M/s.Astik Dyestuff Pvt. Ltd., Ankleshwar ANNEXURE I …environmentclearance.nic.in/writereaddata/FormB/TOR/Additional... · ANNEXURE I TERMS OF REFERENCE As per MoEF & CC guideline

M/s.Astik Dyestuff Pvt. Ltd., Ankleshwar

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar 1

ANNEXURE I

TERMS OF REFERENCE

As per MoEF & CC guideline with 5 km study area.



ANNEXURE II

LIST OF DIRECTORS

Name of Director Address Telephone Number

Designation

Mr. C.B. KARKERA 402, Bhimsen Chs Ltd, Vishal Nagar, Malve Road, Malad (W) Mumbai

09821240311 M.D.

Mr. R.D. AJEKAR 52,Royal Accord 4, Lokhandwala Complex, Nr Swami Samarth Mandir, Andheri (W) Azad Nagar Mumbai 400053

09821029879 M.D.

Mr. MITHUN AJEKAR

52,Royal Accord 4, Lokhandwala Complex, Nr Swami Samarth Mandir, Andheri (W) Azad Nagar Mumbai 400053

09820270769 Director

Mr. S.B. Shetty A-402, Seven Star, Jairaj Nagar, Vazira Naka, Opp. Amezon Complex, Borivali (W) Mumbai

09821118867 Director

15.77 MT.

10

.7

7 M

T.

5.1

1 M

T.

2.63 MT.

15.77 MT.

20

.7

7 M

T.

10

.2

7M

T.

2.8

6 M

T.

15.77 MT.

6.13 MT.

10

.7

7 M

T.

5.1

1 M

T.

2.63 MT.

15.77 MT.

10

.7

7 M

T.

5.1

1 M

T.

2.63 MT.

15.77 MT.

20

.7

7 M

T.

10

.2

7M

T.

AREA TABLE

-TOTAL PLOT OF AREA [P-707/B]

1

SQ.MT

6641.80

13557.90

2 COMMON PLOT REQUIRED. 8%

COMMON PLOT PROVIED

NET TOTAL PLOT OF AREA [1-2]

PRE. BUILT UP AREA ON GF. 50%

1084.63

1025.80

12473.27

6236.63

PERMISIBLE F.S.I - 1:1.60

EXISTING APPROVED AREA

REVISED AREA

PROPOSED AREA

FLOOR B/U AREA

19957.23

4853.58

1624.42

BASAMENTS AREA

GROUND FLOOR AREA

MAZANINE FLOOR AREA

FIRST FLOOR AREA

SECOND FLOOR AREA

THIRD FLOOR AREA

FOURTH FLOOR AREA

FIFTH FLOOR AREA

SIXTH FLOOR AREA

STAIR CABIN AREA FSI. LESS

TOTAL BUILT UPAREA

46.60

2734.69

373.23

1488.95

638.39

346.55

346.55

183.28

183.28

45.28

6389.71

FSI COSUMED

PARKING AREA

/ 12473.270.512

1022.44

TOTAL PLOT OF AREA, [P-707/B-C]

- TOTAL PLOT OF AREA [P-707/C]6916.10

6389.71

3

3

4

5

6

7

8

9

-

-

-

-

-

-

10

11

12

-

-

-

-

STR. NO-16, AREA CALC

FLOOR

GF

GF

L

15.77

2.63

B

21.04

5.11

NOS.

1

1

TOTAL

15.77

2.63

GF TOTAL AREA IN M2

FF TOTAL AREA IN M2

345.24

345.24

SF

SF

SF

15.77

2.63

6.13

10.77

5.11

2.86

1

1

1

169.84

13.44

17.53

SF TOTAL AREA IN M2 200.81

TF

TF

15.77

2.63

10.77

5.11

1

1

169.84

13.44

TF TOTAL AREA IN M2

4TH TOTAL AREA IN M2



183.28

183.28

183.28

183.28

DRAWING SHEET NO:- 1 OF 2

PROPOSED FACTORY BUILDING

PLAN ON PLOT NO:- 707/B+C,

AT - G.I.D.C. ESTATE, ANKLESHWAR

DIST-BHARUCH

FOR. "M/S ASTIK DYE-STUFF PVT.LTD.

RESIDENCE BUILDINGS BUILT UP AREA STATEMAN IN SQ.MT.

