M/S. AARTI INDUSTRIES LTD. - environmentclearance.nic.in · environmental impact assessment report of m/s. aarti industries ltd. (al chemie organics division) for manufacturing of

ENVIRONMENTAL IMPACT ASSESSMENT REPORT

OF

M/S. AARTI INDUSTRIES LTD.

(ALCHEMIE ORGANICS DIVISION)

FOR

MANUFACTURING OF DYE/DYE INTERMEDIATES

& PESTICIDES PRODUCTS

EXISTING SITE

PLOT NO. 902 & 923 , PHASE -III ,

GIDC , VAPI, DIST. VALSAD , GUJARAT .

PREPARED BY

M/s. JYOTI OM CHEMICAL RESEARCH

CENTRE PVT.LTD.

Shed No. K -1, 7705/2,3,4 GIDC ESTATE,

Ankleshwar - 393002

Phone: (02646)220293; Fax: (02646)239454

Website:www.jyotiom.com

Email: [email protected]

www.jyotiom.com

TABLE OF CONTENTS

SR.

NO.

CONTENTS PAGE

NO.

CHAPTER -1 INTRODUCTION

1.1 PURPOSE OF THE REPORT AND REGULATORY FRAMEWORK 1.1

1.2 IDENTIFICATION OF THE PROJECT AND PROJECT PROPONENT 1.2

1.3 KEY INFORMATION OF PROJECT 1.6

1.3.1 IMPORTANCE AND JUSTIFICATION OF PROJECT 1.6

1.3.2 NATURE OF THE PROJECT 1.7

1.3.3 COST OF THE PROJECTAND TIME OF COMPLETION 1.7

1.3.4 SITE SELECTION 1.8

1.3.5 LOCATION OF THE PROJECT 1.8

1.4 SALIENT FEATURES 1.8

1.5 REGULATORY FRAMEWORK 1.9

1.6 SCOPE AND OBJECTIVE OF EIA STUDY 1.9

1.7 STRUCTURE OF EIA REPORT 1.10

1.8 TERMS OF REFERENCE AND ITS COMPLIANCE 1.13

CHAPTER - 2 PROJECT DESCRIPTION

2.1 TYPE OF PROJECT 2.1

2.2 NEED FOR THE PROJECT 2.2

2.3 DETAILS OF PRODUCTS AND RAW MATERIAL 2.2

2.3.1 DETAILS OF PRODUCT 2.2

2.3.2 DETAILS OF RAW MATERIAL 2.4

2.3.3 TRANSPORTATION OF RAW MATERIAL AND FINISHED 2.12

2.4 PROCESS DESCRIPTION 2.16

2.4.1 MANUFACTURING PROCESS 2.16

2.5 DETAILS OF SOLVENT RECOVERY SYSTEM & ITS

MANAGEMENT

2.64

2.6 RESOURCE REQUIREMENT 2.64

2.6.1 INFRASTRUCTURE FACILITIES (LAND) 2.64

2.6.2 WATER REQUIREMENT 2.67

2.6.3 ENERGY REQUIREMENT 2.71

2.6.4 UTILITIES 2.72

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2.6.5 MAN POWER 2.73

2.6.6 EQUIPMENTS/MACHINERIES 2.73

2.7 POLLUTION POTENTIAL SCENARIO 2.77

2.7.1 EFFLUENT AND SEWAGE GENERATION 2.78

2.7.2 GASEOUS EMISSION 2.78

2.7.3 HAZARDOUS WASTE GENERATION 2.80

CHAPTER - 3 BASELINE ENVIRONMENT STATUS

3.1 INTRODUCTION 3.1

3.2 WINDROSE 3.4

3.3 AIR ENVIRONMENT 3.6

3.4 WATER ENVIRONMENT 3.13

3.5 NOISE ENVIRONMENT 3.20

3.6 SOIL 3.21

3.6.1 BASELINE DATA 3.21

3.7 LAND USE PATTERNS 3.23

3.8 BIOLOGICAL ENVIRONMENT & SOCIO –ECONOMICENVIRONMENT

3.26

3.8.1 ECOLOGICAL INFORMATION 3.26

3.8.2 FOREST 3.26

3.8.3 FLORA 3.26

3.8.4 FAUNA 3.30

3.9 SOCIO-ECONOMIC ENVIRONMENT 3.31

3.9.1 DEMOGRAPHIC DATA WITHIN THE REGION OF INTEREST 3.31

3.9.2 LITERACY RATE 3.36

3.9.3 OCCUPATIONAL STRUCTURE 3.40

3.10 EARTHQUAKE VULNERABILITY 3.51

3.11 WIND AND CYCLONE VULNERABILITY 3.51

CHAPTER - 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS

4.1 IDENTIFICATION OF IMPACT 4.1

4.2 PREDICTION AND ASSESSMENT OF IMPACT 4.8

4.2.1 WATER ENVIRONMENT 4.8

4.2.2 AIR ENVIRONMENT 4.8

4.2.3 NOISE ENVIRONMENT 4.19

4.2.4 LAND ENVIRONMENT 4.19

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4.2.5 ECOLOGICAL ENVIRONMENT 4.20

4.2.6 INFRASTRUCTURE AND SERVICES 4.20

4.2.7 SOCIO-ECONOMIC IMPACT 4.21

4.3 IMPACT MATRIX 4.21

CHAPTER - 5 ENVIRONMENT MONITORING PROGRAM

5.1 POLLUTION MONITORING AND SURVEILLANCE SYSTEM 5.1

CHAPTER -6 QUANTITATIVE RISK ASSESSMENT & DISASTER MANAGEMENT

PLAN

6.1 SCOPE OF THE STUDY 6.1

6.2 INTRODUCTION TO RISK ASSESSMENT 6.2

6.2.1 OBJECTIVES OF RISK ASSESSMENT 6.2

6.3 RISK ASSESSMENT 6.10

6.3.1 QUALITATIVE RISK ASSESSMENT 6.11

6.3.2 QUANTITATIVE RISK ASSESSMENT 6.21

6.4 COMMENTS / RECOMMENDATIONS BASED ON CONSEQUENCE

ANALYSIS

6.59

6.4.1 SAFETY SYSTEMS/SAFEGUARDS TO REDUCE THE RISK OF

FIRE, EXPLOSION AND TOXIC RELEASE:

6.59

6.5 AREA SPECIFIC RECOMMENDATIONS BASED ON

QUALITATIVE RISK ASSESSMENT (SUMMARIZED):

6.67

6.6 DISATER PREPAREDNESS & EMERGENCY MANAGEMENT

PLAN

6.67

6.6.1 DEFINING THE NATURE/LEVEL OF EMERGENCY 6.68

6.6.2 OBJECTIVES OF EMERGENCY MANAGEMENT SYSTEM 6.68

6.6.3 STRUCTURE OF EMERGENCY MANAGEMENT SYSTEM 6.71

6.7 OCCUPATIONAL HEALTH & SAFETY PROGRAMME 6.80

6.7.1 OCCUPATIONAL HEALTH 6.80

6.7.2 HOSPITAL FACILITIES & FACTORY MEDICAL OFFICER 6.80

6.7.3 FACTORY MEDICAL OFFICER/OHC 6.80

6.7.4 PERIODIC MEDICAL EXAMINATION 6.81

6.7.5 DETAILS OF EXISTING OCCUPATIONAL AND SAFETY

HAZARDS

6.81

6.7.6 ACTION PLAN FOR THE IMPLEMENTATION OF OHS

STANDARDS AS PER OSHAS/USEPA

6.81

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6.7.7 MEASURES ADOPTED BY COMPANY TO KEEP AIR BORNE

CONCENTRATION OF HAZARDOUS CHEMICALS BELOW PEL:

6.81

6.7.8 WORKPLACE MONITORING ARRANGEMENTS FOR

HAZARDOUS CHEMICALS

6.82

6.7.9 HEALTH EVALUATION OF WORKERS (EXPOSURE SPECIFIC) 6.83

6.7.10 ACTION PLAN FOR SAFE HANDLING & SAFETY SYSTEM 6.83

6.7.11 PLAN AND FUND ALLOCATION TO ENSURE THE

OCCUPATIONAL HEALTH & SAFETY OF ALL CONTRACT AND

CASUAL WORKERS

6.84

6.7.12 ARRANGEMENTS FOR ENSURING HEALTH AND SAFETY OF

WORKERS ENGAGED IN HANDLING OF TOXIC MATERIALS

6.86

6.7.13 MOCK DRILLS 6.86

6.8 TOXIC MANEGEMENT PLAN 6.86

6.9 TREATMENT OF WORKERS AFFECTED BY ACCIDENTAL

SPILLAGE CHEMICAL

6.87

CHAPTER- 7 PROJECT BENEFIT

7.1 SOCIO ECONOMIC ACTIVITIES 7.1

7.2 OTHER TANGIBLE BENEFITS 7.2

7.3 EMPLOYMENT POTENTIAL 7.2

7.4 ACTION PLAN 7.2

7.5 BUDGETARY ALLOCATION 7.3

CHAPTER- 8 ENVIRONMENT MANAGEMENT PLAN

8.1 INTRODUCTION 8.1

8.2 AIM AND OBJECTIVE 8.1

8.3 ENVIRONMENTAL MANAGEMENT CELL 8.2

8.4 ENVIRONMENT MANAGEMENT PLAN 8.3

8.4.1 OPERATIONAL PHASE 8.3

8.4.2(A) AIR ENVIRONMENT 8.3

8.4.2(B) WATER ENVIRONMENT 8.6

8.4.2(C) NOISE ENVIRONMENT 8.17

8.4.2(D) LAND ENVIRONMENT 8.18

8.4.2(E) GREEN BELT DEVELOPMENT 8.21

8.4.2(F) VEHICULAR POLLUTION CONTROL 8.21

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8.4.2(G) ENERGY CONSERVATION PROGRAMME 8.22

8.4.2(H) BUDGETORY PROVISION PROPOSED FOR ENVIRONMENT

POLLUTION CONTROL MEASURES

8.22

8.4.2(I) HEALTH AND SAFETY 8.23

CHAPTER- 9 COMPLIANCE OF ENVIRONMENTAL CONDITIONS9.1 INTRODUCTION 9.1

9.1.1 SHOW CAUSE NOTICE REF. NO.1- GPCB/CCA-VSD-32/ID:22980/119661 DATED 27/07/12.

9.1

9.1.2 SHOW CAUSE NOTICE REF. NO. 2-SCN-132094 DATED 11/12/12. 9.1

9.1.3 SHOW CAUSE NOTICE REF. NO. 3- SCN-144490 DATED20/04/2013.

9.2


9.2


9.2

9.1.6 SHOW CAUSE NOTICE REF. NO. 6- GPCB/VSD/ID-22980/211658DATED 29/04/2014

9.2


9.2

CHAPTER- 10 EXECUTIVE SUMMARY& CONCLUSION

10.1 INTRODUCTION 10.110.1.1 LOCATION 10.110.1.2 INVESTMENT 10.210.1.3 INFRASTRUCTURE FACILITIES 10.210.2 PROJECT DESCRIPTION 10.210.2.1 NEED FOR THE PROJECT 10.210.2.2 PRODUCTION AND RAW MATERIAL 10.210.2.3 RESOURCE REQUIREMENT 10.310.2.4 POLLUTION POTENTIAL SCENARIO 10.310.3 BASELINE ENVIRONMENT STATUS 10.410.3.1 STUDY AREA INCLUDED IN ENVIRONMENTAL SETTING 10.410.3.2 CLIMATE OF THE STUDY AREA 10.510.3.3 AMBIENT AIR QUALITY 10.510.3.4 WATER QUALITY 10.510.3.5 NOISE ENVIRONMENT 10.610.3.6 SOIL 10.610.3.7 LAND USE OF THE STUDY AREA 10.610.3.8 BIOLOGICAL ENVIRONMENT 10.610.4 IDENTIFICATION &ASSESSMENTOF IMPACT 10.610.4.1 WATER ENVIRONMENT 10.610.4.2 AIR ENVIRONMENT 10.710.4.3 NOISE ENVIRONMENT 10.7

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10.4.4 LAND ENVIRONMENT 10.810.4.5 ECOLOGICAL ENVIRONMENT 10.810.4.6 INFRA STRUCTURE AND SERVICES 10.810.4.7 SOCIO-ECONOMIC IMPACT 10.910.5 ENVIRONMENT MONITORING PROGRAM 10.910.6 RISK ASSESSMENT AND DISASTER MANAGEMENT PLAN 10.910.6.1 RISK ASSESSMENT 10.910.6.2 DISASTER MANAGEMENT PLAN 10.910.6.3 OCCUPATIONAL HEALTH AND SAFETY MANAGEMENT

SYSTEM10.9

10.7 PROJECT BENEFITS 10.1010.8 ENVIRONMENTAL MANAGEMENT PLAN 10.10CHAPTER- 11 DISCLOSURE OF CONSULTANT ENGAGED

11.1 SALIENT FEATURES 11.111.2 SERVICES PROVIDED BY THE CENTRE 11.211.3 OUTSTANDING ACHIVEMENTS 11.211.4 STATUS OF NABET ACCREDITATION 11.311.5 DECLARATION BY CONSULTANT 11.4

LIST OF TABLES

TABLE NO. TABLE NAME PAGE NO.


