MSDS amilalkoholr.doc

8/11/2019 MSDS amilalkoholr.doc

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MSDS Number: A6372* * * * *Effective Date:09/09/09* * * * * Supercedes:05/11/07

Amyl Alcohol (Mixed Isomers)

1. Product Identification

SynonymsMixed Pentanols; Pentyl Alcohol (Mixed Isomers)

!AS "o.Not applicable to mixtures

Molecular #ei$ht!!"#!hemical %ormula$#%""&%

Product !odes' aer: +,-.

Mallincrodt: .++/

2. !om&osition'Information on In$redients

Ingredient CAS No Percent

Hazardous--------------------------------------- ------------ ------------

---------

Amyl Alcohol 71-41-0 55 - !"

#es

$-%ethyl&utanol 1'7-'$- $5 - 40"

#es


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Isoamyl Alcohol 1$'-51-' $ - 15"

#es

3. aards Identification*mer$ency +,er,ie-

00000000000000000000000000

#A"I"/0 %AMMA* I4I5 A"5 AP+. AM%4 I% S#A+#*5

I"A*5 + AS+*5 8+4/ S9I". AP+S !A4S* *SPIA8+:

8A!8 II8A8I+" A"5 S*** *:* II8A8I+". I4I5 !A4S*S S9I"

II8A8I+" S*** *:* II8A8I+" A"5 P+SSI* *:* 4"S. A%%*!8S

!*"8A "*+4S S:S8*M.

SA%;8;5A8A(tm)1atin2s (Pro3ided here 4or your con3enience)

00000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000%ealth 1atin2: . 0 Moderate (5i4e)

6lammability 1atin2: . 0 Moderate1eacti3ity 1atin2: " 0 Sli2ht

$ontact 1atin2: - 0 Se3ere

5ab Protecti3e 78uip: 9&9957S S%I75D; 5A $&A AP1&N; 7N %&&D;P1&P71 95&7S; $5ASS 7 throat> and upper respiratory passa2es %i2her

concentrations ha3e a narcotic e44ect and may cause headache> nausea> 3omitin2> di??iness>double 3ision> shortness o4 breath> and delirium In se3ere cases> inhalation may be 4atal May

cause pulmonary edema> a medical emer2ency May cause heart e44ects

In$estion

Moderately toxic by in2estion> can cause headache> nausea> delirium and methemo2lobin4ormation in the blood &ther symptoms may parallel those 4rom inhalation exposure omitin2

may cause aspiration into lun2s and result in chemical pnuemonia

S pain> redness> s@ellin2 5i8uid

contact causes se3ere irritation and possible burns

!hronic *x&osure

1epeated inhalation o4 aerosols may result in lun2 and idney inury $hronic exposure may


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cause sin e44ects

A$$ra,ation of Pre;existin$ !onditions

Persons @ith pre0existin2 sin disorders or eye problems> or impaired li3er> idney or respiratory4unction may be more susceptible to the e44ects o4 the substance

=. %irst Aid Measures

Inhalation

1emo3e to 4resh air I4 not breathin2> 2i3e arti4icial respiration I4 breathin2 is di44icult> 2i3e

oxy2en 9et medical attention

In$estion

I4 s@allo@ed> D& N& IND=$7 &MIIN9 9i3e lar2e 8uantities o4 @ater Ne3er 2i3e

anythin2 by mouth to an unconscious person 9et medical attention immediately

S li4tin2 lo@er and upper

eyelids occasionally 9et medical attention immediately

>. %ire %i$htin$ Measures

%ire

6lash point: --$ (+"6) $$Autoi2nition temperature: -,,$ (#C.6)

6lammable limits in air by 3olume:

lel: ".; uel: ",,5isted 4ire data is 4or amyl alcohol ($AS C"0E"0,) 6lammable =pper explosi3e limit is 4or

",,$ (.".6) $ontact @ith stron2 oxidi?ers may cause 4ire

*x&losionAbo3e 4lash point> 3apor0air mixtures are explosi3e @ithin 4lammable limits noted abo3e apors

can 4lo@ alon2 sur4aces to distant i2nition source and 4lash bac Sensiti3e to static dischar2e

%ire *xtin$uishin$ Media

Dry chemical> 4oam or carbon dioxide Bater spray may be used to eep 4ire exposed containers

cool Bater may be ine44ecti3eS&ecial Information

In the e3ent o4 a 4ire> @ear 4ull protecti3e clothin2 and NI&S%0appro3ed sel40contained breathin2apparatus @ith 4ull 4acepiece operated in the pressure demand or other positi3e pressure mode