STR.NONAME OF BUILDINGS

FLOOR REM ARKSAPPROVED PROPOSED TOTAL

1 FACTORY BUILDING

BASEMENT AREA1-A

GF

FF

824.54

46.60

557.83

112.28

160.49

260.95

260.95

231.46

231.81

240.25

240.25

163.27

163.27

SF

GF

GF

FF

GF

FF

SF

TF

MAZANINE FLOOR

FACTORY BLENDER

NEW STORE STAIR+OTTA

SPRAY DRAYER

4TH 163.27

MAZANINE FLOOR

2

3

4

STAIR CABIN

O/H WATER TANK

STRC

STRC

22.64

22.64

824.54

46.60

557.83

112.28

160.49

260.95

260.95

231.46

231.81

240.25

240.25

163.27

163.27

163.27

22.64

22.64

EXISTING WORK

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-5

6

7

8

9

D.G. SET ROOM

ELECTRICAL ROOM

COOLING TOWER

L.D.O. TANK

OFFICE BUILDING

GF

GF

GF

GF

GF

33.77

29.00

22.88

73.5

113.82

10

11

12

13

14

15

16

WATCH MAN CABIN

UNDER GROUND WATER TANK

UTILITY BUILDING

E.T.O.-A

E.T.P.-B

SOLID WASTE STORAGE

SPRAY DRYER PLANT

FF

SF

GF

GF

GF

GF

GF

GF

GF

113.82

113.82

10.00

35.16

88.56

290.4

91.29

135.06

345.24

33.77

29.00

22.88

73.50

113.82

113.82

113.82

10.00

35.16

88.56

290.40

-

-

-

-

-

-

-

-

-

-

135.06

DELLETE WORKD

EXISTING WORK

PROPOSED WORKD

FF

SF

TF

4TH

5TH

6TH

NET TOTAL B/U AREA IN SQ.MT. 4853.58

345.24

200.81

183.28

183.28

183.28

345.24

345.24

200.81

183.28

183.28

183.28

183.28 183.28

1624.42 6386.71

-

-

-

-

-

-

707/B 707/CASTIK DYE-STUFF

PVT. LTD.

707/D

707/A

707/6

709 708 708/D 450/1

450/2

428

2303/B

2303A

2302/11209J

A

1209J1208J12111105

1210

1106B1106A

1106/C

16.00 MT. WIDE G. I. D. C.ROAD EAST-15

20.00 MT. WIDE G. I. D. C. ROAD EAST-12

16.00M.ROAD

16.00

MT.

WID

E RO

AD

KHADI

KHADI

KHADI

KHAD

I

KHAD

I

KHADI

5021804

ROAD

SOUTH-8

1108/C

( SCALE : 1 CM = 20 MT. )

17.62 7.65

4.5054.81

L B

NOS. TOTAL

340.00

1

301.00

134.79

246.65

34.00 10.00

1

1

1

1022.44

1.20

0.8

0

2.00M

T.

0.35

0.23

N

GATE

T.

12 OFFICEBUILDING

GREEN BELT

PARKING - III

3.50 MT. WIDE ROAD 3.50 MT. WIDE APPROACH ROAD

COMMON PLOT

NEW STORE

FACTORYBUILDING

FACTORY BLENDER

SPRAYDRYER

PROPOSED

SOLIDWASTE

STORAGE

8

5

4.50 MT. WIDE APPROACH ROAD

16.00 MT. WIDE G. I. D. C. ANKLESHWAR INTERNAL ROAD

PLOT NO. 707 / C6916.10SQ.MT.

SITE PLAN( SCALE : 1 CM = 5.00 MT. )

42.50 X 10.00 =425.00M²

30.50 X 35.60 =1035.80M²

30.50 MT.

RWH

17.62 X7.65=134.79M²

10

9

7.90

SOCK PIT

10.23

5.00

18.23 MT.

1

15.23

RWH

1.80

6

4.52

3

5.18 12.45

3.00

RWH

52.00MT. 42.5MT.

2

15 4.85

1.60 2.28

2.88

2.28

4.09

3.00

15.50

1A

PLOT NO.-707/B6641.80SQ.MT.

5.00

7

3.00

GREEN BELT673.32SQ.MT.

GREEN BELT376.00SQ.MT.

11.65 MT.

3.50 MT. WIDE APPROACH ROAD

17.20MT.

17.20 X 10.00 =172.00M²GREEN BELT

GATE

RWH



ANNEXURE IV

LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY

SR.

NO.

NAME OF PRODUCTS QUANTITY

(MT/ MONTH)

EXISTING TOTAL AFTER

PROPOSED

EXPANSION

REACTIVE DYES 130 1000

1 Reactive Blacks

2 Reactive Blues

3 Reactive Reds

4 Reactive Violets

5 Reactive Yellows

6 Reactive Golden Yellows

7 Reactive Navy Blues

8 Reactive Oranges

9 Reactive Red Browns

10 Reactive Greens

Total 130* 1000*

*The quantity refer is for crude dyes. These dyes are further diluted and standardized as per

market requirement. The final sellable quantity will be increase by 30-35%. Unit has obtained

CTE:81761, from GPCB for 200 MT/Month. Copy of CTE is attached as Annexure-XIII.



ANNEXURE- V

OVERALL RAW MATERIAL SCENARIO

Sr.

No.

