NATIONAL ENVIRONMENTAL TESTING INC - SAMPLING ...NET NATIONAL ENVIRONMENTAL i® TESTING, INC. CASE NARRATIVE Ms. Mary Jane Ripp ECOLOGY & ENVIRONMENT, INC 111 West Jackson Blvd. Chicago,

SAMPLINGDATA

NATIONALENVIRONMENTAL

©TESTING, INC. vjCHAIN OF CUSTODY RECORDCOMPANY

ADDRESS

PHONE

PROJECT NAME/LOCATION

PROJECT NUMBER _____

PROJECT MANAGER

FAXS&- ^3-

REPORT TO:.

INVOICE TO. _

P.O. NO. __

NET QUOTE NO.

CONDITION OF SAMPLE: BOTTLES INTACT?FIELD FILTERED? Y

COC SEALS PRESENT AND INTACT? YES / NOVOLATILES FREE OF HEADSPACE?/<E^ / NO

SAMPLE REMAINDER DISPOSAL: RETURN SAMPLE REMAINDER TO CLIENT VIAI REQUEST NET TO DISPOSE OF ALL SAMPLE REMAINDERS

TEMPERATURE UPON RECEIPT^Bottles supplied by NET? YES MC)

DATE

DATE/TIME RELINQUISHED BY: DATETTIME

||PT 1 - ORIGINAL - WHITE PT 2 • NET PROJECT MANAGER • YELLOW PT 3 - CUL ÊR COPY - PINK

ECOLOGY 1 BnMftaiiiit, INC. - rfî .i,,5;: i,,-,:,:.:,:::,,, , ; : : ;Vi: , .- . . , . ' . . ' : .^ ; : ::V x • . ,.

Project Name: C. Ar<^ ~ O

Location (city/county/state):

Team Leader: 7V\|^c /V\A

project TOD/PAN: ToS -

Date Form Submitted: (Q 1

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Date Report Due: 7/t8/W

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NET NATIONALENVIRONMENTAL

i® TESTING, INC.

CASE NARRATIVE

Ms. Mary Jane RippECOLOGY & ENVIRONMENT, INC111 West Jackson Blvd.Chicago, IL 60604

Project Description: T05-9406-601

07/20/1994

NET Job Number: 94.04975

SampleNumber267075

Sample DescriptionDrinking Water

Date DateTaken Received06/28/1994 06/29/1994

Sample analysis in support of the project referenced above hasbeen completed and results are presented on the following pages.Please refer to the enclosed "Key to Abbreviations" for definitionof terms.

The following comments should be noted for the indicated fraction;

Semi-Volatile Organic AnalysisSemi-Volatile Analysis was performed by EPA method 625, per clientrequest; this method applies to wastewater analysis and is notcovered under Illinois EPA SDWA certification.

Semi-Volatile compounds Hexachloroethane and 2-Chloronapthalenewere within control limits on the Laboratory Control Standard(LCS) but below control limits on the LCS Duplicate. Allsurrogate recoveries were within control limits and these twocompounds were not detected in the sample.

Metals Analysis

Arsenic, GFAA; Lead, GFAA and Selenium, AA were analyzed at anNET approved subcontract laboratory, Daily Laboratories. TheDaily QC Deliverables will be forwarded straight to you.

This Quality Control report is generated on a batch basis. Allinformation contained in this report is for the analyticalbatch(es) in which your samples were analyzed. These resultsapply only to the samples analyzed. Reproduction of this reportonly in whole is permitted. Please refer to the enclosed "Key toAbbreviations" for definition of terms. Should you have questionsregarding procedures or results, please do not hesitate to call.NET has been pleased to provide these analytical services for you.

CalickiQuality Assurance Coordinator


i® TESTING, INC.


07/19/1994


Enclosed is the Quality Control Data and Analytical Results for thefollowing samples submitted to NET, Inc. Bartlett Division foranalysis:

Project Description: T05-9406-60:

SampleNumber Sample Description

267075 Drinking Water

DateTaken

DateReceived

06/28/1994 06/29/1994

Sample analysis in support of the project referenced above has beencompleted and results are presented on the following pages. Theseresults apply only to the samples analyzed. Reproduction of thisreport only in whole is permitted. Please refer to the enclosed"Key to Abbreviations" for definition of terms. Should you havequestions regarding procedures or results, please do not hesitate tocall. NET has been pleased to provide these analytical services foryou.

This Quality Control report is generated on a batch basis. Allinformation contained in this report is for the analytical batch(es)in which your sample(s) were analyzed.

oved^by

i-Pierre C. RouanetOperations Manager

NETMATIONAI Bartlelt DivisioniNru iwi>irii_ 85Q w Bartlen Ra

ENVIRONMENTAL Bartlett IL60103Tel: (708) 289-310Fax: (708) 289-5445TESTING, INC. Tel: <708>289'3100

CASE NARRATIVE

Ms. Mary Jane RippECOLOGY & ENVIRONMENT, INC 07/20/1994111 West Jackson Blvd.Chicago, IL 60604 NET Job Number: 94.04975


Sample Date DateNumber Sample Description Taken Received267075 Drinking Water 06/28/1994 06/29/1994Sample analysis in support of the project referenced above' hasbeen completed and results are presented on the following pages.Please refer to the enclosed "Key to Abbreviations" for definitionof terms.

The following comments should be noted for the indicated fraction;' »

Seal-volatile organic AnalysisSemi-Volatile Analysis was performed by EPA method 625, per clientrequest; this method applies to wastewater analysis and i» notcovered under Illinois EPA SDWA certification. ;

'.>*"'.'

Semi-Volatile compounds Hexachloroethane and 2-Chloronapthalenewere within control limits on the Laboratory Control Standard(LCS) but below control limits on the LCS Duplicate. Allsurrogate recoveries were within control limits and these twocompounds were not detected in the sample.Metals Analysis .;x&£-Arsenic, GFAA; Lead, GFAA and Selenium, AA were analyzed air anNET approved subcontract laboratory, Daily Laboratories. TheDaily QC Deliverables will be forwarded straight to you.


__ ilickiQuality Assurance Coordinator

NET NATIONALENVIRONMENTALTESTING, INC.

Bartlett Division850 W Bartlett Rd.Bartlett. IL 60103Tel: (708)289-3100Fax: (708) 289-5445

Ms. Mary Jane RippECOLOGY & ENVIRONMENT,111 West Jackson Blvd.Chicago, IL 60604

INC 07/19/1994


Enclosed is the Quality Control Data and Analytical Results for thefollowing samples submitted to NET, Inc. Bartlett Division foranalysis:


SampleNumber

267075

Sample Description

Drinking Water

DateTaken

DateReceived

06/28/1994 06/29/1994

Sample analysis in support of the project referenced above has beencompleted and results are presented on the following pages. Theseresults apply only to the samples analyzed. Reproduction of thisreport only in whole is permitted. Please refer to the enclosed"Key to Abbreviations" for definition of terms. Should you havequestions regarding procedures or results, please do not hesitate tocall. NET has been pleased to provide these analytical services foryou.

This Quality Control report is generated on a batch basis. Allinformation contained in this report is for the analytical batch(es)in which your sample(s) were analyzed.

y , L

" 'i-P:' ?rre C. Rouanet

Operations Manager


Bartiet! Division350 W. Bartlett RdBartlett. IL 60103Tel: (708)289-3100Fax: (708) 289-5445

ANALYTICAL REPORT


07/19/1994

Sample No. : 267075

NET Job No.: 94.04975

Sample Description: Drinking WaterT05-9406-601

Date Taken: 06/28/1994Time Taken: 08:20IEPA Cert. No. 100221

Date Received: 06/29/1994Time Received: 19:00WDNR Cert. No. 999447130

Parameter

METALSArsenic, GFAABarium, ICPCadmium, ICPChromium, ICPLead, GFAAMercury, CVAASelenium, AASilver, AAMetals Prep, Hg Aqueous

PREP, ACID EXT. AQUEOUSPREP, BN AQUEOUS

ACID CMPOS - 625 AQUEOUS4-Chloro-3-methylphenol2-Chlorophenol2,4-Dichlorophenol2,4-Dimethylphenol2,4-Dinitrophenol2-Methyl-4,6-dinitrophenol2-Nitrophenol4-MitrophenolPentachlorophenolPhenol2,4.6-TrichlorophenolSurr: Phenol-66Surr: 2-FluorophenolSurr: 2,4,6-Tribromophenol

Results Flag Units

<O.OOS0.045<0.010<0.040<0.0050<0.0002<0.0050<0.040Complete

extractedextracted

mo/Lng/Lng/Lng/Lng/Lng/Lng/Lng/L

<50<50<10<50<50

243684

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/LXXX

Date ofAnalysis

07/15/199407/15/199407/15/199407/15/199407/15/199407/13/199407/15/199407/11/199407/13/1994

07/05/199407/05/1994

07/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/1994

MethodPOL

0.00500.0200.0100.0400.00500.00020.00500.040

101010105050105050101010-9421-10010-123

Analyst Batch No.Prep/Run

outmjbmjbmjboutmjboutmjbmjb

laslas

rlarlarlarlarlarlarlarlarlarlarlarlarlarla

Outside832804790

Outside363 355Outside

363

244244

244244244244244244244244244244244244244244

243

528528528528528528528528528528528528528526

AnalyticalMethod

7060(4)6010(4)6010(4)6010(1)7424(1)7471(1)7741(1)7760(1)7471(1)

3500 (1)3500 (1)

625 (3)625. <3X625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)

206.200.200.200.239.245.

2(3)7(3)7(3)7(3)2(3)1(3)

31148(4)272.245.

1(3)1(3)

0 : Parameter analysis was sub-contracted to an outside lab location.

Page 2


Bartlett Division850 W. Baniett Rd.Bartlett. IL 60103Tel: (708) 289-3100Fax; (708) 289-5445

ANALYTICAL REPORT


07/19/1994

Sample No. : 267075

NET Job No.: 94.04975




Parameter Results

BASE/NEUTRALS - 625 AQUEOUSAcenaphthene <10Acenaphthylene <10Anthracene <10Benzidine <50Benzo(a)anthracene <10Benzo(b)fluoranthene <10Benzo(k)fluoranthene <10Benzo(g,h,i)perylene <10Benzo(a)pyrene <10Benzyl butyl phthalate <10Bis(2-chloroethoxy)methane <10Bis(2-chloroethyl)ether <10Bis(2-chloroisopropyl)ether <10Bis(2-ethylhexyl)phthalate <104-Bromophenyl phenyl ether <102-Chloronaphthalene <104-Chlorophenyl phenyl ether <10Chrysene <10Dibenzo(a,h)anthrac«ne <10Di-n-botyl phthalate <101.2-Oichlorobenzene <101.3-Dichlorober.zene <101.4-Oichlorobenzene <103,3'-Dichlorobenzidine <20Diethyl phthalate <10Dimethyl phthalate <102,4-Dinitrotoluene <10

Units

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

Date ofAnalysis

07/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/199407/08/1994

HePI

101010501010101010101010101010101010101010101020101010

Analyst Batch No. AnalyticalPrep/Run Method

rlarlarlarlarlarlarlarlarlarlarlarlarlartarlarlarlarlarlarlarlarlarlarlarlarlarla

244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528244 528

625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)

Page 3


Bartlett Division850 W. Bartlett Rd.Bartlett. IL 60103Tel (708) 289-3100Fax: (708) 289-5445

ANALYTICAL REPORT


07/19/1994

Sample No. :

NET Job No.:

267075

94.04975



Date Received: 06/29/1994Time Received: 19:00 'WDNR Cert. No. 999447130:

Parameter

2,6-DinitrotolueneDi-n-octyl phthalateFluorantheneFluoreneHexachIorobenzeneHexachIorobutad ieneHexachlorocycIopentadieneHexachIoroethaneI ndeno( 1,2,3 - ccOpyreneIsophoroneNaphthaleneNitrobenzeneN-NitrosodimethylamineN-Nitrosodi-n-propylamineN-N i t rosodiphenyI ami nePhenanthrenePyrene1,2,4-TrichlorobenzeneSurr: Nitrobenzene-dSSure: 2-FluorobiphenylSurr: Terphenyl-d14

SOUA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-DichloroethaneT r i chIoroethyIene1,1 -D i chIoroethyIene1,1,1 -Trichloroethane

Results

•00

565080

Units .Date of Method Analyst Batch No.Analysis POL Prep/Run

ug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaug/L 07/08/1994 10 rlaX 07/08/1994 35-114 rlaX 07/08/1994 43-116 rlaX 07/08/1994 33-141 rla

Analytical.

<0.5<0.5<0.5<0.51.0<0.5<0.5

ug/Lug/Lug/Lug/Lug/Lug/Lug/L

07/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/1994

0.50.50.50.50.50.50.5

UjUjUjUjUjUjUj

314314314314314314314

524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)

Page 4


Bartlett Division850 W. Bartlett RdBartlett. IL 60103Tel: (708) 289-3100Fax: (708) 289-5445

ANALYTICAL REPORT


07/19/1994

Sample No. :

NET Job No.:

267075

94.04975




Parameter

p- 0 i ch I orobemeneSurr: 4-BromofluorobenzeneSure: d4-1,2-DichIorobenzeneBroMobenzene01chIorobromomethaneBrc«ofomBronomethaneChtorobenzeneChlorodibromomethaneChloroethaneChloroformChloromethaneo-Chlorotoluenep-ChlorotolueneOibromomethanem-0 i ch I orobenzeneo-D i chIorobenzene1.1-Dichloroethanecis-1,2-Dichloroethylenetrans-1,2-Dichloroethylene0ichIoromethane1.2-Dichloropropane1,3 - D i ch I oropropane2,2-Dichloropropane1,1 -0ichIoropropene1,3-OichloropropeneEthylbenzeneStyrene1,1,1,2- Tet rachIoroethane1,1,2,2-tet rachIoroethane

Results

<0.59684<1.0<0.5<0.5<2.0<0.5<0.5<2.0<0.5<2.0<1.0<1.0<1.0<1.0<0.5<1.0<0.5<0.5<0.5<0.5<1.0<1.0<1.0<1.0<0.5<0.5<1.0<1.0

Units

ug/LXXug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

Date ofAnalysis

07/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/1994

MethodPOL

0.5

1.00.50.52.00.50.52.00.52.01.01.01.01.00.51.00.50.50.50.51.01.01.01.00.50.51.01.0

Analyst

UjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUj

Batch No.Prep/Run

314314314314314314314314314314314314314314314314314314314314314314314314314314314314314314

AnalyticalMethod

524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)

Page 5


Bartleit Division350 W Bartleit RdBartlett. IL 60103Tel: (708) 289-3100Fax 1708) 289-5445

ANALYTICAL REPORT


07/19/1994

Sample No. : 267075

NET Job No.: 94.04975




Parameter Results

Tetrachloroethylene <0.5Toluene <0.51.1,2-Trichloroethane <0.51,2,3-Trichloropropane O.Om&p-Xylene <0.5o-Xylene <0.51,2-Dibromo-3-Chloropropane OOEthylenedibromide (EDB) OOBromoch I oromethane O.On-Butyl benzene O.Osec-Butylbenzene O.Otert-Butylbenzene O.ODichlorodif luoromethane O.OFluorotrichloromethane O.OHexachlorobutadiene O.OIsopropy I benzene O.Op-Isopropyltoluene O.ONaphthalene O.On-Propylbenzene O.O1.2.3-Trichlorobenzene O.O1.2.4-Trichlorobenzene <0.51,2,4-Trimethylbenzene O.O1,3,5-Trimethylbenzene O.O

Units

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

Date ofAnalysis

07/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/199407/06/1994

MethodPOL

0.50.50.51.00.50.510101.01.01.01.01.01.01.01.01.01.01.01.00.51.01.0

Analyst

UjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUjUj

Batch No.Prep/Run

314314314314314314314314314314314314314314314314314314314314314314314

AnalyticalMethod

524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)

Page 6


I® TESTING, INC.

QUALITY CONTROL REPORTCONTINUING CALIBRATION VERIFICATION

ECOLOGY & ENVIRONMENT, INC111 West Jackson Blvd.Chicago, IL 60604

07/19/1994


Analyte

Barium, ICPCadmium, ICPChromium, ICPMercury, CVAASilver, AA

ACID CMPDS - 625 AQUEOUS4-Chloro-3-methylphenol2,4-Dichlorophenol2-NitrophenolPentachlorophenolPhenol2,4,6-Trichlorophenol

BASE/NEUTRALS - 625 AQUEOUSAcenaphtheneBenzo(a)pyrene1,4-DichlorobenzeneDi-n-octyl phthalateFluorantheneHexachlorobutadiene

SDWA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-OichloroethaneTrichloroethylene1,1-Dichloroethylene1,1,1-Trichloroethanep-D i chIorobenzene

RunBatchNumber

832804790355243

528528528528528528

528528528528528528

314314314314314314314314

CCVTrueCone.

2.001.002.000.00250.500

50.050.050.050.050.050.0

50.050.050.050.050.050.0

10.010.010.010.010.010.010.010.0

Cone.Found

2.061.022.050.00240.517

40.9443.5148.0242.3044.7443.93

44.0845.7648.3050.8545.2245.68

9.98.410.110.211.08.59.411.8

PercentRecovery

103.0102.0102.596.0103.4

81.987.096.084.689.587.9

88.291.596.6101.790.491.4

99.084.0101.0102.0110.085.094.0118.0

CCV - Continuing Calibration Verification


.©TESTING, INC.

QUALITY CONTROL REPORTBLANK ANALYSIS


07/19/1994


Analyte

BariLIT, ICPCadmium, ICPChromium, ICPMercury, CVAASilver, AA

Prep RunBatch BatchNumber Number

832804790

363 355243

BlankAnalysisResults

ReportingUnits L i m i t

<0.020 mg/L<0.010 mg/L<0.040 mg/L<0.0002 mg/L<0.040 mg/L

0.0200.0100.0400.00020.040

AnalyticalMethod

6010(4) 200.7(3)6010(4) 200.7(3)6010(1) 200.7(3)7471(1) 245.1(3)7760(1) 272.1(3)

ACID CMPDS - 625 AQUEOUS4-Chloro-3-methylphenol2-Chlorophenol2,4-Oichlorophenol2,4-Dimethyl phenol2,4-Oinitrophenol2-Methyl-4,6-dinitrophenol2-Nitrophenol4-NitrophenolPentachlorophenolPhenol2,4,6-TrichlorophenolSurr: Phenol-d6Surr: 2-FluorophenolSurr: 2,4,6-Tribromophenol

244244244244244244244244244244244244244244

525525525525525525525525525525525525525525

<50<50

<50<50

335366

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L%%%

101010105050105050101010-9421-10010-123

625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)

BASE/NEUTRALS - 625 AQUEOUSBenzyl butyl phthalate 244 525 ug/L 10

625 (3)625 (3)

Advisory Control Limits for Blanks:

All compounds should be less than the Reporting Limit, except for phthalate esters, toluene, methylene chloride,acetone and chloroform should be less than 5 times the Reporting Limit.


©TESTING, INC.



07/19/1994


Analyte

Bis(2-ethylhexyl)phthalateDi-n-butyl phthalateDiethyl phthalateDimethyl phthalateDi-n-octyl phthalateSurr: Nitrobenzene-d5Surr: 2-FluorobiphenylSurr: Terphenyl-d14SOWA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-DichloroethaneTrichloroethylene1,1-Dichloroethylene1,1,1-Trichloroethanep-D i chIorobenzeneSurr: 4-BromofluorobenzeneSurr: d4-1,2-DichIorobenzeneBromobenzeneDichlorobromomethaneBromoformBromomethaneChIorobenzeneChlorodibromomethaneChloroethaneChloroformChloromethaneo-Chlorotoluene

PrepBatchNumber

244244244244244244244244

RunBatchNumber

525525525525525525525525

314314314314314314314314314314314314314314314314314314314314

BlankAnalysisResults

<10<10<10<10<10776771

<0.5<0.5<0.5<0.5<0.5<0.5<0.5<0.59685<1.0<0,5<0.5<2.0<0.5<0.5<2.0<0.5<2.0<1.0

Units

ug/Lug/Lug/Lug/Lug/L%%%

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L%%ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

ReportingLi m i t

101010101035-11443-11633-141

0.50.50.50.50.50.50.50.5

1 .00.50.52.0C.50.52.00.52.01.0

AnalyticalMethod

625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)


Ail compounds should be less than the Reporting L i m i t , except for phthalate esters, toluene, methylene chloride,acetone and chloroform should be less than 5 times the Reporting Lim i t .




07/19/1994


Analyte

p-ChlorotolueneOibromomethanera-D i chIorobenzeneo-D i chIorobenzene1.1-Dichloroethanecis-1,2-Dichloroethylenetrans-1,2-DichloroethyleneDichloromethane1.2-0 i chIoropropane1.3-Dichloropropane2,2 -D i chIoropropane1,1-Oichloropropene1,3-D i chloropropeneEthylbenzeneStyrene1,1,1,2-Tetrachloroethane1,1,2,2-tetrachloroethaneTetrachloroethyleneToluene1,1,2-Trichloroethane1,2,3-Trichloropropanem&p-Xyleneo-Xylene1,2-Dibromo-3-ChloropropaneEthylenedibromide (EDB)BromochIoromethanen-Butylbenzenesec-Butyl benzenetert-Butyl benzene


314314314314314314314314314314314314314314314314314314314314314314314314314314314314314

BlankAna Iys i sResults Units

<0.5

<0.5<0.5<0.5<0.5

<0.5<0.5

<0.5<0.5<0.5

<0.5<0.5

ReportingLimi t

Analyt icalMethod

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

1.01.01.00.51.00.50.50.50.51.01.01.01.00.50.51.01.00.50.50.51.00.50.510101.01.C1.01.0

524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)


All compounds should be less than the Reporting Limit, except for phthalate esters, toluene, methylene chloride,acetone and chloroform should be less than 5 times the Reporting L i m i t .


I® TESTING, INC.



07/19/1994


Analyte

Dichlorodi fluoromethaneFluorotrichloromethaneHexach I orofcxjtadi eneIsopropylbenzenep-IsopropyltolueneNaphthalenen-PropyI benzene1.2.3-Trichlorobenzene1.2.4-Trichlorobenzene1, 2,4-Trimethylbenzene1,3,5-Trimethylbenzene


BlankAnalysisResults Units

ReportingL i m i t

314314314314314314314314314314314

<1.0<1.0<1.0<1.0<1.0<1.0<1.0<1.0<0.5<1.0<1.0

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

1 .01.01.01 .01.01.01.01.00.51.01 .0

Analyt icalMethod

524.2 (6)524.2 (6)524 .2 (6)524.2524.2524.2524.2524.2

(6)(6)(6)(6)(6)

524.2 (6)524 .2 (6)524 .2 (6 )


All compounds should be less than the Reporting L i m i t , except for phthalate esters, toluene, methylene chloride,acetone and chloroform should be less than 5 times the Reporting L i m i t .


QUALITY CONTROL REPORTLABORATORY CONTROL STANDARD


07/19/1994


Analyte

ACID CMPDS - 625 AQUEOUS4-Chloro-3-methylphenol2-Chlorophenol2,4-Dichlorophenol2,4-Dimethylphenol2,4-Dinitrophenol2-Methyl-4,6-dinitrophenol2-Nitrophenol4-Ni trophenolPentachlorophenolPhenol

PrepBatchNumber

244244244244244244244244244244

RunBatchNumber

528528528528528528528528528528

TrueCone.

100100100100100100100100100100

Cone.Found

87.3663.7469.2256.3911196.4670.1679.3410853.32

LCS% Recovery

87.463.769.256.4111.096.570.279.3108.053.3

BASE/NEUTRALS - 625 AQUEOUSAcenaphtheneAcenaphthyleneAnthraceneBenzo(a)anthraceneBenzo(b)fluorantheneBenzodOf luorantheneBenzo(g,h,i Jperylene8enzo(a)pyreneBenzyl butyl phthalate

244244244244244244244244244

528528528528528528528528528

100100100100100100100100100

81.5384.8588.6192.6368.4523.8282.5081.4984.02

81.584.888.692.668.523.882.581.584.0

Advisory Control Limits - Inorganics - LCS recovery should be 80 - 120%.


Bar



07/19/1994


PrepBatchNumber

244244244244244244244244244244244244244244244244244244244244244244244244244244244244244244244

RunBatchNumber

528528528528528528528528528528528528528528528528528528528528528528528528528528528528528528528

TrueCone.

100100100100100100100100100100100100100100100100100100100100100100100100100100100100100100100

Cone.Found

70.5367.4269.7479. u792.8270.5587.3687.3380.8681.6654.2052.4151.7151.7654.6935.0895.9895.9877.0289.3692.4663.9152.6982.5072.3966.1165.7465.4088.8691.4064.61

LCS% Recovery

70.567.469.779.792.870.687.487.380.981.754.252.451.751.854.735.196.096.077.089.492.563.952.782.572.466.165.765.488.991 .464.6

Analyte

Bis(2-chloroethoxy)methaneBis(2-chloroethyl)etherBis(2-chloroisopropyl)etherBis(2-ethylhexyl)phthalate4-Bromophenyl phenyl ether2-Chloronaphthalene4-Chlorophenyl phenyl etherChryseneDibenzo(a,h)anthraceneDi-n-butyl phthalate1.2-Dichlorobenzene1.3-Dichlorobenzene1.4-Dichlorobenzene3,3'-DichlorobenzidineDiethyl phthalateDimethyl phthalate2,4-Dinitrotoluene2,6-Dini trotolueneDi-n-octyl phthalateFluorantheneHexachIorobenzeneHexachlorobutadieneHexachloroethaneIndenoO ,2,3-cd)pyreneIsophoroneNaphthaleneNitrobenzeneN-Ni trosodi-n-propylaminePhenanthrenePyrene1,2,4-TrichIorobenzene



I® TESTING, INC.



07/19/1994


Analyte

SDWA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-DichloroethaneTrichloroethylene1,1-Dichloroethylene1,1,1-Trichloroethanep-D i chlorobenzene


314314314314314314314314

TrueCone.

5.05.05.05.05.05.05.05.0

Cone.Found

4.95.04.94.54.94.55.04.7

LCSRecovery

98.0100.098.090.098.090.0100.094.0

Advisory Control Limits - Inorganics - LCS recovery should be 80 - 120X.


i® TESTING, INC. Fa,

QUALITY CONTROL REPORTMATRIX SPIKE/MATRIX SPIKE DUPLICATE


07/19/1994


Analyte

Prep Run MatrixBatch Batch SpikeNumber Number Result

MSDSample Spike Percent MSD Spike Percent MS/._Result Amount Units Recovery Result Amount Units Recovery RPD

Barium, ICPCadmium, ICPChromium, ICPMercury, CVAASilver. AA

363

832 1.21 0.316 1.00 mg/L 89.4804 0.440 <0.010 0.500 mg/L 88.0790 0.954 0.042 1.00 mg/L 91.2355 0.0025 <0.0002 0.0025 mg/L 100.0243 1.051 <0.040 1.00 mg/L 105.1

1.23 1.00 mg/L 91.4 2.20.500 0.459 mg/L 108.9 21.10.977 1.00 mg/L 93.5 2.50.0025 0.0025 mg/L 100.0 0.01.022 1.00 mg/L 102.2 2.8

NOTE: Matrix Spike Samples may not be samples from this job.

Advisory Control Limits for MS/MSDs:

For Inorganic Parameters and GC Volatiles, the spike recovery should be 75 - 125% if the spike added value was greaterthan or equal to one fourth of the sample result value. If not, the control l i m i t s are not established. The RPD for theMS/MSD pair should be less than 20.

MS = Matrix SpikeMSD = Matrix Spike DuplicateRPD = Relative Percent Difference


i® TESTING, INC.

QUALITY CONTROL REPORTSPIKES


Mr. Dave Hendron

07/19/1994


Analyte

Prep Run SpikedBatch Batch Sample Sample SpikeNumber Number Result Result Added

PercentUnits Recovery

NOTE: Spikes and Duplicates may not be samples from this job.

The values reported above are for post digestion/distillation spikes.

Advisory Control L i m i t s for Spikes - Spike recovery should be 75 - 125%.


