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ASIAN COAL TAR EPOXY PAINT BLACK IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING +091 22 39814000 MATERIAL SAFETY DATA SHEET Product name ASIAN COAL TAR EPOXY PAINT BLACK 1. Emergency telephone number (with hours of operation) : Chemical name Not available. Not available. Synonyms Chemical formula Not applicable. Asian Paints Ltd. 6A, Shantinagar. Opp Hotel Grand Hyatt, Santacruz (E), P.O. Box No. 6818, Mumbai 400 055 Tel No. 091 22 39818000 Fax No. 091 22 39818888 Manufacturer : : : : : Identification of the substance or preparation Company/undertaking identification Asian Paints Ltd. 6A, Shantinagar. Opp Hotel Grand Hyatt, Santacruz (E), P.O. Box No. 6818, Mumbai 400 055 Tel No. 091 22 39818000 Fax No. 091 22 39818888 Supplier : e-mail address of person responsible for this SDS : [email protected] CAS number : Not applicable. Use of the substance/preparation 02590801 Product code : Painting/Coating : HAZARDS IDENTIFICATION 2. Classification : Physical/chemical hazards : Flammable. : Human health hazards May cause cancer. See section 11 for more detailed information on health effects and symptoms. Risk phrases R10- Flammable. R45- May cause cancer. : Toxic COMPOSITION/INFORMATION ON INGREDIENTS tar, coal 8007-45-2 30 - 50 Quartz (SiO2) 14808-60-7 15 - 30 ethylbenzene 100-41-4 5 - 15 xylene 1330-20-7 5 - 15 Epoxy Amine Adduct 1 - 5 methanol 67-56-1 0 - 1 3. Substance/preparation Preparation : CAS number % Ingredient name

MSDS-02590801 Asian Coal Tar Epoxy

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Page 1: MSDS-02590801 Asian Coal Tar Epoxy

ASIAN COAL TAR EPOXY PAINT BLACK

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKING

+091 22 39814000

MATERIAL SAFETY DATA SHEET

Product name

ASIAN COAL TAR EPOXY PAINT BLACK

1.

Emergency telephone number(with hours of operation)

:

Chemical name Not available.

Not available.Synonyms

Chemical formula Not applicable.

Asian Paints Ltd.6A, Shantinagar.Opp Hotel Grand Hyatt,Santacruz (E), P.O. Box No. 6818,Mumbai 400 055

Tel No. 091 22 39818000Fax No. 091 22 39818888

Manufacturer

:

:

:

:

:

Identification of the substance or preparation

Company/undertaking identification

Asian Paints Ltd.6A, Shantinagar.Opp Hotel Grand Hyatt,Santacruz (E), P.O. Box No. 6818,Mumbai 400 055

Tel No. 091 22 39818000Fax No. 091 22 39818888

Supplier :

e-mail address of personresponsible for this SDS

: [email protected]

CAS number : Not applicable.

Use of thesubstance/preparation

02590801Product code :

Painting/Coating:

HAZARDS IDENTIFICATION2.Classification :

Physical/chemical hazards : Flammable.

:Human health hazards May cause cancer.

See section 11 for more detailed information on health effects and symptoms.

Risk phrases R10- Flammable.R45- May cause cancer.

:

Toxic

COMPOSITION/INFORMATION ON INGREDIENTS

tar, coal 8007-45-2 30 - 50Quartz (SiO2) 14808-60-7 15 - 30ethylbenzene 100-41-4 5 - 15xylene 1330-20-7 5 - 15Epoxy Amine Adduct 1 - 5methanol 67-56-1 0 - 1

3.Substance/preparation Preparation:

CASnumber

%Ingredient name

Page 2: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 2/137/9/2010.

COMPOSITION/INFORMATION ON INGREDIENTS3.

Occupational exposure limits, if available, are listed in section 8.

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reportingin this section.

Get medical attention immediately. Wash out mouth with water. Remove dentures ifany. Move exposed person to fresh air. Keep person warm and at rest. If materialhas been swallowed and the exposed person is conscious, give small quantities ofwater to drink. Stop if the exposed person feels sick as vomiting may be dangerous.Do not induce vomiting unless directed to do so by medical personnel. If vomitingoccurs, the head should be kept low so that vomit does not enter the lungs. Nevergive anything by mouth to an unconscious person. If unconscious, place in recoveryposition and get medical attention immediately. Maintain an open airway. Loosentight clothing such as a collar, tie, belt or waistband.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention if irritation occurs.