1.1 DETAILS REGARDING DIRECTORS 1.2

1.2 LIST OF PRODUCTS AS PER CCA 1.4

1.3 LIST OF PRODUCTS AS PER PROPOSED SCENARIO 1.5

1.4 CAPITAL COST PROJECTION 1.7

1.5 SALIENT FEATURES OF THE PROJECT SITE 1.9

1.6 STRUCTURE OF EIA REPORT 1.11

1.7 TERMS OF REFERENCE PROPOSED BY UNIT 1.13

1.8 ADDITIONAL TOR GIVEN BY INDUSTRIAL COMMITTEE OFMOEF

1.15


2.1 PROPETIES OF PRODUCTS 2.2

2.2 DETAILS OF EXISTING RAW MATERIALS CONSUMPTION 2.4

2.3 DETAILS OF PROPOSED RAW MATERIALS CONSUMPTION 2.7

2.4 DETAILS OF RAW MATERIAL SOURCE AND METHOD OF 2.12


TRANSPORTATION

2.5 DETAILS OF SOLVENT RECOVERY 2.64

2.6 DETAILS OF INFRASTRUCTURE 2.65

2.7 LAND USE BREAK UP OF TOTAL PLOT AREA 2.65

2.8 DETAILS OF WATER CONSUMPTION 2.68

2.9 FUEL CONSUMPTION REQUIREMENT 2.71

2.10 ENERGY REQUIREMENT 2.71

2.11 DETAILS OF EXISTING UTILITIES 2.72

2.12 DETAILS OF PROPOSED UTILITIES 2.72

2.13 MAN POWER REQUIREMENT 2.73

2.14 DETAILS OF EQUIPMENT AND MACHINERIES 2.73

2.15 DETAILS OF WASTE WATER GENERATION 2.78

2.16 DETAILS OF FLUE GAS EMISSION 2.78

2.17 DETAILS OF PROCESS EMISSION 2.79

2.18 DETAILS OF PROCESS GASES SEND TO SRUBBER 2.80

2.19 DETAILS OF HAZARDOUS WASTE GENERATION 2.80


3.1 LIST OF MAJOR INDUSTRIES IN THE VAPI 3.2

3.2 METEOROLOGICAL DATA 3.4

3.3 DETAILS OF SAMPLING LOCATION OF AMBIENT AIR

QUALITY MONITORING

3.7

3.4 AMBIENT AIR QUALITY STATUS OF STUDY AREA 3.8

3.5 DETAILS OF GROUND WATER MONITORING LOCATIONS 3.14

3.6 DETAILS OF SURFACE WATER MONITORING LOCATIONS 3.15

3.7 METHOD OF ANALYSIS 3.15

3.8 WATER QUALITY PARAMETERS (GROUNDWATER

SOURCES)

3.17

3.9 WATER QUALITY PARAMETERS (SURFACE WATER

SOURCES)

3.19

3.10 CPCB RECOMMENDATIONS FOR COMMUNITY NOISE

EXPOSURE (1989)

3.20

3.11 NOISE LEVEL DATA 3.21

3.12 LOCATIONS OF SOIL QUALITY MONITORING WITH

RESPECT TO THE PROJECT SITE

3.22


3.13 PARTICLE SIZE DISTRIBUTION OF SOIL SAMPLES 3.23

3.14 LAND USE STATISTICS OF THE STUDY AREA 3.23

3.15 LIST OF FLORA 3.26

3.16 LIST OF FAUNA 3.30

3.17 DEMOGRAPHIC DATA 3.32

3.18 LITERACY RATE WITHIN 10 KM RADIAL DISTANCE

OF STUDY AREA

3.36

3.19 OCCUPATIONAL STRUCTURE 3.41

3.20 DISTRIBUTION OF WORKERS 3.46


4.1 DETAILS OF PROCESS EMISSION 4.10

4.2 CONCENTRATION OF PM 4.11

4.3 CONCENTRATION OF NOX 4.11

4.4 CONCENTRATION OF HCL AND CL2 4.12

4.5 CONCENTRATION OF HBr AND Br 4.12

4.6 ENVIRONMENT IMPACT MATRIX (WITH MITIGATION

MEASURES)

4.23

4.7 CUMULATIVE IMPACT CHART 4.25

CHAPTER - 5 ENVIRONMENT MONITORING PROGRAM

5.1 EMISSION MONITORING PLAN 5.1

CHAPTER -6 RISK ASSESSMENT

6.1 DETAILS OF HAZARDOUS RAW MATERIALS 6.5

6.2 HAZARDOUS PROPERTIES OF CHEMICALS 6.8

6.3 RISK MATRIX FOR QUALITATIVE RISK ASSESSMENT 6.12

6.4 RISK MATRIX FOR QUALITATIVE RISK ASSESSMENT 6.12

6.5 STORAGE AND HANDLING OF TOXIC LIQUID CHEMICAL 6.13

6.6 STORAGE AND HANDLING OF FLAMMABLE

CHEMICALS(LIKE TOLUNE, XYLENE, MCB, etc.)

6.14

6.7 STORAGE AND HANDLING OF SOLID CHEMICALS 6.17

6.8 STORAGE AND HANDLING OF HYDROCHLORIC ACID

(30%)

6.18

6.9 STORAGE AND HANDLING OF CAUSTIC SODA LYE (48%) 6.20

6.10 DAMAGES TO HUMAN LIFE DUE TO HEAT RADIATION 6.22


6.11 EFFECTS DUE TO INCIDENT RADIATION INTENSITY 6.22

6.12 WEATHER DATA USED FOR THE STUDY 6.24

6.13 SCENARIOS IDENTIFIED FOR CONSEQUENCE ANALYSIS 6.25

6.14 SCENARIO#1 – RELEASE OF TOLUENE (FULL BORE

RUPTURE OF UNLOADING HOSE 2”)

6.27

6.15 SCENARIO#2 – RELEASE OF MONO CHLOROBENZENE 6.30

6.16 SCENARIO#3 – RELEASE OF XYLENE (FULL BORE

RUPTURE OF UNLOADING HOSE 2”)

6.34

6.17 SCENARIO#4 – RELEASE OF HYDROGEN GAS 6.38

6.18 SCENARIO#5 – RELEASE OF TRIETHYL AMINE 6.42

6.19 SCENARIO#6 – RELEASE OF CHLORINE 6.47

6.20 RESULTS 6.47

6.21 SCENARIO#7 – RELEASE OF BROMINE 6.50

6.22 RESULTS 6.50

6.23 SCENARIO#8 – RELEASE OF AMMONIA FROM AMMONIA

CYLINDER STORAGE AREA

6.52

6.24 RESULTS 6.52

6.25 SCENARIO#9 – RELEASE OF DIMETHYL SULPHATE FROM

PUMP DISCHARGE LINE

6.54

6.26 RESULTS 6.55

6.27 FLASH FIRE SCENARIOS 6.56

6.28 LATE POOL FIRE SCENARIOS 6.56

6.29 JET FIRE SCENARIOS 6.57

6.30 EXPLOSION OVERPRESSURE SCENARIOS 6.57

6.31 TOXIC RELEASE SCENARIOS: (FOR Cl2 & NH3) 6.58

6.32 TOXIC RELEASE SCENARIOS :( FOR Br & DIMETHYL

SULPHATE)

6.58

6.33 SAFETY PRECAUTIONS 6.60

6.34 RIGHT RESPIRATOR IS USED AS PER THE CHLORINE

CONCENTRATION

6.64

6.35 FIRE PROTECTION EQUIPMENTS 6.66

6.36 DETAILS OF FIRE EXTINGUISHERS 6.66

6.37 LIKELY ONSITE EMERGENCIES 6.69

6.38 LIKELY OFF SITE EMERGENCIES 6.69


CHAPTER- 7 PROJECT BENEFIT

7.1 ACTION PLAN 7.2


8.1 DETAILS OF CONTROL MEASURES FOR FLUE GAS

EMISSION AND PROCESS EMISSION

8.4

8.2 DETAILS OF CONTROL MEASURES FOR FUGITIVE

EMISSION

8.5

8.3 DETAILS OF EXISTING ETP UNITS 8.11

8.4 DETAILS OF PROPOSED ETP UNITS 8.12

8.5 DETAILS OF POWER COSUMPTION 8.12

8.6 DETAILS OF ETP TANKS 8.13

8.7 DETAILS OF ETP PUMPS 8.13

8.8 EXISTING CHARACTERISTICS OF WASTEWATER BEFORE

TREATMENT & AFTER TREATMENT

8.14

8.9 EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE

TREATMENT & AFTER TREATMENT

8.14

8.10 DETAILS OF DIFFERENT STP UNITS 8.14

8.11 DETAILS OF CONTROL MEASURES FOR EFFLUENT AND

SEWAGE GENERATION

8.16

8.12 DETAILS OF CONTROL MEASURES FOR NOISE POLLUTION 8.17

8.13 DETAILS OF HAZARDOUS WASTE GENERATION &

DISPOSAL MODE

8.19

8.14 DETAILS OF HAZARDOUS WASTE STORAGE 8.21

8.15 CAPITAL COST AND RECURRING COST FOR

ENVIRONMENT CONTROL MEASURES

8.22

LIST OF FIGURES

FIGURE

NO.

FIGURE NAME PAGE NO.


1.1 LOCATION OF PROJECT SITE 6

1.2 GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT

LOCATION WITH IN 5 KM

7

1.3 GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT

LOCATION WITH IN 0.5 KM

8

1.4 IMAGE OF ALL FOUR CORNERS OF THE SITE 9

1.5 SITE PLAN OF MEGHNAGAR 10


2.1 WATER BALANCE DIAGRAM (EXISTING) 2.69

2.2 WATER BALANCE DIAGRAM (PROPOSED EXPANSION) 2.70


3.1 WIND ROSE DIAGARM FOR PEROID OF MARCH TO MAY 2014 3.5

3.2 WIND CLASS FREQUENCY DISRTIBUTION 3.6

3.3 LOCATION OF AMBIENT AIR QUALITY MONITORING

STATIONS

3.7

3.4 LOCATION OF GROUND WATER QUALITY MONITORING

STATIONS

3.13

3.5 LOCATION OF SURFACE WATER QUALITY MONITORING

STATIONS

3.14

3.6 LOCATION OF NOISE MONITORING STATIONS 3.20

3.7 LOCATION OF SOIL MONITORING STATIONS 3.22

3.8 LAND COVER MAP WITH VILLAGE LOCATION 3.25

3.9 MAP OF RESERVED FOREST 3.29

3.10 EARTHQUAKE VULNERABILITY MAP 3.51

3.11 WIND AND CYCLONE VULNERABILITY MAP 3.51


4.1 IMPACT NETWORK ON AIR ENVIROENMENT 4.2

4.2 IMPACT NETWORK ON NOISE ENVIRONMENT 4.3

4.3 IMPACT NETWORK ON WATER ENVIRONMENT 4.4

4.4 IMPACT NETWORK ON GROUND WATER ENVIRONMENT 4.5

FIGURE

NO.


4.5 IMPACT NETWORK ON SOCIO-ECONOMIC AND CULTURAL

ENVIRONMENT

4.6

4.6 IMPACT NETWORK ON LAND ENVIRONMENT 4.7

4.7 ISOPLETHS OF NOX (SITE COORDINATES 0, 0) 4.13

4.8 ISOPLETHS OF PM (SITE COORDINATES 0, 0) 4.14

4.9 ISOPLETHS OF HCl (SITE COORDINATES 0, 0) 4.15

4.10 ISOPLETHS OF Cl2 (SITE COORDINATES 0, 0) 4.16

4.11 ISOPLETHS OF HBr (SITE COORDINATES 0, 0) 4.17

4.12 ISOPLETHS OF Br (SITE COORDINATES 0, 0) 4.18

CHAPTER -6 RISK ASSESSMENT

6.1 DETAILS OF STORAGE FACILITIES 6.4

6.2 RISK CONTOURS FOR FLASH FIRE 6.28

6.3 RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION

(OVERPRESSURE RESULTS)

6.28

6.4 RISK CONTOURS FOR LATE POOL FIRE 6.29




6.32



6.9 RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION(OVERPRESSURE RESULTS)

6.36


6.11 RISK CONTOURS FOR FLASH FIRE; 6.39



6.40

6.13 RISK CONTOURS FOR JET FIRE 6.41

6.14 RISK CONTOURS FOR TOXIC DISPERSION OF TEA FOR LEL

CONCENTRATON

6.43




6.44


6.18 RISK CONTOURS FOR CHLORINE (FOR IDLH 6.46

FIGURE

NO.


CONCENTRATIONS: 10 PPM)

6.19 RISK CONTOURS FOR CHLORINE (FOR LC50

CONCENTRATIONS: 293 PPM)

6.48

6.20 RISK CONTOURS FOR DISPERSION OF BROMINE FOR IDLH &

LC50 CONCENTRATIONS:

6.49

6.21 RISK CONTOURS FOR DISPERSION OF AMMONIA FOR IDLH:

300 PPM

6.51

6.22 RISK CONTOURS FOR DISPERSION OF AMMONIA FOR LC50:

2000 PPM

6.53

6.23 RISK CONTOURS FOR DISPERSION OF DMS FOR IDLH & LC50

CONCENTRATIONS

6.55

6.24 ON SITE/OFF SITE DISASTER CONTROL PLAN 6.70


8.1 FLOW DIAGRAM OF ENVIRONMERNTAL MANAGEMENT

CELL

8.2

8.1 EXISTING EFFLUENT TREATMENT PLANT FLOW DIAGRAM 8.9

8.2 EFFLUENT TREATMENT PLANT FLOW DIAGRAM (PROPOSED

EXPANSION)

8.10

8.3 FLOW DIAGRAM OF STP 8.15

LIST OF ANNEXURE

ANNEXURE

NO.

