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OLLI IKKALA academy professor
Department of Applied Physics,
Aalto University School of Science (formerly Helsinki University of Technology),
FIN- 00076 Aalto, Espoo, Finland,
Nanocelluloses for Templates for Functional Matter
Self-assemblies and biomimetics
Congratulations!
Forest industry has a jewel of materials at hand: ”Sustainable steel”
Cellulose I crystal
• Native cellulose I crystal modification • Parallel hydrogen bonded chains
• Modulus ca. 130-150 GPa • Iwamoto, Kai, Isogai, Iwata, Biomacromolecules 2009 10 2571
• Strength in the 2-6 GPa range • Saito, Kuramae, Wohlert, Berglund, Isogai, Biomacromolecules 2013, 14, 248
• Very good mechanical properties ! • cf Kevlar, steel
Inspires to take a new perspective as a materials/polymer engineer
Content Types of nanocellulose
Rånby, Discuss. Faraday Soc. 1951, 11, 158 Revol, Giasson, Marchessault, Gray, Int. J. Biol. Macromol. 1992, 14, 170 Fleming,Gray, Matthews, Chem. Eur. J. 2001, 7, 1831
Turbak, Snyder, Sandberg, J. Appl. Polym. Sci. Polym. Symp. 1983, 37, 815 Pääkkö, Ankerfors, Kosonen, Nykänen, Ahola,Österberg, Ruokolainen, Laine, Larsson, Ikkala, Lindström, Biomacromolecules 2007, 8, 1934 Henriksson, Henriksson, Berglund, Lindström, Eur. Polym. J. 2007, 43, 3434
Zimmermann, Adv Eng Mat 2004 6754
Cellulose nanocrystals
Nanofibrillated cellulose Bacterial cellulose
Tunicates
Nanofibrillated cellulose forms strong gels
Cellulose nanofibrils form strong gels in water
Photograph: M Ankerfors, T Lindström/STFI
• Strong gels • Still flow easily
• Classic applications • Oil recovery, paints, concrete, etc
• Advanced applications • Biomedicine, stem cell growth • Injectable
Pääkkö, Ankerfors, Kosonen, Nykänen, Ahola, Österberg, Ruokolainen, Laine, Larsson, Ikkala, Lindström, Biomacromolecules 2007 8, 1934 Bhattacharya, Malinen, Lauren, Lou, Kuisma, Kanninen, Lille, Corlu, GuGuen-Guillouzo, Ikkala, Laukkanen, Urtti, Yliperttula, J Contr Rel, 164 291 2012
Ultralightweight porous materials by drying
Aerogels
The nanocellulose aerogels are mechanically robust
Pääkkö, Silvennoinen, Vapaavuori, Nykänen, Ankerfors, Kosonen, Ruokolainen, Lindström, Berglund, Ikkala, Soft Matter, 2008, 4, 2492
• Flexible ductile materials • Unlike classic aerogels which are
brittle
Functionalized nanocellulose
aerogels
Magnetic actuating nanocellulose aerogels
Olsson, Azizi Samir, Salazar-Alvarez, Belova, Ström, Berglund, Ikkala, Nogués, Gedde, Nature Nanotech, 5, 584 (2010).
Combine the best of two worlds: Nanocellulose and Carbon nanotubes
Modulus 140 GPa Strength GPa´s Sustainable
Modulus 1000 GPa Strength 30-60 GPa Electrical
Sensing movement"
Wang, Anoshkin, Nasibulin, Korhonen, Seitsonen, Pere, Kauppinen, Ras, Ikkala, Adv Mat 2013
Titanium dioxide functionalization of nanocellulose
Semiconductor
Titanium dioxide coated nanocellulose aerogel
Kettunen (née Pääkkö), Silvennoinen, Houbenov, Nykänen, Ruokolainen, Sainio, Pore, Kemell, Ankerfors, Lindström, Ritala,. Ras, Ikkala, Adv Funct Mat 2011, 21 510
Nanometer thick coatings
Atomic layer deposition/chemical vapour deposition
Burn nanocellulose for hollow oxide nanofibers
Korhonen, Hiekkataipale, Malm, Karppinen, Ikkala, Ras, ACS Nano, 2011 , 5, 1967
Sensors, devices, as oxides are semiconductors
• Absorb oil
• Repel water
• Float on water
Korhonen, Kettunen, Ras, Ikkala, ACS Applied Mat and Interf, 3, 1813 (2011).