QUALITY CONTROL REPORTDUPLICATES


Mr. Dave Hendron

07/19/1994


Analyte

SDUA VOLATILE COMPOUNDS 524.21,2-Oibromo-3-ChloropropaneBromochloromethane

Prep RunBatch Batch Original DuplicateNumber Number Analysis Analysis Units RPD

314314

<250<25

<250<25

ug/Lug/L


RPD - Relative Percent Difference

Advisory Control Limits for Duplicates - RPD should be less than 20.

H


Bartletl Division850 W. Bartlett Rd.Bartlett, IL 60103Tel. (708) 289-3100Fax: (708) 289-5445

QUALITY CONTROL REPORTCONTINUING CALIBRATION VERIFICATION

ECOLOGY & ENVIRONMENT,111 West Jackson Blvd.Chicago, IL 60604

INC 07/19/1994


Analyte


ACID CMPOS • 625 AQUEOUS4-Chloro-3-methylphenol2,4-Dichlorophenot2-NitrophenolPentach I oroptieno IPhenol2,4,6-Trichlorophenol

BASE/NEUTRALS - 625 AQUEOUSAcenaptitheneBenzo(a)pyrene1,4-DichlorobenzeneDi-n-octyl phthalateFluorantheneHexachIorobutadi ene

SOUA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-DichloroethaneTrichloroethylene1,1-Dichloroethylene1,1,1 - T r i chIoroethanep-D i chIorobenzene

RunBatchNumber

832804790355243

528528528528528526

528528528528528528

3U314314314314314314314

ccvTrueCone.

2.001.002.000.00250.500

50.050.050.050.050.050.0

50.050.050.050.050.050.0

10.010.010.010.010.010.010.010.0

Cone.Found

2.061.022.050.00240.517

40.9443.5148.0242.3044.7443.93

44.0845.7648.3050.8545.2245.68

9.98.410.110.211.08.59.411.8

PercentRecovery

103.0102.0102.596.0103.4

81.987.096.084.689.587.9

88.291.596.6101.790.491.4

99.084.0101.0102.0110.085.094.0118.0

CCV - Continuing Calibration Verification


3artletl Division850 W Bartleit RaBanieu. IL 60103Tel (708) 289-3100Fax (.708) 289-5445



07/19/1994


Anatyte

PrepBatchNumber

RunBatchNumber


ReportingL i m i t

AnalyticalMethod

Bar inn, ICPCadmium, ICPChromium, ICPMercury, CVAASilver, AA

363

832804790355243

<0.020<0.010<0.040<0.0002<0.040

mg/Lmg/Lmg/Lmg/Lmg/L

0.0200.0100.0400.00020.040

6010(4) 200.7(3)6010(4) 200.7(3)6010(1) 200.7(3)7471(1) 245.1(3)7760(1) 272.1(3)

ACID CMPOS - 625 AQUEOUS4-Chloro-3-methyI phenol2-Chlorophenol2,4-Dichlorophenol2,4-Dimethylphenol2,4-Dinitropheool2-Methyl-4,6-dinitrophefxjl2-Mitrophenol4-MitrophenolPentachIorophenolPhenol2,4,6-TrichlorophenolSurr: Phenol-d6Sure: 2-FluorophenolSurr: 2,4,6-Tribromophenol

244244244244244244244244244244244244244244

525525525525525525525525525525525525525525

<50<50

<50<50

335366

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/LXX%

101010105050105050101010-9421-10010-123

625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)

BASE/NEUTRALS - 625 AQUEOUSBenzyl butyl phthaiate 244 525 ug/L 10

625 (3)625 (3)




Bartlett Division850 W Bartlett Rd.Bartlett. IL 60103Tel: (708) 289-3100Fax: (708) 289-5445



07/19/1994


Analyte

Bis(2-ethylhexyl)phthalateDi-n-butyl phthalateDiethyl phthalateDimethyl phthalateOi-n-octyl phthalateSurr: Mitrobenzene-dSSurr: 2-FluorobiphenylSurr: Terphenyl-d14SOUA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-DichloroethaneTrichloroethylene1,1-Dichloroethylene1,1,1-Trichloroethanep-DichlorobenzeneSurr: 4-BromofluorobenzeneSurr: d4-1,2-DichlorobenzeneBromobenzeneDichIorobromomethaneBromoformBromomethaneChlorobenzeneChIorod i bromonethaneChloroethaneChloroformChloromethaneo-Chlorotoluene

PrepBatchNumber

RunBatchNumber


ReportingLimit

AnalyticalMethod

244244244244244244244244

525525525525525525525525

314314314314314314314314314314314314314314314314314314314314

<10<10<iQ<10<10776771

<0.5<0.5<0.5<0.5<0.5<0.5<0.5<0.59685<1.0<0.5<0.5<2.0<0.5<0.5<2.0<0.5<2.0<1.0

ug/Lug/Lug/Lug/Lug/LXXX

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/LXXug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

101010101035-11443-11633-141

0.50.50.50.50.50.50.50.5

1.00.50.52.00.50.52.00.52.01.0

625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)625 (3)524.2 (6)524.2 (6}524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)524.2 <6)524.2 (6)524.2 (6)524.2 (6)524.2 <6)524.2 (6)524.2 (6)524.2 (6)524.2 (6)




Bartlett Division55C W Bartleit RdBartlett. IL 60103*el: (708) 289-3100Fax (708) 289-5445



07/19/1994


Analyte

p-ChlorotolueneDibromomethanem-0 i ch I orobenz eneo-D i chIorobenzene1.1-Dichloroethanecis-1,2-0ichloroethylenetrans-I.Z-OichtoroethyleneDichIoromethane1.2-D1chIoropropane1.3-Dichloropropane2,2-DichIoropropane1,1-DichIoropropene1,3-DichloropropeneEthylbenzeneStyrene1,1,1,2-Tetrachloroethane1,1,2,2-tetrachloroethaneTetrachloroethyleneToluene1,1,2-T r i chIoroethane1,2,3-Trichloropropanem&p-Xyleneo-Xylene1,2-Dibromo-3-ChloropropaneEthyIenedibromide (EDB)BromochIoromethanen-Butylbenzenesec -ButyIbenzenetert-Butylbenzene


314314314314314314314314314314314314314314314314314314314314314314314314314314314314314


ReportingLimit

AnalyticalMethod

<1.0<1.0<1.0<0.5<1.0<0.5<0.5<0.5<0.5<1.0<1.0<1.0<1.0<0.5<0.5<1.0<1.0<0.5<0.5<0.5<1.0<0.5<0.5<10<10<1.0<1.0<1.0<1.0

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

1.01.01.00.51.00.50.50.50.51.01.01.01.00.50.51.01.00.50.50.51.00.50.510101.01.01.01.0

524524524.2524524524524524524524524.2524.2524524524524524524524524524524524524524524524524524.2

(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)(6)


All compounds should be less than the Reporting Limit, except for phthalate esters, toluene, methyIene chloride,acetone and chloroform should be less than 5 times the Reporting Limit.

'*"•""*' -».*,,,. .•m

«,.

"

•<••;*.• •,.'

(9;

1/6nVBh

0'[V6n

1/6n o-i

. _

J,3w


3artle!t Division35C W Barnett Ra3artleit, IL 60103'el (708) 289-3100

(708) 289-5445



07/19/1994


Analyte

ACID CMPOS - 625 AQUEOUS4-Chloro-3-methylphenol2-Chlorophenol2,4-Dichlorophenol2,4-Dimethylphenol2,4-Dinitrophenol2-Methyl-4,6-dinitrophenol2-Nitrophenol4-NitrophenolPentachlorophenolPhenol

PrepBatchNumber

RunBatchNunber

244244244244244244244244244244

528528528528528528528528528528

TrueCone.

Cone.Found

100100100100100100100100100100

87.3663.7469.2256.3911196.4670.1679.3410853.32

LCS% Recovery

87.463.769.256.4111.096.570.279.3108.053.3

BASE/NEUTRALS - 625 AQUEOUSAcenaphthene 244 528Acenaphthylene 244 528Anthracene 244 528BenzoCa)anthracene 244 528Benzo(b)fluoranthene 244 528BenzoCk)fluoranthene 244 528Benzo(g,h,i)perylene 244 528Benzo(a)pyrene 244 528Benzyl butyl phthalate 244 528

100100100100100100100100100

81.5384.8588.6192.6368.4523.8282.5081.4984.02

81.584.888.692.668.523.882.581.584.0



Bartlett Division850 W. Bartlett Rd.Bartlett, IL 60103Tel: (708) 289-3100Fax: (708) 289-5445



07/19/1994


Analyte

Bis(2-chloroethoxy)methaneBis(2-chloro«thyl)etherBis(2-chloroisopropyl)etherBi»(2-ethylhexyl)phthalate4-Bromophenyl phenyl ether2-Chtoronaphthalene4-Chlorophenyl phenyl etherChrysene0 i benzo( a , h ) anth raceneDi-n-butyl phthalate1 ,2-Dichlorobenzene1 ,3-Dichlorobenzene1 , A - D i ch I orobenzene3,3' -Dichlorobenzi dineDiethyl phthalateDimethyl phthalate2,4-Dinitrotoluene2,6-DinitrotolueneDi-n-octyl phthalateFluorantheneHexach I orobenzeneHexach I orobutadi eneHexach I oroe thanelndeno(1,2,3-cd)pyreneIsophoroneNaphthaleneNitrobenzeneN-Nitrosodi-n-propylaminePhenanthrenePyrene1,2,4-Trichlorobenzene

PrepBatchNumber

244244244244244244244244244244244244244244244244244244244244244244244244244244244244244244244

RunBatchNumber

528528528528528528528528528528528528528528528528528528528528528528528528528528528528528528528

TrueCone.

100100100100100100•iOO100100100100100100100100100100100100100100100100100100100100100100100100

Cone.Found

70.5367.4269.7479.6792.8270.5587.3687.3380.8681.6654.2052.4151.7151.7654.6935.0895.9895.9877.0289.3692.4663.9152.6982.5072.3966.1165.7465.4088.8691.4064.61

LCS% Recovery

70.567.469.779.792.870.687.487.380.981.754.252.451.751.854.735.196.096.077.089.492.563.952.782.572.466.165.765.488.991.464.6

.ifAS&sff•. - : -, ' ' J

Advisory Control Limits - Inorganics - LCS recovery should be 80 - 120X.


aartletl Division850 W. Bartiett Ra.Baftiett. IL 60103"el: (708) 289-3100Fax (708) 289-5445



07/19/1994


Analyte

SDUA VOLATILE COMPOUNDS 524.2BenzeneVinyl ChlorideCarbon Tetrachloride1,2-DichloroethaneTHchloroethylene1,1-Dichloroethytene1,1,1-TrichloroethBn*p-D i chIorobenzene


314314314314314314314314

TrueCone.

5.0

Cone.Found

4.95.04.94.54.94.55.04.7

LCSX Recovery

98.0100.098.090.098.090.0100.094.0

Advisory Control Limits • Inorganics - LCS recovery should be 80 - 120X.


Bartleti Division850 W. Bartlett Rd.Bartleti. IL 60103Tel: (708) 289-3100Fax: (708) 289-5445

QUALITY CONTROL REPORTMATRIX SPIKE/MATRIX SPIKE DUPLICATE


07/19/1994


Analyte

Prep Run MatrixBatch Batch Spike Sample SpikeMumber Number Result Result Amount Units

MSDPercent MSO Spike Percent MS/HSDRecovery Result Amount Units Recovery RPO


363

832804790355243

1.210.4400.9540.00251.051

0.316<0.0100.042<0.0002<0.040

1.000.5001.000.00231.00

mg/Lmg/Lmg/Lmg/Lmg/L

89.488.091.2100.0105.1

1.230.5000.9770.00251.022

1.00 mg/L 91.4 2.20.459 mg/L 108.9 21.11.00 mg/L 91A J2.50.0025 mg/L 100.0, .0.01.00 mg/L 10zfe2U*:2.B

MOTE: Matrix Spike Samples may not be samples from this job. V

Advisory Control Limits for HS/MSOs:

For Inorganic Parameters and GC Volatiles, the spike recovery should be 75 - 125X if the spike added value was greaterthan or equal to one fourth of the sample result value. If not, the control limits are not established. The RPO for theMS/MSO pair should be less than 20.

MS = Matrix SpikeMSO = Matrix Spike DuplicateRPO = Relative Percent Difference


Bar'lett Division650 W Bartlett RdBartletl IL 60103Tel: (708) 289-3100Fax: (708) 289-5445

QUALITY CONTROL REPORTSPIKES


Mr. Dave Hendron

07/19/1994


Analyte


SpikedSampleResult

SampleResult

SpikeAdded Units

PercentRecovery


The values reported above are for post digestion/distillation spikes.

Advisory Control Limits for Spikes - Spike recovery should be 75 - 125X.


3artielt Division350 W Bartlett Rd.Banletl, IL 60103Tel (708) 289-3100Fax: (708) 289-5445

QUALITY CONTROL REPORTDUPLICATES


Mr. Dave Hendron

07/19/1994


Analyte

SOUA VOLATILE COMPOUNDS 524.21,2-Dibromo-3-ChloropropaneBromochloromethane

Prep RunBatch Batch Original DuplicateNumber Number Analysis Analysis

3143U

<250<25

<250<25

Units RPD

ug/Lug/L


RPD - Relative Percent Difference

Advisory Control Limits for Duplicates - RPD should be less than 20.

RAW DATA

METALS

era/letters/cover, metrd

NETi i A-I-I/~MI i A iNATIONAL

ENVIRONMENTALTESTING, INC.

Sart er. D > v ' s c~350 Wes: Ba .16",

F A X T R A N S M I S S I O N N O T I C E

Date:

To: f-

company: (ri;.l

Sender:

-| i £>>iv : FAX NO ; 7.-

You should receive ~L pages, including this notice. If youdon't receive all pages, please call the sender immediately.This transmission includes:

letter/memo____ other____ project notes (Project ID:__________)

analytical report(s):Sample No(s) :_________ _________ __________

Comments: L

tbrms/fnxcov«r.frm


|® TESTING, INC.

3.0,- 01; 2 1 . . , : ;.-55: A 5a". ?• 1.aa'Het'. - cC' '--•-e; '738! 259-3- :-ax- (7CS) 239-5-

CASE NARRATIVE

Ms. Mary Jane RippECOLOGY & ENVIRONMENT, INC111 west Jackson Blvd.Chicago, IL 60604


07/20/1994


sampleNumber

DateTaken

DateReceivedSample Description

267075 Drinking Water 06/28/1994 06/29/1994

The following comments should be noted for the indicated fraction;

Volatile Organic Analysis524.2 analysis requires a duplicate analysis and a LaboratoryFortied Blank (LFB) per sample batch. MS/MSD analysis does notapply.

Metals Analysis

Barium, ICPCadmium, ICPChromium, ICPMercury, CVAAsilver, AA

Initial CalibrationVerification Standard

% Recovery106.2103.5108.2118.4*109.9

InterferenceCheck Standard

% Recovery87 . 986.585. 1Not ApplicableNot Applicable

*The footnote supplied with the raw data states that the ICVis above control limits, only results below the reportinglimit (<0.002mg/L) were accepted.


^Quality Assurance Coordinator


Bartlett Division850 W. Bartlett Rd.Bartlett , IL 60103Tel: (708) 289-3100Fax: (708) 289-5445

ICP DATA BOOK COVERSHEET

Explanation of Acronyms

RB = Reagent Blank PB = Procedure BlankRLVS = Reporting Limit Verification StandardSRM = Standard Reference Material (from an outside source)ICS = Interference Check StandardS2 = Continuing Calibration StandardPS = Procedure StandardMS/MSD = Matrix Spike/ Matrix Spike Duplicate

S2, ICS, PS and Spike Concentrations:(Unless otherwise noted)

All values are in mg/L

Element

AlAsBaBeCdCoCrCuFeMn

Boron

S2

2.00 £oC2.00 f2.00 '1.00 ajjf1.00 ^ ,1.00 V*2.001.00 i2.00 'l^v1.002.00

ICS

>>eO^2.002.001.00

î!oo2.00LOP-

•Jtffo *j&1.002.00

PS andMS

^ 1.001.001.000.500.500.501.000.50

<*" 2.000.500.50

Element

MoNiPbSbSeSrTiTlVZn

S2

1.001.002.002.002.002.001.002.002.002.00

ICS

1.001.002.002.002.002.001.002.002.002.00

PS andMS

0.500.501.001.001.001.000.501.001.001.00

Sample Calculation to/3* fa.Cone, x dilution 0.352 x 100/2.08 = 16.9

All sample concentrations are in mg/L unless otherwise noted.

-•LASMA 4OO Analysis Ver . '.o Fri 07/15/94 - iO:

R e D1icates:1

39 : 10

'lethad File Name: bqqrp-• arks: analyst mjb

tl!91se!96as!97sb2O7zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396

EMEMEMEMEMEMEMEMEMEMEMEMEMEMEM

178711634O152O31350272637184182964518O29191061957919811165O9237211695016869

CONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONC

10.OOO10.OOO10.00010.00010.00010.0005 . OOOO5.OOO10.00010.0005.OOO10.0005 . OOOO5.000010.000

tl!91se!96as!97sb2O7zn214pb22Ocd228ni232ba233fe238mn25Scr268be313cu325a 1396

EMEMEMEMEMEMEMEMEMEMEMEMEMEMEM

44-24-298443118244111-3132249

CONCCRNCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONC

O.OOOO.OOOO.OOOO.OOOO.OOOO.OOOo.ooooO.OOOO.OOOO.OOOO.OOOO.OOOO . OOOO0.0000O.OOO

1040 7/15/94

1O47 7/15/94

4* JLtl!91se!96as!97sb2O7zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325

1051 7/15/94O.O82O.O5OO.O38-O.O58-O.O04O.OO5

-O.OO2O-O.OO1O.OO3-O.O01O.OOO0.007O.OO27-O.OO21

peak-noisypeak-noisy

peak-noisy

peak—noisy

peak—noisypeak—noisywindow—edgewindow—edgepeak-noisy

1O56 7/15/94tli91se!96as!975b207zn214pb220cd228ni232ba233fe238mn258cr268be313cu325a 1396

Ic/tl!91se!96as!97sb207zn214pb22Ocd228ni232ba233fe238mn258cr26Bbe313cu325a 1396

11191se!96as!97sb2O7zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91se!96as!975b2O7zn214pb22Ocd228

O.2420.081O.2O5O.445O.O82O.113

O.O41OO.O43O.085O.094O.O44O.O92O.O418O.O4110.932

'I

31

r/O.4O3O.146 o-ir>O.181 * °c?C

-O.O23 —/0.1OO0.212'

0. 3O23O.1242.1270.7990.1080.171'

0.37O60.2313

O.319 0 - 3 *

O.152 IO.O58O.O351.O16 /-0.004O.O2O

-O.OO19-O.OO1-O.OOOO.OO10.000O.OO3O. OO32O.OO21-O.O11

1O.O24O.O890.081-0.017O.OO2O.O22

-0.OO3O

11O1 7/15/94

1106 7/15/94

peak—noisy

peak-noisypeak—noisy

window—edgewindow—edgepeak—noisy

peak—noisywindow—edge

window—edge

1111 7/15/94

peak-noisy

peak-noisy

peak-noisy

ba233fe238mn258cr268be313cu325a 1396

OffA

tl!91se!96as!97sb207zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91

-0.0000.005O.OOOO.OO60.O032-O.O003-O.O11

1.037o.oia0.047-0.042O.OO3O.029

-O.OO08O.O01-0.001-O.OO3O.OOOO.OO8O.OO17O.O056-O.011

0.294

peak—noisypeak—noisy

peak—noisywindow-edgewindow—edgepeak—noisy

1116 7/15/94

X> i -a j"i-7

peak—noisypeak-noisypeak-noisywindow-edgewindow—edgewindow—edgewindow—edge

peak—noisy

1121 7/15/94

/Tcr268be313cu325a 1396

t!191se!96as!97sb207

pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91sei96as!97sb2O7zn214pb220cd228ni232ba233fe238mn258cr268be313cu325

0.977O . 46900.45843.064

0.196O.O490.042-O.O510.6253.811

-O.O019O.O390.7211.3740.812O.OB7O.OO21O.O1272.O56

O.O680.1O80.076-O.O250.7O76.234

-0.0019O.O240.9234.2970.836O.197O.OO23O.O219

peak—noisy

1150 7/15/94window-edgepeak—noisy

peak-noisy

window-edge

1155 7/15/94peak-noisywindow—edge

window—edge


window-edge

77/3

zn214pb220cd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91se!96as!97sb207zn214pb220cd228ni232ba233fe238mn258cr268be313cu325a 1396


tl!91se!96as!97sb207zn214pb220cd228ni232ba233fe238mn258cr268be313

i.9922.0351.02421.O212.O662.O321.0142.O531.O1271.OO25O.966

O.O92O.O36O.O65-O.O22O.OO3O.OO9

-O.OO2O0.003-O.OO1O.OO1O.OO1O.OO5O.OO21O.OOOOO.O71

0.012O.1O6O.O27

-O.O43O.113O.O24

-O. OO37O.OO34.762.805.056

0.003O.OO21O.16O71.641

1.O,

O.O17O.O670.1O9

-0.052O.O41O.O18

-O.OO1OO.O073.565O.057O.O18O.OO3O.OO19

121O 7/15/94peak-noisy


peak-noisypeak—noisypeak—noisy

window—edgewindow—edgepeak—noisy

1215 7/15/94window—edge

peak-noisy

peak—noisy

1221 7/15/94window—edgepeak-noisypeak-noisywindow—edge

peak—noisy

window—edgewindow-edge

a 1396 O.447

1226 7/15/94tl!91se!96as!97sb207zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91se!96as!97sb207zn214pb220cd228ni232ba233fe23Bmn258cr268be313cu325a 1396


tl!91se!96as!97sb2O7zn214pb22O

0.048O.O35O.O73-O.O340.2840.029

-O.OO140.013O.0161.263O.027O.O36O.OO17O.O39O0.6O9

0.021O.O26O.O54-O.O34O.O1O0.027

-O.OO29-O.OOO2.5270.392O.027O.011O.OO17O.OO32O.353

O.083O.O12O.221O.O2OO.O650.033

-O.OO1O0.052O.O660.6O8O.O130.147

O.OO21O.O127

4.7O8

0.0450.067O.11O

-0.0330.1560.031

peak-noisypeak-noisywindow—edge

peak-noisypeak-noisypeak—noisy

window-edge

1231 7/15/94peak-noisypeak—noisy

peak—noisy

peak—noisywindow-edge

1236 7/15/94peak-noisywindow—edge

peak—noisy

peak-noisy

1241 7/15/94peak-noisy

peak—noisy

peak—noisy

(S-

ni232ba233fe238mn258cr268be313cu325a!396

tl!91se!96

sb2O7zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91se!96as!97sb2O7zn214pb22Ocd228ni232ba233fe23Bmn258cr26Bbe313cu325a 1396


0.0061.2350.4420.029O.OO8O.OO21O.O5260.7O9

0.131O.O640.128-O.O250.583O.O660.OOO2O.O25O.4992.2160.070O.O28O.OO25O.139122.O61

O.O58O.O790.097

-O.O45O.334O.O61O.OOO8O.OO51.4O91.380O.195O.O10O.OO19O.1311O.764

O.O25O.067O.O5O-O.O45O.O10O.O14

-O.OOO5O.OO10.2310.316O.O390.007

O.OO17O.OO351.367

peak-noisy

window-edge

peak—noisy

1246 7/15/94

peak—noisy

peak-noisy

window-edge

1251 7/15/94

peak—noisy


peak-noisy

1257 7/15/94peak-noisypeak—noisywindow-edge

peak-noisy

peak—noisypeak-noisy

peak-noisywindow—edge

tl!9ise!96as!97sb2O7zn214pb220cd228ni232ba233fe23Bmn258cr268be313cu325a 1396


tl!91se!96as!97sb2O7zn214pb220cd228ni232ba233fe238mn258cr268be313cu325a 1396

tl!91se!96as!97sb2O7zn214pb22Ocd228ni232ba233

0.263O.O49O.204-0.007O.361O.O61

-O.O012O.O77-0.00224.1372.O29O.O300.0021O.O455O.S52

1.9411.9662.O152.O142.0352.O8O

1.O2541.0011.9962.O171.0132.O51

0.98131.0O93

1.OO3

O.O56O.O79O.O51-O.OO8-O.OO3O.O09

-O.0015-O.005-O.OOOO.OO7O.OO1O.OO7O.OO170.0012O.O70

O.114O.O53O.119

-0.0570.418O.O43O.OO25O.OO7O.265

window-edgepeak-noisy

window-edge

window—edgepeak-noisy

window-edgewindow-edge

1307 7/15/94

1312 7/15/94peak—noisy

peak—noisy

peak—noisypeak—noisypeak-noisypeak-noisy

window—edgepeak—noisywindow-edgepeak—noisy

1317 7/15/94

window—edgepeak-noisywindow-edge

window—edge

peak—noisy

mn258cr268be313cu325a 1396

3 JLtl!91se!96as!97sb207zn214pb220cd228ni232ba233fe23Bmn258cr268be313cu325a 1396

tl!91se!96as!97sb207zn214Pb220cd228ni232ba233fe238mn258cr268be313cu325a 1396


1.244o.ooa0.0019O.01831.552

O.O25O.O79O.O81-O.O43O.O060.025O.OOO2-O.OO10.0540.2280.187O.OO6O.OO190.00441.O21

O.O54O.OO9O.O33-O.O65O.598O.135O.OO76O.O76.280.750

tl!91se!96

0.4.0.969O.O12O.O017O.0916O.798

O.O450.067O.O46-O.O680.033O.O15

-O. OO2O-O.OO20.0910.2400.13OO.OO2O.OO15O.OO95O.31O

O.O56O.O54

peak-noisywindow—edge

window—edge

1323 7/15/94peak—noisywindow—edge

peak-noisy

peak—noisy

peak—noisy

peak—noisy

1328 7/15/94peak-noisypeak—noisypeak-noisy

window—edge

1333 7/15/94window-edgepeak-noisywindow—edgepeak—noisy



peak-noisy

1338 7/15/94

sb2O7zn214pb22Ocd228ni232ba233fe238mn258cr268be313cu325a 1396



Ktl!91se!96as!97sb2O7zn214pb22Ocd228ni232ba233fe238mn258cr268

-O.0520.0120.013

-O.OO14O.OO80.1730.088O.O22O.OO9O.O015O.O0350.7O3

1.9722.1582.O482.0022.O151.994

1.O1O11.O142.0O52.O041.OO32.O29O.98911.O0130.955

0.016O.O430.086-O.O19-O.OO1O.O33

-O.OOO3-O.OO3O.OO3O.OO5O.OO1O.OO6O.OO13O.OOO90.095

1.7101.7691.7941.7751.6792.180O.8654O.7941.758

171.622O.8691.7O2

peak—noisy

peak—noisywindow—edgepeak-noisy

peak—noisywindow—edge

peak-noisy

1343 7/15/94

1348 7/15/94

window—edge

window—edgepeak-noisypeak—noisywindow—edgepeak—noisypeak-noisy

window-edge

1353 7/15/94

cu325a 1396

tl!91se!96as!97sb2O7zn214pb220cd228ni232ba233fe238mn258cr268be313cu325a 1396


tl!91se!96as!97sb207zn214pb220cd228ni232

tl!91se!96as!97sb207zn214pb220cd228ni232ba233fe238mn258cr268

0.8477438.326

-O.O06O.O4OO.O45-O.O39-O.O06O.O12

-O.OO19O.OO1

-O.OO1O.OO7O.OOOO.OO5

-O.0013-O.OO53

O.O1O

0.052O.O28O.O7O-O.O57-O.OO50.017

-0.0012-O.OO4-O.OOOO.OO4-O.OOOO.OO7

-O.OO17-O.OO41O.OO6

O.O51O.O7OO.O86-O.O72-O.OO5O.O11

-O.O012-O.OO6

O.O68O.O72O.O45-O.O51-O.OO2O.O23

-O.OO1O-O.OO4O.OO3O.OO4O.OOOO.OO4

1358 7/15/94peak—noisypeak—noisypeak-noisypeak—noisywindow—edge

window—edgepeak-noisywindow-edge

window—edge

window—edge

peak—noisy

14O3 7/15/94peak-noisvpeak—noisypeak—noisy

peak-noisypeak-noisypeak-noisy

peak-noisypeak-noisypeak-noisy

window-edgepeak—noisypeak-noisy

14O8 7/15/94peak—noisypeak—noisypeak-noisy


window—edge

1421 7/15/94

peak-noisywindow—edgepeak—noisypeak-noisy

window-edge

peak-noisypeak-noisypeak-noisywindow—edge

5 -0.0009 peak-noisya!396 0.008 window-edge


I® TESTING, INC.