ANNEXURE NAME

I COPY OF EC-JULY 2003

II COPY OF EC-JULY 2008

III COMPLIANCE REPORT OF EC (FROM BHOPAL) DOCUMENT

IV COPY OF CCA

V CCA COMPLIANCE

VI GPCB REPORTS OF WATER AND WASTE WATER

VII THIRD PARTY MONITORING REPORT

ANNEXURE

NO.

ANNEXURE NAME

VIII QUESTIONNAIRE

IX PLANT LAYOUT AND SITE PLAN

X(A) SITE LOCATION MAPS

X(B) TOPOSHEET OF PROJECT SITE

X(C) 10km RADIAS DISTANCE FROM THE PROJECT SITE

X(D) CO-originate SHOW LATTITUDE LONGITUDE OF FOUR CORNER

X(E) GOOGLE MAP -EARTH

XI COPY OF TOR

XII LAND POSSESSION DOCUMENT

XIII WATER CONSUMPTION LETTER (ADDITIONAL)

XIV PHOTOGRAPHS OF PLANT AREAS

XV METEOROLOGICAL DATA

XVI MONITORING DATES FOR AMBIENT AIR MONITORING

XVII SOP FOR HANDLING HAZARDOUS WASTE

XVIII ENVIRONMENT HEALTH SAFETY POLICY

XIX DRAWINGS OF SCRUBBERS

XX MEMBERSHIP CERTIFICATE OF TSDF SITE

XXI MSDS OF PRODUCTS AND RAW MATERIALS

XXII COMPLIANCE REPORT OF EXISTING UNIT BY MOEF, BHOPAL.

XXIII SHOW CAUSE NOTICE AND REPLY.

XXIV GUJARAT HIGH COURT STAY ORDER.

XXV UNDERTAKING OF JYOTI OM / CONSULTANT

XXVI WORKER REPORTS

XXVII UNDERTAKING NO BOND PESTISIDES

XXVIII PROVISIONAL MEMBER CERTIFICATE FROM RSPL FOR WASTE MIX

PROCESSING FACILITY

XXIX RECOMMENDATION LETTER SUBMITED TI SPCB FOR PROPOSED

ACTIVITY

XXX EXECUTIVE SUMMARY

ENVIRONMENT IMPACT ASSESSMENT REPORT M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC, VAPI.

M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 1

Chapter -1 INTRODUCTION

1.1 PURPOSE OF THE REPORT AND REGULATORY FRAMEWORK M/s. Aarti Industries Ltd. (Alchemie Organics Division) is located at plot no.902, 923, GIDC Estate, Phase-III, Vapi, and District: Valsad, Gujarat. The unit has valid CCA order AWH-53342, issue on dated 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. Existing manufacturing involves unit operations like hydrogenation, diazotization, bromination, condensation and chlorination products. Total existing production capacity is 5595 MT/Year. The unit has proposed expansion for manufacturing of products by hydrogenation, diazotization, bromination, condensation and chlorination. Also, the unit has proposed new products based on hydrolysis. After expansion, total production capacity will be 17378.17 MT/Year. The unit has proposed expansion of existing unit. The products proposed by the unit fall in the schedule attached to the EIA Notification, i.e. Project No. 5(b) &5(f), Dye/Dye intermediates & Pesticides products. Since the project is established in industrial Estate, Vapi, and it is located within 10 Km distance from interstate boundary of Gujarat & Union Territories (Daman and Dadar& Nagar haveli) so it is classified as Category A project. Public hearing is not applicable to this expansion project as the unit is located in GIDC notified area. Environment Clearance will be evaluated by the Industrial committee of MoEF, New Delhi. The purpose of this report is to: Establish a pre-project baseline with respect to environmental indicators. Identify environment related impacts Evaluate safety related risk factors associated with project Propose appropriate mitigation measures for minimizing the adverse impacts to

the extent possible Suggest Environment Management Plan Recommend Risk Management Plan



This report is also made in the overall frame work of the Environmental Impact Assessment (EIA) Notification dated 14th September 2006 (and subsequent amendments to the same) issued by the Ministry of Environment and Forests (MoEF), by providing required information with regards to the project as mentioned in the Terms of Reference issued by the Industrial committee of MoEF, New Delhi. 1.2 IDENTIFICATION OF THE PROJECT AND PROJECT PROPONENT PROJECT PROPONENT M/s. Aarti Industries Ltd. (Alchemie Organics Division) is one of company of Aarti Group. This group has more than 16 chemical industries spread over Gujarat, Madhya Pradesh and Maharashtra. The company has well established Research and Development division situated at GIDC, Vapi. The group has developed strong environment management cell and possess in house capabilities to undertake implementation of cleaner production technologies, green chemistry, zero liquid discharge systems, etc. besides carrying out environment impact assessments. Details regarding Directors are given in Table 1.1. TABLE: 1.1 DETAILS REGARDING DIRECTORS Sr. No.

Name of Directors

Designation Address Telephone No. 1.

Shri. Rajendra V. Gogri

Chairman& Managing Director

1401, Antriksh. Murar road, Mulund (w), Mumbai 400080

022-67976666

2.

Shri. Rashesh C. Gogri

Vice chairman& Managing Director

601,Antriksh Morar Road, Mulund (W) Mumbai 400080

022-67976666

3. Shri. Parimal H. Desai

Whole-Time Director

A/1403 14th Floor, Runwal Heights, L.S.B. Marg, Mulund (W)

022-67976666



Sr. No.

Name of Directors

Designation Address Telephone No. Mumbai- 400080

4. Shri. Manoj M. Chheda

Whole-Time Director

Dunhill Villa CO. OP. HSG. SOC. Ltd., Besant Road, Santa Cruz (W), Mumbai- 400054

022-67976666

5. Shri. Kirit R. Mehta

Whole-Time Director

10, Pushpendra Mension, Phiroj shah Mehta Road, Santa Cruz (W), Mumbai– 400054

0260-2400059 2400366

6. Smt. Hetal GOGRI GALA

Whole - Time Director

558-B, Gopal Sadan, Block no. 801, 8TH Floor, Jamshed Road, Matunga(E), Mumbai– 400019

022 - 67976666

7. Shri. Renil R. Gogri

Whole - Time Director

1401, Antriksh. Murar Road Mulund (W) Mumbai-400080

022 - 67976666

DETAILS OF EC The unit obtained first Environment Clearance [file no.J-11011/79/2002-IA II (I)] in July, 2003 from Ministry of Environment & Forests. Copy of Environment Clearance file no.J-11011//79/2002-IA II (I) is attached as annexure-I. After that the unit obtained second Environment Clearance [file no.J-11011/497/2008-IA II (I)] in 2008 from MOEF but Environment Clearance was not converted to any project and is now lapsed. Copy of Environment Clearance (file no.J11011/497/2008-IA II (I)) is attached as annexure-II. Report on status of compliance of the conditions stipulated in the Environment Clearance file no. J-11011/79/2002-IA II (I)) from Regional Office of Ministry of Environment and Forest, Bhopal is attached as annexure-III.



DETAILS OF CONSENT The unit has valid CCA order no. AWH-53342, issued on date 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. The copy of CCA is attached as annexure-IV. Report on status of compliance of the conditions stipulated in the CCA order no. AWH-53342 is attached as annexure V. Also recent monitoring report of water quality; process emission from Regional Office of Gujarat Pollution Control Board is attached as annexure-VI. Third party monitoring report is attached as annexure-VII. Earlier questionnaire for industry sector is attached as annexure-VIII. Existing manufacturing involves hydrogenation, diazotization, bromination, condensation and chlorination products. The list is given in Table 1.2. TABLE: 1.2 LIST OF PRODUCTS AS PER CCA Sr. No.

Name of Products Quantity As Per Consent (MT / Year)

1. DCBH (Di Chloro Benzene Hydro chloride) 3000 2. 2,3/2,5 DCP (Di Chloro Phenol) 300 3. 3,4,5 Tri Flouro Bromo Benzene 40 4. Para Flouro Phenol (PFP) 100 5. 3,5 Di Chloro Nitro Benzene 1050 6. Quinal phose (TECH) (Diethyl 2-Hydroxy

Thio phosphoryl Chloride) 600

7. 1,3 DFB( Di Flouro Benzene) 100 8. 2 Bromo 4 Flouro Acetanilide 74 9. Di Chloro Bromo Benzene 100 10. 3,5/2,6 DFA (Di Flouro Aniline) 30 11. 2,6 Di Chloro Para Nitro Aniline 25 12. Ortho Chloro Aniline 150 13. Acetic Acid 26 Total 5595 By Products: 14. Sulphuric Acid (70%) 2310 15. Dilute Sulphuric Acid 51326 16. HBr Solution 87.5 Total 53723.5



The unit has proposed expansion for manufacturing of products by hydrogenation, diazotization, bromination, condensation and chlorination. Also, the unit has proposed new products based on hydrolysis. List of proposed new products is mentioned in Table no.1.3 TABLE: 1.3 LIST OF PRODUCTS AS PER PROPOSED SCENARIO

Sr. No.

Products Quantity As Per Consent no. AWH- 53342 in MT / Year

Quantity As Per Proposed Expansion in MT / Year

1. Hydrogenation 1.1 DCBH (Di Chloro

Benzene Hydro chloride)

3000 7800

1.2 1,3 D.F.B.(Di Flouro Benzene) 100

1.3 3,5/2,6 DFA (Di Flouro Aniline) 30

1.4 OT Base 0 1.5 Di Anisidine 0 1.6 Co-Products From Hydrogenation 1.6 Ortho

Toluendine 0 87 1.7 Ortho Anisidine 0 87 1.8 Ortho Chloro Aniline 150 975 2. Diazotization – Sand Mayer Reaction 2.1 2,3/2,5 DCP (Di Chloro

Phenol) 300 2400

2.2 3,5 Di Chloro Nitro Benzene 1050

2.3 1,3,5 TCB 0 2.4 Para Flouro Phenol

(PFP) 100 3. Bromination 3.1 3,4,5 Tri Flouro Bromo

Benzene 40 1000 3.2 2 Bromo 4 Flouro

Acetanilide 74 3.3 Di Chloro Bromo 100



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Products Quantity As Per Consent no. AWH- 53342 in MT / Year

Quantity As Per Proposed Expansion in MT / Year

Benzene 3.4 Co-Product From Bromination Acetic Acid 26 29.17 4. Condensation 4.1 Quinal phose (TECH)

(Diethyl 2-Hydroxy Thio phosphoryl Chloride)

600 600

5. Para Flouro Anisol 0 200 6. Hydrolysis 6.1 4 Chloro Amino Phenol 0 200 6.2 2 Chloro Amino

Phenol 0 6.3 2,3,4 Tri FlouroAniline 0 7. Chlorination 7.1 2,6 Di Chloro Para

Nitro Aniline 25 4000 7.1 2,4,6 Tri Chloro Aniline 0 Total 5595 17378.17 By Products 1. Sulphuric Acid (70%) 2310 20875.2 2. Dilute Sulphuric Acid 51326 147900.24 3. HBr Solution 87.5 874.92 4. HCl (30%) 0 9231.48 5. Sodium sulphate 0 241.68

Total 53723.5 179123.52 1.3 KEY INFORMATION OF PROJECT 1.3.1 IMPORTANCE AND JUSTIFICATION OF PROJECT: This is an existing unit. The customers are established. The unit has already achieved maximum production capacity. There are pending orders with the unit. The products are exported also. The products proposed for expansion are dye intermediates. The dyes manufacturing sector is making progress with average 15% growth rate. The domestic demand is also increasing. In the international market also, the demand for



dyes and pigments is increasing. In this background the early implementation of the project is important. The expansion is proposed in the existing plot itself. There is enough area available for this project. 1.3.2 NATURE OF THE PROJECT The project is developed on principle of unit operations. The proponent has proposed to expand the unit in a way that it can carry out various unit operations. The design is made based on requirement of unit operations rather than based on individual products. The ever changing field of dyes and bulk drugs and discovery of new molecules has forced the chemical manufacturer to establish the unit which can undertake series reactions. The project also serves as pilot facility for group’s other industries. Once products are standardizing, market is developed, expected specifications are meet, and the knowhow will be transferred to other units. The present unit will always look for new products. 1.3.3 COST OF THE PROJECTAND TIME OF COMPLETION Existing investment in plant and machinery, land, building etc. is Rs. 9201 Lacs. The additional investment for proposed expansion will be Rs. 1515 Lacs. It has been classified as Large Scale Industry. TABLE: 1.4 CAPITAL COST PROJECTION Sr. No.

Purpose Existing (Rs. In Lacs)

Proposed (Rs. In Lacs)

Total (Rs. In Lacs)

1. Land 39.50 0 39.50 2. Building 351.04 150 501.04 3. Plant and Machinery 5000.46 500 5500.46 4.

Env. Protection & Safety a) Effluent treatment Plant 3250 800 4050 b) Safety Equipment (PPE, fire extinguishers, Ventilation, etc.)

