

MRC 4.2968 0.6 0.3399

LIM 1.5846 12.1 0.1320

SAP 1.3403 1.2 0.1113

BLK <0.0060U >100 0.0000

M089/1 1.3046 1.9 0.1083

1 1.2050 0.7 0.0999

2 1.1983 1.4 0.0993

2 1.1611 1.6 0.0962

3 1.1064 0.7 0.0915

3 1.2661 0.9 0.1050

4 1.3329 1.3 0.1107

4 1.3016 1.5 0.1081



5 1.0705 0.5 0.0885

5 0.9827 0.6 0.0811

6 0.9002 1.7 0.0741

6 0.9589 2.9 0.0791

7 0.8277 0.5 0.0681

7 0.8485 1.1 0.0698

8 0.9089 4.2 0.0749

8 0.9577 2.9 0.0790

9 1.0023 1.7 0.0828

9 0.8932 1.2 0.0736

10 1.0757 1.3 0.0889

10 1.2721 1.2 0.1056

GPS 0.7436 1.8 0.0610

IH 0.2331 3.8 0.0188

MRC 4.3294 2.8 0.3421

LIM 1.4640 3.7 0.1218

SAP 1.2908 1.6 0.1071

BLK <0.0060U >100 -0.0003

A OVER 0.0 0.5702

B OVER 0.0 0.5656

C OVER 0.0 0.5606

D OVER 0.0 0.5748

E OVER 0.0 0.5609

COMP OVER 0.0 0.5654

BLK 0.0061 65.8 0.0005

BLK <0.0060U >100 0.0001

Method: Co (Flame)


CAL ZERO 0.0000 90.6 -0.0002

STANDARD 1 1.0000 0.6 0.0791

STANDARD 2 2.0000 0.8 0.1619

STANDARD 3 5.0000 0.6 0.3513


Co mg/L

Abs

0.00

0.35

0.10

0.20

0.30

0.0000 5.00002.0000 3.0000 4.0000


Co mg/L

Abs

0.00

0.35

0.10

0.20

0.30

0.0000 5.00002.0000 3.0000 4.0000



r = 1.0000

Calculated Conc = -0.0028 0.9840 2.0226 4.9910

Residuals = 0.0028 0.0160 -0.0226 0.0090

Conc = A



------------------------------------------

(-0.16969 x A x A + 0.03619 x A + 0.07862)


BLK <0.0050U >100 -0.0003

GPS 0.6188 0.3 0.0495

IH 0.9289 0.3 0.0747

MRC 1.4478 0.4 0.1166

LIM 2.4466 1.6 0.1939

SAP 1.2246 1.1 0.0986

BLK <0.0050U >100 -0.0008

M089/1 0.4835 2.4 0.0386

1 0.4772 1.0 0.0381

2 0.4364 1.8 0.0348

2 0.4446 1.2 0.0354

3 0.4323 1.8 0.0344

3 0.4444 0.4 0.0354

4 0.4800 1.7 0.0383

4 0.4900 2.9 0.0391

5 0.3677 3.5 0.0292

5 0.3532 3.4 0.0281

6 0.3370 2.0 0.0268

6 0.3421 2.8 0.0272

7 0.3060 3.5 0.0243

7 0.3127 3.2 0.0248

8 0.3742 2.0 0.0298

8 0.3555 0.5 0.0283

9 0.3696 3.5 0.0294

9 0.3829 1.5 0.0305

10 0.4521 2.0 0.0360

10 0.4624 2.0 0.0369

GPS 0.6396 0.2 0.0512

IH 0.9326 0.8 0.0750

MRC 1.4796 0.4 0.1191

LIM 2.4166 0.4 0.1917

SAP 1.2169 0.3 0.0980

BLK <0.0050U 35.9 -0.0019

A 0.6717 2.0 0.0538

B 0.7804 0.9 0.0626

C 0.7772 1.4 0.0623

D 0.8276 2.4 0.0664

E 0.8238 0.8 0.0661

COMP 0.7321 0.8 0.2764

BLK <0.0050U >100 -0.0001

BLK <0.0050U >100 0.0000

Method: Ni (Flame)


