MASS BALANCETEMPERATURE (°C) 27 27

COMPONENT

RAW MATERIAL STORAGEINPUT OUTPUT

TOTAL Tobacco Leaves TOTAL

Biomass 1318.18418178982 1318.18418178982 1318.18418178982 1318.184182H2O 454.521818465451 454.521818465451 454.521818465451 454.5218185Bio Oil 0 0 0 0Biogas 0 0 0 0Biochar 0 0 0 0Surfactant 0 0 0 0Nitrogen 0 0 0 0

TOTAL 1772.70600025527 1772.70600025527 1772.70600025527 1772.706

1772.70600025527

ENERGY BALANCETEMPERATURE (°C) 27 27 27

RAW MATERIAL STORAGE BELT CONVEYOR 1

INPUT OUTPUT INPUT

Tobacco Leaves

COMPONENTSBiomass 1.81 4771.82673807914 4771.82673807914 4771.826738H2O 4.18 3799.80240237117 3799.80240237117 3799.802402Bio Oil 20.1285 0 0 0Biogas 22.0306 0 0 0Biochar 1.33 0 0 0Surfactant 2.52 0 0 0Nitrogen 815.472 0 0 0

TOTAL 8571.62914045031 8571.62914045031 8571.62914

Raw Tobacco Leaves Feed

Raw Tobacco Leaves Feed

Tobacco Leaves

Cp (kJ/kg°C)

HEAT CAPACITY CALCULATIONBio Oil Biogas

Component Cp (kJ/kg.K) Component Cp (kJ/kg.K)p-Xylene 1.7141 H2 13.12Styrene 1.73 CO 1.036d-Limonene 1.83 CO2 0.826Nicotine 1.19 CH4 2.0872-Pyrrolidinone 1.995 C2H4 1.241Pyridine 1.68 C3H6 1.5306Toluene 1.7075 NH3 2.19Phenol 1.35574-ethylphenol 1.851pentadecane 2.2192Neophytadiene 2.856

TOTAL 20.1285 TOTAL 22.0306

OVERALL ENERGY BALANCEStream INPUT OUTPUTS-106 8571.62914045031 0S-102 0 8571.62914045031S-102 8571.62914045031 0S-103 0 8571.62914045031S-103 8571.62914045031 0S-104 0 8571.62914045031S-104 8571.62914045031 0S-105 0 8571.62914045031S-105 8571.62914045031 0S-112 0 0S-101 0 167433.726795278S-107 0 -111144.220269357S-101 167433.726795278 0S-118 171388.636363636 0S-111 0 97326885.2135237S-111 97326885.2135237 0S-114 0 -4256297.38841455S-113 0 88040428.5048764S-113 88040428.5048764 0S-117 0 283057.03125S-116 0 -13618063.2589936S-116 13618063.2589936 0S-119 0 283057.03125

S-118 0 0S-112 0 -4256297.38841455S-117 283057.03125 0S-119 283057.03125 0S-120 0 566114.0625S-120 566114.0625 0S-121 566114.0625 0S-123 0 570220.875TOTAL 201065399.673755 165029680.705665

TOTAL NO RED 574685.69164045 -3969516.18822936

-4544201.87986981-690.728209518894

574685.69164045 -3969516.18822936

-4544201.87986981-6.90728209518894

MASS BALANCE

27 27 27

BELT CONVEYOR 1 ROTARY CUTTERINPUT OUTPUT INPUT

Tobacco Leaves TOTAL Tobacco Leaves TOTAL Tobacco Leaves

1318.18418179 1318.18418 1318.18418178982 1318.18418178982 1318.18418179454.521818465 454.521818 454.521818465451 454.521818465451 454.521818465

0 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0

1772.70600026 1772.706 1772.70600025527 1772.70600025527 1772.70600026

ENERGY BALANCE27 27 27 27 27

BELT CONVEYOR 1 ROTARY CUTTERS BELT CONVEYOR 2

OUTPUT INPUT OUTPUT INPUT OUTPUT

Tobacco Leaves Fine Tobacco Leaves

4771.82673808 4771.82674 4771.82673807914 4771.82673807914 4771.826738083799.80240237 3799.8024 3799.80240237117 3799.80240237117 3799.80240237