Get medical attention immediately. Flush contaminated skin with plenty of water.Remove contaminated clothing and shoes. Wash contaminated clothing thoroughlywith water before removing it, or wear gloves. Continue to rinse for at least 10minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse.

4.Get medical attention immediately. Move exposed person to fresh air. If it issuspected that fumes are still present, the rescuer should wear an appropriate maskor self-contained breathing apparatus. Keep person warm and at rest. If notbreathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. If unconscious, place in recoveryposition and get medical attention immediately. Maintain an open airway. Loosentight clothing such as a collar, tie, belt or waistband.

Ingestion

Inhalation

Eye contact

:

:

:

:

FIRST AID MEASURES

See section 11 for more detailed information on health effects and symptoms.

FIRE-FIGHTING MEASURES5.

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool. Fire water contaminated with this materialmust be contained and prevented from being discharged to any waterway, sewer ordrain.

Hazardous thermaldecomposition products

Special exposure hazards

Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides

Flammable liquid. In a fire or if heated, a pressure increase will occur and thecontainer may burst, with the risk of a subsequent explosion. The vapor/gas is heavierthan air and will spread along the ground. Vapors may accumulate in low or confinedareas or travel a considerable distance to a source of ignition and flash back. Runoffto sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode.

Special protectiveequipment for fire-fighters

Recommended: alcohol-resistant foam, CO2, powders, water spray.

Extinguishing media

:

:

:

Do not use water jet.

Suitable :

Not suitable :

Page 3: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 3/137/9/2010.

Environmental precautions

Personal precautions

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilled product. Note: see section 1 foremergency contact information and section 13 for waste disposal.

6. ACCIDENTAL RELEASE MEASURES

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8).

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmful tothe environment if released in large quantities.

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble or absorb with an inert dry material and place in an appropriatewaste disposal container. Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor.

Small spill :

Methods for cleaning up

Handling

HANDLING AND STORAGE

Storage

7.Put on appropriate personal protective equipment (see section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Avoid exposure - obtain special instructions before use. Do not get in eyesor on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release tothe environment. Use only with adequate ventilation. Wear appropriate respiratorwhen ventilation is inadequate. Do not enter storage areas and confined spacesunless adequately ventilated. Keep in the original container or an approvedalternative made from a compatible material, kept tightly closed when not in use.Store and use away from heat, sparks, open flame or any other ignition source. Useexplosion-proof electrical (ventilating, lighting and material handling) equipment. Usenon-sparking tools. Take precautionary measures against electrostatic discharges.To avoid fire or explosion, dissipate static electricity during transfer by grounding andbonding containers and equipment before transferring material. Empty containersretain product residue and can be hazardous. Do not reuse container.

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have beenopened must be carefully resealed and kept upright to prevent leakage. Do not storein unlabeled containers. Use appropriate containment to avoid environmentalcontamination.

:

:

Ingredient name Occupational exposure limits

Exposure limit values

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Page 4: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 4/137/9/2010.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONQuartz (SiO2) ACGIH TLV (United States, 1/2007).

TWA: 0.025 mg/m³ 8 hour(s). Form: Respirable fractionethylbenzene EU OEL (Europe, 5/2006). Absorbed through skin. Notes:

Indicativelimit value 8 hours: 100 ppm 8 hour(s).

limit value 8 hours: 442 mg/m³ 8 hour(s). limit value short term: 200 ppm 15 minute(s). limit value short term: 884 mg/m³ 15 minute(s).

xylene EU OEL (Europe, 5/2006). Absorbed through skin. Notes:Indicativelimit value 8 hours: 50 ppm 8 hour(s).

limit value 8 hours: 221 mg/m³ 8 hour(s). limit value short term: 100 ppm 15 minute(s). limit value short term: 442 mg/m³ 15 minute(s).

methanol EU OEL (Europe, 5/2006). Absorbed through skin. Notes:Indicativelimit value 8 hours: 200 ppm 8 hour(s).

limit value 8 hours: 260 mg/m³ 8 hour(s).