Bartlett Division850 W. Bartletl Rd.Bartlett, IL 60103Tel: (708) 289-3100Fax: (708) 289-5445

AA DATA BOOK COVERSHEET

Explanation of Acronyms

RB = Reagent Blank PB = Procedure BlankRLVS = Reporting Limit Verification StandardSRM = Standard Reference Material (from an outside source)S2 = Continuing Calibration StandardPS = Procedure StandardMS/MSD = Matrix Spike/ Matrix Spike Duplicate

Values in the "Abs or Cone" column are concentrations for allparameters except Selenium, and Mercury which are abs. values.

On parameters where results are read out in concentration athree point curve is run to show linearity. The instrumentis then calibrated to the high standard, and concentrationsare read directly off the instrument.

On Mercury and Selenium, a three point curve is run and theresults are obtained as follows:

Conc.= ( Abs. of sample - blk ) x response factor x dilution

All sample concentrations are in mg/L unless otherwise noted.

ATOMIC ABSORPTION

Metal Spl No. std abs coneset abs or cone abs-

blank dilution digestionwt/vol Result mg/L

y /.<?<? 0

0-250

\cVo,

LCC

loy. / »*

3^3 L o,o.

/•/C"lot 1,00 357/ o x

0.37 i

L0,000 1

7e'.&oo 1

1..00O 2 #2-0 I1.00 L0-50

O-WOof

IMM. ('012.

11

M-S

0 -ooo 1

J*£_ L I.DSInotes A/* >

*mg/L unless otherwise noted

NET Analyst: Date:

ATOMIC ABSORPTION InMetal Spl No. std abs cone

set abs or cone abs-blank dilution digestion

wt/vol Result mg/L

.ooo f t l . A

0-000

Z(.1l37tJ3 (OQoy

0.0-Otl0.001fl.gW n6f2&71H 0 00% O-oVp

^/•cecXL 0.513

rv/. *</ /n .QM 7——

HO./.ttoc) / -,&Q.QttA / g 5 ICO.*} &Ao.oso <7-0

(Qy a.o 1(1-0

6*000/00nt /?•?!

'<?<? ccv / /

WW 4-015 •JLJ$notes

*mg/L unless otherwise notec

NET Analyst: Date: fofa

ATOMIC ABSORPTION



261132 A,167/33j.t) QQ /

0.000

L£> 00/0 . O/6

ce- Orcqqis0-0. Go'1

0.001 -^100*113.67*

^T8.01$O'OOl-

0 O'ot- /0.0ft

V-003 100*1 1 5.21*0.0010.00$ too*] /2. If, <o °^0 00 Z.

V' Dt

267^3 o.ooi

IblMO o-oit- roe0.0025 Q.OS\ 1 / I 0-oonbl* 0 Oo\

'7

y^notes

*mg/L unless otherwise noted

NET Analyst: Date:: "7,


Barttett Divisional'850 W. Bartlett Rd.Barttett, IL 60103 ^Tel: (708)289-3100Fax: (708) 289-5445

METALS PREP COVER PAGE

Methods used for preps:

Total Metals aqueous - SW846 method #3010

Total Metals non-aqueous - SW846 method #3050

Silver aqueous - SW846 #3010 (modified to included theaddition of NH4OH to basify samples)

Silver non-aqueous - SW846 #3050 (modified to includethe addition of NH4OH to basify samples)

SW846 method #3020

SW846 method

GFAA aqueous

Mercurys74 T I if V T-f

* All prep batches include a prepped blank and standard.

NET DIGESTION LOG

DIGESTION TYPE:

Analyst Initials:X

DATE PREPPED:

Prep Batch #

. 7 9 I

Z-/

"T .26773?r<< ^6-77 37

ATOMIC ABSORPTION



0. 000

o ,000 -i 0. O'-ff?

HI >, O O O-oo?o.o OQ

0,000

it* o.oisQ ,

LoZQJ. /oo y /

/Q.QQIO 0-010

0-051 C£ » 0

I/I/I

' / 'o-oo\ d. '' i /noi- IO. OOSQ

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O.OOtS o.oeo / 0 • 003^100026 0 - 0 6 1 0,

367N1 /0,001 ^0-0001.

D-OOi 1 /J67'52, 0-001^67/5 1 0 - 0 0 1 /

o .oo ir- 0.00\

notes 7^7 J/«

IC\J O.I l

l t- W ~H *V *mg/L unless otherwise noted

NET Analyst: Date:6 l

ATOMIC ABSORPTION



G 0010*0°)0 *

0.0025 (}>{)</£o- oo\O-Ool / .

1 / )oo9/y

Kef 0 ool0.001

o.ool26"? -7U 0-OOi

O-OOL-

CCN/o.oolQ.OW • / I

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NET

SAMPLEPREPARATION LOG

era/lettens/cover.prep

INSTRUMENTINJECTION LOG

5 ex.-\JoAt>* D"

era/letters/cover.inj

NET-BARTLETT DIVISION : SAMPLE PREP LOG

.,rt OA

To/"

Spike I.D.Spike

Amt. Batch OA Spike I.D.Spike

Amt.

Qi ,JBatch #:__

Date Started: 7/J/^V GKj'4<:^~--\) \

Analyst: ^< C l V

Sanple # DateExtracted

Blank SurrogateI.D. Amount

SampleAmount

S)J

FinalVolume

AdjustedFinal Vol

Date Cone. /Analyst C I eanupProcedure

Comments

I-2667?? lO

^L ^

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Reviewed by:

NETBartlett Division

HP 5970GC/MS INJECTION LOG

INSTRUMENT ID: 7o0

ANALYST: X

DATE > FILE ALSPOS#

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n/z Int . m/z

38.0039.0041 .0043.9044.9049.0549.9550.9551 .9552.9556.0057.006 1 . 0062.0563.0565.0568.9573.0074.0075.0076.0077.0078.0079.0580.0581 .0582.0583.0585.0585.9587.0091 .0092.0093.0094.0098.0599.05

46.00370.0036.00254.0022.0031.00905.003603.00178.0012.00106.00285.0054.0039.00146.0063.00

4397.0023.00303.00519.00177.00

3280.00235.00200.00168.00243.0052.0069.0035.0056.0027.0059.0049.00287.0027.00186.00209.00

99.95100.95102.95104. 10105. 10107.00108. 1011 0.001 1 1 .001 12.05II 6. 05II 7. 0511 7. 95122. 10123.00124.00125.00127.00128. 15129.05130.05134.05135.05136. 10137. 10140.00141 . 10142. 10143.00146.05147. 15148.05149.05151 .75153. 10154.001 55 . 1 0

50PPM

91

Int.

21129386675788145

212428839464964155863837

3074251

1Z2810238

1 1 1335214

137482826651283018433463

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.00

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.00,00.00.00.00'.00.00.00.00.00.00.00.00.00.00.00.00.00.00

BDP luLZI

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m/z Int .

1 56 . 1 0157.20159.00160. 10161 . 15162.05165. 15166.05167.05168.05172.10173.10174.10175. 10177. 15178.25179.05180.15181 .15185. 151 86 . 1 0.187.10188.20189. 10191 .20192.10193. 10194.05t 96 . 1 5196.85198. 15199. 15201 .55203.20204.20205.20206.20

98.0024.0016.0043.0059.0022.0046.0039.00268.00157.0027.0041 .0051 .0088.0048.0016.00199.00128.0074.0095.00

731 .00219.0018.0046.0029.0057.0077.0014.00

215.0036.00

6942.00465.0034.0039.00

161 .00314.001295.00

128

6.36

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207.20208. 102 1 1 . 1 5216. 15217.05218.20221 .20223.20224.20225.20226. 10227.15228.25229.15231 .25234.05235.20237.20239.10241 .20242.20243.25244.25245.25246. 15247. 15249.05255.20256.20257.20258.20259.20265. 15266.05273.20274.20275.20

Int.

167456324343414937571719622

2713955302224201 1134043644771002324

29264053314527521295242

1452

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276. 15277. 15283. 15285.30293. 15296. 15297. 15303.30314. 15315. 15316. 15323.20324. 10327.25333. 15334.20335.20346.25352.20354.20365. 15366.05372.20373. 10383.20390. 10402.20403.20404.00421 . 10422.30423.20424.25441 .25442.25443. 15444. 15

Int .

186.00101 .0017.0017.0027.00340.0040.0040.0020.0034.0021 .00120.0020.0019.0012.0069.0022.0022.0046.0033.00140.0021 .0064.0015.0018.0013.0026.0034.0017.0038.0042.00293.0056.00758.005349.001023.0094.00

initial lauDrauon uaiaHSL Conpounds

Case Ho:

Contractor: hiT-tiiduest, INC.

Contract Ho: 05003!

Instrunent 10: 70020

Calibration Date; 07/12/54

fiininun u for SFCC is 0.05 Haxinun i' R3u for CCC is 36.0*

Laboratory ID: >06125 )D6i26 >G6!30 >06131 >08132Rf Rf Rf Rf Rf

Conpound 20.00 50.00 80.00 120.00 160.00 Rf I RSD CCC SrCC

FyridineN-niirosodinethyiamne2-fluorophenolPhenol -d6Fhenolbisu-ChloroethyDether2-Chiorophenoii ,3-uichiorobtnzene1 ,4-DichiorobenzeneBenzyl alcoholi,2-0ichiorobenzene2-rtethyiphenolbisu-chloroisopropyl )ether4-nethylphenolH-Hitroso-di-n-propyianinenexachioroeinamnnilineN'itrobenzene-d5nitrobenzeneIsophorone2-Niirophenoi2,4-uinetnyiphenoiBenzole acidbisu-Chioroethoxy/neihane2,4-flichiorophenoi1,2,4-Irlchlorobenzenenaphthalene4-ChioroanihneKexachlorobutadiene4-Chioro-3-fiethyiphenoi2-nethyinaphihaieneHexachiorocyciopentadiene

1.52553, 72275

1 . 36742i . 774372.10310i . 657731.421631.476121.5210!.84725

1.357411.31C592.543791.381531.03532.61396

2.53784.39G50.41902.81 5! 9.18875. 35072.08446.52196,26166. 25263

1.02752.36062.14116. 25623. 60622. 1 9226

1.79961.81676

1.34966i . 635772.058791.643501.468131.467761.461 60.89819

1.41743i. 356892.652251.427671.11546.60653.

2.63150.40165. 42507.63758.20454. 35726.13740. 5200!. 27629. 29377

1.03464.36626.14443.31458.60934.23830

1.6! 404.74299

1.276051.691191. 55725t. 574351.409121.384571.38500.87358

1.336231.272512.36551i. ,37388i. (H561.55544

2.51746.38743.4048!.7506!.15402.34076. 1 3372.50116.25665.27! 16.55585.36165, i 3362. 30356. 57676.25153

1.66454.75496

1.245201.575641.755511.572571.37! 67t . 33765i. 37356.87564

1.26746i. 244562.310631.323161.05535

.551262.36333. 39273.35621.75516.15709.33932.15606.49363.26136.26997.53753.38740.13210.30110.56364.27455

1.60648.76965

1 . i 24961.451H1.54481i. 530391.350231.309661.31434.65347

1.25216i.i2itt2.269011.297281.0408!.57501

2.08387.36058.36697.76661,o?06.32811.17456.47145.25412.25841.87126.37155.12757. 25732. 53327.28251

1.64252.76144

1.272701.666461.664701.5957!1.406151.399161.41513.86963

1.336141.261362.426361.366741.05855

.597242.43060.39070.40682.60515.19630.34324. 1 3724.50166.26206.27715.56628.38156.13576.30264.57828.24791

6.4.7.9.

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214.3.5.7,1.5.2.5.

14.

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uonc=4fl.u,iflC.0,160.0,240.0,320..(Conc=40.0,100.0,160.0,240.0,320.

Rf - Response factor (Subscript is anouni in uo/nl)

ft - fiuerage Response factor

liSO - Percent Relative Standard Deviation

CCC - Calibration Check Conpounds <••) SFCC - Systai Ferfomance Check Conpounds \»«)

forn In rage i of 3

initial iauorauon uaiatiai Conpounos

case no:

Contractor: HCH'iiduest, IKC,

Contract no: 050031

Instrument Iii;: iuuiu

Calibration Date: u?v 12/54

Nininun Rf for 5FCC is 0.05

taooratory iu: mutRf

tonpouno

2,4,6-inchiorophenoi2,4,5-Iricbiorophenoi2-Chloronaphthaiene2-fiuorobiphenyi2-nitroaniiineDiwthyiphthalatenceoaphthyiene2,6-Dinitrotoiuene3-Hitroanliineficenaphthene2,4-Dinitrophenoi4-iiitrophenoiDibenzofuran2,4-uinitrotoiueneDieihyiphthalaie4-Chiorophenyi-phenyietherfiuorene4-Hitroaniiine2,4,6-Iribronophenoi4,6-Binitro-2-flethviphenoiOi-phenylhyo'razineN-fiiirosodiphenyianine \i)4-BroNOphenyi -phenyietherHexachlorooenzeneFentachiorophenoiPhenanthreneftnihraceneCarbazoieui-n-butyiphthalatefiaorantheneryreneTerphenyi-dli

L(i.(M

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Rf - Response factor (Subscript is anount in ug/ni.)

Rr - fiverage Response factor

iRSO - Percent Relative, Standard Deviation

CCC - Cailbraiion Check Conpounds v») 5FCC - Systa Ferfornance Check Compounds (*•)

Font 01 rage 2 of 5

aonc=iu.u,iuu.u,iDu.u,nu,u,3£U.

initial Cahnration uataK5L Conpounos

case no: insirunent iu;

Coniractor: nEi-fliduest, Int. lauorauon uate: u//ii/rt

Lontraci no: uiuuii

Hinimjn il for 5FCC Is 6.65 iiannurt i. iSO for ILL is 30.0*

onpoun

Laboratory ID: )D6i25 /Do!26 >DBi30 )06i31 /D8132SF ia if w k7 _

20.00 50.uu 60.GO 120.GO 160.05 R7 X KiU Ul Sril

ButyibenzyipfithaiateBenzidlne3,3'-uichiorob«nzidineBenzowanthraceneChrysenebisu-LihyihexyDpnthaiateui-n-octyiphthaiateBenzo(b)iluorantheneBenzou)fiuorantheneSenzoCa/pyreneIndemni,2,3-cd)pyreneDlbenz(a,h)antnraceneBenzo(g,h,i/peryiene

.04536 .06555 .12611

.33674 .36553 .35664i. 15450 1.17168 1,16671 1

1.12533 1.09565 11.05327 1,11028 i

2.16865 2.4402? 2.42290 i2.15361 2.30040 1.46054 11.51072 1.44674 1.28886

1.33915 1.44575 i.36016 1i.04126 1.12176 i.09112 i1.13675 1.25055 1,20545 I

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.36573 7.351

12510 2.G19G3645 5.66707555 15.11575612 29.31532121 15.55125242 3.17138465 2.857

2G264 3.472

SF - Response Factor (subscript is amount in ug/nL)

RT - riuerage iiesponse Factor

i'MU - Percent «iatiue Standard ueuiation

CCC - Calibration Check Compounds (*) SFCC - 5ysien Ferfornance Check Conpounds (*»)

Forn lil rage 3 of 3

Paqe 1

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940627940627

170020

BTL# 3

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16:4516:1 600000

C o rst <:> o u n d R . r . D i o i L G n c Units

1)2)3)4)5)61

' 71819)10)11)1 2 )1 3 ).14 115)16)17)18)19)20)21 122),23)24125)26)27128)29)30)31 132)33)34)35 ;36)37)38)39)40)41 142)431

*tJ4- 1 , 4-0 i ch 1 or obenzeneP y r i d i n eN-nitrosodi rue t h y 1 am i n e2 - F 1 u o r o p h e n o 1Phenol -d6Phenolbisf 2- Chloroethy 1 Jether2-Ch 1 oropheno 1•i , 3-D i ch 1 or obenzene1 ,4-0 i ch 1 or obenzeneBenzyl alcohol1 , 2-D i ch 1 or obenzene2-Methy f pheno 1b i s ( 2 - c h 1 o r o i s o p r o p v 1 ) e t he r4-Methy 1 chenc'lN - N i t r o s o - d i - n ~ p r o p y 1 arij i rieHexach 1 or oethanefin i 1 i ne

*d8-Naphtha leneN i t r o b e n z e n e - d f > 'N i tr obenzeneIsophor one2 - N i t r o p h e n o !2 , 4 - D i me t h y 1 p hen o 1Benzo i c acidb i s 1 2-Ch 1 or oethoxy 1 rue thane2, 4-D ich 1 oropheno 11 , 2 ,4-Tr i ch 1 or obenzeneNaphtha lene4-Ch 1 or oan i 1 i neHexach 1 or obu tad iene4 - C h 1 o r o - 3 - me t h y 1 p h e n o 12~Methy 1 naphtha lene* d 1 0 - ftcenaph t heneHexach i orocyc 1 opentad iene2,4,6-Trichlorpphenol2 , 4 , 5 - T r ich > o r o p h e n o 12-Ch 1 oronaphtha iene2-F 1 uorob i pheriy 12-NitroanilineD i me t h y 1 p h t h a 1 a t e^cenaphthy lene2 , 6-0 i n i tro-to )-uene

1

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948495796990969788969';9397?<:•9194947296779095859597869096998389e,79287949898979?879o9381

REP OKI

Operator i 0 : RM"uri0 u t p u t t" i i e - ' ,.) SI 2 •/ " • •>• >.'

iliscs S S V O O ? . ) luL.21707

Quant 7 iJuant l ime- 9 4 0 6 2 7 1 6 - 4 5Lii i e c t e d a t' *?' «* 0 6 2 7 1 6 » 1 6

0 i I u t i o n Factor1 : ". , 0 ) 0 0'}Instrument IDs 7 0 0 / D

BTL# r;

i D f: i 1 e i U._ 8 2 7 0 = - F 1T i t l e - EPM Method 8270, C a l i b r a t i o n Curue, HP5970, 7007DLast C a l i b r a t i o n s 94062:5 17'07 Last Qcal Times <none>

Compound R.r. C| ion ftrea C o n c Units

44 145 }46)47)48 )4V)50)51 152}53)54 i55)56)5 7 156)5V )60)61 )6 2 )6.? 164)65)66)67 i68)69)70)7 .1 )72\','':'< l74 (75)76)7 7 )76)79)80)81)82)83)

3-N i tr oan i 1 i neflcenaphthene2 ,4-D in i tr opheno 14 -Hi tr ophenc 1D i ben z of ur an2 ,4-D i n i troto 1 ueneDiethy Iphtha late4-Ch 1 or o pheny 1 -pheny let herF 1 uorene4~N i tr oan i 1 i ne2 ,4 , 6-Tr i bf o moo he no 1

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*dl 2-Chr ysenePyreneTer pheny 1 -d 14Buty 1 benzy 1 phtha 1 ateBen 2. i d i ne3 , 3 ' - D •': >-. h 1 o r o ben -a i d i neBe n z o ( a 1 a n t h r a c e n eChr ysenebis(2-ilthyl hexy 1 ) p lit ha 1 ate

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Quant Output File' AD8129ssfJGInstrument ID* 7002D

EMU-2200 BTL# 3

Id F i1e* D. 82/0= gplTitle: EPfl Hethod 8270, Calibration Curue, HP5970, 70020Last Calibrations 940623 17s07 Last Qcal Time* <none>

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BTL# 3

Data F i 1 e » >D8l25ssD2Names BNfl ST-D. 20PPBhisc= SSTDO/0 luL.217C7

Id Fi les D_8270« s F 1 .Title: EPfl Method 8270, Calibration Curue, HP5970, 7002DLast C a l i b r a t i o n s 940623 17*07 Last Qcal Time: <none>

Operator ID* RfiMON 'Quant Time : 94-0627 16 -45Injected at= 940627 16=16

Page 2 of 2

G p e r a t o r 1 D «I ' , 1- r- 4- r i' ' « • A ' I (• I "> LJ • • I'l <":.]. J X.p u t; r 1 i e • <J o .1. /. b • • U ij

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D i "i u t i o n F s c1 o rI ":=• t r urn en :; 1 D

Li) Pi le» D 8270= =F1T i t l e : EPfl Method 8270, C a l i b r a t i o n Curve, HF597G, 7002DLast C a l i b r a t i o n s 940623 17 = 07 last Qca1, Time:

Page 1

940627 14«47940627 14s18

1 .0000070020

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< n o n e >

Corn pound R . T . Q ion flrea C o f; c Units

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1 0 )1 1 1j. ... 1

1 .•' ).1 -4 Jj. 5 )•16)17)IB)19)^ 0 I2J |22),23)24)2 5 )26 j27}28 )29)30 )3 1 )32)33 )74 )35 :36)37)38)39)40 j41 )42)43 :

*d4- 1 , 4-0 i ch 1 or obenzenePvr i d i neN-nitrosodi met ho 'i am i ne2-F 1 uor op he no 1Phenol -d6Phenolbis( 2-Ch la roethyl ) ether2-Ch 1 oropheno 11 , 3-D i ch 1 or obenzene1 , 4-0 i ch 1 or obenzeneBenzy 1 a 1 coho 11 , 2-D i ch 1 or oLenzene2-Methyl phenolbi5(2-chloroisopropyl )etj"ier4-Plethy 1 pheno 1N - N i t r o s o - d i - n - p r o p v 1 arrv i neHexach 1 or oe thanefin i 1 i ne

*d8-Naphtha Iener IN i tr obenzene-d5N i tr obenzeneIsophorone2-Nitrophenol2 , 4 - D i rue t h y 1 p hen o 1Benzo i c ac idb i s ( 2-Ch 1 or oethoxy ) methane2 ,4-D i ch 1 oropheno 11 , 2 ,4-Tr i ch lorobenzeneNaphtha Iene4-Chloroani 1 ineHexach 1 or obu tad iene4 - C h 1 o r o - 3 -me t h y 1 p hen o 12-Methy 1 naphtha Iene

*d 10-flcenaphtheneHexach 1 or ocyc 1 open tad iene2,4, 6- Tr i ch 1 oropheno 12,4,5-Trichlorophenol2-Ch 1 oron aphtha Iene2-Fluorobip hen v 12-Ni t r oan i 1 i neD i me t h y 1 p h t h a 1 a t eflcenaphthy len'e2 , 6 "D i n itr oto 1 uene

8.4.4.6.7.7.8.8.3.8.G .6.8.8.8.9.

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36848895989905163239596677809700110142212461788299991833455878558013284756836216647768

152794211299949312814614610814610-84510870

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1621801281.2722510714216423719619616217265

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3422676992349431155011570788808070313636666365063395384276064158051113470610884772225949112582129703651516891613586033162579262227684308447954762816777862952234175100298791691102058629443

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Page 2

Operator iD= RM!"M.ir-;Outnut F i l e * " Do I2B: =UOData r i l e : >0* J .28:=D5Monies Bhti STD. 50f-:PBrii SSTDOÔ I u L. 2 1 6 I 7

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940627940627

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* d 1 0 - P hen ant h r ene4,6-D'initro-2 -me thy 1 p hen o i0 i -pheny i hydraz i neN-N i t rosed i pheny 1 am i ne • ( 1 }4-Br orno pheny 1 -pheny 1 ether-Hex ach 1 orobenzenePen tach 1 or opheno 1P h e n a n t h r e n eAnthraceneCar bazo leD i - n-buty 1 phtha 1 ateF 1 uoranthene

*dl 2-ChryseneP y r e n eTer pheny 1 -d 14Buty 1 benzy 1 phtha lateBenz i d i ne3 , 3 ' - D i c h 1 o r o ben 7 i d i neBen zo ( a ) an t h r aceneChr yseneb i s ( 2-Ethy 1 hexy 1 ) phtha 1 ..ate

*dl 2 -Per y leneD i - n -- o c t y 1 p h t h a 1 a t eBenzo ( b ) f 1 uorantheneBenzo ( k ) f 1 uorantheneBenzo ( a ) py reneI ndeno ( 1 , 2 , 3-cd ) py rene >f.oeiD i benz ( a, h ) anthraceneBenzo [ g , h , i ) per y lene

14141414141415151515155.715151516

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Id Fi le': D. 8270= : F 3Title: EPfl Tlethod 8270, Calibration Curue, HP5970, 7002DLa5t Calibrations 940623 17s07 Last Deal Times <none>

Operator ID: RflMQN 'Quant Time : 940627 14:47Injected at: 940627 14:18

Pane 1 of 7

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BTL# 2

Id F i les D.._8270s :F1Titles EPfi method 8270, Calibration Curue, HP5970, 7002DLast Calibration: 940623 17:07 Last Qcal Times' <none'>

Operator 10= RflHOh 'Quant Time : 940627 14=47Injected at= 940627 14=18

Page 2 of 7

QUhr-i i R E P O R T Page 1

OperatorOutput; V iData Fi le'Names BNH

IDs h'firlON'I e •• * D a 1 3 0 = = Q D= >D813Qs 'D2[-,10. 80PPB

S S T D O S O l : j l _ 2 1 7 0 8

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94062? 17=24940627 16 = 55

1.000007002D

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li) M ie = D...8270: * F 1T i t l e : EPfi Method 8270, C a l i b r a t i o n Curye.Last C a l i b r a t ion • 940623 17 = 07

HP597C, 7002DLast lilcaJ - n o r i e >

Compound R. Q ion flrea I- o n c Units

... 1/.)? i4 '!5 1

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8)9)10)11 )12)33 i14115)16 j17)18)19)20)21 )22 i

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*d8-Naphtha leneN i tr obenzene -d5 'N i tr obenzeneIsophor one2~N i t r o pheno 12 ,4-D imethy 1 pheno 1Benzo i c acidb i s ( 2-Ch 1 or oethoxy ) meth'ane2 , 4 - D i c h 1 o r o p hen o 11. 2, 4- T rich] or obenzeneNapn tha 1 ene4 - C h 1 o r a a n i "i i n eH e x a c n 1 o r' o b u t a d i e n e4 - C n ) o r o - 3 - me t h y 1 p he n o 12 -Me thy 1 naphtha lene

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8.4.4.6 ,7.7.8.8.8.8.