0 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0

8571.62914045 8571.62914 8571.62914045031 8571.62914045031 8571.62914045

Tobacco Leaves

Fine Tobacco Leaves

Fine Tobacco Leaves

OVERALL MASS BALANCEINPUT

Stream Biomass H2OS-106 1318.18418178982 454.521818465S-102 0 0S-102 1318.18418178982 454.521818465S-103 0 0S-103 1318.18418178982 454.521818465S-104 0 0S-104 1318.18418178982 454.521818465S-105 0 0S-105 1318.18418178982 454.521818465S-112 0 0S-101 0 0S-107 0 0S-101 1318.18418178982 45.4521818465S-118 0 0S-111 0 0S-111 0 0S-114 0 0S-113 0 0S-113 0 0S-117 0 0S-116 0 0S-116 0 0S-119 0 0S-118 0 0S-112 0 0S-117 0 0S-119 0 0S-120 0 0S-120 0 0S-121 0 0S-123 0 0TOTAL 1318.18418178982 454.521818465SUM 1897.70600025527

7909.10509073891 2318.06127417

COMPONENT INPUT OUTPUTBiomass 1318.18418178982 0H2O 454.521818465451 409.069636619Bio Oil 0 750

Biogas 0 340.909090909Biochar 0 272.727272727Surfactant 125 125Nitrogen 199.5672 199.5672

TOTAL 2097.27320025527 2097.27320026

27 27 27

ROTARY CUTTER BELT CONVEYOR 2INPUT OUTPUT INPUT

TOTAL TOTAL TOTAL

1318.18418178982 1318.18418179 1318.18418178982 1318.18418179 1318.18418178982454.521818465451 454.521818465 454.521818465451 454.5218184655 454.521818465451

0 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0

1772.70600025527 1772.70600026 1772.70600025527 1772.706000255 1772.70600025527

27 100 90 90

ROTARY DRYER PYROLISIS REACTOR

INPUT OUTPUT INPUT

Flue Gas Exhaust Gas

4771.82673807914 0 155084.368987572 0 155084.3689875723799.80240237117 0 12349.3578077063 111144.2202694 12349.3578077063

0 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0

8571.62914045031 0 167433.726795278 -111144.2202694 167433.726795278

Fine Tobacco Leaves

Fine Tobacco Leaves

Fine Tobacco Leaves

Dried Tobacco Leaves

Dried Tobacco Leaves

INPUT OUTPUTBio Oil Biogas Biochar Surfactant Biomass

0 0 0 0 00 0 0 0 1318.184181789820 0 0 0 00 0 0 0 1318.184181789820 0 0 0 00 0 0 0 1318.184181789820 0 0 0 00 0 0 0 1318.184181789820 0 0 0 00 0 0 0 00 0 0 0 1318.184181789820 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0

750 340.909090909 27.2727272727273 0 00 0 0 0 00 0 0 0 0

750 340.909090909 0 0 00 0 0 0 00 0 0 0 0

562.5 340.909090909 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0

187.5 0 0 0 0562.5 0 0 0 0

0 0 0 0 0750 0 0 0 0

0 0 0 125 00 0 0 0 00 0 0 125 01897.70600025527 1556.79690934618

3562.5 1022.72727273 27.2727272727273 125 6590.92090894909

MASS EFFICIENCY CALCULATION

Mass Input (kg/g)Mass Output (KJ)

Mass Loss (KJ)Efficiency (%)

27 27 -

BELT CONVEYOR 2 ROTARY DRYEROUTPUT INPUT

Fine Tobacco Leaves TOTAL TOTAL

1318.18418178982 1318.18418178982 1318.18418179 1318.18418179454.521818465451 454.521818465451 454.5218184655 454.5218184655

