NATURAL RESOURCE TECHNOLOGY

NATURAL

RESOURCE

TECHNOLOGY

Ms. Mary Logan United States Environmental Protection Agency 77 West Jackson Boulevard / SR-6J Chicago, IL 60604-3507

Ms. Kristen DuFresne 2984 Shawano Ave P.O. Box 10448 Green Bay, Wl 54307-0448

September 20, 2005 (1549)

EPA Region 5 Records Ctr.

364525

RE: Groundwater Monitoring Update: 2004 Well Construction, Repair and Abandonment; and November 22,2004 and April 13 <& 14, 2005 (jroundwater Sampling Events Former Manufactured Gas Plant Site, 1603 Ely Street, Marinette, Wisconsin EPA ID# WIN000509952 Wl BRRTS ID # 02-38-000047

Dear Ms. Mary Logan and Ms. Kristen DuFresne:

On behalf of Wisconsin Public Service Corporation (WPSC), Natural Resource Technology, Inc. (NRT) is pleased to provide this update of recent monitoring well construction activities (repair, new construction, abandonment, and replacement) and groundwater monitoring data for wells sampled November 22 and December 2,2004 and April 13 and 14, 2005 at the former Manufactured Gas Plant (MGP) located in Marinette, Wisconsin (Figure 1).

Site monitoring wells were sampled utilizing low-flow techniques in general accordance with ASTM Standard Practice for Low-Flow Purging and Sampling for Wells and Devices Used for Ground-Water Quality Investigations (Publication D 6771-02) and dedicated bailers following WDNR guidelines as specified in Groundwater Sampling Desk Reference (WDNR PUBL-DG-037 96) and Groundwater Sampling Field Manual (WDNR PUBL-DG-038 6). Depth to water was also measured in all site monitoring wells and piezometers. Water table and piezometric surface elevations are summarized on Table 1 and the water table elevations are contoured on Figures 2 and 3. Analytical results are summarized in Tables 2 through 4 and on Figures 4 and 5.

Generally, the data indicate MGP-related constituents have not migrated vertically downward to the bedrock aquifer, constituent concentrations exceeding groundwater quality standards are predominantly present within the former MGP slough, and their extent is defined in the downgradient direction.

WELL CONSTRUCTION, REPAIR, AND ABANDONMENT

The following well construction, repair and abandonment activities were scheduled to be completed in 2004 and 2005, as proposed in NRT's June 21, 2004 letter to Ms. Cathy Rodda, WDNR:

• Construct three shallow monitoring wells and one piezometer, MW-308, MW-309, MW-310 and P-305, to monitor downgradient groundwater quality near Boom Landing Park;

• Repair or replace MW-1 and MW-3;

• Repair or abandon MW-2; and.

23713 W. Paul Rd., Ste. D • Pewaukee, Wl 53072 • Phone: 262.523.9000 • Fax: 262.523.9001 • vwvw.naturairt.com Pewaukee • Madison

http://vwvw.naturairt.com

Ms. Mary Logan and Ms. Kristen DuFresne USEPA and WDNR September 20, 2005 Page 2

• Abandon MW-301 and P-301 prior to the City of Marinette brick interceptor sewer project to prevent downward migration of contaminants along a preferential pathway created by disturbance to the well nest.

The following well construction, abandonment and repair activities were completed as planned:

Groundvfater Monitoring Well/ Piezometer MW-308, MW-310, P-305 MW-1 MW-301/P-301

Activity, Date Installed and developed June 2004. Redeveloped June 2004. Abandoned January 27, 2004.

Trace tar droplets were observed in water from drill cuttings during installation of P-305 at 27 feet below ground surface (bgs), within shallow fractured bedrock. During drilling and well installation activities, approximately 500 gallons of groundwater with trace emulsified tar and sheen were purged from this bedrock interval. The purge water was treated and disposed with the on-site trench water treatment system utilized during the interceptor sewer construction activities conducted by the City of Marinette. NRT did not observe tar, sheen, or odor in the water during subsequent well development or sampling activities.

Deviations to the proposed well repair, replacement and/or installation activities are detailed below:

Location MW-2

MW-3

MW-4

MW-307

MW-309

MW-311

Activity, Date Removed in

2004 Abandonment

Scheduled, Replaced in

October 2004

Abandoned in April 2005 Abandoned

and replaced in October

2004 Installation Postponed

Installed in October 2004

Deviation Description Well was removed during utility construction activities by the City of Marinette. Well could not be located for abandonment. Well location had been determined by WPSC survey crew and staked. Location was subsequently buried with approximately 20 feet of sand by the City of Marinette. Well is scheduled for abandonment concurrent with future drilling activities. Well was damaged and could not be repaired

City of Marinette construction activities damaged the well.

Well is scheduled to be installed upon completion of the construction activities planned at Boom Landing Park as part of WPSC s sediment remediation project.

Initially intended to replace well MW-2; the location was moved per City of Marinette requests and the location of a new utility corridor installed through the former MW-2 location. The well was too far from MW-2 to be considered a replacement well, and was likely within the former MGP operational slough. Well MW-311 now serves to monitor groundwater quality within the former slough.

Replacement To be

evaluated MW-3R

To be evaluated MW-307R

N/A

N/A

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NATURAL RESOURCE TECHNOLOGY


Monitoring wells were constructed and developed in accordance with Wisconsin Administrative Code NR 141. WDNR Soil Boring Log Information, Monitoring Well Construction, Monitoring Well Development and Borehole Abandonment forms are included in Appendix A.

New site wells were surveyed on January 22, 2005 (Appendix B). Survey data from wells MW-308, MW-310, MW-311, and P-305 were inconsistent with previous elevation data, which is likely due to errors in the new survey data. Correspondingly, groundwater elevations from those wells were not used in the construction of groundwater elevation contours as discussed in detail below. An additional survey will be conducted for the wells and.water level elevation data will be included in future groundwater flow analysis thereafter.

GROUNDWATER FLOW DIRECTION AND GRADIENTS

Prior to sampling, elevation measurements in water table wells and piezometers were recorded during both the November 2004 and April 2005 sampling rounds (Table 1). Water table elevations for both rounds (Figures 2 and 3) indicate a generally east-northeast flow for shallow groundwater, similar to historic flow direction interpretations. Piezometric surface elevations could not be contoured for either event due to uncharacteristic groundwater elevations. Evaluation of deep groimdwater flow will be addressed in a groundwater quality update to be issued in early 2006 as discussed below.

ANALYTICAL DATA

Groundwater analytical samples were analyzed by Pace Analytical (formerly En Chem, Inc., Green Bay, Wisconsin) for petroleum volatile organic compounds (PVOCs; including benzene, toluene, ethylbenzene, and total xylenes [BTEX]; 1,2,4- and 1,3,5-trimethylbenzenes [TMBs]; and methyl tert-butyl ether [MTBE], Table 2), available cyanide (OIA-1677 Method, Table 2) and polynuclear aromatic hydrocarbons (PAHs, Table 3). Remedial natural attenuation (RNA) parameters analyzed included dissolved iron, dissolved manganese, nitrate and nitrite, sulfate and methane (Table 4). Limited RNA analytical data has been collected from monitoring wells. Therefore, these data are presented for informational purposes and will be evaluated following subsequent sampling events.

Samples collected from MW-4 on November 22, 2004 were inadvertently damaged after collection. However, a quality control field duplicate sample was also collected from MW-4 (labeled QC-2) and submitted for analysis. Additionally, piezometer P-304 did not recover following sampling purge activities on November 22, 2004; therefore, analytical samples were not collected.

The method of cyanide analysis for the site was transitioned to available cyanide analysis by the OIA-1677 Method for the November 2004 sampling event. Cyanide results from this sampling round appeared to be high (11 to 600 \ig/L), in some cases higher than historic total cyanide concentrations (6 to 474 jxg/L), likely due to sulfide interference. Consequently, future samples for available cyanide will be preserved with lead carbonate to modify the likely effects of sulfide. The samples collected for cyanide analysis during the April 2005 sampling event were field preserved with lead carbonate. The resulting cyanide concentrations were lower, with 10 of the 14 samples indicating non-detects and four samples with concentrations ranging from 5.1 to 8.0 |ig/L, well below the NR 140 Preventive Action Limit (PAL) of 40 ^lg/L. These data indicate the

NATURAL

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November 2004 cyanide samples likely do not represent actual groundwater quality conditions. Therefore, November 2004 cyanide data will not be used when evaluating groundwater quality trends in this and future reports.

Based on a review of the historic and recent analytical data for PVOCs, cyanide, and PAHs in Tables 2 and 3 and Figures 4 and 5, the site groundwater quality has generally remained stable or fluctuated within probable seasonal variations between August 2003 and April 2005. The apparent decline in PAH concentrations observed in most site wells (except MW-305 and MW-306 as discussed below) is likely due to implementation of low-flow sampling techniques and not likely an indication of groundwater quality trends. A number of the wells have had insufficient water volume for low-flow sampling. Therefore, a complete assessment of the impact of low-flow sampling on the groundwater quality data set cannot be evaluated at this time. PAH concentrations will continue to be monitored and assessed for quality trends with samples collected using low-flow techniques.

MGP-related constituent concentrations that exceed Wisconsin groundwater quality standards for PVOCs and PAHs (benzo(a)pyrene [BaP], benzo(b)fluorene [BbF], chrysene, fluoranthene, fluorene, naphthalene, and pyrene) are predominately present in shallow wells located within the former slough (MW-301 (historically), MW-302, and MW-311). A few constituent concentrations (benzene, BaP, BbF, chrysene, and naphthalene) were slightly above PALs in side- and downgradient wells MW-303, MW-304, MW-307R, and MW-308. Constituent concentrations exceeding groundwater quality standards were not detected in samples collected from MW-1, MW-2 (historically), MW-3R (MW-3 historically), and MW-5. Generally, MGP-related constituents were not detected in piezometers except P-302 and P-303. PAH concentrations exceeding PALs or ESs were only detected in samples that could not be collected with true low-flow samphng techniques due to insufficient water volumes within the wells.

Samples collected from upgradient wells MW-305 and MW-306 have contained fluctuating concentrations of PAHs that exceed PALs or ESs. MW-306 samples have also contained fluctuating concentrations of PVOCs as detailed below. Additional sampling rounds are required to assess these trends and determine if these constituent concentrations are related to an off-site source or MGP-related residuals.

Of note during the November 2004 and April 2005 sampling events:

• Cyanide concentrations did not exceed the NR 140 PAL of 40 mg/L in wells sampled during the April 2005 sampling event. As previously noted, the November 2005 cyanide data is likely skewed high due to sulfide interference and not representative of groundwater quality.

• Tar was not noted in any monitoring well or piezometer during either the November 2004 or the April 2005 sampling events. Tar has largely been noted in MW-301 in the past. As previously stated, MW-301 was abandoned January 27, 2004;

• Continued BTEX and naphthalene concentration fluctuations in samples collected from MW-306 since August 2002 suggest a potential off-site source area, possibly related to historical placement of MGP-related fill off-site. However, the ratio of benzene to ethylbenzene, xylenes, and TMBs is dissimilar to those observed in MW-301, MW-302, MW-304, and MW-311 samples, indicating a potential non-MGP source area.

NATURAL

RESOURCE e* 9 W ^ ^ ^ KESOURCE

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• Benzene was detected just above the PAL at MW-307R during both sampling events. PAH compounds were not detected above standards at this location during either event, suggesting the extent of concentrations of MGP residuals above groundwater quality standards is defined in the northern (downgradient) direction.

• Benzene was detected above the ES in MW-311, which appears to be within the former MGP slough. Benzene was detected just below the PAL downgradient of MW-311 at MW-308 and MW-310, along the northern (leading) edge of the plume.

• Naphthalene was detected just above the PAL in MW-308. All other MGP-related constituent concentrations in this well were below detection limits or considerably below their respective PALs.

• Benzene concentrations dropped below the ES of 5 jxg/L in MW-304 for the first time in April 2005. Benzene also remained near the PAL in MW-302. Naphthalene concentrations at these two wells have also decreased over the past few years, suggesting that the extent of MGP-related impacts is defined to the south (side-gradient).

• BTEX compounds were not detected in MW-305 samples from either sampling event. BaP, BbF and chrysene were detected at or slightly above their respective ESs in the April 2005 samples, similar to historic levels, suggesting that the southwestern extent of elevated concentrations is defined and the plume is stable in that direction.

• BaP, BbF and chrysene were detected just above the PAL in the sample fi-om P-303 in November, 2004. These concentrations were detected between the limit of detection and the limit of quantitation and therefore are estimated concentrations. These detections were the only MGP-related constitoent concentrations that exceeded groundwater quality standards in all piezometers during the November 2004 and April 2005 sampling events.

CONCLUSIONS

The extent of MGP-related impacts for BTEX (Figure 4) and PAHs (Figure 5) suggest that BTEX and PAH compounds have not migrated vertically downward to the piezometers. MGP-related constituent concentrations appear to be highest at shallow wells in the vicinity of the former slough (Figures 4 and 5) that traversed the former MGP facility, including wells MW-301 (historically), MW-302, MW-307R, and MW-311. Overall, the groundwater analytical data suggest the downgradient extent of groundwater impacts has been defined.

PROJECT DIRECTION

One additional round of groimdwater sample collection is tentatively scheduled for the week of September 26, 2005. USEPA, WPSC, and NRT have agreed to continue with annual site monitoring until USEPA has had an opportunity to review all project files. NRT recommends annual sampling commence in September 2005, in accordance with previous recommendations to WDNR. Groundwater analytical samples will be collected with low-flow sampling techniques from the 17 site monitoring wells as detailed in the table below. A brief groundwater quality update report summarizing groundwater data collected in September 2005 will be submitted to USEPA in January 2006.

SNATURAL RESOURCE

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Sampling Event Date September 2005

2006

Water Level Measurement

Collected All Monitoring

Wells

To Be Determined

Well Samples Analyzed for Constituents of

Concern (COC) All Monitoring Wells

To Be Determined

Well Samples Analyzed for Remedial Natural Attenuation

(RNA) Parameters MW-302, MW-304, MW-306, MW-310, MW-311, MW-305,

MW-308, MW-5, P-302, P-303, P-305

To Be Determined Monitoring Weils: Monitoring Wells: MW-302, MW-303, MW-304, MW-305, MW-306, MW-307R, MW-308,

MW-310, MW-311, MW-1, MW-3R, MW-4, MW-5, P-302, P-303, P-304, and P-305. COC: Petroleum volatile organic compounds (PVOCs, SW846 8021B), polynuclear aromatic hydrocarbons (PAHs,

SW846 8270), and available cyanide (OIA-1677). RNA: Sulfate (EPA 300.0), dissolved ferrous iron (SW846 6010), nitrate-i-nitrite (EPA 300.0), dissolved manganese

(SW846 6010), methane (EPA 8015 MOD), alkalinity (EPA 310.2), and field measured parameters (temperature, field conductivity, pH, dissolved oxygen, and oxidation/reduction potential).

Please contact the undersigned at 262.523.9000 or Ms. Shiriey Scharff at 920.433.1396 if you have any questions or comments regarding this update or the schedule of future activities.

Sincerely,

NATURAL RESOURCE TECHNOLOGY, INC.

Paula A. Richardson Hydrogeologist

Rebecca J. Cai^ll, Senior Hydrogeologist

Weber, PE Senior Engineer / Project Manager

cc: Ms. Shirley Scharff, Wisconsin Public Service Corporation (w/attach)

Attachments: Figures 1,2,3,4, and 5 Tables 1,2, 3, and 4 Appendices A, B, and C

[P:\1549\Rpts & Wik Plns\Gmdwtr Qulty Updts\2005 April Sanip\1549 EPA GW Qlty Updt 050920 Ltr.doc]

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NATURAL

RESOURCE

TECHNOLOGY

FIGURES

Figure 1 Site Location Map (1549/A02gw) Figure 2 Groundwater Elevation Contours, November 22, 2004 (1549-9-BO6.DWG)

Figure 3 Groundwater Elevation Contours, April 13 & 14, 2005 (1549-9-B07.DWG)

Figure 4 Groundwater Benzene, Total BTEX, and Cyanide Analytical Summary (I549-9-B04.DWG)

Figure 5 Groundwater Naphthalene and PAH Analytical Summary (I549-9-B05.DWG)

r

SOURCE: u s e s 7.5 MINUTE QUADRANGLE, MARINETTE EAST. DATED 1963. PHOTOREVISED 1976.

(vy WISCONSIN i:

QUADRANGLE LOCATION

0 2000 4000

SCALE IN FEET CONTOUR INTERVAL 10 FEET


SITE LOCATION MAP FORMER MARINETTE MANUFACTURED GAS PLANT

WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE, WISCONSIN

DRAWN BYiTAS APPROVED BY: RJC DATE: 04 /01 /05

PROJECT NO. 1549

DRAWING NO. 1549-A02gw

FIGURE NO. 1

" "^"OMlNEERiVEf ,^

LEGEND

<s

* MW-5

583.56

* P-301

MW-2

(579.19)»

NGVD

I 1 I I

WATER TABLE ELEVATION CONTOUR, FT. (NGVD)

SHALLOW GROUNDWATER FLOW DIRECTION

MONITORING WELL AND WATER TABLE ELEVATION, FT. (NGVD)

PIEZOMETER

ABANDONED MONITORING WELL

WATER TABLE ELEVATIONS NOT USED FOR CONTOURING

NATIONAL GEODETIC VERTICAL DATUM

CITY OF MARINETTE PROPOSED BRICK INTERCEPTOR SEWER REPLACEMENT

FORMER SLOUGH

FORMER MGP STRUCTURE

EXISTING STRUCTURE

l l l l l l l l l l l l l l l l l l l l RAILROAD

NOTE: • SURVEY DATA FOR WELLS MW-2R, MW-308 . M W - J t O AND MW-311 ARE INCONSISTENT

wnH PREVIOUS SITE ELEVATION DATA. CONSEQUENTLY, THESE WELLS WERE NOT USED IN CONSTRUCTION OF CONTOURS. WELLS WILL BE RESURVEYED IN 2005.

I 40 80 160

SCALE IN FEET

SOURCE NOTE: t . THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CITY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL HLE FROM STS CONSULTANTS. LTD.

CONSULTING ENGINEERS, GREEN BAY. WISCONSIN. PROJECT NUMBER 26936. REVISED JANUARY 2 0 0 t . HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 2 4 - 2 6 , 2 0 0 1 . VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPUED BY MARINETTE MARINE CORPORATION.

3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILITIES FROM FOTH i t VAN DYKE ENGINEERS/ARCHrTECTS,

GRADING PLAN, DIGITAL FILE 7m755c06.DWG. RECORD DRAWING REVISIONS 2 / 2 2 / 9 0 . 5. WEIX LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8, 2003, REVISED

OCTOBER 3 1 , 2003. 6. BRiCK INTERCEPTOR SEWER REPLACEMENT TAKEN FROM DRAWING BY AYRES

ASSOCIATES, GREEN BAY, WISCONSIN, JOB NO. 1 6 - 0 1 8 9 . 1 0 . DRAWING NO. P101 . SHEET NO. 7. DATED 3 / 1 4 / 0 3 .

7. MONITORING WELLS MW-2R. MW-3R. MW-307R INSTALLED OCTOBER 2004 AND MW-305, MW-310, P - 3 0 5 INSTALLED JUNE 2004 . SURVEYED BY WPSC IN JANUARY 2005. CNGVD88. MARINETIE COUNTY COORDINATES).


PROJECT NO.

1549/9

DRAWN BY; RLH/

TAS 04/04/05

CHECKED BY:

PAR 04/04/05

APPROVED BY;

RJC 09/20/05

GROUNDWATER ELEVATION CONTOURS, NOVEMBER 22, 2004

NOVEMBER 2004 GROUNDWATER QUALITY UPDATE FORMER MARINETTE MANUFACTURED GAS PLANT SITE


DRAWING N 0 ; 1 5 4 9 - 9 - B 0 6

REFERENCE; •

FIGURE NO.

""^"ÔMINEERIVEH^

LEGEND

<s "b ^

MW-5

584.04

^ P-301

MW-2

(579.65)*

NGVD

" -1

CZZl

l l l l l l l l l l l l l l l l l l l l

WATER TABLE ELEVATION CONTOUR, FT. (NGVD)

SHALLOW GROUNDWATER FLOW DIRECTION

MONITORING WELL AND WATER TABLE ELEVATION, FT. (NGVD)

PIEZOMETER


WATER TABLE ELEVATIONS NOT USED FOR CONTOURING

NATIONAL GEODETIC VERTICAL DATUM


FORMER SLOUGH


EXISTING STRUCTURE

RAILROAD

NOTE: • SURVEY DATA FOR WELLS MW-2R, MW-308, MW-310 AND MW-311 ARE INCONSISTENT

WITH PREVIOUS SITE ELEVATION DATA CONSEQUENTLY. THESE WELLS WERE NOT USED IN CONSTRUCTION OF CONTOURS. WELLS WIU BE RESURVEYED IN 2005.

I 40 80 160

SCALE IN FEET

SOURCE NOTE: 1. THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CITY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL FILE FROM STS CONSULTANTS. LTD.

CONSULTING ENGINEERS. GREEN BAY, WISCONSIN, PROJECT NUMBER 26936. REVISED JANUARY 2001. HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 24-26, 2001. VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPUED BY MARINETTE MARINE CORPORATION.

3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILmES FROM FOTH 4 VAN DYKE ENGINEERS/ARCHITECTS.

GRADING PLAN. DIGITAL FILE 7m755c05.DWG. RECORD DRAWING REVISIONS 2/22/90. 5. WaL LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8. 2003, REVISED

OCTOBER 31. 2003. 6. BRICK INTERCEPTOR SEWER REPLACEMENT TAKEN FROM DRAWING BY AYRES

ASSOCIATES, GREEN BAY, WISCONSIN, JOB NO. 16-0189.10. DRAWING NO. PlOl . SHEET NO. 7, DATED 3/14/03.

7. MONITORING WELLS MW-2R. MW-3R. MW-307R INSTALLED OCTOBER 2004 AND MW-308. MW-310. P-305 INSTALLED JUNE 2004. SURVEYED BY WPSC IN JANUARY 2005. (NGVDSS. MARINETTE COUNTY COORDINATES).


PROJECT NO. 1549/9

DRAWN BY: RLH/

TAS 09/07/05

CHECKED BY:

PAR 09/07/05

APPROVED BY; RJC 09/20/05

GROUNDWATER ELEVATION CONTOURS, APRIL 13 & 14, 2005

APRIL 2005 GROUNDWATER QUALITY UPDATE FORMER MARINETTE MANUFACTURED GAS PLANT SITE


DRAWING N0;1549-9-B07 FIGURE NO.

'^^ 'ÔM,NEER,VHR^ MW-1

04/13/94

osnam 08/27/02 08/13/03 MW-1

11/22A)4 04/13/05

BEN <0.7 <0.7

BTEX 3.7 nd

CYNW/U) <3J <3.5

WeU could not be located WeU could not be located

BEN <0.14 <0.I4

BTEX nd nd

CYNAVL 54 Z <5.0

MW-311 11/22/04 04/13/05

BEN SSOK 260

BTEX 2,619 1.335

CYNAVL 12 Z <5.0

MW-2 04/14/94 05/11/94 08/27/02 08/13/03 11/22A)4

BEN <0.7 <0.7

BTEX nd nd

CYNWAD <3.5 <3.5

WeU could not be located WcU could not be localed

WeU abandoned October 2004

Diy WcU

0.14 I nd I

MW-4 (wiAm OS/11/94 O8C7/02 08/14/03 MW-4

11/22/04

04/13A>S

BEN 13

<17.5 0.48 OJO BEN

0.15 0

BTEX 1.943 2,789

nd nd

BTEX 0.2

CYNWAD <3.5 <3.5 40 0

L CYNAVL

I IZ WeU abandoned April 2005 |

< 6 . 0 X

0.20Q

<0M

MW-305

oenAm 08/12/96 08a7/02 08/14/03 MW-305 11/22/04 04/14/05

BEN

<oso <0.50 <0.4« <0J0 BEN 0.14 <0.14

BTEX nd nd nd nd

BTEX nd nd .,

CYNWAD

/ - / - ' / 19/'/

,U / OVNAVL ~

/ /22Z ' /• <5.0

<7

/ •

^ ^

05/10/94

umii>-_A. . ' °5BTSO3/ MW-3a2

liMO

0.76 O

3,090

LEGEND

/

^ MW-1

^ P-301

, SB-333

^ MW-2

A HP-301

t ^ TP-305

L-_~_"_l

l l l l l l l l l l l l l l l l l l l l

1 1

1 1

APPROXIMATE EXTENT OF BTEX CONCENTRATIONS THAT EXCEED AN NR140 ES

APPROXIMATE EXTENT OF BTEX CONCENTRATIONS THAT EXCEED AN NR140 PAL

MONITORING WELL

PIEZOMETER'

SOIL BORING


HYDRO-PUNCH SAMPLE

TEST PIT

CIIY 01- MAKINLIIL PROPOSED BRICK INTERCEPTOR SEWER REPUCEMENT


FORMER SLOUGH

RAILROAD

EXISTING STRUCTURE

FORMER WASTE WATER TREATMENT PLANT STRUCTURE

SA1>(PI.H LOCATION

SAMn£DA-m

BEN

BENZENE 0*1)

BTEX

BENZENE, TOUTOffi,

ETHYLBENZENE, TOTAL

XYLENE 01*1.)

CYNWAD

CYANIDE, WEAK ACID

DISSOCIABLE UlS/L. t-UlLU FILTERED)

CYNAVL

CYANIDE AVAILABLE

01A.16T7 ( M / Z U F I E U J FILTERED)

Waaniun Oiuimlwmi Qnilily Sanlcili (NH 1«, 2003)

EntonxoKBt Stmlxnl (ES) OJ 9

n m

40 200

40 200

N B E N ~ B T E X / ^ e V N A Y K

y ^^.x/^

DATA QUALIFIERS:

£ « CaNCENTRAnON ATT/UNS OR EXCEEDS AN NR 140 PREVENTIVE ACnON LMTT

4 C CONCENTRATtON ATT/UNS OR EXCEEDS AN NR 1 « ENFORCEMENT STANDARD

n d NOT DETECTED

01 STANDARD DAS NOT BEEN ESTABLISHED

ANALYSIS NOT PERFORMED

MtCROORAMS PER LITER

CONSnTUBNr WAS NOT IDENnFIHD ABOVE THE UMTT OP DHTBCTION INDICATED.

L/ÔRATORY NOTE-PRECISION NOT WTTHIN CONTROL LIMTTS.

LABORATORY NOTE-DETECTION UMIT MAY BE ELEVATED DUE TO THE PRESENCE OP /W UNREQUESTED ANALYTE.

CYANIDB ANALYSIS W/IS NOT PERFORMED DUE TO LABORATORY ERROR.

LABORATORY NOTE - THE ANALYTE HAS BEEN DETECTED BETWEEN THE UMTT OF DBTECnON (LOD) AND LIMTT OF QUANnTATION (LOQ).

ftli-

P-302 06/24^6 0S/12M 08/27/02 08/13/03

P-302 11/22/04 (M/14/05

BEN <0.50 O.50 0.48 OJO BEN 0.14 <0.I4

BTEX nd nd nd nd

BTEX nd nd

CYNWAD

_ -13 L

CYNAVL <5Z <5.0

AV/ULABLB CY/WIDB RESULTS MAY BE BIASED HIGH DUE TO INTERFERENCE OF SULFIDE WTTH /^NALYSIS METHOD. SAMPLES WERE NOT FIELD PRESERVED WITH LEAD CARBONATE.

NOTE; I. DUPUCATE S/UrfPLES WERE COLLECTED DURINO EACH

SAMPUNO EVENT. BENZENE. BENZENE, TOLUENE, ETHYLBENZENE, TOTAL XYLENE, CY/UflDE-WEAK ACID DISSOCIABLE. AND CYANIDE-AVAILABLB CONCENTRATIONS SHOWN REFLECT THE HtOHER CONCENTRATION BETWEEN WELL SAMPLES /WD DUPUCATE SAMPLES.

SOURCE NOTE: 1. THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CHY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL RLE FROM STS CONSULTANTS. LTD. CONSULTING ENGINEERS.

GREEN BAY, WISCONSIN, PROJECT NUMBER 26936, REVISED JANUARY 2001. HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 24-26, 2001. VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPUED BY MARINETTE MARINE CORPORATION.

3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILITIES FROM FOTH & VAN DYKE ENGINEERS/ARCHITECTS. GRADING PLAN, DIGITAL

RLE 7m755c06.DWG. RECORD DRAWING REVISIONS 2/22/90. 5. WELL LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8. 2003, REVISED OCTOBER 31. 2003. 6. BRICK INTERCEPTOR SEWER REPLACEMENT T/kKEN FROM DRAWING BY AYRES ASSOCIATES, GREEN BAY. 0

WISCONSIN, JOB NO. 16-0189.10, DRAWING NO. P101. SHEET NO. 7, DATED 3/14/03. 7. MONITORING WELLS MW-2R. MW-3R. MW-307R INSTALLED OCTOBER 2004 AND MW-308. MW-310, P-305

INSTALLED JUNE 2004. SURVEYED BY WPSC IN JANUARY 2005. (NGVDSS. MARINETTE COUNTY COORDINATES).

40 80 160

SCALE IN FEET

MW-5 04/14/94 05/11/94 08^7/02 08/14/03 MW-5

11/22/04 04/14/05

BEN 0 .7 0 .7 0.4S OJO BEN 0.75

0.14

BTEX nd nd nd nd

BTEX 1.4 nd

CYNWAD <3.5 \ <3.5 <2.7

L CYNAVL

<5Z <5.0


PROJECT NO.

1549/9

DRAWN BY: RLH/

TAS 09/12/05

CHECKED BY;

PAR 09/12/05

/APPROVED BY:

RJC 09/20/C5

GROUNDWATER BENZENE, TOTAL BTEX, AND CYANIDE ANALYTICAL SUMMARY


WISCONSIN PUBLIC SERVICE CORPORATION MARINETTE. WISCONSIN

DRAWING NO;1549-9-B04

REFERENCE: \CAD TABLES APRIL 2005.XLS FIGURE NO.

MW-1

04/13/94

05/10/94

attiim OS/13/03

11/22A>4

04/13/05

~—-_ NAPH

<1.10

<1.10

PAH

nd

nd

WeU could not be located


0.14

0.055 0

02

0.1

MW-307

oenAm 0&'13/96

08^7/02

08/13/03

MW-307R

ni22m 04/13/05

NAPH

<1.0

<1.0

<0.067

0.033 Q*

NAPH

3.2 D

0.55 0

PAH

I J

nd

1.9

0.2

PAH

31

15

MW-311

11/22/04

04/13/05

NAPH

3J00D

2,000 D

PAH

3,969

2,679

MW-2

04/14A>4

05/11/94

08^7/02

08/13A)3

11/22A)4

NAPH

334

1.75

PAH

3.3

1.8


WeU could not be localed

WeU abandoned October 2004

MW-310

11/22/04

04/13/05

NAPH

5.4 D

3.7

PAH ,

23

19

MW-4

04/14/94

05/11/94

08^7/02

08/14A)3

11/22/D4

04/13A)5

NAPH

393

147

0.96

0.026 ty

0.026 Q

Well abandons

PAH

393

147

1.0

0.03

0.03

dALpril2005

MW-308

11/22W4

04/13/05

/ / /

/

NAPH

<2.2

72

PAH

|45

P-305

11/22A)4

04/14A)5

NAPH

0.025 Q

0.026 Q 1

60

PAH

0.1

0.04

P-304

06/24/96

08/12«6

08/27/02

08/13/03

U/22M

04/14/05

NAPH

_ <1.0

O.067

PAH 1 _ nd 1 nd 1

DiyweU, not sampled

Dry well, not sampled

O.I7 1 nd 1

..7.9

O.ll 'Cy

,<0.022

WEA/O/W/ÊER,^^^^

Weil ' c o v M i ^ b e l o c ^ B i H H - ,

Well could not be located

Well scheduled for abandonmmt

I D I '

p-303

^06n4ffl6.

08/12/96

7

"N/ t fH—I

P-302

06/24/96

Og/l2«6

08/27/02

08/13/03

n/22m M/\W5

NAPH

<1.0

<1.0

0.18 Q

0.43"

O.022

0.022

PAH

n d \

nd , '

0.2V

0.8 "

nd

nd

~

MW-302

04/14m

05/10/94

0807/02

08/13A)3

11/22^4

04/14/05

NAPH

2J00

2,520

;; 0.85'

«e <0.45

PAH

2,705

2.627

507

13

590

26

.•'MW-'303

'06/24fl6

08/12/96

08^7/02

08/13/03

/ l im /04

xO4/l'4/05

NAPH /

/<1 .0 (

'^ <1.0

,<a067'""

/ 0.039 Q

0.032 Q

0.18

PAH

nd

" \ nd

-.« '9 J

~0.7 "'"^

0.6 " • -

0.7

MW-5

04/14/94

05/11/94

08/27/02

08/14A)3

11/22/04

04/14/05

NAPH

<1.10

<1.10

3.9

Pjulx

nd \ .

0.2

10

Sample botde biokai in transport

1.4 D

0.034 Q

1.7

0.03

MW-304-

06Q4/96'

08/12/96

08/27/02

.08/13/1^

11/22W^

04/14/05

. xNAPH

•^ 310

120

190

100 D

\ 2 7

X 0.06aQ

PAH

402

226

296

121

30

0.5

LEGEND

^ " ^ ^

.fh. MW-1

^ P-301

MW-2

A HP-301

j ^ TP-J05

C I Z U

-Hf+fl-t+fH+HH4-H+f

1 1

APPROXIMATE EXTENT OF PAH CONCENTRATIONS THAT EXCEED AN NR 140 ES

APPROXIMATE EXTENT OF PAH CONCENTRATIONS THAT EXCEED AN NR 140 PAL

MONITORING WELL

PIEZOMETER


HYDRO-PUNCH SAMPLE

TEST PIT



FORMER SLOUGH

RAILROAD

EXISTING STRUCTURE

FORMER WASTE WATER TREATMENT PLANT STRUCTURE

SAMPLE LOCATION

SAMPLE DATE

NAPH

NAPHTHALENE

(Itg/L)

PAH

TOTAL POLYNUCLEAR

/SOMATIC

HYDROCARBONS

(^g/L)

1 Wisconsin Grotmdwatcr Quality Stsndaids (NR 140, 2003)

1 Preventive Action Limit (PAL)

1 Enfoicemcnt Standard (ES)

8 40

ns ns

MW-301

04/1S/U

05/loM -08OTTO

0&'14y<03'

M1/22A)4

NAPH

3J2(i

2J40

.^^300 /

iiiOraD*

/PAH'

/ 3,7»7

2312

8^359-^

^-54340

WeU Abandoned /

DATA QDAUFIERS; 4 CONCENTRATION ATTAINS OR EXCEEDS AN NR 140 PREVENTIVE ACTION LIMIT

310 CONCENTRATTON ATTAINS OR EXCEEDS AN NR 140 ENFORCEMENT STANDARD

Mg/L

X J'-301

~04/14»4

05/^1/94

08 /27 /M '

11/22/04

/NAPH'

/ <1.I0

' /- / / 2 . 7 /

/ PAH

/ 12

_ 3.6

.Well Abmdoned

NOT DETECTED STANDAKD HAS NOT BEEN ESTABLISHED AN/UwYSIS N(7T PERFORMED MICROGRAMS PER LTTER CONSTTrUENT WAS NOT IDENTIPIED ABOVE THE UMIT OF DETECTION INDICATED. LABORATORY N0TE.PRECISI0N NOT WTTtON C»NTROL LDiOTS. LABORATORY NOT1E-ANALYTE VAUJE FROM DILUTED ANALYSIS. LABORATORY NOTE - THE ANALYTE HAS BEEN DETECTED BETWEEN THE LIMIT OF DETECTION (LOD) AND LIMTT OF QUANTITATION (LOQ). LABORATORY NOTE-PRECISION NOT WTIHIN CONTROL LIMTTS.

NOTE: 1. DUPUCATE SAMPLES WERE COLLECTED IXnUNO EACH SAMPUNO

EVENT. NAPHTHALENE AND TOTAL POLYI>JUCLEAR AROMATIC HYDROCARBONS CONCENTRATIONS SHOWN REFLECT THE HIOHER CONCENTRATTON BETWEEN WELL SAMPLES AND DUPLICATE SAMPLES.

SOURCE NOTE; 1. THIS DRAWING WAS DEVELOPED FROM A MAP BY THE CITY OF MARINETTE. 2. PORTIONS OF THE DRAWING ARE FROM A DIGITAL FILE FROM STS CONSULTANTS, LTD. CONSULTING ENGINEERS,

GREEN BAY, WISCONSIN, PROJECT NUMBER 26936. REVISED JANUARY 2 0 0 1 . HYDROGRAPHIC SURVEY OF RIVER WAS PERFORMED BY AYRES AND ASSOCIATES ON JULY 2 4 - 2 6 , 2 0 0 1 . VERTICAL CONTROL IS U.S.G.S. DATUM. BUILDING AND STREET LOCATIONS NORTH OF RAILROAD TRACKS WERE SUPPLIED BY MARINETTE MARINE CORPORATION.

3. PORTIONS OF THIS DRAWING ARE FROM HYDRO-SEARCH DRAWING. 4. EXISTING STRUCTURES AND UTILITIES FROM FOTH Sc VAN DYKE ENGINEERS/ARCHITECTS, GRADING PLAN, DIGITAL

FILE 7m755c06.DWG, RECORD DRAWING REVISIONS 2 / 2 2 / 9 0 . 5. WELL LOCATIONS FROM A SURVEY BY WPSC DATED OCTOBER 8, 2003, REVISED OCTOBER 3 1 , 2003. 6. BRICK INTERCEPTOR SEWER REPLACEMENT TAKEN FROM DRAWING BY AYRES ASSOCIATES, GREEN BAY.

WISCONSIN, JOB NO. 1 6 - 0 1 8 9 . 1 0 , DRAWING NO. P l O l , SHEET NO. 7, DATED 3 / 1 4 / 0 3 . 7. MONITORING WELLS MW-2R. MW-3R, MW-307R INSTALLED OCTOBER 2004 AND M W - 3 0 a , MW-3 tO . P -305

INSTAaED JUNE 2004. SURVEYED BY WPSC IN JANUARY 2005. (NGVDSS, MARINETTE COUNTY COORDINATES).

^ 0 80

SCALE IN FEET

160

\


PROJECT NO.

1 5 4 9 / 9

DRAWN BY; R L h /

TAS 0 9 / 1 2 / 0 5

CHECKED BY:

PAR 0 9 / 1 2 / 0 5

APPROVED BY;

RJC 0 9 / 2 0 / 0 5

GROUNDWATER NAPHTHALENE AND PAH ANALYTICAL SUMMARY



DRAWING NO: 1 5 4 9 - 9 - 8 0 5

REFERENCE; \CAD TABLES APRIL 2005.XLS

FIGURE NO.

TABLES

Table 1 Groun(Jwater Elevations Table 2 Groundwater /Analytical Results - PVOC and Cyanide Table 3 Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAH) Table 4 Groundwater Analytical Results - RNA Parameters

Table 1 - Groundwater Elevations April 2005 Groundwater Quality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS U: 02-38-000047

Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) Top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)

Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04

04/13/05 & 04/14/05

IVIW-1

14.24 10

582.63 585.09 580.85 570.85

Depth to Water from TOC

(feet) 3.84 3.54 4.36 4.31

Water Elevation (NAVD) 581.25 581.55 580.73 580.78

well could not be located well could not be located

Located/repaired October 2004 6.39 5.06

578.70 580.03

IVIW-2

11.65 5

584.66 586.5 579.85 574.85

Depth to Water from TOC (feet)

6.04 5.66 6.02 5.98 5.71

Water Elevation (NAVD) 580.46 580.84 580.48 580.52 580.79

MW-2 could not be located MW-2 could not be located Abandoned October 2004

MW-3 MW-3R Scheduled for Installed Abandonment 10/04

15.53 14.84 10 10

586.03 585.68 587.69 585.50 582.16 580.66 572.16 570.66


6.69 6.46 6.99 6.95 8.16

Water Elevation (NAVD) 581.00 581.23 580.70 580.74 579.53

MW-3 could not be located MW-3 could not be located

6.60 6.24

578.90 579.26

MW-4 12.