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Operator il'JOutput F i leData Fi le=

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Juan t Reu: 7

Di

Page

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JUL 21.708

940627940627

17002D

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itle: fc:Prt Method 8270, Ca 1 i br at i er..ast C a l i b r a t i o n ! V40623 17 '07

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. 66

.22

.75

.67

.37

.49

.62

.44

. 00

.65

. 33

.37

. 06

.43

.09

. 14

.22

. 84

.02

.87, 35. 09.71.00. 18.75.56.95.75,62.73.47.02

ug/mLug/rriLug/rnLug/rnLug/rnLu g /mi-ll g/mLug/rnLug/rnLug/ mi-ll g/mLug/mLug/niLug/rnLug/mLug/mLug/mLijg/mL:jg/mLijg/mLug/mLug/mLug/mLug/mLug/rnLug/rnLug/rnLug/rnLuq/rnLug/mLug/rnLug/mLug/mLug/mLug/rnLug/mLug/mLug/mLug/mLug /mi-ll g/mL

• ug/mLug/mL

98899285709696978996909396999291967197809396859896828898988991959490969698969682939373

Operator ID' 'RftMUr-Output F i l e : "D8132':.QQData F i l e s >D81:52f '02Ncjfie* BNfi S T O . 1601-TRMiso = SSTD160 lul.21710

QllfiNT REPORT

Quant Reu« 7 Quant Time'Injected &t-

D i l u t i o n Factors

F'aoe 2

940627 18=42940627 18s13

] .00000

EMU-2200I n s t r u me n t I D •• 700 2 D

BTL# 6

ID File: D....9270 s s r ]T i t l e s EPfl Method 8270, Calibration Curue, HF'5~970, 70020Last Calibrations 940623 17:07 Last Qcal Time' <none>

C o m p o u n d R.T. Q ion ftrea Cone Units

44 J45 146)47)48)49)50)51 j52)53)54)55)56)57)58)59 )6or61)62)63)64)65)66)67)68)69)70171 \77 }/ 3 174)75 )76 i7 7 )78)7 y }HO i>> .1. )8 2. )83 )

3-IS i tr oan i 1 i neflcenaphthene2 , 4 - D i n i t r o p hen c 14~N i t r o pheno 1D i benzofur an2 , 4-0 i n i tr oto 1 ueneDiethylphthalate4-Ch 1 or o pheny 1 -pheny let her"V 1 uorene4-Nitroaniline2 ,4 , 6 -Tr i br ornopheno 1

*dlO-F'henanthrene4 , 6-D i n i tro-2-methy 1 pheno 1D i -pheny 1 hydraz i neN-N i trosod i pheny 1 ami ne . ( 1 )4-Br ornopheny 1 -pheny let herHexach 1 or o benzeneF'entach 1 or o pheno 1PhenanthreneAnthracene 'Carbazo leDi-n-butyl p h t h a 1 a t eF 1 uor anthene*d!2-ChrysenePyreneTer pheny 1 ~d 14Buty 1 benzy 1 phtha lateElenz i d i ne3 , 3 ' -D i ch 1 or obenz i d i nebenzo f a 1 anthraceneChryseneb i 5 ( 2 - E. t h y 1 hex y 1 ) ph t ha 1 a te

*dl2-F'er y leneD i -n-octy 1 phtha 1 ateBenzo t b ) f 1 uor antheneBenzo ( k ) f 1 uorantheneBenzo fa) pyrene1 n d e n o i 1 . 2 , 3 - c d ) p y r e n e *4D i benz i a , h ) anthraceneBen z o ( g , h , i ) pe r y 1 ene

14.14,14.14.14.14.15.15.15.15 .16.17.15.15.15.16.

. 16.17.17.17.17 .18.19.21 .19.20.20.19 .21 .21 .21 .21.23.22.22.22.23.

*•'»- *£r25.25.

12213658577030393758004567787252842249589161505285077771474955523625888530T*41264

138.153,184,109.168.165.149.204.166.65.

330.188.198.77 .

169.248.284.266.178.178.167.149.202.240.202.244.149.184.252.228.228.149.264.149.252.252.252.276.278.276.

0000000000000000000000000000000000000Qjfl

00

10455428566354824.42986M3906411304243717181.334752794561309509267510254870744625357215589796658606953695

41041040753139277043755138797570525

4151222905672464994175211583233734132686128362265110397485275943(1384152M324823

*^MPt!igO-K277136317628

165.147.183.189.139.144,148.129.142 .194.198.40.

166.169.145.117,106136.148 .149.160.124.136.40,

149 .133.164.186.149.146.139.186 .40.

129 .9?.

218.148.X fcT^î^

172.183.

91.020902488420598721690023348622356700185208100.044377788224035260034335166

9851

ug/rnLug/rnLug/niLug/rnLug/mLug/rnLug/rnLug/rnLug/rnLug/mLug/mLug/mLug/mLug/rnLug/mLug/mLug/rnLug/mLug/mL.ug/rnL.ug/mLug/mLug/mLug/rnLuq/mL.ug/mLug/mLug/mLug/mLug/rnLug/rnl.'jg/mLug/mLug/mLug/mLuq/mLug/mL"ug/rnL *ug/mLug/mL

929391.

74

vjW3989886929991929395929296929488

O/V99997939698959<*899885989893

H> 899695

* Compound is ISTD'

TCTfiL I OH CHROMflTGSRftM

'3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.011.012.013.014.015.0 j

Data F i l e » >D8132= =D2Name' BNfl STD. 160PPBMisc.: SSTD160 1

Ouant Output F i l e s "OBU2- "QOInstrument ID: 7002D

ENU=2200 BTL# 6

Id Fi le= D 8270s : F 1Titles EPfl Method 8270. Calibration Curue, HP5970, 7002DLast Calibration' 940623 17s 07 Last Qcal Times <none>

Operator ID: RflQuant Time s 940627 1.8:42Injected at= 940627 18s 13

Page 1 of 2

<auou> saw i

9 #118

uo

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i 40

f !. s 8 1 i 7, V 0176 : a e P^4 oaf u: &= O T

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TiTSGV * ITJHOI

Operator ID:Output File:Data File:Name: ICVS

RAMON~D8133::QO>D8133::D2SUPELCO

QUANT REPORT

Quant Rev: 77 Quant TimeInjected at

Dilution FactorInstrument ID

Misc: ICVS050 50PPM luL EMV=22iKi

ID File: D_8270:: FlTitle: EPA Method 8270, Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 Last Qcal Time

Pagt- i

940628 15:52940627 18:52

1.000007002D

BTL# 7

<none>

Compound R.T. Q ion Area Cone Units

1 )2)3)4)5)6)7)8)9)10)11)1.2)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28129)30)31)32)33)34)35)36)37)38)39)40)41)42)43)

*d4-l , 4-DichlorobenzenePyridineN-nitrosodimethylamine2-FluorophenolPhenol-d6Phenolbis ( 2-Chloroethyl ) ether2-Chlorophenol1 , 3-Dichlorobenzenei , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis ( 2-chloroisopropyl )ether4-MethylphenolN-Nitroso-di-n-propylamineHexachloroe thaneAniline*d8 -NaphthaleneNitrobenzene-d5 'NitrobenzeneIsophorone2-Nitrophenol2 , 4-DimethylphenolBenzoic acidbis ( 2-Chloroethoxy )methane2 , 4-Dichlorophenol1 , 2 , 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2-Methylnaphthalene*dlO-AcenaphtheneHexachlorocyclopentadiene2,4 , 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-Fluorobiphenyl2-NitroanilineDime thy IphthalateAcenaphthylene2,6-Dinitrotoluene

8446778888888889981099999

1091010101010111114121212121213131314

. 38

.82

.88

.95

.98

.99

.05

.16

. 32

. 39

.59

.66

.77

.80

.98

.01

.11

.01

.42

.21

.24

.62

.78

.82

.02

.99

.18

. 33

.45

. 58

.78

. 55

.81

.13

. 28

.48

.57

.83

.62

.16

.64

.77

.70

1527942112999493128146146108146108451087011793

1368277821391071229316218012812722510714216423719619616217265

163152165

.0

.0

.0

. 0

.0

.0

.0

.0

. 0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

.0

. 0

.0

.0'

. 0

.0

.0

. 0

.0

.0

. 0

. o

.0

.0

.0

.0

. 0

.0

.0

. 0

. 0

.0

.0

.0

380381026045318915160520673511348011425381785984109875264316945257627416267378767757594235576617145177907941108171462404554177875354931352585797873672217242803153670768109162583728981863438591402971522091338356195017599619538559943

4065731251306375617373777462706075743340647550636271746073615774627740416362806677776383

.00

.67

.46

. 27

.45

. 32

.29

.08

.96

. 38

.77

. 28

.60

.44

.87

.26

.58

.15

.00

.03

.05

.04

.92

.51

.26

.28

.96

. 23

.94

. 94

.49

. 01

.46

.00

.24

.48

. 1 3

.46

.09

.93

.57

.75

.44

ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug /mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mL

98889383719196979095939298989292967395758794899799859896998391699491979899999688949367

QUANT REPORT Page

Operator ID: RAMONOutput File: "D8133::QOData File: >D8133::D2Name: ICVS SUPELCOMisc: ICVS050 50PPM lul,

Quant Rev: 7

fcJMV--2200

Quant Time:Injected at:

Dilution Factor:Instrument It):

I'D Fi-le: D_8270::F1Title: EPA Method 8270, Calibration Curve, HP5970, 7002DLast Calibration: 940626 10:34 Last Qcal Time

940628 15:52940627 18:52

1.000007002D

BTL# 7

<none>


44)45)46)48)49)50)51)52)53)54)55)56)57)58)59)60)61)62)63)64)65)66)67)68)69)70)71)72)73)74)75)76)77)78)79)80)ft 4 1Ol }

82)83)

3-NitroanilineAcenaphthene2 , 4-DinitrophenolDibenzof uran2 , 4-Dini trotolueneDiethylphthalate4-Chlorophenyl-phenyl etherFluorene^-Nitroaniline2 , 4 , 6-Tribromophenol

*dl 0-Phenanthrene4 , 6-Dinitro-2-methylphenolDi-phenylhydrazineN-Nitrosodiphenylamine (jL )4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneCarbazole 'Di-n-butylphthalateF luoranthene*d!2-ChrysenePyreneTerphenyl-dl4ButylbenzylphthalateBenzidine3,3' -DichlorobenzidineBenzo ( a ) anthraceneChrysenebis( 2-Ethylhexyl )phthalate*d!2-PeryleneDi-n-octylphthalateBenzo ( b) f luorantheneBenzo ( k ) f luorantheneBenzo ( a ) pyreneIndeno( 1,2, 3-cd) pyrene if. « yDibenz ( a , h ) anthraceneBenzo (g,h, i jperylene

14141414141515151515171515151616.1717171718192119202019212121212322222223*) 'y

2525

.11

.20

. 34

.56

.70

.28

. 38

. 37

. 54

.98

.44

.63

.75

.69

.51

.83

.21

.48

.57

.90

.60

.49

. 50

.83

.06

.77

.71

.46

.49

.55

.52

. 35

.25

.86

.86

.28"-*r4• v A

.08

.61

138.153..184.168.165.149.204.166.65.330.188.198.77.169.248.284 .266.178.178.167.149.202.240.202.244.149.184.252.228.228.149.264.149.252.252.252.O T A£ / D .

278.276.

000000000000000000000000000000000000OA-1U/M00

4895211337717346196686'59943188729705841218675931737400997532400021841810501738504419271807617116717774119836029521316403374528170032116762127215

11375457513908213180916102058739284098256556256556-120470

m k. ^ h&o *»MVll 1873 -101597111873

786378767781776379125406851767574656467798363406563835

79636283409399

13263

•»3 6*6463

.25

.08

.25

.29

.75

.49

.81

.71

.43

.56

.00

.35

.62

. 30

.56

. 33

. 14

.03

.46

. 35

.44

.86

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. 21

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.96

.22

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.88

. 38

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.21

.49

.23

.48•7-**-.30. 34

ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/roLug/mLug/mLug/mL

• ug/mLug/mLug/mL

9292976975"

\Jo978394999697939593949692949799|3

-39998989999089889799989892ft QO "

9696

* Compound is ISTD

-if4(

JL_•>.

ii-•3- •»'.

,'J 5.U 6.0 7.0 8.0 V.Q 10..; 11.0 li .0 i; . J 1*.015.0

Data File: >D8133::D2Name: ICVS SUPELCOMisc: ICVS050 50PPM luL

Quant Output File: "D8133::QOInstrument ID: 7002D

EMV=2200 BTL# 7

Id File: D_8270: :F1Title: EPA Method 8270, 'Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 Last Qcal Time: <none>

Operator ID: RAMON \Quant Time : 940628 15:52Injected at: 940627 18:52

Page 1 of 2

,e *i S •'.; I

1 ,

i! f !: I:' := !! Ii: il i! ;r

Data File: >D8133::D2Name: ICVS SUPELCOMisc: ICVS050 50PE-M luL

Ouant Output File: 'D8133::QOInstrument ID: 7002D

EMV=2200 BTL# 7

Id File: D_8270: :F1Title: EPA Method 8270, 'Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 Last Qcal Time: <none>

Operator ID: RAMON <Quant Time : 940628 15:52Injected at: 940627 18:52

Page 2 of 2

QC REPORT

MS 8EMI-VOLATILES

era/I etters/cover .wsemi

SBSEMIUOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE <DFTPP)

Lab Name: Contract:

Lab cede: Case No.: SAS No.: SDG No.:

Lab File ID: >D8!94

Instrument ID:

OFTPP Injection Date: 7/06/94

DFTPP Injection Tine: !0:44

! it1

!'1!}1

!11

-4,1!!>

i1iii

n/e i

51 !63 i69 !70 i

1 27 !197 !198 1199 !275 !365 !441 i442 1443 i

1

ION ABUNDANCE CRITERIA

30.0 - 60. 0X of mass (98Less than 2.0X of mass 69Mass 69 relative abundanceLess then 2.0X of nass 6940.0 - BO. 0% of nass 198Less than 1 .0X of nass 198Base Peak. I00X relative abundance5.0 - 9.0X mass 19810.0 - 30. 0X of nass 198Greater than 1.00X of nass (98Present, but less than nass 443Greater than 40.0X o'f nass 19817.0 - 23. 0X of nass 442

ABUNDANCE i

49.2 !0.0 ( 0.0)1 t63.4 !0.0 ( 0,0)1143.6 i

.3 !100.0 i6.5 !

20. t i2.1 !

12.1 t78.8 !14.9 ( 18.8)21

1I-Value is X of nass 69 2-Ualue is X of nass 442

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

i!!

01!02!03104105 106 i07 i08109110!(I!(2!13!14!(51(6!17!18!19!20!21!77 \

EPASAMPLE NO.

BNA STD. 5BTt260176BNA BLANKBNA LCSBNA LCSDUPBTt266777BT*267075BTt267l62BTI267189BTt267!90BTt267l9tBTf267l92BTt2671938TI267t94BTt267l95BTi267l96

! LABi SAMPLE ID

! SSTD050! F CK! SUBLKi LCS (00i LCS 1001I

! E&E! NE ILFi NE IDi NE ID! NE !Di NE ID! N NOi N NO! N, ND! Nl. .VDi!!!!!

! LABFILE ID

i >D8(95i >08I96i >08I97i >D8I98! >D8I99! >D8200! >D820I! >D8202! >D6203i >D8204! >D8205

>08206! >08207i >D8208! >D8209i >D82I0t1

! —!! " —!»

DATEANALYZED

07/08/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/3407/06/9407/06/9407/06/9407/06/94

—

! TIME! ANALYZED

! 11:09i 11:51! 12:36i 13:15i 13:54! 14:33! 15:13! !5:53! 1 6 : 33i I7:t3! 17:52! 18:31

(9:11i 19:51t 20:30! 21:09i!i1 .It

File >08194 35.0-514.0 *ttu. fOP050

32000-

3008ft

28000-

26080-

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2200ft

2888ft

18999-

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14008

1200ft

1000ft

800ft

608ft

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50PPCI BOP luL21128

90 100 110 120

54605

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>oei94 eopese87 ADD

File: >D8t94 Scan t:

n/z Int. n/z

36.8538.ee39.ee39.904t.ee42.ee43.ee43.90se.es50.9552.0555. tese.ee57.00et.eeez.es63.es64.eses.es67.es68.9573. te74.ee75.ee76. te77.ee78.ee78.9579.9581.0581.9582.9584.9586.05

156934076651647

1051780

3181169511132t72829tzz145614

4(00Z7Z57490158

2958218190140ZZ262524141

.00

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.00

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.00

.00

.00

.00

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.00

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.00

.00

.00

91.0092.0093.0094.0095.9598.0599.05100.95102.95104.00105.10106.20107.00108.00109.0010.0011.0016.0517.0518.05I2Z.00123.00124.00125.10127.00128.05129.05130.05134.05135.05136.10137. 101 4 1 . 00142. t0

50PPM BOP luL2

87 Retn. tine:

Int. n/z Int.

38.0060.00298.0024.0011.00168.00210.00126.0025.0067.0035.0022.00727.00130.0016.00

t 953. 00268.003e.ee447,0026.0027.0085.0028:0024.00

2819.00208.eet23e.eettz.eezz.ee91 .0024.0021.00100.0040.00

143.10147.15148.15149.05151.35153.10154.00155.20156.10157.00158.10160.10161.05165.05166.25167.15168.05173.20174. (0175.10.176.10t77.ee179.15tee. istst.es185.15186.20187.20189. te192.10193. te196.15i97.est98.es

21.62.127.22.11.24.25.68.tea.te.17.46.37.45.17.

246.183.33.57.80.37.56.178.126.65.71.679.202.41.52.36.198.17.

6463.

eeeeeeeeee0000eeee00000000003000eeee000000000000eeeeeeeeeeeeee000000

128

6."Z7

n/z

199.05200.15201.35203.10204.20205.20206.10207.20208.10210.25210.55210.95216.05217.05217.9522 1 . 1 0223.10224.20225.10227.15229.25237.10241.10242. Z0Z43.Z5Z44.Z5245.15246.15249.05255.20256 . 1 0257.10258.20259.20

Int.

420.0034.0025.0031.00167.00306.001238.00193.0039.0027.0015.0048.0015.00305.0037.00459.0078.00648.00172.00235.0050.0013.0012.0026.0050.00578.0075.0087.0015.00

2623,00363.0033.00133.0015.00

n/z

265.15273.20274.10275.20276.25277.25278.05296.25297.15303.20315.05316.15323.20324.10334.20341.20346.15352.20353.30354.20365.15372.30402.20403.10404.20421.20422.10423.20424.25441.25442.15443.15444.25

Int.

62.0083.00209.001Z99.00157.0096.0013.00Z88.0044.0022.0036.0011.00116.0013.0075.0012.0030.0021.0017.0041.00135.0068.0036.0050.0011.0031.0037.00297.0082.00785.005094.00960.0094.00

2CWATER SEMIVOLATILE SURROGATE RECOVERY

Lab Name: Contract:

Lab code: Case No.: SAS No.: SD6 No.:

! EPAi SAMPLE NO.

0l!BTt26017602IBNA BLANK03IBNA LCS 104IBNA LCSOUP05!BTt26677706IBTt26707507IBT126716208IBTt26718909!BTt26719010!BTt26719l11!BT*267192121BTt26719313!BTt26719414IBTt26719S15IBTt267l9616!17!18119120121!22!23!24!25126127!28!

SI 1 S2 1 S3 1 S4 1 SS ' 1 SB 1 57 STOTI( NBZ )t 1 ( FBP )t ! ( TPH )t 1 ( PHL )t i ( 2FP )* 1 ( TBP )* I ( )t ! OUT !

42 1 37 *! 66 i 25 ! 40 ! 63 !61 1 50 ! 8066 i 58 i 8067 ! 58 ! 79636871486176456625 •6959

————!

——————

——————

291 !

49 ! 7856 1 8053 i 6644 ! 4859 ! 5158 i 6039 »1 30 *54 t 5313 •! 10 *68 1 6450 ! 53

1

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l

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40 ! 56 1 80 1! ! ii 1 1! ! !! ! !I l l1 1 1

1 1 !: i i! i 11 ! !! ! i! 1 !i !

1 ! i ! 1! ! ! 1 !

30! 1 ! i ! i 1 !

1 !/010!0! 3lo0!01J/00!010!0120520

«/

v•s

515253545556

(NBZ)(FBP)(TPH)(PHL)(2FP)(TBP)

Nitrobenzene-d52-FluorobiphenylTerphenyl-d14Phenol-dB2-Fluorophenol

QC LIMITS(35-114)(43-116)(33-141)(10- 94)(21-100)

2 ,4,6-Tribronophenol (10-123)

t Column to be used to flag recovery values* Values outside of contract required QC Units0 Surrogates diluted out

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3CWATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Nane: Contract:


Matrix Spike - EPA Sample No.: LCS/LCSDUP SEP 7-5-94 FV-1.0

1t1

COMPOUND i

Acenaphthene !Acenaphthylene !Anthracene !Benzo<a)anthracene !

' Benzo(b )f luoranthene !8enzo(k )f luoranthene !Benzo(a )pyrene !Benzo(g,h ,i )perylene 1Butylbenzylphthalate !bis(2-Chloroethyl >ether!

i bis(2-Chloroethoxy)methii 1

SPIKEAOOED<UQ/L)

100100100100100100100100100

.100100

•

1 SAMPLEi CONCENTRAT I ON

(ug/L)

00000000000

MSCONCENTRATION

(ug/L)

82778990D 1O 1

1(088958564

MSX

REC

827789908111288958564

67 ! 67!'

! QC !1LIMITS!

ti REC. !

! 47-1 451133-145!127-133!',33-143!124-1591111-162!117-163!i 1-219!! 1-152!112-158!133-184!

_! ____ !

! i! !

COMPOUND !

Acenaphthene 1Acenaphthylene !Anthracene iBenzo(a )anthracene !Benzo(b >f luoranthene 1Benzo(k )f luoranthene !Benzo(a)pyrene !Benzo<g ,h ,1 )perylene IButylbenzylphthalate ibis<2-Chloroethyl Jether!bis(2-Chloroethoxy>meth!

1

SPIKEADDED(ug/L)

100100100100100100100100100100100

i MSD! CONCENTRAT I ON1 (ug/L)

1 61i 59! 66i 66! 97! 1301 651 73i 56! 48! 501

! MSD !X !REC t!

61 i59 i66 !66 !97 i

134 165 173 i56 148 !50 1

1

•

XRPD t

3026303218183126403028

QCRPD

5050505050505050505050

!LIMITS !

i REC. !.| ...... 1147-145!133-145!127-133!133-143!! 24-1 59!111-162!117-163!! 1-219!1 1-152!112-158!133-1841i !

t column to be used to flag recovery and RPD values with an asterisk

* Values outside of OC limits

RPO: 3 out of 51 outside Units

Spike Recovery: 5 out of »* outside limits

COMMENTS: 5 Compounds are out between the LCS and LCSOUP. Both the LCS andi nrnun

FORM III SU-1 1/87 Rev.

3C-2WATER SEMIUOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: Contract:


.Matrix Spike - EPA Sample No.: BNA BLANK

COMPOUND

bis(2-chloroisopropyl )ebis(2-Ethylhexyl >phthal4-Bromopheny 1 -pheny 1 et h2-Chloronaphthalene

'-. 4-Chlorophenyl-phenyletChryseneDibenz( a ,h )anthraceneDi-n-butylphthalate

SPIKE I SAMPLEADDED {CONCENTRATION(ug/L) ! (ug/L)

100100100100100100100i an1 vw

1 ,2-Dichlorobenzene ! 1001 ,3-Oichlorobenzene 1 (1001 ,4-Oichlorobenzene 1 *100

!

0000A

000000

! MS i(CONCENTRATION!1 (ug/L) 1

! 59 1! 90 !! 80 1! 69 !1 82 11 91 11 94 ii 94 I1 51 !! 51 11 52 1! !

MSXREC

5990806982919494515152

! QC 1(LIMITS!

t! REC. !

136-166!! 8-158!153-127!160-118!',25-158!117-168!1 1-227!! 1-1181132-129!1 1-172!120-124!! 1

11

COMPOUND !

bis(2-chloroisopropyl )e!bis(2-Ethylhexyl >phthal 14-Bromopheny 1-pheny 1 et h 12-Chloronaphthalene 14-Chlorophenyl-phenylet !Chrysene !Dibenz(a ,h)anthracene )Di-n-butylphthalate 11 ,2-Dichlorobenzene i1 ,3-Dichlorobenzene !1 ,4-Dichlorobenzene 1

1

SPIKEADDED(ug/L)

100100100100100100100100100100100

MSD !CONCENTRATION!

(ug/L) 1

43 165 158 I51 t59 !65 i72 !68 139 !38 i38 !

1

MSD !X i X

REC t! RPD t

43655851 •5965

333231303233

72 ! 2668 ! 32

QCRPD

5050505050505050

39 ! 27 ! 5038 ! 29 1 5038 ! 33 ! 50

:

LIMITS! REC..)......136-166t 8-158153-127!160-118!125-158!117-168!! 1-227! 1-118532-129I 1-172! 20- 124!

t column to be used to flag recovery and RPD values uith an asterisk

* Values outside of QC limits

RPD: 3 out of 51 outside limits

Spike Recovery: 9 out of *» outside limits

FORM III SV-1-2 1/87 Rev.

3C-3UATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: Contract:

Lab code: Case No.: SAS No.: SDG No.:

Matrix Spike - EPA Sample No.: BNA BLANK

I QC !\1

COMPOUND

3 ,3'-DichlorobenzidineDiethylphthalateDimethylphthalate2 ,4-Dinitrotoluene2 ,6-DinitrotolueneDi-n-octylphthalateFluorantheneHexachlorobenzeneHexachlorobutadieneHexachloroet haneIndeno( 1 ,2 ,3-cd )pyrene

ADDED(ug/L)

100100100100100100100100100100

* 100

CONCENTRATION( ug/L )

.............00000000000

CONCENTRATION!( ug/L ) 1

39 i54 i31 !88 t49 191 !95 !83 !53 i55 !95 !

1

X {LIMITS!REC i! REC. 1......<......<39 t 1-262154 ! 1-IU!31 i 1-112!68 139-139!49 » 150-1 58!91 1 4-146!95 159-121!83 ! 1-152!53 J24-I16!55 140-113!95 ! 1-171!

t 11 1

! 'SPIKE ! MSO ! MSD! ADDED {CONCENTRATION! %

COMPOUND ! (UQ/L) ! (ug/L) ! REC t

3,3'-Dichlorobenzidine ! 100Oiethylphthalate i 100Oinethylphthalate ! 1002,4-Dinitrotoluene ! 1002 ,6-Dinitrotoluene ! 100Oi-n-octylphthalate ! 100Fluoranthene ! 100Hexachlorobenzene ! 100Hexachlorobutadiene i 100Hexachloroethane ! 100

20 ! 2030 ! 301 1 i l l64 1 6450 ! 50 *66 ! 6674 i 7463 ! 6338 ! 3839 ! 39 *

Indenod ,2 ,3-cd)pyrene ! 100 ! 73 ! 73i ! 1

XRPD t

64 *56 *97 *321

322527333226

QC LIMITSRPO REC.

505050

1-2621-114!1-112!

50 139-139!50 150-158!50 4-146!50 159-121!50 1-152!50 124-116!50 140-113150 1-171!

!

f colunn to be used to flag recovery and RPD values with an asterisk



Spike Recovery: 13 out of •* outside limits


3C-4WATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Mane: Contract:

Lab code: Case No.: SAS No.: S06 No.:


COMPOUND

IsophoroneNaphthaleneNitrobenzeneN-Nitroso-di-n-propylanPhenanthrenePyrene1 ,2,4-Trichlorobenzene4-Chloro-3-nethylphenol2-Chlorophenol2 ,4-Dichlorophenol2 ,4-Dinethylphenol

SPIKEADDED(ug/L)

100100100100i no.I <ov100100100100100100

.

SAMPLECONCENTRATION

(ug/L)

00000A

0

0

0

0

0

MSCONCENTRATION!

(ug/L)

7162696290925574595957

MS 1 QCX i LIMITSREC t! REC.

71 121-19662 121-13369 135-18062 1 1-23090 154-12092 152-11555 144-14274 ! 22-1 4759 123-13459 139-13557 132-119

i

COMPOUND

IsophoroneNaphthaleneNitrobenzeneN-Nitroao-di-n-propylanPhenanthrenePyrene1 ,2,4-Trichlorobenzene4-Chloro-3-nethylphenol2-Chlorophenol2 ,4-Dichlorophenol2,4-Dinethylphenol

..

SPIKEADDED 1(ug/L)

100100100100100100100100100100100

MSDCONCENTRATION

(ug/L)

5346514668653976575755

-

MSDXREC t

53465146686539 •76575755

XRPO t

2930303027353334H

! 51

QC LIMITSRPD 1 REC.

50 121-19650 121-13350 135-18050 ! 1-23050 154-12050 152-11550 ! 44- 14250 122-14750 123-13450 139-13550 ! 32-11 9

1

t colunn to be used to flag recovery and RPO values with an asterisk

• Values outside of QC limits


Spike Recovery: 17 out of ** outside Units

POMMCMTC •



Lab Name: Contract:

Lab code: Case No.: SAS No.: SDG No.:


1!i COMPOUND

! 2.4-Dinitrophenol! 4,6-Dinitro-2-methylphei 2-Nitrophenol! 4-Nitrophenol)• Pentachlorophenol! Phenol! 2 ,4,6-Trichlorophenol

SPIKEADDED(ug/L)

100100100100100100100

'

SAMPLE !CONCENTRATIONS

(ug/L) t

0 !0 !0 !0 !0 !0 !0 !