500 50 550

C) Green belt development 15 15 30 d) Fire 45 0 45 Total 9201 1515 10716



The construction work will be started immediately after getting Environment Clearance. The project will be commissioned within 9 months’ time. Equipment suppliers are already sourced and detailed engineering is also completed. 1.3.4 SITE SELECTION The project proponent did not consider any other alternative site for proposed expansion as the unit has adequate space in existing plot for expansion. 1.3.5 LOCATION OF THE PROJECT The project site is located at plot no 902, 923, GIDC Estate, Phase-III, Vapi, Dist. Valsad, Gujarat. It is approximately 26 km distance from District: Valsad. The approximate geographical positioning of the project site is at Latitude: 20°21’47.26”N and Longitude: 72°54' 49.20” E. The unit is spread over in 11,970sq. m. area in GIDC Vapi. The site plant and plant layout are attached as annexure IX. The site location map on Indian map of 1:10, 00,000scales followed by 1:50,000/1:25,000 scales on A3/A2 sheet are attached as annexure-X-A. Topo sheet covered project site is attached as annexure- X-B. Location map showing 10 km radial distance from project site, longitude & latitude is also covered in annexure-X-C. Co-Ordinate showing latitude and longitude of four corner of project site is attached as annexure- X-D. And Google map image from Google earth is attached as annexure- X-E. 1.4 SALIENT FEATURES The plant is located in a well-developed industrial zone, which have all essential facilities such as internal roads, arrangement for supply of water and power to industries, effluent disposal facilities etc. The Vapi GIDC falls at Pardi Taluka of Gujarat. It is positioned on the bank of River Daman Ganga. It is situated to east of Daman (Central Territory) and to the West of Dadra and Nagar Haveli. Vapi is largely an industrial area dominated by small scale industries, especially chemical plants.



Water is available from G.I.D.C. water supply. G.I.D.C. Vapi is large industrial estate with a number of chemical plants, paper mill, textile processing plants and other allied industries total to about more than 705 units. Vapi Industrial Association (VIA) has set up a Disaster Management Cell to take care of any disaster in the vicinity. A Common Effluent Treatment Plant (CETP) and Common Hazardous Waste Storage Site are established and operated by M/s. Vapi Waste & Effluent Management Co. Ltd., Vapi. The treated effluent from CETP is discharged in to sea. The present unit will utilize TSDF facility. The unit is recycling back all effluent and will become zero discharge. The salient features of project site is covered under Table 1.5 TABLE: 1.5 SALIENT FEATURES OF THE PROJECT SITE Particulars Details Distance from project

Site Taluka/ Tehsil Pardi Approx.15 Km District Valsad Approx. 26 Km Approx. Geographical positioning

Latitude:20021’16.16”N Longitude:72’054’49.20”E

-- Nearest City Valsad Approx. 26 Km Nearest Town Vapi Approx. 4.4 Km Nearest Highway NH8 Approx. 3 Km Nearest Railway line/ Railway station

Vapi 3.0 Km Nearest Domestic Airport/ Airbase

Surat 90 Km 1.5 REGULATORY FRAMEWORK The proposed project fall under category 5(b) & 5(f) of the schedule, as per the EIA Notification, September 2006.As project located within 10 km radial distance from interstate boundary of Gujarat & Daman and Gujarat & Dadar Nagar Haveli. The unit requires obtaining Environmental clearance from Industrial Committee of MoEF, Delhi. The EIA report is based on the finalized TOR as received vide ref no. J-11011/47/2015-IA II (I) dated: - 19th January, 2015. Letter containing Terms of Reference (TOR) given by industrial committee of MoEF is attached as annexure-XI.



1.6 SCOPE & OBJECTIVES OF THE EIA STUDY This EIA Report is prepared to comply with the requirements of the Industrial committee, MoEF as per the guideline for the Clearance. The objectives of this EIA are: To describe the Project and associated works together with the requirements for

carrying out the Project. To identify and describe the elements of the community and environment likely to

be affected by the project, and / or likely to cause impacts upon the project, including both the natural and man-made environment;

To identify and quantify emission sources and determine the severity of impacts on sensitive receivers and potential affected uses;

To recognize and quantify any environmental impacts associated with the project and recommend appropriate mitigation measures;

To study existing landscape and visual quality in the study area so as to evaluate the landscape and visual impacts of the project;

To propose mitigation measures to minimise pollution, environmental disturbance and nuisance during construction and operation of the project;

To identify, predict and evaluate the residual (that is, after practicable mitigation) environmental impacts and cumulative effects expected to arise during the construction and operation phases of the Project in relation to the sensitive receivers and potential affected uses;

To identify, assess and specify methods, measures and standards, to be included in the detailed design, construction and operation of the project which are necessary to mitigate these impacts and reduce them to allowable levels within established standards / guidelines;

To investigate the extent of side-effects of proposed mitigation measures that may lead to other forms of impacts;

To identify constraints associated with the mitigation measures recommended in this EIA;

To identify any additional studies necessary to fulfil the objectives to the requirements of this EIA Study.



1.7 STRUCTURE OF EIA REPORT The generic structure of the EIA report, as per the guideline provided by MoEF is illustrated in the following tabulated format. TABLE: 1.6 STRUCTURE OF EIA REPORT Sr. No.

EIA Structure Contents 1. Introduction Purpose of the report and regulatory frame work

Identification of the project and project proponent Key Information of project Regulatory Frame work Scope & Objective of EIA study Structure of EIA report Terms of reference & Its Compliance

2. Project Description Condensed description of those aspects of the project (based on project feasibility study), likely to cause environmental effects. Description contains the details of the following: Type of project Need for the project Location details showing general location, specific location, project boundary & project site layout) Technology and process description Project description. Including drawings showing project layout, components of project etc. Schematic representations of the feasibility drawings which give information important for EIA purpose Description of mitigation measures incorporated into the project to meet environmental standards,



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EIA Structure Contents 3. Anticipated

Environmental Impacts & Mitigation Measures

Details of Investigated Environmental impacts due to project location, possible accidents, project design, project construction, regular operations, final decommissioning or rehabilitation of a completed project Measures for minimizing and / or offsetting adverse impacts identified Irreversible and Irretrievable commitments of environmental components Assessment of significance of impacts (Criteria for determining significance, Assigning significance) Mitigation measures

4. Environmental Monitoring Program

Technical aspects of environmental monitoring for the effectiveness of mitigation measures (incl. Measurement methodologies, frequency, location, data analysis, reporting schedules, emergency procedures, budget & procurement schedules)

5. Additional Study: Risk Assessment & Disaster Management Plan

Hazard Identification Risk Assessment & control/prevention Measures Disaster Management

6. Project Benefits Detail of the Socioeconomic & other tangible benefits of the project



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EIA Structure Contents 7. Environment

Management Plan Description of the administrative aspects of ensuring that mitigation measures are implemented and their effectiveness monitored, after approval of the EIA. The Chapter consist of:

Mitigation measures for impacts Pollution Prevention Plan Greenbelt Development Plan Mangrove Management Plan Dredging management Plan Waste management plan Environment Management Cell Budgetary Provisions for EMS

8. Summary & Conclusion Description of brief of EIA report 9. Disclosure of Consultant

Engaged Detail of the EIA Consultant

1.8 TERMS OF REFERENCE AND ITS COMPLIANCE TABLE: 1.7 TERMS OF REFERENCE PROPOSED BY UNIT

Sr. No.

Terms of Reference Topic Covered Under 1. Site Description and plant

layout Locational Features covered under topic 1.3.5

of Chapter -1 on page no. 1.8 Location map of showing project site in Valsad

District is shown in annexure-X. Site plan & Plant Layout are attached as

annexure-IX. 2. List of raw materials,

solvents and their quantity and properties.

Raw material consumption details are covered in table no.2.2 of chapter-2on page no.2.4.

Physical &chemical properties of raw material are covered in annexure-XXI.

3. List of finished products, their properties and

List of product is covered in table no 1.3 of chapter - 1, on page no.1.5.



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Terms of Reference Topic Covered Under quantities

4. Process details with mass balance.

Manufacturing process & material balance are covered in topic 2.4 of chapter-2 from page no2.16 to page no.2.63.

5. Solvent balance and recovery system

Details covered under topic 2.5 of chapter-2 on page no.2.64.

Details of solvent recovery system are covered in Table no.8.3 of chapter -8 on page no.8.5.

6. Details of process emissions, water discharge and hazardous waste generation and disposal.

Details of flue gas emission and process emission covered under topic 2.7.2 in Table no.2.16 & 2.17 of chapter - 2 on page no2.78.

Details of waste water generation are covered under topic 2.7.1in table no.2.15 under chapter - 2 on page no.2.77.

Details of hazardous waste generation and disposal mode covered under topic 8.4.2(D) in Table no. 8.16 & 8.17 of chapter-8 on page no.8.19.

7. Complete Water balance Details of water balance covered under topic 2.6.2 in figure 2.1 & 2.2 of chapter -2, from page no.2.67 to 2.70.

8. Treatment plant details to achieve zero liquid discharge.

Details of ETP and zero liquid discharge schemes covered under topic 8.4.2.1in Table no.8.5 to 8.13 & figure 8.5 of chapter-8 from page no.8.7 to 8.16.

9. Details of Air pollution control system

Details of air pollution control plan are covered under topic 8.4.2(A) in table no.8.2 & 8.3 of capter-8 from page no.8.3 to 8.6.

10. Steps to control fugitive emissions

Details of air pollution control plan are covered under topic 8.4.2(A) in table no.8.2 & 8.3 of capter-8 from page no.8.3 to 8.6.



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Terms of Reference Topic Covered Under 11. Details of closed handling

system for chemicals and reflux condenser over reactor.

The details of solvent recovery system are covered under topic 2.5 of chapter-2 on page no.2.64 and Table no.8.3 of chapter-8 on page no.8.5 & 8.6.

12. Base line data for soil, water, air and noise for one season.

Baseline details of Air, Water, Noise and Soil are covered in chapter-3 under topic 3.3, 3.4, 3.5 and 3.6 from page no.3.6 to 3.25.

13. Environment impact assessment due to excavation and construction activities, manufacturing process and its operations, generation of wastes and methods adopted for minimizing impacts etc.

No construction activity will be carried out. Other details are covered in chapter-4.

14. Details of Environmental Management Plan (EMP) and mitigation measures.

Details are covered in chapter-8.

15. Occupational health and safety programme.

Details are covered under topic 6.7of chapter-6 from page no.6.80.

TABLE: 1.8 ADDITIONAL TOR GIVEN BY INDUSTRIAL COMMITTEE OF MOEF Sr. No.

TOR condition Remarks Specific TOR 1. Commitment that no banned pesticides will

be manufactured. Commitment that no banned pesticides will be manufactured is attached as an annexure XXVII.

2. Details on solvents to be used, measures for solvent recovery and for emissions Control.

Details covered under topic 2.5 of chapter-2 on page



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TOR condition Remarks no.2.64. Details of solvent recovery system are covered in Table no.8.3 of chapter-8 on page no.8.5.

3. Details of process emissions from the proposed unit and its arrangement to control.

Process emission from the proposed unit is covered in table no.2.16 & 2.17 of chapter-2 on page no.2.78 and table no.8.2 & 8.3 of chapter-8 on page no.8.4 to 8.6.

4. Ambient air quality data should include VOC, other process-specific pollutants* like NH3*, chlorine*, HCl*, HBr*, H2S*, HF*, CS2etc., (* - as applicable)

Details are covered in table no. 3.4 of chapter-3 from page no. 3.8 to 3.12.

5. Work zone monitoring arrangements for hazardous chemicals.

Details are covered in 6.7.8. (D) Of chapter-6 on page no.6.82.

6. Detailed effluent treatment scheme including segregation for units adopting ‘Zero’ liquid discharge.

Details are covered in 8.4.2.1 of chapter-8 from page no.8.7 to 8.15.

7. Action plan for odour control to be submitted.

There are no odour emissions chemicals. However, it is covered with fugitive emissions.

8. A copy of the Memorandum of Understanding signed with cement manufacturers indicating clearly that they co-process organic solid/hazardous Waste generated.

Provisional membership certificate from RSPL for accepting co-process organic solid/hazardous waste generated is attached as



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TOR condition Remarks annexure- XXVIII.

9. Authorization/Membership for the disposal of liquid effluent in CETP and solid/hazardous waste in TSDF, if any.

The disposal of liquid effluent in CETP is not applicable because now, our unit is become zero liquid discharge unit. The details of waste in TSDF are attached as annexure-XX.

10. Material Safety Data Sheet for all the Chemicals are being used/will be used.

MSDS is as annexure-XXI in soft copy CD Foam.

11. Authorization/Membership for the disposal of solid/hazardous waste in TSDF.

Membership for the disposal of solid/hazardous waste in TSDF.as annexure-XX.

12. Details of incinerator if to be installed. Not Applicable. 13. Risk assessment for storage and handling of

hazardous chemicals/solvents. Action plan for handling & safety system to be incorporated.

Details are covered in table no.6.5, 6.6, 6.7, 6.8 and 6.9 of chapter-6 from page no.6.13 to 6.20 and action plan is covered in 6.7.10 of chapter-6 from page no.6.83 & 6.84.

14. Arrangements for ensuring health and safety of workers engaged in handling of Toxic materials.

Details are covered in 6.7.12 of chapter-6 on page no.6.86.

Additional TOR 1. A separate chapter on status of compliance

of Environmental Conditions granted by State/Centre to be provided. As per circular dated 30th May, 2012 issued by MoEF, a certified report by RO, MoEF on status of compliance of conditions on existing unit to be provided in EIA-EMP report.

Details are covered in chapter-9.



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TOR condition Remarks 2. Public hearing is exempted as per Para 7(i)

III Stage (3)(i)(b) of EIA Notification, 2006 For preparation of EIA/EMP Report, being site is located in the Notified industrial area.

Noted.

3. Recommendation of SPCB to be submitted for proposed activity.

Request letter submitted to SPCB is attached as annexure –XXIX.

3 These ‘TORs’ should be considered for the preparation of EIA /EMP for expansion of pesticide (from 5595 MTPA) at plot no.903,923,GIDC Estate, Vapi, Gujarat by M/s. Aarti Industries Ltd. In addition to all the relevant information as per the ‘General structure of EIA’ Given appendix III in the EIA Notification, 2006.

Noted.

Introduction 4.