CAL ZERO 0.0000 87.6 0.0019

STANDARD 1 1.0000 0.6 0.0847

STANDARD 2 2.0000 0.7 0.1692



STANDARD 3 5.0000 0.8 0.3595


Ni mg/L

Abs

0.00

0.36

0.10

0.20

0.30

0.0000 5.00002.0000 3.0000 4.0000


Ni mg/L

Abs

0.00

0.36

0.10

0.20

0.30

0.0000 5.00002.0000 3.0000 4.0000



r = 1.0000

Calculated Conc = 0.0228 0.9913 2.0127 4.9946

Residuals = -0.0228 0.0087 -0.0127 0.0054

Conc = A

------------------------------------------

(-0.17026 x A x A + 0.02651 x A + 0.08445)

BLK 0.0199 42.5 0.0017

GPS 3.6121 1.3 0.2829

IH 2.5412 0.2 0.2097

MRC 3.0560 1.0 0.2464

LIM 2.9244 0.3 0.2373

SAP 3.9546 1.1 0.3037

BLK <0.0100U >100 0.0002

M089/1 4.2854 0.8 0.3226

1 4.1954 0.9 0.3176

2 3.7553 0.5 0.2918

2 3.7328 0.6 0.2904

3 3.8810 0.5 0.2993

3 3.8300 0.8 0.2963

4 4.1142 1.0 0.3130

4 4.2201 0.7 0.3190

5 3.3973 0.3 0.2692

5 3.4939 1.0 0.2754

6 3.1568 0.9 0.2533

6 3.1051 0.5 0.2498

7 2.9446 0.7 0.2387

7 2.9012 0.5 0.2357

8 3.5104 0.8 0.2765

8 3.4810 0.9 0.2746

9 3.2780 0.5 0.2614

9 3.2778 0.5 0.2614

10 4.0896 0.6 0.3116

10 3.9417 0.3 0.3029

GPS 3.5235 0.9 0.2773

IH 2.5435 2.2 0.2099

MRC 3.0669 0.6 0.2472

LIM 2.9087 1.5 0.2362



SAP 3.9087 1.1 0.3010

BLK <0.0100U 19.0 -0.0023

A 0.9021 0.5 0.0771

B 0.8262 0.7 0.0706

C 0.9380 2.2 0.0802

D 0.9058 0.8 0.0774

E 0.8206 0.5 0.0701

COMP 0.8963 0.6 0.1111

BLK <0.0100U 3.3 -0.0025

BLK <0.0100U 70.7 -0.0012

Method: Pb (Flame)


CAL ZERO 0.0000 44.2 -0.0028

STANDARD 1 1.0000 0.9 0.0499

STANDARD 2 2.0000 3.2 0.0852

STANDARD 3 5.0000 1.1 0.1933


Pb mg/L

Abs

0.00

0.19

0.10

0.15

0.0000 5.00002.0000 3.0000 4.0000


Pb mg/L

Abs

0.00

0.19

0.10

0.15

0.0000 5.00002.0000 3.0000 4.0000



r = 0.9996

Calculated Conc = -0.0542 1.0589 1.9036 5.0305

Residuals = 0.0542 -0.0589 0.0964 -0.0305

Conc = A

-----------------------------------------

(0.06113 x A x A - 0.07572 x A + 0.05078)

BLK <0.0100U 36.9 -0.0063

GPS <0.0100U 9.2 -0.0045

IH 0.0356 36.6 0.0018

MRC 0.0218 >100 0.0011

LIM 0.0140 >100 0.0007

SAP <0.0100U 26.7 -0.0013

BLK <0.0100U 16.4 -0.0098

A 0.0873 16.8 0.0044

B 0.0380 90.1 0.0019

C 0.0558 36.8 0.0028

D 0.0527 14.3 0.0027

E 0.0798 39.8 0.0040

COMP 0.0369 7.7 0.0032

BLK <0.0100U 62.4 -0.0015



BLK <0.0100U >100 -0.0007

Method: Ca (Flame)