Raw Material Quantity (MT/Month)

Existing Total after Proposed

Expansion

1 Oil HS (Turkey Red Oil Sulphonated) 0.093 0.731

2 Acetic Anhydride 0.48 3.774

3 Aniline 2,4 Disulphonic Acid 0.9 7.055

4 Aniline 2,5 Disulphonic Acid 0.25 1.955

5 Acetyl MPDSA

(3- amino acetanilide-4-sulphonic

acidd)

4.0 31.552

6 3 Amino 4 Methoxy Acetanilide

(3AMA) 0.016 0.1258

7 4 Amino Diphenylamine 2-

Sulphonic acid (ADAPSA) 0.021 0.1649

8 6 Acetyl amino 2-amino phenol 4-

Sulphonic Acid (6AAPSA) 0.2 1.564

9 Ammonia 0.02 0.1564

10 Blue 198 BASE 0.93 7.293

11 Benzidine Disulphonic Acid (BDSA) 0.034 0.272

12 Cynuric Chloride 5.99 47.005

13 Copper Sulphate 0.26 2.04

14 Caustic Soda Lye 3.0 23.46

15 Common Salt 0.27 2.125

16 C ACID

(2-napathylamine 4,8 Disulphonic

Acid)

0.03 0.238

17 2,5 DMAVS

(2,5 Dimethoxy aniline vinylphone

Ester)

2.48 19.465

18 4,4’-Diamino Stilbene-2, -2’-

disulphonic acid (DASDA) 0.27 2.125

19 Disodium Phosphate 0.01 0.085

20 2-Ethyl Hexanol 0.52 4.08

21 Dedusting Oil/Sauradust Oil 1.98 15.538

22 4 Sulpho Anthranalicacid Hydrazone 0.45 3.536

23 H-ACID (1-Amino 8-Hydroxy

napthalyne 3,6’ Disulphonic Acid 11.84 92.905

24 Hydrochloric Acid (HCL) 14.1 110.636

25 J-ACID (2, Amino-8-Hydroxy-

Naptholene 6-Sulphonic Acid) 0.8 6.256

26 K-ACID (2-Napthilamine 3,6,8

Trisulphonic acid 0.26 2.04

27 1,3-Meta phynelene Diamine 4-

Sulphonic Acid (MPDSA) 2.21 17.34



28 Metauriodo Aniline (MUA) 0.15 1.19

29 Metanilic Acid 0.39 3.06

30 N-ethyl Para Base Ester (EPBE) 0.1 0.782

31 Meta Base Vinyl Sulphone Ester

(MBVS) 0.51 3.995

32 N-Ethyl Meta Base Ester (EMBE) 0.08 0.629

33 Orthanilic Acid (OA) 0.33 2.584

34 Orthophynelene Diamine (OPD) 0.015 0.119

35 Ortho Toluedene 5-Sulphonic Acid

(OT5SA) 0.017 0.136

36 Ortho anesidine Vinyl Sulphone 2.45 19.227

37 2-Ethyl Hexanol 0.2 1.564

38 2-Pyridone 0.544 4.267

39 Para Crysidine Vinyl Sulphone Ester

(PCVS) 1.99 15.606

40 Para Phenylene Diamine Disulphonic

Acid (PPDDSA) 0.1 0.782

41 1(4-Sulphopheynl)3Methyl 5-

parazalone (SPCP) 1.44 11.305

42 1(4-Sulphopheynl) 3-carboxy 5-

parazalone (SPCP) 3.54 16.34

43 Soda Ash 3.63 27.778

44 Sodium Bicarbonate 19.42 152.371

45 Sodium Sulphate 35.6 279.31

46 Sulpho Tobias Acid (STA) 0.682 5.355

47 Sodium Nitrite 6.823 53.55

48 Sulpho J-ACID (2, Amino-8-

Hydroxy-Naptholene 4,6-Disulphonic

Acid)

0.1 0.782

49 Sulpho Para Vinyl Sulphone Ester 0.32 2.516

50 Sulfo Ortho anesidine Vinyl Sulphone

Ester 0.03 0.238

51 Sulfamic Acid 0.051 0.408

52 Sulfanilic Acid 0.015 0.119

53 Sodium Loryl Sulphate (SLS) 0.06 0.476

54 S.D. OIL 2000/1000 0.43 3.366

55 Vinyl Sulphone Ester 20.85 163.591

56 3,5 Diamino Benzoic Acid 0.1 0.782

57 2,Methyl amino -8-Hydroxy 6

Naptholene Sulphonic Acid (NMJ

Acid)

0.2 1.581

58 N-Ethyl Aniline 0.005 0.0391

Total 151.586 1177.3652



Raw material of some representative products:

Sr.

No.

Name of Product Capacity Name of Raw Material Raw Material

qty. (MT/M)

1. BLACK BG/H CONC

And/OR

1000

MT/month

Vinyl Sulphone 316

Antifoam 2

Sulfamic Acid 1

H Acid 172

SPD Oil 5

DDC Oil 10

Hydrochloric Acid 83

Sodium Nitrite 78

Sodium Bi Carbonate 147

Sodium Sulphate 335

Total 1139

2. BLUE HFGN

And/Or

1000

MT/month

Cynauric Chloride 176

Oil HS 3

Aniline 2,5 Di Sulpho

Acid

239

Meta Base Ester 296

Antifoam 5

Blue 198 Base 250

SPD Oil 5

DDC Oil 10

Soda Ash 200

Sodium Sulphate 37


Caustic Soda 32


Total 1323

3. RED F3B

And/Or

1000

MT/month Oil HS 1

Cynauric Chloride 95

Vinyl Sulphone 143

H Acid 164

Sulpho Tobais Acid 158

Antifoam 2

Sulfamic Acid 1

SPD Oil 3

DDC Oil 10



Sodium Nitrite 35



Sr.