0 0 0 00 0 0 00 0 0 00 0 0 00 0 0 0

1772.70600025527 1772.70600025527 1772.706000255 1772.706000255

27 550 550 550 500

PYROLISIS REACTOR CYCLONE

INPUT OUTPUT INPUT OUTPUT

Sweeping Gas Biochar yang di dalam Pyrolisis Vapor Pyrolisis Vapor Biochar

0 0 0 0 00 0 0 0 00 0 7925596.875 7925596.875 00 0 3942976.704545 3942976.70455 00 171388.636363636 19043.18181818 19043.1818182 17229.545454550 0 0 0 0

325482.9274368 0 85439268.45216 85439268.4522 0325482.9274368 171388.636363636 97326885.21352 97326885.2135 17229.54545455

Fine Tobacco Leaves

OUTPUTH2O Bio Oil Biogas Biochar Surfactant

0 0 0 0 0454.521818465451 0 0 0 0

0 0 0 0 0454.521818465451 0 0 0 0

0 0 0 0 0454.521818465451 0 0 0 0

0 0 0 0 0454.521818465451 0 0 0 0

0 0 0 0 00 0 0 0 0

45.4521818465451 0 0 0 0409.069636618906 0 0 0 0

0 0 0 0 00 0 0 0 00 750 340.9090909091 27.2727272727 00 0 0 0 00 0 0 272.727272727 00 750 340.9090909091 0 00 0 0 0 00 187.5 0 0 00 562.5 340.9090909091 0 00 0 0 0 00 562.5 0 0 00 0 0 0 00 0 340.9090909091 0 00 0 0 0 00 0 0 0 00 750 0 0 00 0 0 0 00 0 0 0 00 750 0 0 125

409.069636618906 750 0 272.727272727 1251556.79690934618

125 6590.92090894909 2272.609092327 4312.5 125

MASS EFFICIENCY CALCULATION

2097.273200255272097.27320025527

0100

90 90 27

ROTARY DRYER PYROLISIS REACTOROUPUT INPUT

Exhaust Gas TOTAL Sweeping Gas TOTAL

1318.18418178982 0 1318.18418179 1318.18418178982 0 1318.184181789845.4521818465451 409.069636619 454.5218184655 45.4521818465451 0 45.452181846545

0 0 0 0 0 00 0 0 0 0 00 0 0 0 0 00 0 0 0 0 00 0 0 0 199.5672 199.5672

1363.63636363636 409.069636619 1772.706000255 1363.63636363636 199.5672 1563.2035636364

500 500 100 100 50

CYCLONE CONDENSER 1 CONDENSER 2

OUTPUT INPUT OUTPUT INPUT OUTPUT

Vapor Vapor Liquid Product Vapor Vapor Liquid Product

0 0 0 0 0 00 0 0 0 0 0

7170778.125 7170778.125 283057.03125 849171.09375 849171.09375 283057.031253567455.11363636 3567455.11364 0 563282.386363636 563282.3863636 0

0 0 0 0 0 00 0 0 0 0 0

77302195.26624 77302195.2662 0 12205609.77888 12205609.77888 088040428.5048764 88040428.5049 283057.03125 -13618063.258994 13618063.25899 283057.03125

Dried Tobacco Leaves

Dried Tobacco Leaves

550 550 500

PYROLISIS REACTOR CYCLONEOUTPUT INPUT OUTPUT

Pyrolisis Vapor TOTAL Pyrolisis Vapor TOTAL Biochar

0 0 0 0 0 00 0 0 0 0 00 750 750 750 750 00 340.909090909091 340.909090909091 340.909090909 340.909090909 0

245.454545455 27.2727272727273 272.727272727273 27.2727272727 27.2727272727 27.272727272730 0 0 0 0 00 199.5672 199.5672 199.5672 199.5672 0

245.454545455 1317.74901818182 1563.20356363636 1317.74901818 1317.74901818 27.27272727273