!

MS)NCENTRATION(ug/L)

928055110815567

MSXREC t

928055110815567

I QC iLIMITS!REC. i

1-191 I1-132!

29-182!1-132!14-176!5-112!37-144!

1

COMPOUND

2 ,4-Dinitrophenol4 ,6-Dinitro-2-methylphe2-Nitrophenol4-NitrophenolPentachlorophenolPhenol2 ,4 ,6-Trichlorophenol

SPIKEADDED(ug/L)

' 100100100100100100100

MSDCONCENTRATION

(ug/L)

918254110855568

MSD !X !REC t!

91 i82 154 !

114 i85 !55 i68 !

X !RPD t!...... j .

1 !2 i2 !3 I5 !1 !0 !

QCRPD

50505050505050

LIMITS! REC.

! 1-191! 1-132129-182!1 1-132!114-176!! 5-112!137-1441

! ! 1

t column to be used to flag recovery and RPD values with an asterisk

» Values outside of QC limits


Spike Recovery: 21 out of ** outside limits

COMMENTS:

FORM III SU-1-5 1/87 Rev.

QUANT REPORT Page

Operator ID: RAMONOutput File: ~D8198::QOData File: >D8198::D3Name: SNA LCS 100PPM

Quant Rev: 7

Misc: LCS100 SEP 7-5-94 FV=1.0

Quant Time:Injected at:

Dilution Factor:Instrument ID:

940707 16:31940706 13:15

1.000007002DBTL# 5

ID File: D28270::SCTitle: EPA Method 8270, Calibration Curve, HP5370, 7002DLast Calibration: 940525 15:26 Last Qcal Time: 940706 11:09


1)3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)19)20)21)22)23)24)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)42)43)44)45)46)

*d4-l , 4-DichlorobenzeneN-nitrosodimethylamine2-FluorophenolPhenol-d6Phenolbis ( 2-Chloroethyl ) ether2-Chlorophenol1 , 3-Dichlorobenzene•4 , 4-Dichlorobenzenebenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis ( 2-chloroisopropyl ) ether4-MethylphenolN-Nitroso-di-n-propylamiheHexachloroe thane*d8-NaphthaleneNitrobenzene-d5NitrobenzeneIsophorone i2-Nitrophenol2 , 4-Dimethylphenolbis ( 2-Chloroethoxy ) me thane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2-Methylnaphthalene*dl 0-AcenaphtheneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-Fluorobiphenyl2-NitroanilineDime thy IphthalateAcenaphthylene2 , 6-Dinitrotoluene3-NitroanilineAcenaphthene2 , 4-Dinitrophenol

8467778888888889

109999991010101010111114121212121213131314141414

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15242

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12814614610814610845108701171368277821391079316218012812722510714216423719619616217265163152165138153184

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19320190276568383676'4663346395358353201433519246853108433580569313501429234158417698345265494119507918184335985652725490262881037941593012460382936452938364919018068197556230254581349253296310791432447M236577208710564

40.61.

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00321374303838791449828440310074001526595717876678329096873600203248050199063637450576

ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mL

988766768596959192949497859296959786919291958285949987929698939597989496859494

899374

QUANT REPORT Page

Operator ID: RAMONOutput File: ~D8198::QOData File: >D8198::D3Name: BNA LCS 100PPM

Quant Rev 7 Quant Time:Injected at:



940707 16:31940706 13:15

1.000007002DBTL# 5



47)48)50)51)52)53)54)55)56)58)59)60)61)62)63)64)65)66)67)68)69)70)72)73)74)75)76)77)78)79)80)81 )82)83)

4-NitrophenolDibenzofuranDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline2 , 4 , 6 -Tr i br omopheno 1*dlO-Phenanthrene.4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine (1)4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneCarbazoleDi-n-butylphthalateFluoranthene*dl 2-ChrysenePyrene \Terphenyl-dl4Butylbenzylphthalate3,3' -DichlorobenzidineBenzo ( a ) anthraceneChrysenebi s ( 2-Ethylhexy 1 ) phthalate*dl 2-PeryleneDi-n-octylphthalateBenzo ( b ) f luorantheneBenzo ( k ) f luorantheneBenzo ( a ) pyreneIndeno (1,2, 3-cd ) pyreneDibenz ( a , h ) anthraceneBenzo (g,h,i )perylene

14.14.15.15.15.15.15.17.15.15.16.16.17.17.17.17.18.19.21.19.19.20.21.21.21.21.23.22.22.22.23.25.24.25.

49471929284589345460427314404882534344759971394247452720767920489746

10916814920416665330188198169248284266178178167149202240202244149252228228149264149252252252276278276

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* Compound is ISTD

T I C300 sec

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Data File: >D8198: :D3 Quant Output File: ~D8198::QOName: BNA LCS 100PPM Instrument ID: 7002DMisc: LCS100 SEP 7-5-94 FV=1.0 BTL# 5

•

Id File: D28270::SCTitle: EPA Method 8270, 'calibration Curve, HP5970, 7002DLast Calibration: 940525 15:26 ' Last Qcal Time: 940706 11:09

Operator ID: RAMON IQuant Time : 940707 16:31Injected at: 940706 13:15

Page 1 of 2

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Data File: >D8198::D3 Quant Output File: ~D8198::QOName: BNA LCS 100PPM Instrument ID: 7002DMisc: LCS100 SEP 7-5-94 FV=1.0 BTL# 5

•

Id File: D28270::SCTitle: EPA Method 8270, 'Calibration Curve, HP5970, 7002DLast Calibration: 940525 15:26 " Last Qcal Time: 940706 11:09

Operator ID: RAMON iQuant Time : 940707 16:31Înjected at: 940706 13:15

Page 2 of 2

QUANT REPORT Page

Operator ID: RAMONOutput File: ~D8199::QOData File: >D8199::D3Name: BNA LCSDUP 100PPM

Ouant Rev: 7

Mice: LCS100 SEP 7-5-94 FV=1.0

Ouant TimeInjected at:


940707 16:34940706 13:54

1 . 000007002DBTL# 6

ID File: D28270::SCTitle: EPA' Method 8270, Calibration Curve, HP5570, 7002DLast Calibration: 940525 15:26 Last Qcal Time: 940706 11:09


1)3 )4)5)6)7)8)9)10)11 )12)13)14)15)16)17)19)20)21)22)23)24)26)27)28)29)30)31)32)33)34 )35)36)37)38)39)40)41)42)43)44)45)46)

*d4-l , 4-DichlorobenzeneN-nitrosodimethylamine2-FluorophenolPhenol-d6Phenolbis ( 2-Chloroethyl )ether2-Chlorophenol1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis( 2-cnloroisopropyl )ether4-Methylphenol.N-Nitroso-di-n-propylamilieHexachloroe thane*d8-NaphthaleneNitrobenzene-d5NitrobenzeneIsophorone i2-Nitrophenol2 , 4-Dimethylphenolbis ( 2-Chloroethoxy )methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2-Methylnaphthalene

*dl 0-AcenaphtheneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-Fluorobiphenyl2-NitroanilineDime thy IphthalateAcenaphthylene2 , 6-Dinitrotoluene3-NitroanilineAcenaphthene2 , 4-Dinitrophenol

8,4.6.7.7.7.8.8.8.8.8.3.8.8.8.9.10.' 9.9.9.9.9.9.10.10.10.10 .10.11.11.14.12.12.12.12.12.13.13.13.14.14.14.14.

29718890929908253251576871899202321417536973900924364969487104193847745307556860011125

1524211299949312814614610814610845108701171368277821391079316218012812722510714216423719619616217265

163152165138153184

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978567778497969192939497839196969785919292958482979987919896959798999595869393

939473

QUANT REPORT Page

Operator ID: RAMONOutput File: ~D8199::QOData File: >D8199::D3Name: BNA LCSDUP 100PPM

Quant Rev: 7 Quant Time:Injected at:



940707 16:34940706 13:54

1.000007002D

BTL# 6


Compound R,T. Q ion Area Cone Units

47)48)50)51)52)53)54)55)56)58)59)60)61)62)63)64)65)66)67)68)69)70)72)73)74)75)76)77)78)79)80)81)82)83)

4-NitrophenolDibenzofuranDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline2,4, 6-Tribromophenol*dl 0-Phenanthr ene4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine ( 1 )4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneCarbazoleDi -n-butylphthalateFluoranthene*dl 2-ChrysenePyrene iTerphenyl-dl4But ylbenzylphtha late3,3' -DichlorobenzidineBenzo ( a ) anthraceneChrysenebis ( 2-Ethylhexyl )phthalate*d!2-PeryleneDi-n-octylphthalateBenzo ( b ) f luorantheneBenzo ( k ) f luorantheneBenzo ( a ) pyreneIndeno (1,2, 3-cd ) pyreneDibenz ( a , h ) anthraceneBenzo ( g , h , i ) pery lene

14141515151515171515161617171717181921191920212121212322222223252425

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109 .168.149.204.166.65.

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Data File: >D8199::D3 Quant Output File: ~D8199::QOName: BNA LCSDUP 100PPM Instrument ID: 7002DMisc: LCS100 SEP 7-5-94 FV=1.0 BTL# 6

Id File: D28270::SCTitle: EPA Method 8270, 'Calibration Curve, HP5970, 7002DLast Calibration: 940525 15:26 Last Qcal Time: 940706 11:09

Operator ID: RAMON iQuant Time : 940707 16:34Injected at: 940706 13:54

Page 1 of 2

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Data File: >D8199::D3 Quant Output File: "D8199::QOName: BNA LCSDUP 100PPM Instrument ID: 7002DMisc: LCS100 SEP 7-5-94 FV=1.0 BTL# 6

*

Id File: D28270::SCTitle: EPA Method 8270, 'Calibration Curve, HP5970, 7002DLast Calibration: 940525 15:26 Last Qcal Time: 940706 11:09

Operator ID: RAMON ,Quant Time : 940707 16:34Injected at: 940706 13:54

Page 2 of 2

Continuing Calibration CheckHSL Compounds

Case Ho:

Contractor: HET-fliduest, INC.

Contract No: D90031

Instrument ID: 70820

Calibration Date: 07/66/91

Tine: 11:09

Laboratory IB: HSI95

Initial Calibration Date: 06/28/91

ttininun RF for SPCC is 0.05 fadiM I Diff for CCC is 25.01

Conpound RF KF ffliff CCCSPCC

Pyridine 1H-nitrosodwethvlamne2-FluornphemlPhenol-d6Phenolbis<2-CMoroethyl>ether2-ChlorapheMlt,3-0ichlortbenzeneM-OichlorobenzeneBenzyl alcohol1,2-ftcUorobenzene2-tlethylpbenolbls(2-chloroifopr«pyl)ether1-nethylphenolN-Hitroso-di-n-propylaRineHexachloroethaneRnllineNltrobenzene-d5NitrobenzeneIsophorone2-UtropheMl2,HinethylphenolBenzole acidbis(2-Chloroethoitv>nethBne2,1-Dlchlorophenol1,2,1-rrichlorobenzeneNaphthaleneKhloroanilineNeiachlorobutadieneHhloro-3-nethylphenol2-nethylnaphthaleneHeuchlorocyclopentadiene

.61292 .82737

.76)11 .61213

.27278 I.1I3K

.66618 1.53669

.88178 1.71593

.59571 1.19198

.10815 1.21938

.39916 1.30508

.115131.33887

.8(963 .80197

.3381? 1.26625

.281361.1(182

.12836 1.98111

.36071 1.22227

.05855 .97622

.59721 .599102.13080 2.0610?.39070 .35555.10682 .37867.80515 .69981.19630 .17313.31321 .38535.13721 .12663.50168 .13921.26206 .22577.27719 .21931.96628 .86539.38196 .31960.13578 .12221.30261 .26935.57828 .53765.21791 .22703

19.6115.63 «12.517.797.36 *6.50 *

11.28 *6.72 *5.95 *7.115.37 *

•9.33 •18.28 •10.18 «

7.78 •.31 *

15.21 *9.008.89 •

13.08 *11.80 *11.01 «7.73

12.15 *13.85 »10.05 *I8.H »16.339.98 »

11.08 «7.83 *8.12 >

(Conc*10D.08)(CooH 00.00)

M

RF - Response Factor fron daily standard file at 50.00 ig/hL

RF - Overage Response Factor fron Initial Calibration Fora Id

ZOiff - I Difference fron original average or curve

OC - Calibration Check Conpounds <*) SPCC - SystafeFfonmce theok Conpoondt <**>

Torn Oil Page 1 of 3

Continuing Calibration CheckHSLConpounds

Case No:

Contractor: HEHlouest, IK.

Contract Mo: 090031

Instrument ID: 70020


line: tt:09

Laboratory ID: MBIK


Z Oiff for CCC is 2S.OZ

RT Miff CCC SPOT

<Conc«100.00>

ttiniiwn RF for SPCC is 0.05

Conpound RF

2,1,6-lricnlorgpkenol2,1,5-TrlcnloroptKMl2-OiloroiiaBhthalene2-fluoroblihenyl2-fetrwtuhr*Dinethylphthalateflcemphthvlene2,6-6initrtigltiene3-totroanilifwRcenaphthene2,1-eimtropnenolHUtroiReiwlOibenzofgran2,1-fiinitrotolueneOiethylphthalate1HFlHhtroaniline2.1,6-Tribronophenol1,6-flinitr»-2-tteth'OifhenylhydrazineN-Nltrowdi|ihenyli

NexachlorobenzenePentacbloroohenolPhenanthreneflnthraceneCarbazoleDi-n-butylphthalateFluorantnenePyreneTerphenyl-dl1

KT - Response Factor fron daily stanoard file at M.flfl ug/nL

Rf - Average Response Factor fron Initial Calibration Torn UI

ZBiff - I Difference fron original average or carve

CCC - Calibration Check Conpounds (•) SPCC - Systen Perfomance Check Compounds <«)

Fora (III Page 2 of 3

feral .33357fenol .35587ene 1.03799

1.11118.13618

e 1.211911.68165

ne .39120.31325.02971

I .12163.12658

1.11158ne .12306

1.27063tanylether .19776

I.IH963.10975

cool .16311thvlphenol .11081ne 1.69682lanine <l> .55189lenylether .20131e .22619il .11127

.07191

.05617

.00216ate .11863

.03000

.39858

.99139

.27981

.29226

.91073

.98109

.383361.186571.15137.38281.29209.91602.12001.12613

1.29857.383lf

1.16278.11150.97330.31327.13819.13011

1.67351.16396.17731.I9H6.09801

1.00118.95911.91589

1.39069.93920

1.15165.81076

16.11 «17.87 •9.37 »

11.7112.11 »11.11 »13.52 *2.88 «

11.9111.01 <

1.30. .12

8.209.11 »8.50 *

10.70 «7.27 »

16.2315.267.59J.37

12.31 *13.21 •11.03 *11.20 *6.57 «9.22 »8.611.97 •8.82 *

17.66 "18.22

Continuing Calibration CheckHSL Conpounds

Case (to:

Contractor: Hn-ltiduest. IK.

Contract Ho: 090031

Instrunent ID: 70020

Hinlnun V for SPCC is 0.05


Tine: 11:09

Laboratory ID: >D819S


flaximn I Oiff for CCC is 25.01

tunpound

ButylbeazvlphthalateBenildlne3,3'HHchlorobenzldineBenzo<a)anthraceneChrysenebis<2-Ethvlhexvl)phthalateDl-n-octylphthslate8enzo(b)fluormtheneBenzodOfluoranthene8en»<a)pyreReIndeno(l,2,3-cd)pyreneOlbenzCa.hJanthraceneBenzo<g,h,i)pervlene

RT RT Miff CCCSPCC

.82197

.10236

.36973

.17081

.12510

.036152.07559.75612.32121.29212.20281.07599.20281

.71263

.00871

.255261.01071.93827.95210

2.815271.772111.27923t.129771.151921.051901.15192

13.30(91.13-(3JU6-1l.lt16.618.112.91.93

3.1812.583.98

•1.963.98

«

,

•*

c•«i•**

tf - Response Factor tron daily standard file at SO. 00 ug/hl

RT - towage Response Factor fron Initial Calibration Tom VI

IDiff • 1 Difference fron original average or curve

CCC - Calibration Check Compounds <») SPCC - Syste« Perfomance Check Conpounds (•«)

ForfiUTI Pact 3 of 3

Operator ID: RAMONOutput File: ~D8195::QOData File: >D8195::D3Name: BNA STD. 50PPBMisc: SSTD050

QUANT REPOE<T

Ouant Rev: 7 Quant Time:Injected at:

Dilution Factor;Instrument ID:

luL21619

ID File: D_8270::FlTitle: EPA Method 8270, Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 Last Qcal Time;

Page l

940706 11:38940706 11:09

1.000007002DBTL# 2

<none>


1)2)3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)42)43)

*d4-l , 4-DichlorobenzenePyridineN-nitrosodimethylamine2-FluorophenolPhenol-d6Phenolbis ( 2-Chloroethyl ) ether2-Chlorophenol1 , 3-DichlorobenzeneJ. , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis( 2-chloroisopropyl ) ether4-MethylphenolN-Ni troso-di -n-propylamineHexachloroe thaneAniline*d8-NaphthaleneNitrobenzene-d5Nitrobenzene ,Isophorone2-Nitrophenol2 , 4-DimethylphenolBenzoic acidbis ( 2-Chloroethoxy ) methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2-Methylnaphthalene*dlO-AcenaphtheneHexachlorocyclopentadiene2 ,4 , 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chlor ©naphthalene2-Fluorobiphenyl2-NitroanilineDime thy Iphtha lateAcenaphthylene2 , 6-Dinitrotoluene

844677788888888897

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1010101010111114121212121213131314

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341433531127418M95042

131168•745146367653322556995680034355540424958584692521654166425569879641384276152364138121096299585283521911759993906643144149742553012115146607930317288820685254962662885710893873492810082013250834881M

40.25.42.87.92.46.46.44.46.47.46.47.45.40.44.46.50.42.40.45.45.43.44.44.46.43.43.44.44.41.45.44.46.40.45.41.41.45.44.43.44.43.48.

00181949213275366402283134869111163900505646104813770898788401504900799506321595442456


978384826880oy9596939398949192967397809297909> 19V829697998390959691959797989788949446

QUANT REPORT Page

Operator ID: RAMONOutput File: ~D8195::QOData File: >D8195::D3Name: BNA STD. 50PPBMisc: SSTD050

Quant Rev;

1UL21619

7 Quant Time:Injected at:


ID File: D_8270::F1Title: EPA Method 8270, Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 Last Qcal Time:

94070*.". 11:3894U706 11:09

1.000007002DBTL# 2

<none>


44)45)46)47)48)49)

W50)51)52)53)54)55)56)57)58)59)60)61)62)63)64)65)66)

^ 67)68)69)70)71)72)73)74)75)76)77)78)79)80)81)82)83)

3-NitroanilineAcenaphthene2 , 4-Dini trophenol4-NitrophenolDibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline2,4, 6-Tr ibromophenol

*dl 0-Phenanthrene4 , 6-Dinitro-2-methylphenolDi-phenylhydrazineN-Nitrosodiphenylamine (1)4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthracene |CarbazoleDi-n-butylphthalateFluoranthene*d!2-ChrysenePyreneTerphenyl-dl4ButylbenzylphthalateBenzidine3,3' -DichlorobenzidineBenzo f a ) anthraceneChrysenebis(2-Ethylhexyl)phthalate*d!2-PeryleneDi-n-octylphthalateBenzo ( b ) f luorantheneBenzo ( k ) f luorantheneBenzo ( a ) pyreneIndeno (1,2, 3-cd ) pyreneDibenz ( a , h ) anthraceneBenzo ( g , h , i ) perylene

141414141414151515151517Ib15151616•1717171718192119192019212121212322222223252425

.02

.11

.24

.48

.47

.60

.18

.29

. 26

.45

.88

. 35

.54

.66

.60

.42

.73

.13

.40

.47

.82

.53

.42

.43

.75

.99

.70

.65

. 39

.42

.46

.45

.27

.19

.76

.76

.18

.47

.96

.47

13815318410916816514920416665

33018819877169248284266178178167149202240202244149184252228228149264149252252252276278276

.0

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26612834591093711519

T1831334905

105941404988867731275252361007621638821078360958223372449312445

126139120802115359175161118294843841214768551975168919

269251097749896910042767984171258150619M108709M96008981458964598145

4244494945454544464184404649434342444645454945404140434344441454048504843484948

. 55

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.70

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ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mL

91939174636388929894939888979392919596939497999999989098998793899897979792919697

* Compound is ISTD

r . i D8195::D3 Quant Output File: ~D8195::QOName: BNA STD. 50PPB Instrument ID: 7002DMisc: SSTD050 luL21619 BTL# 2

*

Id File: 0 8270::F1Title: EPA Method 8270, "Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 Last Qcal Time: <none>


Page 1 of 2

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D8195::D3 Quant Output File: "D8195::QOName: BNA STD. 50PPB Instrument ID: 7002DMisc: SSTD050 luL21619 BTL# 2

*

Id File: D_8270::F1Title: EPA Method 8270, -Calibration Curve, HP5970, 7002DLast Calibration: 940628 10:34 • Last Qcal Time: <none>


Page 2 of 2

SEMI-VOLATILE EXTERNAL STANDARD SUMMARY(Continuing Calibration Verification-Water Matrix)

Date of Analysis: 7/06/94 11:09

Data File Name : >D8I95::D3

Instrument ID : 7002D

AcenaphtheneBenzo<a)pyrene4-ChloPo-3-methylphenol1,4-Dichlorobenzene2,4-OichlorophenolDi-n-octylphthalateFluoranthene•Hexachlorobutadiene'4-NitrophenolN-Nitrosodiphenylamina (1 )PentachlorophenolPhenol2,4,6-Trichlorophenol

44.48043.70844.50047.02343.07648.54745.59245.01249.94143.84744.40046.31841.946

ug/mLug/mLug/mLug/mLug/nLug/mLug/mLug/mLug/nLug/nLug/mLug/mLug/mL

8BSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: Contract:

Lab code: Case No.: SAS No.:

Lab File ID <Standard): >D8(95

Instrument ID:

S06 No.:

Date Analyzed: 07/06/94

Tine Analyzed: It:09

!

12

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLENO.

BT*260 1 76BNA BLANK

3!BNA LCS 14IBNA LCSDUP5!BTt2667776!BT*2670757!BTf267l628!BTt267l899!BT*267I9010JBTt267l9l1 1 !BT»267I92I2!BT*267I93(3!BT*267I94(4!BTt267(95(5!BTt26719616!1718!(920!21

ISKDCB)AREA *

34143

68286

17071

2506025646 *(9320(8599(986118938192762159523388206542218925769276242737827010

!22! !

!!

I1

t

1tt

I*

!iijiii{iI\\ttii

iii1iit

!RT i

8.30!

8.80!

7.80!

1111

8.30!8.3018.29!8.29!8.29!8.30!8.29!8.31!8.30!8.29!8.30!8.2918.30!8.30!8.30!

1

i11

11

i

IS2(NAP) !AREA * i

138427 i

276854 !

692(3 !

1

98865 !100766 t76983 !73624 !76005 i73933 !74147 !964 1 8 !

1 11204 !8(492 !86830 !(05087 i111442 !t 1 0759 !(08084 !

11i1j1

!RT !

10.31'!

10.81!

9.81!

(0.32!10.32!10.32!10.321(0.31 !(0.32!(0.33110.33!10.34!10.33!10.33!10.32!10.33!10.32!10.32!

1

1

i

j

111

!

IS3(ACE> iAREA t !

72888 i

1 45776 !

36444 !

5(681 i51595 !38364 !36577 !331 71 -.1.(35630*.!)37ZB6" !49235 i556 1 2 !4(680 !47735 !59570 !56909 !53878 !57952 !

1iiijj!

11

RT i

(4.03!

14.53!

13.53!

11t1

(4.04!(4.04!(4.04!14.04!14.03)14.03!14.03!(4.03!(4.03!14.03!14.03!14.03!(4.04!(4.03!14.03!

151 (DCB) - d4-t .4-Dichlorobenzene152 (NAP) - d8-Naphthalene153 <ACE) = d)0-Acenaphthene

UPPER LIMIT - + 100Xof internal standard area.LOWER LIMIT - - 50%of internal standard area.

t Column used to flag Internal standard area values with an asterisk

page _ of _.FORM VIII SU-I 1/87 Rev

8CSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: Contract:


Lab File ID (Standard): >D8I95

Instrument ID:

SDG No.:


Tine Analyzed: tI:09

1t1

.„.-......„>.

12 HOUR STD!..«.--„..„.,;.UPPER LIMIT!

LOWER LIMIT!

EPA SAMPLE !NO. !

l!BTt260l76 i2!BNA BLANK !3!BNA LCS 1 !4JBNA LCSOUP i5IBT*266777 !6 1 BTt267075 !7!BT*267I62 !8!BTt267189 i9!BT*267190 !!0!BTt267l9l !11!BT*267I92 !I2!BT*267I93 i13!BT*267I94 i141 Bit 26? 195 !15!BT*267I96 !16! !17! !18! !19! !20! !21! !22! i

IS4(PHN) !AREA * i

100762 i

201524 !

50381 i

71463 !72577 . i54135 i50020 *!56508 !52259 i54926 i78505 !84698 !57819 !72024 !90862 !80888 !89917 !81822 i

t1

(

1

11

j

1

1

iRT !

17.35!

17.85!

1 6 . 85 !

l1

17.35!17.35!17.34!17.36!17.34!17.35!17.35!17.35!17.36!17.35!17.34!17.34!17.35!17.35!17.35!

1I11

1

11t1

11

ISS(CHR)AREA t

84384

168768

42192

597255954546109469904883943302487607381975373536636476784788568208461660807

I1

RT !

21 .43J

21.93!

20.93!

21.44!21 .44!21 .44!21.43!21.43121 .44!21 .44!21.44!21.44!21.43!21 .44!21 .43!21.43!21 .44!21 .44!

11

1I

1

j

111

!

IS6(PER) !AREA t i

67984 i

135968 i

33992 !

I1

46283 i47660 i36866 !35638 !

C3JJ97J_J)l38795 !57333 !61969 i45254 !50305 i66961 !23364 »!36772 !29037 «!

ji1iji»

iiRT !

23.27!

23.77!

22.77!

t111

23.26!23.26!23.27!23.27!23.26!23.27!23.27!23.27!23.26!23.27!23.27!23.26!23.26!23.26!23.27!

1

!1111

111

I

154 (PHN)155 (CHR)156 (PER)

d10-Phenanthrened!2-Chrysenedt2-Perylene

UPPER LIMITof internalLOWER LIMITof internal

- + I00Xstandard area.- - 50Xstandard area.

t Column used to flag internal standard area values with an asterisk

page _ of _.FORM VIII SV-2 1/87 Rev

QC REPORT

MS SEMZ-VOLATILES

era/ let ters/cover. inssemi

SBSEMIVOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)

Lab Wane: Contract:

Lab code: Case No.:

Lab File ID: >D82I3

Instrument ID:

SAS No.: SD6 No.:

DFTPP Injection Date: 7/07/94

DFTPP Injection Tine: 10:38

m/e !

51 !68 !69 i70 i127 !197 !198 !199 i275 !365 !441 !442 !443 I

1

ION ABUNDANCE CRITERIA

30.0 - 60. 0X of mass 198Less than 2.0X of mass 69Mass 69 relative abundanceLess then 2.0X of mass 6940.0 - 60. 0S of mass 198Less than .1 .0X of mass 198

'

Base Peak, 100X relative abundance5.0 - 9.0X mass 19810.0 - 30. 0X of mass 198Greater than 1.00X of massPresent , but less than massGreater than 40. 0X of mass17.0 - 23. 0X of mass 442

*

198443198

.

X RELATIVE !ABUNDANCE

51.3.6 < .8)1

69.7.2 < .3)1

47.6.4

100.06.220.82.8

11.474.814.4 < 19.2)2!

I-Value is X of mass 69 2-Value is X of mass 442

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS. AND STANDARDS:

i EPA! SAMPLE NO.!«....««.=..