5 35

586.06 587.92 580.27 575.27


(feet) 5.89 5.84 5.97 5.96 6.02 6.45 6.81 8.02

Water Elevation (NAVD) 582.03 582.08 581.95 581.96 581.90 581.47 581.11 579.90

Abandoned April 2005


Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04

04/13/05 & 04/14/05

MW-5 16.66

10 590.14 591.76 585.10 575.10


(feet) 7.27 7.25 6.78 6.76 6.04 7.40 8.11 8.20 7.72

Water Elevation (NAVD) 584.49 584.51 584.98 585.00 585.72 584.36 583.65 583.56 584.04

MW-301 16.1 10

587.00 ""58a'55 ^'

583.45 573.19


8.81 8.68 9.08 nm

8.59 10.00

Water Elevation (NAVD) 580.74 580.87 580.47

nm 580.96 579.55

Tar present - not measured Abandoned February 2004

MW-302 18.27

id 591.82 594.'94' 586.67 576.67


13.37 13.25 13.23 13.12 12.15 11.20 14.24 14.07 13.46

Water Elevation (NAVD) 581.57 581.69 581.71 581.82 582.79 583.74 580.70 580.87 581.48

MW-303 12.57

10 584.99 584.62 582.05 572.05


(feet)

Water Elevation (NAVD)

Constructed August 1996 3.40 4.65 5.57 5.62 5.05

581.22 579.97 579.05 579.00 579.57

1549GWQualilyData 050809 TbI 1 WTR Elevations Page 1 of 3 S^

Table 1 - Groundwater Elevations April 2005 Groundwater Quality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047

Well Construction Data Well Depth from TOC (feet) Screen Lengtfi (feet) Surface Elevation {NAyp)_ top of Casing Elevation (NAVD) Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)

Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04

04/13/05 & 04/14/05 .

IVIW-304 15.97

10 585.20 587;73 581.76 571.76


(feet)



581.74 583.63 579.48 579.82 580.38

MW-305 22.57

10 ' " 594.71 597'25 584.68 574.68




593.85 582.77 582.10 581.29 581.86

MW-306 10.19

10 586.22 585'77 585.58 575.58




582.02 581.62 581.28 580.11 581.33

MW-307 Abandoned

10/04

11.78 To

584.98 584!47' 582.70 572.70


(feet)

Constructed 3.59 4.85 5.63 5.94 5.47

MW-307 R Installed

10/04

12.6 10

585.07 584.70 582.10 572.10 Water

Elevation (NAVD)

August 1996 581.11 579.85 579.07 578.76 579.23

Well Construction Data Well Depth from TOC (feet) Screen Length (feet) Surface Elevation (NAVD) fop of Casing'Elevatiori(NA\/bj Top of Screen Elevation (NAVD) Screen Bottom Elevation (NAVD)

Date 08/13/03 11/22/04

04/13/05 & 04/14/05

MW-308 12.59

10 586.94 586'62 584.04 574:04 " "


(feet)


Constructed June 2004 8.21 7.79

578.41 578.83

MW-310 12.58

10 585.90 585!50 581.89 "57i:89



Constructed June 2004 6.31 5.85

579.19 579.65

MW-311 14.29

10 585.60 585.20 580.91 570:9



Constructed October 2004 | 7.01 6.19

578.19 579.01

1549G WQualityData 050809 TbI 1 WTR Elevations Page 2 of 3

Table 1 - Groundwater Elevations April 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047


Date 04/14/94 04/15/94 05/10/94 05/11/94 08/13/96 08/27/02 08/13/03 11/22/04

04/13/05 & 04/14/05

P-301 43.00

5 587.24 589.67 551.67 '546.67


(feet) 40.89 41.81 42.36 42.95 40.55 33.50 41.58

Water Elevation (NAVD) 548.78 547.86 547.31 546.72 549.12 556.17 548.09

Abandoned February 2004

P-302 30.74

5 591.46 594.00 568.26 563:26




581.92 580.80 579.76 579.93 580.52

P-303 34.72

5 585.43 587.65 557.93 552.93



Constructed August 1996 32.46 14.20 30.84 30.45

nm

557.21 575.47 558.83 559.22

nm

P-304 34.80

5 585.68 587.92 558.12 553.12


(feet)


Constructed August 1996 27.71 23.05 32.49 32.85 nm

561.96 566.62 557.18 556.82

nm


Date 08/13/03 11/22/04

04/13/05 & 04/14/05

P-305 26.63

5 586.96 586.96 565.33 560.33


(feet)


Constructed June 2004 | 7.32 6.94

579.64 580.02

[JTB/XSRL Ofl/OZKRJCJTB t I/02J[PAR/JTB 0'X)3I[MJR''JTB-2'05I[PAR/TILH5/05|

Notes: Monitoring wells were surveyed October 8, 2003 and January 2005. Survey data for wells MW-308, MW-310 and MW-311 are inconsistent with 2003 ground surface elevations. Wells will be surveyed in 2005.

TOC NAVD

Top of PVC well casing Vertical Datum is NAVD88 (North American Vertical Datum • Water level elevation above top of screen elevation

feet) MW

PZ nm

monitoring well piezometer not measured

1549GWQualityData 050809

TbI 1 WTR Elevations Page 3 of 3

Table 2 - Groundwater Analytical Results - PVOCs and Cyanide Apri l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047

Sample Location

Preventive Actio Enforcement Stc

MW-301

MW-302 dup

dup

dup (QA/QC 1)

dup (QC-2)

MW-303

MW-304 dup

dup(QC-l)

MW-305

MW-306

dup(QC-1)

Sample Date

Wisconsin n Limit (PAL) mdard (ES)

04/15/94 05/10/94 08/27/02 08/14/03 11/22/04

04/14/94 04/14/94 05/10/94 05/11/94 08/27/02 08/27/02 08/13/03 08/13/03 11/22/04 04/14/05

06/24/96 08/12/96 08/27/02 08/13/03 11/22/04 04/14/05

06/24/96 06/24/96 08/12/96 08/27/02 08/13/03 08/13/03 11/22/04 04/14/05

06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 04/14/05

06/24/96 08/13/96 08/27/02 08/14/03 11/22/04 11/22/04 04/13/05

Petroleum Volatile Organic Compounds (pg/L)

c

s c m

01 c 0) N c

UJ

0)

c 3

re

o c 0)

>. X

Groundwater Quality Standards (NR 0.5 5

770 321

2,600 1,200 K

1,230 980 482 <0.7

0.58 Q 0.76 Q

19 19 4.6 £9

<0.50 <0.50 <0.48 <0.30 <0.14

1.5

150 180 260 100 94 K 97 29

M <0.50 <0.50 <0.48 <0.30 <0.14 <0.14

<0.50 <0.50 <2.4

<6.0K 0.20Q 0.15 Q <0.34

140 700 650 720 910

520 K

200 1,000 580 434 830

470 K Well abandoned

380 440 538 <0.9 <0.43 <0.43 4.2 4.2 8.6

0.57 Q

<1.0 <1.0 <0.43 <0.60 <0.40 0.53 Q

48 64 39 13

11 K 12 5.9

<0.40

<1.0 <1.0 <0.43 <0,60 <0.40 <0.40

4.7 9.5 390

930 K 0.41 O <0.40 350

520 640 405 <1.0 <0.47 <0.47 <0.58 <0.58 <0.36 <0.36

<1.0 <1.0 <0.47 <0.58 <0.36 <0.36

23 29 62 22

21 K 22 5.1

<0.36

<1.0 <1.0

<0.47 <0.58 <0.36 <0.36

<1.0 <1.0 88

150 K <0.36 <0.36

13

1,000 10,000

840 782

680 O 510K

X LU 1 -

m

o

U IT)

c " -o '-" 5 -a

t CM

f=6

Cyanide (pg/L)

.-1

.;«: O

0) <n

5 5 140, February 2004)

ns ns

2,840 2,257 5,020 2,700

96 480

--

140 Q 162 KQ

ns ns 76

474 81 L

as part of sewer construction during 2004

390 1.030 1,090 <1.5 <1.4 <1.4 <1.2 <1.2 6.2

<0.74

<3.0 <3.0 <1.4 <1.2 <0.74 <0.74

58 76

<150 28

22.6 K 22.6 8.6

<0.74

<3.0 <3.0 <1.4 <1.2 <0.74 <0.74

21 66

1,020 2.160 K

2.3 1.8 690

2,520 3,090 2,515

nd 0.6 0.8 23 23 19 5.5

nd nd nd nd nd 2.0

279 349 361 163 149 154 49 1.1

nd nd nd nd nd nd

26 76

1,498 3,240

2.9 2.0

1,053

----

<0.52 <0.52 <0.66 <0.66

0.61 Q <0.40

--

<0.52 <0.66 <0.40 <0.40

--~

10.7 0 6.0 KQ 6.0 KQ 2.53 Q <0.40

--

<0.52 <0.66 <0.40 <0.40

--

321 920 K

5.5 4.2 375

68 72 77

<3.5 <2.7 8,0 Q

L L

----

6 Q L

-----20 L L

----19 L

----

<2.7 L -" -

5 ! ^ .a <o ra 1-•5 <

40 200

----

--------

69 Z 8.0

----

38 Z <5.0

------

660 Z 7.8

----

22 Z <5.0

----

28 Z 31 Z <5.0

1 o "5 c 0) .c Q.

1,200 6,000 7,460 140 --

138 493 <15 20 ------------------------------— --

1549GWQualityData 050809 TbI 2 GW PVOC + Cn Page 1 of 3 SE;

Table 2 - Groundwater Analytical Results - PVOCs and Cyanide Apr i l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #.- 02-38-000047

Sample Location

Preventive Actio Enforcement St<

MW-307

IVIW-307R

dup(QC-l)

MW-308

MW-310

MW-311

MW-1

MW-2

MW-3

MW-3R

MW-4

dup (QC-2)

MW-5

dup (QC-2)

Sample Date

Wisconsin n Limit (PAL) mdard (ES)

06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 11/22/04 04/13/05 04/13/05

11/22/04 04/13/05

11/22/04 04/13/05

11/22/04 04/13/05

04/13/94 05/10/94 08/27/02 08/13/03 11/22/04 04/13/05

04/14/94 05/11/94 08/27/02 08/13/03 11/22/04

04/14/94 05/11/94 08/27/02 08/13/03 11/22/04 11/22/04 04/14/05

04/14/94 05/11/94 08/27/02 08/14/03 11/22/04 11/22/04 04/13/05

04/14/94 05/11/94 08/27/02 08/14/03 11/22/04 04/14/05 04/14/05


0) c 0) N c iS

hyl

benze

ne

luene

lenes,

Tota

l

tal B

TE

X

meth

ylbenze

ne

2,4

-an

d 1

,3,5

-)

^ o ;»> o 1. -LU 1- X 1- 1- C

Cyanide (pg/L)

2 ^

X o ca in Q) (/}

5 5 Groundwater Quality Standards (NR 140, February 2004)

0.5 5

0.63 1.2

<0.48 <0.30

0.67 0.57 0.80

0.61 0.33 Q

0.68 <0.14

SSOK 260

<0.7 <0.7

<0.14 <0.14

<0.7 <0.7

<0.7 <0.7

<0.14 <0.14

13 <17.5 <0.48 <0.30

0.15 Q

<0.7 <0.7 <0,48 <0.30 0.73

<0.14 <0.14

140 200 1,000 ns 96 700 1,000 10,000 ns 480

<1.0 <1.0 <3.0 0.6 <1,0 <1.0 <3.0 1.2

<0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66

ns ns

--

5.0 Q L

Well abandoned October 2004, replaced with MW-307R <0.40 <0.36 <0,74 0.6 0.69 Q <0.40 <0.36 <0.74 0.6 <0.40 <0.40 <0.36 <0.74 0.8 <0.40

<0.40 <0.36 1.00 Q 1.6 0.90 Q 0.71 Q <0.36 0,76 Q 1.8 1.4

0.89 Q <0.36 <0.74 1.6 0.46 Q <0.40 <0.36 <0.74 nd <0.40

1 , 2 0 0 K 1 9 Q , K 820 K 2,619 207 K 700 15 360 1,335 110

<0.9 1.1 2.6 3.7 <0.9 <1.0 <1.5 nd

---------

<3.5 <3.5

Well could not be located during the sampling event. Well could not be located during the sampling event.

<0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40

<0.9 <1.0 <1.5 nd <0.9 <1.0 <1.5 nd

--

<3.5 <3.5


Well abandoned during October 2004

<0.9 <1.0 <1.5 nd - <3.5 <0.9 <1.0 <1.5 nd - <3.5


Well scheduled for abandonment, replaced with MW-3R <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40

280 270 1.380 1.943 411 568 1,810 2,789

<0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66

--

<3.5 <3.5 40 Q

L Samples damaged, unable to analyze

<0.40 <0.36 <0.74 0.2 <0.40 | Well damaged, abandoned April 2005

<0.9 <1.0 <1.5 nd <0.9 <1.0 <1.5 nd <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66 0.63 Q <0.36 <0.74 1.4 <0.40 <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40

<3.5 <3.5 <2.7

L ---

Si (O re 1-re < ^ 2 .

40 200

----

46 Z <5.0 6.6

27 Z <5.0

68 Z 5.1

12Z <5.0

__ -

54 Z <5.0

--

--

<5Z <5.0

----

11Z

----

<5Z <5.0 <5,0

1j "5,

(A O

"5 c Q)

a

1.200 6,000

----

---------

8 <15

--24 <15

30 20

--<8 20 --

14 <15 -----

1549GWQualityData 050809 TbI 2 GW PVOC + Cn Page 2 of 3

Table 2 - Groundwater Analytical Results - PVOCs and Cyanide Apr i l 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS tt: 02-38-000047

Sample Location

Preventive Actio Enforcement Stj

Sample Date

Wisconsin n Limit (PAL) indard (ES)


0)

c V N c

<s

hyl

benze

ne

luene

lenes,

Tota

l

tal

BTE

X

meth

ylbenze

ne

2,4

-an

d 1

,3,5

-)

m K X t- ^ Z ,

Cyanide (pg/L)

J£ O

5 5 Groundwater Quality Standards (NR 140, February 2004)

0.5 5

140 200 1,000 ns 96 700 1,000 10,000 ns 480

ns ns

.Q (O re 1 -

re < < o

40 200

PIEZOMETERS P-301

P-302

dup (QA/QC 2)

P-303

P-304

P-305

04/14/94 05/11/94 08/27/02 08/13/03 11/22/04

06/24/96 08/12/96 08/27/02 08/27/02 08/13/03 11/22/04 04/14/05

06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 04/14/05

06/24/96 08/12/96 08/27/02 08/13/03 11/22/04 04/14/05

11/22/04 04/13/05

<0.7 <0.7 <0.48

<0.50 <0.50 <0.48 <0.48 <0.30 <0.14 <0.14

<0.50 <0.50 <0.48 <0.30 <0.14 <0,14

22 2.1

<0.48 <0.30

<0.14

<0.14 <0.14

0.9 33.6 <1.5 35 <0.9 26 <1.5 26 <0.43 <0.47 <1.4 nd <0.52

--

<2.7 Well not sampled - well did not recover after purge

Well abandoned as part of sewer construction during 2004

<1.0 <1.0 <3.0 nd <1.0 <1.0 <3.0 nd

<0.43 <0.47 <1.4 nd <0.52 <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66 <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40

<1.0 <1.0 <3.0 nd <1.0 <1.0 <3.0 nd <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0,66 <0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40

5.7 1.5 8.3 38 <1.0 <1.0 <3.0 2.1 <0.43 <0.47 <1.4 nd <0.52 <0.60 <0.58 <1.2 nd <0.66

--13

<2.7 L ----16 L

. ---~

7.0 Q L

Insufficient water volume to purge and sample <0.40 <0.36 <0.74 nd <0.40

<0.40 <0.36 <0.74 nd <0.40 <0.40 <0.36 <0.74 nd <0.40

--

---

-----

<5Z <5.0

----

53 Z <5.0

----

-<5Z <5.0

s (A O

0 C 0)

a

1,200 6,000

13 --

---------— -----------

Temporary Monitoring Locations | SB-327

SB-333

SB-338

SB-340

04/01/96

04/01/96

04/02/96

04/02/96

<0.50

<0.50

5,300

650

<1.0 2.8 <3.0 nd

<1.0 <1.0 <3.0 nd

3,900 3,700 <3,000 12,900

1,400 <100 900 2,950

---~

----

----

2/051IPAR/RLH OT5

Notes:

1) 2)

dup : * •

A : D: H : K: L : N : Q ; Z :

n d :

ns :

Not detected. Analysis not performed, standard not established

Concentrations that attain/exceed a PAL are underlined/italicized. Concentrations that attain/exceed an ES are underlined/bold. Field duplicate sample, field identification in parentheses. Laboratory note - precision not within control limits. Laboratory note - Detected in method blank at 0.16 pg/L. Laboratory note - Analyte value from diluted analysis. Laboratory note - Extraction or analysis performed past hold time. Laboratory note - Detection limit may be elevated due to the presence of an unrequested analyte. Cyanide analysis was not performed due to laboratory error. Laboratory note - Spiked sample recovery not within limits. Interference not related to sulfides/aldehydes Laboratory note - Analyte detected between the limit of detection (LOD) and limit of quantitation (LOQ). 11/22/04 available cyanide samples were not field preserved with lead carbonate. Data may be biased

high due to sulfide interference. 1549GWQualityData 050809 K ^ TbI 2 GW PVOC -I- Cn Page 3 of 3 S8?;

Table 3 - Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAHs) Apri l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047

c o '^ re u

3 0) a E re

Prevent ive Ac t i on

En fo rcemen t Stanc

MW-301

MW-302

dup

dup

dup (QA/QC 1)

dup (QC-2)

MW-303

MW-304

dup(QC-l)

dup(OC-l)

MW-305

MW-306

dup(QC-l)

3 re Q 0)

a . E re CO

Limi t (PAL)

Jard (ES)

04/15/94

05/10/94

08/27/02

08/14/03

11/22/04

04/14/94

04/14/94

05/10/94

05/11/94

08/27/02

08/27/02

08/13/03

08/13/03

11/22/04

04/14/05

06/24/96

08/12/96

08/27/02

08/13/03

11/22/04

04/14/05

06/24/96

06/24/96

08/12/96

08/27/02

08/13/03

08/13/03

11/22/04

04/14/05

06/24/96

08/12/96

08/27/02

08/14/03

11/22/04

04/14/05

06/24/96

08/13/96

08/27/02

08/14/03

11/22/04

11/22/04

04/13/05

Po lynuc lea r A roma t i c Hyd roca rbon (pg/L)

a c

lU

Q. re c 0) o < ns

ns

<7.26

<0.66

240

1 ,300*

<7.26

<7.26

<0.66

<0.66

2.4

1.9

0 . 8 7 *

1 .4*

5.3 Q

0.40 0

<1.0

<1.0

<0.053

0.11

0.46

0.26

<1.0

<1.0

20

13

3.1

2.8 Q,*

<1.9

<0.019

<1.0

<1.0

<0.053

<0.036*

<0.019

<0.019

<1.0

<1.0

<0.053

0 . 1 7 *

0.18

0.080

0.67 E

0) c 0) >. .c

a re (U u

<

ns

ns

<17.6

<1.60

340

2,900 *

<17.6

<17.6

<1.60

<1.60

1.4

<0.16

0.51 *

0.61 *

27

1 .2Q

<2.0

<2.0

<0.16

0.025 Q

0.060 Q

0.068

<2.0

<2.0

61

9.9

2.2

<1.9*

<1.9

<0.019

<2.0

<2.0

<0.16

0 . 4 2 *

<0.019

0.35

<2.0

<2.0

<0.16

0.055 Q,*

<0.019

<0.019

0.082

c V u 5 .c c

<

600

3,000

26

13

240

1.700

17

15

23

<0.05

29

19

0.56

0 . 4 9 *

45

0.96 Q

<0.20

<0.20

0.19

<0.021

<0.018

<0.018

2.8

3

1.4

2.5

<0.40

<2.0

<1.8

0.027 Q

0.33

<0.20

<0 .024 .

0.12 Q

<0.018

0.098

<0.20

<0.20

<0.024

<0.020

<0.018

<0.018

0.022 Q

(U c (U

m 01

ns

ns

8.5

1.28

220

1,300

2.7

1.6

1.83

<0.04

53

28

1.0

0.98

70

2.5

<0.050

<0.050

0.80

0.035 Q

<0.020

<0.020

0.14

0.21

0.65

16

0.53 Q

<1.2

<2.0

0.020 Q

0.71

0.31

<0.030

0.23

<0.020

0.24

0.05

0.05

<0.030

<0.012

<0.020

<0.020

<0.020

0)

c

o

N C m

0.02

0.2

7.6

1.69

34

1.100

2.6

1.1

1.75

<0.05

54

27

1.1

1.0

80

M <0.024

<0.024

0.59

0.045 Q

<0.018

<0.018

<0.024

0.18

0.65

3.1

0.54 Q

<1.4

<1.8

0.023 Q

0.26

0.14

0.21

0.20

<0.018

0.20

<0.024

<0.024

<0.022

<0.014

<0.018

<0.018

<0.018

(1) c (U

f l c o

0.02

0.2

3.6

0.51

80

720

<0.88

<0.88

0.61

<0.08

55

25

0.78

0.70

45

Z 3

<0.050

<0.050

1.0

0.051

<0.018

<0.018

0.05

0.05

2.2

3.9

0.46 Q

<1.3

<1.8

0.036 Q

0.15

0.08

0.26

0.26

<0.018

0.24

0.05

0.05

<0.036

<0.013

<0.018

<0.018

<0.018

Is O 0)

ffl a.

ns

ns

<0.77

<0.07

44

560

<0.77

<0.77

<0.07

<0.07

30

19

0.61

0.56

4 2 *

2.0

<0.20

<0.20

0.54

0.039 Q

<0 .021*

<0.021

<0.20

<0.20

0.54

2.4

0.35 Q

<1.6

< 2 . r

0.026 Q

0.41

<0.20

0.36

0.28

<0 .021*

0.24

<0.20

<0.20

<0.087

<0.016

<0 .021*

<0.021

<0.021

o c 01

2-5

1 = CD m

o c a> (A

>.

O

c c re 0)

• re

0) c 0) £ c re o 3 Li.

c o o 3

W i s c o n s i n G r o u n d w a t e r Qual i ty S tanda rds (NR

ns

ns

2.9

0.43

69

780

1

0.5

0.47

<0.04

22

12

0.72

0.65

4 7 *

1.9

<0.050

<0.050

0.42

0.039 Q

<0.019*

<0.019

0.05

<0.050

0.12

0.67

0.41 Q

<1.9

<1.9*

0.028 Q

0.3

0.07

0.37

0.21

<0.019*

0.21

0.05

0.05

<0.067

<0.019

<0.019*

<0.019

<0.019

0.02

0.2

4.5

0.84

47

1,200

ns

ns

~ ~ 25

180 Q

80

400

<0.28

<0.28

130

3,400

Wel l abandoned February 2004

1.4

0.8

1.4

<0.05

45

22

0.83

0.83

59

1.9

<0.10

<0.10

0.96

0.043 Q

<0.016

<0.016

<0.10

<0.10

0.28

2.8

0.51 Q

<1.4

<1.6

0.025 Q

0.32

0.18

<0.022

0.23

<0.016

0.21

<0.10

<0.10

<0.022

<0.014

<0.016

<0.016

<0.017

~ -~ ~

8.1

3.9

0 .17Q

0 .16Q

13 Q , *

0.62 Q

--

0.12

<0.017

<0.022*

<0.022

---

0.59

<0.32

<1.6

<2.2*

<0.022

--

0.080 Q

0.071 Q

<0.022*

0.071 Q

-..

<0.036

<0.016

<0.022*

<0.022

<0.022

<3.08

<3.08

<0.28

<0.28

73

37

1.4

1.4

1 1 0 D

3.5

<0.20

<0.20

1.9

0 .10&

0.032 Q

0.017 Q

3.0

2.5

3.0

6.9

1.4&

<1.3

<1.7

0.041 Q

0.62

<0.20

<0.053

0.25

0.018 Q

0.21

<0.20

<0.20

<0.053

0.036 Q

0.035 Q

0.037 Q

0.12

80

400

74

43

390

2,100 *

62

55

46

<0.11

5.4

5.9

0.18 Q,*

0 .35 *

4.9 Q

<0.44

<0.40

<0.40

<0.025

<0.018

<0.022

<0.022

29

23

9.1

4.3

0.60 Q

<1.7*

<2.2

<0.022

<0,40

<0.40

<0.025

<0.034*

<0.22

<0.022

<0.40

<0.40

<0.025

0.099 *

0.031 Q

<0,022

0.17

c >. 4) a.

.E u

a c V re

a re Z

140, February 2004)

ns

ns

4.4

0.66

70

500

1.4

<0.88

0.58

<0.08

41

20

0.54

0.51

3 9 *

1.8

<0.10

<0.10

0.64

0,033 Q

<0.017*

<0.017

<0.10

<0.10

0.49

6.1

<0.42

<2.1

<1.7*

0.021 Q

0.29

<0.10

0.34

0.21

<0.17*

0.19

<0.10

<0.10

<0.030

<0.021

<0.017*

<0,017

<0.017

8

40

3,520

2,240

4,300

18,000 D,*

2,500

1,770

2,520

<1.10

11

6.6

0.60

0 . 8 5 *

13 O

<0,45

<1.0

<1.0

<0.067

0.039 Q

0.032 Q

0.18

310

230

120

190

100 D

81 D,*

2 7

0.060 Q

<1.0

<1.0

<0.067

0.11 Q,*

<0.022

0.098

<1.0

7.9

<0.067

600 D.*

0.37

0.11

410 D

c

£ c re c 0) .c a.

ns

ns

135

11

720

6,000 D

117

108

31

0.15

16

13

0.27

0.32

22

1 .2Q

<0.40

<0.40

0.76

0.030 Q

<0.020

<0,020

9

11

5.0

4.4

0.72 Q

<1.6

<2.0

<0.020

<0.40

<0.40

<0.036

0.11

<0.020

0.10

<0.40

<0.40

<0.036

0.077

<0.020

<0.020

0.050 Q

0) c 0)

a.

50

250

<0.33

<0.03

320

2,900

<0.33

<0.33

<0.03

<0.03

56

28

1.2

1.2

78

3.0

<0.20

<0.20

1.4

0.091 &

0.035 Q

0.020 Q

1.1

0.69

1.4

4.5

1.2&

<1.7

<1.6

0.031 Q

1.5

<0.20

<0.13

0.35

<0.016

0.32

<0.20

<0.20

<0.13

0.067

0.24

0.24

0.23

0) c 0)

t l 1 re

1 - c

ns

ns

<1.20

-520

4,100 D,Q,*

<1.20

<1.20

--

0.84

<0.095

0 . 4 7 *

0 . 6 6 *

<4.0

<0.40

<1.0

<1.0

<0.095

<0.019

<0.020

0.063 Q

35

19

<1.0

18

7.0

6 , 4 *

2.5 Q

0.12

<1.0

<1.0

<0.095

<0.036*

<0.020

0.025 Q

<1.0

<1.0

<0.095

6.7 D,Q,*

1 .8D

0.54 D

7.4 E

0) c 0)

It ^ re CM c

ns

ns

<0.21

-770

5,600 D,*

<0.21

<0.21

-3.5

<0.096

<0.068*

0.079 Q,*

<4.5

<0.45

<1.0

<1,0

<0.096

<0.018

<0.023

0.058 Q

12

14

<1.0

6.5

2.2

2.2 Q,*

<2.3

<0.023

<1.0

<1.0

<0.096

0.043 Q,*

<0.023

0.036 Q

<1.0

<1.0

<0.096

<3.4 D*

<0.023

<0.023

0.46

(fl X < Q.

2 o 1-

ns

ns

3,787

2,312

8,559

54,340

2,705

1,952

2,627

0.15

507

268

12

13

590

26

nd

nd

9.3

0.7

0.6

0.7

402

304

226

296

121

92

30

0.5

4.9

0.8

1.6

3.1

0.02

2.8

0.2

8,1

nd

: 607

: 2.7

! 1.0

i 419

0) 3

t o re V cn 1-

bailer

bailer

bailer

bailer

-bailer

bailer

bailer

bailer

bailer

bailer

low f low

low f low

low f low

low f low

bailer

bailer

bailer

low f low

low f low

low f low

bailer

bailer

bailer

bailer

low f low

low f low

low f low

low f low

bailer

bailer

bailer

low f low

low f low

low f low

bailer

bailer

bailer

low f low

low f low

low f low

low f low

m 'c 0) E E o XJ 0)

i l 1

--

MGP type odor, sheen, black

MGP type odor, emulsif ied tar

-

----

---

insufficient well volume for complete purge

-

-

---

---

slight MGP type odor

--

well parameters did not stabi l ize

---


-insufficient well volume for complete purge

--


MGP type odor

-- •


1549GWQualityData 050809 TbI 3 - GW PAH Page 1 of 3

Table 3 - Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAHs) Apri l 2005 Groundwater Quality Update - 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS It: 02-38-000047

o TO U

0) a. B re t n

£ re Q o o . E re

CO

Prevent ive A c t i o n L im i t (PAL)

En fo rcemen t S t a n d a r d (ES)

IVIW-307

MW-307R

dup(QC- l )

MW-308

MW-310

MW-311

MW-1

MW-2

MW-3

MW-3R

MW-4

dup (QC-2)

06/24/96

08/13/96

08/27/02

08/14/03

11/22/04

04/13/05

04/13/05

11/22/04

04/13/05

11/22/04

04/13/05

11/22/04

04/13/05

04/13/94

05/10/94

08/27/02

08/13/03

11/22/04

04/13/05

04/14/94

05/11/94

08/27/02

08/13/03

11/22/04

04/14/94

05/11/94

08/27/02

08/13/03

11/22/04

11/22/04

04/14/05

04/14/94

05/11/94

08/27/02

08/14/03

11/22/04

11/22/04

04/14/05

P o l y n u c l e a r A romat i c Hyd roca rbon (pg/L)

0) c 0)

o. re c 0) u

<

ns

ns

<1.0

<1.0

<0 .053

0.038 Q,*

7.4 D

3.4

5.5

11

19

5.2 D

5.3

< 2 4 0 D

170 D,Q

<0.66

<0.66

0.022 Q

0.042 0

<0.66

<0.66

<0.66

<0.66

1 4 D

<0.019

<0.66

<0.66

<0.053

<0.018*

<0 .019

a> c (U

>. .c Q. re c 0) o

<

ns

ns

<2.0

<2.0

<0.16

<0.019

0.25

<0.20

<0.39

3.6 Q

2.3 Q

0.067

<0.39

3.7 Q

4.6 Q

<1.60

<1.60

<0.019

<0.020

<1.60

<1.60

<1.60

<1.60

0.28

<0.019

<1.60

<1.60

<0.16

<0.019*

<0.019

u c 0) o re

<

600 •

3.000

0.39

<0.20

0.23

<0.020

1.0 D,Q

0.55 Q

1.2

1.8 Q

2.0 Q

0.70 D,Q

1.3

9.9

15 •

<0.05

<0.05

<0.018

<0.018

<0.05

<0.05

<0.05

<0.05

0.15

0.018 Q

0.06

<0.05

<0.024

<0.020

<0.018

c

ns

ns

0.15

<0.050

<0.030

<0.012

0.50 0 , 0

<0.20

<0.39

<2.0

<2.0

0.051 Q

<0.40

<2.0

<3,9

<0.04

<0.04

<0.020

<0.020

<0.04

<0.04

0.21

<0.04

<0.020

<0.020

<0.04

<0.04

<0.030

<0.012

<0.020

0) c <u i ->. a. S-"o" N C <u m

0.02

0.2

<0.024

<0.024

0.15

<0.014

0.31

<0.18

<0.36

<1.8

<1.8

<0.018

<0.37

<1.8

<3.6

<0.05

<0.05

<0.018

<0.018

<0.05

<0.05

<0.05

<0.05

<0.018

<0.018

<0.05

<0.05

<0.022

<0.014

<0.018

0)

f l c o

0.02

0.2

<0.050

<0.050

0.24

0.015 Q

0.180 Q

<0.18

<0.36

<1.8

<1.8

<0.018

<0.36

<1.8

<3.6

<0.08

<0.08

<0.018

<0.018

<0.08

<0.08

0.18

<0.08

<0.018

<0,018

<0.08

<0.08

<0.036

<0.013

<0.018

Benzp

(ghi)

pery

lene

Ben

zo(l<

) flu

ora

nth

ene

Ch

ryse

ne

Dib

enz(

ah)

an

thra

cen

e

Flu

ora

nth

ene

Flu

ore

ne

W i s c o n s i n G roundwa te r Qual i ty S tanda rds (NR

ns ns 0.02 ns 80 80

ns ns 0.2 ns 400 400

c ><

0) a

It

0) c: 3 re

Q. re Z

140, February 2004)

ns

ns

<0.20 <0.050 <0.10 - 0.31 <0.40 <0.10

<0.20 <0.050 <0.10 - <0.20 <0.40 <0.10

<0.087 <0.067 0.31 <0.036 0.37 <0.025 <0.030

0.017 Q <0.019 <0.014 <0.016 0.029 Q <0.017* <0.021

Wel l abandoned during October 2004, replaced with MW-307R

0.15* 0.17* 0.34 0.053 Q,* 1.8 D 2.5 D

<0.21 <0.19 <0.17 <0.22 0.53 0 0.90

<0.41 <0.39 <0.33 <0.44 0.56 Q 1.2 O

<2 .1 * <1.9* <1.6 <2.2* <1.6 <2.2

<2.1 <2.0 <1.7 <2.2 <1.7 <2.2

<0.021* <0 .019 ' 0.035 Q <0.022* 0.37 1.9 D

<0.42 <0.39 <0.33 <0.44 0.41 0 1.6

< 2 . 1 * <1.9* <1.6 <2.2* 3.9 0 36

<4.1 <3.9 <3.3 <4.4 3.8 37

<0.07 <0.04 <0.05 - <0.28 <0.11

<0.07 <0.04 <0.05 - <0.28 <0.11

Wel l could not be located during the sampling event.


<0.021* <0.019* <0.016 <0.022* <0.016 <0.022

<0.021 <0.020 <0.017 <0.022 <0.017 <0.022

0.14*

<0.17

<0.34

<1.7*

<1.7

<0.017*

<0.34

<1,7*

<3.4

<0.08

<0.08

<0.017*

<0.017

<0.07 <0.04 <0.05 - <0.28 <0.11 <0.08

<0.07 <0.04 <0.05 - <0.28 <0.11 <0.08



Wel l abandoned October 2004 - Replacement is not Planned

<0.07 <0.04 <0.05 - <0.28 0.61

<0.07 <0.04 <0.05 - <0.28 0.27


Wel l cou ld not be located during the sampling event.

Well scheduled for abandonment, replaced with MW-3R

<0.021* <0.019* <0.016 <0.022* 0.15 2.4 D,Q

<0.021 <0.019 <0.016 <0.022 <0.016 <0.022

<0.07 <0.04 <0.05 ~ <0.28 <0.11

<0.07 <0.04 <0.05 ~ <0.28 <0.11

<0.087 <0.067 <0.022 <0.036 <0.053 <0.025

<0.016 <0.019 <0.014 <0.016 <0.013 <0.017*

Samples damaged, unable to analyze

<0.021 <0.019 <0.016 <0.022 <0.016 <0.022

Wel l damaged, abandoned April 2005

<0.08

<0.08

<0.017*

<0.017

<0.08

<0.08

<0.030

<0.021

<0.017

8

40

<1.0

<1.0

<0.067

0.033 0

3.2 D

0.48 0

0.55 0

<2.2

1 2

5.4 D

3.7

3,200 D

2,000 D

<1.10

<1.10

0.14

0.055 0

3.34

1.75

2.52

0.29

<1.1 D

<0.022

393

147

0.96

0.026 Q,*

0.026 0

o c Si c re c <u . c a .

ns

ns

<0.40

<0.40

0.26

0.017 O

4.8 D

1.1

2.1

11

3.7 0

3.0

2.8

32

33

<0.15

<0.15

<0.020

<0.021

<0.15

<0.15

0.69

<0.15

0.049 0

<0.020

<0.15

<0.15

<0.036

<0.016

<0.020

0) c Si >.

Q .

50

250

0.38

<0.2P

0.37 0

0.028 0

1.6 D

0.51

0.59 0

<1.6

<1.7

0.39

0.46 0

3.7 0

5.1 O

<0.03

<0.03

<0.016

<0.017

<0.03

<0.03

<0.03

<0.03

0.093

<0.016

<0.03

<0.03

<0.13

<0.017

<0.016

0) c u

^ ^ S °-, re 1 - c

ns

ns

<1.0

<1.0

<0.095

<0.018*

6.0 D

2.1

3.0

1.8 21

4.4 D

3.4

350 D ,0

170 D,Q

<1.20

<1.2

<0.020

<0.020

<1.20

2.63

0,18

<0.020

<1.20

<0.095

<0.018*

<0.020

o c 0)

>> re

1 re

CM c ns

ns

<1.0

<1.0

<0.096

<0.017*

0.84 D,0

<0,23

<0.45

<2.3

<2.3

1.3 D,Q

<0.46

330 D,Q

240 E

<0,21

<1.2

<0.023

<0.023

<0.21

<0.21

0.051 0

<0.023

<0,21

<0.096

<0.017*

<0.023

(A X < Q .

1 ns

ns

1.2

nd

1.9

0.2

31

10

15

45

60

23

19

3,969

2,679

nd

nd

0.2

0.1

3.3

1.8

6.8

0.6

17

0.02

393

147

1.0

0.03

0.03

OJ 3

9) . ?

fc O re IB If) \ -

c

£ E o o •o a i l

1

bailer

bailer

bailer

low f low

bailer

low f low

low f low

low f low

low f low

low f low

low f low

bailer

low f low

bailer

bailer

low f low

low f low

bailer

bailer

bailer

bailer

low f low

low f low

bailer

bailer

bailer

low f low

low f low

low f low

gray/black, organic odor

insufficient well volume for comple te purge

-

-

;

-

-

:


1549GWQualityData 050809 TbI 3 - GW PAH Page 2 of 3

Table 3 - Groundwater Analytical Results - Polynuclear Aromatic Hydrocarbons (PAHs) Apr i l 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047

c _o re

0) Q-E re O)

Preventive Action Enforcement Stanc

MW-5

dup (QC-2)

i i

V Q. E re

Limit (PAL) Jard (ES)

04/14/94 05/11/94 08/27/02 08/14/03 11/22/04 04/14/05 04/14/05

Polynuclear Aromatic Hydrocarbon (pg/L) I

0) c «

Q. re c 0) u <

ns ns

<0.66 <0.66

<0.053

0.060 0 <0.019 <0.019

0) c Q)

a. re c 0) u < ns ns

<1.60 <1.60 <0.16

<0.019 <0.019 <0.019

«> c 0) o E .n c <

600 3,000

<0.05 <0.05 0.22

<0.018 <0.018 <0.018

V

Si ns ns

<0.04 0.06

<0.030

<0.020 <0.020 <0.020

0) c o >. Q. "re" o N C 0)

CQ

0.02 0.2

<0.05 <0.05 0.69

<0.018 <0.018 <0.018

0) c 0)

S B N £ c o m ;?