Limestone OSHA PEL 1989 (United States, 3/1989).TWA: 15 mg/m³ 8 hour(s). Form: Total dust

TWA: 5 mg/m³ 8 hour(s). Form: Respirable fractionNIOSH REL (United States, 12/2001).TWA: 10 mg/m³ 10 hour(s). Form: Total

TWA: 5 mg/m³ 10 hour(s). Form: Respirable fractionOSHA PEL (United States, 11/2006).TWA: 5 mg/m³ 8 hour(s). Form: Respirable fraction

TWA: 15 mg/m³ 8 hour(s). Form: Total dustQuartz (SiO2) OSHA PEL Z3 (United States, 9/2005).

TWA: 250 mppcf 8 hour(s). Form: Respirable TWA: 10 mg/m³ 8 hour(s). Form: Respirable TWA: 30 mg/m³ 8 hour(s). Form: Total dust.ACGIH TLV (United States, 1/2007).TWA: 0.025 mg/m³ 8 hour(s). Form: Respirable fraction

NIOSH REL (United States, 12/2001).TWA: 0.05 mg/m³ 10 hour(s).

OSHA PEL 1989 (United States, 3/1989). Notes: as quartzTWA: 0.1 mg/m³, (as quartz) 8 hour(s). Form: Respirable dust

Ethyl benzene ACGIH TLV (United States, 1/2007).TWA: 100 ppm 8 hour(s).

STEL: 125 ppm 15 minute(s).OSHA PEL 1989 (United States, 3/1989).TWA: 100 ppm 8 hour(s).

TWA: 435 mg/m³ 8 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m³ 15 minute(s).NIOSH REL (United States, 12/2001).TWA: 100 ppm 10 hour(s).

TWA: 435 mg/m³ 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006).TWA: 100 ppm 8 hour(s).

TWA: 435 mg/m³ 8 hour(s).

Xylene ACGIH TLV (United States, 1/2007).TWA: 100 ppm 8 hour(s).

TWA: 434 mg/m³ 8 hour(s). STEL: 150 ppm 15 minute(s). STEL: 651 mg/m³ 15 minute(s).OSHA PEL 1989 (United States, 3/1989).TWA: 100 ppm 8 hour(s).

TWA: 435 mg/m³ 8 hour(s).

Page 5: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 5/137/9/2010.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Recommended monitoringprocedures

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product and thesafe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.

Eye protection

Respiratory protection :

:

:

:

Skin protection Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialist beforehandling this product.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

Occupational exposurecontrols

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilationor other engineering controls to keep worker exposure to airborne contaminantsbelow any recommended or statutory limits. The engineering controls also need tokeep gas, vapor or dust concentrations below any lower explosive limits. Useexplosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safetyshowers are close to the workstation location.

Exposure controls

Hygiene measures :

STEL: 150 ppm 15 minute(s). STEL: 655 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006).TWA: 100 ppm 8 hour(s).

TWA: 435 mg/m³ 8 hour(s).

Not available.

PHYSICAL AND CHEMICAL PROPERTIESPhysical state

Melting point

Boiling point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

1.42

3.7 [Air = 1]

0.9 kPa (6.72 mm Hg)

Not available.

Not available.Odor

pH

Flash point Closed cup: >28°C (>82.4°F) [Abel's close cup]

Lower: 1%Upper: 15.6%

9.

Not applicable.

0.05 ppmOdor threshold

Explosion limits

:

:

:

:

:

:

:

:

:

:

:

:

Page 6: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 6/137/9/2010.

PHYSICAL AND CHEMICAL PROPERTIES9.Evaporation rate <1 (Butyl Acetate = 1)

Auto-ignition temperature 235°C (455°F)

:

:

Density : 1.42 g/cm3 [30°C (86°F)]

Flammability : Not available.

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do notallow vapor to accumulate in low or confined areas. Avoid exposure - obtain specialinstructions before use.

STABILITY AND REACTIVITYThe product is stable.Chemical stability

10.

No known incompatibility

:

:

Materials to avoid :

Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

TOXICOLOGICAL INFORMATION11.Potential acute health effects

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : May cause skin irritation.

