N2 (9) + 3 Hz(g) - 2 NH3(g)

2NOCg) f Br2(g) - 2 NOBr (g)

H30 + (aq) -I- OH-(aq) - 2 H20 (1)

ca (s) + C02(9) - cao (s) + co (g)

Mg (8) + C12(9) - MgC12 (5)

A + B - c

CH 3 4 3

. . . (1 .1 1

3

aO

Y YW-lWl?JMPIU

T

&“glainia~fk$jfiSei = - d[A] 2 - d[83 ..-*. (I -3)- -cl -t d t

CH 343

1 0 CH 3 4 3

1 2 CH 343

6ml~noJ6Quu6~u ,a kl ,0 +

3 O2(6%)

\

k-l

0 + o3k2

+ 2 O2 6'7)

K = kl = [01[021

k-1 LO3 1

LWfltQttu7~16 [Ol ” K[‘j I

co,1 --. ..(1.13)

66mfil (1.13) lu (1.12) XiM

- <d[O31 =,- k2KL%lZ . . . . . (I .14)dt ro2 1

CH 3 4 3 1 3

d[‘27 = k2 C031[Ol . . . ..(l .15)d t

l7lbJh~llJ [OJ.~W~ltQt~U~~ Steady State Approximation

d[Ol = 0 =d t

kl LO,1 - k-,[01[021 - k2[Ol[031

LW~ltQt&4 k, [03 I = kqI[01[021 + k2[01[031 . . . ..(I .16)

(1 -17)

LLYlUh (1.17) ll.4 (1.15) TJrM

91 = kl k2 LO3 I2

d t k-l [021 + k21031

1 4 CH 343

- d[Pil = v = k C; .a.... (1 -18)d t.

logv = logk + n log CA . . . ..(I .19)

CH 343 1 5

log ”

:_

log k

/

s2°82-

+ 2 1 - - 2 so42- + I2 . . . ..(1.20)

1 6 CH 343

2- + - '4'62-2 '2'3 I2

+ 2 1 - . . . . - (I -21 !

2-+ I- 3-'2'8 d S2081 (3

'2'8' 3-+ I- - 2 soy + I2 (62)

-&08-2 I =

dt-k[S2082-1[I-l

A[S2082-l2-= k[S208 lo [I-l 0

A t

AI S2082 .- ]

= 2Ax =A t -E-

k [S20;- lp-10

CH 343 1 7

rszo;-10

= m1u&Ju"prL3uhsloJ s2 0; -

k [Ala[Blb[CIC

- d[Al =7-F

k.kl[AIa

kl = [BlblCIC = +iTWfi

1 8 CH 343

Iw” ka = k . . . ..(I -24

a:Gi - d[Al = dx = k’(b-x) . . . ..(I .25dt at

CH 343 19

k’ = 2.303 log . . . ..(1.26)bt b-x

CH3COOC2H5 + H20 - CH3COOH + C2H50H

2 0 CH 343

k, = -2 -303 iW-m~$Ul . . . _. (I .34)

15 lna = In 2

a 7 2kl

= 2 . 3 0 3 l o g 2 0 . 6 9 3 . . . (I -35)=

kl kl

2 4 CH 343

I

- d[Al =dt-

k2 [Al2

= k$AI[BI = k2[A12 dfl [AI=IBI

%&I dx =(a-x)"

kgdt

1- = .k2t + til"Jia-x

1 -1 = k2t-a-x a

X

ala-x) = k2t . . . ..(I .40)

3 0 CH 343

. . . . . (1 -41 1

44 0

XiTll ~inmmi~ (1.48) (t&= (2)

n - l

w2 “1

LWlWil (150 1 . 0 3n - l

- =7 5 ) ( 0.51 )

Ii log PYvi l o g 2 = (n-l ) log 2

n - l = 1

n = 2

% = 1

k2a-1

k2= 1 dm3 .mol -1 . set

0 . 5 1 x 175

= 1 . 3 1 x IO-2

dm3 .mol-’-1

_ set

CH 3 4 3 3 5

dxZT

= (kI+ k-,) (m-x)

b&J t = 0 , x = 0 otMfhd = - In m

&4 k,tkwl = 1 In m . .._. ( 1 . 5 4 )F m-x

C6H5- CH C6H5-CH

!I --‘ I INC - CH CH-CN

H2+ I2 k2 2 HI

k-2*

a-+ b- (z) x

d[HIl dx-= k2 (a-t) (b+-ks2x2 _. . ( 1 . 5 4 )dt TE =

38 CH 343

k,+k-, = 1 Int (

oo- um1

u - urnt

nT0 In (ca*- am) = In ho- aa) - (k,+k-, ) t

4 2

ad 1.9 Lfi~0J~O~@t+lblhl~~ (Dilatometer)

CH 343

\ I

4 4 CH 343

2 N O + H2' N2+ 2 Hz0 1&4iHAR1aJ9)1~1J

4 6 CH 343

4 8 CH 343