Titanium dioxide-coated nanocellulose aerogels for oil-spills
Extremely water repellant materials
• Spray-dried nanofibrillated cellulose • Leads to surface patterns • Coat with fluorinated surfactant • Lotus-like superhydrophobic surface • Water rolls off, dirt repellent, like lotus
Mertaniemi, Laukkanen, Teirfolk, Ikkala, Ras, RSC Advances, 2, 2882, (2012). .
Extremely water repellent surfaces using nanocellulose
Lotus
• Classic applications of superhydrophobicity • Dirt repellency, self-cleaning antifogging, anti-icing, etc
• We have shown recently unforeseen new options • Water based logic circuits (Advanced Materials 2012) • Water based displays (Proc National Acad Sciences 2012) • Droplet oscillators (Nature Communications 2013) • Dynamic on surfaces (Science 2013)
• They may lead new microfluidic devices
Future of extreme water repellancy
Functionalization of cellulose nanocrystals
Polymer coatings on cellulose nanocrystals: Tuning the properties
Majoinen, Walther, McKee, Kontturi, Aseyev, Malho, Ruokolainen, Ikkala, Biomacromolecules, 12, 2997, 2011
Well defined polymerization on cellulose nanocrystals: only recently identified Modular approaches demonstrated: relevant for applications
Electron microscopy
Filpponen, Kontturi, Nummelin, Rosilo, Kolehmainen, Ikkala, Laine, Biomacromolecules, 13, 736, 2012
Coating resolved !
Strong composites
Mimicking pearl of nacre
Learning from Nature for nanocomposites
Laaksonen, Walther, Malho, Kainlauri, Ikkala, Linder, Angew Chem 2011 50 8688
Chitin nanofibers
Wu, Saito, Fujisawa, Fukuzumi, Isogai, Biomacromolecules 2012, 13, 1927
Pearl of nacre combines strength, stiffness, and toughness in a way that is difficult to achieve with manmade materials
Calcium carbonate nanosheets
Nanofibrillated cellulose/graphene
Protein glue
Nanofibrillated cellulose/nanoclay
Nanoclay content
Combine nanofibrillated cellulose and nanosheets
Strong macroscopic fibers based on native nanocellulose nanofibers
Iwamoto, Isogai, Iwata, Biomacromolecules, 2011, 12 831 Walther, Timonen , Díez, Laukkanen , Ikkala , Adv Mat, 2011, 23, 2924
Macroscopic fibers of nanocellulose
• Excellent mechanical properties • Can be functionalized
• Electrically conducting • Magnetic • Drug release • Patterned
Summary"
• The paper industry has at hand nanocellulose • Strong, functionalizable, sustainable
• Totally new applications are at hand beyond the classic paper/cardboard “Next generation nanomaterial”
• Need new expertizes, polymer chemistry, supramolecular chemistry, soft electronics, materials science, biology, analytical chemistry, materials physics, pharmacy,
• Special high tech applications, new application connections • Materials that are tough, strong, and stiff • Various functionalizations
Specific challenge: Make tough! Solutions are now at hand!
Cracks propagate in a stable manner!
Funding acknowledgement
Finnish Center for Nanocellulose Technologies, UPM, Academy of Finland, TEKES Sustaincomp/EU NMP Designcell/Woodwisdom ERC Advanced Grant Center of Excellency (Ikkala, Laine, Linder, Penttila Aalto/VTT collaboration)