Public hearing is exempted as per para 7(i) III stage (3) (i) (b) of EIA Notification, 2006 for preparation of EIA/EMP report, being site is located in the Notified industrial area. You are requested to kindly submit the final EIA/EMP Prepared as per TORs to the Ministry for considering the proposal for environmental clearance within 3 years as per the MoEF O.M No. j-11013/41/2006-IA.II(I) dated 8th October.2014

Noted.

5. The consultants involved in the preparation of EIA/EMP report after accreditation with quality council of India/National accreditation board of Education and training (QCI/NABET) would need to

Name and address of Consultant: Jyoti Om Chemical Research Centre Pvt. Ltd. F-11, Surajmoti Complex,



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TOR condition Remarks include a certificate in this regard in the EIA/EMP reports prepared by them and data provided by other Organization(s)/Laboratories including their status of approvals etc.

Nr. Hariom Nagar, Vadodara- 390 023. The consultants has got the stay order from HON. Gujarat high court and it is attached as annexure-XXIV

Generic terms of Reference(TOR) In respect of industry sector 1. Executive summary (maximum 2-3 sheets in

A4 Size paper) of the project covering project description, description of the environment, anticipated environmental impacts & its mitigation measures, environmental management plan, environmental monitoring programme, public consultation, project benefits, Soc, impacts including R&R.

Executive summary is attaches as annexure - XXX.

2. SITE DETAILS i Location of the project site covering village,

Taluka/Tehsil, district and state on Indian map of 1:1000, 000 scale.

Location of project site covering village, Taluka/Tehsil, district and state on Indian map of 1:1000, 000 scales is attached as annexure-X- A.

ii A topo sheet of the study area of radius of 10km and site location on 1:50000/1:25000 scale on an A3/A2 sheet.

A topo sheet of the study area of radius of 10km and site location on 1:50000/1:25000 scales on an A3/A2 sheet is attached as annexure-X-B.

iii Co-ordinates (lat-long) of all four corners of the site.

A co-ordinates show (latt-long) of all four corners of the site is attached as



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TOR condition Remarks annexure-X-D.

iv Google map-earth downloaded of the project site.

Google map on Google earth show the project site is attached as annexure- X-E.

v A map showing environmental sensitivity [land use/land cover ,water bodies ,reserved forests wildlife sanctuaries, National parks, tiger reserve etc. ] and from critically/severely polluted area(s) and Eco-sensitive Area within 10km radius of the project site vis-a-vis shortest (aerial) distance from the project. If the project is located within 10km of CPA/severely polluted area, confirm whether moratorium has been imposed on the area.

Map is attached as annexure- X-B.

vi Layout maps indicating existing unit as well proposed unit indicating storage area, plant area, green belt area, utilities etc. In addition, if located within the industrial area/estate/complex, layout of industrial area and location of unit within the industrial area/Estate/complex, layout of industrial.

Layout map indicating all the things is attached as annexure-IX.

vii Photographs of the proposed and existing (if applicable) plant site. If existing, In addition to Side map, provide photographs of plantation /greenbelt in Existing project. If fresh EC application ,photographs

Photographs are attached as annexure-XIV.

3. Land use break-up of total land of the project site (identified and acquired), government/private - agricultural, forest,

Details are covered under topic 3.14 of chapter-3 on page no.3.23.



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TOR condition Remarks wasteland, water bodies, settlements, etc shall be included.

4. A copy of the mutual agreement for land of the acquisition singed with land included.

Land possession document is attached as annexure-XII.

5. Proposed shall be submitted to the ministry for environmental clearance only after acquisition of land shall be included.

Existing unit. Full land acquired.

6. Forest and wildlife related issues (if applicable):

Not Applicable.

I Permission and approval for the use of forest land (forestry clearance), if any, and recommendations of the State Forest Department.

--

ii Land use map based on High resolution satellite imagery (GPS) of the proposed site delineating the forestland (in case of projects involving forest land more than 40 ha)

--

iii Status of Application submitted for obtaining the stage I forestry clearance along with latest status shall be submitted.

--

iv The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the project location and the recommendations or comments of the Chief Wildlife Warden-thereon

--



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TOR condition Remarks V Wildlife Conservation Plan duly

authenticated by the Chief Wildlife Warden of the State Government for conservation of Schedule I fauna, if any exists in the study area

--

vi Copy of application submitted for clearance under the Wildlife (Protection) Act, 1972, to the Standing Committee of the National Board for Wildlife

--

7. Expansion/modernization proposal i Copy of all the Environmental clearance (s)

including Amendments thereto obtained for the project from MOEF/SEIAA shall be attached as an annexure .A certified copy of the latest Monitoring report of the regional office of the Ministry of environmental and forests as per circular dated 30th may, 2012 on the status of compliance of condition stipulated in all the existing environmental clearance including amendments should be provided. In addition, status of compliance of consent to operate for the on-going /existing operation of the project from SPCB shall be attached with the EIA-EMP reports.

Copies of old EC are attached as Annexure –I and II. and Compliance report of last EC is attached as Annexure –III.

ii In case the existing project has not obtained environmental clearance, reasons for not talking EC under the provisions of the EIA notification 2006 shall be provided copies of consent to establish /No objection certificate and consent to operate (in case of units

Not Applicable.



Sr. No.

TOR condition Remarks operating prior to EIA Notification 2006, CTE and CTO of FY 2005-2006) obtained from the SPCB Shall be submitted.

Details of industrial operations 8. A list of major industries with name and

type within study area (10km radius) shall be incorporated.

Details are covered in Table no.3.1 of chapter-3 from page no.3.2 to 3.4.

9. Details of proposed raw material and products along with production capacity. If expansion project, details for existing unit, separately for existing and new (proposed) unit.

Details are covered under topic 2.3 in Table no.2.2 & 2.3 of chapter-2 from page no.2.4 to 2.11.

10. Details of manufacturing process, major equipment and machinery. If expansion project details of existing unit, separately for existing and new (proposed) unit.

Details are covered under topic 2.4 of chapter-2 from page no.2.16 to 2.63. Details of Equipment and machinery are covered in Table no.2.14 of chapter-2 on page no.2.73 to 2.77.

11. List of raw material required and its sources long with mode of transportation shall be included. All the trucks for raw material and finished product transportation must be “ environmentally compliant”

Details are covered in Table no.2.4 of chapter-2 from page no.2.12 to 2.15.

12. Quantity of fuel required ,its sources and characteristic and documentary evidence to substantiate confirmed fuel linkage shall be furnished

Details are covered in Table no. 2.9 of chapter-2 on page no. 2.71.Steam is coming from neighbour industry.

13. Project site layout plan to sale using Auto CAD showing raw material ,fly ash and other storage plans bore well or water

Plant layout is attached as annexure-IX.



Sr. No.

TOR condition Remarks storage ,acquires dumping ,waste disposal ,green areas water bodies ,rivers/drainage passing through the project site shall be include.

14. Manufacturing process details of all the plants including captive power plant if any along process flow chart shall be include.

Details are covered under topic 2.4 of chapter-2 from page no.2.16 to 2.63.

15. Mass balance for the material and products shall be included.


16. Energy balance data for all the compensates of the plant shall be incorporated.

Electricity connected load given in Table no.2.10 of chapter -2, on page no.2.71.

6. Environmental Status 17. Geological features and geo-hydrological

status of the study shall be included. Geological features given under topic 1.4 in chapter-1 on page no.1.4 & 1.5. Geo Hydrological is not applicable.

18. Details of drainage of the project up to 5 km radius of study area. If the site within 1 km radius of any major river ,peak and lean river discharge as well as flood occurrence frequency based on peak rainfall data of the past 30 years. Details of RL of the project site and mRL of the river should also be provided.

Not Applicable.

19. One season site-specific micro-metrological data using temperature relatively humanity ,hour, wind speed and direction and rainfall

Details are covered in table no. 3.2, 3.3 & 3.4 of chapter-3 from page no 3.4 to 3.12.



Sr. No.

TOR condition Remarks and AAQ data (except monsoon)at 8 location for PM10 ,PM2.5 ,SO2 ,NOX,CO and HC (methane & non-methane) should be collected. The monitoring stations should take into account the pre-dominant wind direction, population zone and sensitive receptors including reserved forests.

20.. Surface water supply quality of nearly river (60m upstream and downstream) and other surface drains at eight locations to be provided.

Details are covered under topic 3.4 and Table no.3.6 of chapter-3 on page no. 3.13 & 3.15.

21. Ground water monitoring minimum at 8 locations shall be included.

Details are covered under topic 3.4 and Table no.3.5 of chapter-3 on page no.3.13 & 3.14.

22. Noise level monitoring at 8 locations shall be included.

Details are covered in Table no.3.11 of chapter-3 on page no.3.21.

23. Traffic study of the area for the proposed project the respect of the exist traffic ,type of vehicles, frequency of vehicles for transportation of material additional traffic due to proposed project ,parking arrangement etc.

Details are covered under topic 4.2.6.1 in chapter-4 on page no.4.20.

24. Detailed description of flora and fauna (terrestrial and aquatic) existing in the study area shall be given with special reference to rare, endemic and endangered species. If Schedule-I fauna are found within the study area, a Wildlife Conservation Plan shall be prepared and furnished.

Details are covered in Table no.3.14 & 3.15 of chapter-3 from page no.3.26 to 3.31.



Sr. No.

TOR condition Remarks 25. Emission (g/sec) with and without the air

pollution control measures. Details are covered in table no.2.18 of chapter 2 on page no. 2.80

26. Cumulative impact of all sources of emission (including transportation) on the AAQ of the area shall be well assessed. Details of the model used and input model used and input data used for modelling shall also be provided. The air quality contours should be plotted on allocation map showing the location of project site, habitation nearby, sensitive receptors, if any.

Details are covered in Table no.4.1 of chapter-4 on page no.4.10. Location map is shown in Figure no. 4.7 to 4.12 of chapter-4 on page no. 4.13 to 4.18.

27. Impact of the transport of the raw materials and end products on the surrounding environment shall be assessed and provided. On this regard, options for transport of raw materials and finished products and wastes (large quantities) by rail or rail – cum road transport or conveyor – cum – rail transport shall be examined.

Details are covered under topic 4.2.6.1 of chapter-4 on page no.4.20.

28. Details of water requirement, water balance chart for new unit or for existing unit as well as proposed expansion (in case of expansion)

Details are covered under topic 2.6.2 of chapter-2 from page no.2.67 to 2.70.

29. Source of water supply and quantity and permission of withdrawal of water (surface/ground) from Competent Authority.

Source of water supply and quantity and permission of withdrawal of water (surface/ground) from Competent Authority is attached as annexure-XIII.



Sr. No.

TOR condition Remarks 30. Details regarding quantity of effluents

generated, recycled and reused and discharged to be provided. Methods adopted/to be adopted for the water conservation shall be included. Zero discharge effluent concepts to be adopted.

Details are covered under topic 2.7.1 of chapter-2 on page no.2.77 & 2.78.

31. A note on treatment of wastewater from different plant operations, extent recycled and reused for different purposes shall be included. Complete scheme of effluent treatment. Characteristics of untreated and treated effluent to meet the prescribed standards of discharge under E(P) Rules.

Details are covered under topic 8.4.2.1 of chapter-8 on page no.8.7 to 8.15.

32. Action plan for control of ambient air quality parameters as per NAAQES Standards for PM10, PM2.5, SO2 and NOx, etc as per GSR 826(E) dated 16thNovember, 2009.

Details are covered under topic 8.4.2 (A) of chapter-8 from page no.8.5 to 8.8.

33. An action plane to control and monitor secondary fugitive emissions from all the sources as per the latest permissible limits issued by the ministry vide G.S.R. 414 (E) dated 30th May, 2008.

Details are covered under topic 8.4.2 (A) of chapter-8 from page no.8.3 to 8.6.

34. Action plan for solid/hazardous waste generation, storage, utilization and disposal. Copies of MOU regarding utilization of solid waste shall also be included. EMP shall include the concept of waste-minimization, recycle/reuse/recover techniques, Energy conservation and natural resource conservation.

Details are covered under topic 8.4.2 (D) of capter-8 on page no.8.18 to 8.21.



Sr. No.

TOR condition Remarks 35. Proper utilization of fly ash shall be ensured

as per Fly Ash Notification, 1999 and subsequent amendment in 2003 and 2009. A detailed plan of action should be provided.

Not Applicable.

36. Action plan for the green belt development plan in 33% area i.e. land with not less than 1.500 trees per ha. Giving details of species, with of plantation, planning schedule etc. Shall be included. The green belt shall be around the project boundary and a scheme for greening of the roads used for the project shall also be incorporated. All rooftops/terraces shall have some green cover.

Details are covered under topic 8.4.2 (E) of chapter-8 on page no.8.21.

37. Action plan for rainwater harvesting measures at plant site shall be submitted to harvest rainwater from the roof tops and storm water drains to recharge the groundwater recharge structures may also be constructed outside the plant premises in consultation with local gram Panchayat and village hand to augment the ground water level, incorporation of water harvesting plan for the project is necessary, if source of water is bore well.

Not Applicable. In GIDC estate, rain water recharging is not recommended.

38. Environment Management Plan (EMP) to mitigate the adverse impacts due to the project along with item wise cost of its implementation. Total capital cost and recurring cost/annum for environmental pollution control measures shall be

Details are covered under topic 8.4.2(H) in Table no.8.18 of chapter-8 on page no. 8.22.



Sr. No.

TOR condition Remarks included.

39. Details of Rehabilitation & Resettlement (R & R) involving the project. R & R shall be as per policy of the state govt. And a detailed action plan shall be included.

Not Applicable.

