Nalco -1800 -Corrosion Inhibitor

7/24/2019 Nalco -1800 -Corrosion Inhibitor

1/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800

EMERGENCY TELEPHONE NUMBER(S)See section 16, for Emergency Telephone Numbers.

NALCO EUROPE B.V.Postbus 627 2300 AP LeidenThe Netherlands 0031 71 5241100For additional copies of an MSDS visit www.nalco.com and request access

1 / 15

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKING

PRODUCT NAME : Tri-ACT 1800

APPLICATION : BOILER STEAM CONDENSATE TREATMENT

COMPANY IDENTIFICATION : NALCO EUROPE B.V.Postbus 6272300 AP Leiden, The Netherlands

EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.

Date issued : 06.10.2010Version Number : 5.0

COMPANY CONTACT TELEPHONE NUMBERS.NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00NALCO AB (SE) +46 (0)31-707 22 70 Distributor Nalco Mobotec Polska

Sp. z o.o.PRZEMYS OWA 55PL-43-110 TYCHYTEL:+48 (0)32-3262750FAX:+48(0)32 329 13 11e-mail: [email protected]

NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P) +351 214121852NALCO APPLIED SERVICESOF EUROPE BV

+31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325

NALCO BELGIUM BVBA +32 (0)3-450 69 10 Nalco Switzerland AG (CH) +41 (0)52 235 38 38NALCO DANMARK ApS +45-48195800 Nalco Company OOO +7 (0)495 980 72 80NALCO DEUTSCHLAND GmbH(D)

+49 (0)69-79340 NALCO STERREICHGes.m.b.H. (A)

+ 43(0)1 27026350

NALCO ESPAOLA S.L. (E) +34 93-4095555 First Distributor: Nalco Czechias.r.o. (CZ)

Hlavn 1222/60,141 00 Praha4,Czech Republic,+420 267 912350 & +420 272 913 512

NALCO FINLAND OY (FI) +358 (0)9 2519 5600 Local Support: Nalco Hungary Kft.(HU)

+36 1 8805610

NALCO FRANCE SAS +33 (0)3 20 11 70 00 Local Support: Nalco sterreichGes.m.b.H., Representation OfficePredstavnistvo Zagreb (HR)

+385 (0)1 377 95 21

NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco sterreichGes.m.b.H. Representation OfficeROMANIA (RO)

+40 (0) 21 224 17 93

NALCO ITALIANA S.R.L.(I) +39 06-54565000 NALCO LIMITED +44 (0)1606 74488NALCO NETHERLANDS B.V. +31 (0)13-5952200

For Product Safety information please contact Jacqueline Dudley, e-mail [email protected]

2. HAZARDS IDENTIFICATION

HAZARD CLASSIFICATION :

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Causes burns. May cause sensitization by skin contact. Harmful in contact with skin and if swallowed. Possiblerisk of impaired fertility.

HUMAN HEALTH HAZARDS - ACUTE :


2/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



2 / 15

INHALATION :Irritating, in high concentrations, to the eyes, nose, throat and lungs. Vapors may have a strong offensive odorwhich may cause sensory response including headache, nausea and vomiting.

SKIN CONTACT :May cause severe irritation or tissue damage depending on the length of exposure and the type of first aidadministered. Harmful if absorbed through skin. May cause sensitization by skin contact.

EYE CONTACT :Corrosive. Will cause eye burns and permanent tissue damage. Exposure to low vapor concentrations can resultin foggy or blurred vision, objects appearing bluish and appearance of a halo around lights. These symptoms aretemporary.

INGESTION :Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. Harmful ifswallowed.

HUMAN HEALTH HAZARDS - CHRONIC :Possible risk of impaired fertility.

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Hazardous Substance(s) EINECS /ELINCS NO

CAS NO SYMBOL R-PHRASES /NOTAS

% (w/w)

Cyclohexylamine 203-629-0 108-91-8 C R10, R21/22,R34, R62

5 - < 10

Monoethanolamine 205-483-3 141-43-5 C R20/21/22, R34 10 - < 20Methoxypropylamine 226-241-3 5332-73-0 C R10, R22, R35,

R43, R5210 - < 20

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

4. FIRST AID MEASURES

INHALATION :Remove to fresh air, treat symptomatically. Get medical attention.

SKIN CONTACT :

Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower.Remove contaminated clothing. Wash off affected area immediately with plenty of water. Get immediate medicalattention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

EYE CONTACT :PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15minutes while holding eyelids open. Get immediate medical attention.