May cause eye irritation.:Eye contact

Acute toxicity

tar, coal LD50 Dermal Rabbit >7950 mg/kg -Quartz (SiO2) LDLo

IntratrachealRat 250 mg/kg -

LDLoIntratracheal

Rat 200 mg/kg -

LDLoIntravenous

Rat 90 mg/kg -

TDLoIntratracheal

Rat 50 mg/kg -

TDLoIntratracheal

Rat 30 mg/kg -

TDLoIntratracheal

Rat 25 mg/kg -

TDLoIntratracheal

Rat 15.69 mg/kg -

TDLoIntratracheal

Rat 10 mg/kg -

TDLoIntratracheal

Rat 5 mg/kg -

TDLoIntratracheal

Rat 1.5 mg/kg -

TDLoIntratracheal

Rat 1 mg/kg -

TDLoIntratracheal

Rat 1250 ug/kg -

TDLoIntratracheal

Rat 150 mg/kg -

TDLoIntratracheal

Rat 100 mg/kg -

TDLo Oral Rat 120 g/kg -ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -

LD50 Dermal Rabbit 17800 uL/kg -LD50 Oral Rat 3500 mg/kg -TDLoIntraperitoneal

Rat 1062 mg/kg -

xylene LD50 Dermal Rabbit >1700 mg/kg -

Product/ingredient name Result Species Dose Exposure

Page 7: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 7/137/9/2010.

TOXICOLOGICAL INFORMATION11.

Potential chronic health effects

No known significant effects or critical hazards.Chronic effects :

Denmark – Carcinogen list : Contains a substance or substances listed under National Working EnvironmentAuthorities Executive Order 908/2005.

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

xylene LD50 Dermal Rabbit >1700 mg/kg -LD50Intraperitoneal

Rat 2459 mg/kg -

LD50 Oral Rat 4300 mg/kg -LD50Subcutaneous

Rat 1700 mg/kg -

methanol LD50 Dermal Rabbit 15800 mg/kg -LD50Intraperitoneal

Rat 7529 mg/kg -

LD50Intravenous

Rat 2131 mg/kg -

LD50 Oral Rat 5600 mg/kg -TDLo Oral Rat 8 g/kg -TDLo Oral Rat 3500 mg/kg -TDLoIntraperitoneal

Rat 3490 mg/kg -

TDLoIntraperitoneal

Rat 3000 mg/kg -

TDLo Oral Rat 3 g/kg -

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Over-exposure signs/symptoms

Skin

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eyes : No specific data.

Product name Carcinogeniceffects

Mutagenic effects Developmentaleffects

Fertility effects

tar, coal Carc. Cat. 1; R45 - - -

ECOLOGICAL INFORMATION12.Ecotoxicity : Water polluting material. May be harmful to the environment if released in large

quantities.

Aquatic ecotoxicity

tar, coal - Acute EC50 0.18to 0.31 ppmFresh water

Daphnia - Waterflea - Daphniamagna - LARVAE

48 hours

- Acute EC500.048 to 0.5 ppmFresh water

Daphnia - Waterflea - Daphniamagna - LARVAE

48 hours

- Acute LC50 0.9to 1.23 ppmFresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss

96 hours

- Acute LC50 0.64to 0.7 ppm Freshwater

Fish - Bluegill -Lepomismacrochirus

96 hours

- Acute LC50 0.43to 0.5 ppm Fresh

Fish - Rainbowtrout,donaldson

96 hours

Product/ingredient name Test SpeciesResult Exposure

Page 8: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 8/137/9/2010.