0.02 0.2

<0.08 <0.08 0.50

Is O V

CQ Q.

ns ns

<0.07 <0.07 0.31

Ben

zo(k

) flu

oran

then

e

Chr

ysen

e

Dib

enz(

ah)

anth

race

ne

Flu

oran

then

e

Flu

oren

e

Wisconsin Groundwater Quality Standards (NR ns 0.02 ns 80 80 ns 0.2 ns 400 400

<0.04 <0.05 ~ <0.28 <0.11 <0.04 <0.05 ~ <0.28 <0.11 0.45 0.54 0.070 0 0.92 <0.025

CO CV4 <U

« a

0) c re

.c o. re z

140, February 2004)

ns ns

<0.08 <0.08 0.35

Sample bottle broken in transit to laboratory, analysis could not be performed <0.018 <0.018 <0.018

0.022 0 <0.021 <0.021

0.022 O 0.025 Q <0.022 <0.016 <0.022 <0.019 <0.016 <0.022 <0.016 <0.022 <0.019 <0.016 <0.022 <0.016 <0.022

<0.017 <0.017 <0.017

8 40

<1.10 <1.10

3.9

1.4 D <0.022 0.034 O

c u .c c re c 0) .c a.

ns ns

<0.15 <0.15 0.55

0.027 0 <0.020 <0.020

c

0)

Q.

50 250

<0.03 0.18 0.71

<0.016 <0.016 <0.016

0) c «

, re 1 - c

ns ns

<1.20 —

0.32

0.087 <0.020 <0.020

0) c «

>. re

.c £ o .c S °-. re

CM c

ns ns

<0.21 -

0.56

0.085 <0.023 <0.023

lA X < Q.

"re

1°

ns ns

nd 0.2 10

1.7 nd

0.03

3

c o re 0) in 1-

bailer bailer bailer

-bailer

low flow low flow

O E E o

0)

i l 1

---

insufficient well volume for complete purge --

PIEZOMETERS | P-301

P-302

dup (QA/QC 2)

P-303

P-304

P-305

04/14/94 05/11/94 08/27/02 08/13/03 11/22/04

06/24/96 08/12/96 08/27/02 08/27/02 08/13/03 11/22/04 04/14/05

06/24/96 08/12/96 08/27/02 08/14/03 11/22/04 04/14/05

06/24/96 08/12/96 08/27/02 08/13/03 11/22/04 04/14/05

11/22/04

04/13/05

<0.66 -

<0.053

<1.0 • <1.0 <0.053 <0.053 <0.018* <0.019 <0.019

-<1.0

<0.053 <0.018* <0.019 <0.019

-<1.0

<0,053

<0.15

0.051 0

<0.019

<1.60 -

<0.16

<2.0 <2.0

<0.16 <0.16

<0.019* <0.019 <0.019

-<2.0 <0.16

0.024 O* 0.027 0 <0.019

-<2.0 <0.16

<0.15

<0.019

<0.019

0.49 -

0.18

<0.20 <0.20 <0.024 <0.024 <0.020 <0.018 <0.018

-<0.20

<0.024 <0.020 <0.018 <0.018

-<0.20

<0.024

<0.13

<0.018

<0.018

0.08 —

0.21

0.1 <0.050 <0.030 <0.030 0.022 O <0.020 <0.020

— <0.050

0.18 0.048

0.050 Q <0.020

-<0.050 <0.030

<0.15

<0.020

<0.020

<0.05 -

<0.022

<0.024 <0.024 <0.022 <0.022 0.030 Q <0.018 <0,018

-<0.024 <0.022 0.042 Q 0.041 Q <0.018

--<0.024 <0.022

<0.14

<0.018

<0.018

<0.08 -

<0.036

<0.050 <0.050 <0.036

0.20 0.036 Q <0.018 <0.018

-<0.050 <0.036 0.032 Q 0.026 Q <0.018

-<0.050 <0.036

<0.07 -

<0.087

<0.04 <0.05 - <0.28 0.62 ..

<0.067 0.090 <0.036 <0.053 <0.025 Well not sampled - well did not recover after purge

<0.08 -

<0.030

Well abandoned as part of sewer construction during 2004

<0.20 <0.20

<0.087 <0.087 0.058

<0.021 <0.021

-<0.20 <0.087 0.025 0 0.023 O <0.021

-<0.20

<0.087 Not sampled

<0.14

<0.018

<0.018

<0.16

<0.021

<0.021

<0.050 <0.10 - <0.20 <0.40 <0.050 <0.10 - <0.20 <0.40 <0.067 <0.022 <0.036 <0.053 <0.025 <0.067 <0.022 <0.036 <0.053 <0.025 0.025 0 0.021 Q 0.047 0 0.020 0 <0.017* <0.019 <0.016 <0.022 <0.016 <0022 <0.019 <0.016 <0.022 <0.016 <0.022

.. <0.050 <0.10 - <0.20 <0.40 <0.067 0.12 <0.036 <0,053 <0.025 0.027 Q 0.033 Q <0.016 0.059 <0.017* 0.030 0 0.039 Q <0.022 0.071 <0.022 <0.019 <0.016 <0.022 0.027 0 <0.022

-<0.050 <0.10 - <0.20 <0.40 <0.067 <0.022 <0.036 <0,053 <0.025

<0.10 <0.10

<0.030 <0.030 0.054 0 <0.017 <0.017

-<0.10

<0.030 0.022 0 0.019 Q <0.017

-<0.10

<0.030 Well did not recover sufficiently after purge for analysis of PAHs

Insufficient water volume to purge and sample <0.15 <0.12 <0.17 <0.12 <0.16

<0.019 <0.016 <0.022 <0.016 <0.022

<0.019 <0.016 <0.022 0.018 0 <0.022

<0.13

<0.017

<0.017

<1.10 -

2.7

<1.0 <1.0

<0.067 0.18 0 0.43* <0.022 <0.022

-<1.0

<0.067 <0.024 <0.022 <0.022

<1.0 <0.067

<0.17

0.025 0

0.026 0

<0.15 -

0.46

<0.40 <0.40

<0.036 <0.036 <0.016 <0.020 <0.020

-<0.40

<0.036 0.034 Q 0.044 0 <0.020

-<0.40

<0.036

<0.15

<0.020

<0.020

<0.03 -

<0.13

<0.20 <0.20 <0.13 <0.13

0.020 0 <0.016 <0.016

-<0.20 <0.13 0.065* 0.067

0.027 0

-<0.20 <0.13

<0.12

<0.016

<0.016

<1.20 -

<0.095

<1.0 <1.0

<0.095 <0.095 <0.018* <0.020 <0.020

-<1.0

<0.095 <0.018* <0.020 <0.020

-<1.0

<0.095

<0.15

<0.020

<0.020

<0.21 -

<0.096

<1.0 <1.0

<0.096 <0.096 <0.017* <0.023 <0.023

-<1.0

<0.096 <0.017* <0.023 <0.023

-<1.0

<0.096

<0.17

<0.023

<0.023

1.2 -

3.6

nd nd nd 0.2 0.8 nd nd

-nd nd 0.4 0.4 0.05

--nd nd

nd

0.1

0.04

bailer bailer bailer

--

bailer bailer bailer bailer

low flow low flow low flow

bailer bailer bailer bailer bailer bailer

bailer bailer bailer bailer bailer bailer

low flow

low flow

1

--

----

insufficient well volume for complete purge --

---

insufficient well volume for complete purge insufficient well volume for complete purge insufficient well volume for complete purge

--

slight MGP type odor --


-

-

|U -JTB /GHL08 /021 |U-RJC/JTB12 /021 (U-PAR/JTB 9 /0311U-MJR/JTB 2/0511PAR/RLH 5/05]

Notes: 1) Concentrations that attain/exceed a PAL are underlined/italicized. 2) Concentrations that attain/exceed an ES are underlined/bold,

nd : Not detected. ns : Standard has not been established. ~ : Analysis not performed.

dup : Field duplicate sample, field identification in parentheses. - : Not recorded.

< : Constituent was not identified above the limit of detection indicated. D : Laboratory note - Analyte value from diluted analysis. E : Laboratory note - Analyte value exceeds calibration range. Q : Laboratory note - The analyte has been detected between the limit of detection (LOD) and limit of quantitation (LOO). & : Laboratory note-Laboratory Control Spike recovery not within control limits. * : Laboratory note-precision not within control limits.

1549GWOualityData 050809 TbI 3 - GW PAH Page 3 of 3

Table 4 - Groundwater Analytical Results - RNA Parameters Apr i l 2005 Groundwater Ouality Update -1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #; 02-38-000047

S a m p l e L o c a t i o n Sam

ple

Dat

e

L a b o r a t o r y Pa rame te rs (mg/L)

•D 0) > o in in

5 c o

c "> re .i2 E D

(A

< o

CM O z

• I -CO O z c 0) O) o z

c re 3

re I S 3 in

W i s c o n s i n G r o u n d w a t e r Qua l i t y S t a n d a r d s (NR 140

P r e v e n t i v e A c t i o n L im i t (PAL)

E n f o r c e m e n t S t a n d a r d (ES)

MW-302

MW-303

MW-304

MW-305

MW-306

d u p ( Q C - l )

MW-307R

d u p ( Q C - l )

MW-308

MW-310

MW-311

MW-1

MW-3R

MW-4

d u p ( Q C - 1 )

MW-5

dup (QC-2)

11/22/04

04/14/05

11/22/04

04/14/05

11/22/04

04/14/05

11/22/04

04/14/05

11/22/04

11/22/04

04/13/05

11/22/04

04/13/05

04/13/05

11/22/04

04/13/05

11/22/04

04/13/05

11/22/04

04/13/05

11/22/04

04/13/05

11/22/04

04/14/05

11/22/04

11/22/04

04/14/05

11/22/04

04/14/05

04/14/05

0.15 0.3

0.92

1.1

8.9

0.19

0.28

0.026

0.061

15

4.5

20

28

0.71

0.35

28

21

1.2

2.7

11 12

1 1 <0.017

M

0.018

<0.017

0.025

0.05

0.13

0.16

1.3

0.92

0.25

0.32

0.00045

0.0081

0.39

0.39

0.65

2J

1.5

1.5

2.2

1.5

3

2.7

0.81

1.3

1.2

0.021

0.68

0.48

0.42

140

700

2 5 0

3 8 0

600

4 0 0

2 2 0

490

2 7 0

2 6 0

350

350

380

6 5 0

710

590

540

400

370

1,100

690

590

5 4 0

850

4 0 0

410

2 7 0

3 0 0

2

10

<0.063

<0.061

<0.063

0.43

0.064 0

0.58

4.3

6.6

<0.063

<0.063

<0.061

<0.063

<0.061

<0.063 <0.061

<0.063 <0.061

<0.063

<0.061

<0.063 <0.061

0.80

0 4

ns

ns

0.22

0.04

0.85

0.48

0.033

<0.01

<0.01

<0.01

0.043

0.05

0.11

4.1

4.2

2.1

0.66

0.17

0.034

1.3

1.2

3.2

5.3

0.035 <0.01

125 250

52

160

24

67

490

630

34

47

9.8

9.7

100

5.3

12

25

14

49

32

13

28

5.0

20

290

280

Samples damaged,

<0.063 <0.01 93

Wel l damaged, aban

2 .7

Z 9

<0.01

<0.01

66

38

F ie ld Pa rame te rs

3

X a.

B, °

o 3

, February 2004)

ns ns

ns

ns

o o

O 3

1 .

a E

ns

ns

c: O) >> X O T3 C _>

o S

ns ns

E.

X 0)

ns

ns

insufficient well vo lume for readings

6.73 2.22 7.58 0.87 427

7.31

7.21

8.00

7,14

7.9 7.24

7.52

7.43

8.1

7.05

8.05

6.-97

7.23

6.88

7.18

7.17

7.27

7.07

7.61

7.01

1.766

1.48

1.425

1.92

1.400

2.17

0.615

0.911

1.313

1.39

2.1

2.01

1.237

0.98

1.984

2.12

2.870

2.390

1.960

1.260

jnab le to analyze

7.85 1.73

doned April 2005

7.76

7.10

1.439

1.54

13.18

9.13

13.53

5.98

12.98

8.73

10.77

6.2

12.7

6.23

11.8

11.56

12.94

8.02

12.11

6.82

10.31

4.82

13.96

7.90

10.16

11.67

9.86

1.48

0.29

1.39

1.16

5.99

2.27

1.45

0.70

0.40

0.56

0.64

0.45

1.2

0.64

1.08

0.96

0.76

1.77

6.88

2.83

0,84

0.70

93,5

160

72.9

430

360

425

104.5

320

220

219

250

265

63.2

224

167.5

337

284

244

385

395

420

168.1

423

P IEZOMETERS |

P-302

P-303

P-304

P-305

11/22/04

04/14/05

11/22/04

04/14/05

11/22/04

04/14/05

11/22/04

6.6

6 ^

0.04 0

0.033 0

4.7

0.23

0.23

0.0038 0.034

1.7

2 6 0

250

2 0 0

190

0.063 0

<0.061

0.26

0 . 1 8 Q

<0.01

0.017

<0.01

<0.01

30

30

670

680

Insufficient water volume

Insufficient water volume

720 0.22 0.038 76

8.22

7.28

--

to purge

to purge

7.42

0.970

1.09

::

12.00

10.18

-and sample

and sample

1.99 12.78

0.68

0.30

-

3.60

238

80

""

366

1549GWQualityDala 050809 TbI 4 - RNA Page 1 of 2

Table 4 - Groundwater Analytical Results - RNA Parameters A p r i l 2 0 0 5 G r o u n d w a t e r Oua l i t y Upda te - 1603 E l y St reet , Mar ine t te , W i s c o n s i n

W i s c o n s i n Pub l i c Se rv i ce C o r p o r a t i o n • F o r m e r M a r i n e t t e M a n u f a c t u r e d G a s P lant S i te

B R R T S #; 02-38-000047

S a m p l e Loca t i on

s 0) a. E re

CO

L a b o r a t o r y Pa ramete rs (mg/L)

0)

> o (A 0)

5 C o

Man

gane

se,

Dis

solv

ed

Alk

alin

ity (

as

CaC

03)

Nitr

ogen

, N

03 -i

N02

Met

hane

Sul

fate

W i s c o n s i n G r o u n d w a t e r Qua l i t y S tanda rds (NR 140

P reven t i ve Ac t i on L im i t (PAL)

E n f o r c e m e n t S t a n d a r d (ES)

04/13/05

0.15 0.3

6 ^

0.025 140 2 ns 125 0.05 700 10 ns 250

1.8 690 0,11 0 0.054 150

Field Pa ramete rs |

3 J2-X a

li = E o 3

, F e b r u a r y ^ 2 0 0 ^

ns ns

6.71

ns

ns

1.46

o o

s; 3

£ Q. E 0)

1-

ns

ns

9.36

c o ai >. O •o >

§ 1 5 S

ns ns

0.82

>" E,

I

ns

ns

323

IJTB/PAR 2;05)|PAFVRLH 5/05)

Notes :

1) 2)

R N A : ns :

p m h o s / c m

d u p :

Concentrat ions that attain/exceed a PAL are underlined/italicized.

Concentrat ions that attain/exceed an ES are unde r l i ned /bo ld .

Remedial Natural Attenuat ion.

Standard has not been establ ished.

Analysis not performed.

Iîcromhos per centimeter.

Field duplicate sample, f ield identif ication in parentheses.

°C : Degrees Celsius.

mV : Millivolts.

s . u . : Standard units.

Q : Laboratory note - Analyte detected between the limit of detection (LOD) and limit of quantitation (LOO).

1549GWQualityData 050809 TbI 4 - RNA Page 2 of 2

APPENDIX A

SOIL BORING LOG INFORMATION, MONITORING WELL CONSTRUCTION, MONITORING WELL

DEVELOPMENT, AND BOREHOLE ABANDONMENT FORMS

State ofWisconsin Department of Natural Resources

W E L L / D R I L L H O L E / B O R E H O L E A B A N D O N M E N T Form 3300-5 2/2000 Page 1 of 2

Nodce: Please complete Form 3300-5 and return it to the appropriate DNR office anci bureau. Completion of this report is required by chs. 160, 281, 283,289, 291. 292, 293, 295. and 299, Wis. Stats., and ch. NR 141, Wis. Adm. Code. In accordance with chs. 281. 289, 291, 292, 293,295, and 299. Wis. Stats., failure to file this form may result in a forfeiture of between $10 and $25,000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable infonnation on this form is not intended to be used for any other purpose. NOTE: See the instructions for more infomiation.

Route to:l I Drinking Water I I Waiershed/Wastewater I I Waste Management I 1 Remediation/RedevelopmentI 1 Other

(1) G E N E R A L I N F O R M A T I O N i (2) F A C I L I T Y / O W N E R I N F O R M A T I O N Wl Unique Well No. DNR Well ID No. County Facility Name

Former Marinette M G P Site (1549)

Common Well Name. M W - 2

1/4 of Grid Location

)/4ofSec.

Gov't Lot (if applicable)

_ N ; R n ^

• W

Facility ID

238000047

License/Permit/Monitoring No.

.ft. n N. D s.,

Street Address of Well

Mann St. Marinette, Wl

.ft. D E. n W. City, Village, or Town

Local Grid Origin W (estimated: I I ) or Well Location I I

O I t l o t t '

Lat Long or

Present Well Owner

Shirlev Scharff

Original Owner

Wisconsin Public Service CorDoration

State Plane. .fi.N.

S C N

.ft. E. D D D Zone Street Address or Route of Owner

400 N. Adams St. PO Box 19002 Reason For Abandonment

Utility Construction

Wl Unique Well No.

of Replacement Well N/A

City, State, Zip Code

Green Bav,Wl 54307 (3) W E L L / D R I L L H O L E / B O R E H O L E I N F O R M A T I O N f4) P U M P . L I N E R . S C R E E N . C A S I N G . & S E A L I N G M A T E R I A L

Original Construction Date

l2Sl Monitoring Well D Water Well

D Drillhole/Borehole

Construction Type:

Kl Drilled

D Other (Specify)

Formation Type:

5/25/1990

If a Well Consttuction Report is available, please attach.

Pump & Piping Removed? Liner(s) Removed? Screen Removed? Casing Left in Place?

D Yes D No l SI Not Applicable • Yes D No M Not Applicable Kl Yes D No D Not Applicable D Yes I S No

I I Driven (Sandpoint) D Dug

Was Casing Cut Off Below Surface? Did Sealing Material Rise to Surface? Did Material Senle After 24 Hours?

If Yes, Was Hole Retopped?

D Yes D No D Yes D No D Yes D No D Yes n No

Unconsolidated Formation

9.9 Total Well Depth ( f t )_ (From ground surface)

Lower Drillhole Diameter (in.)_

I I Bedrock

Casing Diameter (in.).

Casing Depth (ft.)

2.05

Required Method of Placing Sealing Material

I I Conductor Pipe - Gravity I I Conductor Pipe - Pumped I I Screened & Poured ^ Other (Explain) Construction

(Bentonite Chips) Activities

9.9

8.0

Was Well Annular Space Grouted? CD Yes

If Yes, To What Depth?

Depth to Water (Feet)

No I I Unknown

Feet

3.9

Sealing Materials I I Neat Cement Grout I I Sand-Cement (Concrete) Grout I I Concrete I I Clay-Sand Slurry I I Bentonite-Sand Slurry I I Chipped Bentonite

For monitoring wells and monitoring well boreholes only

I I Bentonite Chips I I Granular Bentonite I I Bentonite-Cement Grout I I Bentonite - Sand Slurry

(5) Sealing Material Used From (Ft.) To (Ft.) Mix Ratio or Mud Weight

Granular Backfill Surface > 9 . 9

(6) Comments Removed dur ing utility construction.

(7) Name of Person or Firm Reporting

Natural Resource Techno logy . Inc. rft of Person Reponii Z ! L ^

Street or Route

23713 W. P a u l R d . Ste. D

Date of . ilinnrlnnwifni

8^27/04 i ^ a m t g D Date SigT^d

Telephone Numbe!

262.523.9000 Cit>', State. Zip Code

Pewaukee, Wl 53072

STS Consultants Ltd.

OWNER

C i t y of M a r i n e t t e

PROJECT NAME Former Coal G a s i f i c a t i o n P l a n t

LOG OF BORING NUMBER

B-2 ( f V \ U j - 2 -

ENGINEER STS C o n s u l t a n t s , L td .

SITE LOCATION

S

Wastewater T rea tmen t P l a n t C i ty of M a r i n e t t e , Wisconsin

WELL INSTALLATION TOP STANDPIPE EL. + 586.38

DESCRIPTION OF MATERIAL

SURFACE ELEVATION 584.42

^ t :

I -< CO

LU m

o

O LU

otr: <

CO a . < ^

i n >

LU fC S i i

SS

SS

SS

Dark brown to black fine sand (SM) - trace of coarse sand - trace of fine gravel - trace of wood, organics - dry - loose to medium dense fluvial

12 210

SS

-te

ll

SS

Brown to reddish brown silty clay (CL) - trace of fine sand - trace of fine to medium gravel -wet - loose - fluvial

Black fine to medium silty sand (SM) - trace of fine to coarse gravel - a little wood - wet -extremely dense - fluvial

15

End of Boring Boring advanced from 0.0 to 10.9 feet with hollow stem auger 2-inch Schedule 40 PVC monitoring well installed at 9.9 feet with protector pipe and lock

1004 320

Thtf s i ra l t l l ca t ion lines reoreaant ine apofoxtmi ia DounOfV o^ lwtBn so*l types. In altu. tn« i r a n m i o n may DC graouaj. W i w f tevwft w r e maaaureo at trw urrws ind tca l t l . W t e r Igv ia may vafV aeaaonil

«l- 6 . 5 ' WS

WL.T. PIPE DATE

BORING STARTHD 5-25-90

BORING COMPLETED 5 - 2 5 - 9 0

RIO M o b i l e B61

FOREMAN TT

STS OFFICE 540 Lambeau S t r e e t Green Bay, Wl 54303

DRAWN BY PDP

APP-D. BY p L E STS JOB NO. 17538XF

BCG 9421

£5^ HELD WELL INSTALLATION DIAGRAM

TND CAP WTTM HOLt r >-''-' ON STANDAPIPE

^ , ^ ' STANDPIPE SnCK-UP

I

i I a

z "3 E

U

It.

o a.

PIPE DIA.

'Z- INCH

SCH. J i ^ (F r<ve laD)

( p ^ '

' f ' f

zx nLTER.PACK

lo BACI

I ;LL NO.

ILLER .

ELEV. TOP OP PIPE

PROTECTIVE PIPE LENCTW ^ - . O

SURFACE SEAL

ANNULAR SPACE SEAL

BENTONITE SEAL

c-r)'SCREEN •' LENGTH

1) TTPE OF PIPE?

C ^ D GALVANIZED. STAJNliSS, OTHER

2) TrPE OF PIPE JOINTS? Q H R E A D ^ (3THER

3) TYPE OF WELL SCREEN?

( ^ J ) (3ALVANI2ED. STAINLESS. OTHER

4) SCREEN SIZE? 10 6uo-r

5) INSTALLED PROTECTOR PIPE WITH LOCK?

( ^ ) NO

6) WAS DRILUNG MUD USED? YES

SOUD AUGER. CWLLOW STEM AUGES) WATER. REVERTT BENTONITE

7) DID S T M W \ P t COME UP WHEN CASINO WAS PULLED? ^ — 1 ^

8) DEPTH OF WEU FROM TOP OF PVC ' ' • '

9) FILTER PACK: NO. OF BAGS. D.'Z>

10) RNE SAND SEAL: NO OF BAGS

11) BENTONITE SEAL NO. OF BAGS OR PAILS. /

12) ANNULAR SPACE SEALS; BAGS/INCHES WATER

/ INCHES

TTÊMIE D POURED D

INCHES PUMPED

NOTE: INCHES OF WATER AS MEASURED IN SS GAL DRUM

BOTTOM CAP , ^ , WTFH HOLE - ^ E . - )

3 ' l J m r ' ^ ^ ^ INSTALLED ^ - " ^ ^ ^ ^ ^

^ • V - M - DRILL CREW 0-^- ^ ^ - ^ -

DRILL RIG ^ 3

3/CLIENT C ^ ^ ^ 6r'-ASS\?ÎCATiOvJ STS JOB Kin n ^ ^ ' b ^ F

MBtT'.

Stale of Wisconsin Depanment of Natural Resources

MONITORING WELL CCWSTRUCTION Form 4400-113A 8-89

Faciiiiy/Projeci Name f^}r(Y\^r !%sf i ^ t t c

Facility License, Permit or Momionng Numbw

Gndl

lypeofWeil Wsie Table Obsavaioa Weli,

PiezCTneter D12 Chstance Well is rrom Waste/ilource tioundaiy

- - 3 0 0 ft Is WeU A Pomiof Enforcement Std. Applicaaon?

ISfYes n hfc

shxre^'V\£ij\€ Coord' nare .

^ m . ^ U . O ft. ^ K n s. a . l rW^^n .^ ft. )Ê. DW.

SecooB Location ^ ^ 1/4 of S ^ 1/4 of Section ^

Location of WeU ReUuve ^ Wasiey'Source Q Upgradmt

^ S ^ Downgradient D Sidegndoent n Not Known

Well Name \i\\}0 - z-

"DRTwar

bate Well Insuiletf

WeU installed By: (Peisoo's Name

0.^1^^12.0. m m 0 o Y V

and firm)"

A. Protective pipe, \ap elevation ft. MSL

B. WeU casing, top elevation _ ^ £'ii? -sS 2 ^ ^ ^ ^

C. Land surface elevation _ i . % ^ . ^ f* MSL

D. Surface seaL botttwn ._ ft M S L or _ i 2 . Z ft-

1. Cap and lock? 2. PrDlectivc cover pipe;

£. Inside diameter b. Length: c. MateriaL

12. u s e s classification of soil near screen: D G P n G M n G C D G W D S W D S P B S M D S C n M L D M H ; ^ C L D CH DBedrock

13. Sieve analysis attached? D Yes W No

14. Drilling method used: Rotary 0 5 0 Hollow Stem Auger ^ 0 ^ 4 1

d. Additional protection? If yes, describe;

Surface seal:

15

i <

17

Drilling fluid used:Water D 0 2 Drilling Mud [3 0 3

Drilling additives used? D Yes

Describe Source of water (attach analysis):

\JIISS

Air None

D 01 J S ( 9 9

x

E. Benionite seal, top fl. MSL or ._ ft.

F. Fine sand, top ft. MSL or fl

G. FUter pack, top ft-MSLor_^_2 ^ '

H. Well SCTeen, top ft. MSL or _ _ ^ . 5

[. Well screen, bottom ft- MSL or _ J ^ f^

I. Filter pack, bottom ft- MSL or _ j ^ Q ^

K. Borehole, bottom ft- MSL or _ X (2 . 2

' ^.i-^r-^Knlc Akcsn^' isr r-/ r^ iL.U ^^

M. C D . well casing _ ( £ .-2 in.

^. LD. wen casing _ ^ . 0 . 6 . ~ »»-

^ Y « D

Sted JE^ 0 4

D Yes a ; hfe

Bentonite Concrete

D D

30 01

. Material between well casing and proiecdvei)ip)e: protecnvepiise: Bentonite D

Annular space seal M Otter D

5. Annular space seal: Granular Bentoniie O Lbs/gal mud weight... BentoniiB-sand shiny n Lbs/gal mud weight Bentonite shmy D % Bentqnite Bauonite-cemenl grout D

' " vohitne added for any of the above Tremie Q

Tremie pumped •

30

33

35

31

50

01

02 Gravity " ^ o 8

Bentonite granules • 33

D1/4 in. D3/8 in. D 1/2 in. Bentonite pellets Q 3 2

Other D 1_:

7. Fine sand material: Manufacturer, product name and mesh size

8. Filler pack material: Manufactuier, product nam<

Voliine added " / 7 < ft3 9. Well casing:

le and mesh size

Flush ihreadsd PVC schedule 40 JSL 2 3 Flush threaded PVC schedule SO C 24

Otter D m

10. Screen material: Screen type;

^ D V T "

Facteay cm JS^ 11 Continuous slot O 0 1

^ Other D 1 1 Manufacmrer GTTPfS i i H t^ I j ] / o r ^ igr»T A^^ 5t^pplid SkK size: ' Q. dLQ'rs-Stotied lengdi: _i ' .Oft-

11. BadcGU material (bdowSlterps^v J NCSB •

Q^;gl Qbv certify that the information on this form is true and correct to the best of my knowledge.

>l£D&£urc mill Û . ^ , , . _ . . ..,„„.... . 1 ^ Q- - ^ P i e a » complete Hid tetmil'lJQlh sKiei(4!)t tins form as reqiured oy ch^ 144, 147 and 160, Wis. Stais^ anft ch. NR 141. Wit. Aom. Cooe. in accordance with h. 144, Wis Stais.. failure to fik this form i i u y r e s u k in a forfeitiBe of not lest tiiacSlO.iiac more than SS.OOO for each day of v iola tk^ inaccordance îth ciL 147, Wis. Stats., failure to fik this form may result in a forfeiture of not HXKB than 510,000 far each day of violatioii.

i-fOTH: Shaded areas arc for DNR use onty. See instructions for moRinfcnnaticK.

Stale ofWisconsin Depanment ofNatural Resources

Route To: Waiershed/Wastewater D

Remediation/Redevelopment I

SOIL BORING LOG INFORMATION Form 4400-122 Rev. 7-98

Waste Management D

Other D

Page 1 of 2 Facillly/Projecl Name

Former Marinette MGP Site (1549) License/PermiL/Moniioring Number Boring Number

MW-3R Boring Drilled By: Name of crew chief (first, last) and Finn

Paul Boart Longyear

Date Drilling Started

10/7/2004

Date Drilling Completed

10/8/2004

Drilling Method

hollow Stem auger

Wl Unique Well No. DNR Well ID No. Common Well Name

MW-3R Final Static Water Level

579.2 Feet MSL Surface Elevation

585.7 Feet MSL Borehole Diameter

8.3 inches Local Grid Origin

State Plane

1/4 of

(estimated; Q ) or Boring Location Q

N, E S/C/N 1/4 of Section T N, R

Lat .

L o n g .

Local Grid Location

lEl N Kl E JH8447.37 Feet D S 805728.41 Feel D W

Facility ID

238000047 County

Marinette County Code

38 Civil Town/City/ or Village

Marinette

Sample

Z a

— -a < E

CJ OJ

-J a:

o U

m

Soil/Rock Description

And Geologic Origin For

Each Major Unit 1/3

U t / ) tn 00

— 00

O'

g u. Q

Soil Properties

u in o D =

0 0

0'-2' ORGANIC SOIL organic material and sand

OL

1 SS

2

s's

SS

4 SS

5 SS

24 24

24 20

24 24

24 18

24 10 12 13 16

— 4

-5

-6

— 7

2'-4.5' POORLY GRADED SAND light brown, fine, trace gravel

\ (5), 4.5' 1" layer of wood 4.5'-7.5'SILTY CLAY, black

(@ 5' 2" sand lens @ 5.5' few fine sand @ 6' few organics and wood pieces,

petroleum-like odor

SP

:L/MU

7.5'-12' POORLY GRADED SAND grey, fine, trace rounded gravel, no odor

- 1 0

— 11

•12

SP

I hereby certify that the information on this form is true and correct to the best of my knowledge.

Sianature J > - ^ ^ /_ Firm ]\jatural Resource Technology, Inc. 23713 W. Paul Road, Unit D Pewaukee. Wl 53072

Tel: (262) 523-9000 Fax:(262)523-9001

Template: WDNR SBL 1998 - Projeci; 1549GINT.GPJ This form is authonzed by Chapters 281. 283, 289. 291. 292, 293. 295. and 299. Wis. Stats. Completion of this form is mandatory. Failure 10 file this form ma\ result in forfeiture of between $10 and S25.000, or imprisonment for up to one year, depending on the program and conduct involved. Personally ideniifiabic information on this form is not intended to be be used for any other purpose. NOTE: See instructions for more information, including where the completed fon should be sent.

State ofWisconsin Depanment ofNatural Resources

SOIL BORING LOG INFORMATION SUPPLEMENT Fomi4400-122A

Boring Number M W - j R Use only as an attachment to Form 4400-122. Page 2 of 2

Sample

i ^ < H

cb O QJ ID

O



Each Major Unit c/) U t / i nj CO

63 ? Q D

Soil Properties

u

CJ

a 5

6 SS

7 SS

24 17

24 16

9 1 1 15 19

10 15 20 25

•13

- 1 4

•15

•16

12'-16'SILT, pink, trace rounded gravel

14' pink to gray, no odor, sheen ML

END OF BORING (a). 16'

Slate ofWisconsin Departmeni of Natural Resources „ _ ,,, , . , , , , i—i

Route To: Waiershed/Wastewater LJ Remediation/Redevelopment [

Waste Management D MONITORING WELL CONSTRUCTION Other D Form4400-113A Rev. 7-98

Faciliiy/Projecl Name

Former Marinette MGP Site (1549)

Local Grid Location of Well

148447.37 fl ^ ^ - 805728.41 _fl. G W .

Well Name

MW-3R Facility License, Permit or Monitoring No. Local Grid Origin

Lat.

(estimated: n ) of

Long. 1

Well Location •

or

Wis. Unique Well No. DNR Well Number

Facility ID St. Plane ft. N. ft. E. S /C /N 238000047 Section Location of Waste/Source

Date Well Installed

10/O8/2004 Type of Well

Well Code 11/mw .1/4 of. 1/4 of Sec. T. . N. R.

DE -D W

Distance from Waste/ Source ft.

Enf. Slds. Apply

Location of Well Relative to Waste/Source u D Upgradieni s D Sidegradient

d D Downgradient n D Nol Kjiown

Gov. Lot Number

Well Installed By: (Person's Name and Firm)

PauJ

Boart Longyear

585.68 f,, MSL A. Protective pipe, top elevation _

B. Well casing, top elevation _

C. Land surface elevation _

D. Surface seal, bottom 584.7 ft M S L or '•O ft.

585.50 fi. MSL

585.7 f,, MSL

12.

13

14

15

16

17

u s e s classification of soil near screen: GP D GMD GCD GWD SW D SP 12 SMD s e n MLSI MHD CL SI CH D Bedrock D

Sieve analysis attached? D Yes S No

Drilling method used: Rotary DSC Hollow Stem Auger S 4 1

Other n

Drilling fluid used: Water D 0 2 Air D 0 1 DnllingMud DO 3 None Kl 9 9

Drilling additives used? DYes H No

Dpsri-ibp

Source of water (attach analysis, if required):

n/a

E. Bentonite seal, top

F. Fine sand, lop

G. Filter pack, top

H. Screen joint, lop

1. Well bottom

fl. MSL or

582.7 fl, MSL or 3.0 ft.

582.2 ft MSI, or 3.5 ft.

580.7 ft MSL or 5.0 ft .

570.7 ft, MSL or ' 5 0 ft.

J. Filter pack, bottom 570.2 ft MSl .nr '5.5 ft

K. Borehole, bottom 569.7 ft, M S L or I M ft.

L. Borehole, diameter "•3 in.

M. O.D. well casing -^33 in.

N. l.D. well casing 2.07

1. Cap and lock?

• 2. Protective cover pipe:

a. Inside diameter:

b. Lengih:

c. Material:

Yes D No

8.0

iS/tiiL d. Additional protection?

If yes, describe:

Steel D

Other K

D Yes B

' 3. Surface seal: Benionite D

Concrete IE

_ Other D

4. Material between well casing and protective pipe:

Bentonite D sand Other IS

• 5. Annular space seal: a. Granular/Chipped Bentonite B

b Lbs/gal mud weight. . . Bentonite-sand slurry D

c Lbs/gal mud weight. . . Bentonite slurry D

d % Bentonite . . . Benionite-cemenl grout D

e Ft'' volume added for any of the above

r How installed: Tremie D

Tremie pumped D

Gravity H

6. Benionite seal: a. Benionite granules D

b. D 1/4 in. D 3/8 in. D l / 2 m . Bentonite chips •

c Other O

, 1 . Fine sand material: Manufacturer, product name & mesh :

a itl Badger

in.

L ft. 04

No

30 01

30

33 35 3 1 50

01

02

08

33

32

b. Volume added ft^ _ 8. Filter pack material: Manufacturer, product name & mesh size

a #40 Badger

b. Volume added ft

9. Well casing: Flush threaded PVC schedule 40 B 2 3

Flush threaded PVC schedule 80 D 2 4

Other D

10. Screen material:

a. Screen Type:

PVC

Factory cut K 11

Continuous slot D 0 1

Other D Boart Longvear b. Manufacturer _

c. Slot size:

d. Slotted length:

11. Backfill material (below filter pack):

O.OIO in.

'0-0 ft.

None D 1 4

Other Kl

I hereby certify that the information on this form is true and correct to the best of my knowledge. Signature

^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ Firm Natural Resource Technology. Inc.

23713 W. Paul Road, Unit D Pewaukee. Wl 53072 Tel: (262)523-9000 Fax: (262) 523-9001

Please iofnpleie Both Forms 4400-113A and 4400-113B and rerum them to the appropriate DNR office and bureau. Completion of these reports is required bv chs. 160. 281. 283. 289, 291. 292. 293. 295. and 299. Wis. Siai.s.. and ch. N'R 141. Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295. and 299. Wis. Siais.. failure to file these forms may result in a forfeiture of between SIO and S25,000. or imprisonment for up to one year, depcndinii on the program and conduct involved. Personally identifiable information on these form IS not intended to be used for any other purpose. NOTL. Sec Ihe instruciions for more infonnation. including where the completed forms should be seni.

Stale ofWisconsin Department ofNatural Resources

MONITORING WELL DEVELOPMENT Form 4400-113B Rev. 7-98

Route To: Watershed/WastewaterCH

Remediaiion/RedevelopmenB

Waste Management CI

Other D Facility/Project Name

Former Marinette MGP Site (1549) Facility License, Permit or Moniloring Number

1. Can this well be purged dry?

2. Well development method: surged with bailer and bailed surged with bailer and pumped surged with block and bailed surged with block and pumped surged with block, bailed, and pumped compressed air bailed only pumped only pumped slowly other

3. Time spent developing well

4. Depth of well (from top of well casing)

5. Inside diameter of well

6. Volume of water in filter pack and well casing

7. Volume of water removed from well

8. Volume of water added (if any)

9. Source of water added N/A

10. Analysis performed on water added? (If yes, attach results)

IS

D D D • D D D

D D

D

County

Marinette Counry Code

38

Yes D No

4 1 61 42 62 70 20 1 0 5 1 50

54 min.

14.8 fl.

2.07 in.

8.0 gal.

24.0 gal.

0.0 gal.

Yes D No

Well Name

MW-3R Wis. Unique Well Number DNR Well Number

Before Development After Development 11. Depth to Water

(from top of ^ 6 5 0 ^ 13.53 ft. well casing)

Date b. 10/8/2004 10/8/2004

B a.m. S a. Time c. 10:40 D p.m. 11:34 D p

12. Sediment in well 0.8 inches inches bottom

13. Water clarity Clear D 10 Clear H 20 Turbid B 1 5 Turbid D 2 5 (Describe) (Describe)

Dark brown, silty,

opaque

Fill in if drilling fluids were used and well is at solid waste facility:

14. Total suspended mg/1 mg/1 solids

15. COD mg/1 mg/1

16. Well developed by: Person's Name and Firm

Jody Barbeau

Natural Resource Technology, Inc. 17. Additional comments on development:

Pumped dry 4 t imes during d e v e l o p m e n t

Facility Address or Owner/Responsible Parly Address'

Name: Shirley Scharff

Film: Wisconsin Public Service Corpo ra t i on

Street: 700 N . Adams St. PO Box 19002

City/Staie/Zip: Green Bay, Wl 54307

I hereby certify that the above infonnation is true and correct lo the best of my knowledge.

Signamre:

y Pnm Name: Jody B a r b e a u .

YxYm: Na tu ra l Resou rce Technology. Inc.

N O T E : See instructions for more in format ion including a list of county c o d e s and well type codes.

Stale o fWiscons in

Department ofNatural Resources

W E L L / D R r L L H O L E / B O R E H O L E A B A N D O N M E N T Form 3300-5 2/2000 Page I of 2

Notice: Please complete Form 3300-5 and rerum it to the appropriaic DNR office and bureau. Completion of this report is required by chs. 160, 281. 283, 289, 291, 292,293, 295, and 299, Wis. Stats., and ch. NR 141, Wis. Adm. Code. In accordance wiih chs. 281. 289. 291, 292, 293, 295, and 299, Wis. Stais.. failure to file ihis form may result in a forfeiture of between SIO and S25.000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable information on this form is not intended to be used for any other purpose. NOTE: See the instruciions for more information.