INGESTION :DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get immediate medicalattention.

NOTE TO PHYSICIAN :


3/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



3 / 15

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of thepatient, the physician's judgement should be used to control symptoms and clinical condition.

5. FIRE FIGHTING MEASURES

FLASH POINT : 57 C PMCC

EXTINGUISHING MEDIA :Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use waterspray or fog, thoroughly drenching the burning material.Water mist may be used to cool closed containers.

FIRE AND EXPLOSION HAZARD :

Flammable Liquid; may release vapors that form flammable mixtures at or above the flash point. May evolveoxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. Emptyproduct containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flameor other sources of ignition.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS :Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment

recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so.Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnelonly. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available.Notify appropriate government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP :SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeledcontainer. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches orby diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaceswith water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recoveredmaterial. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS :

Do not contaminate surface water.

7. HANDLING AND STORAGE

HANDLING :Do not get in eyes, on skin, on clothing. Do not take internally. Do not breathe vapors/gases/dust. Use withadequate ventilation. Avoid generating aerosols and mists. Keep away from acids and oxidizing agents. Do notuse, store, spill or pour near heat, sparks or open flame. Keep the containers closed when not in use. Haveemergency equipment (for fires, spills, leaks, etc.) readily available.

STORAGE CONDITIONS :Store the containers tightly closed. Store away from heat and sources of ignition. Use proper groundingprocedures. Store separately from acids. Store separately from oxidizers. Amine and sulphite products should

not be stored within close proximity or resulting vapors may form visible airborne particles.


4/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



4 / 15

SUITABLE CONSTRUCTION MATERIAL :HDPE (high density polyethylene), Natural rubber, Polypropylene, Stainless Steel 304, Stainless Steel 316L,Surface-modified HDPE (high density polyethylene), PTFE, Perfluoroelastomer, Fluoroelastomer, Compatibilitywith Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.

UNSUITABLE CONSTRUCTION MATERIAL :Carbon Steel C1018, Epoxyresin coating

SPECIFIC USE(S) :BOILER STEAM CONDENSATE TREATMENT

For specific dosages and customized applications please contact your representative.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) areshown below.