No.

Name of Product Capacity Name of Raw Material Raw Material

qty. (MT/M)

Sodium Sulphate 321

Total 1210

4. YELLOW F3R

And/Or

1000

MT/month

Oil HS 1

Vinyl Sulphone 131

Cynauric chloride 86

Antifoam 3

SPD Oil 4

DDC Oil 10

K Acid 184

MUA HCL 70

Sulfamic Acid 1


Hydrodchloric Acid 111

Sodium Sulphate 328

Sodoum Nitrite 32

Total 1171



ANNEXURE- VI

BREIF MANUFACTURING PROCESS:

GENERAL MANUFACTURING PROCESS OF REACTIVE DYESTUFF

Reactive Dyestuff intermediate aromatic amine is diazotised using hydrochloric acid and

sodium nitrite in aqueous medium and coupled with coupling components like H- acid, J-

acid, acetylated H-acid or J-acid, Metaurido aniline etc. using caustic soda/Soda Bicarbonate/

Soda Ash for adjustment of reaction pH conditions. Generally these reactions are carried at 0-

10 oC. Dyestuffs thus obtained are sometimes directly spray dryed and packed. Sometimes

additional reactions like cyanuration with Cyanuric chloride and condensation reaction with

reactive vinyl sulphone esters are carried. The dyestuffs thus obtained in solution form is

spray dryed and packed. Many times these Dyestuff clear solutions are passed through nano-

filtration systems for concentration purposes (for increasing solid content. The crude powder

obtained from spray dryer blended with Globour salt to make final finished product.



GENERAL MANUFACTURING PROCESS FLOW DIAGRAM:

1 2

3

5

6 7

8

9



1.0 REACTIVE BLACKS

1.1 BLACK BG H CONC

Proecess Discription

Vinyl sulphone is diazotized and coupled with H acid and spray dryer.

Chemical Reaction

Material Balance:



2.0 REACTIVE BLUES

2.1 BLUE HEGN:

Process: Aniline 2.4 Disulphonic Acid is cynurated & condensed with Blue 198 Base &

Spray dried.

Chemical Reaction

Material Balance:

2.2 BLUE 3R: H-Acid is acetylated coupled with 2,5 DMAVS Diazo, metal complexed with

copper sulphate and spray dried.

2.3 BLUE F4R: 4-ADAPSA Diazo,is coupled with H-Acid, cyanurated condensed with



vinyl sulphone ester and spray dried.

2.4 BLUE HERD: 4 sulpho Anthranilic acid hydrozone is coupled with 6-AAPSA diazo

product obtained is complexed with Copper Sulphate.The mass filtered Wet Caked

hydrolised and base is condensed with cynurated Metanilic Acid & with cynurated PPDDSA.

Product obtained & Spray dried.

2.5 BLUE FBRL: 4 sulpho Anthranilic acid hydrozone is coupled with 6-AAPSA diazo

product obtained is complexed with Copper Sulphate.The mass filtered Wet Caked

hydrolised and base is condensed with N Ethyl Meta Base Ester.

2.6 BLUE HFGN: Aniline 2.5 Disulphonic Acid is cynurated & condensed with Blue 198

Base and with Meta Base Vinyl sulphone Ester.

2.7 BLUE DS3B/FBS: - MPDSA cynurated condensed with vinyl Sulphone. Product

diazotized & coupled with H Acid, Product again coupled with Sulfo Tobias Acid & spray

dried.

2.8 BLUE FGBD: MPDSA cynurated condensed with Meta Base Ester. Product diazotized

& coupled with H Acid, Product again coupled with Sulfo Tobias Acid & spray dried.

2.9 : BLUE BB : 4 Sulpho Anthronalic Acid Hydrozone is coupled with sulpho OAVS Ester

and product is complexd with copper sulphate and spray dried.

3.0 REACTIVE RED

3.1 RED F3B:

Process: Vinyl Sulphone is cynurated and condensed with H Acid, product obtained coupled

with Sulfo Tobias Acid & spray dried.

Chemical Reaction:



Material Balance:

3.2 RED FBS: Cynurated H-Acid is condensed with H Acid. The product coupled with

Vinyl Sulphone diazo & spray dried.

3.3 RED FRB: Cynurated H-Acid is coupled with vinyl sulphone diazo, & condensed with

vinyl sulphone and spray dried.

3.4 RED HE3B: Cynurated H-Acid is coupled with orthanilic acid diazo, & condensed with

PPD and spray dried.

3.5 RED 5B: Acetyl H-Acid is coupled with vinyl sulphone ester diazo and spray dried.

3.6 RED F3GL: Vinyl Sulphone is cynurated & condensed with MPDSA product diazotized

& coupled with Acetyl H Acid & Spray dried.