Route to:l I Drinking Water I ^ Waiershcd/Wastcwaicr I I Waste Management B ] Rcmcdiation/Redevelopmenll I Other

( I ) G E N E R A L I N F O R M A T I O N | (2) F A C I L I T Y / O W N E R I N F O R M A T I O N

Wl Unique Well No.

N/A

DNR Well ID No. County

Marinet te

Facility Name

Former Marinette M G P Site (1549)

Common Well Name _

1/4 of Grid Location

MW-4

1/4 of Sec.


_ . N ; R n ^

• w ft. D E. n w.

Facility ID

238000047

Liccnse/Pcrmit/Monilorine No.

ft. D N. D s.,

Local Grid Origin QQ (estimated: I I ) or Well Location I I

O < It o I "

Lat Lone oi


1603 Ely St. Marinette. Wl City. Village, or Town

Marinette Present Well Owner

Shirlev Scharff

Original Owner

Wisconsin Public Service Corpo ra t i on

Slate Plane. . ft. N. .ft E. D D D Zone Street Address or Route of Owner

400 N. Adams St. PO Box 19002 Reason For Abandonment

Ulilitv Conslruclion

Wl Unique Well No.

of Replacement Well N/A

City, State. Zip Code

Green Bay. Wl 54307

(3) W E L L / D R I L L H O L E / B O R E H O L E I N F O R M A T I O N (4^ P U M P . L I N E R . S C R E E N . C A S I N G , & S E A L I N G M A T E R I A L


QSi Monitoring Well

D Water Well

n Drillhole/Borehole

Construction Type:

1 3 Drilled

n Other (Specify)

Formation Type:

5/25/1990

If a Well Construction Report is available, please attach.

Pump & Piping Removed?

Lincr(s) Removed?

Screen Removed?

Casing Left in Place?

D Yes D No I2SJ Not Applicable

D Yes n No ^ Nol Applicable

1 3 Yes n No D Nol Applicable

D Yes 1 3 No


Was Casing Cut Off Below Surface?

Did Sealing Material Rise to Surface?

Did Malerial Seitlc Afier 24 Hours?

If Yes, Was Hole Retopped?

a Yes

1 3 Yes

D Yes

D Yes

D No

No

No

No

Unconsolidated Formation

9.9

8.0

Total WellDeplh(ft)_ (From ground surface)

Lower Drillhole Diameter (in.)_

Was Well Annular Space Grouted? I I Yes

If Yes, To What Depth?

Depth to Water (Feet).

i m Bedrock

Casing Diameter (in.).

Casing Depth (ft.)

2.05

Required Method of Placing Sealing

Q^ Conductor Pipe - Gravity

l_J Screened & Poured

(Bentonite Chips)

Material

1 I Conductor Pipe - Pumped

D Other (E.xplain)

9.9

No I I Unknown

Feet

5.0

Scaling Materials

I I Neat Cement Grout

I I Sand-Ccmcnt (Concrete) Grout

I 1 Concrete

I I Clay-Sand Slurry

I I Bcntonitc-Sand Slurry

123 Chipped Bentonite

For monitoring wells and

monitoring well boreholes only

' I I Bentonite Chips

ID Granular Bentonite

I I I Bentonite-Cement Groui

I I I Bentonite - Sand Slurry

Sealing Material Used From (Ft.) To (Ft.) Mix Ratio or Mud Weight

3/8" Chipped bentoniie Surface 12.5

(6) Comments Well dama.ged beyond repair

(7) Name of Person or Firm Ding Sealing Work

Namral Resource Technology. Inc.

Date of Abandonment

8/27/04

Sigoauire of Person Doing Work . r r l / ^

./Cr2>.^v.-j^_./_ '<LJ>c/..-i^nJu...tf Street or Route < \

23713 W. Paul Rd. Ste. D

Date Signed

9 / / 9 /0 r Telephone Number

262 .523 .9000

City, State, Zip Code

Pewaukee. W l 53072

STS Consultants Ltd.

OWNER

City of Marinette

PROJECT NAME Former Coal Gasification Plant

LOG OF BpRING NUMBER

B-4 / i H u ) - ^ ENGINEER STS Consultants, Ltd.

SITE LOCATION Wastewater Treatment Plant City of Marinette, Wisconsin

SE

WELL INSTALLATION „ . , , . , TOP STANDPIPE EL. + 5B7.67

DESCRIPTION OF MATERIAL

SURFACE ELEVATION 585 .61

E ^

S=:

IXJC/?

o-o < " J

i s 2 i i

SS Topsoil

- n -

ss

SS

ss

ss 5A SS

Brown fine to medium sand (SM) to (SP) - t r a ce of fine gravel - t race to a l i t t l e s i l t a t 7.5 to . 9.0 feet - wet at 5.0 feet - loose to dense -g lac ia l outwash

Gray clayey s i l t (ML) - t r ace of fine to medium sand - t r ace of organics - wet - dense -l acus t r ine

24

^ 1

-= 1

<Ll

41 •1

-11

End of Boring Boring advanced from 0.0 to 12.5 feet with hollow stem auger 2-inch Schedule 40 PVC monitoring well installed at 10.9 feet with protector pipe and loclc

Tne atrittlicatton lines repreaeni ttw appfojtimaie tX)uno«fy wtwwn ion tvpaa. in aitu. the tranalllon rrmv pa Qimouml. Wwar i»vwa wun m—aurgo at ine itmas indioieo. Walw levaia miy v»fv saasonidy

5 . 0 ' WS TIME WL.T, PIPE TIME

SORING STARTED 5-25-90

BORING COMPLETED 5 - 2 5 - 9 0

RIG CME 55

FOREMAN EVH

b4C) Lambeau S t r e e t Green Bay, Wl 54303

DRAWN BY PDP

PLE

SHEET 1 OF 1

17538XF BCG B421

HELD WELL INSTALLATION DIAGRAM

STANDPIPE

sncK-up

-7

m

Ul

in

I § E O

O

0.

PIPE DIA.

_ 1 _ | N C H

SCH. _ ! £ ,

6.1

u

WELL NO.

DRILLER _

RLTER, PACK

3ACKF11X 1 ^ 1 llf?

END CAP VWTH HOL£ x / ^ ON STANOAPIPE J _ I T

ELEV. TOP or PIPE

PROTECTIVE PIPE LENCTH 5 ' , o '

SURFACE SEAL

ANNULAR SPACE SEAL

BENTONITE SEAL

FINE SAND

WELL <'SCREEN

LENGTH

BOTTOM CAP WITH HOLE

1) TYPE OF PIPE?

C ^ J ) GALVANIZED. STAINLESS, OTHER

2) TYPE OF PIPE JOirfTS? C^REAOm^ OTHER

3) TYPE or WEa SCREEN?

( F ^ GALVANIZED, STAINLESS, OTHER

10 6 LOT 4) SCREEN SIZE?

3) INSTALLED PROTECTOR PIPE WTTH LOCK?

C ^ ^ NO

6) WAS DRIUJNC MUD USED? YES . C N O ^

SOUD AUGER. <pOUJDW STEM A U G ^ WATER. REVERT. BENTONITE

7) DID STANDPIPE COME UP WHEN CASING WAS PULLED? ^—s.

8) DEPTH or WELL FROM TOP OF PVC !!.=?

9) FILTER PACK: NO. OF BAGS. 6 10) nNE SAND SEAL; NO OF BAGS '

11) BENTONITE SEAL: NO. OF BAGS OR PAILS, , 7 -

12) ANNULAR SPACE SEALS: BAGS/INCHES WATER

/ INCHES

TREMIE D POURED D

INCHES PUMPED

NOTE: INCHES OF WATER AS MEASURED IN 35 GAL DRUM

DATE INSTALLED

DRILL CREW

^'ZS'°}0

u.e i f.(3-. DRILL RIG. ZS

JQR/CLIFNT mAi(.l*J5rTEr COAU C^^<£.[<^\i^îod STS JOB N O J 3 S M _ v J ^

Stiie ofWisconsin Depvtmeni of Natural Resoutcss

raciiiiyypro,eci Name f i r m e r / / h o V l f / f£^ pridLocabon 5 t f l t e "^loft* (JXira)na.VC IWeUNinie

Coal (Sasifitrafio^t^lmii- I ^ 7 4 ^^4^/^ f«- p( H D S

MONITORING WELL CONSTRUCTION Fom 4400-113 A 8.89

I i-aciliiy License, Peniiii or Moniionng Number

lypeofWeU WucTTaUeOtaerviticmWeUJ^

PJezometer WO, L>jstance Well is hom Wasta/Source Boundajy

-(303 / is WtU A Pouuof Enfoicemem SuL Applicauon?

'Yes D hfa

;5[2sS22l ft-^ E. D w. ^ n o n Lr>r>rmR

. S ^ 1/4 of 5 ^ 1/4 of Section C^

T : ? 0 N . R ^ ^ t r E D W Location of WeU Relative to Wasi^/Source

a Upipadiea D Sioegradien I t Etewngradiatt • Not Known

B

Date Well installed ' ^ 7 7 , . . '

^ £ / 4 4 / £ i 2 m m g o y V

Well installed By: (Penon's lâme n d Rnn)"

1

67:^5 CnnûlJ-oiAi^. l i - J A. ProtecDve pipe, top elevation . _ _ ft- MSL •

B. Well casing, top elevation ^ ^ . Z I . L ' l ^ MSL •

C. Land surface elevation ^ 6 . 1 ^ 6 .le f* MSL>

D. Surface seaL bottom ft. MSLor _ ' X . O ft-s

f l Z u s e s classification of soil near screen: DGP DGMnocncwnsw H'SP S'SM D SC OML D MH D CL B CH • Bokock

13. Sieve analysis attached? DYes ^B^Ni

14. Drilling method used; Rotary D 5 0 Hollow Stem Auger £ l 4 1

. Otter D mmi

12. Drilling fluid used-Watff J } 0 2 Air D 0 1 Dtil l ingMudDoB N O K D 9 9

16. Drilling additives used? D Y e s

Describe

35'No

17. Source of water (attach analysis):

. 1 . Cap and lock? . 2. Protective cover pqie:

a. inside diameter b. L x n j ^ c. MateriaL

d. Additional protection? If yes, describe:

• O i f

oiter n u D Yei JSLl

E . Bentonite seal, top . , ft- ^ ^ ^ °^ . - f \

F. Fine sand, top ft. MSL or ft-

G. Filler pack, top ft. MSLor _ _ j / _ ^ ft

H. WeU screen, top ft- MSL or _ _ . 5 . 2

L Wel l screen, bottom ft.MSLor__/5 2

J. Filter p a c t bottom ._ ft-MSLor _ J^S ^ fL.

K. Borehole,bottom ft.MSLot_iS.^ ft-^

L. Borehole, diametH ' _ ^ ^ 0 in.

M. O.D. weD casing _ 3 ^ 3 ^ in.

•>(. LD.wellciiing _ A .Q . -^ in. -

' 3. Surface seaL 1 Bentoniie D 31

/ I Concrete LJ 0! hgn-bnii-&/-^nrf .^/urnj othg -a^ J

' 4. Matoial between well casing and proiectiveîpe: ~W Benionite D 3 (

Annular space seal Q • ^ Other n J

- 5. Aimuiar space seal: Granular B«ntoniiB O 3 3 Lbs/gal mud weight.. . BenKsiite-sand slurry V ^ 3 j Lbs/gal mud weiglu Bentonite shmy D 31 % Bentonite Bentonite-cement grout O 5

How installed: .Ft volume added for any of the above

Tremie • 0 Tremie pumped Q 0

Gravity j ^ Q

6. Bentonite seal: Bentonite granules • 3 D1/4 in. 03/8 in. D 1/2 in. Bentonite pellets Q 3

Other n ;_ , 7. Fine sand material: Manufacturer, product name and mesh S)

Volume added nnaini [e and mesh si , 8. Filter pack material: Manufacturer, product

Vofiime added ^ a , 0 ft 3 9. WeU casing: Bush threaded PVC schedule 40 3 ^ ^ 2 3

Bush threaded PVC schedule 80 Q 2

Oew D i

I I 8

I 1 1

' 10. Screen material: Screen type:

^VO F a c m t y c u i ^ ^ ^ B

Continuous slot Q 0 l l .Other D i l

' hereby certify that the information on this form is true and correct to th* beaf of my knowledge

Manufacmter G r P ^ I i r € ^ / / y f J f i h p ( Y \ / t i < ^ Slot size; 7 O . O I u a M Sk)iuxi length: j i - O f W

iL-BaekfiUmaterial (bekw Stterpfck): / None Q

r ^ / W 7â(-rî l i ra ^ i d n ^ ' ^

til fuim as recnuret r r -n - t r romplm Bitd iTiTim tvith liiirri iriT^ ^ ^ H I MT iiiilK>n VVii "ran iiirtrh NF 111 Wji Aiim nwli In •rmnlnTifT in-iih • :h. 144, WisStats.. failitretofUethiafoimmayresiihinaforfeiiiireofiiotleaa tfaai$10.Hrin(MethmS5,000foreachdayofviolatioiL Ina B vitti ch. 147. Wis. Stats., failure to fik ifaia form may resolt in a forfeiwre of not more than SlOjOOO fior each day of violation.

, j f r i ' t - ' . ct>.«ia>4 —.^ — . c — r t k T B •-- "--• • ' . . .

I piTw ofWisconsin. lenarnneat of Natural Resources

W E L U D R I L L H O t E / B O R E H O L E ABANDONMENT Fonn 3300-5 2/2000 Page 1 of2

Niiiice: Please complete Form J300-5and return il lotheappropiate DNR office and bureau. Completion of tliis report is required by clis.160,281.283,289, '291.292,293,295, and 299.Wis.Stats.,and ch. imi41. Wis. .Adm. Code. In accordance with chs.. 281, 289, 291, 292, 293. 295, and 299, Wis.Sl2is.. failure to file liiis form may result in a forteiture of between SIO and 225.000, or imprisonment for up to one year, depending on theprogram and conduct involved. Personally identifiable iniormation on tiiis form is not intended to be used for any other purpose. NOTE: See the instructions for more information.

Rome lo: I I Drinking Water Cj Vatereiled/Waste^watE^ D Waste Management • REmediacion/'RedgveiormicnT DOther (I) GENSHAL INFORMATION (2) F A a U T Y I O VVNER iWFORJViATlON Wl Uniaue Weil No. DNR Well ID No. Counry Facility Name

(y \ \ ) J ' l>o \ Gov't Lai flf applicable)

S 2 Common Well Name

i ^ 1/4 of i ^ l / 4 o f S c c _ L ; T. ^ ° N;R. i ^ L Grid Locarion

fi. • N. n s.-Local Grid Oriain Q ( estimated: Q ) or Weil Location Q

o f f l » r II

Lat : Long : or S C N

St.Plane ft N. __ft. E. 0 1 1 1 0 Zone

Faciitty LD License/Perrait/Monitoring No.

Street Address of Weil

ft. D E. n "w. City, Village, or Town

Present Weil Owner Originai Owner

street Address jor Route of Owner

Resson For Abandonmcai IW IWlUniojueWellNo.

Seniacement Weil

City, State, Zip Code \ ^ 'SMl.o^

(3) WELL/DRILLHOLE/BOREHOLE INFORMATION 1(4) P U M P , LDJER, SCREEN, CASING. & SEAUNG MATERIAL

If a Well Consiruciion Report is available, pieas-e attach.

Original Consirucrion Date _ £ ^ J _ ^ ^ J j _ W \

lA^ Monitoring "Well

• Water Wen

• Borehole/Drillhole

Consnuction Tyj^c:

I ^ Drilled [ ] Driven (Sandpoint) D ^ S

• Other (Specify)

Formaiion Type:

K ! Unconsolidated Fomiadtjn LJ Bedrock

Total Well Depth (ft.) ' ^ Casing Diameter fm.) ^•O^*'? ^t>

(Fiomgroundsurfacs) Casing,Depth (ft.)

Lower Drillhole Diameter (in.) j £

Was Well Annular Space Grooted? • Yta 0 No • Unknown

IfYes. To Whar Depth? Feet.

Depth to Water {Peel)

P i n n p i Piping Rcmtyved? • Yes Q No • Not A-ppiitable

Ljncr(s) Removed? • Yes • No Q Not Applicable Screen Removed? Q Yes Q No Q Not Appiicajjlc Casing Left. in.Placii? 1 3 Yes • ' N o

Was Casing Car Off Below Surface? ^ Yes Q No .

Did Scaling MaierialRiie TO Surface? 0 Yes Q No

Did Mitcrial Settle After 24 Hoars? Q Yes ^ No

If Yes, Was Hole Retopped? Q Y e s ^ No

Required Method of Plating Scaling Material

1 2 Conductor Pipe-Gravity 1 I Condntanr Pipe-Pumped

n Screened 3L Poured O Other (Explain) (Bentonite Chips)

Sealing Materials 1 I Neat Clement Grout [~1 Sand-^Zement (Concrete) Grout n Concrete [~l Clay-Sand Sluny (11 IbJgal. wt) • Benioniie-Sand Sluny " " r~l Bentonite Chips

Formonitoring wells and monitoring well boieiioies tmly

H Bentonite Cliips

I I Granular Bentonite

M Bentonite - Cement Groui

I I Bentonite - Sand .Slurry

(5) Maierial Used To FHI Well/Drillhole

V?" cUlfpc-) la -^-Vc

From (Ft)

Surfata:

To (Ft).

T or Vohmic ""•=)

1

Mix Ratio or Mud Weight

(6) Comments:

(7) Name of Person or Firm Domg Scaling Woric Dale ot Abandonment FOR DNK OR COUT TY USE ONLY

Signature of Person Doing Woii: DaieSignca , I / / IS

j Date Reixived Noted Bv

Sfiieet or Route Tcicprione Ntimbcr I Comments

C:ty, Slate. Zio Code

StJia of Wisconsin aouiC IS: soua waste U M«. W u t r U Wastewater U DcpsnmcntofN»nffalR«ouro:s Env. ResDsnsc i Rcoair D UndcrOTund TsrJa • O&a D

MO.NTTORING V,-ELL CON'STRuJ Form 4400-n3A Rc^B

^ ^ • ^ , . . ^ / t ^ ^ g ^ - ^ / ^ S C j 7^l l r> ' ljc=nsc Pcnrai or Momtormg N u m t w

'ype oi WcU Water Table Observanon W e U a 4 1 T / " a n Pjezometg

T>isu:«e WcJJ is rtnm Wasie/Soince Boundaiy

f t is Well A Point oi Eniorccmaii Sid. Appiication?

n Ya n hb

Grid Origin Locidon

St Plane .

DE. DJiL

fWcilKOTK

W'li. UnwueW

, Long,

ft. .N. .ft-E. Secaon Ltjcationof Waste/Sotn-ci

îiJ.1/4 of | ife"l/4 of Sec. _C.,T. •?(? N. R. 2fC

Locauon of Weil Reifidvc to Waste/Source u D Upgradient s D Sidegradiait

d D Downgradient n D Not Known

tli Number::;;. cUN

Dale-WeU imiAUed . , _ " — — ^

m in a d Y V ^ 1 Wellinsumcd ijy: (i^cBon's Wamt: and P M

A. Protective pipe, top elevation ft M S L "

B. Well tasing, lop elevziion ft- M ^ L -

C Ijmd sinface elevation . _ ft M S L

D. Surface seal bonom f t MSL or .rtTTtT f t

IZ u s e s dassiiication of soil near screen:

GP a G M D G C D G W D S W S C SP n . S M D s e n M L D M H D CL-^D CH D

B e a r a t D . 13. Sieve analysis anachsd? • Yes ' S j f a

14. Drilling method used; Rotary • 5 0 HoUow Stem Auger S 0 1

Otha - ' a l i

15. Drilling Quid used: Wan- 0 0 2 Air D 0 1 Drilling Mud • o 3 Nane~;;0c2 9

16. Diiliing additives used? D Yes J ^ 5 t .

Deso i te .

17. Source of water (attach analysis):

L. Boreiolt, diameter ^ 0

M. O.D. well casing J L ' . h ' l . in.

N. LD. weD casing _ ' L . t ^ in.

E Bentonite seal, top ft- MSL or (l Jz. f u

F. Fine sand, top ft MSL or Z O ^'-N

G. Filter pack, top ft MSL or { J^. ^^v

H. Screen joint top fl. MSL or f . i ) f t .

L Wcllbonom ft MSL o r _ j j g ' . D i t ^

J. FDicT pick, bonom ft. MSL or _ _/ f'. f ft-

K. Borehole, boaom ft MSL or _ 1 f . ^ f t .

- 1 . Cap and lock?

J l . Protective cover pipe:

a. Inside diameter:

b. Lengih:

c Material:

I Sled 'a: ; Qteln

d. Aciditional proieciion?

If yes, describe; n Yes KL' I

'S.Suri&cesffzl: BenioiuLT

Concrete

Ote D n

4 . Matnial between well caiing and piDiccrivc pipe: ^

B e n i D m t e i ^ ^ J

Annular space s e a J ^ n ^ P

Otha-^ i - , . . ^ ( ) a. Gnmuiar Bcnionile'^,E^ H

Lbs/gal mud weigh t . . . Bentonite-sand shmy D fl

' 5 . Anmalai space seal:

b c Lbs/gal mud weight Bentonite sluny • d . . z: % Benionite Bcntonite-cemcm grout D

e. [^ - -^ Ft volimic added for any of the above

£ How installed: Treme •

Trnnie ptimpKi D 0

Gravity ' 'Qc

6. Bentonite seal: a. Bentonite granul: I b. n i / 4 i i i . n 3 / 8 in. D 1/2 in. BcntDnitepellets'D 3

c • - ^ ' Othr D m p . Fine sand material: Manufacmrer, product name k. mesh s i z H

b. Voiume'ifeided O- S ' ftS

8. rilterpack material: Manufacturer, nroduci name and mesh

b. Volumi 9. Well casing:

^ Hush threaded PVC schedule 4Q..-^S_ 21

Flush threaded PVC schedule 80 D 21

Oths- D -10. Screen material: f"^C 6 ^ . ' ^ O

•a. Screen-tj'p;: Factory cut

Continuous slot' Q Q

. Oihe D i b . Manufacmrer

c Sbl sixe:

d Sloned length:

11. BacJdiD material (below filler pack): Othr n

.ierebv ceniiv ihal Ihe iniorrr.aiion on this iorm is true antj correci lo ihe best of my knowletjoe.

I I

I I I

Nar=;:sd 1

:3ignarurs_^-'

i^rz ^ ^ j 4 ^ ^ ^ ^ ± 2 ^ / _ ^ 0^-=^ /rri. '- ' ^ C ^ Please complete both sides ot this iorm and reaim to the sppropnaie DHX. oiiicc k'iied at the top ol^lhis lorm as required tjy chs. 144, 14? and It^lfWis^ Stztij and ch. NR'l41. Wis. Ad. Code. In accordance with ch.l'W, W'is Stats., failure lo Hie this form may result in i t'orfcimre of not less than SIO, nor more than S5000 for eschday of violadon. In accordance whh ch. 147, Wis. Stau.. I'tilure lo Tile this form may result in a foncinirc of not more than SIO.OOO for each day of vioiauon. NOTE: Shaded areas are for DNR use only. See instructions for more informaiion inciuding where the compleied form should be seni.

s t a t e 01 Wisconsin

D e p a r t m e n t of Natu ra l Resources

Houte lo: D Solid Waste

D Emergency Response

D Wastewater

D S u p e r t u n d

D H a z . Waste

D Underground Tanks

D Water Resources

• D Other:

SOIL BORING LOG INFORMATK Form 4400-122 Rev. 5-

Page I c

iFecDIty/ProjetrtKame •PSC-MSP/Marinette, H I

License/Permlt/Monltorlng Number Boring Numt>er Mi^-301

Bortng Drilled By (Firm name and naitis Hisconsin Test Drilling Eric Schoenberg

of crew chief) Date Drilllns S ta r ted 3 / 3 0 / 9 4

Date OrllllnQ Conipieted 3 /30 /94

Drilling Method l-iollow stem Auger

DNR Faci l i ty Well No. MI Unique Mel! No. Common Well Name MW-301

Final S ta t i c Water Level Feet MSL

SurfBi:e Elevation 5B7.07 Fest MSL

Borehole Dlametsr 6 inches

Boring Location Sta te Plane SH 1/4 of NE 1/4 of Section 6, T30N. R24E

Lat Long

Local Grid Location (If applicable) 5459 feet E l W 1342 feet E I £

a s atf County Marinette

DNR County Code 38

Civil Town/City/ or Village Ci ty of Marinette

Sample

m a tt) a

Soil/Rock Descript ion

And Geologic Origin For Each Major Unit CO

CJ cn CD CT

i - O CD _ 1

a

a

Soli Properties

a ^ E «; o — o cn

CO —

o S D o D

Cl c:

— 2

— 4

fîbin anrt STI T- ToDsoil, Drown to black fine sands, silts, and gravels.

SjANO^Dark t)rown to brown, loose, fine, poorly gradea sands - look like beach sands - little odor. Mosit to wet at 6 lee t .

r SE. ML

SP Hit concrete or weathered bearoc:k between B and 9 feet.

— 10

MW-301-13

5/5 5/8

MW-301-15

4/3 Stop

-12

•14

-16

169

Hit concrete or bearack at 15 feet Daring at IS feet.

227

— 18

—20

— 22

I h e r e o y cer t i iy that the information on this form is t rue and correct to the oest of my knowledge.

Locate 3 feet from MW-301A. Drilled blind to i; feet where spoon samples were collected. Log, based boring MW-301A.

•qnaturs

/ Z - t ^ / 2 . - J -

g ^ : ^ ^ ^ Natrual Resource Technology

This form is authonzed by Chapters 144.147 and 1B2, Wis. Stats. Completion of this rsDort is manaatory. Penalties; Forfeit not less than £10 nor more than SS.OOO for each violation. Fined not less than SIO or more than S100 or imprisoned not less than 30 days, or both t o r each violation. Each day of ctjni inued violat ion is a separate offense, pursuant to ss 144.99 and 162.06, Wis. Stats.

Stale ofWisconsin Depamncnc of Nannal Resources

WELLyORILLHOLE/BOREHOLE ABANDONMETsrr Form 3300-5 272000 Page 1 of 2

Niitice: Please complete Form J30O-5and return it lotheappropiate DNB. oSicE and bureau. Completion of this report is required by chs. 160,281.233,289, 191. 292, 293, 295. and 299.Wis. Stats..3nd cii. NUl41. Wis! .4dm. Code, in accordance wiiit chs. 281, 289. 291, 292, 293. 295. and 299, Wis.Stats., failure to file this form may result in a forteiture of between 510 andS25,000, or imprisonment for up to one year, depending on theprogram and conduct involved. Personally identifiable information on this form is not intended to be used forany other purpose. NOTE: See the instructions for more informauon.

Romero: d j Drinking "Water CjWatersietl/Wssiewater O WastB Managemciii D Remctiiatinn/Redeveiaomgnt DOih i r

(I) GENERAL INFORMATION (2) F A a U T Y / O W N E R UNFORJVlATiON

Wl Unique Weil No. DNRWelUDNo. County . ¥ V c

Facility Naine

Common Well Name p - ^ o l

Sv^' 1/4 of j ^ IMofScs. ^ ; T: 1 ° N;R. "^H Grid Location

Gov't Lt:! fif aippiicabic^ H E

.ft D N - Ds.. , ft • R • -w. Local Grid OriainQ ( estimated: Q ) or Weil Location Q

9 1 I I » I n

Lat : Long . or S O N

StPlane ft N. ft. E. D D D Zone

n aciiily l u License/ P ermit/fvioniioring iN o.

Street Address of Weil

City, Village, or Town r ^ <^v:/^cVV<L-

P eseIU: Well Owner Original Owner

Street Address jor Route of Owner 7 ( 0 0 \ / - K ^ K r ^ i jyv-ccV, ^ p . 0 . 0 . 0 / . ^ ^ 0 0 " ^

Reason For Aijandomncnc WlUmmieWenNo.

of Reniacement Well

City, State,Zip Code V/vJ ^ M ^ O ^

(3) WELL/DRILLHOLE/BOREHOLE INFORMATION 1(4) P U M P , LINER. SCREEN, CASING, & SEAUNG MATERIAL

If a Well Construction Report is available, please attacii.

Original Construction Date - f / P ' a / I ' 4

iKj Monianjag WeU

n Water Well

• Borehole / Drillhole

Consnuiaion. Type:

^ Drilled • Dnvea (Sandpoint) D ^ ^

• Other (Specify) '

Pump (tPrping Removed? Liner(s) Removed? Screen Removed? Casing Left in.Place?

• Yes • No • Not Applitable

• Yes • Ko • Not Applicable • Yes • No • Kot Applicable 12 Yes n - N o

Parmaiion Type:

I I UnctJnsolidaied FonnatitJii S Bedrtick

Total Well Depth ( f t . ) _ i i £ : £ _ _ Casing Diameter fm.) 'X.O^'T^'^ (From gnatmdsurfatis) Casing. Dtrpth (ft.) HQ-O

Lower DrilHiolc Diameter (in.)

Was WeU Ammlar Space Granted? • Yes 0 No • Unknown

IfYes, To What Depth? Feet

Depth to Water (Feet) '

Was Casing Cat Off Bciow Surface? g ] Yes • No

Did Scaling Material Rise to Surface? 0 Yes [ ] No

Did Material Settle After 24 Hotrts? • Yes ^ No

If Yes, Was Hole Retopped? Q Y e s Q No

Required Method of Placing Scaling Matcnai

1^ Condntsor Pipe-Gravity Q Ctmductor Pipe-Pmnped n Screened &. Poured Q Other (Explain)

(Bentonite Chips) Scaling Materials n Neat Cement Grout I I Sand-Ccmcal (Concrete) Grout I 1 Concrete • aay-Sand Slurry (11 IbJgal. -vrt.)

• Bentonite-Sand Slurry " "

r~l Bentonite Chips

Formonittsring wells and monitoring well borchoies cmly

Ixj Bentonite Chips


I I Bentonite - Cement Groui

M Bentonite - Sand Slurry'

(5) Maierial Used To FHT Well/Drillhole

Vf-" ck-YpJ i,_v.-,-.u

Frtmi (Ft.)

Surface

To (FL).

Ho ^ ^ ' ^ '

3

Mix Ratio or Mud Weight

(6) Comments:

(7) Name of Person or Firm Domg Scaling WorK

tw '^^ ' ' ' ^ -»J^»;5^ ; ' 5 w i _ .

Date of Abandonment

Sigpannp of Person Doing Woti: DareSignca ' / / X , / X o o H

gircet or Route Telephone Number

Ciry, Slate. Zip Coac ^ ? A 15 T X.

i FOR DNR OR CDUiNTi' USE ONLY \ Date Received Noted By

ConmientK

^ ^ l i ^ m t ^ N ^ i u n d Rcsourees ^ ^ Restxinse & Retair D UndenjT".rvJ Tir,to D Otto D ^"^^ — - ' II I A _ ^ T' _ T " ' " M V " 11

Form 4400-1 IS.-k v-U.'t STRUCT

Rev.;

r .ahty/r to^J

rialJty Lc=n5C I'crnut or Momtormg .'ûmtw Gild Origin Locsbon

MI.

i'cil Wntc-Table Obsen-shon WcH D 11

Pieiomeier " " SQ^ Disifflte Well is rrom Wasie/Soun^ Boundary

ft is Weil A Point oi Hnioitwnaii Sid. Applicauon!

DYes Dhfa

Local Gnd Lociucm o( ^''cil ,, DN. ft.

DE.

nw

Well Name

5 ' Pl-ne

Long,

ft. .' ,

Section Location of WasiA'Source

gVl/4 of /S)fl/4 of Sec. ^ , T . J D N . R.!:!.! Location of Well Relaave to Waste/Source u n UpgrDdiail d • Eb-ft-ngradient

5 D Sidegradiait n D Not Known

?'Z:0.\

Date Weil Installed ^ ,,. ^ ^ ^ ~

m in Q d v v' Well installed By: (Pciron's iâm: md Pu^

uj)~rjN CJ

A. Protecdve pipe, top eievauon

B. Wen casing, top elevalion

C. Land surface ele -adon

D. Surface seal boaom

fLMSL

ft. MSL

ft. MSL.

fLMSL or _ ^ . 0 ft.

12. u s e s ciassklcation of soil near screen:

GP n GMD G C D G W D SW • SP • S M D s e n M L D M H D C L D C H n Be!iT5*>eri

13. Sieve analysis anached? • Yes "'^;>3'T^

14. Drjlliiig —cthod used: K o i s ^ ^ ^ S : ; ^ Hollow Stem Auger D 4 1

Other n i ^

15. Diilliiig fluid iised: Wai=- D 0 2 Drilling Mud • o 3

16. Drilling ac5dirives used? D Yes

None 0 9 9

Describe.

17. Source of water (attach ar.ajysis):


F. Fine sand, top

G. Filter pack, top

H. Screen joint, top

L Wen bonom

J. Filler pack, boaom

. K. Borehoie, bononi

L Borehole, diameter

M. O.D. well casing

N. l.D. well casing _ Z . d h

__ ft. MSL or _ ^ : ? - . ^ ft.

_ ft. MSLor__J2.X> "•

__ f L M S L o r _ 3 j . ^ fL.

._ fi.}ASLar _ S ^ _ d ft.

__ fi..MSLoT_Jf^j^ fl.

._ fL MSL or _ J ^ . / ) ft-

. _ f L M S L o r _ i / i . O ft.

.1 .l<

1. Cap and lock? • 2. Protective cover pipe:

a. Inside diameter: b. Length: . c Material:

^>Q:Y= Yes D >

d. Additional protection? If yes, describe:

if-Q

SleelJQ—J

a Yes n N

3 . Surface seal; BemoiiiLt-^Sl. :

Cono-ete D C

Otic- n ;: 4 . Maierial betweai well casing and protective pipe:

BmionitE^j;^ 3

-Aimuiar space jcal D

othe- n 5. Annular space seal: a. Grsnulzr Bentonite D 3

_Lbs/gal mud weight . . . Bcruonite-sand shrry D 3 _Lbs/gal mud weigh: Bentonite siuny ! HC 3 , To Bentonite Bentoniie-cemeni grout D 5

:^ Ft ^ voiume added for any of ihe aixive How installed: Tremie Q 0

Trnnie pumpad ' ^ ^ g GraMty Q g

6. Bentonite seal: ' a. B enLonite granules • 3

b. D1/4 in. I23/8 in. D 1/2 in. B enionitc pclleis>3 3

c — : othe- n m .7. Fine sand material: Manufacturer, product name & mesh size

X b. Volume ^ e d .

8. Filter pact: maifjiai: Manufacmrer... .n-'

b. Volume

9. Well casing:

• pacKmaiinaJ: Manufacnirer^nroductnai

Dlume a d S i < ft-^

iuct name and mesh si

Rush threaded PVC schedule 40 W 2 :

Flush threaded PVC sciiedule SCro" 2 :

oibe- n ?••;'*

10. Screen material: a. Screen t)pe:

T'I/C S . - l ^ ur) FactDiy cut 5 [ 11

Continuous s l o t ' n o j

Other D Pv

b. Manufacmrer _ c Slot siie; d Sloned length:

• . \ r ^ ^ t^^ S.?--

oo/Qi^

11. Bacidill material (below iiltcTpaci:): N O T T ^ '

oths-' d

. I - Q n 1 4

•reby ceniiv Ihat the iniormaiion on this form is true and correcl 10 the best of mv knowledoe.

^ g a / ^ ychs. 144, 14/ «finrreQ/Wi:.: laicise complete oolh sides or ihu form and return to the ippropnaie DNK olfic: iL<;u at the top 01 this lonn as requircB-t?y chs. IM, 14/ «finn^7Wi:. Suas.,

andch. N R ' M I . Wis Ad Code. In accordance with ch.l44. Wis Stats., failure to file this form may result in 1 fon'eimrt of not less than SJfif noi more than 15000 for each day of vioiarion. In accordance with ch. !47, Wis. Stau,. I'ailurc 10 ul!: this form may result in a forfcinire of not more than SICOOO for c*:h day of violation. NOTE: Shaded areas are for DNR use only. See insmjctions for more infotmaiion including where the completed form-should be sent. .

s ta te of Wisconsir Route To: SOIL BORING LOG INFORMATlM Department of Natural Resources • S o l i d Waste DHaz. Waste Form 4400-122

D Emergency Response D Underground Tanks D Wastewater D Water Resources D Stjperfund D Other:

'acl l l ty/ProJect Name ,PSC-HlpP/Marinette. MI

BorIno Drll lsd By (Firm name and name of crew chief)

Hisconsin Test Drilling

Eric Schoenberg

DNR Faclf l ty HeB No, Wl Unique Well No, Common Well Name P-301

Boring Locat ion

State Plane

Ucsnse/Permlt /Monitar lng Number

Date DrllUna S t a r t e d 4/4/94

F l n ^ Stat ic Water Level Feet MSL

Lat Lono "

SH 1/4 o f NE 1/4 o f Section 6. T30N, R24E 1 "

County Marinette

Sample

,_ D. Q) > .

n 1—

•^ CD

— -o

OJ OJ

_ j a :

•<*-

= 3

o o o

CD •

. 0)

£ "Q.

OJ

D

_

^ 1 — — — 4 — _

^ 6

—

1 1

1 1

1 1

1 II

1 1

1 F3

o

°=

-—

t-!4 L

— IR

^ 1 8

~ 2 2

DNR County Code 38

Soil/Rock Description And Geologic Origin For

Each Major Unit

RANH Rnct STl T: ToD.'jnll. brown to tilacl< 11ns "\ sands, silts, ana gravels. / "

SAiiDlOark Brown to brown, loose, fine, well graded sands - look like beach sands - little odor. MosIt to wet at 6 feet.

Hit weathered bedrock at approximately 12 feet. Have layers of weathered bedrock and sediments.

nni OMTTP- Have coranatent bedrock at IB feet. Doloirlte, hard, grey, dense. Water yreldeo throughout arming but amount decreases with depth.

. cn CJ cn

5£. ML

SP

DLM

DLM

Boring Number P-301


4/sm

Surface Hevat ion 587.17 Fee t MSL

Drilling Method

Rev. 5 - ~

• j

Page 1 o |

• 1

Mud/Air Rotary ^

Borehoie Diameter | 6 inches

Local Grid Locat ion (If applicable) 5452 feet Ei N 1326 feet S E

D s Dy^ Civil Town/Ci ty / or vniage City of Marinette

o

• •

* _ •

, • . •

• •

• : •

;

T ^

/

7 "

/

/

/ / /

/ / • /

/ / /

/ / )

/ / /

/ -/ 1

1 / /

E m

_ CT

3 a

1 ^ f S $ % • ^

1 %

1 ^ ^ ?$ 1 !8

1 1 ^

s

'

s

!

a u, o SI

\ -

I i

I 3 R

E

\

\

I '

•

X

i <

! .

<

X

>

Soil Properties

>. S £

£2. C

O —

o cn

•

(U — .

3 £ o o S CJ — 1 — J l a

c=> o C\J

c

• • 1 ••

1 C3 D ^ OZ CJ

• 1

Drilled to 23 feet with mud.B Only • water w a ^ used directly _ from theH City of H Marinette water systsm M • bentonl t™ Due to the _

. IncredlbiS hardness^ of the aoiomite switched • to air • rotory W drilling below 23 faet. I

1 • • • ^ • • •

I herepy certify tiiat ttie information on this form is true and correct to.the oest of my knowleoge.

•nature ^ ^ - y j / C ^ ^ ^ Natrual Resource Technology •

This form is authorized by Chapters 144.147 and 162, Wis. Stats. Completion of this report is mandatory. Penalties: Forfeit not less than £10 nor more than $5,000 for each violation. Fined not less than SIO or more than $100 or imprisoned not less than 30 days, or Doth for each violation. Each day of continued violation is a separate offense, pursuant to ss 144.99 and 162.06, Wis. Stats.