Country/Source Substance(s) Category: ppm mg/m3AUSTRIA Cyclohexylamine MAK 10 40

MAK CEIL 10 40Skin*

Monoethanolamine MAK 1 2.5MAK STEL 3 7.6Skin*

BELGIUM Cyclohexylamine TWA 10 42

Monoethanolamine TWA 1 2.5STEL 3 7.6Skin*

BULGARIA Cyclohexylamine TWA 20

Monoethanolamine TWA 8STEL 15

DENMARK Cyclohexylamine GV 10 40Skin*GV 10Skin*

Monoethanolamine GV 1 2.5Skin*GV 1Skin*

FINLAND Cyclohexylamine HTP 8H 1 4.1HTP 15MIN 10 41Skin*

Monoethanolamine HTP 8H 1 2.5HTP 15MIN 3 7.6Skin*

FRANCE Cyclohexylamine VME 10 40

Skin*


5/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



5 / 15

Monoethanolamine VME 1 2.5

VLE 3 7.6Skin*

GERMANY Cyclohexylamine MAK 2 8.2

Monoethanolamine AGW 2 5.1Skin*

IRELAND Cyclohexylamine TWA 10 40Skin*

Monoethanolamine TWA 3 8STEL 6 15

ITALY Monoethanolamine TWA 1 2.5STEL 3 7.6

Skin*

NETHERLANDS Monoethanolamine TGG 2.5TGG 15 7.6Skin*

NORWAY Cyclohexylamine ADM. NORM 10 40Skin*

Monoethanolamine ADM. NORM 3 8ADM. NORM 1 2.5Skin*

SPAIN Cyclohexylamine VLA-ED 10 41

Monoethanolamine VLA-ED 1 2.5

VLA-EC 3 7.5Skin*

SWEDEN Cyclohexylamine NGV 5 20KTV 10 40

Monoethanolamine NGV 3 8KTV 6 15Skin*

SWITZERLAND Cyclohexylamine TWA 2 8.2STEL 4 16.4Skin*

Monoethanolamine TWA 2 5STEL 4 10

UNITED KINGDOM Cyclohexylamine TWA 10 41


POLAND Cyclohexylamine MAC-NDS 40MAC-NDSCh

80

Monoethanolamine MAC-NDS 2.5MAC-NDSCh

7.5

HUNGARY Cyclohexylamine K 40

CK 40


6/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



6 / 15

Monoethanolamine K 2.5

CK 7.6Skin*

LATVIA Cyclohexylamine TWA 1

Monoethanolamine TWA 0.5

CZECH REPUBLIC Cyclohexylamine PEL 20NPK-P 40Skin*

Monoethanolamine PEL 2.5NPK-P 7.5Skin*

CROATIA Cyclohexylamine GVI 10 41

Monoethanolamine GVI 1 2.5KGVI 3 7.6Skin*

ROMANIA Cyclohexylamine TWA 5 20STEL 10 40


RUSSIANFEDERATION

Cyclohexylamine (Vapour.) CEIL 1

Monoethanolamine (Vapor and aerosol.) CEIL 0.5

SERBIA Cyclohexylamine MAC 10 40Skin*

Monoethanolamine MAC 3 8Skin*

SLOVAKIA Cyclohexylamine TWA 2 8.2CEILING 16.4

Monoethanolamine TWA 1 2.5CEILING 7.6Skin*

SLOVENIA Cyclohexylamine TWA 10 41STEL MULT

Skin*

Monoethanolamine STEL MULTSkin*TWA 1 2.5

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes andthe eyes.

MONITORING MEASURES :A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbedor removed and analyzed as referenced below:Substance(s) Method Analysis AbsorbantCyclohexylamine US NIOSH: 2010 Gas chromatography Silica gel


7/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



7 / 15

Monoethanolamine US NIOSH: 2007 Gas chromatography Silica gel

Methoxypropylamine No method identified

ENGINEERING MEASURES :General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor.

PERSONAL PROTECTION

GENERAL ADVICE :The use and choice of personal protection equipment is related to the hazard of the product, the workplace and theway the product is handled. In general, we recommend as a minimum precaution that safety glasses withside-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an areawhere this product is handled should at least wear safety glasses with side-shields. The applicable Europeanstandard can be found in EN 166.

RESPIRATORY PROTECTION :Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or airsupplied breathing apparatus is recommended. A suitable filter material depends on the amount and type ofchemicals being handled. The applicable European standard can be found in EN 140, EN 137, EN 143 and EN14387. Consider the use of filter type: AX-P In event of emergency or planned entry into unknown concentrations

a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a completerespiratory protection program including selection, fit testing, training, maintenance and inspection.

HAND PROTECTION :When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends onwork conditions and what chemicals are handled, but we have positive experience under light handling conditionsusing gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed.Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standardcan be found in EN 374.

SKIN PROTECTION :When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicableEuropean standard can be found in EN 14605 and EN ISO 20345.

EYE PROTECTION :Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.

HYGIENE RECOMMENDATIONS :Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep asafety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handlingthis product never eat, drink or smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid


8/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



8 / 15

APPEARANCE Light yellow

ODOR Amine

FLASH POINT : 57 C PMCCSPECIFIC GRAVITY 0.99 (25 C) ASTM D-1298SOLUBILITY IN WATER CompletepH (100 %) 12.8VISCOSITY 5 cps (25 C) ASTM D-2983MELTING POINT -13.33 C ASTM D-1177

Note: These physical properties are typical values for this product and are subject to change.

10. STABILITY AND REACTIVITY

STABILITY :Stable under normal conditions.

HAZARDOUS POLYMERIZATION :Hazardous polymerization will not occur.

CONDITIONS TO AVOID :Heat and sources of ignition including static discharges.

MATERIALS TO AVOID :

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,permanganate) may generate heat, fires, explosions and/or toxic vapors., Strong acids, Contact with strong acids(e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxicvapors., Avoid contact with SO2 or acidic bisulfite products, which may react to form visible airborne amine saltparticles.

HAZARDOUS DECOMPOSITION PRODUCTS :Under fire conditions: Oxides of carbon, Oxides of nitrogen

11. TOXICOLOGICAL INFORMATION

The following results are for the product. The following results are for the hazardous components.