40. Action plan for post – project environmental monitoring shall be submitted.

Environment monitoring plan covered in chapter-5.

41. Disaster Preparedness and Emergency Management Plan including Risk Assessment and damage control needs to be addressed and included.

Details are covered under topic 6.3 in Table no.6.3 & 6.4 of chapter-6 from page no. 6.10 to 6.12.

42. Occupational Health: i Details of existing occupational & safety

hazardous. What are the levels of above mentioned they are within permissible Exposure level (PEL).If these are not with in PEL so that health of the workers can be preserved.

Details are covered under topic 6.7.7 of chapter-6 on page no.6.81.

ii Details of exposure specific health status evaluation of worker. If the workers’ health is being evaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far & Near vision, colour vision and any other ocular defect) ECG, during pre-placement and periodical examinations give the details of the same. Details regarding last month analysed data of above mentioned parameters as per age, sex, duration of exposure and department wise.

Details are covered under topic 6.7.9 of chapter-6 on page no.6.83. Reports of premedical, post medical, and last medical are attached as annexure-XXVI.

iii Annual report of health status of works with Details are covered under



Sr. No.

TOR condition Remarks special reference to occupational health and safety.

topic 6.7.9 of chapter-6 on page no.6.83.

iv Action plan for the implementation of OHS standard as per OSHAS/USEPA.

Details are covered under topic 6.7.6 of chapter-6 on page no.6.81.

v Plan and fund allocation to ensure the occupational health & safety of all contract and causal workers.

Details are covered under topic 6.7.11of chapter-6 on page no.6.84 & 6.85.

43. Corporate Environmental Policy i Does the company have a well laid down

Environment Policy approved by its Board of Directors? If so, it may be detailed in the EIA report.

Environment policy approved by its Board of Directors is attached as annexure-XVIII.

ii Does the Environment Policy prescribe for standard operating process / procedures to bring into focus any infringement / deviation / violation of the environmental or forest norms / conditions? If so, it may be detailed in the EIA.

Details are covered under topic 8.3 of chapter-8 on page no. 8.2.

iii What is the hierarchical system or Administrative order of the company to deal with the environmental issues and for ensuring compliance with the environmental clearance conditions? Details of this system may be given.


iv Does the company have system of reporting of non-compliances / violations of environmental norms to the Board of Directors of the company and / or Shareholders or stakeholders at large? This reporting mechanism shall be detailed in




Sr. No.

TOR condition Remarks the EIA report

44. Details regarding infrastructure facilities such as sanitation, fuel, restroom etc. to be provided to the labour force during construction as well as to the casual workers including truck drivers during operation phase.

This is existing unit and no construction will be carried out. Details are covered under topic 2.6.1 in Table no.2.6 of chapter-2 on page no.2.64.

45. At least 5% of the total cost of the project shall be earmarked towards the enterprise social commitment based on public hearing issue and item wise details along with time bound action plan shall be included. Social-economic development activities need to be elaborated upon.


46. Any litigation pending against the project and/or any direction/order passed by any Court of Law against the project, if so, details thereof shall also be included. Has the unit received any notice under the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and Water Acts? If so, details thereof and compliance/ATR to the notice(s) and present status of the case.

All details are covered under chapter 9.

47. The questionnaire for industry sector (available on MoEF Website) shall be submitted as an annexure to the EIA-EMP reports.

The questionnaire for industry sector is attached as annexure-VIII.

48. ‘TORs’ prescribed by the expert appraisal Committee (industry) shall be considered for preparation of EIA-EMP reports for the

Instruction followed.



Sr. No.

TOR condition Remarks project in addition to all the relevant information as per the ‘genetic structure of EIA’ is given is appendix IIIA in the EIA notification ,2006.where the documents provided are in language other than English ,an English translation shall be provided. The draft EIA –EMP, report shall be submitted to the state pollution control board of the concerned state for the conduct public hearing. The SPCB shall conduct public hearing/public consultation, district wise, as per the provisions of EIA Notification, 2006.the issues raised in the public hearing and during the consultation process and the committee made by the project proponent the same shall include separately in EIA-EMP reports in the from tabular chart with financial budget (capital and revenue) along with time-schedule of implementation for complying with the commitments made. The final EIA reports shall submitted to the ministry for obtaining environmental clearance.

49. A tabular chart with index for point wise compliance of above TORs.

Details are covered in Table no.1.7 & 1.8 of chapter-1 from page no.1.13 to 1.29.

50. The TORs prescribed shall be valid for a period of three years for submission of the EIA-EMP Reports. Along with public hearing proceedings(whatever stipulated )

Noted.



Sr. No.

TOR condition Remarks ADDITIONAL TORs FOR SYNTHETIC ORGANIC CHEMICAL INDUSTRY 1. Manufacturing process details along with

the chemical reaction and process flow chart.


2. Name of all solvent to be used in the process and details of the solvent recovery system.


3. Design details of ETP, incinerator, if any along with boiler, scrubber/bag filters etc.

Design details of ETP are covered in Table no.8.4 to 8.13 of chapter-8 on page no.8.11 to 8.15. Drawing of scrubber is attached as annexure-XIX.

4. The details of solid and hazardous waste generation, storage, utilisation and disposal particularly related to the hazardous calorific value of hazardous waste and detailed characteristic of the hazardous waste .action plan of the disposal of fly ash generated from boiler shall include.

Details of solid and hazardous waste generation, storage are covered under topic 2.7.3 and 2.3.2.1 in Table no.2.19 of chapter-2 on page no.2.12 & 2.80. The details of solid and hazardous waste utilisation and disposal are covered under topic 8.4.2 (D) in Table no. 8.16 & 8.17 of chapter-8 from page no. 8.18 to 8.21.

5. Precaution to be taken during the storage and transportation of hazardous chemical shall be clearly mentioned and incorporated.

Details are covered in Table no. 6.33 of chapter-6 on page no. 6.60 & 6.61.

6. Material safety data sheet for all the chemicals are being used/will be used. AS

Material safety data sheets for all raw material and



Sr. No.

TOR condition Remarks No./RTECS No./DOT/UN ETC to be mentioned against each chemicals.

products are attached as annexure-XXI.

7. Details of VOC monitoring in the working zone environment, and other hazardous emission such as chlorine, HCl, etc if any.

Details are covered under chapter-6.

8. Authorization/membership for disposal of the solid/hazardous waste in TSDF.

Authorization/membership for disposal of the solid/hazardous waste in TSDF is attached as annexure-XX.

9. Risk assessment for the storage for chemicals /solvents. Action plan for the handing & safety system.

Details are covered under topic 6.5 of chapter-6 on page no 6.67.

10. Details of occupation health programme. Details are covered under topic 6.7 of chapter-6 on page no.6.80.

i To which chemical, workers are exposed directly or indirectly.

Details are covered under topic 6.7.7 of chapter-6 on page no. 6.81.

ii Whether these chemical, are chemical within threshold limit values (TLV)/permissible exposure levels as per ACGIH recommendation.


iii What measure company has taken to keep these chemicals within PEL/TLV?


iv How the workers evaluated concerning their exposure to chemical during pre-placement and periodical medical monitoring.


v Liver function test (LFT) during pre-placement and periodical examination.

Details are covered under topic 6.7.9 of chapter-6 on



Sr. No.

TOR condition Remarks page no. 6.83.

10. A toxic management plan shall be prepared. Details are covered under topic 6.8 of chapter-6 in page no. 6.86.

11. A write up on “safe practice” followed for handing, storage, transportation and unloading of chemical to be submitted.

Details are covered under topic 6.4.1 of chapter-6 on page no.6.60 & 6.61.

12. What are onsite and offsite emergency plan during chemical disaster.

Details are covered in table no. 6.37 & 6.38 on page no. 6.69.

13. A write up on “treatment of workers affected by accidental spillage chemical”.




Chapter – 2 PROJECT DESCRIPTION 2.1 TYPE OF PROJECT M/s. Aarti Industries Ltd. (Alchemie Organics Division) located at plot no 902, 923, GIDC Estate, Phase-III, Vapi, Dist.:-Valsad, Gujarat is manufacturing Dye/Dye intermediates & Pesticides products. The project falls under category 5(f) and 5(b) of the schedule, as per the EIA Notification, September 2006 and its amendment. The unit has valid CCA order no. AWH-53342, issued on date 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. Total existing production capacity is 5595 MT/Year. After proposed expansion proposed production capacity will be 17378.17 MT/Year. The unit has proposed expansion in existing products and also proposed some new products. The production capacity of existing and proposed products is given in Table 1.2and 1.3. 2.2 NEED FOR THE PROJECT Any investment decision is done based on techno economic viability of the project. The project has to be technically feasible and financially viable in nature. The existing unit is in export market for several years. They have range of products from various units and catering to the need of industries. The demand for newer molecules used to be regular feature from several countries as well as from India. This necessitude the project proponent to explore in the R& D department the manufacturing possibility. Once getting success in synthesizing these products at laboratory scale the financial viability was evaluated. The edge over other products resulted in the management decision to implement the project at the custom division. Once the production and manufacturing is optimized, the product may be scaled up at different location also. Moreover, the demand for existing product was constantly fluctuating. There arise competitions from other manufacturers for existing range of products. So as long term planning, the management decided to introduce new range of products.

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2.3DETAILS OF PRODUCTS AND RAW MATERIAL 2.3.1 DETAILS OF PRODUCT Existing total production capacity of the unit is 5595 MT/Year. The By-product formation is 53723.5 MT/Year. After expansion the total production will be 17378.17 MT/Year and the byproduct formation will be 179123.52 MT/Year. The list of the existing and proposed products and their production capacity are given in Table 1.2 and 1.3. Properties of products are given in Table 2.1 TABLE: 2.1 PROPETIES OF PRODUCTS

Sr.No.

Name of Products

Physical State

FP OC

BP OC

Vapor Density (Air=1)

LEL UEL %

LD50 Mg/Kgs LC50 Mg/L

TLV By OSHA (Ppm)

Sp. Gravity (Water=1)

1. DCBH (Di Chloro Benzene Hydro chloride)

Solid NA

NA NA NA 3.820 NA NA

2. 2,3/2,5 DCP (Di Chloro Phenol)

Solid NA

211 NA NA NA NA 1.37

3. 3,4,5 Tri FlouroBromo Benzene

Solid /Liquid

56 144 1.802g/ml

NA NA NA NA

4. Para Flouro Phenol (PFP)

Solid 72 143 6.3 NA 300-200 NA NA

5. 3,5 Di Chloro Nitro Benzene

Solid NA

NA NA NA NA NA NA





6. Quinal phose (TECH) (Diethyl 2-Hydroxy Thiophosphoryl Chloride)

Liquid 105

66-67

NA NA NA NA 1.32

7. 1,3 DFB( Di Flouro Benzene)

Liquid 2 82 1163 g/cm3

NA NA NA NA

8. 2 Bromo 4 Flouro Acetanilide

Solid NA

NA NA NA NA NA NA

9. Di Chloro Bromo Benzene

Solid NA

NA NA NA NA NA NA

10. 3,5/2,6 DFA (Di Flouro Aniline)

Solid 0 100 NA NA NA NA 1

11. 2,6 Di Chloro Para Nitro Aniline

Solid NA

NA NA NA 1500 NA NA

12. Ortho Chloro Aniline

Liquid 104

209 4.41 NA NA NA 1.22

13. Acetic Acid

Liquid 39-43

118.1

2.07 NA NA NA 1.049 14. Sulphuric

Acid (70%) Liquid N

A 160 3.4 NA 2140 NA 1.615

15. Dilute Sulphuric Acid

Liquid NA

100 3.4 NA 21400 NA 1.05

16. HBr Solution

Liquid NA

126-128

NA NA >90 NA 1.490





2.3.2 DETAILS OF RAW MATERIAL Product wise raw material consumption for existing and proposed products is covered in Table no. 2.2. The list of name of existing and proposed raw materials with consumption quantity in MT/Month for each product is provide in Table no.2.3 and 2.3. TABLE: 2.2 DETAILS OF EXISTING RAW MATERIALS CONSUMPTION

Sr. No.

Name of Products

Proposed production Capacity (MT/ Month)

Name of Raw Materials

Consumption per ton of ton product

Proposed consumption Quantity (MT/Month)

1 Hydrogenation 1.1

DCBH (Di Chloro Benzene Hydro chloride)

250

ONCB 1.61 402.50 Caustic lye 0.25 61.25 Fresh Toluene

0.09 22.50 Rec. toluene

3.24 810.00 Catalyst 0.0008 0.20 H2 0.07 17.50 HCl 30% 1.77 443.00 Soda ash 0.07 17.00 H2SO4 62% 4.84 1209.50 NaCl 1.02 255.75

1.2

1,3 D.F.B.(Di Flouro Benzene)

8.333

Di Flouro Chloro Benzene

1.35 11.25

Tri ethyl amine

0.05 0.42 Rec. Tri ethyl amine

1.03 8.58

Catalyst 0.0018 0.01 Hydrogen 0.027 0.22 HCl 30 % 0.22 1.83 Caustic flakes

0.45 3.75 1.3

3,5/2,6 DFA (Di Flouro Aniline)

2.5

DI Chloro Di Flouro Benzene

2.13 5.33

Ammonia 0.005 0.01 Catalyst 0.054 0.14 Caustic lye 48%

1.60 4.00





Sr. No.