• 1 1

Number and Type

Lengih A l l . G Recovered (In)

Blow Counts

1 I I I I l~IT| I I I I I I I I [ I I I I I I I I I I I I I I I I I I I I I I I I I I I i I I I I I I I I I I I I I I I I I I I I I I I i I I I I I I I I I I I I I I i i I I I I I I I I I i I I cn ro O

Ol 00

cn CD

a i en t \ j

Ol O 133 cn ro o

OJ CD CD

CJJ CO ro

CO o

ro CD

ro CD

Depth in Feet

Q. 9

- • " • S '

ill l 5

o =>

uses

Graphic Log

\;:^f:•:.i•^.;V;:X.:V:r^^'cf:•<i:::•!^^;i•;;^^.;^•rî;• r i j : - : - : - ; ^ Well Diagram

PID/FID

Compressive

Strength

Moisture

Contenl

Liquid

Limit

Plasllcl ly Index

P 200

RQD/ Commeiils

Sta te o f W i s c o n s i n

D e p a r t m e n t o fNa tu ra l Resources

W E L L / D R I L L H O L E / B O R E H O L E A B A N D O N M E N T Form 3300-5 2 / 2 0 0 0 Page 1 of 2

Notice: Please complete Form 3300-5 and return it to the appropriate DNR office and bureau. Completion of this report is required by chs. 160. 281, 283. 289, 291, 292 .293. 295, and 299, Wis. Stats., and ch. NR 141, Wis. Adm. Code. In accordance with chs. 281. 289, 291, 292, 293, 295, and 299, Wis. Stats., failure to Hie this form may result in a forfeiture of berween $10 and $25,000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable information on this form is not intended to be used for any other purpose. NOTE; See the instructions for more information.

Route loj I Drinking Water I I Watershed/Wastewater I i Waste Management L J Remediation/RedevelopmentI I Other

( n G E N E R A L I N F O R M A T I O N (2) F A C I L I T Y / O W N E R I N F O R M A T I O N Wl Unique Well No. DNR Well ID No. County

Marinet te

Facility Name

Former Marinet te M G P Site (1549)

Common Well Name M W - 3 0 7

. 1/4 of Sec. _ 1/4 of Grid Location

;T.

.ft. a N. D s..


_ N ; R . ^ n ' ^ • W ft. n E. n w.

Facility ID

238000047

License/Permil/Monitoring No.


Mann St. Mar ine t te . Wl

Local Grid Origin IAI (estimated: I I ) or Well Location I I

O I n O t M

Lat Long or

City, Village, or Town

Marinette Present Well Owner

Shirley Scharff

State Plane. . ft. N.

S C N

. ft. E. D D D Zone Street Address or Route of Owner

400 N. A d a m s St. PO Box 19002

Original Owner

Wiscons in Public Service Corporation

Reason For Abandonment

well d a m a g e d and replaced

Wl Unique Well No.

of Replacement Well

City, State. Zip Code

Green Bay. W l 54307

(3) W E L L / D R I L L H O L E / B O R E H O L E I N F O R M A T I O N (4) P U M P , L I N E R . S C R E E N . C A S I N G , & S E A L I N G M A T E R I A L


K l Monitoring Well

[ D Water Well

n Drillhole/Borehole

Construction Type:

1 3 Drilled

D Other (Specify)

Formation Type:

6/12/1996

If a Well Construction Report is available, please attach.

Pump & Piping Removed?

Liner(s) Removed?

Screen Removed?

Casine Left in Place?

n Yes d l No K Nol Applicable

D Yes • No K Not Applicable

K Yes CH No n Not Applicable

D Yes • No


Was Casing Cut Off Below Surface?

Did Sealing Maierial Rise to Surface?

Did Matenal Settle After 24 Hours?

IfYes, Was Hole Retopped?

n Yes m K Yes D D Yes K D Yes K l

No

No

No

No

12SI Unconsolidated Formation

Total Well Depth rfi) 12.5

6.0

(From groimd surface)

Lower Drillhole Diameter (in.)

Was Well Annular Space Grouted? CD Yes

IfYes, To What Depth?

Depth to Water (Feet).

CH Bedrock

Casing Diameter ( in . ) .

Casing Depth (ft.)

2.00

Required Method of Placing Sealing Material

l2Sl Conductor Pipe - Gravity I I Conductor Pipe - Pumped

I I Screened & Poured I I Other (Explain)

(Bentoniie Chips)

12.5

No I I Unknown

Feet

5.4

Sealing Materials

I I Neat Cement Grout

I I Sand-Cement (Concrete) Groui

I I Concrete

I I Clay-Sand Slurry

I I Bentonite-Sand Slurry

1 ^ Chipped Bentonite

For monitoring wells and

monitoring well boreholes only

I I Bentonite Chips


I I Bentonite-Cement Groui

L J Bentonite - Sand Slurry

(5) Sealing Material Used From (Ft.) To (Ft.; Mix Ratio or Mud Weigh!

3/8" Ch ipped benionite Surface 14.0

(6) Comments Overdri l led to 14', backfilled with bentoni te

(7) Name of Person or Firm Doing Sealing Work

Natura l Resource Technology. Inc. Signature of Person Doin ing Work

SUA Street o t ^ o u i e f

23713 W. Paul Rd, Ste. D

' JMJA--mic

Date of Abandonment

10/7/08 Date Signed

Telephone Number

262 .523 .9000 City. State, Zip Code

P e w a u k e e . Wl 53072

FOR DNR OR COUNTY USE ONLY

Date Received Noted By

Comments

E t a t e o f Wiscons in

D e p a r t m e n t o f N a t u r a l R e s o u r c e s

I Route To:

D Solid Waste

D Emergency Response

D Wastewater

D Super fund

D Haz. Waste

n Underground Tanks

D Water Resources

D Other:

I

SOIL BORING LOG INFORMATION Form 4 4 0 0 - 1 2 2 R e v . 5 - 9 2

Page i of i

FacffltyyProiect Name NPSC-MGP/Marinet te, Wl

Ucense/Pennlt/Honltoring Number Borlng MuBber

MH-307

Bor ing Dril led By (Firm name and name of crew chief)

Wisconsin Test Drill ing

Dan Z ie lszowsid

Date Drilling 6/12/96

Sta r ted D a t e Drilling Completed

6 /12 /96 Orllllna Method Hollow Stem A u g e r

DNR Fac i l i t y Well No. HI Unique Well No. CoRiBon Mell Name M H - 3 D 7

Final S ta t i c Hater Level

Feet MSL

S u r f a c e Beva t ion

F e e t MSL Borehoie Diameter 6 inches

Bor ing L i jca t lon

S t a t e Plane

SW 1/4 of NE 1/4 o f Sect ion 6. T30N, R24E

F e e t N

F e e t E Lat Long

Loca l Srid Locat ion (I f applicable)

UN D E U s Un

Coun ty

Mar ine t te

DNR County Code 3B

Civil T o w n / a t y / or VDlage

City o f Mar ine t te

Sample

0) Q. >,

t—

-o fO

MW-3 0 7 - 3

" 5

MW-307-6

MW-3 0 7 - 8

MW-307-10

MW-307-12

24

o 2

6 /4 I3/ ia

14/11 11/13

4/1 I/I — a

IB

4/2 3/7

5/6 9/8

Q. 0)

— 10

— 12

1—14

-16

— 18

— 20

— 22

Soi l /Rock Desc r ip t i on


Each Major Unit

B" o< Aasphait underlain oy 1.5 tes t large gravel 1111.

FTLL-SANO/GRAVFL: Park Drown, f - c , loose sanas, crs. gravel, red brick, dry to moist.

/ "

SAND: Dark Drown to tJlat:k, f - c , loose well graded sanas, trc. silt with slight odor (not tar odor though).

SAHIXLSILI l Dark red crown, silt w/ f. sands S organic material.

SANHY ni AY- Red Drown to red gray clay till w/ f - c sand, sticky, plastic - hit bedrock at 13 feet.

Hii bearactc at 13 feet - e n a boring at 13 leet.

cn cn 3

10 _ 5i QJ J 5 3: a

Asoh.

SE. GP

SW

(dL SM

CL SC

• - O - i

Soil Properties

c! c

o — o cn

J2 c o o z a

3.8

4.1

Q.8

o o

a o cc o

I he rePy ce r t i f y tha t the information qn this form is t rue and correct to the best of my knowledge.

S igna tu Firm Natural Resource Technology

This form is author ized by Chapters 144.147 and 162, Wis. S ta ts . Completion of this reoort is mandatory . Penalties: Forfei t not less

t h a n SIQ nor more than 35 ,000 for each violation. F ined not less than SIO or more than SIQO or imprisoned not less than 30 cays,

or b o t h for each violat ion. Each day of cont inued v io la t ion is a separate of fense, pursuant to ss 144.99 and 162.06, Wis. Stats.

Stale ofWisconsin Depanment ofNatural Resources

Route To:

SOIL BORING LOG INFORMATION Form 4400-122

Watershed/Wastewater CD

Remediaiion/Redevelopmeni I

Waste Management D

Other D

Rev. 7-98

of 2 Facility/Project Name

Former Marinette MGP Site (1549) License/Permit/Monitonng Number Boring Number

MW-307R Boring Drilled By: Name of crew chief (first, last) and Firm

Paul Boart Longvear


10/7/2004

Date Drilling Compleied

10/7/2004

Drilling Method

hollow Stem auger


MW-307R Final Static Water Level

579.1 Feet MSL Surface Elevation


8.3 inches Local Grid Ongin

State Plane

1/4 of

(estimated: • ) or Boring Location Q]

N , E S / C / N

1/4 of Section , T N. R

Lat .

Long .

Local Grid Location

lEI N lEl E 48820.08 Feel D S 805551 Feet D W

Facility ID

238000047 Counly



Marinette

Sample

••h- CJ) o ^ o (o to

_1 Di

o u _o ED

- 3

—4

- 7

- 1 0

- 1 1

- 1 2



Each Major Unit

0'-14' Blind drill-lithology taken from log of MW-307. See soil boring log for MW-307 for complete description.

cn U cn

O J

SW

SW

ML

CL

Q c- U cn

Soil Properties

u S- E '3 '3

o

c_ .E O- o

1 hereby certify that the infonnation on this form is true and correct to the besl of my knowledge.

Signature

/.--^>- /3Ue^^ Finn Natural Resource Technology, Inc. 23713 W. Paul Road. Unit D Pewaukee, Wl 53072

Tel: (262) 523-9000 Fax: (262)523-9001

T'' Templaie: WDNR SBL I99K - Frqjeci: 1549GINT.GPJ(_ This form is authorized by Chapters 281. 283. 289. 291. 292, 293. 295. and 299. Wis. Slats. Completion of this form is mandatory. Failure to file this form maN result in forfeiture of between $10 and $25,000, or imprisonment for up lo one year, depending on the program and conduct involved. Personally identifiable information on ihis form is nol intended to be be used for any other purpose. NOTE: See instruciions for more infonnation. including where the compleied fo should be sent.

Slate ofWisconsin Depanment ofNatural Resources

SOIL BORING LOG INFORMATION SUPPLEMENT Fonn 4400-122A

Bonng Number IVTW-SOTR Use only as an attachment to Form 4400-122. Page 2 of

Sample

' ^ < 2

U

CD



Each Major Unit cn U cn

CL ra DO •- o 5 Q

D

0) -3

(J on

Soil Properties

a u

- 1 3

•14

CL

^ @ 14'refusal-bedrock END OF BORING (a! 14'


Route To: Watershed/Wastewater D Remediation/Redevelopment I

Waste Management CD Other D

IMONITORING WELL CONSTRUCTION Fonn 4400-113A Rev. 7-98

Facility/Project Name

Fonner Marinette MGP Site (1549)


148820.08 ft ^ ^ ' - 805551 , ISE. -fi- D W .

Well Name

MW-307R Facility License, Permit or Moniloring No. Local Grid Origin

Lat. 1

(estimated: Q ) or

Long.

Well Location D

or

Wis. Unique Well No. DNR Well Number

Faciliiv ID St. Plane ft. N, ft. E. S / C / N 238000047 Section Location of Waste/Source

Date Well Installed

10/07/2004 Type of Well

Well Code I 1/mw .1/4 of. 1/4 of Sec. . T.. .N.R.

D E . D W

Distance from Waste/ Source

ft.

Enf. Slds. Apply

Location of Well Relative to Waste/Source u n Upgradient s D Sidegradient

d D Downgradient n D Not Known

Gov. Lot Number


Paul

Boart Lonavear

A. Protective pipe, top elevation

B. Well casing, top elevalion

C. Land surface elevation

585.07 fl. MSL

584.70 f,. MSL

D. Surface seal, bottom

585.1 ft. MSL

584.1 fl. MSL or '-0 ft.

12.

13.

14

15

16

17

u s e s classification of soil near screen: GP D GMD GCD GWD SWB SP D SMD SC D MLK MHD CLE! CH D Bedrock D

Sieve analysis attached? D Yes B No

Drilling method used: Rotary 0 5 0 Hollow Stem Auger H 4 1

Other n

Drilling fiuid used: Water D 0 2 Air D 0 1 Drilling Mud D 0 3 None 13 9 9

Drilling additives used? D Yes H No

Describe Source of water (attach analysis, if required):

n/a


F. Fine sand, top

G. Filter pack, top


I. Well bottom

J. Filler pack, bottom

K. Borehole, bottom

L. Borehole, diameter

M. O.D. well casing

N. l.D. well casing

fl. MSL or

582.1 ft. MSL or M .

581-6 fl. MSL or 3.5 ft

581.1 ft MSl.nr 10_ ft.

57L1 fl. MSL or '4.0 ft

57L1 ft. MSL or '4.0 ft

571.1 fl. MSL or '4.0 fl

8.3

2.33

1. Cap and lock?

2. Protective cover pipe:

a. Inside diameter:

b. Length:

c. Maierial:

Yes D No

;.o

d. Additional protection?

If yes, describe:

Steel D

Other S

D Yes B

3. Surface seal: Bentoniie D

Concrete B

_ Other D

in .

L ft.

04

No

30

0 1

4. Material between well casing and protective pipe:

Bentonite D

52nd Other IS

5. Annular space seal: a. Granular/Chipped Bentonite B


c Lbs/gal mud weight . . . Benionite slurry D

d % Bentonite . . . Bentonite-cement grout D

e Fr volume added forany of the above

How installed: Tremie D

Tremie pumped D

Gravity K

6. Bentonite seal: a. Bentoniie granules D

b, D 1/4 in. D 3/8 in. D 1/2 in. Benionite chips D

c Other D

7. Fine sand material: Manufacturer, product name & mesh i

a #7 Badger

30

33

35

3 1

50

01

02

08

3 3

32

b. Volume added ft

8. Filter pack maierial: Manufacturer, product name & mesh size

#40 Badger

b. Volume added fl'

9. Well casing: Flush threaded PVC schedule 40 El 2 3


Other D

10. Screen matenal:

a. Screen Type:

PVC

Factory cut E 11


Other D _ _ Boart Longvear b. Manufacturer

c. Slot size:

d. Slotted length:


2.07

0.010 ,n

'O-O ft.

None D 1 4

Other K _ _

1 hereby certify thai the information on Ihis fomi is true and conect lo the best of my knowledge. Signature

j : ^ ^ ^ ^ , , .

Firm Natural Resource Technology. Inc. 23713 W. Paul Road. Unil D Pewaukee. Wl 53072

Tel: (262)523-9000 Fax: (262)523-9001

Plea.sc cornffleic both Fonns 4400-1 MA and 4400-113B and rerum them to the appropnaie DNR ofike and bureau. Completion of these reports is required by chis. 160. 28] , 283. 2 291,292. 293. 295. and 299. Wis. Stats., and ch. NR 141. Wis. Adm. Code. In accordance with chs. 281. 2S9. 291. 292. 293. 295. and 299. Wis. Slats., failure to file these foniis may resiili in a forfeiture of berween S10 and S25.000. or imprisonment for up to one year, depending: on the program and conduci involved. Personally idcniifiable infonnation on these fon" is not intended to be used foi any other purpose. NOTE. See ihe instruciions for more infomiation. including where the completed foniis should be sent

Stale of Wisconsin Depanment ofNatural Resources

MONITORING WELL DEVELOPMENT Forni 4400-113B Rev. 7-98

Route To: Watershed/WastewaterCH

Remediation/Redevelopment

Waste ManagemenlD

Other D



County Marinette

Well Name

MW-307R Facility License, Permit or Moniloring Number County Code

38

Wis. Unique Well Number DNR Well Number


2. Well development method: surged with bailer and bailed surged with bailer and pumped surged with block and bailed surged with block and pumped surged with block, bailed, and pumped compressed air bailed only pumped only pumped slowly other









Yes D No

D 4 1 D 6 1 D D

42 62

D 70 D 20 D

a D

1 0 5 1 50

66 min.

13.3 ft.

2.07 in.

7.1 gal.

16.0 gal.

0.0 gal.

D Yes D No

11. Depth to Water (from top of well casing)

Date

Time

Before Development After Development

5.88 ft.

10/7/2004

D a.m. 12:55 SI p.m.

8.2 inches

7.59 ft.

10/7/2004

D a.m. 02:01 IS p.m.

12. Sediment in well bottom

13. Water clarity Clear D 10 Clear D 20 Turbid IS 1 5 Turbid K 2 5 (Describe) (Describe)

Dark brown, silty. Light brown, opaque translucent

inches


mg/I mg/1 14. Total suspended solids

15. COD mg/1 mg/1


Jody Barbeau


Pumped dry 7 times during development

Facility Address or Owner/Responsible Party Address

TManie: Shirley Scharff

Firm: Wisconsin Public Service Corporation

Street: 700 N. Adams St. PO Box 19002

Ciiy/Staie/Zip: Green Bay. Wl 54307

I hereby certify that the above information is true and correct to the best of my knowledge.

Signature: /

Pnm Name: Jodv Barbeau

Finn: Natural Resource Technology, Inc.

"NOTE: See iiistnjctions for more infomiation includins a list of countv codes and well tyoe codes.

State ofWisconsin Departmeni of Natural Resources

SOIL BORING LOG INFORMATION Form 4400-122 Rev. 7-98

Route To: Watershed/Wastewater D

Remediation/Redevelopment K

Waste Management CD

Other D

Page of Facility/Project Name

Former Marinette MGP Site (1549) License/Permit/Monitoring Number Boring Number

MW-308 Boring Drilled By: Name of crew chief (first, last) and Firm

Boart Longyear


6/21/2004

Dale Drilling Completed

6/21/2004

Drilling Method

hollow Stem aueer

WI Unique Well No. DNR Well ID No. Common Well Name

MW-308 Final Static Water Level

Feet MSL Surface Elevalion



State Plane

1/4 of

(estimated: CD ) or Boring Location Q

N , E S / C / N

1/4 of Section T N.R

Lat .

Long.

Local Grid Location

IE! N lEI E 48611.73 Feet D S 805727.28 Feel D W

Facility ID

238000047 County



Marinette Sample

1 SS

2

s's

3

ss

4 SS

5 SS

— -a < a

24

24

24 6

24 9

24 16

o U

- 1

-2

-3

-4

-5

-6

-7

-8

1-9

• 1 0

-11

•12

-13



Each Major Unit

0-2' ORGANIC SOIL WITH SAND organic material (roots) trees, old asphalt pieces DL/OF

2' - 6'FILL, 2' - 2.3' old asphalt, gravel, 2.3' - 4' Sand seam, red to yellow, fine (a). 3' - 4' Sand with debris(slag, etc.)

4' to 6' Sand with trace clay, debris(glass, slag, broken brick)piedium. no odor, end of spoon wet

8' - 13' POORLY GRADED SAND gray to brown, wet

8' to 10' one-inch lens of wood debris in middle of spoon

END OF BORING (% 13'

^ 15 D

• . OB

S g O cn

Soil Properties

u a 5 c; u

300 1b hammer

1 hereby certify that the information on this form is true and correct lo the best of my knowledge.

Signature Firm NJatural Resource Technology, Inc. . 23713 W. Paul Road, Unil D Pewaukee. Wl 53072

Tel: (262) 523-9000 Fax: (262)523-9001

^ Template: WDNR SBL 1998 - Projeci: ! ,549G1NT.GPJ This fonn is authorized by Chapters 2S1. 2S3. 289. 291. 292. 293. 295. and 299, Wi.s. Stats. Completion of this form is mandator)'. Failure lo file this form ma resull in forfeiture of between JIO and S25.000, or imprisonment for up lo one year, depending on the program and conduci involved. Personally identifiable information on this fomi is nol inlended to be be used for any other purpose. NOTE: See instructions for more information, including where the completed fo should be seni.

State ofWisconsin Department of Namral Resources R ^ ^ , ^ J ^ . Walershed/Waslewaier D Waste Management D MONITORING W E L L CONSTRUCTION

Remediaiion/Redevelopmeni Kl Other D Forni 4400-113A Rev. 7-98


FonnerMannelte MGP Site (1549) Facility License, Permit or Moniloring No.

Facility ID

238000047 Type of Well

Well Code 11/mw Distance from Wasie/ Source „

Enf. Slds. Apply ^


148611.73 ft ^ ^ - 805727.28 f, S E . D W ,

Local Grid Origin ^ (esiimated: D ) or Well Local

Lai ° ' " long.

St Plane ft N

Section Location of Wasie/Source

1/4 of IMofSer ,T Location of Well Relative to Wasie/Source

u D Upgradient s D Sidegradient

d D Downaradienl n D Not Known

_ ft. E.

N.R. _

ion D

or

S/C/N

D E

nw Gov, Lot Number

Well Name

MW-308 Wis. Unique Well No. DNR Well Number

Dale Well Installed

06/21/2004 Well Installed By: (Person's Name and Firm)

Mike

Boart Longyear


B. Well casing, top elevalion

C. Land surface elevalion

586.94 ft. MSL

586.62 ft, MSL

586.9 ft. MSL

D. Surface seal, bottom 584.4 ft M S L or ^-5 ft.

12

13

14

15

16

17

uses classification of soil

GP D GMD G C D SMD SC D M L D Bedrock D

Sieve analysis attached?

Drilling method used: Holl

Drilling fluid used: Water Drilling Mud

Drilling additives used?

Desrrihe

Source of water (attach ana

near screen:

GWD S W D SP El M H D CL D CH D

D Yes

Rotary ow Stem Auger

Other

DO 2 Air D 0 3 None

D Yes

ysis, if required

D N o

D 5 0 S 4 1

D

D O l

D 9 9

H N o

:

584.4 ft. MSL or L l fl.

583.9 ft. MSL or 1 1 ft.

E. Bentonite seal, top fl. MSL or

F. Fine sand, top ft. MSL or

G. Filter pack, top


1. Well bottom 573.9 ft M S L or '3.0 ft

J. Filter pack, bottom 573.9 f, MSl.nr '3.0 ft

K. Borehole, bottom 573.4 ft M S L or '3.5 ft

L. Borehole, diameter 8 3 . in.

M. O.D. well casing ---^3 jt,.

N. l.D. well casing --Q^ in.

1. Cap and lock?

- 2. Protective cover pipe:

a. Inside diameter:

b. Lengih:

c. Maierial:

Yes D No

;.o

t£f£JlX d. Additional protection?

If yes, describe:

Steel D

Other K

D Yes la

' 3 . Surface seal Bentonite D

Concrete H

_ Other D

in.

0_ ft.

04

No

30

01

' 4. Material between well casing and protective pipe:

Bentonite D Sand Other 12

Annular space seal: a. Granular/Chipped Bentonite SI

Lbs/gal mud weight. . . Bentonite-sand slurry D

Lbs/gal mud weight. . . Bentonite slurry D

% Bentonite . . . Benionile-cement grout D

Ft voiume added for any of the above

How installed: Tremie D

Tremie pumped D

Gravity IS

Bentonite seal: a. Bentoniie granules H

b. D 1/4 in. D 3/8 in. D 1/2 in. Bentoniie chips D

c Other D

, 7. Fine sand maierial: Manufacturer, product name & mesh size

30

3 3

35

3 I

50

01

02

0 8

33

32

a

b. Volume added ft-

8. Filter pack material: Manufacturer, product name & mesh size

a Red Flint

b. Volume added fl'

9, Well casing: Flush threaded PVC schedule 40 Kl 2 3


Other D

• 10. Screen material:

a. Screen Type:

PVC

Factory cut K 11


Other D _ _ Boart Longyear b. Manufacturer _

c. Slot size:

d. Slotted length;

11. Backfill maierial (below filter pack):

0.010 in

'Q-Q ft.

None D 1 4

Other El

1 hereby certify that the information on this fonn is true and conecl lo the besl of my knowledge.

Natural Resource Technology. Inc. 23713 W. Paul Road. Unit D Pewaukee. Wl 53072

Tel: (262)523-9000 Fax: (262)523-9001

S igna tu r e^ . y ' Z ^ Fi rm

Pfease coniplete both Forms 4400-113A and 4400-113B and return them to the appropriate DNR office and bureau. Completion oi these reports is required by chs. 160. 281. 283. 289, 291.292. 293. 295. and 299. Wis. Siais.. and ch. NR 141. Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295, and 299. Wis. Stats., failure to file these fomis may lesulf jn a forfeiture of hcrv\-een .SIO and 525.000. or impri.sonmeni for up lo one year, dcpendinij on ihc proi:ram and conduct involved. Personally ideniifiabic infonnalion on ihese fom) is nol intended to be used for any other purpose. NOTE: See the instructions for more information, ineludinij where the completed forms should be sent.

State ofWisconsin Department ofNatural Resources

MONITORING W E L L DEVELOPMENT Forni 4400-113B Rev. 7-98

Route To: Watershed/WastewaierD Waste ManagemenlD

Remedialion/Redeve Facility/Project Name

Former Marinette MGP Site (1549) Facility License, Permit or Moniloring Number

opmenS Other D Counly


38

Well Name

Wis. Unique Well Number MW-308

DNR Well Number


2. Well development method:

surged with bailer and bailed

surged with bailer and pumped

surged with block and bailed

surged with block and pumped

surged with block, bailed, and pumped

compressed air

bailed only

pumped only

pumped slowly

other







9. Source of water added i^'P^

10. Analysis performed on water added?

(If yes, attach results)

D Yes S No

D D D El D D D D D D

4 i

6 1

4 2

6 2

7 0

2 0

1 0

5 1

5 0

6 0 min.

12.6 ft.

2 .07 in.

gal.

6 5 . 0 gal.

0 .0 gal.

D Yes D No

1 1. Depth to Water (from top of

Before Development After Development

well casing)

Dale b.

Time c.

6.30 ft.

6/22/2004

6.44 ft.

6/22/2004

Kl a.m. l l : 5 4 D p . m .

inches

D a.m. 12:54 Ei p.m.


13. Water claniy Clear D 10 Clear El 2 0 Turbid B 1 5 Turbid D 2 5

(Describe) (Describe)

Dark brown, silt

inches


mg/1 mg/1 14. Total suspended solids

15. COD mg/1 mg/I


Jody Barbeau


Water turned clear after approximately 8 gallons removed.



Finn: Wisconsin Public Service Corporation

Street: 700 "N. Adams St. PO Box 19002

City/Siaie/Zip: Green Bay. W] 54307

1 hereby certify thai the above information is true and correct to the besl of my knowledge.

Signalure: ^ A ^ - ^ ^ ^.w^L^^^ Pnm Name: Jody Barbeau

Finn: Natural Resource Technology, Inc.

NOTE: See instructions for more information includin.s a list of county codes and well type codes.

State ofWisconsin Department ofNatural Resources


Remediation/Redevelopment [

Waste Management D

Other D

SOIL BORING LOG INFORMATION Fonn 4400-122 Rev. 7-98

Page 1 of 1



MW-310 Bonng Drilled By: Name of crew chief (first, last) and Firm

Boart Longyear


6/21/2004

Dale Drilling Completed

6/21/2004

Drilling Method

hollow stem auger



Feet MSL Surface Elevation



Slate Plane

1/4 of

(estimated: • ) or Bonng Location •

N, E S/C/N 1/4 of Section N.R

La t .

Long .

Local Grid Location

Kl N S E 48714.51 Feet D S 805639.53 Feet D W

Facility ID

238000047 County

Marinette Counry Code

38 Civil Town/City/ OT Village

Marinette Sample

=« o

U

24

15 17 17 19

16 16

14 11 10 4

10 1 1 9

6 9 4

9 1 I 11 9

— 1

'—2

' - 3

- 4

5

- 6

- 7

-8

-9

-10

-11

-12

-13

-14



Each Major Unit

0' -8' FILL 0'-0.5' asphalt 0.5' - 6' Poorly graded sand with gravel, brown to black, medium to fine sand, end of spoon moist

(a} 4' Trace silt, scattered debris(slag), moist

6' red brick pieces.slag, possible weathered tar, odor present wet

8'-13' POORLY GRADED SAND gray, medium, trace fine gravel, rounded, water in spoon

13'-14' SILTY LEAN CLAY, tan, hard

END OF BORING O, 14'

Fill

SP

? 5

D u-D

D. P O . U (

Soil Properties

^ i a o C4 u

I hereby certify that the information on this form is true and correcl to the best of my knowledge.

Signature

^ : ^ ^ ^ ^'"^ Natural Resource Technology, Inc.

23713 W. Paul Road, UnitD Pewaukee. Wl 53072 Tel: (262) 523-9000 Fax:(262)523-9001

^ . Template: WDNR SBL 1998 - Prqiect: J549G1NT.GP.I This form is authonzed by Chapters 281. 283, 289. 291, 292,293, 295. and 299, Wis. Stats. Completion of this form is mandatory. Failure to file this form ma> result in forfeiture of between $10 and S25.000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable infomiation on this form is not intended to be be used for any other purpose. NOTE: See instructions for more infomiation. including where the completed fon should be sent.

State ofWisconsin Deparrment of Natural Resources Route To: Watershed/Wastewater D

Remediation/Redevelopment I Waste Management CH Other D

MONITORING WELL CONSTRUCTION Fomi 4400-113A Rev. 7-98


Former Marinette MGP Site (1549)

Local Grid Location of Well , K N . ft- n s . 148714.51 805639.53 ^ S E .

-fl- D W .

Well Name

MW-310 Facility License, Permit or Moniloring No. Local Grid Origin

Lat. 1

(estimated: Q ) o''

Long.

Well Location Q Wis. Unique Well No. DNR Well Number

Facility ID St. Plane ft.N, fl. E. S / C / N

238000047 Section Location of Waste/Source

Date Well Installed


Well Code 11/mw .1/4 o f . 1/4 of Sec. . -, T. .N, R.

D E . D W


ft.

Enf Stds. Apply

Location of Well Relative to Waste/Source u D Upgradient s D Sidegradient

d D Downeradienl n D Not Known

Gov. Lot Number


Mike

Boart Longvear


B. Well casing, lop elevation

C. Land surface elevation

D. Surface seal, bottom ^"-^-^ ft. MSL or

585.90 ft. MSL

585.50 ft. MSL

585.9 ft. MSL

2.5 ft.

12.

13

14

15

16

17

u s e s classification of soil near screen: GP D GMD GCD GWD SWD SP B SMD SC D MLEl MHD CL El CH D Bedrock D

Sieve analysis attached? D Yes D No

Drilling method used: Rotaiy D 5 0 Hollow Stem Auger K 4 1

Other n

Drilling fluid used: Water D 0 2 Air DOl Drilling Mud D 0 3 None D 9 9

Drilling additives used? D Yes K No

rv<;r-rihp


E. Bentoniie seal, top

F. Fine sand, top

G. Filter pack, top


I. Well bottom

J. Filler pack, bottom

K. Borehole, bottom

L. Borehole, diameter

ft. MSL or

ft. MSL or

583.4 ft. MSL or 2.5 ft..

582.9 ft. MSL or l i ft.

572.9 ft. MSL or '3-0 ft. -

571.9 ft. MSL or '4-0 ft.

57L9 ft. MSL or '4.0 ft.

8.3

1 Cap and lock?

•2. Protective cover pipe:

a. Inside diameter:

b. Lengih:

c. Material:

Yes D No

8.0 in.

£ . fl.

0 4

cSrtSfL d. Additional protection?

1 f ves, describe:

Steel D

Other K

D Yes IE No

' 3. Surface seal Bentonite D

Concrete K

_ Other D

30 0 1

4. Maierial between well casing and protective pipe:

Benionite D Sand Other S

- 5. Annular space seal: a. Granular/Chipped Bentonite B



d % Bentonite . . . Benloniie-cement grout D

e Ft volume added for any of the above

f. How installed: Tremie D

Tremie pumped D

Gravity K

6. Bentonite seal: a. Bentonite granules K

b. D 1/4 in. D3/8in. D 1/2 in. Bentoniie chips D

c Other D

. 7. Fine sand material: Manufacturer, product name & mesh size

30

3 3

3 5

3 1

5 0

0 1

0 2

0 8

3 3

3 2

b. Volume added ft' . 8. Filter pack material: Manufacturer, product name & mesh size

a Red Flint

b. Volume added ft'

9. Well casing: Flush threaded PVC schedule 40 El 2 3


Other D


a. Screen Type:

PVC

Factory cut H 11


Other D Boan Longyear

M. O.D. well casing 2.33 jf,

N. LD. well casing 2.07 jp

b. Manufacturer _

c. Slot size:

d. Slotted length:

1 1. Backfill material (below filter pack):

0.010 ,n.

lQ-0 ft.

None D 14

Other K

I hereby cenify that the information on this form is true and conect to the best of my knowledge. Signaiure

, ^ , / ^ Firm Natural Resource Technology. Inc.

23713 W. Paul Road, Unil D Pewaukee, Wl 53072 Tel: (262)523-9000 Fax: (262) 523-9001

Pleastf compleic both Forms 4400-113A and 4400-113B and rerum them to the appropriate DNR office and bureau. Completion of ihese reports is required by chs. 160. 281. 283. 289 291. 292. 293. 295, and 299, Wis. Stats., and ch. NR 14L Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295. and 299, Wis, Stats., failure to file these forms may resull in a forfeiture of between SIO and S25.000. or imprisonment for up lo one year, depending on the program and conduci involved. Personally identifiable infon^nation on these foi IS noi inlended lo be used for any other purpose. NOTE: See the instructions for more information, including where the completed forms should be seni.


MONITORING WELL DEVELOPMENT Forni 4400-113B Rev. 7-98

Route To: Watershed/WastewaierD

Remediation/Redevelopment Facility/Project Name

Former Marinette MGP Site 11549) Facility License, Permit or Moniionng Number

1. Can this well be purged dr>'?

2, Well development method: suraed with bailer and bailed surged with bailer and pumped surged with block and bailed surged with block and pumped surged with block, bailed, and pumped compressed air bailed only pumped only pumped slowly nthnr


4. Depth of well (from lop of well casing)





0 Sniircp nf water adflprl N/A

D

D D D

D D D D D D

County

Waste ManagemenlD Other D


38

Yes 12 No

4 1 61 42 62 70 20 1 0 5 1 50

50 min,

12.6 ft.

2.07 m.

gal.

60.0 gal.

0.0 gal.

Well Name

MW-310 Wis, Unique Well Number DNR Well Number

Before Development After De 1 1, Depth lo Water

(from top of ^ 5Qg^^ well casing)

Date b. 6/21/2004

D a.m. Time c. 03:35 El p.m.

12. Sediment in well inches bottom

13. Water clarity Clear D 10 Clear Turbid H 1 5 Turbid (Describe)

Gray, siltv

velopment

5.72 ft.

6/21/2004

D a.m 04:20 El p.m

D (Describe)

inches

20 25


14. Total suspended mg/1 solids

15. COD mg/1


mg/1

mg/1


D Yes D No Jody Barbeau


Facility Address or Owner/Responsible Pany Address


Finn: Wisconsin Public Service Corporation

Street: 700 N. Adams SL P Q BOX 19002

Ciiy/State/Zip: Green Bay, WI 54307

I hereby cenify that the above information is true and correct lo the best of my knowledge.

Signature: ^

Pnm Name: Jody Barbeau

Z^^ ^ / 2^^^

Finn: Natural Resource Technoloiry, Inc.

NOTE: See instructions for more information including a list of county codes and well type codes.

State OfWisconsin Department ofNatural Resources


Remediation/Redevelopment

Waste Management D

Other D

SOIL BORING LOG INFORMATION Fomi 4400-122 Rev. 7-98

Page 1 of 2



MW-311 Bonng Drilled By: Name of crew chief (first, last) and Firm

Paul Boart Longyear


10/7/2004


10/7/2004

Drilling Method

hollow stem auger

WI Unique-Well No.

PP724 DNR Well ID No. Common Well Name


579.1 Feet MSL Local Grid Origin g ] (estimated: • ) or Boring Location •

State Plane N , E S /C /N

1/4 of 1/4 of Section , T N, R

Surface Elevation


8.3 inches

Lat .

Long

Local Grid Location

13 N Kl E 148612.58 Ft n S 805565.06 Feet D W

Facility ID

238000047 County



Sample

z l

u



Each Major Unit cn U cn

O -J m ^ 5 Q

o. S o . U c

Soil Properties

3 C ••— a>

l a J J

Q E C o CJ U

— 1

19 16 0 0

— 4 100 r 0 0 -0 - 5

40 10 5 5

2 2 4 6 1-9

0'-9' FILL. ORGANIC SOIL

@ 1' POORLY GRADED SAND WITH GRAVEL, light brown, fine angular gravel

(^2 ' slightly moist

OL

SP

o •. ,1

m ) : • • • : : • ;

• o : • . • • . . <

):-. (@ 8' weathered tar in sand matrix,

sheen, odor, wet

9'-10'SILTY SAND, gray, fine sand, few organics SM

16 25 25 30

-10 10'-12' POORLY GRADED SAND WITH GRAVEL, fine to medium sand, coarse rounded gravel, organics, wood pieces, plant parts, sheen, odor

SP a

•O;-

•12

1 hereby certifi' that the information on this form is true and conect to the best of my knowledge.

Firm ivjatural Resource Technology, Inc. 23713 W. Paul Road, Suite D. • Pewaukee, WL 53213

Tel: (262) 523-9000 Fax: (262) 523-9001

T Template: WDNR SBL 1998-Proiect: 1549GINT.GP.1 This forni is authorized by Chapters 281, 283, 289, 291, 292, 293, 295, and 299, Wis. Stats. Completion of this fonn is mandatory. Failure to file this form may result in forfeiture of between $10 and $25,000, or imprisonment for up to one year, depending on the program and conduct involved. Personally identifiable infomiauon on this fomi is not intended to be be used for any otlier purpose. NOTE: See instmctions for more information, including where the completed fomi should be sent.

State OfWisconsin Department of Natural Resources

SOIL BORING LOG INFORMATION SUPPLEMENT Form 4400-122A

Boring Number M W - 3 1 1 Use only as an attachment to Form 4400-122. Page 2 of 2

Sample

OJ

•Bf-

E -a

_J Qi

u



Each Major Unit cn O cn ca 60

62 = : DO

^ Q

D

D

Soil Properties

u 6

SS 24 12

5 7 9 18 h '

12'-14.5' SILTY SAND, pink to gray, trace fine rounded gravel, hard, odor

ML

- 1 4

Pocket penetrometer: 0.5

END OF BORING (S, 14.5'

State ofWisconsin . Department of Natural Resources „ _ ,,, , , „ , , r—i

Route To: Watershed/Wastewater U Remediation/Redevelopment

Waste Management D M O N I T O R I N G W E L L C O N S T R U C T I O N Other D Form 4400-113A Rev. 7-98



Local Grid Location of Well ft. ^ N . 805565.06 ft. ^ ^ 148612.58

Well Name

MW-311 Facility License, Permit or Monitoring No. Local Grid Origin

Lat. 1

(estimated: • ) or

Long. 1 Facility ID

St. Plane ft.N,

Well Location •

or

.ft. E. S / C / N .

Wis. Unique Well No.

PP724

DNR Well Number

238000047 Section Location of Waste/Source

Date Well Installed


Well Code 11/mw 1/4 o f . 1/4 of Sec. ,T, .N , R,

D E - D W


ft.