ECOLOGICAL INFORMATION12.water trout -

Oncorhynchusmykiss

- Acute LC50 3.13ppm Fresh water

Fish - Bluegill -Lepomismacrochirus

96 hours

- Acute LC50 2 to2.4 ppm Freshwater

Fish - Bluegill -Lepomismacrochirus

96 hours

ethylbenzene - Acute EC5013300 to 18100ug/L Fresh water

Crustaceans -Brine shrimp -Artemia sp. -Nauplii

48 hours

- Acute EC50 6530to 9460 ug/LFresh water

Crustaceans -Brine shrimp -Artemia sp. -Nauplii

48 hours

- Acute EC50 2970to 4400 ug/LFresh water

Daphnia - Waterflea - Daphniamagna - Neonate

48 hours

- Acute EC50 2930to 4400 ug/LFresh water

Daphnia - Waterflea - Daphniamagna - Neonate

48 hours

- Acute LC5013300 to 18100ug/L Fresh water

Crustaceans -Brine shrimp -Artemia sp. -Nauplii

48 hours

- Acute LC50 150to 200 mg/LFresh water

Fish - Bluegill -Lepomismacrochirus -Young of the year- 0.32 to 1.2 g

96 hours

- Acute LC50 9600ug/L Fresh water

Fish - Guppy -Poecilia reticulata

96 hours

- Acute LC50 9100to 11000 ug/LFresh water

Fish - Fatheadminnow -Pimephalespromelas - 30days - 0.079 g

96 hours

- Acute LC50 9090to 11000 ug/LFresh water

Fish - Fatheadminnow -Pimephalespromelas - 28 to32 days - 19.5mm - 0.088 g

96 hours

- Acute LC50 8780to 13700 ug/LFresh water

Crustaceans -Brine shrimp -Artemia sp. -Nauplii

48 hours

- Acute LC50 280to 290 ppmMarine water

Fish -Sheepsheadminnow -Cyprinodonvariegatus -Juvenile(Fledgling,Hatchling,Weanling) - 8 to15 mm

96 hours

- Acute LC50>5200 ug/LMarine water

Crustaceans -Opossum shrimp- Americamysisbahia

48 hours

Page 9: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 9/137/9/2010.

ECOLOGICAL INFORMATION12.- Acute LC50 5100

to 5700 ug/LMarine water

Fish - Atlanticsilverside -Menidia menidia

96 hours

- Acute LC50 4200ug/L Fresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss

96 hours

- Acute LC5013900 to 17200ug/L Fresh water

Daphnia - Waterflea - Daphniamagna - Neonate

48 hours

- Acute LC5040000 ug/LMarine water

Crustaceans -Dungeness oredible crab -Cancer magister- Zoea

48 hours

- Acute LC5075000 to 120000ug/L Fresh water

Daphnia - Waterflea - Daphniamagna

48 hours

- Acute LC5018400 to 25400ug/L Fresh water

Daphnia - Waterflea - Daphniamagna - Neonate

48 hours

- Acute LC50 4.3to 4.7 ul/L Marinewater

Fish - Stripedbass - Moronesaxatilis -Juvenile(Fledgling,Hatchling,Weanling) - 6 g

96 hours

- Chronic NOEC88 ppm Marinewater

Fish -Sheepsheadminnow -Cyprinodonvariegatus -Juvenile(Fledgling,Hatchling,Weanling) - 8 to15 mm

96 hours

- Chronic NOEC3300 ug/L Marinewater

Fish - Atlanticsilverside -Menidia menidia

96 hours

xylene - Acute LC50 8.5ppm Marinewater

Crustaceans -Daggerbladegrass shrimp -Palaemonetespugio - Adult

48 hours

- Acute LC5013500 to 15034ug/L Fresh water

Fish - Bluegill -Lepomismacrochirus - 0.9g

96 hours

- Acute LC5013500 to 19200ug/L Fresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss - 0.9 g

96 hours

- Acute LC5013400 ug/L Freshwater

Fish - Fatheadminnow -Pimephalespromelas - 31days - 18.4 mm -0.077 g

96 hours

- Acute LC50 Fish - Bluegill - 96 hours

Page 10: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 10/137/9/2010.

ECOLOGICAL INFORMATION12.13300 to 16114ug/L Fresh water

Lepomismacrochirus - 1.1g

- Acute LC5012000 to 16114ug/L Fresh water

Fish - Bluegill -Lepomismacrochirus - 1.1g

96 hours

- Acute LC5012000 to 13762ug/L Fresh water

Fish - Bluegill -Lepomismacrochirus - 1.1g

96 hours

- Acute LC50 8600to 9591 ug/LFresh water

Fish - Bluegill -Lepomismacrochirus - 0.9g

96 hours

- Acute LC50 8500ug/L Marinewater

Crustaceans -Daggerbladegrass shrimp -Palaemonetespugio

48 hours

- Acute LC50 8200to 10032 ug/LFresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss - 0.6 g

96 hours

- Acute LC50 3300to 4093 ug/LFresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss - 0.6 g

96 hours

- Acute LC5013500 to 16100ug/L Fresh water

Fish - Bluegill -Lepomismacrochirus - 1.1g

96 hours

methanol - Acute EC5022200 to 23400mg/L Fresh water

Daphnia - Waterflea - Daphniaobtusa - Neonate

48 hours

- Acute EC5024500000 to29350000 ug/LFresh water

Daphnia - Waterflea - Daphniamagna - LARVAE

48 hours

- Acute EC5013000000 to13400000 ug/LFresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss - Juvenile(Fledgling,Hatchling,Weanling) -0.813 g

96 hours

- Acute EC5012700000 to13700000 ug/LFresh water

Fish - Bluegill -Lepomismacrochirus -Juvenile(Fledgling,Hatchling,Weanling) - 3.07g

96 hours

- Acute EC50>10000000 ug/LFresh water

Daphnia - Waterflea - Daphniamagna - 6 to 24hours

48 hours

- Acute LC50 Fish - Bluegill - 96 hours

Page 11: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 11/137/9/2010.