01! BNA STD. 502! BNA BLANK03! BNA LCS041 BNA LCSDUP05! BNA BLANK061 BNA LCS07 t BTf267252D08! BTI267280D09 i BT1267323D10! BTt267324Dt 1 ! BTt267075R12! BTt267l62D13! BTS267189D14! BTI267252R15! BTt267280R16! BTt267323R17! BTt267324R18119120!21 i77!

LABSAMPLE ID

SST0050SVBLKLCS 100LCS 100SUBLKLCS 100

-

(iE&ENt FN ., /CCCC

.

LABFILE ID

>D8214>D8215>D82I6>D8217>D82!8>D82 1 9>D8220>D8221>D8222>D8223>D8224>D8225>D8226>D8227>D8228>D8229>D8230

i DATEi ANALYZED

! 07/07/94! 07/07/94! 07/07/94i 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94! 07/07/94!I1

111I

TIMEANALYZED

11:0311:4612:2613:0513:4514:2415:0415:4316:2217:0217:4218:2119:0119:4020:2021:0021:39

9-

0T-

03-

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09-

8*

88-

86-

88T-

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>D82I385

BOP 50PPBADO

File: >D82I3 Scan *:

m/z

39.0039.9040.9043.0044.0045.0050.0550.9551.9554.0055.00

, 56.00• 57.0061.0061.9063.0565.0567.9568.9570.0573.0074.1075.0076.0077.0078.1079.0580.0580.95

Int

238.85.51.17.

973.22.579.2214.131.10.21.78.187.19.19.

101.51.24.

3010.10.16.189.369.132.

2169.174.159.132.156.

•

0000000000000000000000000000000000000000000000000000000000

m/z

81.9583.0585.0585.9591.1092.0093.0098.0599.05101 .05102.95104.00105.10107.101 08 . 1 0109.0010.0011.0016.1517.0518.05122.00123.00125.10127.10128.05129.05130.051 35 . 1 5

BOP050

85 Retn.

Int.

29.0030.0023.0041.0058.0046.00230.00150.00173.0090.0020.0044.0055.00513.0057.0015.00

1402.00186.0020.00347:0038.0023.0055,0018.00

2055.00145.00890.0069.0073.00

m/z

137.20141.10143.10147.15148.15149.15153.20155.10156.20157.10160.00161.05165.15166.15167.15168.05169.10174.20175.20176.20177.00179.15180.15181.25185.15186.20187.20189.101 92 . 1 0

time:

Int.

42.00103.0017.0047.0096.0021.0021.0052.0076.0013.0016.0053.0038.0019.00178.00142.0011.0036.0065.0017.0024.00139.0096.0056.0062.00465.00122.0017.0024.00

luL2H28

6, -25

m/z

193.201 96 . 1 51 96 . 75198.15199.15203.10204.20205.20206 . 20207.20208.20210.65211.15217.15221.10222.20223.10224.20225.20227.25228.25229.15242.20243.15244.25245.15246.25254.10

Int

47.126.18.

4316.268.19.

132.

•

00000000000000

194.00886.137.17.13.21.239.255.23.47.450.112.162.17.23.16.10.365.22.42.12.

0000000000000000000000000000000000000000

EMU-2300

.m/z

255.20256.20258.10265 . 1 5273.20274.10275.20276.25277.15296.15303.10323.30334.30352.20354.20365.15372.30402.30403.20421.10422.00422.40423.10424.35441.25442.25443.25444.25

Int.

1834.00235.0092.0025.0062.00160.00897.00100.0076.00212.0029.0080.0047.0015.0017.00123.0050.0015.0018.0014.0013.0028.00175.0044.00490.003228.00621.0071.00

20SOIL SEMIVOLATILE SURROGATE RECOVERY

Lab Name: Contract:


Level:(lou/ned)

! EPA i SIi SAMPLE NO. !<NBZ>-.....„.«„!„...

0I!BNA BLANK * \ —— 66-A91DUA 1 r*O t 1 £C

ATI I QUA i r>cr\i ID & i c i

04JBNA BLANK i 4705IBNA LCS t ! 5006IBTt267252DL t 807IBT*2B7280DL ! 708!BT*267323DL i 209!BTt2673240L i 11 0 ! BTt267P7SPF *t 56ll!BTt2B7163PU»! —— I*l2!BTtaC71QODLrif —— !3IBTt267252RE •!4!BTt267280REI5IBT*267323RE!6!BTt2B7324RE!7!18!19!20!21 !22!23!24!25!26!27!28!29!30!

423628It

,

i S2 t>*!(FBP)t!

—4 — 60 — i-

t CO 1

i 48 !i 56 !

*! 11 *!*! II »!*! 3 *!»! 1 *!i en i

-*•! —— W-M--H —— Mr-M-• ! 47 !

! 42 !! 27 »!

•I 12 »!

1 !

S3 !(TPH)t!

— 73 — ^— S4 —— h— 86 —— fr

58 !58 !II »!13 *l3 *!0 !

flffl 1— 23 — 1-

48 i50 i32 i14 *i

I

54 ! S5(PHL)f !(2FP

— 48 —— 1 —— 43-56 —— 1 — 55"

— 52 —— 1 — 54-49 4250 i 4410 *! 810 * i 82 •! 2t *! 1

10 n t".,

47402412 •

! ! !! i !! i! i1 ;

I1

1

I ! ii t ii i i! ! !1 j ;! ! !I i i! I i

403823It

I 56)* i ( TBP

— t —— 95— \ —— 9t

i 77! 79

*! 14*! 15»! 3*i 1

-M — 26-H — 35

! 72! 72

• 1 34«! 14

11

1

! S7 !TOT!)t i< )t!OUT!

! i 0!i 1 0 1! i 0!i i 0!! i 0!

*i i 6!*i ! 61*i O i 6!*! 0 ! 5!i ! 0!i i 4i ! 5i i 0i ! 0! ! 2

*i i 6i I1 1

i ! iI j i

t ii ! !1 1 f

t 1 1t 1 1

! ! I! t !t 1 11 1 t

i i i

j1

!! i i! i !

St525354SBSB

(NBZ)(FBP)(TPH)(PHL)<2FP)(TBP)

Nitrobenzene-d52-FluorobiphenylTerphenyl-dl4Phenol-dB2-Fluorophenol

QC LIMITS(23-120)(30-115)(18-137)(24-H3)(25-121)

2,4.B-Tribronophenol <19-122)

t Column to be used to flag recovery values* Values outside of contract required QC limits0 Surrogates diluted out

FORM II SV-1 1/87 Rev

2CWATER SEMIVOLATILE SURROGATE RECOVERY

Lab-Name: Contract:


! EPA! SAMPLE NO.

01 IBNA BLANK02! SNA LCS03! SNA LCSDUP04!BNA BLANK*05 IBNA LCS • 1

07 ! BTt3S72B9DL'no i OT»o»T»-»-»m •Dll 1 QT*T P''*'* Mm h

!0!BTt267075RE1I!BT*267162DLl2l8Tt267l89DL1 3 ! BT*3673i3RE «14IBTt2C7a80R6 '

i e i E»T**)B*r*** jor-^

17!18!19120!21!22!23!

i SI!(NBZ

i 56i 65! 61

A — S»•4 —— 8-•4 —— ?•-1 —— 3-H —— »-i 56! 16i 14H —— 43-M — 36-

-» —— 1+!!! >11

!t1

!

! S2 i S3)*!(FBP)*i(TPH

! 50 ! 77i 62 i 841 58 ! 85

— ! —— 46 — 1 — 56-— H — 56 — 1 — 56-*H —— H-*H —— H--M —— W-M —— «•-*4 —— »-«4 —— 3--H —— 1— «-" —— *

i 50»! 17 **! 14 *

-H — 27 • i-H —— H2— »H

jj1t

1t

24! ! !25!26!27!28!29!301

1

!11

!!!

I

11It

802316

1 — 46-1 — 50-

1 —— K-

1 S4)*!<PHL>*

! 48i 56i 52

— 1 — 46 ——— 1 — 50 ——

-<H —— W-H-H —— 2— — 1 ——— t— H! 24

• 1 10 **! 10 *— 1 —— 47 —— 1— 1 — 40 — 1-H — 24 — 1-H —— H2 —— 1

I1!ii111jiI

I I1 I

i !t 1t 1

1 ji!

SS ! S6 1 S7 !TOT!(2FP)t!(TBP)*!( )*!OUTi

475551

t — 4S —1 — 44 —1 —— 8— *-1 —— 8— *-

"* "1 "

3612 *13 »

1 — 40 — 11 — 36 — 1

1 —— H-*H

759591

i r-

1 —— 5- »i — ^ »

842635

1 — 721 — 341 —— H

————

I1

I!!1

ii1

11

• 1

I

i

0!0i0!0!0!415!6!5!0!5!510!1!3!4!

Ii I! t!1

!1

! !i i* 1

! !1 1

! i!t

1

1

5152535455SB

(NBZ)(FBP)(TPH)(PHL)(2FP)(TBP)

Nltrobenzene-d52-FluoroblphenylTerphenyl-dl4Phenol-d62-Fluorophenol

QC LIMITS<35-lt4)(43-116)(33-Ut >(10- 94)(21-100)

2,4,6-Tribronophenol (10-123)

t Column to be used to flag recovery values» Values outside of contract required QC limits0 Surrogates diluted out

3CWATER SEMIVOLAJILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Nane: Contract;

Lab code: Case No.: SnS No.: 506 No.:

Matrix Spike - EPA Sample No.: LCS/LCSDUP SEP 7-5-94

t I

i ii COMPOUND !

i Acenaphthene !i Acenaphthylene ii Anthracene I! Benzov'a)anthracene i! Benzov'b )f luoranthene !j Benzovk )f luoranthene ii Benzova /pyrene i! Benzov'g ,h,i )perylene !i Butylbenzylphthalate ii blsv'2-Chloroethyi )ether!i bisv'2-Chloroethoxy )methfi !

SPIKEADDEDv ug/'L )

100100100100100100100100100100100

*

! SAMPLE! CONCENTRATIONi \ ug/'L)

i 0! 0i 0

0i 0i 0i 0

0! 0! 0

0i

MSCONCENTRATION

v ug/'L )

82• 65

89S31201508182846771

MSA

REC

62856993124145816264

1 571 71

i QC iiLIMITSI

4i REC. i

J47-I45I133-1451127-133!133-143!i 24- 159!ill-162!i 17-1631i 1-219!i 1-1521i 12-1581133-1841r !

i !1 I1 1

i COMPOUND i

! Acenaphthene i! Acenaphthylene i! Anthracene !! Benzova )anthracene !j Benzo(b )f luoranthene !! Benzov'k )f luoranthene ii Benzova >pyrene ii Benzov'g ,h ,i )perylene ji Butylbenzylphthalate ii bisv'2-Chloroethyi >etherii bisv'2-Chloroethoxy )methii i

SPIKEADDED< ug/L )

100100100100100100100100100100100

i MSD(CONCENTRATIONi vug/L)

i 57t 60i 64

65i 95i 110i 60! 60i 53i 46

50!I

MSD !%

REC *i

57 i60 i64 i65 i95 i

Ml i60 !60 i56 i46 i

1 50 ii

XRPO *

3634323527273031363734

QCRPD

50505350505050

i 50i 50! 50i 50i

iLIMITS i

i REC. !«l».«.|147-145!i 33- 1 45 !127-133!i 33- i 43 !i 24- 159!ill-162!117-163!i 1-219!i 1-152!it 2- 158!! 33- 1 84 it 11 1

4 column to be used to flag recovery and RPO values with an asterisk


RPO: 3 out of 51 outside limits

Spike Recovery: 2 out of •» outside limits

COMMENTS: 2 Compounds out on LCSD, however all compounds are OK in the Ics.The batch is acceptable. RLA


Lab Name: Contract:

Lab code: Case No.: 5AS No.: 506 No.:

Matrix Spike - EFA Sample No.: BNA BLANK

COMPOUND

1{1

bisvZ-chloroisopropyl )e!bisi 2-Ethylhexyl )phthal !I4-Bromopheny 1-pheny let hi

Tii!1

i

11J

!{!{!1I

!!I

I1

!!i

2-Chloronaphthalene4-Chlorophenyi-phenyletChryseneDlbenzi a ,h )anthraceneDi-n-butylphthalatet ,2-Dichlorobenzene1 ,3-Dichlorobenzenet ,4-Dichlorobenzene

COMPOUND

bis( 2-chloroisopropyl )ebisi 2-Ethylhexyl )phthal4-Bromopheny 1 -pheny let h2-Chloronaphthalene4-Chloropheny 1-pheny letChryseneDibenzCa ,h /anthraceneDi-n-butylphthalatet ,2-Dichlorobenzenet ,3-Dichlorobenzene1 ,4-Dlchlorobenzene

!t!!ttiii!1

11I

!1!!1

!!1!i{1t

11

SPIKEADDED< ug/L >

t00100100100100100100100100100100

*

*

SPIKEADDED{ ug/L )

100100100100100100100100100100100

! SAMPLE ! MS !! CONCENTRATION! CONCENTRATION !1 v ug/L )

i 0i! 0

0! 0i 0i 01i 0i 0! 0!

1 MSD

!

!11}

i1

!i!tiii{i

{{CONCENTRATION!i < ug/L )

i 49i 62! 69! 50i 61i 62i 60! 61! 39! 36! 3711

!

i«!1

I

(ug/L

'MSDX

REC

4962695061626060393637

!1

ii!

!

!

!1

• i!1]11

i!i{ii

)

7080937187878182545252

XRPD

3526303535333030333733

t1

ii

!ii!»1

!11i!ii

1!

4!

i11

i!Ii!1!»1

ii

MSX

REC

7080937187878181545252

QCRPD

5050505050505050505050

1 QC iiLIMITS!

*! REC. !. i ...... j! 36-166!i 8-156!,'53-127!150-1 18!i 25-158!S17-I68!i 1-227!! 1-116!132-129!i t-172!120-1241i !

iLIMITS !

i REC. !

136-1661! 8-158!! 53-1 27 i160-1161! 25- 1 58 !i 17- 168!! 1-227!i 1-116!532-129!! 1 - 1 72 ii 20- 124!i i

i column to be used to flag recovery and RPD values with an asterisk



Spike Recovery: 4 out of »* outside limits

COMMENTS: _____________________,_______________________'


Lab Name: Contract:

Lab code: Case No.: 5AS No.: 5DG No.:

Matrix Spike - EPA Sample No.: 8NA BLANK

i i SPIKE i SAMPLE i N5 i MS i QC i1 i ADDED ! CONCENTRATION! CONCENTRATION! A i LIMITS I1 COMPOUND ! <ug/L> i Cug/L) i vug/L) ,' REC #! REC. I

3,3'-Dichiorobenzidine iOlethylphthalate iDlnethylphthalaie i2,4-Dlnitrotoluene i2 ,6-Dinitrotoluene !Di-n-octyiphthalate 1

C' Fluoranthene !! Hexachlorobenzene ii Hexachlorobutadiene !i Hexachloroethane !i Indeno< I ,2 ,3-cd )pyrene I

(00 i100 i100 ;100 :100 i100 i!00 i100 i100 i100 i100 i

0 i0 i0 i0 !0 !0 i0 i0 i0 i0 i0 !

52. 55

359696778992645382

! 52i 55i 35i 96i 96i 77i 69! 92! 84i 53i 82

! 1-262!i 1-114!! 1-112!139-139!i 50- 1 58 ii 4-1 46 i!59-12l !i 1-152!124-1 16!S40-1 13!! 1-171!

i SPIKEi ADDED

COMPOUND v1 ug/'L )

3,3'-Dichlorobenzidine 100Diethylphthalate 100Dimethylphthalate 1002,4-Dinitrotoluene 1002,6-Dinitrotoluene i 100Dl-n-octylphthalate ! 100Fluoranthene ! 100Hexachlorobenzene 1 100Hexachlorobutadiene i 100Hexachloroethane i 100Indenoi 1 ,2 ,3-cd >pyrene ! 100

!

i MSDi CONCENTRATIONi ( ug/L )

i 27i 30

121 65i 65i 60i 68i 69

45i 35! 60}1

MSD !2 !

REC *i

27 !30 i12 i65 !65 i60 !68 !69 i45 i35 * i50 i

1I

i :A i QC LIMITS J

RPD «! RPD ! REC. !

62 • ! 50 i t-262!53 •! 50 1 1-1 U!99 •,' 50 ! 1-112!39 ! 50 !39-139!39 i 50 150-158124 ! 50 ! 4-146!27 ! 50 S59-12I!29 ! 50 i 1-152134 i 50 124-118!41 i 50 140-113!31 i 50 ! 1-171!

i !

I colunn to be used to flag recovery and RPD values with an asterisk



Spike Recovery: 8 out of *• outside Units

COMMENTS:

3C-4WATER SEHIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Nane: Contract:

Lab code: Case No.: SAS No.: 5DG No.:


i i SPIKE ! SAMPLEi ! ADDED i CONCENTRATIONi COMPOUND ! (UQ/L) i iug/L>

i Isophorone !i Naphthalene ii Nitrobenzene iI N-Nitroso-di-n-propylan!1 Phenanthrene !i^ Pyrene !»' 1 ,2 ,4-Trichlorobenzene ii 4-Chloro-3-methylphenol !1 2-Chlorophenoi !• 2,4-Dichlorophenol !i 2,4-Olnethylphenol i\ i

tee i103 i100 i100 !100 i

100 i100 i100 i100 i100 i100 i

i* i

0000A

00

MS iCONCENTRATION!

<ug/L) i

73 i. 66 i

66 170 i89 i31 i65 !

0 i 82 i0 i 64 i0 i 69 i0 i 56 i

! i

MS i QC iX SLIMITS!

REC 4! REC. i

7366667089916582646956

i 2 1 - 1 96 i121-133!135-180!! 1-230!i54-120i152-115!i 44-4 42!122-147!! 23- 134!139-135!!32-l19ii i

COMPOUND

IsophoroneNaphthaleneNitrobenzeneN-Nitroso-di-n-propylamPhenanthrenePyrene1 ,2 ,4-Trichiorobenzene4-Chloro-3-methylphenol2-Chiorophenol2 ,4-Dlchlorophenol2 ,4-Dimethylphenol

SPIKEADDED{ ug/L )

100100100100100100100100100100

100

! MSD i! CONCENTRATION!i (ug/L) !

, > «»».»-»». j ,! 53 ii 48 !! 46 i! 50 !i 64 ii 65 i! 45 !! 80 !! 57 ii 64 i! 51 !

MSD iX iREC 1!

53 i48 i46 i50 i54 165 !45 !80 )57 i64 !51 i

iiX !RPD 4!...... ;-33 !32 i35 !34 !33 !34 !35 i3 !

.1 1 i8 i

10 i

QC iRPD

5050505050505050505050

1t

-INIT5 1i REC. i

121-196!121-133!135-180!i 1-230!154-120!!52-H5!i 44- 1 42 i.!22-!4?i123-134!i39-t35i132-119!

i4 column to be used to flag recovery and RPD values with an asterisk



Spike Recovery: 8 out of *« outside limits

COMMENTS:


Lab Name: Contract:

Lab code: Case No.: 5A5 No.: 506 No.:


i ! SPIKE ,! SAMPLE i MSi i ADDED i CONCENTRATION i CONCENTRATION! COMPOUND i <ug/L) I <ug/L> i <ug/L>

i 2 ,4-Dinitrophenoi ii 4.6-Dinitro-2-methylpheii 2-Nitrophenol 11 4-Nitrophenol !i Pentachlorophenol !i Phenol if> 2,4,6-Trichlorophenol i: i

100 !100 i100 i100 !100 !100 !100 i

!

0 i0 i0 i0 i0 i0 i0 i

i

1109670791065380

MS i QC iX ! LIMITS!

REC ii REC. i

i 1 19670791065360

! i-191!i i-132!i 29- 1821i 1-1321i 14-1 76!i 5-1121i37-144ii i

ii: COMPOUNDi 2 ,4-Dinitrophenol! 4,6-Dinltro-2-methyiphe! 2-Nitrophenol! 4-Nitrophenol! Pentachlorophenol1 Phenol! 2 ,4 ,6-Trichlorophenoli

SPIKEADDED<,ug/L>

100100

' 108103100100100

1

i MSD iI CONCENTRATION!! (ug/L) i,;.„.......--«!,j 105 ij 95 i! 63 i! 74 ii 103 ii 52 i! 74 ii

MSD !X i

REC *!

105 !55 i63 i74 !

103 i52 i74 i

i

IRPD i

6t-i

i 17438

QCRPD

50505050505050

11

LIMITS ii REC. !

! i-13lii 1-132!i 29-1 82 ii 1-1321i i4-17Si! 5-i 12 i137-144!i i

* column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC Units


Spike Recovery: 10 out of *• outside limits

COMMENTS:

FORM III SU-I-B 1/87 Rev.

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Page 2 of 2

Continuing Calibration CheckHSL Conpoundf

Cast No:

Contractor: HT-ttiAiest. INC.

Contract No: 090031

Calibration late: 07/07/91

Tine: 11:03

Laboratory ID: HJ82H

Instnnent ID: 70020 Initial Calibration Date: 06/20/91

Ilininvn tt for SftC is 0.95 flaniwn Z Diff for CCC is 2S.OX

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CCC - Calibratian Check Conpau* (•) SPCC - Systen PerfornaMC Check CONJOIMS (••>

Fom UII Page 1 of 3


Case Ho:

Contractor: HET-Hiduest, INC.

Contract Ho: 090031

Inctrunent II: 70020

fliniiw RT for SPCC is 0.05

Conpound RT

Calibration Oate: 07/07/91

Tine: 11:03

Laboratory ID: >OK14

Initial Calibration Bate: 8(/28/94

Itadnw X Oiff for CCC is 25,01

XDiff CCC SPCC

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1.24494 1.0633*1.61165 1.32874.39428 .3(1(2.34325 .27970

1.02971 .98784.121(3 .12193.12(58 .12151

1.41458 1.29128.12306 .3(1(2

1.27083 1.071(2.4977( .45518

1.049(3 .94239.40975 .32428.1(344 .13742.14881 .13325

l.6%82 1.58746.55189 .4%10.28434 .182(3.22(19 .28520.11127 .09415

1.07191 .981451.05(47 .938531.00246 .942041.418(3 1.373771.03000 .931(51.39858 1.1(878.99139 .82116

12.15 >12.72 •

5.71 •8.84

22.28 •12.98 •28.99 •

1.26 •18.5111.04 *

.253.95

*8.S114.52 *15.61 •8.55 *

10.22 *28.8615.92

5.34(.44

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(.033.16 *9.55 •

16.13 •16.36

(CooHOO.OO)

RT - Response Factor fron daily standard file at 51.00 ua/nL

RT - Iterate Response Factor fron Initial Calibration Fern W

ZBiff - I Bifference fron original average or curve

CCC - Calibration Check Conpomb (•) SKI - Syftrn Perfnwct Check Conpounds <«)

Torn VII Page 2 of 3


Case No:

Contractor: KT-ffifcest, IK.

Contract Do: 090031

Instnmnt ID: 78820

Hiniiwi RF for SPCt is 0.05

tapowd «f

Calibratim Date: 07/07/91

fine: 11:03

laboratory ID: MM214

Initial Calibration Date: 0(/28/91

I Diff for CCC is 2S.OI

ZDiff CCCSPCC

btylbenzylpbthalateBenzidineSJ'Hliehlorokttzidinelenzo(a>anthraceiKChrystaebis(2-CthylhexyDphthalateh-iroctvlphtfcalateknn>flwrwtheMDent(k)flwrantheMDen«(a>pyreiKI(*M<1,2,3-cd>wr«*Dibeu(a,k)wthraceneBeno(g>h,i)perylene

.82197 .64532

.10236 .90910

.3(973 .20M1l.tTOW .9taOOI.12S10 .959101.03(15 .913092.07S59 Z.1109(1.75(12 1.7IKK1.32121 1.KUC1.29212 1.182791.2K81 1.2(9051.07599 1.151211.28281 1.2(915

18.91 *91.1121.9918.81 *11.73 »11.901.70 *2.81 «

10.01 •8.18 «5.58 *7.27 •

'S.58 *

tf • Response Factor frn dtily staMfard file at 58.08 ui/hL

RT - Rveraoe Response factor fron Initial Calibratim Fora 01

ZDiff - I Difference fron original average or curve

CCC - Calibration Check Conpomb (*> SKC - Systat Performce Check Canpounds (»>

forhKII Page 3 of 3

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BTL.it 2

1 d F i l e s • ) 8 2 7 0 s s T :i.T i t le ' Erft Method 8270. Ca 1 i br at i on Curue. HP5970, 70C2D

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Data F i l e : > 0 8 2 1 4 = = D 2 Ouan'. Output K i 1 e = " 0 8 2 1 4 = : Q ONames BHfl S ' T D . tOPF'B 1 •••?*:r ument ID* /002DI'M so = SSTD050 !ul. 21619 BTLtt 2

*

id f i - le- 0._8?.705 i f- 1T i t l e s EPfi .Method 8270, C a l i b r a t i o n Curue, HP?97C, 7002DLast Calibration: 940 2:8 10 = 34 Last Qcal T i rne f <none>

Operator ID: RflMON 'Quant Time : 940707 ll-:?/1

Injected at= 940707 .11:0:*

Page 2 of 2'

8CSEMIVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab, Name: Contract:


Lab File ID (Standard): >D82U

Instrument ID:

SDG No.:


Time Analyzed: I 1:03

t 11 t

! 12 HOUR STOi

UPPER LIMIT!

LOWER LIMIT!

EPA SAMPLE !NO. !

1 !BNA BLANK !2! BNA LCS !3! BNA LCSDUP !4! BNA BLANK !5! BNA LCS t !6!BTt267252DL !7!BTf267280DL !8!BTt267323DL !9!BTt267324DL !l0!BTt267075RE !It !BTt267162DL i12!BTt267189DL !13!BTt2672S2RE !14!BT*267280RE i1S!BTf267323RE !16!BTt267324RE !17! t18! !19! i20! i21 ! i22! !

IS4CPHN) !AREA t !

102559 '

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51280.....«.».:

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!RT !

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2AWATER VOLATILE SURROGATE RECOVERY

Lab Nane: NET MIDUEST-BARTLETT Contract:

Lab code: Case No.: SAS No.: SDG No.

: ERA,' SAMPLE NO.:============

01 ISDUA BLANK02ISDUA LFB03!BTt26S85904IBTS26586005!BT*26641506 !BTf 26707507!BT«26733808 IBTf 26733909!BT*26734010!BT*265859DP11 !BTf265860DP12!13114!15!16!17118119! !

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5152

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page _ of _.FORM II VOA-1 1/87 Rev

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BFB Injection Tine: 12:B9

Matrix: (soil/water) WATER Level:<low/med) LOW Column:(pack/cap> CAP

n/e I ION ABUNDANCE CRITERIA! X RELATIVE! ABUNDANCE

! 50 i75 I

1 95 !j 96 1i 173 !

174 I175 1176 !177 1

!

15.0 - 40. 0X of mass 9530.0 - 60. 0X of mass 95Base Peak, 100X relative abundance5.0 - 9.0X of mass 95Less than 2.0X of mass 174Greater than 50X of mass 955.0 - 9.0X of mass 17495.0 - 101.0% of mass 1745.0 - 9.0X of mass 1*76

'.

16.840.7

100.06.6.7 <

92.45.8 (

91.2 (6.4 (

!1(I1

1.8)1 i

!6.3)1!98.8)1 !7.0)2!

I1

I-Value is X of mass 174 2-Value is X of mass 176

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

EPAI SAMPLE NO.

0 1 I SDWA STAND02! SOWA BLANK031 SDWA LFB04! BTf 26565905! BTt26586006! BT*26641507! BU26707508! BTt26733809! BTt26733910! BTt2673401 1 ! BTt265859012! BTf 265860013!14!15!16!17!18!19!20!21!99 !

LABSAMPLE ID

SDWA010SDWABLKLCB005F 25XF 2SX

ERECOLOGYH IKI* IKC IKf JUP1 3UP

.