50 100 50 62.5 62.5

CONDENSER 2 BIO OIL STORAGE MIXING TANK

OUTPUT INPUT OUTPUT INPUT

Fluidizing Gas Fuel Gas Liquid Product Liquid Product Liquid Product Liquid Product

0 0 0 0 0 00 0 0 0 0 00 0 283057.03125 283057.03125 566114.0625 566114.06250 187760.795454545 0 0 0 00 0 0 0 0 00 0 0 0 0 00 4068536.59296 0 0 0 00 -4256297.3884145 283057.03125 283057.03125 566114.0625 566114.0625

Biochar yang didalam

500 500 100

CYCLONE CONDENSER 1OUTPUT INPUT OUTPUT

Vapor TOTAL Vapor TOTAL Vapor

0 0 0 0 0 00 0 0 0 0 0

750 750 750 750 187.5 562.5340.9090909 340.90909091 340.909090909091 340.90909090909 0 340.909090909091

0 27.272727273 0 0 0 00 0 0 0 0 0

199.5672 199.5672 199.5672 199.5672 0 199.56721090.909091 1317.7490182 1290.47629090909 1290.4762909091 187.5 903.409090909091

27 62 50 50 500 550

MIXING TANK BIOGAS STORAGE CHAR COLLECTION TANK

INPUT OUTPUT INPUT OUTPUT INPUT INPUT

Surfactant Biopesticides Biogas Biogas Biochar

0 0 0 0 0 00 0 0 0 0 00 558565.875 0 0 0 00 0 187760.795454545 187760.79545455 0 00 0 0 0 17229.545455 171388.636363636

630 11655 0 0 0 00 0 4068536.59296 4068536.59296 0 0

566114.0625 570220.875 4256297.38841455 -4256297.388415 17229.545455 171388.636363636

Liquid Product

Biochar yang di dalam

100 100 50

CONDENSER 1 CONDENSER 2OUTPUT INPUT OUTPUT

TOTAL Vapor TOTAL Vapor

0 0 0 0 00 0 0 0 0

750 562.5 562.5 562.5 0340.909090909091 340.9090909091 340.909090909 0 340.9090909

0 0 0 0 00 0 0 0 0

199.5672 199.5672 199.5672 0 199.56721290.47629090909 1102.976290909 1102.97629091 562.5 340.9090909

500 50

CHAR COLLECTION TANK NITROGEN RECOVERY UNIT

OUTPUT INPUT OUTPUT

Biochar Vapor Nitrogen Biogas

ENERGY EFFICIENCY CALCULATION0 0 0 0 Energy Input (KJ)0 0 0 0 Energy Output (KJ)0 0 0 0 Energy Loss (KJ)0 187760.7954545 0 187760.7955 Efficiency (%)

172295.454545455 0 0 00 0 0 00 4068536.59296 4068536.59296 0

-172295.454545455 4256297.388415 4068536.59296 -187760.795

Liquid Product

50 100 50 62.5 62.5

CONDENSER 2 BIO OIL STORAGE MIXING TANKOUTPUT INPUT OUTPUT INPUT

TOTAL Liquid Product TOTAL TOTAL Liquid Product

0 0 0 0 0 0 00 0 0 0 0 0 0

562.5 187.5 562.5 750 750 750 750340.90909091 0 0 0 0 0 0

0 0 0 0 0 0 00 0 0 0 0 0 0

199.5672 0 0 0 0 0 01102.9762909 187.5 562.5 750 750 750 750

ENERGY EFFICIENCY CALCULATIONEnergy Input (KJ) 210,092,095.56

Energy Output (KJ) 168,926,779.23 Energy Loss (KJ) -41165316.3293956

Efficiency (%) 80.4060613419553

Liquid Product

Liquid Product

27 62 50 50

MIXING TANK BIOGAS STORAGEINPUT OUTPUT INPUT OUTPUT

Surfactant TOTAL Biopesticides TOTAL Biogas TOTAL Biogas

0 0 0 0 0 0 00 0 0 0 0 0 00 750 750 750 0 0 00 0 0 0 340.9090909 340.909090909091 340.9090909090 0 0 0 0 0 0