Name of Products





Hydrogen 0.035 0.09 2 Diazotization 2.1

2,3/2,5 DCP (Di Chloro Phenol)

25

H2SO4 4.78 119.53 DCA 1.25 31.25 Mixed acid 2.75 68.75

2.2

3,5 Di Chloro Nitro Benzene

87.5

2,6 DCPNA

1.35 118.13 NSA 36 % 2.40 210.00 Formaldehyde 37 %

0.68 59.50 Soda ash 0.006 0.53

2.3

Para Flouro Phenol (PFP)

8.333

H2SO4 70% 2.60 21.67

Sodium Nitrate

0.79 6.57 Para flouro aniline

1.25 10.42 HCl 30% 3.02 25.17 MIBK 0.12 1.00 Rec. MIBK 2.59 21.58 Lime 0.45 3.75

3 Bromination 3.1

3,4,5 Tri Flouro Bromo Benzene

3.333

H2SO4 2.03 6.77 Sodium nitrate

0.41 1.37 Tri flouro aniline

1.23 4.10 HBr solution

1.32 4.40 Cupurious bromide

0.02 0.07 3.2

2 Bromo 4 Flouro Acetanilide

6.166

Para Flouro Aniline

0.56 3.47

Acetic an hydried

0.60 3.67 Bromine 0.64 3.96 H2O2 (50%)

0.31 1.92 NaHSO3 20% solution

0.64 3.97

Soda 25 % solution

0.80 4.95





Sr. No.

Name of Products





Fresh Mono chloro benzene

0.12 0.75

Rec. Mono chloro benzene

3.12 19.24

3.3

Di Chloro Bromo Benzene

8.333

Fresh ortho di chloro benzene

0.68 5.67

Rec ortho dichloro benzene

1.32 11.00

Aluminum chloride

0.01 0.08 Bromine 0.71 5.92 NaHSO3 10 %

0.0007 0.01 Soda ash 10%

0.0007 0.01 4 Condensation 4.1

Quinalphose (TECH) (Diethyl 2-Hydroxy Thiophosphoryl Chloride)

50

HQ 0.39 19.40 Acetone 0.07 3.50 Rec. acetone

1.73 86.50 KOH 0.06 2.80 K2CO3 0.36 18.00 DETPC 0.50 25.00 Xylene 0.22 11.00 Rec. Xylene

1.18 59.00 Stabilizer 0.11 5.50

5 Chlorination 5.1

2,6 DCPNA

2.083

PNA W/c 0.8627 1.80 MCB 9.1556 19.07 Dry HCl 0.2525 0.53 Borex 0.0057 0.01 Chlorine 0.8167 1.70 10%NaHCO3

0.026 0.05





TABLE: 2.3 DETAILS OF PROPOSED RAW MATERIALS CONSUMPTION

Sr. No.

Name of Products





1 Hydrogenation 1.1

DCBH (Di Chloro Benzene Hydro chloride)

650

ONCB 1.61 1046.50 Caustic lye 0.25 159.25 Fresh Toluene

0.09 58.50 Rec. toluene

3.24 2106.00 Catalyst 0.0008 0.52 H2 0.07 45.50 HCl 30% 1.77 1151.80 Soda ash 0.07 44.20 H2SO4 62% 4.84 3144.70 NaCl 1.02 664.95

1.2

Di Anisidine

650

ONA 1.56 1014.78 Rec. Toluene

3.20 2080.00 Toluene 0.10 65.00 Dichlone 0.01 6.11 Emulsifier 0.004 2.47 Caustic lye 48%

0.25 160.49 Catalyst 0.01 4.49 Hydrogen 0.05 33.15 HCl 3% 4.68 3044.41 Soda Ash 0.20 132.67 Spent Acid 3.55 2306.85 Thio urea 0.02 12.74 HCl 1.32 860.93 Salt Soln 3.70 2407.67

1.3

OT Base

650

ONT 1.59 1031.75 Toluene 0.06 39.00 Rec. Toluene

3.30 2145.00 Dichlone 0.0095 6.18 Emulsifier 0.0038 2.47 Caustic lye 48%

0.28 182.26 Catalyst 0.0068 4.42 Hydrogen 0.06 37.64 HCl(3%) 4.76 3095.24





Sr. No.

Name of Products





Soda Ash 0.21 134.81 Spent Acid 3.85 2504.26 Thio urea 0.02 11.96 HCl 1.44 933.86 Salt Soln 4.03 2619.76

1.4

1,3 D.F.B.(Di Flouro Benzene)

650

Di Flouro Chloro Benzene

1.35 877.50

Tri ethyl amine

0.05 32.50 Rec. Tri ethyl amine

1.03 669.50

Catalyst 0.0018 1.17 Hydrogen 0.027 17.55 HCl (30 %) 0.22 143.00 Caustic flakes

0.45 292.50 1.5

3,5/2,6 DFA (Di Flouro Aniline)

650

DI Chloro Di Flouro Benzene

2.13 1384.50

Ammonia 0.005 3.25 Catalyst 0.054 35.10 Caustic lye 48%

1.60 1040.00 Hydrogen 0.035 22.75

2 Diazotization 2.1

2,3/2,5 DCP (Di Chloro Phenol)

200

H2SO4 4.78 956.20 DCA 1.25 250.00 Mixed acid 2.75 550.00

2.2

3,5 Di Chloro Nitro Benzene

200

2,6 DCPNA

1.35 270.00 NSA 36 % 2.40 480.00 Formaldehyde 37 %

0.68 136.00 Soda ash 0.006 1.20

2.3

1,3,5 TCB

200

2,4,6TCA 1.27 253.96 NSA 39% 2.11 421.00 H2SO4 0.63 126.66 HCHO 37%

1.08 215.50 Soda ash 0.0024 0.48

2.4

Para Flouro Phenol (PFP)

200

H2SO4 70% 2.60 216.66





Sr. No.

Name of Products





Sodium Nitrate

0.79 65.66 Para Flouro aniline

1.25 104.16

HCl 30% 3.02 251.66 MIBK 0.12 10.00 Rec. MIBK 2.59 215.82 Lime 0.45 37.50

3 Bromination 3.1

3,4,5 Tri Flouro Bromo Benzene

83.33

H2SO4 2.03 169.16 Sodium Nitrate

0.41 34.17 Tri Flouro aniline

1.23 102.50 HBr solution

1.32 110.00 Cupurious bromide

0.02 1.67 3.2

2 Bromo 4 Flouro Acetanilide

83.33

Para Flouro Aniline

0.56 46.91

Acetic an hydride

0.60 49.66 Bromine 0.64 53.50 H2O2 (50%)

0.31 26.00 NaHSO3 20% solution

0.64 53.66

Soda 25 % solution

0.80 66.83 Fresh Mono chloro benzene

0.12 10.17

Rec. Monochloro benzene

3.12 259.99

3.3

Di Chloro Bromo Benzene

83.33

Fresh ortho di Chloro benzene

0.68 56.66

Rec ortho dichloro

1.32 110.00





Sr. No.

Name of Products





benzene Aluminum chloride

0.01 0.83 Bromine 0.71 59.16 NaHSO3 10 %

0.0007 0.06 Soda ash 10%

0.0007 0.06 4 Condensation 4.1

Para Flouro Anisol

16.66

PFA 1.03 17.16 DMS 1.23 20.49 NaOH 15%

2.54 42.32 NaHCO3 10%

0.23 3.83 5

Quinalphose (TECH) (Diethyl 2-Hydroxy Thiophosphoryl Chloride)

50

HQ 0.39 19.40 Acetone 0.07 3.50 Rec. acetone

1.73 86.50 KOH 0.06 2.80 K2CO3 0.36 18.00 DETPC 0.50 25.00 Xylene 0.22 11.00 Rec. Xylene

1.18 59.00 Stabilizer 0.11 5.50

6 Hydrolysis 6.1

4 CAP

16.66

2,5-DCNB 1.63 27.22 Caustic Lye

1.83 30.49 Ammonia 0.03 0.54 Catalyst 0.01 0.25 Hydrogen gas

0.05 0.85 H2SO4 0.65 10.86 Charcoal 0.11 1.89 Sodium Dithionate

0.01 0.20 Hydrazine Hydrate

0.0079 0.13 6.2

2 CAP

16.66

3,4-DCNB 1.63 27.22 Caustic Lye

1.83 30.49 Ammonia 0.03 0.54





Sr. No.

Name of Products





Catalyst 0.01 0.25 Hydrogen gas

0.05 0.85 H2SO4 0.65 10.86 Charcoal 0.11 1.89 Sodium Dithionate

0.01 0.20 Hydrazine Hydrate

0.0079 0.13 6.3

2,3,4 TFA

16.66

2,3,4 TFNB

1.35 22.51 Extract 2,3,4 TFNB

0.05 0.83

Ammonia 0.01 0.24 Catalyst 0.007 0.11 Hydrogen gas

0.05 0.83 7 Chlorination 7.1

2,6 DCPNA

333.33

PNA W/c 0.8627 287.56 MCB 9.1556 3051.84 Dry HCl 0.2525 84.17 Borax 0.0057 1.90 Chlorine 0.8167 272.23 10%NaHCO3

0.026 8.67 7.2 2,4,6 TCA 333.33 Aniline 0.6175 205.83

MCB 1.833 610.99 HCl gas 0.2424 80.80 Chlorine 1.4143 471.43 Soda Ash 0.0133 4.43 NaOH Flakes

0.0133 4.43 Thio urea 0.0133 4.43





2.3.2.1 RAW MATERIAL STORAGE AND HANDLING Raw materials are stored in M.S. Tank, S.S. Tank, and HDPE Carboys, fiber drums, glass bottle and cylinders. Hazardous flammable substances are separately stored in solvent tank farm area within premises. Solvents like Xylene, Toluene, Acetone, MCB and MIBK etc. are stored in MS/SS tank with all precautionary process instrumentation and safety appliances. Tank storing hazardous liquid chemicals are provided with dyke wall. Flame arrester cum breather valve and flame proof fittings are provided at tank farm. Solvent transfer is done by pumps. Reactor and solvent handling pumps have mechanical seal with flame proof electrical fitting. The solvent storage area is restricted for unauthorized persons. Proper earthling is provided in all electrical equipment whenever solvent handling is done. 2.3.3 TRANSPORTATION OF RAW MATERIALS AND FINISHED PRODUCTS The raw materials and finished goods are transported through tankers and trucks. There is well developed road structure in GIDC, Vapi as well as within premises also. No additional road infrastructure will be required for transportation. The raw material source will be standard manufacturer or supplier. Indicative list along with mode of transportation is included in Table no. 2.4. TABLE: 2.4 DETAILS OF RAW MATERIAL SOURCE AND METHOD OF TRANSPORTATION Sr. No.

Name of Raw Material

Mode of Transport

Type of Container

Source 1. ONCB Truck Above Ground

Tank Aarti Industries ltd , Vapi

2. Fresh Toluene Tanker Under Ground Tank

Reliance Industries , Surat

3. Rec. toluene Tanker Under Ground Tank

In House 4. Catalyst Truck HDPE drum Ravinda Heruse ,

Udaipur 5. Hydrogen Cylinder bank Cylinder Bank Aarti Industries ltd ,

Jhagadia 6. HCl 30% Tanker Above Ground

Tank Aarti Industries ltd , Vapi





Sr. No.


Mode of Transport

Type of Container

Source 7. Soda ash Truck Bag Nirma Industries 8. H2SO4 62% Tanker Above Ground

Tank In House

9. NaCl Truck Bag Chugule Salt , Vatva 10. ONA Tanker Above Ground

Tank Aarti industries Ltd , Vapi

11. Dichlone Truck Bag Chem clone, Ahmedabad

12. Emulsifier Tanker Drum 13. Caustic lye 48% Tanker Above Ground

Tank Gujarat Alkali , Dahej

14. HCl 3% Tanker Above Ground Tank

In House 15. Spent Acid Tanker Above Ground

Tank In House

16. Thiourea Truck Bag Zibo Linza Fine Chem , China

17. Salt Soln Tanker Bag In House 18. Di Flouro Chloro

Benzene Tanker HDPE Drum Aarti Industries Ltd ,

Vapi Nescent Division 19. Triethyl amine Truck HDPE Drum Alkali Amine, 20. Rec.Tri ethyl

amine Tanker Above Ground

Tank In House

21. Caustic flakes Truck Bag Gujarat Alkali , Dahej 22. Di Chloro Di

Flouro Benzene Tanker HDPE Drum Aarti Industries Ltd ,

Vapi Nescent Division 23. Ammonia Truck Cylinder Vadilal Gas , Vapi 24. H2SO4 Tanker Above Ground

Tank Aarti Industries Ltd , Vapi

25. DiChloro Aniline Tanker HDPE Drum Aarti industries ltd , Jhagadia

26. Mixed acid Tanker Above Ground Tank

Aarti Industries Ltd , Vapi Nescent Division

27. 2,6 DCPNA Truck Bag Shanti Intermediate , Vapi

28. NSA 36 % Truck Above Ground Tank

Aarti Industries Ltd , Vapi Nescent Division

29. Formaldehyde 37 %

Tanker Above Ground Tank

Atul Ltd, 30. 2,4,6TCA Tanker Bag Aarti Industries Ltd ,

Vapi 31. NSA 39% Truck Above Ground

Tank Aarti Industries Ltd , Vapi Nescent Division





Sr. No.