Enf Stds, Apply

Location of Well Relative to Waste/Source u D Upgradieni s D Sidegradient d D Downgradient n D Not Kno-wn

Gov, Lot Number


Paul

Boan Longyear

585,60 ft. MSL A, Protective pipe, top elevation _

B, Well casing, top elevation _

C, Land surface elevation _

D, Surface seal, bottom 584,6 ft M S L or '-0 ft.

585.20 ft. MSL

585,6 ft. MSL

12

13

14

15

16

17

u s e s classification of soil near screen:

GP D G M D G C D G W D S W D SP El SM El s c D ML El MH D CL D CH D Bedrock D

Sieve analysis attached? D Yes

Drilling method used: Rotary

Hollow Stem Auger Other

Drilling fluid used: Water D 0 2 Air

Drilling Mud D 0 3 None

Drilling additives used? D Yes

Describe


n/a

El No

D 5 0

E14 1

D£l

DO 1 E199

El No

E, Bentonite seal, top

F, Fine sand, top

G, Filter pack, top

H, Screen joint, top

1, Well bottom

J, Filter pack, bottom

K, Borehole, bottom

L, Borehole, diameter

M, 0 ,D, well casing

N, 1,D, well casing

ft, MSL or

582,6 ft. MSL or 3,0

582,1 ft. MSL( J A ft.

58 L6 ft. MSL or ^-0 ft,

571-6 ft. MSL or ' 4 0 ft.

57L1 ft MSL or '4,5 ft

57 ' - ' ft, MSL or '4-5 ft.

8,3

1, Cap and lock?

-2, Protective cover pipe;

a. Inside diameter:

b. Length:

c. Material:

Yes D No

JLL ft.


If yes, describe:

Steel D 04

Other El 'LM

D Yes El No

"3, Surface seal: Bentonite D 3 0

Concrete 01

Other D m

^ 4, Material between well casing and protective pipe:

Bentonite D 3 0 sand Other El S i

•5, Annular space seal: a, Granular/Chipped Bentonite B 33

b Lbs/gal mud weight. , , Bentonite-sand slurry D 3 5

c Lbs/gal mud weight, , , Bentonite slurry D 3 1

d % Bentonite , , , Bentonite-cement grout D 5 0

e Ft volume added for any of the above

f How installed: Tremie D 0 1

Tremie pumped D 0 2

Gravity El 0 8

6, Bentonite seal: a, Bentonite granules D 3 3

b, D l / 4 m . D 3/8 in, D 1/2 in, Bentonite chips D 3_2

c Other D M i

, 7, Fine sand material: Manufacturer, product name & mesh size

a #7 Badger 'Wt

b. Volume added ,ft ' ^ 8, Filter pack material: Manufacturer, product name & mesh size

a #40 Badger j ^

b. Volume added

9, Well casing: .ft '

Flush threaded PVC schedule 40 E

Flush threaded PVC schedule 80 D

Other D

23 24

2.07


a. Screen Type:

b. Manufacturer

c. Slot size:

d. Slotted length:

PVC ' ^

Factory cut H 1 1 .


Boart Longvear


Other n »4-

0.010 in

10.0 fl

None D 1 4 O t h e r U •*•«'<

hereby certify that the infonnation on this form is true and conect to the best of my knowledge. Signau-ire C ~-y Fimi Natural Resource Tecluiology, Inc.

23713 W. Paul Road. Suite D. Pewaukee, Wl. 53213 Tel: (262)523-9000 Fa.x: (262)523-9001

Mease complete both Forms 4400-1 13A and 4400-113B and return them to the appropriate DNR office and bureau. Compleiion of these reports is required by chs. 160, 281, 283, 289, 291, 292. 293, 295, and 299. Wis. Stats., and ch. NR 141, Wis. Adm Code. In accordance with chs. 281, 289, 291, 292. 293, 295, and 299. Wis. Stals.. failure to file these forms may result in a t'orfeuure of between $10 and S25.000. or imprisonment for up to one vear, depending on Ihe program and conduct involved. Personally identifiable information on these forms is nol intended to be used for anv other purpose NOTE. See the instriictians for more information, including where the completed forms should be sent.

State of V/isconsin Department ofNatural Resources

MONITORING WELL DEVELOPMENT Fonn 4400-1 !3B Rev. 7-98


Remediation/Redevelopment t

Waste Management LZl

Other D


Former Marinette MGP Site (1549) County

Marinette

Well Name

MW-311 Facility License, Permit or Monitoring Number County Code

38

Wis. Unique Well Number

PP724 DNR Well Number







surged with block, hailed, and pumped

compressed air

bailed only

pumped only

pumped slowly

other










El Yes D No

D 4 1

D 6 1

D 42

D 62

D 70

D 20

D 1 0

El 5 1

D 50

D m

155 mm.

14.3 ft.

2 .07 in.

7.5 gal.

9.0 gal.

0.0 gal.

D Yes D No

Before Development After Development 11

12

13

Depth to Water (from top of well casing)

Date

Time

Sediment in well bottom

Water clarity

a.

b.

c.

Clear Turbid

6.44 ft.

10/8/2004

H a.m. 07:13 D p.m.

2.9 inches

D 1 0 Clear El 1 5 Turbid

12.90 ft.

10/8/2004

El D

(Describe) (Describe)

Dark brown, silty. opaq ue, odor

Ei a.m 09:48 D p.m

inches

20 25


mg/1 14. Total suspended solids

15. COD mg/I

mg/1

mg/1


Jody Barbeau


Pumped dry 5 times during development, took approximately 2.5 hours to recover.



Firni: Wisconsin Public Service Corporation

Street:

City/State/Zip: Green Bay, Wl 54307

700 N. Adams St. PO Box 19002

1 hereby certify that the above information is true and conect to the best of my knowledge.

Signature: ~ ^

/ i ^ < ^ ^ Z ^ - ^ - " - -

Pnnt Name: Jody B a r b e a u

Fimi: Natural Resource Technology, Inc.

NOTE: See instructions for more information including a list of county codes and well type codes.


SOIL BORING LOG INFORMATION Forni 4400-122 Rev, 7-98

Route To: Watershed/Wastewater d

Remediation/Redevelopment S

Waste Management D

Other D

Page of 2 Faciliiy/Project Name

Former Marinette MGP Site (1549) License/Permit/Moniloring Number Boring Number

P-305 Boring Drilled By: Name of crew chief (first, last) and Firm

Boart Longyear

Dale Drilling Started

6/21/2004

Date Drilling Completed Drilling Method

6/22/2004 hsa/air rotary Wl Unique Well No, DNR Well ID No, Common Well Name

P-305 Final Static Water Level

Feet MSL Surface Elevalion


6.1 inches Local Grid Ongin ^ (estimated: • ) or Bonng Location •

State Plane N , E S / C / N

1/4 of 1/4 of Section , T N.R

Lat .

L o n g .

Local Grid Location

Kl N M E j|48612.26 Feet D S 805734,08 Feet D W

Facilily ID

238000047 County



Marinette Sample

< ^ . =

o

-9

-10

1—11

-12

-13

•14

-15



Each Major Unit

0'-6'FILL, (ORGANIC SOIL WITH SAND), organic material (roots) trees, old asphalt pieces

@ 2' asphalt and gravel @ 2.3' - 4' (POORLY GRADED SAND), red to yellow, fine @ 3' Sand with slag, bricks, and gravel (@ 4' trace clay,glass, slag, broken brick medium sand, no odor

"\(S, 6' wet 6' - 12' POORLY GRADED SAND gray to brown, wet

(5) 9' one-inch lense of wood

12'- 17' WELL GRADED SAND WITH GRAVEL brown, medium with trace rounded gravel,

14' - 17'POORLY GRADED SAND medium brown, trace gravel,

cn U cn Z)

Fill (OL)

Fill (SP)

SP

SW

Q C L

y.-y. • • a t . ' . '

CL

o . O c

Soil Properties

S u D S O 5 oi U

4 1/4 HSA

Refusal for Hollow Stem Auger,Change| to Air Rotary

I hereby certify that the infonnation on this form is true and conect to the besl of my knowledge.

Signature

"A^^ ^ /3^. Firm "Natuj-al Resource Technology, Inc. 23713 W. Paul Road. UnitD Pewaukee, Wl 53072

Tel: (262) 523-9000 Fax: (262)523-9001

W Template: WDNR SBL 199K-Hroiecl: 1549G1NT.GP, This form is authorized by Chapters 281, 283. 289, 291, 292, 293, 295. and 299, Wis. Stats. Completion of this form is mandatory. Failure lo file this form maT resull in forfeiture of between SIO and £25.000. or imprisonment for up lo one year, depending on the program and conduci involved. Personally identifiable information on this fonn is nol intended lo be be used for any other purpose. NOTE: See instructions for more infonnation, including where ihe completed foi should be sen


SOIL BORING LOG INFORMATION SUPPLEMENT Fonn 4400-122 A

Boring Number P - 3 u 5 Use-only as an attachment to Form 4400-12 22. Page 2 of 2

Sample

Z 5 -1 Qi

U

m



Each Major Unil

a J ? Q

a u. D o iz

U cn

Soil Properties

2 u a o

16

•17

h i s

-19

-20

-21.

-22

-23

-24

-25

-26

-27

12' - 17' WELL GRADED SAND WITH GRAVEL brown, medium with trace rounded gravel,(continued) grinding on rock fragments weathered surface of bedrock, moist

bedrock, fractured, weathered chips, wet

22' - 25' competent bedrock, no discussable fractures, wet

6" fracture, rods "dropped" through faster large amounts of steady water and pressure Tar @ 27', tar droplets present in water

Afrom cuttings f END OF BORING @ 27.5'

HSA Refusal @ 17', Change to 6" Air Rotary

Slate ofWisconsin Departmeni of Namral Resources „ -n „ , , j / , , , rn

Route To: Watershed/Wastewater U Remediation/Redevelopment I

Waste Management D MONITORING WELL CONSTRUCTION Other D Form 4400-113A Rev. 7-98




148612.26 IN jl. ^!,^- 805734.08 f, ^ W^

Well Name

P-305 Facility License, Permit or Moniloring No. Local Grid Origin

o

Lat.

(estimated: • ) or

Long.

Well Location •

or

Wis, Unique Well No, DNR Well Number

Facilily ID St. Plane ft.N, ft.E, S / C / N 238000047

Type of Well

Well Code 12/p2

Section Location of Waste/Source

1/4 of 1/4 of Sec

Dale Well Installed

06/22,/2004

, T. .N .R. D E

_D W

Distance from Waste/ Source ft.

Enf Slds, Apply

Location of Well Relative to Waste/Source u D Upgradient s D Sidegradieni

d D Downgradient n D Nol Known

Gov, Lot Number


Boart Lonsjvear

586,96 ft. MSL A. Protective pipe, top elevalion _

B. Well casing, lop elevation _

C. Land surface elevation _

D. Surface seal, bottom 584.5 ft. MSL or L l . ft.

586.96 ft. MSL

587.0 ft. MSL

12,

13.

14

15

16

17

u s e s classification of soil near screen:

GP D GMD G C D GWD S W H SP El S M D SC D M L D MHD CL D CH D Bedrock K

Sieve analysis attached? D Yes D No

Drilling method used: Rotary D 5 0

Hollow Stem Auger S 4 1 Air rotary Other Kl

Drilling fluid used: Water D 0 2 Air D 0 1

Drilling Mud D 0 3 None D 9 9

Drilling additives used? D Yes S No

DpRrrihe


E. Bentoniie seal, top

F. Fine sand, lop

G. Filler pack, top


I. Well bottom

ft. MSL or

ft. MSL or

584.5 fl, MSLor 2.5 ^

565,0 ft. MSL or ^2.0 ft.

560.0 ft. MSL or 27.0 ft.

J. Filler pack, bottom 559.5 f, M ^ I nr 27.5 ft

K. Borehole, bottom 559.5 ft M,S1 or 27.5 ft

L. Borehole, diameter "-' in.

M, C D , well casing 2,33 jn

N. l.D, well casini; 2.07 jî.

1, Cap and lock?

-2, Prolective cover pipe:

a. Inside diameter:

b. Length:

c. Material:

Yes D No

8.0 in.

1 . ft, 0 4

LStLiStt.

•:-j:


If yes, describe:

Steel D

Other B _ _

D Yes E) No

' 3. Surface seal: Bentoniie D

Concrete K

_ Other D

30 0 1

' 4 . Material between well casing and protective pipe:

Benionite D Sand Other Kl

• 5, Annular space seal: a, Granular/Chipped Benionite K



d % Bentoniie . . , Benionile-cement grout D

e Ft' volume added forany of the above

f How installed: Tremie D

Tremie pumped D

Gravity S

6, Bentonite seal: a. Benionite granules K

b. D 1/4 in. D3/8in . D 1/2 in. Bentoniie chips D

c Other D

, 7, Fine sand material: Manufacturer, product name & mesh size

30

3 3

3 5

3 1

5 0

0 1

0 2

0 8

3 3

3 2

b. Volume added ft' 8, Filter pack material: Manufacturer, product name & mesh size

a Red Flint

b. Volume added ft'

9, Well casing: Flush threaded PVC schedule 40 B 2 3


Other D _ _

• 10, Screen material:

a. Screen Type:

PVC

Factory cut B 11


Other D Boart Longvear b. Manufacturer _

c. Slot size:

d. Slotted length:

11, Backfill material (below filter pack):

0,010

l A . ft. None D 1 4

Other Kl

1 hereby certify thai the information on this form is irue and correct lo the besl of my knowledge. Signaiure ure ^ Firm Natural Resource Technology. Inc.

23713 W. Paul Road, Unit D Pewaukee. Wl 53072 Tel: (262)523-9000 Fa.x: (262)523-9001

Please coinpleie both Forms 4400-1 13A and 4400-1 13B anci rerum them to the appropnaie DNR office and bureau. Compleiion of these rcport.s is required by chs. 160. 281. 283. 289 291, 292. 293. 295. and 299. Wis. Stats., and ch. NR 141. Wis. Adm. Code. In accordance with chs. 281. 289. 291. 292. 293. 295. and 299. 'iVis. Slats., failure lo file these forms may resull in a forleiiurc of between SIO and S25.000. or imprisonment for up to one year, dependini; on the program and conduci involved. Personally identifiable infon-naiion on these fonl i.s noi inlended lo be used for any oihcr purpose. NOTE: Sec the instructions for more mfomtaiion. includinL' where the compleied forms should be seni.

Natural Resource Technoloiiv

MONITORING WELL DEVELOPMENT

N R r


Former Marinette MGP Site (1549) County

Marinette Well Name

P-305 Facility License, Pennit or Monitoring Number Slate Unique Well Number Well Number







surged with block, bailed, and pumped

compressed air

bailed only

pumped only

pumped slowly

other

3 Time spent developing well



6 Volume of water in filter pack and well casing

7 Volume of water removed from well


9. Source of water added



D Yes 0 No

D 4 1

D 6 I

D 42

D 62

D 70

D 20

D 1 0

B 5 I

D 50

D Wl

62 min.

26.6 ft.

2 .07 in.

gal.

50 .0 gal.

gal.

D Yes D No

Before Development After Development 11. Depth to Water

(from top of well casing)

Date b.

Time

7.19 ft.

7/6/2004

M a.m. 08:30 D p.m.


13. Water clarity Clear H 1 0

Turbid D 1 5

(Describe)

inches

7.37 ft.

7 / 6 / 2 0 0 4

El a.m. 0 9 : 3 2 D p.m.

inches

Clear IS 2 0

Turbid 0 2 5

(Describe)


mg/I 14. Total suspended solids

15. COD mg/1

mg/I

mg/1


Jody Barbeau



NpniP Shirley Scharff

Firm Wisconsin Public Service Corporation

.Street 700 N. Adaois St. PO Box 19002

ri,v/s;tn,e./7ip- Green Bay, WI 54307

1 hereby certiiy that the above information is true and correct to the best of my knowledge.

.lon.n.r.- J ^ ^ / / ? ^ - a - - ^ Jody Barbeau

Pnri.N.mP Jody Bafbeau

Firm- Natural Resource Technology, Inc.

1 einplale: NRT WELL DEVELOPMENT - Projeci 1549G1NT.GPJ

. APPENDIX B

JANUARY 2005 SURVEY DATA

Appendix B November 2004 Groundwater Quality Update • 1603 Ely Street, Marinette, Wisconsin Wisconsin Public Service Corporation - Former Marinette Manufactured Gas Plant Site BRRTS #.- 02-38-000047

Field Survey Completed by Wisconsin Public Service Corporation Survey Group Horizontal Datum is Marinette County Coordinates Vertical Datum is NGVDSS

Field Survey Conducted on January 21, 2005.

Location ID MW3R MW307R MW308 MW310 MW311 P305

Northing 148447.37 148820.08 148611.73 148714.51 148612.58 148612.26

Easting 805728.41 805551.00 805727.28 805639.53 805565.06 805734.08

Grd. Elev. 585.68 585.07 586.94 585.90 585.60 586.96

T/Casing 585.68 585.07 586.94 585.90 585.60 586.96

T/PVC 585.50 584.70 586.62 585.50 585.20 586.96

1549GWQualityDataNovember04 App B - Survey Data Page 1 of 1 s NMURAL

APPENDIX C

LABORATORY ANALYTICAL REPORTS

/ x « ( ace Analytical REVISED 1241 Bellevue Street, Suite 9

Green Bay, Wl 54302

920-469-2436, Fax: 920-469-8827

Analytical Report Number: 853784

Client: NATURAL RESOURCE TECHNOLOGY, INC.

Project Name: WPSC - MARINETTE

Project Number: 1549

Lab Contact: Tom Trainor

Lab Sample Number Field ID

853784-001 MW-302

853784-002 MW-303

853784-003 MW-304

853784-004 MW-305

853784-005 MW-306

853784-006 MW-307R

853784-007 MW-308

853784-008 MW-310

853784-009 MW-1

853784-010 MW-311

B53784-011 MW-3R

853784-013 MW-5

853784-014 P-302

853784-015 P-303

853784-017 P-305

853784-018 QC-1

853784-019 QC-2

853784-020 TRIP BLANK

Collect ion Matrix Date

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

WATER 11/22/04

I certify that the data contained In this Final Report has been generated and reviewed In accordance with approved methods and Laboratory Standard Operating Procedure. Exceptions, If any, are discussed in the accompanying sample comments. Release of this f inal report is authorized by Laboratory management, as is verif ied by the fo l lowing signature. This report shall not be reproduced, except in ful l , without the wri t ten consent of Pace Analytical Services, Inc. The sample results relate only to the analytes of Interest tested.

y ] d 4 y < ^ ^ 1'?-o5~ Approval Signature Date

En Chem A Division of Pace Analytical Services, Inc.

Client: NATURAL RESOURCE TECHNOLOGY, INC

Project Name : WPSC - MARINETTE

Project Number : 1549

Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436

Matrix Type : WATER

Collection Date : 11/22/04 Report Date : 12/07/04

Field ID :

I N O R G A N I C S

Test

MW-302

Result LOD LOQ EQL Dll. Units

Lab Sample Number : 853784-001

Code Anl Date Prep Method Anl Method

Iron - Dissolved

Manganese - Dissolved

Alkalinity as CaC03

Nitrogen, N03 + N 0 2

Sulfate

920

130

250

< 0.063

52

17

0.14

8.3

0.063

0.36

55

0.48

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL Dll. Units Code Anl Date

Prep Date: 11/24/04

Prep Method Anl Method

1,2,4-Trimethylbenzene


Benzene

Ethylbenzene

Methyl-tert-butyl-ether

Toluene

Xylene, o

Xylenes, m + p

a,a,a-Trlfluorotoluene

0.61

< 0.40

4.6

8.6

< 0.36

< 0.36

4.4

1.8

99

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

Q

Q

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 503OB

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW845 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

220

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil .

1

Dll .

Units

ug/L

Units

Code Anl Date

12/01/04

Code Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04


1 -Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene

Benzo(b)fluoranthene

Benzo(ghi)perylene

Benzo(k)fluoranthene

Chrysene

Diben2(a,h)anthracene

Fluoranthene

Fluorene

lndeno(1,2,3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< 4.0

< 4.5

5.3

27

45

70

80

45

42

47

59

13

110

4.9

39

13

22

78

0

0

0

4.0

4.5

3.9

3.9

3.5

3.9

3.6

3.6

4.1

3.9

3.3

4.4

6.6

4.4

3.4

4.5

4.1

3.3

13

15

13

13

12

13

12

12

14

13

11

15

22

15

11

15

14

11

200

200

200

200

200

200

200

200

200

200

200

200

400

200

200

200

200

200

200

200

200

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

% Recov

% Recov

Q

* '

Q*

D

Q

• Q

D

D

D

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C.-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

En Chem Analytical Report Number: 853784 A Division of Pace Analytical Services, Inc.

C l i en t : NATURAL RESOURCE TECHNOLOGY, INC.


Pro jec t Number : 1549

Field ID : MW-303

1241 Bellevue Street Green Bay, Wl 54302 920-469-2436

Matrix Type : WATER

Collect ion Date ; 11/22/04

Report Da te : 12/07/04


I N O R G A N I C S

Test Result LOD LOQ EQL Dll. Units Code Anl Date Prep Mett iod Anl Method

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03- i -N02

Sulfate

8900

1300

600

0.063

24

17

0.14

17

0.063

0.36

55

0.48

56

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte Result LOD LOQ EQL DiL Units Code Anl Date

Prep Date: 11/24/04


1,2,4-Trimethylben2ene


Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p

a,a,a-Trifluorotoluene


2-l\/lethylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene

Dibenz(a,h)anthracene

Fluoranthene

Fluorene

Indenod ,2,3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

0.39

0.40

0.14

0.40

0.36

0.36

036

0.74

99

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW84B

SW846

5030B

5030B

5030B

5030B

5030B

5030B

5030B

5030B

5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

850

Result

LOD

LOD

LOQ

LOQ

EQL

50

EQL

Dil.

5

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04


0.020

0.023

0.46

0.060

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.032

0.022

0.017

0.032

0.020

0.035

88

61

62

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.017

0.022

0.017

0.022

0.020

0.016

0.067

0.076

0.065

0.065

0.059

0.066

0.061

0.060

0.069

0.065

0.055

0.074

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

%Recov

%Recov

11/29/04

11/29/04

11/29/04

Q 11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

Q 11/29/04

11/29/04

11/29/04

Q 11/29/04

11/29/04

Q 11/29/04

11/29/04

11/29/04

11/29/04

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

8270C-SIM

8270C-SIM

S270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-S1M

8270G-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM





Field ID : MW-304


Matrix Type : WATER

Collection Date : 11/22/04

Report Date : 12/07/04

Lab Sample Number: 853784-003

INORGANICS

Test Result LOD LOQ EQL Dll. Units Code Anl Date Prep Method Anl Method

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 -(• N02

Sulfate

190

250

220

0.064

490

17

0.14

8.3

0.063

3.6

55

0.48

28

0.21

12

ug/L

ug/L

mg/L

mg/L

0 mg/L

Q

11/30/04

11/30/04

12/01/04

12/07/04

11/30/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 601OB

EPA 310.2

-EPA 353.2 •

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL Dil. Units

Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i- p

a.a,a-Trifluorotoluene

1.8

0.73

29

5.9

< 0.36

5.1

4.0

4.6

98

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

0

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846M8021

SW845M8021

SW846M8021

SW846 M8021

SW846M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846M8021

M E T H A N E

Analyte

Methane

P A H / P N A

Analyte

Result

33

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Units

ug/L

Units

Code

Code

An l Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< • <

< < < < < < < < < < < <

< <

2.5

2.3

1.9

1.9

1.8

2.0

1.8

1.8

2.1

1.9

1.6

2.2

1.7

2.2

1.7

27

2.0

1.6

0

0

0

2.0

2.3

1.9

1.9

1.8

2.0

1.8

1.8

2.1

1.9

1.6

2.2

1.7

2.2

1.7

2.2

2.0

1.6

6.7

7.6

6.5

6.5

5.9

6.6

6.1

6.0

6.9

6.5

5.5

7.4

5.5

7.3

5.7

7.5

6.8

5.4

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

ug/L Q 11/30/04

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov D

%Recov D

%Recov D

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11 /30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW845 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIIV1

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SiM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIIVI

8270C-SIM

8270C-SIM


C l ient : NATURAL RESOURCE TECHNOLOGY, INC



Field ID : MW-305

Analytical Report Number: 853784 1241 Bellevue Street Green Bay, Wl 54302 920^69-2436

Matrix Type: WATER




I N O R G A N I C S

Test Result LOD LOQ EQL Dil. Units Code Anl Date Prep Method Anl Method

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

26

0.45

270

4.3

34

17

0.14

8.3

0.063

0.36

55

0.46

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

Q

Q

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 601 OB

SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p

a.a.a-Trlfluorotoluene

< < < < < < < <

0.39

0 4 0

0.14

0.40

0.36

0.36

036

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

M8D21 M8021 M8021 M8021 M8021 M8021 M8021 M8021 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

< 10

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SWB46M8015 SW846M8015

Prep Date: 11/24/04

Prep Method An l Method

1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene

Benzo{k)fluoranthene

Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < < < < < < < < <

< < < < <

0.020

0.023

0.019

0 019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.018

0.022

0.017

0.022

0020

0.016

56

40

58

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

1 ug/L

1 ug/L

•ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

ug/L Q 11/29/04

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%ReGOV

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35100

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 35100

SW846 351 OC

SW846 351 OO

SW846 3510C

SW846 351 OC

SW846 3510O

SW846 351 OO

SW846 35100

SW846 35100

SW846 35100

SW846 351 OC

SW846 3510C

SW846 3510C

6270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

5270C-SIM

En Chem A Division of Pace Analytical Sen/ices, Inc.

C l i en t : NATURAL RESOURCE TECHNOLOGY, INC




Matrix Type : WATER



Field ID :

INORGANICS

Test

MW-306

Result LOD LOQ EQL Dil. Units



Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 -i- N02

Sulfate

4500

390

350

< 0.063

9.8

17

0.14

8.3

0.063

0.36

55

0.48

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 601 OB

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p

a,a,a-Trlfluorotoluene

5.5

< 0 4 0

0.20

0.41

< 0.36

< 0.36

2.3

< 0.74

100

0.39

0 40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

Q

Q

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 503OB

SW846 5030B

SW846 5030B

SW846 5030B

SW846 503OB

SW846 5030B

SW846 503OB

SW846 5030B

SW846 503OB

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

43

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

DiL

1

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04

Prep Method An l Method

SW846 M8015 SW846 M8015

Prep Date: 11/24/04



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene

lndeno{1,2,3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nltrobenzene-d5 •

2-Fluorobiphenyl

Terphenyl-d14

<

< < < < < < < < <

<

<

1.8

0.023

0.18

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.035

0.031

0.017

0.37

0.020

0.24

82

59

61

0.10

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.33 5 ug/L

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

D

* *

• 0

0

*

12/01/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client: NATURAL RESOURCE TECHNOLOGY, INC




Matrix Type : WATER Collection Date : 11/22/04


Field ID :

I N O R G A N I C S

Test

MW-307R




Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N 0 3 + N02

Sulfate

20000

2300

650

< 0.063

5.3

17

0.14

17

0.063

0.36

55

0.48

56

0.21

1.2

1

1

2

1

1

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p

a,a.a-Trifluorotoluene

<

< < < < <

0.69

0.40

0.61

0.40

0.36

0.36

0.36

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

Q 11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

P A H / P N A

Analyte

Result

4100

Result

LOD

LOD

LOQ

LOQ

EQL

500

EQL

Dil .

50

Dil .

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

6.0

0.84

7.4

0.25

1.0

0.50

0.31

0.18

0.15

0.17

0.34

0.053

1.8

2.5

0.14

3.2

4.8

1.6

91

60

56

0.50

0.57

0.48

0.019

0.44

0.49

0.018

0.018

0.021

0.019

0.016

0.022

0.41

0.54

0.017

0.56

0.51

0.41

1.7

1.9

1.6

0.064

1.5

1.5

0.060

0.060

0.069

0.064

0.055

0.073

1.4

1.8

0.057

1.9

1.7

1.4

25

25

25

1

25

25

1

1

1

1

1

1

25

25

1

25

25

25

1

1

1

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

D

QD

D

QD

QD

* •

•

Q-

D

D

• D

D

D

12/01/04

• 12/01/04

12/01/04

11/30/04

12/01/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

12/01/04

12/01/04

11/30/04

12/01/04

12/01/04

12/01/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 35IOC

SW846 351 OC

SW846 3510C

SW846 35IOC

SW846 351 OC

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

82700-SIM

8270C-SIM

e270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


C l i en t : NATURAL RESOURCE TECHNOLOGY, INC




Matrix Type : WATER


Report D a t e : 12/07/04

Field ID :

I N O R G A N I C S

Test

MW-308

Result LOD LOQ EQL Dil . Units

Lab Sample N u m b e r : 853784-007


Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

710

1500

590

0.063

25

17

0.14

17

0.063

0.36

55

0.48

56

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 5010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL Dil . Units Code Anl Date

Prep Date: 11/24/04



1,3,5-Tnmethylbenzene

Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p

a,a,a-Tritluorotoluene

<

< < <

<

0.90

0.40

0.61

0.40

0.36

0.36

1.0

0.74

99

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1,2

1.2

2.5

1 ug/L

1 ug/L

1 ug/L

1 ug/L

1 ug/L

1 ug/L

1 ug/L

1 ug/L

1 %Recov

Q

Q

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846M8021

SW846M8021

SW846 l\/I8Q21

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

2100

Result

LOD

LOD

LOQ

LOQ

EQL

200

EQL

Dil.

20

DIL

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghl)perylene


Chrysene


Fluoranthene

Fluorene

lndeno(l,2,3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

<

< < < < < < < < < < <

<

18

2.3

11

3.6

1.8

2.0

1.8

1.8

2.1

1.9

1.6

2.2

1.6

2.2

1.7

2.2

11

1.6

0

0

0

2.0

2.3

1.9

1.9

1.8

2.0

1.8

1.8

2.1

1.9

1,6

2.2

1.6

2.2

1.7

2.2

2.0

1-6

6.6

7.6

6.6

6.4

5.9

6.5

6.0

6.0

6.9

6.4

5.5

7.3

5.5

7.3

5.7

7.5

6.8

5.4

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q

Q

* •

*

*

D

D

D

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SWB46 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Cl ient : NATURAL RESOURCE TECHNOLOGY, INC.




Matrix Type : WATER



Field ID :

I N O R G A N I C S

Test

MW-310

Result LOD LOQ EQL DIL Units



Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

28000

2200

400

0.063

49

17

0.14

8.3

0.063

0.36

55

0.48

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

SW846 60108

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C Prep Date: 11/24/04

Analyte



Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i- p

a,a,a-Trifiuorotoluene

<

< < < <

Result

0.46

0.40

0.68

0.89

0.36

0.36

0.36

0.74

100

LOD

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

LOQ EQL Dil. Units

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

Code

Q

Q

Anl Date

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

Prep Method

SW846 5030B

SW846 5030B

SWB46 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

Anl Method

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

170

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene

Dibenz{a,h)anthracene

Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-FlLorobiphenyl

Terphenyl-d14

4.4

1.3

5.2

0.067

0.70

0.051

< 0.018

< 0.018

< 0.021

< 0.019

0.035

< 0.022

0.37

1.9

< 0.017

5.4

3.0

0.39

72

52

46

0.40

0.45

0.39

0.019

0.35

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.44

0.017

0.45

0.41

0.016

1.3

1.5

1.3

0.064

1.2

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

1.5

0.057

1.5

1.4

0.054

20

20

20

1

20

1

1

1

1

1

1

1

1

20

1

20

20

1

1

1

1

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

D

QD

D

QD

Q

* • Q

*

D

* D

D

12/01/04

12/01/04

12/01/04

11/30/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

12/01/04

11/30/04

12/01/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35IOC

SW846 35100

SW846 3510C

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 35100

SW846 3510C

SW845 3510O

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client : NATURAL RESOURCE TECHNOLOGY, INC




Matrix Type : WATER



Field ID :

I N O R G A N I C S

Test

MW-1




Iron - Dissolved


Alkalinity as CaC03


Sulfate

11000

810

590

< 0.063

5.0

170

0.14

17

0.063

0.36

550

0.48

56

0.21

1.2

10

1 .

2

1

1

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/29/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 60108

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte


2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene

lndeno(1,2.3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14


Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

3200

Result

LOD

LOD

LOQ

LOQ

EQL

250

EQL

Dil .

25

Dil .

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846 M8015 SW846 M8015

Prep Date: 11/24/04


< <

< < < < < < < < < < < <

< <

0.020

0.023

0.022

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.14

0.020

0.016

73

53

48

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

11/29/04

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

351 OC

351 OC

351 OC

351 OC

3510C

351 OC

351 OC

35 IOC

351 OC

3510C

351 OC

3510C

3510C

3510C

3510C

3510C

351 OC

3510C

3510C

3510C

3510C

82700-SIM

82700-SIM

82700-SIM

8270C-SIM

82700-SIM

82700-SIM

82700-SIM

82700-SIM

82700-SIM

8270C-SIM

8270C-SIM

82700-SIM

82700-SIM

8270C-SIM

8270C-SIM

82700-SIM

82700-SIM

82700-SIM

8270C-SIM

8270C-SIM

82700-SIM

Pace Analytical Services, Inc.


Cl ien t : NATURAL RESOURCE TECHNOLOGY, IN


Project N u m b e r : 1549

Field ID : MW-311

REVISED


Matrix Type : WATER




INORGANICS

Test Result LOD LOQ EQL Dil. Units Code Anl Date Prep Method Anl Method

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

1200

3000

1100

0.083

13

17

0.14

42

0.063

0.36

55

0.48

140

0.21

1.2

1 ug/L

1 ug/L

5 mg/L

1 mg/L

1 mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 601QB

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL Dil. Units Code Anl Date

Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


1-Methylnaphthalene

2-Methyln3phthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzp(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

150

57

580

1200

< 9.0

19

310

510

99

9.8

9.9

3.4

10

9.0

8.9

9.0

19

33

33

11

33

30

30

30

62

25

25

25

25

25

25

25

25

1

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

K 11/24/04

K 11/24/04

K 11/24/04

K 11/24/04

K 11/24/04

QK 11/24/04

K 11/24/04

K 11/24/04

11/24/04

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

50308

5030B

5030B

5030B

5030B

5030B

5030B

50308

5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

PAH/ P N A

Analyte

Result

1300

Result

LOD

LOD

LOQ

LOQ

EQL

100

EQL

Dil.

10

Dll.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SWe46M8015

Prep Date: 11/24/04


350 250

330 280

< 240 240

3.7 1.9

9.9 1.8

< 2.0 2.0

< 1.8 1.8

< 1.8 1.8

< 2.1 2.1

< 1.9 1.9

< 1.6 1.6

< 2.2 2.2

3.9 1.6

36 2.2

< 1.7 1.7

3200 280

32 2,0

3.7 1.6

0

0

0

830

940

810

6.4

5.9

6.5

6.0

6.0

6.9

6.4

5.5

7.3

5.5

7.3

5.7

930

6.8

5.4

12500

12500

12500

100

100

100

100

100

100

100

100

100

100

100

100

12500

100

100

100

100

100

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

%Recov

%Recov

QD 12/01/04

QD 12/01/04

D 12/01/04

Q 11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

Q 11/30/04

11/30/04

11/30/04

D 12/01/04

11/30/04

Q 11/30/04

D 11/30/04

D 11/30/04

D 11/30/04

SW846 351 OC

SW845 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW845 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

En Chem A Division of Pace Analytical Services. Inc.

Cl ient : NATURAL RESOURCE TECHNOLOGY, INC




Matrix Type : WATER

Collect ion Date : 11/22/04

Report Date: 12/07/04

Field ID :

I N O R G A N I C S

Test

MW-3R

Result LOD LOQ EQL Dll. Units



Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

1100

1200

850

0.80

290

17

0.14

17

0.063

3.6

55

0.48

56

0.21

12

1 ug/L

1 ug/L

2 mg/L

1 mg/L

10 mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte

P A H / PNA

Analyte

Result LOD LOQ EQL Oil. Units

Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

99

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 503OB

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

Result

35

LOD LOQ EQL

10

DiL

1

Units

ug/L

Code Anl Date

12/01/04

Prep Date: 12/01/04


SW846M8015 SW846M8015

Result LOD LOQ EQL Dil. Units Code Anl Date

Prep Date: 11/24/04


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

0.18

0.051

14

0.28

0.15

< 0.020

< 0.018

< 0.018

< 0.021

< 0.019

< 0.016

< 0.022

0.15

2.4

< 0.017

< 1.1

0.049

0.093

97

61

64

0.020

0.023

0.97

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

1.1

0.017

1.1

0.020

0.016

0.066

0.076

3.2

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

3.6 ;

0.057

3.7 ;

0.068

0.054

ug/L

ug/L

50 ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

50 ug/L

ug/L

JO ug/L

ug/L

ug/L

%Recov

%Recov

% Recov

Q

D

* "

*

QD

• D

Q

11/30/04

11/30/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

12/01/04

11/30/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 35IOC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


C l i en t : NATUFIAL RESOURCE TECHNOLOGY, INC.




Matrix T y p e : WATER



Field ID :

I N O R G A N I C S

Test

MW-5

Result LOD LOQ EQL DiL Units



Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

18

480

270

2.7

66

17

0.14

8.3

0.063

0.36

55

0.48

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 60108 SW845 6010B

SW846 601 OB SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


0.39

0.40

0.73

0.63

0.36

0,36

0.36

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW845 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

< 10

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/24/04


1-Methylnaphthalene

2-Methylnaphfhalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < <

c

< < <:

<

0.087

0.085

0.060

0.019

0.018

0.020

0.018

0.018

0.022

0.022

0.025

0.022

0.016

0.022

0.017

1.4

0.027

0.016

71

55

103

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.015

0.022

0.017

0.089

0,020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.30

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

I ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

0

Q

Q

0

D

Q

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

12/01/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 35100

SW846 3510C

SW846 3510C

SW846 35100

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

a270C-SIM

8270C-SIM

8270C-SIM


Client: NATURAL RESOURCE TECHNOLOGY, INC. Project Name : WPSC - MARINETTE




Report Date: 12/07/04 Field ID :

I N O R G A N I C S

Test

P-302




Iron - Dissolved


Alkalinity as CaC03


Sulfate

6600

230

260

0.063

30

17

0.14

8.3

0.063

0.36

55

0 4 8

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

0

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 11/24/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

100

0.39

0 4 0

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 50308

SW846 50308

SW846 50308

SW846 50308

SW846 50308

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

PAH/ PNA

Analyte

Result

< 10

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dll.