6. Accidental elease Measures


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entilate area o4 lea or spill 1emo3e all sources o4 i2nition Bear appropriate personal

protecti3e e8uipment as speci4ied in Section ! Isolate ha?ard area Feep unnecessary and

unprotected personnel 4rom enterin2 $ontain and reco3er li8uid @hen possible =se non0sparin2 tools and e8uipment $ollect li8uid in an appropriate container or absorb @ith an inert

material (e 2> 3ermiculite> dry sand> earth)> and place in a chemical @aste container Do not use

combustible materials> such as sa@ dust Do not 4lush to se@erG I4 a lea or spill has not i2nited>use @ater spray to disperse the 3apors> to protect personnel attemptin2 to stop lea> and to 4lush

spills a@ay 4rom exposures

' aer S&5=S&1H sol3ent adsorbent is recommended 4or spills o4 this product

7. andlin$ and Stora$e

Protect a2ainst physical dama2e Store in a cool> dry @ell03entilated location> a@ay 4rom any

area @here the 4ire ha?ard may be acute &utside or detached stora2e is pre4erred Separate 4rom

incompatibles $ontainers should be bonded and 2rounded 4or trans4ers to a3oid static sparsStora2e and use areas should be No Smoin2 areas =se non0sparin2 type tools and e8uipment>

includin2 explosion proo4 3entilation $ontainers o4 this material may be ha?ardous @hen empty

since they retain product residues (3apors> li8uid); obser3e all @arnin2s and precautions listed 4orthe product

?. *x&osure !ontrols'Personal Protection

Air@orne *x&osure imits0 AI%A Borplace 7n3ironmental 7xposure 5e3el (B775):

",, ppm (-/, m2m-)> !0hour> BA

entilation SystemA system o4 local andor 2eneral exhaust is recommended to eep employee exposures as lo@ as

possible 5ocal exhaust 3entilation is 2enerally pre4erred because it can control the emissions o4

the contaminant at its source> pre3entin2 dispersion o4 it into the 2eneral @or area Please re4erto the A$9I% document>Industrial Ventilation, A Manual of Recommended Practices> most

recent edition> 4or details =se explosion0proo4 e8uipment

Personal es&irators ("I+S A&&ro,ed)

6or conditions o4 use @here exposure to the substance is apparent and en2ineerin2 controls are

not 4easble> consult an industrial hy2ienist 6or emer2encies> or instances @here the exposurele3els are not no@n> use a 4ull04acepiece positi3e0pressure> air0supplied respirator BA1NIN9:

Air puri4yin2 respirators do not protect @orers in oxy2en0de4icient atmospheres

S includin2 boots> 2lo3es> lab coat> apron or co3eralls> as

appropriate> to pre3ent sin contact

*ye Protection


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=se chemical sa4ety 2o22les andor a 4ull 4ace shield @here splashin2 is possible Maintain eye

@ash 4ountain and 8uic0drench 4acilities in @or area

. Physical and !hemical Pro&ertiesA&&earance

$lear> colorless li8uid

+dor

$haracteristic odor

Solu@ility-

S&ecific /ra,ity

,!" J .,$E$

&No in4ormation 4ound

B olatiles @y ,olume C 21! (7D%)

",,

oilin$ Point

"--$ (.C"6)

Meltin$ PointNo in4ormation 4ound

a&or 5ensity (AirE1)

-,

a&or Pressure (mm $). J .,$ (/!6)

*,a&oration ate (uAcE1)

,./

1D. Sta@ility and eacti,ity

Sta@ilityStable at room temperature in sealed containers

aardous 5ecom&osition Products

$arbon dioxide and carbon monoxide may 4orm @hen heated to decomposition $an 4orm

aldehydes burnin2 in limited air

aardous PolymeriationBill not occur

Incom&ati@ilitiesStron2 oxidi?ers Stron2 inor2anic acids %eat and sources o4 i2nition

!onditions to A,oid

%eat> 4lames> i2nition sources and incompatibles


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11. 8oxicolo$ical Information

6or amyl alcohol ($AS K C"0E"0,): &ral rat 5D#,: ..,, m22; sin rabbit 5D#,: L -.,,m22; irritation sin rabbit> standard Drai?e: -.,, m22.E% se3ere; eye rabbit> standard

Drai?e: !" m2.E% se3ere In3esti2ated as a muta2en

6or .0methylbutanol ($AS K "-C0-.0/): &ral rat 5D#,: ">,,, m22; Sin rabbit> 5D#,: -#E,

u52

Isoamyl alcohol: &ral rat 5D#, "-,, m2F2; Sin rabbit 5D#, -+C, u5F2; Irritation sin

rabbit ., m2.E% moderate; Irritation eye rabbit ., m2.E% moderate In3esti2ated as a

tumori2en

--------(Cancer )ists(------------------------------------------------------

---N*P Carcinogen---

Ingredient +no,n Anticiated IA.C Category

------------------------------------ ----- ----------- ------------- Amyl Alcohol /71-41-0 No No None