ACUTE ORAL TOXICITY :Species: RatLD50: 1,267 mg/kgTest Descriptor: Product

ACUTE DERMAL TOXICITY :Species: RabbitLD50: 400 - 2,000 mg/kgTest Descriptor: Hazardous component Monoethanolamine

Species: Rabbit

LD50: > 2,000 mg/kgTest Descriptor: Product


9/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



9 / 15

ACUTE INHALATION TOXICITY :Species: RatLC50: 8000 PPM (4 hrs)Test Descriptor: Hazardous component Cyclohexylamine

PRIMARY SKIN IRRITATION :Species: RabbitDraize Score: /8.0Test Descriptor: Similar Product

Remarks: Causes burns.

PRIMARY EYE IRRITATION :Remarks: Causes burns.

SENSITIZATION :Methoxypropylamine is reported to cause skin sensitization in guinea pigs.

CARCINOGENICITY :Possible risk of impaired fertility.

For additional information on the hazard of the preparation, please consult section 2 and 12.

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS :

The following results are for the product.

ACUTE FISH RESULTS :Species Exposure LC50 NOEC Method Test DescriptorRainbow Trout 96 hrs 200 mg/l 150 mg/l ProductFathead Minnow 96 hrs 194 mg/l 150 mg/l ProductInland Silverside 96 hrs 1,464.3 mg/l Product

ACUTE INVERTEBRATE RESULTS :Species Exposure LC50 EC50 Method Test DescriptorDaphnia magna 48 hrs 326 mg/l 250 - 400

mg/lProduct

Mysid Shrimp(Mysidopsis bahia)

96 hrs 614.0 mg/l Product

PERSISTENCY AND DEGRADATION :

Chemical Oxygen Demand (COD) : 524,000 mg/l


10/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



10 / 15

Biological Oxygen Demand (BOD) :Incubation Period Value Method Test Descriptor

6,400 mg/g Product

The organic portion of this preparation is expected to be readily biodegradable.

BIOACCUMULATION POTENTIALThis preparation or material is not expected to bioaccumulate.

13. DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste

Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.

This product is ashless and can be burned directly in appropriate equipment. Dispose of wastes in an approvedincinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose ofwastes in local sewer or with normal garbage. This product is NOT suitable for disposal by either landfill or viamunicipal sewers, drains, natural streams or rivers.

Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensedcontractor.

EUROPE WASTE CODE :16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangeroussubstances. If this product is used in any further processes, the final user must redefine and assign the most

appropriate European Waste Catalogue Code.

NATIONAL REGULATIONS AUSTRIA :Waste Code :55352

NATIONAL REGULATIONS CZECH REPUBLICValid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No.477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. 381/2001Coll.), as amended

NATIONAL REGULATIONS POLAND :Waste Code: Regulations of 27 September 2001, Waste catalogue, J. of Laws No. 112, item 1206.Act of 22 January 2010 amending the Act on waste and certain other acts (J.oL. no. 28, item 145.)Directive 2006/12/EC of the European Parliament and of the Council of 5 April 2006 on waste.91/689/EEC Council Directive of 12 December 1991 on hazardous waste.94/62/EC Directive of the European Parliament and of the Council of 20 December 1994 on packaging andpackaging waste.Do not dispose into a local sewage system or with normal household waste. Do not dispose into municipal drains,sewers, soil, natural streams or rivers. The waste product should be disposed of at an authorised incineration plantor a waste treatment/disposal plant in line with the existing regulations (Act of 27 April 2001 on Waste,consolidated text annexed to the J. of Laws No. 39, item 251 of 2007). The product incineration produces ash. Theproduct may be incinerated directly using suitable equipment.Reclamation, recycling and disposal of packaging waste should comply with the existing regulations (Act of 11 May2001 on Packaging and Packaging Waste, J. of Laws No. 63, item 638, as amended).Use the services of appropriately authorised businesses.Decree about waste of 27.04.2001 (DZ.U nr.62 item 628 with later changes Dz U 2003, nr 7 item 78


11/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



11 / 15

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORTProper Shipping Name : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.Technical Name(s) : Methoxypropylamine, CyclohexylamineUN/ID No : UN 2734Hazard Class - Primary : 8Hazard Class - Secondary : 3Packing Group : II

ADR/RID H.I.n. : 83CLASSIFICATION CODE : CF1

AIR TRANSPORT (ICAO/IATA)Proper Shipping Name : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.Technical Name(s) : Methoxypropylamine, CyclohexylamineUN/ID No : UN 2734Hazard Class - Primary : 8Hazard Class - Secondary : 3Packing Group : IIIATA Cargo Packing Instructions : 812IATA Cargo Aircraft Limit : 30 L (Max net quantity per package)IATA Passenger Packing Instructions : Y808 / 808