3.7 RED H7BL: Acetyl H Acid is coupled with diazotized PCVS & spray dried.

3.8 RED DS4B: Vinyl Sulphone Ester is dizotised and coupled with MPDSA and then

condensed with Red M8B & product spray dried.

3.9 RED RB: H Acid is cynurated & coupled with diazotized Vinyl Sulphone. Product

condensed with Metanalic Acid & Spray dried.

3.10 RED F2B: Orthanilic Acid is diazotized coupled with Cynurated H Acid & condensed

with Vinyl Sulphone & spary dried.

3.11 CRIMSON SEL: H-Acid is acetylated & coupled with Sulfo Tobias acid Diazo,

hydrolyzed and isolated. The wet cake is cynurated & then condensed with OPD and sprays

dried.

3.12 RED DSGD CONC : Red M8B is condensed with H-acid and product obtained is

coupled with dizotised Para Base V.S. Ester and Spray dried.

3.13 MAROON CLD : PCVS Ester and Sulpho Para V.S. Ester are dizotised and coupled



with j acid and spray dried.

3.14 BRILL RED DSGR : Sulpho Tobais Acid dizotised and coupled with Acetyl H-acid

product obtained is hydrolised, Cynaurated and condensed with reactive G.Yellow R product

obtained is spray dried.

4.0 REACTIVE VIOLETS

4.1 VIOLET 5R : Vinyl sulphone Ester is dizotised and coupled with Acetyl H-acid and

product obtained is subjected to oxidative coppering and product obtained is Sprary dried.

5.0 REACTIVE YELLOW

5.1 YELLOW F3R: K-Acid is diazotized and coupled with MUA & Cynurated and

condensed with vinyl sulphone ester and sprays dried.

Chemical Reaction



Material Balance:

5.2 YELLOW HE4R: K-Acid is diazotised and coupled with MUA & Cynurated and

condensed with BDSA and spray dried.

5.3 YELLOW F4G: Cynurated MPDSA is diazotised, coupled with 2-Pyridone &

condensed with VS ester and spray dried.

5.4 YELLOW H4G:- Cynurated MPDSA diazo coupled with SPCP and & condensed with

DASDA and spray dried.

5.5 YELLOW 15 (GR):- PCVS diazo is coupled with SPMP and spray dried.

5.6 YELLOW DS5R: K-Acid is diazotized and coupled with MUA & Cynurated and

condensed with G Yellow R and spray dried.

5.7 YELLOW SEL: C Acid diazotized coupled with 3AMA product is cynurated &

condensed with OPD & sprays dried.

5.8 YELLOW HE4G:- cynurated MPDSA diazotized & coupled with SPCP. Products are

condensed with DASDA & spray dried.

5.9 YELLOW FG CONC: Para Base V.S. Ester is dizotised & coupled with SPCP and

Product obtained is Spray dried.

5.10 YELLOW BROWN DSBR: MPDSA is cynurated and condensed with MPDSA and

Product obtained is dizotised and coupled with MPDSA. Product obatained is again coupled

with dizotised Para Base V.S. Ester product obtained is spray dried.

5.11 YELLOW WNN : Sulpo Para V.S. Ester and Para V.S. Ester diazotized and coupled

with MPDSA and the product obtained is spry dried.

5.12. YELLOW 2RW : Para Base V.S. Ester (2Moles) diazotized and coupled with MPDSA

and product obtained is spray dried.



6.0 REACTIVE GOLDEN YELLOW

6.1 GOLDEN YELLOW R: Vinyl Sulphone diazotized coupled with MPDSA & Spray

dried.

6.2 GOLD YELLOW RN: Vinyl Sulphone ester is diazotized and coupled with Acetyl

MPDSA, and spray dried.

7.0 REACTIVE NAVY BLUE

7.1 NAVY BLUE 2G: Vinyl Sulphone Ester and DMAVS are dizotised and coupled with H

acid and Spray dried.

7.2 NAVY SEL: Cynurated MPDSA condensed with OT5SA product is diazotized &

coupled with H Acid & spray dried.

7.3 NAVY RGB: Vinyl Sulphone Ester and OAVS Ester are dizotised and coupled with H

acid and Spray dried.

8.0 REACTIVE ORANGE

8.1 ORANGE MIX: Vinyl Sulphone diazotized & coupled with J Acid & Spray dried.

8.2 Orange 2R :- Vinyl Sulphone diazotized & coupled with sodium Napthionate & Spray

dried.

8.3 Orange WNN : Sulpho Para V.S. Ester and Vinyl Sulphone Ester are dizotied and

coupled with J acid & Spray dried.

9.0 Acid Green:- Schffers Acid is dizotised and complexed with Ferric Chloride product

obtained is spray dried.

Followings products are mixtures of above colours

1. BLACK WRS:- It is a mixture of Reactive Black BG H Conc and Reactive Orange Mix

and reactive G. Yellow R.