1

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846 M8015 SW846 M8015

Prep Date: 11/24/04


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene

Benzo{b)fluoranthene

Benzo(ghi)perylene

Benzo{k)fluoranthene

Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < < < < < < < < < < < < < < <

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

72

58

91

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

% Recov

1 %Recov

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client : NATURAL RESOURCE TECHNOLOGY, INC Project Name : WPSC - MARINETTE



Matrix Type : WATER


Report Date: 12/07/04 Field I D : P-303

I N O R G A N I C S

Test

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

P V O C

Analyte

1,2,4-Trimethylt3enzene


Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)3nthracene

Benzo{a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene

lndeno(l,2,3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

Result

40

3.8

200

0.26

670

Result

< 0.39

< 0.40

< 0.14

< 0.40

< 0.36

< 0.36

< 0.36

< 0.74

100

Result

< 10

Result

< 0.020

< 0.023

< 0.019

0.027

< 0.018

0.050

0.041

0.026

0.023

0.030

0.039

< 0.022

0.071

< 0.022 ,

0.019

< 0.022

0.044

0.067

62

54

82

LOD

17

0.14

8.3

0.063

7.2

LOD

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

LOD

LOD

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0020

0.016

LOQ EQL

55

0.48

28

0.21

24

LOQ EQL

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

Dil. Units

1 ug/L

1 ug/L

1 mg/L

1 mg/L

20 mg/L

Dll. Units

1 ug/L

t ug/L

1 ug/L

1 ug/L

1 ug/L

1 ug/L

ug/L

1 ug/L

1 %Recov

LOQ EQL Dil . Units

10 ug/L

LOQ EQL Dil . Units

0.066

0.076

0.065

0.064

0.059

0.065

O.O60

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.066

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

( ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov


Code

Q

Code

Code

Code

Q

Q

Q

0

Q

Q

0

Q

Q

Anl Date

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

Anl Date

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

11/24/04

Anl Date

12/01/04

Anl Date

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

Prep Method

SW846 601 OB

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

Anl Method

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

Prep Date: 11/24/04

Prep Method

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

Anl Method

SW846 IVI8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SWa46 M8021

Prep Date: 12/01/04

Prep Method

SW846M8015

Anl Method

SW846M8015

Prep Date: 11/24/04

Prep Method

SW84e3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

Anl Method

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

3270C-SIM

82700-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

82700-SIM

8270C-S1M

82700-SIM

82700-SIM







Report Date : 12/07/04 Field ID : P-305

I N O R G A N I C S

Test

Iron - Dissolved


Alkalinity as CaC03


Sulfate

P V O C

Analyte



Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

1 -Methylnaphtha lene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Ben20(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-dl4

< < < < < < < <

< <

< < < < < < < < < < < <

< <

Result

4700

1700

720

0.22

76

Result

0.39

0.40

0.14

0.40

0.35

0.36

0.36

0.74

100

Result

38

Result

0.020

0.023

0.051

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.025

0.020

0.016

95

76

94

LOD

17

0.14

17

0.063

0.36

LOD

0.39

0.40

0.14

0.40

0.35

0.35

0.36

0.74

LOD

LOD

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

LOQ EQL

55

0.48

56

0.21

1.2

LOQ EQL

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

LOQ EQL

10

LOQ EQL

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

Dil. Units

1 ug/L

1 ug/L

2 mg/L

1 mg/L

1 mg/L

Dil. Units

1 ug/L

ug/L

1 ug/L

1 ug/L

1. ug/L

1 ug/L

1 ug/L

1 ug/L

1 %Recov

Dil. Units

1 ug/L

Dil. Units

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov


Code Anl Date

11/30/04

11/30/04

12/01/04

12/07/04

11/24/04

Code Anl Date

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

Code Anl Date

12/01/04

Code Anl Date

11/30/04

11/30/04

Q 11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

Q 11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

Prep Method

SW846 6010B

SW846 60108

EPA 310.2

EPA 353.2

EPA 300.0

Anl Method

SW846 601 OB

SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

Prep Date: 11/25/04

Prep Method

SW846 5030B

SW846 5030B

SW846 5030B

SW846 50308

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

Anl Method

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

Prep Date: 12/01/04

Prep Method

SW846M8015

Anl Method

SW846M8015

Prep Date: 11/29/04

Prep Method

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 351 OC

SW846 35IOC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 35100

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

Anl Method

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

82700-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM


Cl ient : NATURAL RESOURCE TECHNOLOGY, INC




Matrix Type : WATER



Field ID :

INORGANICS

Test

QC-1




Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

4500

390

350

0.063

9.7

17

0.14

8.3

0.063

0.36

55

0.48

28

0.21

1.2

ug/L

ug/L

mg/L

mg/L

mg/L

11/29/04

11/29/04

12/01/04

12/07/04

11/24/04

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte


2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene

Ben2o(k)fluoranthene

Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-dS

2-Fluorobiphenyl

Terphenyl-d14


Prep Date: 11/25/04




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


<

< < <

<

4.2

0.40

0.15

0.40

0.36

0.35

1.8

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

11/25/04

11/25/04

ug/L Q 11/25/04

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

50

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Units

ug/L

Units

Code

Code

Anl Date

12/01/04

Anl Date

Prep Date: 12/01/04


SW846M8015 SW846M8015

Prep Date: 11/29/04


0.54

0.023

0.080

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.037

0.022

0.017

0.11

0.020

0.24

88

70

88

0.040

0.023

0.019

0.019

0.018

0.020

0.018

0,018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.13

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

%Recov

%Recov

D 12/02/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

Q 11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

11/30/04

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35100

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SWe46 3510C

SW846 35100

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

a270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

6270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


C l ien t : NATURAL RESOURCE TECHNOLOGY, INC



Field ID : QC-2

Analytical Report Number: 853784 1241 Bellevue Street Green Bay, W l 54302 920-469-2436

Matrix Type : WATER




INORGANICS

Test Result LOD LOQ EQL DiL Units Code Anl Date Prep Method Ant Method

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

1400 17

680 0.14

410 8.3

0.063 0.063

93 1.8

55

0.48

28

0.21

6.0

ug/L

ug/L

mg/L

mg/L

mg/L

11/29/04

11/29/04

12/01/04

12/07/04

11/24/04

SW846 60108

SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL Dll. Uni ts Code Anl Date

Prep Date: 11/25/04

Prep Method A n l Method



Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


0.39

0.40

0.15

0.40

0.36

0 3 6

0.36

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

7oRecov

11/25/04

11/25/04

Q 11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

5030B

5030B

5030B

5030B

5030B

5030B

5030B

5030B

5030B

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

M8021

M8021

M8021

M8021

M8021

M8021

M8021

M8021

M8021

METHANE

Analyte Result LOD LOQ EQL DiL Uni ts

Prep Date: 12/01/04

Code Anl Date Prep Method A n l Method

Methane 10 10 ug/L 12/01/04 SW846M8015 SW846M8015

PAH/ PNA

Analyte Result LOD LOQ EQL Dll. Uni ts Code Anl Date

Prep Date: 11/29/04


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Ben20(ghi)perylene

Benzo(k)fiuoranthene

Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < < < < < < < < < < < <

< <

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.026

0.020

0.016

85

66

91

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0,073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

ug/L Q 12/01/04

ug/L

ug/L

VoRecov

%Recov

%Recov

12/01/04

12/01/04

12/01/04

12/01/04

12/01/04

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client : NATURAL RESOURCE TECHNOLOGY, INC



Field ID : TRIP BLANK


Matrix Type : WATER




PVOC

Analyte



Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i- p


< < < < < < < <

Result

0.39

0.40

0.14

0.40

0.36

0.35

0.36

0.74

100

LOD

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

LOQ EQL Dil . Units Code Anl Date

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

11/25/04

Prep Date: 11/25/04

Prep Method

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

Anl Method

SW846 M8021

SW846 M8021

SW846M8021

SW848 M8021

SW846M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

Qualifier Codes

Flag Applies To Explanation

Inorganic

B

B

C

D

E

Inorganic

Organic

All

All

Inorganic

E

F

F

H

HF

J

J

K

K

L

M

N

0

P

0

Organic

Inorganic

Organic

All

Inorganic

Inorganic

Organic

Inorganic

Organic

All

Organic

All

Organic

Organic

All

Organic

U

V

w X

& -< 1

2

3

4

5

6

7

All

All

All

All

All

All

All

Inorganic

Inorganic

Inorganic

Inorganic

Inorganic

Inorganic

Inorganic

Analyte is detected in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally, method blank acceptance may be based on project specific criteria or determined from analyte concentrations in the sample and are evaluated on a sample by sample basis.

The analyte has been detected between the method detection limit and the reporting limit.

Analyte is present in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally, method blank acceptance may be based on project specific criteria or determined from analyte concentrations in the sample and are evaluated on a sample by sample basis.

Elevated detection limit.

Analyte value from diluted analysis or surrogate result not applicable due to sample dilution.

Estimated concentration due to matrix interferences. During the metals analysis the serial dilution failed to meet the estatilished control limits of 0-10%. The sample concentration is greater than 50 times the IDL for analysis done on the ICP or 100 times the IDL for analysis done on the ICP-MS. The result was flagged with the E qualifier to indicate that a physical interference was observed.

Analyte concentration exceeds calibration range.

Due to potential interferences for this analysis by Inductively Coupled Plasma techniques (SW-846 Method 6010), this analyte has been confirmed by and reported from an alternate method.

Surrogate results outside control criteria

Preservation, extraction or analysis performed past holding time.

This test is considered a field parameter, and the recommended holding time is 15 minutes from collection. The analysis was performed in the laboratory beyond the recommended holding time.


Concentration detected is greater than the method detection limit but less than the reporting limit.

Sample received unpreserved. Sample was either preserved at the time of receipt or at the time of sample preparation.

Detection limit may be elevated due to the presence of an unrequested analyte.

Elevated detection limit due to low sample volume.

Sample pH was greater than 2

Spiked sample recovery not within control limits.

Sample received overweight.

The relative percent difference between the two columns for detected concentrations was greater than 40%.

The analyte has been detected between the limit of detection (LOD) and limit of quantitation (LOQ). The results are qualified due to the uncertainty of analyte concentrations within this range.

The relative percent difference between quantitation and confirmation columns exceeds internal quality control criteria. Because the result is unconfirmed, it has been reported as a non-detect with an elevated detection limit.

The analyte was not detected at or above the reporting limit.

Sample received with headspace.

A second aliquot of sample was analyzed from a container with headspace.

See Sample Narrative.

Laboratory Control Spike recovery not within control limits.

Precision not within control limits.


Dissolved analyte or filtered analyte greater than total analyte; analyses passed QC based on precision criteria.

Dissolved analyte or filtered analyte greater than total analyte; analyses failed QC based on precision criteria.

BOD result is estimated due to the BOD blank exceeding the allowable oxygen depletion.

BOD duplicate precision not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.

BOD result is estimated due to insufficient oxygen depletion. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.

BOD laboratory control sample not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.

BOD result is estimated due to complete oxygen depletion. Due to the 48 hour holding time for this test, it is not practical tc reanalyze and try to correct the deficiency.

En Chem Analysis Summary by Laboratory A Division of Pace Analytical Services, Inc.

1241 Bellevue Street Green Bay, Wl 54302

1090 Kennedy Avenue Kimberly.WI 54136

Test Group Name

ALKALINITY AS CAC03

IRON - DISSOLVED

MANGANESE - DISSOLVED

METHANE

NITROGEN, N03-1-N02

PAH/ PNA

PVOC

SULFATE

OJ U l OJ

00

o o

G

G

G

G

G

G

G

G

CD t n w CD 4 ^

8 ro

G

G

G

G

G

G

G

G

0 0 O l OJ

CD 4 ^

O o OJ

G

G

G

G

G

G

G

G

0 0 O l OJ

0 0

6 o

G

G

G

G

G

G

G

G

00 O l OJ

o o c n

G

G

G

G

G

G

G

G

OO

a OO

o o CJJ

G

G

G

G

G

G

G

G

OO O l OJ

o o - 4

G

G

G

G

G

G

G

G

OJ O l OJ • > !

2 o o CD

G

G

G

G

G

G

G

G

0 3 O l OJ

00

§ CD

G

G

G

G

G

G

G

G

CD cn CO - CO

o o

G

G

G

G

G

G

G

G

O l OJ --J CO

o

G

G

G

G

G

G

G

G

0 0 O l OJ -v/ 00

o OJ

G

G

G

G

G

G

G

G

OJ O l OJ

00

o

G

G

G

G

G

G

G

G

0 0 c n CO - ^ I 0 0

CD

cn

G

G

G

G

G

G

G

G

OJ cn CO - , 1 CO

o

G

G

G

G

G

G

G

G

CD t n CJ

c a 4 ^

o CD

G

G

G

G

G

G

G

G

0 0 cn

CO

OJ

o CD

G

G

G

G

G

G

G

G

00 cn CO - v i 05

o o

G

Wisconsin Certification

G-

K =

S =

'C =

- En Chem Green Bay

= En Chem Kimberly

= En Chem Superior

405132750 / DATCP: 105 000444

445134030

Not Applicable

= Subcontracted Analysis

Batch No. ^ ^ S ? ^ " / Project Name or ID I S n !

En Chem, Inc. Cooler Receipt Log

Temps: { ' ^ t ^ No. of Coolers: /

A. Receipt Phase: Date cooler was opened: j ' g ^ S C J n Bv: ( S ^

1: Were samples received on ice? (Must be < 6 C ) (.YES NO ' NA

2. Was there a Temperature Blank? YES

3: Were custody seals present and Intact on cooler? (Record on COC) YES

4: Are COC documents present? ./<YES

5: Does this Project require quick turn around analysis? YES

6; Is there any sub-work? YES

7: Are there any short hold time tests? YES

8: Are any samples nearing expiration of hold-time? (Within 2 days) YES

9: Do any samples need (o be Filtered or Preserved in the lab? YES

B. Check-in Phase: Date samples were Checked-in: \ \ ' ' ^ ^ ' C i ' ^ By: { ^ ^

Contacted by/Who_

Contacted by/Who_

1: Were all sample containers listed on the COC received and intact?..

2: Sign the COC as received by En Chem. Completed

3: Do sample labels match the COC?

4: Completed pH check on preserved samples {This statement does noi apply to water VOC, O&G, TOC, ORG, Total Rec. Phenolii

5: Do samples have correct chemical preservation? /^.YES (This statement does not apply to water VOC, O&G, TOC, DRO, Total Rec. Phenolic

6: Are dissolved parameters field filtered?

7: Are sample volumes adequate for tests requested?

8: Are VOC samples free of bubbles >6mm :

9: Enter samples into logbook. Completed :(YES,

10; Place laboratory sample number on all containers and COC. Completed <YES

11: Complete Laboratory Tracking Sheet (LTS). Completed YES

12: Start Nonconformance form ' .YES

13: Initiate Subcontracting procedure. Completed ,/ YES

14: Check laboratory sample number on all containers and COC.

Short Hold-time tests:

7 7 ÊS

o(723AîQ>

24 Hours or less Coliform Corrosivity = pH Dissolved Oxygen Hexavalent Chromium HPC Ferrous Iron Eh Odor Residual Chlorine Sulfite

48 Hours BOD Color Nitrite or Nitrate Ortho Phosphorus Surfactants Turbidity En Core Preservation Power stop preservation

7 days A«h

^--"Aqueous Extr^ctable Organics- ALL "" " ^ Flashpoint - ^

Free Liquids Sulfide TDS TSS Total Solids TVS TVSS Unpreserved VOC's

Footnotes 1 Notify proper lab group immediately. 2 Complete nonconformance memo.

Rev. 2/05/04, At tachment to 1-REC-5. Subject to Q A Audit . Rev iewed by/date_ fvf iiliili

p:/everyone/forms/samplereceiving/cri.doc

(Please Prim Legibly) Company Name-. < V s V i / V ^ \ V -~<-> t jVc ' - V c A ^ ^ j ' \ i i cj-J

W c ^ - j ^ " U -c Branch or Localion: V

Project Conlaci: ~ ^ 0 M ' \ b u > ^ V ' - " ' ^

^ ^ v - <; - \ V « V i Telephone:

Project Number: * S n \

Project Nama: ^ ^ ^ ^ ' ^ ' • - ^ ^ V ' ^ • - ' V-^ ^ ^

Projeci Stale; W T

Sampled By (Priril) :

P 0 # :

. - J o J ^ ^ l > ^ . y V l , ^ ' ^

Data Package Options - (please circle il requested)

Sample Results Only (no QC)

EPA Level II (Subject to Surcharge)

EPA Level 111 (Subject to Surcharge)

EPA Level IV (Subject to Surcharge)

LftBORATORY ID (Lab Use Only) FIELD ID

Regulalory Program

UST RCRA SDWA NPDES

CERCLA

EN CHEM INC.

C3 1241 BeUevue St., Suite 9 Gieen Bay, Wl S4302

920-469-2436 Fax 920-469-8827

...clttntiitryfor llil environnieiit.

CHAIN OF CUSTODY N° 130183 /

Page_

Quote #:_

Mail Report To: ,: 'sL.cNû... UJ-A^ •Preservallon Coiles

A=None B=HCL C=H2S04 D=HN03 E=EnCote F=Melhanol G=NaOH , v i v--, - _ , H^Soillum BIsullale Solullon USoilluni Thiosulfale JjOlher / Company: A / - v V ' ^ ^ ' ^ ' V - i . >agt- '- '^ V<..V-., i i^

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COLLECTION

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(Rush TAT subject to approval/surcharge)

Date Needed:

Transmit Prelim Rusti Results by (circle);

Phone Fax E-Mail

Ptioiie #:

Fax#:

E-Mail Address:

Samples on HOLD are subject to special pr ic ing and release o l l iabil i ty

Dale/Time; ua ien ime: , \ ^ _ '

14'. CO ll'-^ Date/Time:

Relinquished By; Date/Time;

Relinquished By; Date/Time;

Relinquished By; Date/time:

IDats/Tjme:

EuuW 11^1 iw En Chem Project No.

Sample Receipt Temp, :e lp l Ten

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Receipt Ter

Receipt pH

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Received By; Date/Time;

Cooler Custoay.Se(r i—-. ,

Present / lôt P r e s e n t , - ^

Intact/Not Intact Vetsion 4.0; 07/03

(Please Print Legibly)

Company Name: / ^ ' ^ W v 4 \ > - t . > , u v < . ^ T c L ^ - , » ] a ^ V

Branch or Locat ion :^ & U ^ i * ^ / ^ ' - * - , \ ^ ' ^

Project Contact:

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Project Number;

Projeci Name:

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Data Package Options - (please circle if requested)



EPA Level IM (Subject lo Surcharge)


LABORATORY ID (Lab Use Only) FIELD ID

Regulalory Pmqram

UST RCRA SOWA NPDES

CERCLA

EN CHEM INC.

3 1241 Bellevue St., Suite 9 Green Bay, WI 54302

920-469-2436 Fax 920-469-8827

/ L ^ /

i lry for lite t'liviroiiweiif. 1_ Z .

CHAIN OF CUSTODY N? 130 184 'PreserDalion Codes

A=None B=HCL C=H2S04 D=HN03 E=EnCore F=Melh3nol H=So(lium Bisulfate Solution l-Sodium Thiosullale J=Dther

FILTERED? (YES/NO) / ^

PRESERVATION (CODE)-

G^NaOH

Quote #:

Mail Report To: WoVc... Cu.y.w

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LAB COMMENTS (Lab Use Only)

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^ ^ ' g / * Olie P - ^ o ^ T h ^ h t ^

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i^7% Rush Turnaround Time Requested (TAT) - Prelim


Date Needed: ^ ' R

Transmit Prelim Rush Results by (circle):

Phone Fax E-Mail

Phone #:

Fax »:

E-Mail Address:

Samples on HOLD are subject to special pr ic ing and release of l iabil i ty

. Dale/ l ime: ^_^

elinquished By:

RelinquishecfBy:

Date/Time:

Dale/Time;

Relinquished By; Date/Time:

Relinquished By: Dale/Time:

Received By; Dale/Time:

Received By;

Received By:

Dale/Time;

Dale/Time:

En Chem Projeci No.

Sample Receipt Temp.

Sample Receipt pH (WeVMelalsJ. J ^

Cooler Cusj j

Present / Not Present

Intact / Not Intact Version fl.O: 07/03

ace Analytical m\SE\) 1241 Bellevue Street, Suite 9 Green Bay, Wl 54302

920-469-2436, Fax: 920-469-8827


Client: NATUFtAL RESOURCE TECHNOLOGY

Project Name: WPSC - MARINETTE


Lab Contact: Tom Trainor

Lab Sample Number

858276-001

858276-002

858276-003

858276-004

858276-005

858276-006

858276-007

858276-008

858276-009

858276-010

858276-011

858276-012

858276-013

858276-014

858276-015

858276-016

858276-017

858276-018

858276-019

Field ID

MW-302

MW-303

MW-304

MW-305

MW-306

MW-307R

MW-308

MW-310

MW-1

MW-311

MW-3R

MW-5

P-302

P-303

P-304

P-305

QC-1

QC-2

TRIP BLANK

Collection Matrix Date

WATER 04/14/05

WATER 04/14/05

WATER 04/14/05

WATER 04/14/05

WATER 04/13/05

WATER 04/13/05

WATER 04/13/05

WATER 04/13/05

WATER 04/13/05

WATER 04/13/05

WATER 04/14/05

WATER 04/14/05

WATER 04/14/05

WATER 04/14/05

WATER 04/14/05

WATER 04/14/05

WATER

WATER

WATER 04/13/05

I certify that the data contained in this Final Report has been generated and reviewed in accordance with approved methods and Laboratory Standard Operating Procedure. Exceptions, If any, are discussed in the accompanying sample comments. Release of this fmal report is authorized by Laboratory management, as is verified by the following signature. This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. The sample results relate only to the analytes of interest tested.

( ^ ^>v^^

Approval Signature

/ l / b l ^ t y ^ I'J-'or-Date


Client: NATURAL RESOURCE TECHNOLOGY



1241 Bellevue Street Green Bay, Wl 54302 920^69-2436


Report Date : 04/29/05 Field ID :

INORGANICS

Test

MW-302



Code Anl Date Prep Method An l Method

Iron - Dissolved


Alkalinity as CaC03


Sulfate

1100

160

380

< 0.061

160

17

0.14

6.3

0.061

4.2

55

0.48

21

0.20

14

1

1

1

1

5

ug/L

ug/L

mg/L

mg/L

mg/L

04/23/05

04/23/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW856 6010B

SW856 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 04/19/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i p


< <

< < < <

0.39

0.40

4.9

0.57

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0,46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

Q

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 50308

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

P A H / PNA

Analyte

Result

40

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Units

ug/L

Units

Code Anl Date

04/25/05

Code Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< 0.40

< 0.45

0.40

1.2

0.96

2.5

3.0

2.3

2.0

1.9

1.9

0.62

3.5

< 0.44

1.8

< 0.45

1.2

3.0

0

0

0

0 4 0

0.45

0.39

0.39

0.35

0.39

0.36

0.36

0.41

0.39

0.33

0.44

0.33

0.44

0.34

0.45

0.41

0.33

1.3

1.5

1.3

1.3

1.2

1.3

1.2

1.2

1.4

1.3

1.1

1.5

1.1

1.5

1.1

1.5

1.4

1.1

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q

Q

Q

Q

Q

D

D

D

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

04/27/05

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

8270C-SIM

e270C-SIM

8270C-SIM

8270C-SIM

a270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Cl ient : NATURAL RESOURCE TECHNOLOGY




Matrix Type : WATER



Fie ld ID

I N O R G A N I C S

Test

MW-303

Result LOD LOQ EQL DIL Units



Iron - Dissolved


Alkalinity as CaC03


Sulfate

8300

920

400

0.43

67

17

0.14

6.3

0.061

0.83

55

0.48

21

0.20

2.8

ug/L

ug/L

mg/L

mg/L

mg/L

04/23/05

04/23/05

04/25/05

04/18/05

04/18/05

SW846 6O10B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW856 6010B

SW856 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 04/19/05


1,2,4-Thmethylbenzene


Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< <

< < < <

0.39

0:40

1.5

0.53

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

Q

04/19/05

04/19/05

04/19/05

04/19705

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 MB021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

PAH/ P N A

Analyte

Result

480

Result

LOD

LOD

LOQ

LOQ

EQL

50

EQL

Dil .

5

DiL

Units

ug/L

Units

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene Dibenz(a,h)anthracene

Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

0.053

0.058

0.26

0.068

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.017

0.022

0.017

0.18

0.020

0.020

45

51

80

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0,022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q 04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/06

SW846 3510C

SW846 3510C

SW846 3510C

SW845 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW845 3510C

SW846 35IOC

SW846 3510C

SW845 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

a270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM





Field ID : MW-304


Matrix Type : WATER




INORGANICS

Test

Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 ^ N02

Sulfate

Result LOD LOQ EQL Dil. Units Code Anl Date Prep Method Anl Method

280

320

490

0.58

630

17

0.14

6.3

0.061

8.3

55

0.48

21

0.20

28

ug/L

ug/L

mg/L

mg/L

0 mg/L

04/23/05

04/23/05

04/25/05

04/18/05

04/18/05

SW846 6010B SW856 6010B

SW846 601 OB SW856 601 OB

EPA 310.2 EPA 310.2

EPA 353.2 EPA 353.2

EPA 300.0 EPA 300.0

PVOC

Analyte



Benzene

Ethylbenzene


Toluene

Xylene, o Xylenes, m -i- p


PAH/ PNA

Analyte

Result LOD LOQ EQL Dil. Unite Code Anl Date

Prep Date: 04/19/05


e <

e <

< < < < <

0.39

0.40

1.1

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 MB021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

Result

< 10

LOD LOQ EQL

10

Dil.

1

Unite

ug/L

Code Anl Date

04/25/05

Prep Date: 04/25/05


SW846M8015 SW845M8015

Result LOD LOQ EQL Dll. Unite Code Anl Date

Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

0.12

< 0.023

< 0.019

< 0.019

0.027

0.020

0.023

0.036

0.026

0.028

0.025

< 0.022

0.041

< 0.022

0.021

0.060

< 0.020

0.031

64

52

83

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q

Q

Q

Q

Q

Q

Q

0

Q

Q

Q

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


C l ien t : NATURAL RESOURCE TECHNOLOGY




Matrix Type : WATER



Field ID :

INORGANICS

Test

MW-305




Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

61

8.1

260

6.6

47

17

0.14

6.3

0.31

0.83

55

0.48

21

1.0

2.8

1 ug/L

1 ug/L

1 mg/L

5 mg/L

1 mg/L

04/23/05 SW846 6010B SW856 6010B

04/23/05 SW846 6010B SW856 6010B

04/25/05 EPA 310.2 EPA 310.2

04/18/05 EPA 353.2 EPA 353.2

04/18/05 EPA 300.0 EPA 300.0

P V O C

Analyte

1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene

Dibenz(a.h)anthracene

Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nltrobenzen6-d5

2-Fluorobiphenyl

Terphenyl-d14


Prep Date: 04/19/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< < < < < < < <

0,39

0,40

0.14

0.40

0.36

0.36

0.36

0.74

104

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46 ~

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 50306

SW846M8021

SW846M8021

SW846M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

P A H / PNA

Analyte

Result

< 10

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

DIL

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


0.025

0.036

0.019

0.35

0.098

0.24

0.20

0.24

0.24

0.21

0.21

0.071

0.21

0.022

0.19

0.098

0.10

0.32

66

60

76

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q 04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 3610C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW848 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW845 351 OC

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

B270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

a270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


C l ien t : NATUFIAL RESOURCE TECHNOLOGY




Matrix Type : WATER



Field ID :

I N O R G A N I C S

Test

MW-306

Result LOD LOQ EQL Dil. Unite



Iron -Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

4500

650

380

< 0.061

100

17

0.14

32

0.061

4.2

55

0.48

110

0.20

14

1

1

5

1

5

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte Result LOD LOQ EQL Dll. Unite Code Anl Date

Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i- p


300

75

< 0.34

350

< 0.90

13

300

390

104

0.98

0.99

0.34

1.0

0.90

0.89

0.90

1.9

3.3

3.3

1.1

3.3

3.0

3.0

3.0

6.2

2.5

2.5

2.5

2.5

2.5

2.5

2.5

2.5

1

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846M8021

SW846 M8021

SW846 M8021

M E T H A N E

Analyte

Methane

P A H / PNA

Analyte

Result

110

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

7.4

0.46

0.67

0.082

0.022

< 0.020

< 0.018

< 0.018

< 0.021

< 0.019

< 0.017

< 0.022

0.12

0.17

< 0.017

410

0.050 •

0.23

89

65

71

0.020

0.023

0.020

0.020

0.018

0.020

0.018

0.018

0.021

0.019

0.017

0.022

0.017

0.022

0.017

45

0.021

0.016

0.067

0.076

0.065

0.065

0.059

0.066

0.061

0.060

0.069

0.065

0.055

0.074

0.055

0.073

0.057

150 ;

0.069

0.055

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

?000 ug/L

ug/L

ug/L

%Recov

%Recov

% Recov

E

E

Q

D

Q

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/20/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 35IOC

SW846 3510C

8270C-SIM

8270C-SIIVI

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client: NATURAL RESOURCE TECHNOLOGY Project Name ; WPSC - MARINETTE



Matrix Type: WATER

Collection Date: 04/13/05 Report Date: 04/29/05

Field ID :

INORGANICS

Test

MW-307R

Result LOD LOQ EQL Dil . Unite



Iron - Dissolved


Alkalinity as CaC03


Sulfate

28000

2900

710

< 0.061

12

17

0.14

32

0.061

0.83

55

0.48

110

0.20

2.8

1

1

5

1

1

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/16/05

04/18/05

SW846 60108

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 601 OB

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL Dil. Unite Code Anl Date

Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m •»- p


< <

< < < < <

0.39

0.40

0.57

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0 4 0

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5O30B

SW846 5O30B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

P A H / P N A

Analyte

Result

4200

Result

LOD

LOD

LOQ

LOQ

EQL

250

EQL

Dil .

25

Dil .

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW845M8015 SW846M8015

Prep Date: 04/18/05



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene

lndeno( 1,2,3-cd)pyrene

Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

2.1

< 0.23

3.4

< 0.20

0.55

< 0.20

< 0.18

< 0.18

< 0.21

< 0:19

< 0.17

< 0.22

0.53

0.90

< 0.17

0.48

1.1

0.51

0.0

0.0

0.0

0.20

0.23

0.20

0.20

0.18

0.20

0.18

0.18

0.21

0.19

0.17

0.22

0.17

0.22

0.17

0.23

0.21

0.16

0.67

0.76

0.65

0.65

0.59

0.66

0.61

0.60

0.69

0.65

0.55

0.74

0.55

0.73

0.57

0.75

0.69

0.55

10 10

10

10

10

10

10

10

10

10

10

10

10

10

10

10

10

10

10

10

10

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q

Q

Q

Q

D

D

D

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SWB46 351 OC

SWB46 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8Z70C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-S1M

8270C-SIM

8270C-SIM


C l ien t : NATURAL FIESOURCE TECHNOLOGY




Matrix Type : WATER



Field ID :

INORGANICS

Test

MW-308




Iron - Dissolved


Alkalinity as CaC03

Nitrogen,.N03 + N02

Sulfate

350 17

1500 0.14

540 32

< 0.061 O.061

14 0.83

55

0.48

110

0.20

2.8

1 ug/L

1 ug/L

5 mg/L

1 mg/L

1 mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0 •

PVOC

Analyte Result LOD LOQ EQL Dil . Unite Code Anl Date

Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene

Benzo(b)nuoranthene

Benzo(ghi) perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

1.4 0.39

< 0.40 0.40

0.33 0.14

0.71 0.40

< 0.36 0.36

< 0.36 0.36

0.76 0.36

< 0.74 0.74

102

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

Q 04/20/05

Q 04/20/05

04/20/05

04/20/05

Q 04/20/05

04/20/05

04/20/05

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

5030B

5030B

5030B

5030B

5030B

5030B

5030B

5030B

5030B

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

M8021

M8021

M8021

M8021

M8021

M8021

M8021

M8021

M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

660

Result

LOD

LOD

LOQ

LOQ

EQL

50

EQL

Dil.

5

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846 M8015

Prep Date: 04/18/05


21

2.3

19

2.3

2.0

2.0

1.8

1.8

2.1

2.0

1.7

2.2

1.7

2.2

1.7

12

3.7

1.7

0

0

0

2.0

2.3

2.0

2.0

1.8

2.0

1.8

1.8

2.1

2.0

1.7

2.2

1.7

2.2

1.7

2.3

2.1

1.7

6.8

7.7

6.6

6.6

6.0

6.7

6.2

6.1

7.0

6.6

5.6

7.5

5.6

7.4

5.8

7.6

6.9

5.5

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

04/20/05

04/20/05

04/20/05

Q 04/20/05

Q 04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

Q 04/20/05

04/20/05

D 04/20/05

D 04/20/05

D 04/20/05

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 35IOC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 35IOC

SW846 35IOC

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SII\/1

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client: NATURAL RESOURCE TECHNOLOGY Project Name : WPSC - MARINETTE


Field ID: MW-310





INORGANICS

Test Result LOD LOQ EQL Dil. Unite Code Anl Date Prep Method Anl Method

Iron - Dissolved Manganese - Dissolved Alkalinity as CaC03 Nitrogen, N03 + N02 Sulfate

21000

1500

370

0.061 32

17 0.14 32 0.061

0.83

55

0.48

110 0.20 2.8

ug/L ug/L mg/L mg/L mg/L

04/27/05 04/27/05 04/25/05 04/18/05 04/18/05

SW846 6010B SW846 6010B EPA 310.2 EPA 353.2 EPA 300.0

SW846 6010B SW846 6010B EPA 310.2 EPA 353.2 EPA 300.0

PVOC


Prep Date: 04/20/05


1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene

Benzene Ethylbenzene Methyl-tert-butyl-ether

Toluene Xylene, o Xylenes, m + p a,a,a-Trifluorotoluene

< < < < < < < <

0.39 0.40 0.14

0.40 0.36 0.36 0.36 0.74 103

0.39 0.40 0.14 0.40

0.36 0.36 0.36 0.74

1.3 1.3

0.46 1.3 1.2 1.2 1.2 2.5

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

% Recov

04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05

SW846 5030B SW846 5030B

SW846 5030B SW846 5030B SW846 5030B

SW846 5030B SW846 5030B SW846 5030B SW846 5030B

SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

34

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


1 -Methylnaphthalene 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene

Benzo(a)pyrene Benzo(b)fluoranthene Benzo(ghi)perylene

Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene lndeno(1,2,3-cd)pyrene

Naphthalene Phenanthrene Pyrene Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14

3.4

0.46

5.3

0.39

1.3

0.40

0.37

0.36

0.42

0.39

0.33

0.44

0.41

1.6

0.34

3.7

2.8

046

0

0

0

0.40

0.46

0.39

0.39

0.36

0.40

0.37

0.36

0.42

0.39

0.33

0.44

0.33

0.44

0.34

0.45

0.41

0.33

1.3

1.5

1.3

1.3

1.2

1.3

1.2

1.2

1.4

1.3

1.1

1.5

1.1

1.5

1.1

1.5

1.4

1.1

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

ug/L ug/L

ug/L ug/L ug/L

ug/L ug/L ug/L ug/L ug/L

ug/L ug/L ug/L ug/L ug/L ug/L

ug/L ug/L %Recov %Recov %Recov

04/19/05 04/19/05

04/19/05 04/19/05 04/19/05 04/19/05 04/19/05 04/19/05 04/19/05

04/19/05

04/19/05

04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

O 04/19/05

D 04/19/05

D 04/19/05

D 04/19/05

SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW845 3510C SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C

8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM B270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-S1M 8270C-SIM

En Chem Analytical Report Number: 858276 A Division of Pace Analytical Sen/ices, Inc.

C l i e n t : NATURAL RESOURCE TECHNOLOGY



Field ID : MW-1


Matrix Type : WATER




I N O R G A N I C S


Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

12000

1300

540

0.061

20

17

0.14

32

0.061

0.83

55

0.48

110

0.20

2.8

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW346 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 60108

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C


Prep Date; 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m • p



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SWB46 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

5300

Result

LOD

LOD

LOQ

LOQ

EQL

500

EQL

Dil.

50

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


0.020

0.023

0.042

0.020

0.018

0.020

0.018

0.018

0.021

0.020

0.017

0.022

' 0.017

0.022

0.017

0.055

0.021

0.017

84

65

84

0.020

0.023

0.020

0.020

0.018

0.020

0.018

0.018

0.021

0.020

0.017

0.022

0.017

0.022

0.017

0.023

0.021

0.017

0.068

0.077

0.066

0.066

0.060

0.067

0.062

0.061

0.070

0.066

0.056

0.075

0.056

0.074

0.058

0.076

0.059

0.055

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

04/19/05

04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

Q 04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SWB46

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

35 IOC

351 OC

3510C

351 OC

351 OC

351 OC

351 OC

351 OC

351 OC

351 OC

35 IOC

351 OC

351 OC

351 OC

351 OC

351 OC

351 OC

351 OC

351 OC

3510C

3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIIVI

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIIVI

8270C-SIM

Pace Analytical Services, Inc.




Project Number: 1549 REVISED


Matrix Type : WATER

Collection Date: 04/13/05


Field ID :

I N O R G A N I C S

Test

MW-311




Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N 0 3 -i- N02

Sulfate

2700

2700

690

< 0.061

28

17

0.14

32

0.051

0.83

55

0.48

110

0.20

2.8

1

1

5

1

1

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte Result LOD LOQ EQL DiL Unite Code Anl Date

Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


88

22

260

700

< 0.72

15

170

190

102

0.78

0.79

0.28

0.80

0.72

0.71

0.72

1.5

2.6

2.6

0.92

2.7

2.4

2.4

2.4

4.9

2

2

2

2

2

2

2

2 .

1

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5Q30B

SWB46 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

.SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

METHANE

Analyte

Methane

P A H / P N A

Analyte

Result

1200

Result

LOD

LOD

LOQ

LOQ

EQL

100

EQL

Dil .

10

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

An l Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene

Benzo(b)nuoranthene

Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

170

240

170

4.6

15

< 3.9

< 3.6

< 3.6

< 4.1

< 3.9

< 3.3

< 4.4

3.8

37

< 3.4

2000

33

5.1

0

0

0

160

4.5

160

3.9

3.5

3,9

3.6

3.6

4.1

3.9

3.3

4.4

3.3

4.4

3.4

180

4.1

3,3

530

15

520

13

12

13

12

12

14

13

11

15

11

15

11

600

14

11

8000

200

8000

200

200

200

200

200

200

200

200

200

200

200

200

8000

200

200

200

200

200

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

QD

E

QD

Q

Q

D

Q

D

D

D

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

B270C-SIM

B270C-SIM

8270C-SIIV!

8270C-S1M


C l ien t : NATURAL RESOURCE TECHNOLOGY




Matrix T y p e : WATER

Col lect ion Date : 04/13/05


Field ID :

INORGANICS

Test

MW-2R




Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

2700

2700

690

0.061

28

17

0.14

32

0.061

0.83

55

0.48

110

0.20

2.B

1 ug/L

1 ug/L

5 mg/L

1 mg/L

1 mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.O

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C


Prep Date: 04/20/05


1,2,4-Trimelhylben2ene


Benzene

Ethylbenzene

Methyl-tert-butyl-ethei

Toluene

Xylene, o Xylenes, m •<• p



2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nltrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

8B

22

260

700

< o:72

15

170

190

102

0.78

0.79

0.28

0.80

0.72

0.71

0.72

1.5

2.6

2.6

0.92

2.7

2.4

2.4

2.4

4.9

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846M8021

SW846 M8021

SW846MB021

SW845 M8021

SW846 M8021

SW846M8021

SW846 MB021

SW846M8021

METHANE

Analyte

Methane

PAH/PNA

Analyte

Result

1200

Result

LOD

LOD

LOQ

LOQ

EQL

100

EQL

Dil.

10

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


170

240

170

4.6

15

< 3.9

< 3.6

< 3.6

< 4.1

< 3.9

< 3.3

< 4.4

3.8

37

160

4.5

160

3.9

3.5

3.9

3.6

3.6

4.1

3.9

3.3

4 4

3.3

4.4

< 3.4 3.4

2000 180

33 4.1

5.1 3.3

0

0

0

530

15

520

13

12

13

12

12

14

13

11

15

11

15

11

600

14

11

8000

200

8000

200

200

200

200

200

200

200

200

200

200

200

200

8000

200

200

200

200

200

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov %Recov

QD

E

QD

Q

Q

D

D

D

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 3510C

SW846 35IOC

SW846 35IOC

SWB46 3510C

SWB46 3510C

SWB46 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

B270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM


Client: NATURAL RESOURCE TECHNOLOGY Project Name : WPSC - MARINETTE





Field ID :

INORGANICS

Test

MW-3R




Iron - Dissolved Manganese - Dissolved Alkalinity as CaC03 Nitrogen, N03 + N02 Sulfate

17

21

400

6.4

280

17

0.14

6.3

0.31

8.3

55

0.48

21

1.0

28

1

1

1

5

10

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846e010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte

1 -Methylnaphthalene 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(ghi)perylene Ben2o(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene lndeno(1,2,3-cd)pyrene Naphthalene Phenanthrene

Pyrene Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14


Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1-2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

< 10

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Unite

ug/L

Unite

Code

Code

Anl Date

04/25/05

Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


0.020 0.023 0.019

0.019 0.018 0.020 0.018

0.018 0.021 0.019 0.016

0,022

0.016 0.022 0.017

0.022

0.020

0.016 87 66

98

0.020 0.023 0.019 0.019 0.018 0.020 0.018 0.018 0.021 0.019 0.016 0.022 0.016 0.022 0.017 0.022 0.020 0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

ug/L ug/L ug/L

ug/L ug/L

ug/L ug/L ug/L %Recov %Recov %Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SWB46 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C

8270C-S1M 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-S1M 8270C-S;M

8270C-S1M 8270C-S1M 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM





Field ID : MW-5


Matrix Type: WATER




INORGANICS


Iron - Dissolved


Alkalinity as CaC03

Nitrogen, N03 + N02

Sulfate

< 17

420

300

2.9

38

17

0.14

6.3

0.061

0.83

55

0.48

21

0.20

2.8

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 601 OB

SW846 601 OB

EPA 310.2

EPA 353.2

EPA 300.0

PVOC

Analyte

PAH/ PNA

Analyte


Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i- p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

D.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

Resul t

< 10

LOD LOQ EQL

10

Dil.