ECOLOGICAL INFORMATION12.

Other adverse effects : No known significant effects or critical hazards.

15400000 to17600000 ug/LFresh water

Lepomismacrochirus -Juvenile(Fledgling,Hatchling,Weanling) - 3.07g

- Acute LC50 19 to20 ml/L Freshwater

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss - 0.8 g

96 hours

- Acute LC50 3289to 4395 mg/LFresh water

Daphnia - Waterflea - Daphniamagna - Neonate

48 hours

- Acute LC5010000000 to33000000 ug/LMarine water

Fish - Hooknose -Agonuscataphractus -Adult

96 hours

- Acute LC5020100000 to20700000 ug/LFresh water

Fish - Rainbowtrout,donaldsontrout -Oncorhynchusmykiss - Juvenile(Fledgling,Hatchling,Weanling) -0.813 g

96 hours

- Acute LC502500000 ug/LMarine water

Crustaceans -Common shrimp,sand shrimp -Crangon crangon- Adult

48 hours

- Acute LC50>100000 ug/LFresh water

Fish - Fatheadminnow -Pimephalespromelas -Juvenile(Fledgling,Hatchling,Weanling) - 0.2 to0.5 g

96 hours

- Acute LC5028200000 ug/LFresh water

Fish - Fatheadminnow -Pimephalespromelas - 0.12 g

96 hours

- Acute LC5028000000 ug/LMarine water

Fish - Bleak -Alburnusalburnus - 8 to 10cm

96 hours

- Acute LC50>28000000 ug/LMarine water

Fish - Bleak -Alburnusalburnus - 8 cm

96 hours

Conclusion/Summary : Not available.

Page 12: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 12/137/9/2010.

DISPOSAL CONSIDERATIONS13.The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable productsvia a licensed waste disposal contractor. Disposal of this product, solutions and anyby-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authorityrequirements. Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers.

:Methods of disposal

ADR/RID Class

14.International transport regulations

UN1263 - Paint, Paintrelated Material,Flammable

3 III

IMDG Class UN1263 - Paint, Paintrelated Material,Flammable. Marinepollutant (tar, coal)

3 III

UN1263 - Paint, Paintrelated Material,Flammable

1263IATA Class 3

TRANSPORT INFORMATION

3UN1263 - Paint, Paintrelated Material,Flammable

III1263

Regulatoryinformation

UN number Proper shipping name Classes PG* Label

III

1263

1263

ADNR Class

PG* : Packing group

Additionalinformation

-

-

Marine pollutant

-

REGULATORY INFORMATION15.

Safety phrases S53- Avoid exposure - obtain special instructions before use.

R10- Flammable.R45- May cause cancer.

Hazard symbol or symbols

Risk phrases

Contains

:

:

:

:

Product use Industrial applications.:

Toxic

tar, coal

OTHER INFORMATION

7/9/2010.

History

16.

Date of printing :

:National Fire ProtectionAssociation (U.S.A.)

Health

Flammability

Instability/Reactivity

Special

31 0

Page 13: MSDS-02590801 Asian Coal Tar Epoxy

Date of issue/Date of revision : 13/137/9/2010.

OTHER INFORMATION16.Date of issue/ Date ofrevision

Version

Information contained in this material safety data sheet is believed to be reliable and given in good faith,but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for aparticular application or results to be obtained from them.The user of this material decides what safety measures are necessary to safely use this material, either aloneor in combination with other materials.Asian Paints Limited makes no warranties expressed or implied in respect of the adequacy of this document forany particular purpose.

Disclaimer

Date of previous issue

:

:

:

Indicates information that has changed from previously issued version.

7/9/2010.

No previous validation.

1

ASIAN COAL TAR EPOXY PAINT BLACK