2. BLACK WNN CONC:- It is a mixture of Reactive Black BG H Conc and Reactive

Orange WNN and Reactive Yellow WNN.

MAROON PBS:- It is a mixture of Reactive Red FBS and Reactive G. Yellow R.

RED RGB:- It is mixture of Reactive Red RB and Reacitve Red F3B.

RED P3RB:- It is mixture of Reactive Red F3B and G. Yellow R.

SUPRA RED P5BR:- It is a mixture of Reactive Red FBS and G. Yellow R.

YELLOW RGB:- It is a mixture of Reactive Yellow F3R and G. Yellow RN.

OLIVE GREEN P3G:- It is a mixture of Reactive N. Blue 2G and Reactive Yellow FG.



ORANGE P3R:- It is a mixture of Reactive Red F3b and G. Yellow R.

RED BBLC CONC:- It is a mixture of Reactive Red F3GL and Reactive Red H7BL.



ANNEXURE- VII

DETAILS OF WATER CONSUMPTION

DETAILS OF WASTE WATER GENERATION

Sr.No. Particulars Waste Water Generation in KL/Day

Quantity as per

CCA: AWH-69150

in KLD

Quantity as per

Proposed for EC

in KLD

Quantity After

Expansion in KLD

1 Domestic 20 10 30

2 Boiler 0 0 0

3 Washing 40 55 95

4 Process 5 30 35

TOTAL 65 95 160

Remark: Till NCT start taking extra hydraulic load, unit will maintain existing discharge

quantity. Unit will install RO for recycling of effluent. After getting proper permission from

NCT/GPCB, effluent quantity will increase and recycling will be stopped.

Sr.

No.

Particular Water Consumption in KL/Day

Quantity as per

CCA: AWH-69150

in KLD

Quantity as per

Proposed for EC

in KLD

Quantity After

Expansion in

KLD

1. Domestic 20 10 30

2. Industrial

a) Process 25 110 135(45 fresh+90

recycle)

b) Boiler 10 20 30

c) Cooling 0 5 5

d) Washing 40 55 95

e) Gardening +

Other

0 5 5

Total

(Domestic +

Industries)

95 205 300(210 fresh+90

recycle)



WATER BALANCE DIAGRAM

(As per existing CCA)

Process

25 KL/Day

Water Requirement

95 KL/Day

Domestic

20 KL/Day

Boiler

10 KL/Day

Washing

40 KL/Day

ETL 65 KL/Day

Sewage

20 KL/Day

Washing

effluent

40 KL/Day

Effluent from

process

5 KL/Day

Loss

20 KL/Day



WATER BALANCE DIAGRAM AFTER EXPANSION

RO permeate will be recycled in process and RO reject will be sent to spray dryer.

Process

135 KL/Day

Water Requirement

300 KL/Day

(210 fresh + 90 recycle)

Domestic

30 KL/Day

Boiler

30 KL/Day

Washing

95 KL/Day

ETP 65 KL/Day

Sewage

30 KL/Day

Washing

effluent

95 KL/Day

Effluent from process

35 KL/Day

RO

95 KL/Day

RO Permeate

90 KL/Day

RO reject

5 KL/Day

Manufacturing

165 KL/Day

Spray Dryer

135 KL/Day

Gardening

5 KL/Day

Cooling

Tower

5 KL/Day

5KL

130 KL



ANNEXURE-VIII

EFFLUENT TREATMENT PROCESS:

M/s. Astik Dyestuff Pvt. Ltd. has an Effluent Treatment Plant (ETP) comprising of Primary

and Secondary treatment followed by Tertiary treatment.

Washing effluent from reaction vessels cleaning ,press cleaning , spray drier cleaning and

from bathing comes to Oil and Grit separator and then into equalization tank.(Approx.800 –

900mg/lit COD) , Equalization’s tanks COD is adjusted to 1300 – 1500 mg/lit by dosing the

required quantity of Nano filtrations permuit solution. Then pH is adjusted to 3.5 with

Sulphuric Acid. This solution is passed in between two assemblies of static mixtures at the

rate of 4 KL/hr where dosing of FeSO4 - 25 % solution and H2O2 -50 % solution is feed at

desired rate. The outlet of static mixture then enters into reaction tanks – 2 nos. and then

passed into neutralizer tanks where lime slurry is pumped with continuous monitoring and

outlet effluent with pH 7.0 – 8.0. This solution enters into flocculator where polyelectrolyte

solution dosing is done. The outlet of flocculator enters into setting tanks. The overflow of

setting tanks then passed into aeration tanks. The aeration tanks overflow effluent passed

through sand filter. The outlet of sand filter discharged through discharge tank. Treated

effluent is discharged into GIDC underground drainage system leading to inlet of M/s.

Narmada Clean Tech Ltd. (NCT), Ankleshwar for further treatment and its ultimate disposal

to deep sea through NCT pipeline.

The sludge from the setting tanks is filtered through filter press No. 1 to 3 the sludge obtained

after unloading filter press is dried in sludge drying bed and sent to TSDF site of M/s.