1

Unite

ug/L

Code Anl Date

04/25/05

Prep Date: 04/25/05


SW846M8015 SW846M8015


Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < < < < < < < < < < < < < < <

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.01 B

0.022

0.016

0.022

0.017

0.022

0.020

0.016

64

52

87

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 351 OC

SW846 35IOC

SW846 35IOC

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIIV1

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M


C l i e n t : NATURAL RESOURCE TECHNOLOGY



Fie ld ID : P-302


Matrix Type : WATER




INORGANICS


Iron - Dissolved


Alkalinity as CaC03


Sulfate

6300

230

250

< 0.061

30

17

0.14

6.3

0.061

0.83

55

0.48

21

0.20

2.8

ug/L

ug/L

mg/L

mg/L

mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.O

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte Result LOD LOQ EQL Di l . Unite Code Anl Date

Prep Date: 04/20/05

Prep Methtod Anl Method



Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -t p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

1 ug/L

1 ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

PAH/ PNA

Analyte

Result

17

Result

LOD

LOD

LOQ

LOQ

EQL

10

EQL

Dil.

1

Dil.

Unite

ug/L

Unite

Code Anl Date

04/25/05

Code Anl Date

Prep Date: 04/25/05


SW846M8015 SW846M8015

Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-dS

2-Fluorobiphenyl

Terphenyl-d14

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

90

70

95

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0073

0,055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L .

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

SW846

35 IOC

3510C

351 OC

3510C

3510C

351 OC

35 IOC

3510C

3510C

35 IOC

35 IOC

35 IOC

35 IOC

3510C

351 OC

35 IOC

3510C

351 OC

3510C

351 OC

3510C

e270C-SIIVI

8270C-SIM

8270C-SIM

8270C-SIM

S 2 7 0 C - S ; M

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8276C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIIW

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M


C l i en t : NATUFWL RESOURCE TECHNOLOGY




Matrix Type : WATER

Col lect ion Date : 04/14/05


Field ID :

INORGANICS

Test

P-303




Iron - Dissolved


Alkalinity as CaC03


Sulfate

33

34

190

0.18

680

17

0.14

6.3

0.061

17

55

0.48

21

0.20

56 "

1

1

1

1

20

ug/L

ug/L

mg/L

mg/L

mg/L

Q

Q

04/27/05

04/27/05

04/25/05

04/18/05

04/18/05

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

P V O C

Analyte

P A H / P N A

Analyte


Prep Date: 04/20/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m • p


< < < < < < < <

0,39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

103

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1-2 .

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

1 ug/L

ug/L

%Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SWB46 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte

Methane

Result

< 10

LOD LOQ EQL

10

Dil .

1

Unite

ug/L

Code Anl Date

04/25/05

Prep Date: 04/25/05


SW846M8015 SW846M8015


Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < < < < < < < < <

< < < <

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.027

0.022

0.017

0.022

0.020

0.027

95

69

93

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

ug/L Q 04/19/05

ug/L

ug/L

ug/L

ug/L

04/19/05

04/19/05

04/19/05

04/19/05

ug/L Q 04/19/05

%Recov

%Recov

%Recov

04/19/05

04/19/05

04/19/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 35IOC

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIWI

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIIV1

8270C-SIM




Project Name : WPSC Project Number: 1549

Field ID: P-304

PVOC

Analyte

1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene

Benzene Ethylbenzene Methyl-tert-butyl-ether

Toluene Xylene, o Xylenes, m • p a,a,a-Trifluorotoluene

PAH/ PNA

Analyte

1-Methylnaphthalene

2-Methylnaphthalene Acenaphthene Acenaphthylene

Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(ghi)perylene Benzo(k)fluoranthene

Chrysene Dibenz(a,h)anthracene

Fluoranthene Fluorene lndeno(1,2,3-cd)pyrene

Naphthalene Phenanthrene Pyrene Nitrobenzene-d5 2-Fluorobiphenyl

Terphenyl-d14

- MARINE 1 1 b

< < < < < < < <

< < < < < < < < < < < < < < < < < <

Result

0.39 0.40 0.14

0.40

0.36

o:36

0.36

0.74

104

Result

0.15

0.17

0.15

0.15

0.13

0.15

0.14

0.14

0.16

0.15

0.12

0.17

0.12

0.16

0.13

0.17

0.15

0.12

94

51

88

LOD

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

LOD

0.15

0.17

0.15

0.15

0.13

0.15

0.14

0.14

0.16

0.15

0.12

0.17

0.12

0.16

0.13

0.17

0.15

0.12

LOQ EQL Dil.

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

LOQ EQL Dil.

0.50

0.57

0.49

0.49

0.45

0.49

0.46

0.45

0.52

0.49

0.41

0.56

0.42

0.55

0.43

0.56

0.51

0.41

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

1241 Bellevue Street Green Bay, Wl 64302 920469-2436

Matrix Type: WATER

Collection Date : 04/14/05 Report Date: 04/29/05

Lab Sample

Unite Code

ug/L ug/L ug/L ug/L ug/L ug/L ug/L

ug/L %Recov

Unite Code

ug/L

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L %Recov

%Recov %Recov

Anl Date

04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/06 04/20/05

Anl Date

04/20/05

04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05 04/20/05

04/20/05 04/20/05 04/20/05 04/20/05

.04/20/05 04/20/05 04/20/05

fûmber: 858276-015

Prep Date: 04/20/05

Prep Method

SW846 5030B

SW846 5030B SW846 5030B SW846 5030B SW846 5030B SW846 5030B SW845 5030B SW846 5030B SW846 5030B

Anl Method

SW846 M8021 SW846M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846M8021 SW846 M8021 SW846 M8021 SW846 M8021

Prep Date: 04/18/05

Prep Method

SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW845 351 OC SW846 3510C SW846 3510C SW846 351 OC SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 3510C SW846 351 OC SW846 3510C

Anl Method

8270C-SIM 8270C-SIM 8270C-SIM 8270C-S1M 8270C-S1M 8270C-S1M 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM 8270C-SIM

8270C-SIM 8270C-SIM e270C-SIM 8270C-SIM 8270C-S1M 8270C-S1M

8270C-SIM 8270C-SIM

8270C-SIM 8270C-S1M





Field ID : P-305


Matrix Type: WATER




INORGANICS


Iron - Dissolved


Alkalinity, as CaC03

Nitrogen, N03 + N02

Sulfate

6200

1800

690

0,11

150

17

0.14

32

0.061

4.2

55

048

110

0.20

14

1 ug/L

1 ug/L

5 . mg/L

1 mg/L

5 mg/L

04/27/05

04/27/05

04/25/05

04/18/05

04/19/05

SW846 6010B

SW846 6Q10B

EPA 310.2

EPA 353.2

EPA 300.0

SW846 6010B

SW846 6010B

EPA 310.2

EPA 353.2

EPA 300.0

PVOC


Prep Date: 04/19/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

101

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.45

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

METHANE

Analyte Result LOD LOQ EQL Dil. Unite

Prep Date: 04/25/05


Methane 54 10 ug/L 04/25/05 SW846M8015 SW846M8015

PAH/ PNA


Prep Date: 04/18/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

< < < < < < < < < < < <

< <

< <

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.016

0.021

0.019

0.016

0.022

0.018

0.022

0.017

0.026

0.020

0.016

102

78

84

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.064

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

1 ug/L

1 ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

ug/L Q 04/19/05

ug/L

ug/L

04/19/05

04/19/05

ug/L Q 04/19/05

ug/L

ug/L

%Recov

%Recov

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-SIM

8270C-SIM

B270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM





Field ID: QC-1


Matrix Type : WATER

Collection Date :



PVOC


Prep Date: 04/19/05



1,3,5-Trimethylbenzere

Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m + p


< <

< < < < <

0.39

0.40

0.80

0.40

0.36

0.36

0.36

0.74

100

0.39

0.40

0.14

040

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.6

1 ug/L

ug/L

t ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846M8021

PAH/ PNA


Prep Date: 04/19/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghi)perylene


Chrysene

Dibenz(a.h)anthracene

Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nitrobenzene-d5

2-Fluorobiphenyl

Terphenyl-d14

3.0

< 0.45

5.5

< 0.39

1-2

< 0.39

< 0.36

< 0.36

< 0.41

< 0.39

< 0.33

< 0.44

0.56

1.2

< 0.34

0.55

2.1

0.59

0

0

0

0.40

0.45

0.39

0.39

0.35

0.39

0.36

0.36

0.41

0.39

0.33

0.44

0.33

0.44

0.34

0.45

041

0.33

1.3

1.5

1.3

1.3

1.2

1.3

1.2

1.2

14

1.3

1.1

1.5

1.1

1.5

1.1

1.5

14

1.1

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

%Recov

%Recov

Q

Q

Q

Q

D

D

D

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/06

04/20/05

04/20/05

04/20/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-S1M

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM





Field ID : QC-2


Matrix Type : WATER

Collection Date :


Lab Sample Number : B58276-018

PVOC


Prep Date: 04/19/05




Benzene

Ethylbenzene


Toluene

Xylene, o

Xylenes, m -i- p


< < < < < < < <

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

100

0.39

0.40

0.14

0.40

0.36

0.36

0.36

0.74

1.3

1.3

0.46

1.3

1.2

1.2

1.2

2.5

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

%Recov

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

04/19/05

SW846 5O30B

SW846 5O30B

SW846 5O30B

SW846 5030B

SW846 5030B

SW846 5O30B

SW846 5030B

SW846 5O30B

SW846 5030B

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

SW846 M8021

PAH/ PNA


Prep Date: 04/19/05


1-Methylnaphthalene

2-Methylnaphthalene

Acenaphthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene


Benzo(ghl)perylene


Chrysene


Fluoranthene

Fluorene


Naphthalene

Phenanthrene

Pyrene

Nltrobenzene-d5

2-Fluorobiphenyl

Terpheriyl-d14

< < < < < < < < < < < < < < <

< <

0,020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.034

0.020

0.016

106

79

106

0.020

0.023

0.019

0.019

0.018

0.020

0.018

0.018

0.021

0.019

0.016

0.022

0.016

0.022

0.017

0.022

0.020

0.016

0.066

0.076

0.065

0.064

0.059

0.065

0.060

0.060

0.069

0.054

0.055

0.073

0.055

0.073

0.057

0.075

0.068

0.054

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

ug/L Q 04/20/05

ug/L

ug/L

%Recov

%Recov

% Recov

04/20/05

04/20/05

04/20/05

04/20/05

04/20/05

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 3510C

SW846 35IOC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 3510C

SW846 3510C

SW846 351 OC

SW846 35IOC

SW846 3510C

SW846 351 OC

SW846 3510C

SW846 3510C

SW846 35IOC

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-SIM

8270C-S1M

8270C-S1M

8270C-S1M

8270C-SIM


Analytical Report


Project Name: WPSC Project Number: 1549

MARINbl I t

Field ID: TRIP BLANK

PVOC

Analyte

1,2,4-Trimethylbenzene 1,3.5-Trimethylbenzene Benzene

Ethylbenzene Methyl-tert-butyl-ether Toluene

Xylene, o Xylenes, m + p a,a,a-Trifluorotoluene

< < < < < < < <

Result

0.39 0.40 0,14

0.40 0.36 0.36 0.36 0.74

101

LOD

0.39 0.40 0.14

0.40 0.36 0.36 0.36 0.74

LOQ

1.3 1.3

0.46 1.3 1.2 1.2 1.2 2.5

EQL

Number: 858276 1241 Bellevue Street Green Bay, Wl 54302 920-469-2436

Matrix Type: WATER Collection Date : 04/13/05

Report Date: 04/29/05 Lab Sample Number: 858276-019

3il. Unite Code Anl Date

ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05

ug/L 04/19/05 ug/L 04/19/05 ug/L 04/19/05 %Recov 04/19/05

Prep Date: 04/19/05

Prep Method

SW846 5030B SW846 5030B SW846 5030B SW846 5030B SW846 503OB SW846 5030B SW846 5030B SW846 5030B

SW846 5030B

Anl Method

SW846 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW346 M8021 SW846 M8021 SW846 M8021 SW846 M8021 SW846 MB021

B

B

C

D

E

Inorganic

Organic

All

All

Inorganic

Qualifier Codes Flag Applies To Explanation ' A Inorganic Analyte is detected in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally,

method blank acceptance may be based on project specific criteria or detemnined from analyte concentrations in the sample and are evaluated on a sample by sample basis.


Analyte is present in the method blank. Method blank criteria is evaluated to the laboratory method detection limit. Additionally, method blank acceptance may be based on project specific criteria or determined from analyte concentrations in the sample and are evaluated on a sample by sample basis.

Elevated detection limit.

Analyte value from diluted analysis or surrogate result not applicable due to sample dilution.

Estimated concentration due to matrix interferences. During the metals analysis the serial dilution failed to meet the established control limits of 0-10%. The sample concentration is greater than 50 times the IDL for analysis done on the ICP or 100 times the IDL for analysis done on the ICP-MS. The result was flagged with the E qualifier to indicate that a physical interi'erence was observed.

Analyte concentration exceeds calibration range.

Due to potential interferences for this analysis by Inductively Coupled Plasma techniques (SW-846 Method 6010), this analyte has been confirmed by and reported from an alternate method.

Surrogate results outside control criteria.

The result is estimated because the concentration is less than the lowest calibration standard concentration utilized in the initial calibration. The method detection limit is less than the reporting limit specified for this project.

Preservation, extraction or analysis performed past holding time.

This test is considered a field parameter, and the recommended holding time is 15 minutes from collection. The analysis was performed in the laboratory beyond the recommended holding time.

Concentration detected equal to or greater than the method detection limit but less than the reporting limit.

Sample received unpreserved. Sample was either preserved at the time of receipt or at the time of sample preparation.

Detection limit may be elevated due to the presence of an unrequested analyte.

Elevated detection limit due to low sample volume.

Sample pH was greater than 2

Spiked sample recovery not within control limits.

Sample received overweight.

The relative percent difference between the two columns for detected concentrations was greater than 40%.

The analyte has been detected between the limit of detection (LOD) and limit of quantitation (LOQ). The results are qualified due to the uncertainty of analyte concentrations within this range.

Organic The relative percent difference between quantitation and confirmation columns exceeds internal quality control criteria. Because the result is unconfirmed, it has been reported as a non-detect with an elevated detection limit.

Inadequate sample volume received to perform the method required MS/MSD.


Sample received with headspace.

A second aliquot of sample was analyzed from a container with headspace.

See Sample Narrative,

Laboratory Control Spike recovery not within control limits.

Precision not within control limits.


Dissolved analyte or filtered analyte greater than total analyte: analyses passed QC based on precision criteria.

Dissolved analyte or filtered analyte greater than total analyte: analyses failed QC based on precision criteria.

BOD result is estimated due to the BOD blank exceeding the allowable oxygen depletion.

BOD duplicate precision not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.

BOD result is estimated due to insufficient oxygen depletion. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.

BOD laboratory control sample not within control limits. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency. BOD result is estimated due to complete oxygen depletion. Due to the 48 hour holding time for this test, it is not practical to reanalyze and try to correct the deficiency.

E

F

F

G

H

HF

J

K

K

L

M

N

0

P

Q

Organic

Inorganic

Organic

All

All

Inorganic

All

Inorganic

Organic

All

Organic

All

Organic

Organic

All

T

U

V

W

X

& • < 1

2

3

4

5

6

7

All

All

All

All

All

All

All

All

Inorganic

Inorganic

Inorganic

Inorganic

Inorganic

Inorganic

Inorganic

En Chem Analysis Summary by Laboratory A Division of Pace Analytical Services, Inc.

1241 Bellevue Street Green Bay, Wl 54302

1090 Kennedy Avenue Kimberly, Wl 54136

Test Group Name

ALKALINITY AS CAC03

IRON - DISSOLVED

MANGANESE - DISSOLVED

METHANE

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PAH/PNA

PVOC

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G

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G

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0 0 cn 0 0 ro - J a> o

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0 0 cjy 0 0 r o

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G

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0 0 O l 0 0 r o

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G

G

G

G

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0 0 CJl 0 0 r o • v j cn

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G

G

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0 0 CJI OO ro ~ o

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G

G

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G

G

G

G

G

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Wisconsin Certificafion

G = En Chem Green Bay

K = En Chem Kimberly

S = En Chem Superior

C = Subcontracted Analysis

1 = Other Pace Lab Analysis

405132750 / DATCP: 105-444

445134030

Not Applicable

r.r-D'.-î / En Chem, Inc. Cooler Receipt Log

Batch N o . _ 2 ^ Z I I J = l _ _ Project Name or I p tAJ P S C - ' / l / l . X l r / V l X r t i g No. of Coolers: ^ Temps

A. Receipt Phase: Date cooler was opened: A ' l 5 > ' 0 ^ Bv: l\f)

1: Were samples received on ice? (Must be < 6 C ) ( ^ H ^ '^^^

2. Was there a Temperature Blank? YES / ' ^ ° ~ )

3: Were custody seals present and intact on cooler? (Record on COC) YES / ^ )

4: Are COC documents present? / ^ ^ J "^^^

5: Does this Project require quick tum around analysis? YES K ? ^

6: Is there any sub-work? : YES / f K ) \

7: Are there any short hold time tests? / * ^ ^ ^ ^ °

8: Are any samples nearing expiration of hold-time? (Within 2 days) YES' / ^

9: Do any samples need to be Filtered or Preserved in the lab? YES^

B. Check-in Phase: Date samples were Checked-in: n ] ! D ~ O Z P Bv: n r /

1: Were all sample containers listed on the COC received and intact? / f ^ ^'-'^

2: Sign the COC as received by En Chem. Completed .>ljiS} NO

3: Do sample labels match the COC? . V ^ NO^

4: Completed pH check on preserved samples f ^ ^ '^*-*

(This statement does not apply to water VOC, O&G, TOC, DRO, Total Rec. PhenoHcS)^^ 5: Do samples have correct chemical preservation? " ^ 3 NO^

(This statement does not apply to water VOC, O&G, TOC, DRO, Total Rec. P h e n o i i c s ^ 6: Are dissolved parameters field filtered? YES N O '

7: Are sample volumes adequate for tests requested? • / ' ^ ^ ^ ^ ^

8: Are VOC samples free of bubbles >6mm YgS/ NO^

9: Enter samples into logbook. Completed - r ^ ^ '*"^

10: Place laboratory sample number on all containers and COC. Completed / ^ § ^ ' ^ ^

11: Complete Laboratory Tracking Sheet (LTS). Completed YES NO

12: Start Nonconformance form YES NO

13: Initiate Subcontracting procedure. Completed j . YES NO

14: Check laboratory sample number on all containers and COC L X / ( i /O ' / Y E S ^ NO

Short Hold-t ime teste:


Rev . 2 /05/04, A t tachment to 1-REC-5. Subject to QA Audi t . Reviewed by/date

M i

NA

Contacted by/Who_

Contacted by/Who_

NA

NA

NA

NA

NA


48 Hours BOD Color Nitrite or Nitrate Ortho Phosphorus Surfactants Turbidity En Core Preservation Power stop preservation

7 days Ash

l-lashpoint Free Liquids Sulfide TDS TSS Total Solids TVS TVSS Unpreserved VOC's

Footnotes 1 Notify proper lab group immediately. 2 Complete nonconformance memo.

j - f 'j/irAr

p:/everyone/forms/samplereceiving/cri.doc

(Please Piifit Legibly) __ Company Name: ;VV^ i. i - • ' ! g^j.ov.^v' '- ' g c ' - • , . / " j " / r - -

Branch or Localion: \ ' ' ^ ^ - • - ^ ' - , L- | ,

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Project Number: I S ' ' ' '

Project Name:

Project State:

. , f ^ c - ^ , „ , , H.

U />

Sampled By (Print)

PO/f:

3,J/rs...\.,..^ v .j. , ri-'-^'-"

Data Package Options - (please circle if requested) Sample Results Only (no QC) EPA Level II (Subject to Surcharge) EPA Level III (Subject to Surcharge) EPA Level IV (Subject lo Surcharge)

LABORATORY 10 (Lal) IJse Oiily)' FIELD ID

Regulatory Prporam

UST RCRA SDWA NPDES CERCLA

y<' ^ J :HEM #

« ^ INC. ..chemistry for the environment.

J S J ^

,1S0 [XI 1241 Bellevue St . , Sui te 9 ~ Green Bay, WI 5 4 3 0 2

9 2 0 - 4 6 9 - 2 4 3 6 F a s 9 2 0 - 4 6 9 . 8 8 2 7

• 7 -

CHAIN OF CUSTODY Page_

I ":- 111133 Quote #:.

'Preservallon Codes A^None B^HCL C=H2S04 D=HN03 E EnCore H^Sodium BisuKalfl Solullon l-Sodium ThiosuKate JÔIher

' ' Mail Heport To: l l e l v , c c - ~ C ^ v . ) ' l \

' / FILTERED? (YES/NO) / T j ^ / ^ A " / ^ - / C / f t

PRESERVATION (CODE)' / f J / i ^ / f ^ / Y

Company: A ' C - U . V - - ' ^ ^'^'^ ' ^ ^ > - . -^" j ' '

/ A d d r e s s : ^ ' ^ - ^ t ' ^ ^ - ' < ' - - ' ^ 1 - ^ ^ . . ^ ^ - • ' - b

Matrix Codes

W^Water S=Soll A=Air

C=Charcaal B=Biola

Sl Sludge

COLLECTION DATE! TIME

MATRIX

W t J . . - ' i 1 1 \ ^ 1 . •S V o ?-">-

Company: A/ V T

1 ./ / I /

"- '.. ' \ X i j .J

' /

/ cHy Invoice To; ^ - ^ V. r ^ 1.

/ J ^ / X ) / Address:

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f... y.\^

-<^ CLIENT COMMENTS .LAB COMMENTS '(|.ati'Uieqn|y|-

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M i X >

i ^ . _DD l -Jc- , M i 6Z>ii -OS 3 oV. '/v:^?^ / i h lUl -i o l \K fe im. £vÛ_Ji f^ ^

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y

A /

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A

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y X %

BiaaWll2S)4tfô^î Mi^

- ^ ^ \ ? Rush Turnaround Time Requested (TAT) - Prelim


Date Needed: .. ^ ^

Rejlpt^yished By:' _j Date/Time:


Phone Fax E-Mail

Phone #:

F a x > : •.. -•

/

Rpii^&liit^d By; ^-^ V-^S^-

RelinqtiishM"Byl."-"

Dgte/Time:

Mai

E-Mail Address;

Relii1( uiShei

Samples on HOLD are subject to pial p r i c i n ^ n d release ot liability

Relinquished By:

^ J - t : ^

Date/Time;

I 9 ^ • ' \ Date/Time:

Date/Time:

Received By:

/ 2 -Reeeiyed By:

I Date/Time

Y y ( I A O . ^

lyi

V/ Date/Time

' /S>.f J rM'O Retiivea'Byi'' / T ' / Date/Time

R6 j^ ib fec rBy ! | l ' ^ ^ " * ^^ H Date/Time

Received By: Date/Time

En qheiii Proigct fjq

g3rp|3|e F|ecelpt Tefpp

âniplg Receipt pft

loojer Custpay Se Coojpr Cust^py Sâl

presepj / (Jpi Pr fs 'gpf^T?

iQtac) / Mo{ Intact '

^ ^ ^ g ^ ^ ^ _ ^ ^ ^ _ Vcr!^^^^7/03 ^ ^ ^ ^ ^ ^ ^ ^

(Please Print Legibly)

Company Name: Z ^ ' ' ^ ' ' ' ^ ' ^ ' ) X o ' ^ « . t , k . i . \ o ^ ; ^ )

Branch or Location: v.^-5;:

Project Contact: ^ - ^ - . " S ^ w ^ - ^ V i V '

Telephone: C U V T I "^ - - ^ \ Q " ^

Project Number: \ - ^ M ^ ^ ? ^ ^ ^ A n ^ ^ U c ^ V - ^ C

Project Name

Project Stale: V^ Sl

Sampled By (Print)

PO# :

:=>oJSV>^^\^^- ,'?î..'':i Tby'-V^N

Data Package Opt ions • (please circle il requested)



EPA Level ill (Subject to Surcharge)


UBORATORY ID (Lab Use Only)

_fl.ll M m m M

FIELD 10

P-1.0-X

?-^-> ? ^ t -T» t , ^ &.c.~]

Regulalory Pronram

UST RCRA SDWA NPDES

CERCLA

EM GHEM ••- • y I N C .

1 3 - 1241 BeUevue St., Suite 9 Green Bay, WI 54302

920-469-2436 Fax 920-469-8827

...citemistty for iht environment.

CHAIN OF CUSTODY N? 111134 •Preservation Codes

A:^None B=HCL C=H2S04 D=HN03 EÊnCore F=Metlianol H=Sodium Bisulfate Solullon hSoillum Tliiosulfale J=Olher

FILTERED? (YES/NO) / j ^ / / v " y p / < ^ / f J / ^

PRESERVATION (CODE)' / Q , / ^ / \ / >

G=HaOH

i ^ .o f • 2 . Page.

Quote #:

Ivlail Report To: I ? . L V - c.tC'v C^v . J .

Company:A^ A " " - " ^ K - > a < ^ ^ ' ^ T C - C U . Q I

A d d r e s s : ^ " ^ " ^ ' ^ ^ - ^ - ^ ^ • ' ^ ^ - ^ - • ^ \ >

Matrix CDdes

U/=lValer S=Soil AsAir

CsCharcoal B=Blota

SkSludge

COLLECTION

OATE

m/dL m mfM.

a< Tv>^ ^K .

TIME

ma

MATRIX

V/J -t A X. X--%-7<

A

i r j < -:2^

- ^

A

A ^

A

K

JL

? -X

K

- ^

X

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l-Ujukzir^, ^7.^KA1^"^. U H D M I ^

l l d O i V L l X f e

I 3

'3 fHI)Mf^" vT

w

Tt

Rush Turnaround Time Requested (TAT) - Prelim ^ 'Rpllnq

(Rush TAT subject to approval/surcharge) ' - ^

Date Needed:


Ptione Fax E-Mail

Phone #:

Fax #:

E-Mail Address:

^ Date/Time Date/Time:

S\\j^Q> TJaTe/Time

i Date/Time:

Date/Time: A-\^-m \50[)

Date/Time:

Samples on HOLD are subject to special pr ic ing and release of l iabil i ty

Relinquished By: Date/Time: Date/Time:

En Chem Project No.

Sample Receipt Temp.

Eoi Sample Receipt pH (WeVMutals) ft 1 /

Cooler Custody Seal

Pr"T"n*TTJrit PrTTgnT

Intact / Not Intact Vflrslon 4.0: 07/03

http://_fl.ll

t3y/iy/:î305 I D I S J )iZ\iZblbr/\^ TAWATER PAGE 01/18

TestAmerica ANALYTICAL TESTING CORPORATION

WDNR No. 128053530 602 COMMEKCEDWVE . WATEKTOWN, VW S30W 920-26J-JI660 FAX 920-261-8120

ANALYTICAL REPORT

Ms. Rebecca Caudill NATURAL RESOURCE TECH, 23713 W. Paul Road Pewaukee, WI 53072

INC 09/19/2005

Job No: 05.0300!

Page 1 of 6

The following samples were received by TestAmerica for analysis

1549 WPSC Marinette

Sample Number

612713 612714 612715 612716 612717 612716 612719 612720 512721 612722 612723 612724 612725 612726 612727 612728 612729 612730 612731 612732

Sai

MW-30 6 MW-311 MW-307R MW-1 MW-310 P-305 MW-308 P-303 MW-3R MW-5 MW-303 MW-304 MW-305 MW-302 P-302 QC-1 QC-2 MW-801 PZ-801 MW-806

Sample Description Date Taken

04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/13/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/14/2005 04/13/2005 04/13/2005 04/13/2005

Date Received

04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15 04/15

/2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005 /2005

Karen R. Wenta Inorganic Operations Manager

www.ifsiainerlcalnc.cofn

TeslAmerici An*lyilc»l Testing Corporaiion | TestAmerica Drilling Coiporsllon | TcjtAinrriea Air Emisjion Corporation

http://www.ifsiainerlcalnc.cofn

ay/iy/liUUb It).-53 9202518120 TAWATER PAGE 02/10

TesUtoerica ANALYTICAL TESTING CORPORATION

WDNR No, 128053530 602 COMMERCE DRIVE • WATERTOWN. Wl 53094 92O-261-]660 • FAX 9 2 0 - 2 6 ) - 8 1 2 0

ANALYTICAL REPORT

Ms. Rebecca Caudill NATURAL RESOURCE TECH, INC 23713 W. Paul Road Pewaukee, WI 53072

09/19/2005

Job No: 05.0300!

Page 2 of 6

The following samples were received by TestAmerica for analysis

1549 WPSC Marinette

Sample Number Sample Description

MW-807 612734 PZ-802 612735 PZ-803 612736 QC-1 4/13

Date Taken

04/13/2005 04/13/2005 04/13/2005 04/13/2005

Date Received

04/15/2005 04/15/2005 04/15/2005 04/15/2005

www.tesumtrletlnc.cora TtistAmcrlcj Annlyllcul Testing Corporation j TcjiAmcrIca Drilling Corpor»tlo« | TesiAmerlcj Air Emission Corporitlon

http://www.tesumtrletlnc.cora

09/19/2005 15:53 9202B18120 TAWATER PAGE 0 3 / 1 0

TestAmerica WDNRNo. J28053530 ANALYTICAL TESTING CORPORATION 602 CoMMERCT DRIVE • WATERTOWN, W [ 53094 • 920-261-1660 • FAX 920-261-8120

NATURAL RESOURCE TECH, INC 09/19/2005 Job No: 05.03008 Page 3 of 5

KEY TO DATA FLAGS The attached sample(s) may have a result flag shown on the report. The following are the result flag definitions:

h = fi.nalyzed/e:-:tracted past hold time B = Blank is contaminated C = Standard outside of control limits D = Diluted for analysis E = TCLP extraction outside of method required temperature range F = Sample filtered in lab G = Received past hold time H = Late eluting hydrocarbons present I = Improperly handled sample J = Estimated concentration L = Common lab solvent M = Matri.x interference P = Improperly preserved sample Q = Result confirmed via re-analysis S = Sediment present T = Does not match typical pattern W = BOD re-set due to missed dilution X - Unidentified compound(s) present z = Internal standard outside limits * = See Case Narrative

KEY TO ANALYST INITIALS

The attached sample(s) may have been analyzed by another certified laboratory. If a number appears in the Analyst Initials field, the following are the appropriate certifications (if the lab code does not appear below, that means that certification is not required for the work performed):

Certification Number Lab Code

OOS 013 020 030 070 090 130 149 148 300 400 510 700

WDNR - 999766900 WDNR - 999917160; ILNELAC - 100261 WDNR - 999447680 ILNELAC - 100230; WDNR - 998294430 lA - 007; ILNELAC - 000663; MDH - 019-999-319; WDNR - 999917270 ILNELAC 200006; WDNR - 399031270 WDNR - 632021390 WDNR - 721026460 WDNR - 399017190 ELNELAC - 87358; lA - 131; MDH - 047-999-345; WDNR - 998020430 WDNR - 113133790 WDNR - 241249360 WDNR - 113289110

TestAmerica Watertown Certifications: ,WI DNR - 123053530; IL NELAC - 100453; lA DNR - 294; MN DoH - 055-999-366; ND DoH R-046; AR DEQ - 88-0809

unless sub-contracted (see above), volatiles analyses (including VOC, PVOC, GRO, BTEX and TPH Gasoline) performed by TestAmerica Watertown at 1101 Industrial Drive, Units 9&10. All other analyses performed at 602 Commerce Drive, Watertown WI 53094.

Results reported between the Method Detection Limic (MDL) and Limit of Quantitation (LOQ) are less certain than results at or above the LOQ.

Tor questions regarding this report, please contact Dan Milews)cy or Warren Topel.

www.u j iamer ica inc .com

TestAuitr lcS Ana)yiic»l T t t i l n j Corporation | T«slAincrica Drill ing Corporailon j TcsiAmerlca Air Emission Corporailon

http://www.ujiamericainc.com

09/19/2005 15:53 9202618120 TAWATER PAGE 04/10

TestAmerica ANALYTICAL TESTING CORPORATION

WDNRNo. 1280535J0 602 COMMERCE DRIVE • WATERTOWN, Wl 53094 • 920-26M66O • FAX 920-26i~e:20

ANALYTICAL REPORT


Job Description: 1549 WPSC Marinette Marinette, WI Rec'd on ice

09/19/2005 Job No: 05.03008 Account No: 52450 Purchase Order: Page 4 of 6

6:2113

Cyanide,

6127H

Cyanlda,

612115

Cyanide,

612716

Cyanide,

612717

Cyanide,

612716

Cyanide,

612719

Cyanide,

612720

Cyanide,

Paraaecar

MM-306

available

MW-311

availabls

MW-307R

available

MW-1

available

MW-olO

available

P-30S

available

Mn-306

available

P-303

available

Date Prap/Run

R e s u l t s Uni ta MDI, LOQ Methofl Analyzed Analys t Batch

Data/Time Taken; 0 4 / 1 3 / 2 0 0 5 13 :30

<0.0050 roO/L 0 .0050 EPA 1677 0</21/2005 090 52

Date/Time Token: 04 /13 /2005 13 ;50

<0.0050 mg/L 0.0050 ZP?. 1677 04 /21 /2005 090 52

Dacs/Tima Taken: 04 /13 /2005 H ; 2 2

<0.0050 mg/L 0.0050 EPa. 1677 01 /26 /2005 090 53

Date/Time Taken: 0« /13 /200S 15 :30

<D.0050 mg/L 0.0050 EPA 1677 04 /26 /2005 090 53

Date/Time Taken: 04 /13 /2005 16:07

0 , 0 0 5 1 m<3/L 0.0050 EfA 1677 04 /26 /2005 Q90 S3

Dace/Time Taken: 04 /13 /2005 16 :45

<0.OnS0 mg/L O.OOSO EPA 1677 04 /26 /2005 0?0 53

Date/Time Taken: 04 /13 /2005 16:40

<O.O0S0 mg/L 0.0050 EPA 1677 04 /26 /2005 090 S3

Date/Time Taken: 04 /14 /200S 07 :30

<0 .0050 mg/ l 0.0050 EPA 1677 01 /26 /2005 090 54

www.tesiamcrtcalnc.coin

TejlAmerica Ani ly i l ca l Tesi ine Corpora i lon | TejtATntrlc» Drilling Corporation | Tes iAmc i i c j Air EmlsJlcn Corpor«Oon

http://www.tesiamcrtcalnc.coin

09/19/2005 15:53 9202618120 TAWATER PAGE 05/10

Test^toerica ANAUVTICAL TESTING CORPORATION

WDNR No. 128053530 602 COMMERCE DIOVE • W.JITEKTOWN. W I 53094 • 920-261-1660 • FAX 920-2S1-8120

ANALYTICAL REPORT

Ms. Rebecca C a u d i l l NATURAL RESOURCE TECH, INC 23713 W. Paul Road .Pewaukee, WI 53072

Job D e s c r i p t i o n : 1549 WPSC Mar ine t t e M a r i n e t t e , WI Rec'd on ice

09/19/2005 Job No: 05.03008 Account No: 52450 Purchase Order: Page 5 of 6

612721

Cyanide,

612722

Cyanide,

612723

Cyanide,

612721

Cyanide,

6127J5

Cyanide,

612726

Cyanide,

612727

Cyanide,

612728

Cyanide,

Parameter

NW-3R

available

MW-5

available

MW-303

availflbls

W-304

available

MW-30S

a-»ailoble

KM-30J

available

P-302

available

QC-1

available

Date Prap/Run

R e s u l t s Uni ta MDL LOQ M e t h o d Analyzaa A n a l y s t Batch

Cote/Txms Taken; 04 /14 /2005 07;36

<0.0050 ros/L 0 .0050 EPA 1577 04/29/2005 090 54

Data/'Time Tsksn ; 04 /14 /2005 0S;15

<0.0050 mg/L 0.0050 EPA 1677 04/28/2005 050 51

Date/Time Taken: 04 /14 /2005 09;06

<0.0050 mg/L 0.0050 EPA 1677 04/26/2005 090 54

Date/Time Taken; 04 /14 /2005 09;OS

0.0076 mg/L 0.0050 EPA 1677 04/2S/200S 090 54

Pa te /Time Tak«n: 04 /14 /2005 09:45

fO.OOSO mg/L 0 .0030 EPA 1677 04/26/2005 090 54

Date/Time Takan; 04 /14 /2005 10:15

O.OOSO mg/L O.OOSO EPA 1677 04/29/2005 090 54

Date/Time Taken: 04 / l ( i /2005 10:16

<0.OOS0 mg/L O.OOSO EPA 1677 04/28/2005 090 5<l

Date/Tlrae Taken: 04 /14/2005 UNKNOVW

<0.0050 mg/L 0.0050 EPA 16?7 04/26/2005 090 54

www.iesn incr lca lnc .com

Tts tAmcrlca Analytical Te j l lng Corporiitloii | TestAmerica Dii l l ing Corporai lon | TeciAracrlet Air Emijjlon Corporntlon

http://www.iesnincrlcalnc.com

09/19/2005 15:53 9202618120 TAWATER PAGE 05/10

Test/toerica ANALYTICAL TESTING CORPORATION

WDNRNo. 128053530 602 COMMERCE DRIVE • WATERTOWN. w i 53094 • 920-Z6I-166O • FA.K 920-26I-8120

ANALYTICAL REPORT


Job Description; 1549 WPSC Marinette Marinette, WI Rec'd on ice

09/19/2005 Job No: 05.0300B Account No: 52450 Purchase Order: Page 6 of 6

612729

Cyanide,

612730

Cyanide,

612731

Cyanide,

612732

Cyanide,

612733

Cyanide,

612734

Cyanide,

612735

Cyanide,

612736

Cyanide,

7arams usr

QC-2

available

MW-BOl

available

PZ-801

fli7ailablc

KH-e06

available

Mn-eo7

available

e2-802

available

e2-803

available

OC-1 4/13

available

Date Prcp/Run

R e s u l t s U n i t s MPL LOQ M a t h o d .Analyzed A n a l y s t Batch

Date /Time Taken: 04 /14 /2005 UNKNOWN

<0.0050 EVCI/L 0 .0050 EPA. 1677 0 1 / 2 8 / 2 0 0 5 090 S4

Data /Time Token: 04 /13/2005 09 :00

0.0097 mg/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 09Q 55

Date /Time t a k e n : 04 /13 /2005 0 3 : 0 5

<0.OOSO mj/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55

Date /Time Takan; 04 /13 /2005 08 :35

0.0064 mg/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 090 SS

Date /Time Taken: 04 /13 /2005 10:18

<0.0050 mg/L O.OOSO EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55

Date /Time Taken; 04 /13 /2005 09 :40

<0.0050 mg/L O.OOSO EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55

Date/Time Taken; 04 /13 /2005 10 :20

<0.0050 nig/L O.OOSO EPA 1677 0 4 / 2 7 / 2 0 0 5 090 55

Data/Time Taken; 04 /13/2005 UNKKOMtl

0 .0066 mg/L 0.0050 EPA 1677 0 4 / 2 7 / 2 0 0 5 090 SS

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