$-%ethyl&utanol /1'7-'$- No No None

Isoamyl Alcohol /1$'-51-' No No None

12. *colo$ical Information

*n,ironmental %ate

Bhen released into the soil> this material is expected to leach into 2round@ater Bhen releasedinto the soil> this material may biode2rade to a moderate extent Bhen released into the soil> this

material may e3aporate to a moderate extent Bhen released into @ater> this material maybiode2rade to a moderate extent Bhen released into @ater> this material may e3aporate to amoderate extent his material has an estimated bioconcentration 4actor ($6) o4 less than ",,

his material is not expected to si2ni4icantly bioaccumulate Bhen released into the air> this

material is expected to be readily de2raded by reaction @ith photochemically produced hydroxylradicals Bhen released into the air> this material may be remo3ed 4rom the atmosphere to a

moderate extent by @et deposition

*n,ironmental 8oxicityNo in4ormation 4ound

13. 5is&osal !onsiderations

Bhate3er cannot be sa3ed 4or reco3ery or recyclin2 should be handled as ha?ardous @aste andsent to a 1$1A appro3ed @aste 4acility Processin2> use or contamination o4 this product may

chan2e the @aste mana2ement options State and local disposal re2ulations may di44er 4rom

4ederal disposal re2ulations Dispose o4 container and unused contents in accordance @ith4ederal> state and local re8uirements


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1=. 8rans&ort Information

5omestic (and 5.+.8.)

00000000000000000000000Pro&er Shi&&in$ "ameP7NAN&5S

aard !lass-

4"'"A=N"",#Pacin2 9roup: III

Information re&orted for &roduct'sie-C#5

International (#ater I.M.+.)

00000000000000000000000000000

Pro&er Shi&&in$ "ameP7NAN&5S

aard !lass-



International (Air I.!.A.+.)

00000000000000000000000000000

Pro&er Shi&&in$ "ameP7NAN&5S

aard !lass-



1>. e$ulatory Information

--------(Chemical Inentory Status - Part

1(---------------------------------

Ingredient *SCA 2C 3aan Australia

----------------------------------------------- ---- --- ----- ---------

Amyl Alcohol /71-41-0 #es #es #es #es

$-%ethyl&utanol /1'7-'$- #es #es #es #es

Isoamyl Alcohol /1$'-51-' #es #es #es #es

--------(Chemical Inentory Status - Part

$(---------------------------------

--Canada--

Ingredient +orea S) NS) Phil

----------------------------------------------- ----- --- ---- -----

Amyl Alcohol /71-41-0 #es #es No #es

$-%ethyl&utanol /1'7-'$- #es #es No #es

Isoamyl Alcohol /1$'-51-' #es #es No #es


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--------(6ederal State 8 International .egulations - Part

1(----------------

-SA.A '0$- ------SA.A

'1'------

Ingredient .9 *P9 )ist Chemical

Catg

----------------------------------------- --- ----- ----

--------------

Amyl Alcohol /71-41-0 No No No No

$-%ethyl&utanol /1'7-'$- No No No No

Isoamyl Alcohol /1$'-51-' No No No No

--------(6ederal State 8 International .egulations - Part

$(----------------

-.C.A- -*SCA-

Ingredient C2.C)A $1'' !/d

----------------------------------------- ------ ------ ------

Amyl Alcohol /71-41-0 No No No

$-%ethyl&utanol /1'7-'$- No No No

Isoamyl Alcohol /1$'-51-' No No No

Chemical :eaons Conention; No *SCA 1$/&; No C*A; No

SA.A '11


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Bash thorou2hly a4ter handlin2

a@el %irst Aid

I4 s@allo@ed> D& N& IND=$7 &MIIN9 9i3e lar2e 8uantities o4 @ater Ne3er 2i3eanythin2 by mouth to an unconscious person In case o4 contact> immediately 4lush eyes or sin

@ith plenty o4 @ater 4or at least "# minutes @hile remo3in2 contaminated clothin2 and shoes

Bash clothin2 be4ore reuse I4 inhaled> remo3e to 4resh air I4 not breathin2> 2i3e arti4icialrespiration I4 breathin2 is di44icult> 2i3e oxy2en In all cases 2et medical attention immediately

Product 4se

5aboratory 1ea2ent

e,ision Information

No $han2es

5isclaimer

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MSDS amilalkoholr.doc