Bharuch Enviro Infrastructure Ltd. (BEIL), Ankleshwar for disposal.

NAME AND SIZE OF ETP UNITS (EXISTING)

SL. NO. DESCRIPTION CAPACITY EXISTING (KL)

1 Oil and Grit Separators 1

2

Equalization Tank (ET) 48

Storage Tanks (NT1+NT2) 32

3 Static Mixtures (1 &2 ) Dosing points on online treatment

4 Reaction Tank-1

Reaction Tank-2

6.5

2.5

6 Neutralizer 2.5

7 Flocculator 2.5

8 SETLLING TANK NO.1 10

9. SETLLING Sintex Tank –No.1 10

10 SETLLING Sintex Tank –No.2 10

11 Aeration Tank 20

13 Storage Tank 12

14 Sand Filter --




15 Discharged Tank 100

16 Filter Press 3 Nos.

17 Dosing Pumps 3 Nos.

NAME AND SIZE OF ETP UNITS (PROPOSED)


1 Oil and Grit Separators 2

2

Equalization Tank (ET) 96

Storage Tanks (NT1+NT2) 64

3 Static Mixtures (1 &2 ) Dosing points on online treatment

4 Reaction Tank-1

Reaction Tank-2

13

5

6 Neutralizer 5

7 Flocculator 5

8 SETLLING TANK NO.1 20

9. SETLLING Sintex Tank –No.1 20

10 SETLLING Sintex Tank –No.2 20

11 Aeration Tank 40

13 Storage Tank 24

14 Sand Filter --

15 Discharged Tank 10

16 Filter Press 6 Nos.

17 Dosing Pumps 6 Nos.

STAGEWISE PERFORMANCE OF ETP PROCESS

STAGE Equalization Static

Mixture

Settling Aeration Sand

Filter

Discharge

Tank

COD 1300-1500 1300-

1500

700-900 400-500 300-400 300-400

PH 6-7 3-4 7-8 7-8 7-8 7-8

TDS 5000 5000 11000 7000 7000 7000

TSS 500-600 500-600 400-500 100-200 100-200 50-100



EFFLUENT TREATMENT PLANT FLOW DIAGRAM

Change the digram

1. OIL & GRIT SEPARATOR

Aeration Tank

FeSO4 -25 % sol.

H2O2 - 50 % sol. Lime Slurry

Polyelectrolyte Soln.

To FETP of NCTL, Ankleshwar for

further treatment and final

disposal.

Filter Press Filter Press Filter Press

Raw Effluent

Sludge Drying Bed To TSDF of BEIL, Ankleshwar for disposal Sludge

H2SO4 -70 % soln.



ANNEXURE-IX

ELECTRICITY AND FUEL CONSUMPTIONS

Sr.

No.

Particulars Existing

Quantity as

CCA

Proposed

Quantity

Total

Quantity

after

Expansion

Source

1. Natural Gas 166 SM3/hr 564 SM3/hr 730 SM3/hr Gujarat

Gas

2. Diesel 40 liter/hr 0 40 liter/hr Local

3. Energy-

Electricity

300 KVA 150 KVA 450 KVA DGVCL



ANNEXURE- X

DETAILS OF FLUE GAS EMISSIONS

SR.

NO

SOURCE

OF

EMISSION

TYPE OF

EMISSION

STACK

HEIGHT

(METER)

STACK

DIAMETER

(METER)

FUEL

NAME

AND Qty.

POLLUTION

CONTROL

EQUIPMENT

Exising

1 Boiler

PM

SO2

NOx

15 0.35 Natural Gas

50 SM3/hr -

2

Hot Air

Generator of

Spray

Dryer-1

PM

SO2

NOx

25 0.375 Natural Gas

90 SM3/hr Wet Scrubber

3

Hot Air

Generator of

Spary

Dryer-2

PM

SO2

NOx



Proposed

4

Hot Air

Generator of

Spary

Dryer-3

PM

SO2

NOx



5

Hot Air

Generator of

Spary

Dryer-4

PM

SO2

NOx



6

D.G. Set -

200 KVA

(emergency

used only)

PM

SO2

NOx

10 0.15 LDO

40 Liter/hr -

PROCESS EMISSION

There is no process emission. There will be no process emission due to proposed

expansion.

M/s. Astik Dyestuff Pvt. Ltd., Ankleshwar


ANNEXURE- XI

DETAILS OF HAZARDOUS WASTE

SR.

NO.

NAME OF

THE

WASTE

CATEGORY

WASTE

GENERATING

PROCESS /

STEP

STATE

QUANTITY

MODE OF DISPOSAL

EXISTING ADDITIONAL TOTAL

1 ETP Sludge 34.3 Effluent

Treatment

Semi

solid/Solid

75 MT/Annum

75 MT/Annum 150

MT/Annum

Collection and Storage

within premises &

Transportation and

Disposal at TSDF of

BEIL, Ankleshwar

2 Used Oil 5.1 Maintenance and

used lubricant oil

generated from

Maintenance

Activities

Liquid 0.36 KL/Annum

0.14 KL/Annum

0.5 KL/Annum

Collection and Storage

within premises &

Disposal by selling to

registered re-processor

3 Discarded

Containers/

Bags/Liners

33.3 Manufacturing

and Utilities

Solid 3030

Nos./Annum

6000 Nos./Year

9030

Nos./Annum

Collection, Storage and

Decontamination within

premises & Disposal by

selling to authorized re-

cycler



ANNEXURE- XII

LIST OF HAZARDOUS CHEMICAL

STORAGE DETAIL OF HAZARDOUS CHEMICAL EXISTING

SR.