CAL ZERO 0.0000 >100 0.0002

STANDARD 1 0.5000 0.2 0.0951

STANDARD 2 1.0000 1.2 0.1530

STANDARD 3 1.5000 0.4 0.2315


Ca mg/L

Abs

0.00

0.23

0.10

0.15

0.20

0.0000 1.50000.5000 1.0000


Ca mg/L

Abs

0.00

0.23

0.10

0.15

0.20

0.0000 1.50000.5000 1.0000



r = 0.9970

Calculated Conc = 0.0010 0.5358 0.9177 1.5384

Residuals = -0.0010 -0.0358 0.0823 -0.0384

Conc = A

------------------------------------------

(-0.14810 x A x A - 0.14941 x A + 0.19304)

BLK 0.0031 59.8 0.0006

GPS 1.3714 1.1 0.2121

IH 1.1450 0.2 0.1838

MRC OVER 0.0 0.4177

LIM 0.9433 1.8 0.1566

SAP OVER 0.0 0.2630

BLK 0.0217 5.0 0.0042

M089/1 OVER 0.0 0.7518

1 OVER 0.0 0.7895

2 OVER 0.0 1.1418

2 OVER 0.0 1.0951

3 OVER 0.0 0.9045

3 OVERa 0.0 1.5939a

4 OVER 0.0 0.9396

4 OVER 0.0 0.7648

5 OVER 0.0 0.8669

5 OVER 0.0 0.9172

6 OVER 0.0 0.7651

6 OVER 0.0 0.7479

7 OVER 0.0 1.3816

7 OVER 0.0 1.3661

8 OVER 0.0 0.6706

8 OVER 0.0 0.7238



9 OVER 0.0 0.6344

9 OVER 0.0 0.5033

10 OVER 0.0 0.5710

10 OVER 0.0 0.4469

BLK <0.0010U 22.7 -0.0009

BLK <0.0010U 25.7 -0.0017

Method: Al (Flame)


CAL ZERO 0.0000 23.9 -0.0008

STANDARD 1 20.0000 0.5 0.1006

STANDARD 2 50.0000 0.6 0.2472

STANDARD 3 100.0000 0.5 0.4613


Al mg/L

Abs

0.00

0.46

0.20

0.30

0.40

0.0000 100.000050.0000


Al mg/L

Abs

0.00

0.46

0.20

0.30

0.40

0.0000 100.000050.0000



r = 1.0000

Calculated Conc = -0.1619 19.9925 50.0131 99.9939

Residuals = 0.1619 0.0075 -0.0131 0.0061

Conc = A

------------------------------------------

(-0.00257 x A x A + 0.00029 x A + 0.00503)

BLK 0.0426 82.0 0.0002

GPS 11.5656 1.6 0.0583

IH 1.9999 3.7 0.0101

MRC 35.5186 0.8 0.1775

LIM 59.4951 1.0 0.2912

SAP 30.3620 0.5 0.1522

BLK 0.2447 25.5 0.0012

M089/1 29.4199 0.9 0.1475

1 29.5755 2.3 0.1483

2 28.2812 0.7 0.1419

2 27.8832 1.3 0.1399

3 27.7381 1.5 0.1392

3 30.7742 0.9 0.1542

4 29.9878 0.7 0.1503

4 24.9313 33.0 0.1253

5 21.1453 1.1 0.1064

5 22.3420 0.7 0.1123

6 19.6944 0.2 0.0991



6 19.0987 1.4 0.0961

7 16.1620 2.1 0.0814

7 15.9782 0.9 0.0805

10 35.5406 1.3 0.1776

10 31.0711 1.9 0.1557

8 18.3721 0.9 0.0925

8 17.6793 0.2 0.0890

9 19.3952 0.7 0.0976

9 21.2849 1.0 0.1071

BLK 0.0803 51.8 0.0004

BLK 0.1949 29.5 0.0010


Documents

npi.pdf