'

LABFILE ID

>A0363>A0365>A0366>A0367>A0368>A0369>A0370>A0371>A0372>A0373>A0374>A0375

DATEANALYZED.»..««.*:

07/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/9407/06/94

TIMEANALYZED====.==..=,

13:1615:0715:4416:2116:5817:3418:1018:4719:2319:5820:34 *21 :11 3

QC REPORTMS VOLATILES

era/Ietters/cover.msvoI

TOTPl. ION CHPOMOTOGRPMFile >fl?73* 33.0-309.0 amu.

T I L>50PPB SHFE DRINKING

20.0 400 608 800 1000.. I .... I

26 28

Data File: >A9736::D4 Quant Output File:Name: SDUA STD 50PPB ,Misc: SAFE DRINKING WATER ACT, 10UL 21413, 50UL 21412, 25ML

Id File: A_524W::F1Title: VOLATILE ANALYSIS - METHOD 524.2 - 7001ALast Calibration: 940419 12:16

Operator ID: LANQuant Time: 940506 12:29Injected at: 940506 11:59

Compound R.I'. U ion Rrea Lone Units

44)45)46)47)48)49)50)51 )52)53)54)55)56)57)58)59)60)61)62)

PropylbenzeneBromobenzene1,3,5-Tri me thylbenzene2-Chlorotoluene4-Chloroto luenetert-Butylbenzene1,2 ,4-lr i me thy 1 benzenesec-Butylbenzenep- 1 sop ropy 1 to luene1,3-Dichlorobenzene1,4-Dichlorobenzenen-Butylbenzenel,2-Dichlorobenzene-d41 ,2-Dichlorobenzene1 ,2-Dib romo-3-ch loropropane^1,2,4-Trichlorobenzene•Hexach lorobutadieneNaphtha lene1,2,3-Trichlorobenzene

19192020202121212121222222232426272727

.89

. 87

.26

.22

.33

. 05

. 12

.54

.84

.96

. 19,79.98.02.81.83.24.38.99

91.156.105.91.91.119.105.105.119.146.146.91.150.146.157.180.225.128.180.

U000000000000000000

1284971204163804829723870645926H88965771456912739579833923848303694711U07996628 10H27596417191196854226643150211121636

51.53.50.55.46.52.51.51.52.51.51.51.10.51.57.54.52.56.51.

68359112412048863244372695831351325498

ug/Lug/Lug/Lug/Lug/L -ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

899787959878979685959394^6\^6194879788

* Compound is 1STD

QOANT REPORT

Quant Rev: 6Operator ID: LANOutput File: -^9736::QTData File: >A9736::D4Name: SDUA STD 50PPBnisc: SAFE DRINKING WATER AC1, 100L 21413, 50UL 21412, 25ML

Quan t Iime:Injected at:

Oi lution Factor:

940506 12:29940506 11:59

1.00000

ID File: A_524UI: :F1Title: VOLATILE ANALYSIS - METHOD 524.2 - 70U1ALast Calibration: 940419 12:16

Compound R.T. Q ion Area Cone On its

1)2)3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41 )

*r luorobenzeneDichlorodif luorome thaneChloro me thane-Uiny 1 ch lor ide'Bromome thaneCh loroe thaneTrichlorofl uorome thane1,1-DichloroetheneDichlorome thane1,2-trans-Dichloroethene1 , 1-U ich loroe thane1 ,2-c is-D ich loroe thene "2,2-DichloropropaneChloroformBromoch loromethane t1 , 1 , 1-Tr ich loroethane1,1-DichloropropeneCarbon tet rach lor ide1,2-Dich loroe thaneBenzeneTr ich loroe thene1,2-DichloropropaneD ich 1 orobromome thaneDibromome thane1,3-cis-DichloropropeneTo luene1,3-trans-Dichloropropene1,1,2-Trichloroethane1,3-DichloropropaneTet rach loroe theneCh lorodlbromomethane1,2-Dibromoethane (EDB)Ch lorobenzene1,1,1,2-TetrachloroethaneEthy Ibenzenem&p-Xy leneo-Xy leneSt yreneBromof orm1,1,2,2-TetrachloroethaneI sooroDvlbenzene

10.2.2.2.3.3.3.4.5.5.6.7.7.8.8.9.9.9.9.9.11.11.11.11.13.13.14.14.15.15.15.15.16.17.17.17.18.18.18.19.18.

2721495809195139228366847717440032517981114692991075174700145193880204251524853399

96.85.50.62.94.64.101.96.84.96.63.96.77.83.130.97.75.117.62.78.130.63.83.174.75.92.75.97.76.166.129.107.112.131.106.106.106.104.173.83.1U5.

000000000000000000000000000000000000000U0

151098377885M165279M197708M2640891343376194152850801713232963434320702505034411074885311325055333224372155074141419926307003835051824773258641091692230434467661461089238113780944339520388213151047118821509126308167585628391741544010426494685

1007977

1051454850495151495051495251505150525249515052515350555351515454505150995152595550

.00

.34

. 13

.42

.31

.62

.89

. 05

.58

.53

.Ob

.95

.04

.78

.71

.53

.39

.99

. 12

.28

.21

.23

.88

.93

.72

. 11

.20

.38

.98

.72

.90

.31

.36

.72

.48

.10

.09

.58

.33

.16

.42

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

8993949891769b776b8792959593938788b69298629997b59595959492939397809792949085999691

TOTfll. ION CHPOMPTOKROMio -> f l<»73<;T* .8 -300 .0 affi'j. S- ' - - TIC

366000-

320000-

230000

240890-

200090-

200 400

STD 30PPB

600 . 800

SRFF DRINKING MPTF.R

1000

10! ' ! • I ' I ' 1^12 14 16

D a t a F i l e : > 'R973^::D4 Quan t O u t p u t F i l e : 'Name: SDUIA STD 30PPB ,M i s c : SAFE D R I N K I N G LJAl t£R ftCT , 10UL 21413, 30UL 21412,

Id File: A_'524U: :F1Title: VOLATILE ANALYSIS - FIETHUD 524.2 - 7001ALast Calibration: 940419 12:16

Operator ID: LANQuant Time: 940>?06 11:52Injected at: 94U5G6 11:22

: : LJ I

Compound R. I . U ion ftrea Cone Uni ts

44)45)46)47)48)49)50)51)52)53 )54)55)56)57)58)59)60)61)62)

Propy IbenzeneBromobenzene1,3,5-Tri me thylbenzene2-Chlorotoluene4- Ch loroto luenetert-Butylbenzene1/2, 4- Tri me thylbenzenesec-Butylbenzenep- Isopropyl to luene1 ,3-Dich lorobenzene1 ,4-Dich lorobenzenen-Butylbenzenel,2-Dichlorobenzene-d41 ,2-Dich lorobenzenel,2-Dibromo-3-chloropropane-1,2,4-Trichlorobenzene'Hexach lorobutadieneNaphtha 1 ene1,2,3-Trichlorobenzene

19.19.20.20.20.21.21.21.21.21.22.22.22.23.24.26.27.27.27.

89862621330212518395217695027884233797

91-.156.105.91.91.119.105.105.119.146.146.91 .150.146.157.180.225.128.180.

0000000000000000000

74308412177447673436289442687449816841177871050055646'cl22777922044055140068685162604998011

1121231177818367877212

29.31.29.27.30.28.29.28.29.29.30.27.11 .30.32.30.26.31.32.

41326719187719461496165979066455760047

ug/Lug/Lug/Lug/Lug/L.,ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

9095979594769897869395967895

99959774

* Compound is IS ID

QUANT KEHUKI

Uuan t Rev: 6 -Operator ID: LANOutput File:Data Fi le: >A9735: : D4Name: SDWA STD 30PPBflisc: SAFE DRINKING WATER AC1 , 10LJL 21413, 30UL 21412, 25hL

Quan t Time:Injected at:

D i l u t i o n Factor:

940506 11:52940506 11:22

1. 00000

ID File: A_524W::F1Title: VOLATILE ANALYSIS - NETHUD 524.2 - 701)1 ALast Calibration: 940419 12:16

1)2)3)4)5)6)7)8)9)10)11)12)13)14)15 )16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)

Compound

*FluorobenzeneDichlorodifl uorome thaneCh lorome thaneÔmy 1 ch lor ide* B r o mo methaneCh loroe thaneTr ich lorof luoromethane1,1-DichloroetheneDichloro me thane1 , 2 - 1 rans-Dich loroe thenfi1,1-D ich loroe thane1,2-cis-Dichloroethene"2,2-DichloropropaneChloroformBromoch lorome thane ;1,1,1-Trichloroethane1,1-D ich IoropropeneCarbon t e t rach lor ide1,2-D ich loroe thaneBenzeneTr ich loroe thene1,2-Dich loropropaneD i ch 1 orobromome thaneD ibromorne thane1,3-cis-Dich Ioropropene"1 o 1 u e n e1 ,3-t rans-Dich Ioropropene1 , 1 , 2 - 1 r i c h i o r o e t h a n e1 ,3-LJich loropropanefetrachloroetheneChlorodibrorno methane1,2-Dibromoethane CEDB)Ch lo robenzene1,1,1,2-TetrachloroethaneEthy Ibenzenem&p-Xy 1 eneo-Xy 1 eneStyreneBromof orm1,1,2,2-TetrachloroethaneI sop ropy Ibenzene

R.

10.2.2.2.3.3.3.4.^ .5.6.7.7.8.8.a.9.9.9.9 .11.11.11.11.13.13.14.14.15.15.15.15.16.16.17.17.18.18.18.19.18.

T.

30194758071951392280648479194798324979Bl114592991077164600165192879906221724873398

Q i

9685506294641019684966396778313U977511762781306383174759275977616612910711213110610610610417383105

on

. 0

.0

. 0

.0

. 0

. 0

. 0

. 0

.0

. 0

. 0

.0

. 0

.0

.0

. 0

. 0

.0

. 0

. 0

.0

. 0

. 0

.0

.0

. 0

. 0

. 0

. 0

. 0

. 0

.0

.0

.0

.0

. 0

. 0

.0

.0

. 0

.0

Area

153537219335M100266M11343415278180650361380165491993291732312522561511662590182868367847730954826068029607883387

37900222615210664019259667652129189262500822875411481385

259816122025756852731851306641616224090861679232417935756955237585979

Cone

10.29.26.27.28.29.29.29.28.29.29.29.30.29.29.29.29.30.30.29.29.28.30.31.30.28 .30.30 .30.29.32.30.28.30.30.59.29.30.32.31.28.

003394346432791629073566079256435743121472897667629860,'' S

21833376739252037312246784

Units

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Luq/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Luq/L

q•-ty

\_J;98969277997668929593949897ay8tJ6

W39884989792959697ay97899797849691988882959092

TOTPL ION CHROMPTOGRfiMFi l e >R9732 33.9-309.0 affi'j . SHUG STD 19PPB

130000-

120000-

110000-

100000-

90000-

80000-

70000-

60000-

50080-

48880-

30080-

20000-

10000-

0-

200 400

SPFF. T IRTNKtNC I.IPTFP

1600

' r "* T I ' I • I 'I'l')'!'!'!'?'!'!'!'!'!'!'!'!'10 12 14 16 18 28 22 24 26 28

Data File: >'A97?2::D3 Quant Output File: ~A9732::QTName: SDUA STD 10PPB ,Misc: SAFE DRINKING UlATtR AC! , 10UL 21413, 1UUL 21412,

Id File: A_524U::F1Title: UOLAT1LE ANALYSIS - METHOD 524.2 - 7CIU1ALast Calibration: 940419 12:16


Compound R.T. U ion ftrea Cone Units

44)45 )46)47)48)49;50)51 )52)53)54)55)56)57)58)59)60)61)62)

Propyl benzeneBromobenzene1,3,5-Tr imethylbenzene2-Chlorotoluene4- Chioro toluenet e r t - Bu tylbenzene1/2,4-Tr imethylbenzenesec-Bu t y 1 benzenep-Isopropyl toluene1 ,3-Dich lorobenzene1, 4- Dich lorobenzenen-Bu tylbenzenel/2-Dichlorobenzene-d41,2-Dich lorobenzene1 ,2-Dibromo-3-ch loropropane

-,1 r'2 ,4- Tr ich lorobenzene'HexachlorobutadieneNaph t ha lene1, 2, 3-Trich lorobenzene

19192020202121212121222222222426272727

.85

.85

.22

.20

.29

.01

. 10

.50

.82

.94

.19

.75

.94

.98

.79

.82

.22

.38

.98

91.156.105.91.91.

119.105.105.119.146.146.91.

150.146.157.180.225.128.180.

0000000000000000000

26264838719161400129649139724182301144418259960201342777157372321334351994536132849M38418559782597225681

10101091010101010101010910910139

11

.69

.24

.33

.99

.16

.82

.53

.71

.84

.51

.37

.98

. 17

.19

.58

.76

.08

.89

. 11

ug/Lug/Lug/Lug/Lug/L:-ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

959792949477999986959496

'iS

85859781

* Compound is 1STD

QUAN) RLPORT

Uluant Rev: 6Operator ID: LANOutput Fi le: • ' "A9732::QrData File: >A9732:: D3Name: SDUA SID 10PPBMisc: SAFE DRINKING WATER ACT , 100L 21413, 1UUL 21412, 25ML

Quan t Time:Injected at:

D i l u t i o n Factor:

940506 10:03940506 09:25

1. UUU U U

TitLas '

1)2)3)4)5)6 )7)8)9 )10)11)12)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41 1

le: UOLATILE ANALYSIS - I1ETHUD 524.t Calibration: 940419 12:16

Compound R.

*FluorobenzeneDich lor od i f luorome thaneCh lorome thane-U my 1 chloride' B r o mo me thaneCh loroe thaneTrichlorof luorome thane1,1-DichloroetheneDichloro me thane1/2-trans-Dichloroethene"1 , 1-Dich loroe thane1,2-cis-Dichloroethene'2,2-DichloropropaneCh lorof ormBromoch lorome thane i1,1,1- Frichloroethane1,1-DichloropropeneCarbon t et rach lor ide1,2-Dich loroe thaneBenzeneTr ich loroe thene1,2-DichloropropaneDichlorobromomethaneD i b romome thane1,3-cis-DichloropropeneTo luene1,3-trans-Dichloropropene1 , 1 ,2-Tr ich loroethane1,3-DichloropropaneTetrach loroe theneChlorodibromomethane1 ,2-Dibromoethane IEDB)Ch lorobenzene1,1,1,2-TetrachloroethaneEt hy Ibenzenem&p-Xy leneo-Xy leneStyreneBromo f orm1,1,2,2-Tetrachloroethane1 nnrnn>.jlbpn7ene

10.2.2.2.3.3.3.4.5.5.6.7.7.8.8.8.9.9.9.9.11.11.11.11.13.13.14.14.14.15.15.15.16.16.17.17.18.18.18.19.18.

2 -

T.

2721475607185136207861817716449730467678Ob4389960774134499134892879803211421863097

- 7001A

U i on

96.85.50.62.94.64.

101.96.84.96.63.96.77.83.130.97.75.

117.62.78.

130.63.83.174.75.92.75.97.76.166.129.107.112.131.106.106 .106.104.173.83.

105.

0000000000000000000000000000000000000000u

Area

14933053895M34251M414585344426717125454596593277161116845425035093749'94748255251078229021410407626413130238810513565761041214544020210475625371166642565795176350942361593350412925377414064458831798711719315925209490

Cone

10791010910109101010111091010119101091010911999119910101020101099HI

. 00

.41

.46

.27

.30

.99

.63

.81

.60

.55

. 11

. 16

. 19

. 16

.88

.54

.52

. 00

.81

.30

.95

.93

. 02

.33

.80

.89

.70

.74

.79

.23

.56

.87

.09

.05

.44

.87

.71

.23

.90

.39

. 60

Units

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lua/L

q89

999587749d7468799386959891918379939878969b9b9497889294949695789596968590979091

TOTPL ION CHROMfiTOGRPMFile >R973433.0-300.0 amu. S D M P S T O 5 P P B

TICSPFE DRINKING UPTEIR

880 1000

T I4

I ! r I T I 1 I ' T ' I ' I ' I ' I ' I ' I " T I I I I l l l l6 8 IB 12 14 16 18 20 22 24 26 28

Data File: >A9734::D4 Quant Output F i le : 'NA9724: : L|TName: SDUA STD 5PPB (Misc: SAFE DRINKING WATER ACT, 10LJL 21413, ÛL 21412, 25ML

Id File: A_524U: :F1Title: UOLATILE ANALYSIS - METHOD 524.2 - 7UU1ALast Calibration: 940419 12:16


Compound R.T. Q ion ttrea Cone Units

44)45)46)47)48)49)50)51 )52)53)54)55 )56)57)58)59)60)61)62)

Propy IbenzeneBromo benzene1,3,5-Tri me thy Ibenzene2-Chiorotoluene4-Ch loro toluenetert-Butylbenzene1,2,4-Trimethylbenzenesec-Butylbenzenep- Isopropylto luene1,3-Dichlorobenzene1, 4- Dich loro benzenen-Butylbenzenel,2-Dichlorobenzene-d41,2-Dichlorobenzenel,2-Dibromo-3-chloropropane-1,2,4-Trichlorobenzene'HexachlorobutadieneNaphtha lene1,2,3-Trichlorobenzene

19.19.20.20.20.21.21.21.21.21.22.22.22.23.24.26.27.27.27.

87852522310310528296197793008184213898

91.156.

.105.91.91.

119.105.105.119.146.146.91.

150.146.157.180.225.128.180.

0000000000000000000

128236199478085071116672/4870847262912727196676410213698310041351467282251560M20715249821471113560

5555455555558555555

.15

.21

. 11

.41

.83

.10

.23

. 18

. 14

.48

. 14

.10

.97

.30

.18

.73

.76

.53

.79

ug/Lug/Lug/Lug/Lug/L'-ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

9191869694799596849493948392

94949487

* Compound is 1STO

QUANI REPORT

Operator ID: LAN UuantOutput File: ~A9734::QTData File: >A9734::D4Name: SDUA STD 5PPBMisc: SAFE DRINKING WATER ACT, 10UL 21413,

Fl

6 " Quan t Time:Injected at:

Dilution Factor:

5UL 21412, 25ML

940506 11:16940506 10:46

1.00000

Title: VOLATILE ANALYSIS - HE THUD 524.Last Calibration: 940419 12:16

Compound R.

1)2)3)4)5)6)7)8)9)10)11)12)13)14)1 '.-• )16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41 i

*FluorobenzeneD ich lorodifluorome thaneCh loromethane,JJiny 1 ch lor ide"Bromomet haneCh 1 oroe t haneTr ich lorof luoro me thane1,1-DichloroetheneD ich loromethane1,2-trans-Dichloroethene*1 , 1-Dich 1 oroe thane1,2-cis-Dichloroethene"2 ,2-DichloropropaneCh lor of ormBrornoch lor orne thane >1,1,1-Trichloroethane1,1-DicnloropropeneCarbon te t rach lor ide1,2-DichloroethaneBenzeneTrichloroethene1,2-DichloropropaneDich lorobromome thaneDibromome thane1 ,3-cis-DichloropropeneTo luene1,3-trans-Dichloropropene1,1,2-Trichloroethane1,3-DichloropropaneTet rach lo roe theneChlo rod ibromo me thane1/2-Dibromoethane (ED8)Ch lorobenzene1,1,1,2-TetrachloroethaneEthy Ibenzenem&p-Xy leneo-Xy leneSt yreneBromoform1,1,2,2-TetrachloroethaneI =. n n r n rn. .1 1 h f» n 7 P n f=>

10.2.2.2.j, _3.3.4.5.5 .6.7.•".»S .

8.8.8.9.9.9.9.11.11.11.11.13.13.14.14.

' 15.15.15.15.16.17.17.17.18.18.18.19.IB.

2 -

T .

2921475809185339228266847916469932487880104591980976164601155092860005231423853299

- 7001A

Q ion

96.85.50.62.94.64.101.96.84.96.63.96.77.83.130.97.75.117.62.78.130.63.83.174.75.92.75.97.76.166.129.107.112.131.106.106.106.104.173.83.

i us.

00000000000u000IJ0000000u0000000000000000n

Area

15123737234fl16999M19944258971323160967285391741029492421622576042745482091342451494451664963614061644953840U18118310441123420903457951333188391403543893194171261347556212212696469851290114069589668839

•| runs 3

Cone

10.5.4.4.4.4.5.5.5.5.4.5 .5.5 .5.4.5.5.5.5 .5.4.5.5 .5.5.5.5.5.5 .5 .5 .5.5.5.10.5.5.5.5.5 .

000564yy938810110302981304111397201816031298033403130310291222200810172322151014I'm

Un i ts

ug/Lug/LUQXLug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/LugXLug---'Lug-'Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lpin/!

q91

939993til957462969090979791878'J•Y/

_ 09985979791969b96899993969777989'/96808589959 /

TOTfll ION CHROMOTORRfiMFile >fl9733 33.0-300.0 amu. SPMP STT) 1PPK

I TICSPFE G WOTFP ]

44000-

40000-

36000-^

32008^

26000-J

24888-

20000-

16000-

12808-J

8008-

400

0J

200 400 600 800 1000

•*OS

CM

I F T T l l T ' I ' l ' ! ' ! ' ! ' ! ' ! ' ! ' ! '4 6 8 10 12 14 16 18

* ! ' I " I " 1 * F '20 22 24 26

* I I28

Data File: >'A9733::D3 Quant Output F i l e : 9733 : : CJTName: SDWA SID 1PPB ,Misc: SAFE DRINKING WATER ACT, 10OL 21413, 10L 21412, 2<?riL

Id File: A_524U::F1Title: UOLATILE ANALYSIS - METHOD 524.2 - 7U01ALast Calibration: 940419 12:16

Operator ID: LANQuant Time: 940S06 1U:39Injected at: 9405G6 10:09

Compound R.i. Q ion ftrea Cone Uni ts

44)45)46)47)48)49)50)51)52)53)54)55)56)57)58)59)60)61)62)

Propy IbenzeneBromobenzene1,3,5-Trimethylbenzene2-Chlorotoluene4-Chlorotoluenetert-Butylbenzene1,2 ,4-Tr i me thy Ibenzenesec-Butylbenzenep-Isopropyltoluene1,3-Dichlorobenzene1,4-Dichlorobenzenen-Buty Ibenzenel,2-Dichlorobenzene-d41,2-Dichlorobenzenel,2-Dibromo-3-chloropropane-1,2,4-Trichlorobenzene"HexachlorobutadleneNaphtha lene1/2,3-Trichlorobenzene

19.19.20.20.20.21.21.21.21.21.22.22.22.22.24.26.27.27.27.

87872422310310518195187695998083233799

91-.156.105.91.91.

119.105.105.119.146.146.91.

150.146.157.180.225 .128.180.

0000000000000000000

269744606178391517715000187641597426418204099427870821040551426838396M4703539240413492

.

1.1.1...

1..•

1.1..

8.1.1.1.1.1.1.

96070003969802969712089555141716113533

ug/Lug/Lug/Lug/Lug/L--ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

919993939673939686959189

^ \ f76

97859880

* Compound is ISTD

UUANI KLPUKl

Operator ID: LAN Uuant Kev: 6 - ljuant lime:Output F i l e : "-A9733: : QI Injected at:Data File: >A9733::D3 D i l u t i o n I-actor:Name: SDUIA STD 1PPBriisc: SAFE DRINKING WA I ER ACT, 1UUL 21413, 1UL 21412, 25ML

ID File: A_524UI: :F1Title: YULATILE ANALYSIS - NEVHOD 524.2 - 7001ALast Calibration: 940419 12:16

940506 1U:39940506 1U:09

1.00000

1)2)3)4)5 )6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41 ,1

1 Compound

*FluorobenzeneDichlorodifluoromethaneCh loromethane,Uinyl chloride•Bromomet haneCh loroe thaneTrichlorofluoro me thane1,1-DichloroetheneDich loromethane1,2-trans-Dichloroethene1 , 1-Dich loroe thane1,2-cis-Dichloroethene*2 ,2-DichloropropaneChloroform 'Bromoch loromethane .1,1,1-Trichloroethane1,1-DichloropropeneCarbon tet rach lor ide1,2-DichloroethaneBenzeneTrichloroethene1,2-DichloropropaneDi ch lorobromome thaneD ib romome thane1,3-cis-DichloropropeneCo luene1,3-trans-Dichloropropene1 ,1,2-rrichioroethane1 ,3-DichloropropaneTet rach lo roe theneCh lorodibromo me thane1,2-Dibromoethane CEDB)Ch lorobenzene1,1,1,2-TetrachloroethaneEthylbenzenem&p-Xy leneo-Xy leneSt yreneBromof orm1,1,2,2-letrachloroethaneisoproovlbenzene

R.

10.2.2.2.3.3.3.4.5.5.6.7.7.8.8.8.9.9.9.9.11.11.11.11.13.13.14.14.15.15.15.15.16.17.17.17.18.IB.18.19.18.

T.

2921475809185141228063837916469732508082124493980976154801154993860004231322873199

Q i

96855062946410196849663967783130977511762781306383174759275977616612910711213110610610610417383105

on

. 0

.0

.0

.0

. 0

. 0

. 0

.0

.0

. 0

. 0

.0

.0

.0

. 0

.0

.0

. 0

.0

. 0

. 0

. 0

. 0

.0

.0

.0

. 0

. 0

.0

. 0

. 0

. 0

. 0

.0

. 0

. o-,0. 0. 0.0. 1.1

Area

1698785214M35223846562126611222457294243M6260875054968760

1071629111045589529515310814332

75514159M693624394273

11308292020683181949141242907M1090446045989155026359915919891997

21281

Cone

10........

1.....

1.....

1.1.•

1.1.1..

1..

1.1...

1.1.•

1.2.1.1.1.1..

0063868495879191099592979201999092880100900200039213980607989907049802020203010395

Units

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

q89

999882879377

879395959092868682869988

949195989098949297

769492948288858990

Calib F i l e t OC524H::F1 Comp * 1

Co flip ;

fiver»g« RF

Cone .

55-

50-

45-

40-

35-

30

20-

16-

10-

5-

/

X.X .X

9.9

XX

.s 1.2 i.e.Response Ratio

2.9 2.S

Compound t 1 Calib File: ACS24W::F1

Compound: Dichlorodi fluoromethaneIstd: Fluorobenzene

File: >A9733 >A9734 >A9732 >A9735 >A9736Cone: 1.00 5.00 10.00 ' 30.00 50.00

Rf: .30693 .49239 .36091 .47618 .50019

Averaae of 5 Rfs: .42732 (20.55 % Rsd) Rx: .0000000 Ry:1st Oearee Eauation: y - .1189578 + 1.97166l(x)

1st Degree Corn Coef: .99843692hdJ)earee Equation: j --=—r«538389 + 2.243674(x) + -. 108006( x*2 )

2nd' Deqree^Corr Coef: [ 989688 (

In the above equations:

Cone Std Area Stdv » ——————— x. * —————

Cone Istd Area Istd

Istd Cone for all calibration points is: 10.00

.0000000

Continuing Calibration CheekHSL Conpounds

Case Ho:

Contractor:

Contract No:

Instrunent ID:


Tine: 21:20

Laboratory ID: MB718

tlinimn RT for SPCC is

Conpound


fexinun I Diff for CCC is 30.01

RT RT IDiff CCC SPCC

t.U.2-Tetrachloroethaoe[thvlbenzeneriM-Xvleneo-XyleneStvreneBrwforn1.1,2.2-retrachloroethaMIsoprapvlbenzeneBrMflurobenzene1 .2.3-lrichlsropropanePrttvlbenzeneBronokeazene1,3,5-TrlnetbvlbenHfle2-CUorotoluene1-CUorotoluenetert-fctvloenzene1,2.1-Trinethvlbenzene .secHhitvlbenzenep*Isoprspvltoluene1.3-Oichlorobenzene1 .Wichlorobenzenen-flutylbenzem1.2-Oichlorobenzene-dl1.2-hchlorobeniene1 .2-OibnM-3-chlaropropanel.2.HrichlorobenzeneHeochlorobutadienenaphthalene1 .2,3-Trichlorobenzenetert-ftityl nethvl ether (HIDE)

.27931

.35367

.15600

.37816.53710.12276.11727

1.31728.29076.02755

1.67132.26576

1.06009.88961.89801

1.11722.91151

1.611561.26759.52131.19260

1.30529.37523.37062.02119.26211.31567.19737.17710

-

..31259.10523.31190.48208.10601.10702-

.29573----- •----- i

.13916

.39812-

.37360

.313%---

.16236-

.18906

.