NO

NAME OF

HAZARDOUS

MATERIAL

QUANTITY

MAX. THAT

CAN BE

STORED

PLACES

OF ITS

STORAGE

NO. OF

STORAGES

OPERATING

PRESSURE

&

TEMP.

TYPE OF

HAZARDS

POSSIBLE

(FIRE, EXPLOSIVE,

TOXIC RELEASE,

SPILLAGE ETC.

CONTROL

MEASURES

PROVIDED

1 Acetic

anhydride

1.0 MT Drums 05 # (HDPE

200 Ltr.

Drum)

Atm pressure,

Ambient temp

Fire

Leakage / Spillage Drums are stored

on pallet with the

suitable trap.

Fire hydrant

system

Flame proof

fittings

Avoid direct sunlight

2 Caustic Lye 4.0 MT Tank Farm

area

01 #

(M.S.

Storage

Tank)

Atm pressure,

Ambient temp

---- Dyke around the

tank is provided.

Fire Extinguishers

and Fire hydrant

system

3 Hydrochloric

Acid

10.0 MT Tank Farm

area

01 # (FRP

Storage

Tank)

Atm pressure,

Ambient temp

Corrosive,

Leakage / Spillage Dyke around the

tank will be

provided.

Fire Extinguishers

and Fire hydrant

system



4 Sulphuric Acid

(70%) for ETP

2.0 MT Carbouys 33 # (HDPE

60 Ltrs

Carbouys)

Atm pressure,

Ambient temp

Corrosive,

Leakage / Spillage Carbouys will be

stored on pallet with

the suitable trap.

Fire Extinguishers

& Fire Hydrant

system

5 Hydrogen

Peroxide for

ETP


60 Ltrs

Carbouys)

Atm pressure,

Ambient temp

Toxic Carbouys will be

stored on pallet with

the suitable trap.

Fire Extinguishers

& Fire Hydrant

system

6 Ammonia for

Ice plant

0.5 MT Tank

(Horizontal)

1 # 10kg/Cm2

Ambient temp

Toxic Water jet spray

provided for

scrubbing



STORAGE DETAIL OF HAZARDOUS CHEMICAL EXISTING

SR.

NO

NAME OF

HAZARDOUS

MATERIAL

QUANTITY

MAX.

THAT

CAN BE

STORED

PLACES

OF ITS

STORAGE

NO. OF

STORAGES

OPERATING

PRESSURE

&

TEMP.

TYPE OF

HAZARDS

POSSIBLE

(FIRE,

EXPLOSIVE,

TOXIC

RELEASE,

SPILLAGE

ETC.

CONTROL MEASURES

PROVIDED

1 Acetic

anhydride

3.0 MT Drums 05 # (HDPE

200 Ltr.

Drum)

Atm pressure,

Ambient temp

Fire

Leakage /

Spillage

Drums are stored on pallet

with the suitable trap.

Fire hydrant system

Flame proof fittings

Avoid direct sunlight

2 Caustic Lye 12.0 MT Tank Farm

area

01 #

(M.S.

Storage

Tank)

Atm pressure,

Ambient temp

---- Dyke around the tank is

provided.

Fire Extinguishers and Fire

hydrant system

3 Hydrochloric

Acid

20.0 MT Tank Farm

area

01 # (FRP

Storage

Tank)

Atm pressure,

Ambient temp

Corrosive,

Leakage /

Spillage

Dyke around the tank will be

provided.

Fire Extinguishers and Fire

hydrant system

4 Sulphuric Acid

(70%) for ETP


60 Ltrs

Carbouys)

Atm pressure,

Ambient temp

Corrosive,

Leakage /

Spillage

Carbouys will be stored on

pallet with the suitable trap.

Fire Extinguishers & Fire

Hydrant system

5 Hydrogen

Peroxide for

ETP


60 Ltrs

Carbouys)

Atm pressure,

Ambient temp

Toxic Carbouys will be stored on

pallet with the suitable trap.

Fire Extinguishers & Fire

Hydrant system



6 Ammonia for

Ice plant

2.0 MT Tank

(Horizontal)

1 # 10kg/Cm2

Ambient temp

Toxic Water jet spray provided for

scrubbing



Documents

M/s.Astik Dyestuff Pvt. Ltd., Ankleshwar ANNEXURE I …environmentclearance.nic.in/writereaddata/FormB/TOR/Additional... · ANNEXURE I TERMS OF REFERENCE As per MoEF & CC guideline