125 125 125 125 0 0 00 0 0 0 0 0 0

125 875 875 875 340.9090909 340.909090909091 340.909090909

50 500 550 500 50 50

BIOGAS STORAGE CHAR COLLECTION TANK NITROGEN RECOVERY UNITOUTPUT INPUT OUTPUT INPUT OUTPUT

TOTAL Biochar TOTAL Biochar TOTAL Vapor TOTAL Biogas

0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0

340.9091 0 0 0 0 0 340.9091 340.9091 340.90910 27.2727273 245.454545455 272.727273 272.7273 272.7273 0 0 00 0 0 0 0 0 0 0 00 0 0 0 0 0 199.5672 199.5672 0

340.9091 27.2727273 245.454545455 272.727273 272.7273 272.7273 540.4763 540.4763 340.9091

Biochar yang di dalam

50

NITROGEN RECOVERY UNITOUTPUT

Nitrogen TOTAL

0 00 00 00 340.90910 00 0

199.5672 199.5672199.5672 540.4763

Material Balance kg/hStream 1 Stream 2 Stream 3 Stream 4 Stream 5

P (bar)T (°C) 27 27 27 27 27

Component

Biomass 1318.18418179 1318.18418179 1318.18418179 1318.18418179 1318.18418179H2O 454.521818465 454.521818465 454.521818465 454.521818465 454.521818465Bio Oil 0 0 0 0 0Biogas 0 0 0 0 0Biochar 0 0 0 0 0Surfactant 0 0 0 0 0Nitrogen 0 0 0 0 0Oksigen 0 0 0 0 0

Total 1772.70600026 1772.70600026 1772.70600026 1772.70600026 1772.70600026

utility

Raw Tobacco Leaves

Raw Tobbacco Leaves Feed

Tobacco Leaves

Tobacco Leaves

Fine Tobacco Leaves

Stream 6 Stream 7 Stream 8 Stream 9 Stream 10 Stream 11 Stream 12

27 27 27 100 90 90 27

Air Air Hot Air Exhaust Gas Nitrogen

1318.18418179 0 0 0 0 1318.18418179 0454.521818465 0 0 0 409.069636619 45.4521818465 0

0 0 0 0 0 0 00 0 0 0 0 0 00 0 0 0 0 0 00 0 0 0 0 0 00 1580 1580 1580 1580 0 199.56720 420 420 420 420 0 0

1772.70600026 2000 2000 2000 2409.06963662 1363.63636364 199.5672

Fine Tobacco Leaves

Dry Tobacco Leaves

Stream 13 Stream 14 Stream 15 Stream 16 Stream 17 Stream 18 Stream 19

27 550 500 500 100 50 50

Nitrogen Vapor Biochar Vapor Vapor Biogas Biogas

0 0 0 0 0 0 00 0 0 0 0 0 00 750 0 750 562.5 0 00 340.909090909 0 340.909090909 340.909090909 340.909090909 340.9090909090 27.2727272727 27.2727272727 0 0 0 00 0 0 0 0 0 0

199.5672 199.5672 0 199.5672 199.5672 199.5672 00 0 0 0 0 0 0

199.5672 1317.74901818 27.2727272727 1290.47629091 1102.97629091 540.476290909 340.909090909

Stream 20 Stream 21 Stream 22 Stream 23 Stream 24 Stream 25

100 50 62.5 27 27 27

Bio Oil Bio Oil Bio Oil Surfactant Surfactant Surfactant

0 0 0 0 0 00 0 0 0 0 0

187.5 562.5 750 0 0 00 0 0 0 0 00 0 0 0 0 00 0 0 125 125 1250 0 0 0 0 00 0 0 0 0 0

187.5 562.5 750 125 125 125

Stream 26 Stream 27

62 62

Biopesticide Biopesticide

0 00 0

750 7500 00 0

125 1250 00 0

875 875