IATA Passenger Aircraft Limit : 0.5 L / 1 L

MARINE TRANSPORT (IMDG/IMO)Proper Shipping Name : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.Technical Name(s) : Methoxypropylamine, CyclohexylamineUN/ID No : UN 2734Hazard Class - Primary : 8Hazard Class - Secondary : 3Packing Group : II

OTHER APPLICABLE INFORMATIONCEFIC TREMCARD REFERENCE : 80GCF1-IIEMERGENCY ACTION CODE : 2W

15. REGULATORY INFORMATION

CLASSIFICATION AND LABELLING :

GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous PreparationsDirective 1999/45/EC.

HAZARD SYMBOLS


12/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



12 / 15

CORROSIVE

Contains:..Methoxypropylamine Cyclohexylamine Monoethanolamine

RISK PHRASESR34 - Causes burns.

R43 - May cause sensitization by skin contact.R21/22 - Harmful in contact with skin and if swallowed.R62 - Possible risk of impaired fertility.

SAFETY PHRASESS24/25 - Avoid contact with skin and eyes.S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

NATIONAL REGULATIONS CZECH REPUBLICThis preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. 356/2003 Coll.)

This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and per Act 371/2008 Coll.Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No.178/2001 Coll. laying down conditions of health protection of employees at work

NATIONAL REGULATIONS FRANCETable of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s):49, 49 bisSpecial medical supervision - Decree of 11 July 1977: Relevant.Classified Industrial Sites (ICPE): Relevant. Headings: 1432B

NATIONAL REGULATIONS GERMANY

WGK 1 (Annex 4)

NATIONAL REGULATIONS HOLLANDABM RESULTABM RESULT Substance(s) % (w/w)9 B

NATIONAL REGULATIONS HUNGARYRelevant and applicable Hungarian legislation on protection of human health and the environment:


13/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



13 / 15

Decree 44/2000. (XII.27.) EM (Minister of Health Affairs) and its amendments: Decree 33/2004. (IV.26.) ESzCsM(Minister of Health, Social and Family Affairs) and Decree 26/2007. (VI.7.) EM (1907/2006/EK - REACH) ondetailed rules of certain procedures and activities related to dangerous substances and preparations.Joint Ministerial Decree: 25/2000. (IX.30.) EM-ESzCsM on chemical safety at work.

NATIONAL REGULATIONS POLANDAct on chemical substances and preparations of 11 January 2001 (J.oL. No. 11, item 84 as amended). Unified text(J.oL of 2009, No 152, item 1222).Minister of Health Regulation of 8 February 2010 concerning a list of dangerous substances including classificationand labelling (J.oL. no. 27 item 140).Minister of Health Regulation of 2 September 2003 concerning criteria and way of classification of chemicalsubstances and preparations (J.oL. No 171, item 1666 as amended).

Minister of Health Regulation of 5 March 2009 concerning labelling of dangerous substances and preparations(J.oL. no. 53 item 439).Regulation of MPiPS [Minister of Labour and Social Policy] dated 29 November 2002 on maximum allowableconcentrations and levels of harmful factors in the working environment (J.oL. No. 217, item 1833 as amended).Government Statement dated 16 January 2009 on introduction of changes in appendices A and B to EuropeanAgreement on road transport of hazardous goods (ADR) prepared in Geneva on 30 September 1957 (J.oL. No 27,item 162).Minister of Economy Regulation of 21 December 2005 on essential requirements for Personal ProtectiveEquipment (J.oL. No. 259, item 2173 of 2005).Minister of Health Regulation of 20 April 2005 on tests andmeasurements of factors hazardous for health in the working environment (J.oL. No. 73, item 645 dated 2005 asamended).Regulation 1907/2006/EC concerning Registration, Evaluation, Authorization and Restriction of Chemicals(REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council

Regulation (EEC) No 793/93 and No 1488/94, as well as Council Directive 76/769/EEC and CommissionDirectives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/ECRegulation 1272/2008/EC of the European Parliament and of the Council of 16 December 2008 on theclassification, labelling and packaging of substances and mixtures, amending and repealing Directive 67/548/EECand 1999/45/EC and amending Regulation (EC) No 1907/2006.1999/45/EC Directive of the European Parliamentand of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrativeprovisions of the Member States relating to the classification, packaging and labelling of dangerouspreparations.790/2009/EC Commission Regulation of 10 August 2009 amending, for the purposes of itsadaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and ofthe Council on classification, labelling and packaging of substances and mixtures.453/2010/ EC Commissionregulation of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of theCouncil concerning Registration, Evaluation, Authorization and Restriction of Chemicals (REACH).