3.1311.159.66

10.2913.618.71-1.71----

«

-----

16.2519.12-.13

15.29---7.60--

(Conc-20.00)

(Conc-IO.M)

(CoicMO.00)

RT - Response Factor frm daily standard file at IO.OOw/1

RF - Average Response Factor fron Initial Calibratin fora VI

ZOiff - I Difference fran original average ar curve

CCC - Calibration Check Conpounds (»> SPCC - Sviten Performance Check Conpounds <**>

Fora WI Pate 2 of 2

Continuing Calibration CheckHSL Cowounds

Case No:

Contractor:

Contract No:

Instrument ID:

Calibration Date: 05/flt/91

Tine: 21:20

Itinimn Rf for SPCC is

Conoound

Laboratory 10:

Initial Calibration Date:

flariiwi I Oiff for CCC is 30.01

RT RF XOiff CCC SPCC

OichlorodifluoronethaneChlorine thaneUiwl chlorideBrononethaneChlroethmeIrichlonrfluoronethaneI.HichloroetheneOichlironethne1 ,2-trans-OichloroetheneU-Oichloroethane1 .2-cis-8ichloroethene2.2-flicUoropropaneChlrofornBronochloroMthawI.U-TrlchloroethaneU-OichloropropeneCarbon tetrachloride1.2-OichloroethaneBenzeneTrichloroethene1 ,2-OichlororopaneOichlorobroMMe thaneOibrononethaM1 .3-cis-OichloropropeneToluene1 ,3-trans-Oichloropropene1,1.2-Irichloroethane1,3-lichloroxopMeTetrachloroetheneChlorodibrononethane1.2-Oibronoethane(E08)Chlorobenzene

.12732

.21959

.25515

.31250

.17289

.79108

.37016

.22837

.38722

.551(7

.33222

.57099

.(3111

.17312

.(7928

.57K1

.(1558

.18295

.81527

.19871

.23925

.11511

.11511

.27158

.(2(80

.17802

.11800

.18075.58519.25387.1((89.(2253

-.15995.21997.29310.11911.(7797.313(2.20150.31077.51(50.29727

-.58158-

.(2112-

.(1(05

.1(518

.75713

.15021

.22131

.3(118-

.217(2

.53113

.K2H

.10713-

.528(3

.22170-

.57115

C 27.16"13.79

11.1213. «11(27.17

11.7712.00(.37

10.52-7.86

*

8.52-1.579.55

10.398.137.50

13.05-9.82

11.718.758.95-9.71

12.(7-8.25

RT - Response Factor fron dailv statdard file at 10.08 uq/L

RF - Rveraoe Response Factor fron Initial Calikratlon Font VI

ZOiff - Z Oifference fron original averaqe or curve

CCC - Calibration Check Conpoumfa (*) SPCC - Svsten Perfornance Check Conoounds (*•)

Torn vll Page 1 of 2

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Uuan t He1-,'Uperator ID: LANOutput File: ~A0366::UlL'ota Fi'le: >A0366::U3Name: SDUA LKB 5PPBMisc: LI-BO05 5UL 21654, 10UL 21675, 25f1L PURGED

6 Uuan t I imeInjected at

Dilution l-actor

ID File: ft!524W. :F1T i t l e : VOLATILE ANALYSIS - HE!HDD 524.2Last Cal ibration:' 940706 14:2?

- 7001M

940706 16 : 15941)706 15:44

1. U U U 0 U

Compound U ion Area Lone Un i ts

1 J2 J3 )4)5)6;7)8 )9 )

10 J11 )12 J13)14)15)16)17)18)19)20)21)22)23)24)25)26)27 J28)29)30)31 )32)33)• .; -.' •

36)3 7 j38J3 9 )4 ',: i-4 - .'

. L'

*K luorobenzeneDichlorodifl uorome thaneCh lorome thaneUiny 1 ch lor ideBromome thaneCh lo roe thane

'Trichlorofluoro me thane1,1-DichloroetheneDie h lorome thane1,2-trans-Oichloroethene1,1-Dichloroethane1,2-cis-Dichloroethene2 ,2-Dich loropropaneCh loro t ormBro mo ch lorome thane1,1,1-lrich-loroethane1,1-DichloropropeneCarbon tet rach lor ide {

1,2-DichloroethaneBenzene1 r ichloroethene1,2-DichloropropaneDich lorobromo me thaneD i b romome t'hane1 ,3-c is-Dich loropropene1 o luene1,3-trans-Dichloropropene1,1,2-1 r i c h 1 o r o e t h a n e1 ,3-DichloropropaneTet rach lo roe theneCh 1 o rod i b romome thane1 ,2-Dibromoethane '' EU8 >Ch lor obenre r -:-1 , .' .1 , 2 - 1 e t r a c h 1 o r o e t h a n eLt J-iy 1 benzenern&p-Xy leneo-;'.y i eneot yreneBrorno for rn1 , 1 ,2 ,2- ie t rach 1 c ro^h-ani?I =•:>•. .,->., :b-.::-.z*rie•:J '.' •'. " . c i' ! -j c '• o benzene:,:',.' '. <• • •::-. ' o ; - - - p r •-•- = r ~

10.2 .•"Jz. •

2.3.3.3.4.5.6.7.8.8.8.

. 8.9 .9.10.10.10.11.11.12.12.13.14.14.14.15.15 .15 .16 .17.17.1 7 .17.18.18.i • '19.r- .19.• i i :

77427086375388857533lo37306997528201293358933946552059924559•j _•,38304246635562

71'•687• t

96.85 .50.62.94.64.

101.96.84.96.63.96.77.83.130.97.75.117.62.78.

130.63.83.174.75 .92.75.97.76.166 .12'- .1U7.112.131.106.106.106.104.1 ' '.'

y J .1 '.i ':• .1 74 .1 'J !! .

00000000000IJ000000000000000000!'.!

IJ0U000IJ'_!

IJ!.l

0IJ

124511. 19283H

988113337189829 5 8 2 h397731783114587M2469131659204673159236804100773962934402399081042550806332471314124093942515198367359 U 1 7/ 0 8 i

10341402 3 U•1549 -'9756403091766922560582982359132629

"•' -'646968823894 U 9 6 51673

10445544455444444544444444444454444594444494

. 00

.81

.39

.02

. 00

.98

.95

.53

.26

.22

.92

.82

.90

.73

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.98

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.89

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84938492998387868794Vb

j.

949893919:"909 .-'•-> ••

9 2'-.' :-,'•V V

719696971.1 •;

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, V ,,

U i o n t4r ea Lone Un i t s

^+6 J47)

49 )^ u ;i'/1 )

'; 6 )

';- 9 J6L! )61 ;62 :•

H r o p V 1 b e n z e n eBromobenzene1,3,£-Irime t hy12-Ch lo ro to luene4-Ch lo ro to luenet e r t - Bu t y i b e n z e n e1 ,2 ,4- Ir irne thy 1 bsee-butyibenzenep-lsopropyltoluene1,3-Dichlorobe nrenei , 4 - D i c h I o r o b e n z e n en-Bu ty i u e n zene1/2-Dichlorobe1,2-Dichiorobenzene1 ,2 - D i b r o mo - 3 - c h 1 o r1,2,4-TrichlorobenzHe x a c h 1 o r o b u t a d i e n eNapht hoi ene

benzene

nebenzeneeener e n ezene

z e n e - d 4zeneh 1 o r opropanebenzenei ene

benzene

_•2222• i22• *• .222

U .U .U.U .!J .1 .1 .1.2 .2 .2 .3.

23..222^L

2

3 ."?.7.'

7.

a .

2626c.1617 i4U49H921f "*

'.-•6113237i1?i'-J6

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91 .It'6.1111? .91 .91.119.1U5.lU'j.119.146.146.91 .

l^-ll.146.157.18 U.225.1 2 y .180.

uuuuuuuuuuu0uu!Juu0u

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9286as9Uy/'7"?9498829189948191

99939683

L o ii'i p o u n ci is i b T D

16 18 20 22 24 26

Data F i le : > A O > 6 6 : : 05Name: SDUIA LFBMisc.: LFBGO*

Quant Uutput F i le : '"AU366: : IJi

10UL 21675, 2^ML HUKULD

Id F i le : A1^24W: :F1T i t l e : UOLftTlLE ANALYSIS - nt I HUD '^24. 2 - /UU1ALast Ca l i b ra t i on : V4U706 14:27

Operator ID: LANUuant T ime : 940706 16 : 1>In jected at: 94071)6 i1? : 44

!Jp e i a ': •". i i L1 • LAN. i . - . * ; .. • .'v .'* Ti "i z ^ • . i ••- i r' U >. . - . c • n U - 5 . . - . . _

L''.5 t« ^ : 1 e : ' : f t ! J /6 / : : I.'1

Name : 'JU'.Jr-. .:'! ft'!D'iV':V

Uuari f ! ! V 4 ill/06 13:46•j in MI/, i '.: ^6

1 . IJ U13 0 0

1 _ .

i ,12)3)4)5 )6 )7)8)y )10)11)12)13)14)15 )16 )1 7 )18)19 )20)21)22)23)24)2$)26)27)28)29)30)31)32)33)34)35 )36)37)38)39)40)41)42)43)

! •- " ' ''.."i..";. ' ' !.!L fliiV • ' • • • . - ... r*W ''MM

'.' •;. r-.'i,:. .. . ;

' ! l -wC. : jbenzeneD i c h 1 o r o d i f 1 u o r o me t h .a n eCh 1 or orne thaneUinyl chlorideBromo me thaneCh loroethane

'* T r i c h 1 o r o f 1 u o r o me t h a r: e1 ,1-DichloroetheneDie hloro methane1 ,2-t rans-Dich loroethene1 , 1-Dich ioroethane1 ,2-c is-Uich loroethene .2,2-DichloropropaneCh lor o f ormB r o rno c h 1 o r o me t h a n e1 , 1 , 1 - T r i c h 1 o r o e t h a n e1 . 1 - D i e h 1 o r • o p r o p e n e iCarbon tetrachloride1 f 2 - D i e h loroethaneBenzene1 richloroethene1,2-DichloropropaneD i ch 1 orobromome thaneDibromome thane ,1 ,3-c is-DichloropropeneTo luene1 ,3-t rans-Dich loropropene1 ,1,2- trichloroethane1,3-Dichloropropanelet rach loroetheneChlorodibro mo me thane1,2-Dibromoethane ttUB)Ch lorobenzene1 , 1 , 1 ,2-Tet rach loroethaneEt hy Ibenzenem&p-Xy leneo-Xy leneSt yreneBromo form1,1,2,2-Tetrachloroethane1 sop ropy IbenzeneBromo f luorobenzene1 , 2 , 3 - T r i c h 1 o r o p r o p a n e

•- r- 1 !-" 1

D <-•:•' 4.

;. •_

10.2.2 .2.3.3 .3.4.5 .6.7.8.8 .8.

- 8.9 .9.9.10.10.11.11.12.12.13.14.14.14.15.15.15 .16.17.17.17.17.10.18.19.19.19.19.20 .

n._.»i ;L

'.' _

: .

V v.

42700437518583733316353069974883992931569337445320609U435 792362840446356632769378302

1 ':

U

1

1

1

1

1

i111111111

111

• ' I l l l

10

V6 .85.50 .62 .94.64.01.96.04.96 .63.96.77 .03.30.9 7 .75 .17.62 .78 .30.63.83.74.75 .92 .75 .y / .76 .66.29.07.12.31.06.06.06.04.73.83.05 .74.10.

! i-i

n

o00000000000000000000000000000000000000000u

Area

1260U6. 4004an229 U 22/068386b619599118 175 OM40 076 H2822.-'48 i '• 0655 7 i43219656497932222^36a i u 166945582606236 Oa10595469307284305302821062343537683921876x 5 V 1 022613b 1 0 7 13643U2 2 5 5 88/3i!J3896444683H1255b6H50839720971769115469

168231431353V 45

Lone

10.7 .8.8.8.8 .8.a.9 .9 .9.10.9 .

• 9.10.9.9 .10.10 .9.10.9 .10.11.9.9.9.

1 0 .9 .10.11 .10.11.11.y .21.10.10.11.10.10.11 .11.

0065223791y5125475bO372607863641530910899637078587676yc.4879232660600967159703740077029

Units

LI Q s ' L.LI Q '*' 1 _

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug-'Lug/Lug/Lug/Lug-"Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lu g • Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Luq ' L

qa 7y694yy8071977061849487939983yo36yo92yo76y698**J *}

*j f\

y 394yoyy94yyy 7759767

8378yyy293an40

44;45 )46 )47)48 )49 )50 )51 )52)53 )54)55 )56 )57)58)59 )60)61)62)

Compound

PropyibenzeneB r o rno b e n z e n e1 , 3 , 5 - 1 r i me t h y 1 b e n z e n e2 - Ch 1 o r o t o 1 u e n e4-Ch 1 or o t o 1 uenetert-Butylbenzene1 ,2 , 4 - T r i rue t h y 1 b e n z e n esec-Butylbenzenep- Isopropylto luene1 , 3 - L) i c h lorobenzene1 , 4- L) i c h lorobenzenen-butylbenzenel/2-Dichlorobenzene-d41,2-0 ich lorobenzene1 , 2 - D i b r o mo - 3 - c h I o r o p r o p a ne1 ,2 ,4-1 r ich lorobenzeneHexach lorobutad leneNaph t ha lene

•-, 1 ,2 , 3 - T r ich lorobenzene

K.

2U .20.2 LI .20.20 .21.2 1 .21 .22.22 .22.23 .23 .23 .25.27.27 .2 .-' .2S.

i .

252562626941438919J>3561233381319567333

U 10

91.156.1U5.91.91.

119.105 .105.119.146.146 .91.150 .146.157.180.225 .128.iao .

n

0000000000000000000

Mr ea

2 U I j 4 U 4402

13551049

2127H5111

1244121491120721061599

733

527537

383468232262

1724956354t174M

481552H11M752253

C o n c

9 .11 .10 .9 .10 .10.10 .1U .9 .11.11 .9.11 .11.10.11.11 .9 .

11 .

469308309325111295367557U943105171286V

Ur, x t s

ug/Luq/Lu g / Lug/Lug/Lug/Lug/Lu g / Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

q99! Uy

9 5

8875a a9982

94937b94

iSre97bl

* Compound is 1SIU

TOTflL I OH

90000;

80060-^

-70000--

tocos'

50000^

4RB90.:i

20680;J

10883;

0:

TIC100 260 300 400 500

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i

Data Fi le: >f tU>63: :Ul Uluant Output Fi leName: SUUft SIRNDftHD lUppbHisc: SDWA010 lOuL 2l67«? ,2l6'?4/2l?mL PURULD

Id File: A_524U::F1 iT i t l e : UOLAT1LE RNHLYblS - ntTHUD 524.2 -Last Ca l i b ra t i on : 940^06 14:31

Operator ID: LANQuant Time: 940706 1^:46I n j ec ted at: 9407U6 1^:16

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Continuing Calibration CheckNSl Conpounds

Case No:

Contractor:

Contract Ho:

Instrument 10:


line: 13:16

Laboratory ID: >H0363


tlinimin RF for SPCC is

Conpound RF

flaxinun Z Diff for CCC is 30.0Z

RF XOiff CCC SPCC

DichlorodifluoronethaneChl or one thaneUinyl chlorideBronone thaneChloroethaneIrichlorofluorone thane1,1-flichloroetheneOichloronethane1 ,2-trans-Oichloroethene1,1-Oichloroe thane1 ,2-cis-flichloroethene2,2-OichloropropaneChlorofornBronochloronethane1 ,1 ,1 -Irichloroethane1 ,1-OichloropropeneCarbon tetrachloride1 ,2-OichloroethaneBenzeneIrichloroethene1 ,2-DichloropropaneDichlorobrononethaneDibrononethant1 ,3-cis-DichloropropeneToluene1 ,3-trans-Oichloropropene1,1,2-Irichloroethane1 ,3-OichloropropaneTetrachloroetheneChlorodibrononethane1 ,2-Dibronoethane (EDB)Chlorobenzene

.12732 .32213

.21959 .16061

.25515 .21346

.31250 .30508

.17269 .15156

.79408 .61469

.37016 .31601

.22837 .22260

.38722 .37962

.55167 .51710.33222 .31083.57099 .51771.63111 .62551.17312 .17930.67928 .63890.57161 .51773.61558 .65141.18295 .18617.81527 .83556.19874 .51656.23925 .22120.11511 .11818.11511 .17211.27458 .27091.62680 .60596.17802 .17252.11800 .12553.18075 .17BJ3.58549 .63933.25387 .28729.16689 .17789.62253 .68853

24.3517.7516.3410.9310.5018.8114.622.531.966.272.59

"9.331.403.575.954.68.91

1.761.159.596.29.67

18.541.343.333.096.391.349.20

13.176.59

10.60

RF - Response Factor fron daily standard file at 10.00 ug/L

RF - Average Response Factor fron Initial Calibration Forn UI

XOiff - I Difference fron original average or curve

CCC - Calibration Check Conpounds (») SPCC - Svsten Perfornance Check Conpounds <«*)

Continuing Calibration CheckHSL Compounds

Case No:

Contractor:

Contract No:

Instrunent ID:


line: 13:16

laboratory 10: >R0363


Hin«wi Of for SPCC is

Conpound

flaxiiw Z Diff for CCC is 30.01

RF RF ZDiff CCC SPCC

1,1,1,2-TetrachloroethaneCthylbenzenenlp-Xyleneo-XyleneStyreneBronoforn1,1.2,2-letrachloroethweIsopropylbenzeneBronofluorobenzene1 ,2,3-IrichloropropanePropylbenzeneBronobenzene1 ,3,5-Irinethvlbenzene2-Chlorotoluene1-Chlorotoluenetert-Butylbenzene1 ,2,1-Trinethylbenzenesec-Butylbenzene 'p-Isopropyltoluene1 ,3-Oichlorobenzene1 ,Hichlorobenzenen-Butylbenzenc1 ,2-Oichlorobenzene-d11 ,2-Dichlorobenzene1 ,2-Oibrono*3-chloropropane1 ,2,1-IrichlorobtnzeneHeuchlorobutadieneNaphthalene1 ,2,3-Trichlorobenzenetert-Butyl wethyl ether (KIBD

.27931

.35347

.15608

.37816

.53710

.12276

.117271.31728.29076.02755

1.67132.26576

1.06009.889(1.89801

t. 11722.91151

1.611561.26759.52131.19260

1.30529.37523.37062.02119.26211.31567.19737.17710

-

.30727.35237.19519.10092.57187.13951.12199

1.32668.31017.03111

1.58010.31719

1.06877.82765.98112

1.17595.95201

1.661551.26118.59582.57863

1.21881.1)597.123(0.02170.30212.36966.18313.20703

-

10.01.37

8.575.936.97

13.651.03.71

14.9912.92S.i1

'19.35.82

6.979.262.501.111.22.18

13.6317.16

1.3310.8611.291.00

15.1317.10

7.2116.90-

(Cone-20.00)

(Conc'10.00)

(Conc'10.00)

RF - Response Factor fron daily standard file at lO.OOug/L

RF - Rverage Response Factor fron Initial Calibration Forn UI

ZDiff - Z Difference fron original average or curve

CCC - Calibration Check Compounds <«> SPCC - Systen Perfomance Check Conpounds (»)

Fnr« (IT! Panp ? nf 7

8AVOLATILE INTERNAL STANDARD AREA SUMMARY

Lab Name: NET MIDWEST-BARTLETT

Lab code: Case No.:

Lab File ID (Standard): >A03B3

Instrument ID: 700IA

Contract:

SAS No.: SDG No.:


Tine Analyzed: 13:16

Matnx:(soil/uater ) WATER Level:(lou/med ) LOU Column: ( pack/cap ) CAP

1t

1

! 12 HOUR STD

! UPPER LIMIT

! LOWER LIMIT

! EPA SAMPLEi NO.!====*==»====

1 ISDWA BLANK21SDWA LFB3!BTt2658594!BT*2658605!BT*2664156!BTt2670757!BTt2673388 IBTt 2673399!BT*26734010!BT*265859DP11 !BT*265860DP12!13!14!15!16!17!18!19!20!21 !22!

ISKFB )AREA t

126806

164848

88764

i f-

123173.12451 11225841193231225851 191781 190271 14603128002124422122033

RT

10.75

1 1 .25

10.25

10.7910.7710.7910.7910.7910.7910.7910.8010.7910.8010.77

IS2( )AREA t

0

0

0

RT

0.00

0.00

0.00

IS3( )AREA t

0

0

0

RT

0.00

0.00

0.00

151 (FB > = Fluorobenzene152 ( ) = d12-Perylene153 < ) = LOWER LIMIT = - 707.

UPPER LIMIT «= + 657.of internal standard area,

of internal standard area.

t Column used to flag internal standard area values with an asterisk

RAW DATAMS VOLATBLES

era/Ietters/covcr.msvoIraw

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V4 0,--' U 6 18:41V4U/U6 la: 1U

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Compound R. V . U ior, !Jor-c Ur, i t s

1 .' * f 1 u o r o b e n z e n e'..' - ! r : ch i •:• r •:•<? t henet _ / b i o mo f 1 u o r o b e n z e n e

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Data I- i le: >H037U: :D3Name: BT#26707'->Misc: tCULUbY 10UL

Uuant Output r i l e

PURULD

Id K i le: H1524W: :K1 Il i t l e : UOLHT1LE ANALYSIS - METHOD 324.2Last Calibration: 940706 14:27

Operator ID: LANQuant lime: 940706 18:41Injected at: 940706 18:11)

Ti le >fi?S.'t. Fluorobenzene S-: an i9c-T.« 1 . «-it_ *?*• ft t- K L« I 107 SUB 10.98 mir..

J

;c. c! ,„ 70 1

39 5tf , ^C1 v. 75 0

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SOWPI. F SPFCTRUM rppr:KGROUNTi SUTiTRRCTFTllr i 1 o ->00"570 pT^-^yg^c Sc=tr;Bok fib 12937 SUB 10.79

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SOKPLE SPECTRUM (UHflLTERED)File >F)0370 BT«26787S ScanBpk fib 12937 18.79

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ca 51 63 70 ,r |J/ </ \ "I '/ ^ 1

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Data Kile: >AU37U::D5 • Uuant Output h i l e : ">ftU370::UI"Name: BT#267075Misc: ECOCOSY 1UUC 2167^?, 2bHC POKLitUUuant lime: 94U7U6 lb|:41 Uuant 1U File: ftlb24W::F"iInjected at: 94U7U6 Id: it) Cast Calibration: 940706 14:27

Compound No: 1 (.IS ID)Compound Name: FluorobenzeneScan Number: 374Re tention T i me : 1U . 79 mm.Uuant Ion: 96.0ftrea: 119178Concentration: 1U.UO ug/Cq-âlue: U9

R E F E P! £ N Li c S 7 M N C i-i R C 3 r E C T P ! j nf i i & >H~8~i T r i c h i o roe then e ScanUp!- Sb l^ l f f -J «;!; J

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Data h i le :Name:Ilisc: ECULUGYQuant T i m e : V407LI6 la: 41I n j e c t e d at: 940/116 18:10

Uuant Uutput K i l e : "ttU^/U : : U

1UUL 216>"?, 2^HL PUKUbD

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ENVIRONMENTAL PROTECTION AGENCYOffice of Enforcement

CHAIN OP CUSTODY RECORD

REGIONS77 West Jackson Boulevard

Chicago. Illinois 60604PROJ. NO. PROJECT NAME

- 0/fSAMPLERS: (Print Name and Sign)

STA. NO. DATE TIMECD

2o•f 1V7 STATION LOCATION

NO.

OF

CON-TAINERS f

Activity Code:

TAG NUMBERS

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Relinquished by: (Signature)


Date / Time

Date /Time

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Ship To:

ATTN:Relinquished by: (Signature) Date / Time Received for Laboratory by:

(Signature) / y

Sfe

Date / Time Airbill Number

Chain of Custody Seal NumbersDistribution: White - Accompantee Shipment; Pink - Coordinator Raid Files; Yellow - Laboratory File

m Rpcvr/ed Paoer/Printed with Soy-Based Ink


CHAIN OF CUSTODY RECORDPROJ. NO. PROJECT NAME

SAMPLERS: (Print Name and Sign)

STA. NO. DATE TIMECD

STATION LOCATION

NO.

OF

CON-TAINERS

TAG NUMBERS

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Date / Time

Date / Time

ReceivecLby: (Signature)

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Ship To:


(Signature)Date / Time Airbill Number

Chain of Custody Seal NumbersDistribution: White - Accompanies Shipment; Pink - Coordinate '«ld Files; Yellow - Laboratory File


CHAIN OF CUSTODY RECORD


Chicago, Illinois 60604PROJ. NO. PROJECT NAME


STA. NO. DATE TIME0

STATION LOCATION

NO. ,

OF

CON-TAINERS

Code:

TAG NUMBERSIX

Relinquished by: (Signature


Date / Time

Date / Time


ReceiviM by: (Signature)

Ship To:


(Signature)Date / Time Airbill Number

Chain of Custody Seal NumbersDistribution: White- Accompanies Shipment; Pink - Coordinator Field FHesTYellow - Laboratory Fite

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REGION 577 West Jackson Boulevard

Chicago. Hllnols 60604PROJ. NO.

7PROJECT NAME

SAMPLERS: (Print Name and S/|

STA. NO. DATE TIME(ISTATION LOCATION

NO.

OF

CON-TAINERS

Activity Code:

TAG NUMBERS

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Date / Time

'/i/1Date / Time



Ship To:


(Signature)

Distribution: White - Accompanies Sfiipment; Rnk-Coorr iles;

Date / Time Airbill Number

Yellow - LaboratoryTileChain of Custody Seal Numbers




Chicago. Illinois 60604ihlcago. IlllrActivityPROJ. NO. PROJECT NAME


STA. NO. DATE TIMEO

STATION LOCATION

NO.

OF

CON-TAINERS

Code:

TAG NUMBERS

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: vMvA -Relinquished by: (Signature)


Date /Time

/ Time

Received by: (Signature) //


Ship To:

ATTN:Relinquished by: (Signature) Date / Time Received for Laboratory by: Date / Time Airbill Number

Chain of Custody Seal NumbersîDistribution: White - Accompanies Shipment; Pink - Coordinator Field Fries; YeHovr- Laboratory FUe

Printed on Recycled Paper/Printed with Soy-Based Ink 5-4083?



REGION 6 ,230 South Dearborn StrMt

Chicago. Illinois 60604PROJ. NO. PROJECT NAME

SAMPLERS: (Sigmturt)

STA. NO. DATE TIME STATION LOCATION

NO.

OF

CON-TAINERS

REMARKS

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Relinquished by: (Signtture) Date/Time Received by: (SigntwriJ .., Relinquished by: Date /Time Received by:

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Relinquished by: (Signature) Date /Time Received for Laboratory by:«*"W/ ./' ..

Date /Time Remarks

Distribution: White — Accompanies Shipment; Pink — Coordi \ Field Files; Yellow — Laboratory File



REGION 6 ,230 South ,D««rbom Stract

Chic«ao. Illinois 60604PROJ.NO. PROJECT NAME

SAMPLERS: (Signttunl

\ :*STA. NO. DATE TIME STATION LOCATION

NO.

OF

CON-TAINERS

REMARKS

4

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Relinquished by: ISignaturt) Date/Time Received by:i

Relinquished by: (Si Date/Time Received by:

Relinquished by: ISigntwre) Date /Time Received by: (Signtturt) / Relinquished by: fS/gntturti Date/Time Received by:

Relinquished by: (Signtturti Date/Time Received for Laboratory by:fSigntturt) /' -

Date /Time

r:~;~y

Remarks

Distribution: White — Accompanies Shipment; Pink — Coord! } Field Files; Yellow — Laboratory File

Documents

NATIONAL ENVIRONMENTAL TESTING INC - SAMPLING ...NET NATIONAL ENVIRONMENTAL i® TESTING, INC. CASE NARRATIVE Ms. Mary Jane Ripp ECOLOGY & ENVIRONMENT, INC 111 West Jackson Blvd. Chicago,