NATIONAL REGULATIONS RUSSIAN FEDERATIONThe law of Russian Federation "About the sanitary-epidemiological safety of the population", 30 March 1999 N52-FZ.The law of Russian Federation "About the safety of the dangerous industrial objects", 21 July 1997 No. 116-FZ.The law of Russian Federation "About protection of the rights of the consumers", 07 February 1992 N 2300-1.The law of Russian Federation "Basics of the legislation ofThe law of Russian Federation "About the industrial regulation", 27 December 2002 N 184-FZ.The law of Russian Federation "On Environmental Protection", 10 January 2002, N 7-FZ.GOST 30333-2007: Chemical production safety passport. General requirements.GOST 19433-88: Dangerous goods. Classification and marking.GOST 12.1.007-76 (Occupational safety standards system. Noxious substances. Classification and general safetyrequirements).

PRODUCT REGISTRATION NUMBER


14/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



14 / 15

Denmark 1784346

INTERNATIONAL CHEMICAL CONTROL LAWSEUROPE

The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

Safety Data Sheet according to Regulation (EC) No 1907/2006.

Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import intoEuropean Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.

Should you require any further information on Nalco's REACH programme please contact us at [email protected] visit our website.

UNITED STATES :The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

CANADA :The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

JAPAN

All substances in this product comply with the Law Regulating the Manufacture and Importation Of ChemicalSubstances and are listed on the Existing and New Chemical Substances list (ENCS).

16. OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3R10 - Flammable.R20 - Harmful by inhalation.R21/22 - Harmful in contact with skin and if swallowed.R22 - Harmful if swallowed.R34 - Causes burns.R35 - Causes severe burns.R43 - May cause sensitization by skin contact.R52 - Harmful to aquatic organisms.

R62 - Possible risk of impaired fertility.- REVISED INFORMATION: section(s):- 2- 3- 8- 11- 15

This product material safety data sheet provides health and safety information. The product is to be used inapplications consistent with our product literature. Individuals handling this product should be informed of therecommended safety precautions and should have access to this information. For any other uses, exposuresshould be evaluated so that appropriate handling practices and training programs can be established to insuresafe workplace operations. Please consult your local sales representative for any further information.


15/15

SAFETY DATA SHEET

PRODUCT

Tri-ACT 1800



15 / 15

EMERGENCY TELEPHONE NUMBER(S)

Trans-European +32-(0)3-575-5555

Belgium / Luxembourg +32-(0)3-575-0330Bulgaria +32-(0)3-575-5555Croatia +385 (0)91-1-25-75-23Czech Republic +420-602-669421Denmark +47-22-33-69-99Finland +358-(0)9-471 977France / French Switzerland +33-(0)6-11-07-32-81Germany / Austria / German Switzerland +49-(0)6232-130128Hungary +36-30-9-506-447Italy / Italian Switzerland +39-333-210-7947

Latvia +32-(0)3-575-5555 & Local emergency telephone number 112The Netherlands +32-(0)3-575-0330Norway +47-22-33-69-99Poland +48-(0)601-66-2626 (SGS) / +48(0)14 637 40 81 (SPOT)Portugal +351-91-911-1399Romania +40-744 -34-14-53Russia / Belarus +7-812-449-0474Saudi Arabia +966-(3)847-1515Serbia +32-(0)3-575-5555Slovak Republic +421-(0)905-585-938Slovenia +386-41-634-916Spain +34-977-551577

Sweden +47-22-33-69-99UAE +44-(0)7071-223-738UK and Republic of Ireland +44-(0)7071-223-738Nalfleet International +32-(0)3-575-5555

POISON CONTROL CENTER TELEPHONE NUMBERS

Belgium +32-70-245245Czech Republic +420 224 91 92 93France +33-(0)145-42-59-59 ORFILAHungary +36-80-201-199 (ETTSZ, 1096 Budapest, Nagyvrad tr 2)Latvia + 371 67042473Slovak Republic +421 (0)2 5477 4166

Prepared By : SHE DepartmentDate issued : 06.10.2010Version Number : 5.0

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenthand 0.001 = 1 thousandth

Documents

Nalco -1800 -Corrosion Inhibitor