Mode of Transport

Type of Container

Source 32. H2SO4 70% Tanker Above Ground


33. Sodium nitrate Truck Bag R Nandalal& Sons , Mumbai

34. Para flouro aniline Tanker HDPE Drum Aarti Industries Ltd , Jagadia

35. Methyl Iso Butyl Ketone

Tanker Underground Tank

Urmi Chemicals 36. Rec. MIBK Tanker Underground

Tank In House

37. Lime Truck Bag Devashi Petoleum 38. Tri flouro aniline Tanker HDPE Drum Aarti Industries Ltd ,

Tarapure 39. HBr solution Tanker Above Ground

Tank In House

40. Cupurious bromide

Truck Bag Yogi Dye Chem Industries Ltd ,Mumbai

41. Acetic anhydride Tanker Above Ground Tank

Ashok Organics Industries , Vadodara

42. Bromine Truck Glass Bottle Sejal Chemicals 43. H2O2 (50%) Tanker HDPE Drum Suvidhi Enterprise,

Vapi 44. NaHSO3 20%

solution Tanker Above Ground

Tank In House

45. Soda 25 % solution


In House 46. Mono chloro

benzene Tanker Above Ground


47. Rec. Mono chloro benzene


In House 48. Ortho Di Chloro

Benzene Tanker Above Ground


49. Rec Ortho Di chloro Benzene


In House 50. Aluminum

Chloride Truck Bag Trevadi Chemical ,

Vadodara 51. Nahso3 10 % Tanker Above Ground

Tank In House

52. Soda Ash 10% Tanker Above Ground Tank

In House 53. HQ Tanker Above Ground

Tank Prolific Chemical , Tarapure

54. Acetone Tanker Underground Tank

C,J, Shaha & Company ,Mumbai

55. Rec. Acetone Tanker Underground Tank

In House





Sr. No.


Mode of Transport

Type of Container

Source 56. KOH Truck Bag Gujarat Alkali , Dahej 57. K2CO3 Truck Bag Vital Organics 58. DETCL Tanker Above Ground

Tank Excel Industries , Roha

59. Xylene Tanker Underground Tank

Reliance Industries , Surat

60. Rec.Xylene Tanker Underground Tank

In House 61. Stabilizer Tanker HDPE Drum Meckwell Industries ,

Vapi 62. DMS Truck HDPE Drum Aarti Industries Ltd ,

Vapi 63. Naoh 15% Tanker Above Ground

Tank In House

64. Nahco3 10% Tanker Above Ground Tanku

In House 65. 2,5-DCNB Truck Bag Aarti Industries Ltd ,

Jhagadia 66. Charcoal Truck Bag Hershil Entriprise,

Mumbai 67. Sodium Dithionate Truck Bag Remik Chemical Pvt.

Ltd 68. Hydrazine Hydrate Tanker Glass Bottle Antares Chem Private

Limited 69. 2,3,4 TFNB Truck HDPE Drum Aarti Industries Ltd ,

Tarapure 70. Extract 2,3,4

TFNB Truck HDPE Drum Aarti Industries Ltd ,

Tarapure 71. PAN W/C Truck Bag Aarti Industries Ltd ,

Vapi 72. DRY HCl Cylinder Bank Cylinder Gujarat Floro chem Ltd 73. Borex Truck Bag Sumukha Farm

Products Pvt. Ltd. 74. Chlorine Truck Cylinder Gujarat Alkali , Dahej 75. Aniline Truck HDPE Drum Aarti Industries Ltd ,

Jhagadia





2.4 PROCESS DESCRIPTION 2.4.1 MANUFACTURING PROCESS 1. HYDROGENATION 1.1 PRODUCT: DICHLORO BENZIDEN HYDROCHLORIDE (DCBH) BRIEF MANUFACTUIRNG PROCESS 1) ONCB reacts with hydrogen in presences of cat & caustic lye to form OCA & hydrazo.Toluene is used as a solvent. 2) Reaction mass filter to remove catalyst. Catalyst is reused for next batch. 3) Remove water layer by separation. 4) OCA removed by making hydrochloride by hydrochloric acid 5) OCA hydrochloride neutral by soda ash & distilled out. 6) Hydro toluene reacts with Sulphuric acid to form Di Chloro benzidine sulphate. 7) Toluene layer neutralized & distilled, Recovered toluene used for next batch. 8) Di Chloro benzidine sulphate reacts with hydrochloric acid & salt to form Di Chloro benzidine hydrochloride, which on centrifuging get wet cake of product.





CHEMICAL REACTION

NO2 Cl

Ortho-Nitro Chloro Benzene + 5 H2

2 x 157.5Hydrogen

5 x 2

CatlystToluene

N NH H

Hydrazo253

+ 4 H2O

Water4 x 18

253Hydrazo

HHNN + H2SO4 + H2O

Sulphuric Acid98

Water18

NN H2H2Di Chloro Benzidene Sulphate

Cl Cl .H2SO4

35118WaterH2O +

+ 2HClClCl

H2 H2N NHCl HCl+ H2SO4

ClCl

ClCl

351

.H2SO4ClCl

H2 H2N N

73 326 98





MATERIAL BALANCE









1.2 PRODUCT: DI ANISIDINE BRIEF MANUFACTURING PROCESS ONA reacts with Hydrogen in the presence of catalyst to form OA and hydro toluene. The hydro toluene layer reacts with H2SO4 and HCl in the presence of this urea to form Di anisidine CHEMICAL REACTION Step-1 Hydrogenation of Ortho nitro anisole

NO2OCH3+ 5H2

CatalystNaOH,Dichlone

NHH3CO NH OCH3

+ 4H2O

1-methoxy-2-nitrobenzene 1,2-bis(2-methoxyphenyl)hydrazine

2

2 X 153 5 X 2 244 4 X 18

Step-2 Rearrangement H3CO NH OCH3NH

+ HCl+ H2SO4 NH2 NH2

H3CO OCH3

HCl. .HCl

244 g/mole 317 g/mole1,2-bis(2-methoxyphenyl)hydrazineDianisidine





MATERIAL BALANCE









1.3 PRODUCT : OT BASE BRIEF MANUFACTURING PROCESS ONT reacts with Hydrogen in the presence of catalyst to form OT and hydro toluene. The hydro toluene layer reacts with H2SO4 and HCl in the presence of thio urea to form OT Base. CHEMICAL REACTION Step-1 Hydrogenation of Ortho nitro anisole

NO2CH3 + 5H2

CatalystNaOH,Dichlone

NHCH3 NH CH3

+ 4H2O2

2 X 137 5 X 2 212 4 X 181-methyl-2-nitrobenzene 1,2-bis(2-methylphenyl)hydrazine

Step-2 Rearrangement

CH3 NH CH3NH

+ HCl+ H2SO4 NH2 NH2

CH3 CH3

HCl. .HCl

212 g/mole 285 g/moleOT Base1,2-bis(2-methylphenyl)hydrazine





MATERIAL BALANCE









1.4 PRODUCT : 1,3 D.F.B.(DI FLOURO BENZENE) BRIEF MANUFACTURING PROCESS 1) Di Flouro Chloro benzene reacts with hydrogen in presences of catalyst to get

crude Di Flouro benzene. Tri ethyl amine use as a solvent. 2) Reaction mass filter to remove catalyst. Catalyst reuse for next batch. 3) Filter reaction mass acidify with hydrochloric acid to get crude DFA & TEA

hydrochloride. 4) TEA hydrochloride the neutral with caustic flakes to get TEA which is recycled to

next batch. 5) Crude DFB distilled to get pure DFB. CHEMICAL REACTION





MATERIAL BALANCE





1.5 PRODUCT : 3,5/2,6 DFA (DI FLOURO ANILINE) BRIEF MANUFACTURING PROCESS 1) Di chloro di flouro nitro benzene reacts with hydrogen gas in presences of

catalyst, ammonia, caustic lye to get crude DFA. 2) Reaction mass then filters to remove catalyst. CATALYST reuse in next batch. 3) Remove water layer by separating. 4) After distillation gets pure product CHEMICAL REACTION





MATERIAL BALANCE





2 DIAZOTIZATION 2.1 PRODUCT :2,3/2,5 DCP (DI CHLORO PHENOL) BRIEF MANUFACTURING PROCESS 1) Di Chloro aniline reacts with sulphuric acid to for Di chloro aniline sulphate. 2) Di Chloro aniline sulphate reacts with mix acid to for dizo mass. 3) Dizo mass reacts with dilute sulphuric acid to form crude Di Chloro phenol. In 1) This reaction N2 gas evold & spent acid generate. 4) Crude Di Chloro phenol separate out & distilled to get pure di chloro phenol. CHEMICAL REACTION





MATERIAL BALANCE





2.2 PRODUCT : 3,5 DI CHLORO NITRO BENZENE BRIEF MANUFACTURING PROCESS 1) DCPNA reacts with mix acid/NSA to get dizo mass. 2) Dizo mass reacts with formaldehyde & water to get crude 3.5 dichloride nitro 5) Benzene & dilute Sulphuric acid. 3) After separation & distilled get pure 3, 5 di chloro nitro benzene. CHEMICAL REACTION





MATERIAL BALANCE





2.3 PRODUCT : 1,3,5 TCB BRIEF MANUFACTURING PROCESS 2, 4, 6 TCA, NSA & H2SO4 undergone for Diazotization. The Diazotized mass will decompose in presence of formaldehyde and water. The Organic layer getting after decomposition will wash and distilled we will get distilled 3, 5 TCB. CHEMICAL REACTION

2, 4, 6-TCA NSA Diaz Formaldehyde 1, 3, 5-TCB Formic Acid 196.5 127 30 192.5 46

HCOOH + N2+H2SO4ClCl

Cl

+ HCHO + H2OClCl

Cl

N=N HSO4

NO2O

OSHO + ++

NH2ClCl

Cl





MATERIAL BALANCE





2.4 PRODUCT : PARA FLOURO PHENOL (PFP) BRIEF MANUFACTURING PROCESS 1) Para Flouro aniline reacts with hydrochloric acid to form tri Flouro aniline 4) Hydrochloride. 2) Para Flouro aniline hydrochloride reacts with sodium nitrate to form dizo mass. 3) These dizo mass reacts with dilute Sulphuric acid to form crude Para Flouro 5) Phenol. This is extract with methyl isobutyl ketone. 4) After separation & distillation get pure Para Flouro phenol. 5) Distilled MIBK reuse for next batch.





CHEMICAL REACTION





MATERIAL BALANCE









3 BROMINATION 3.1 PRODUCT: 3, 4, 5 TRI FLOURO BROMO BENZENE BRIEF MANUFACTURING PROCESS 1) Tri Flouro aniline reacts with Sulphuric acid to form Tri Flouro aniline sulphate. 2) Tri Flouro aniline sulphate reacts with sodium nitrate to form dizo mass. 3) These dizo mass reacts with hydrogen bromide solution & cuprous bromide to form crude triflouro bromo benzene & dilute sulphuric acid. 4) After separation & distillation get pure Tri Flouro Bromo benzene.





CHEMICAL REACTION





MATERIAL BALANCE









3.2 PRODUCT:2 BROMO 4 FLOURO ACETANILIDE BRIEF MANUFACTURING PROCESS Para Flouro aniline reacts with acetic anhydride to gets acetic acid & PFA slurry. Acetic acid recover & remaining mass dumped in water to get PFA slurry. PFA slurry reacts with bromine & hydrogen peroxide to gate crude PFAC slurry. This is neutral by sodium bi sulphate solution & soda ash. Crude BFAC slurry extracted in mono chloro benzene for purification. Water separated removed mono chloro benzene to gate wet cake of BFAC. Recovered MCB reuse in next batch. Wet cake of BFAC on drying get pure product of Bromo Flouro Acetanalide. CHEMICAL REACTION





MATERIAL BALANCE





3.3 PRODUCT :DI CHLORO BROMO BENZENE BRIEF MANUFACTURING PROCESS Ortho di chloro benzene reacts with bromine in presences of aluminum chloride to get reaction mass of DCBrB & hydrogen bromide solution Reaction mass natural by sodium bi sulphate & soda ash. Crude reaction mass take for distillation & remove excess ODCB which is reuse in next batch. After distillation pure product DCBrB gets. CHEMICAL REACTION





MATERIAL BALANCE





4. CONDENSATION 4.1 PRODUCT :PARA FLOURO ANISOL BRIEF MANUFACTURING PROCESS PFP reacts with DMS & NaOH, then the organic layer will wash and distilled we will get pure PFA. CHEMICAL REACTION Step 1

OH

F

+ SO

O OCH3OCH3

NaOHO CH3

F

+ SO

O ONaOCH3

+ H2O

CH4

112.1 126.13

40

126.13 134

18

Para Flouro Phenol DMS Para Flouro Anisole





MATERIAL BALANCE





5. PRODUCT: QUINALPHOSE (TECH) (DIETHYL 2-HYDROXY THIOPHOSPHORYL CHLORIDE) BRIEF MANUFACTURING PROCESS 1) 2 hydroxyquazilinol react with di ethyl thiophosporil chloride in presences of Potassium carbonate & potassium hydroxide to form crude quinalphose . Acetone is as a solvent. 2) Acetone recover & use in next batch. 3) Crude quinalphose extract in xylene. 4) After separation of xylene extracted mass added stabilizer. Concentrated ML Sends for incineration. 5) Removed xylene gets pure quinalphose (tech grade) 6) Recovered xylene recycles in next batch. CHEMICAL REACTION





MATERIAL BALANCE





6 HYDROLYSIS 6.1 PRODUCT :4 CAP BRIEF MANUFACTURING PROCESS 2, 5 DCNB, Caustic lye Ammonia & water is undergone for hydrolysis. Then the reaction mass will hydrogenated in presences of catalysts. This reaction mass will react with H2SO4 after filtration we will get crude 4CAP.It will undergone for charcoal treatment and filtration will get wet cake of 4CAP.The wet cake will drying and produce pure 4CAP. CHEMICAL REACTION





MATERIAL BALANCE









6.2 PRODUCT : 2 CAP BRIEF MANUFACTURING PROCESS 3, 4 DCNB, Caustic lye Ammonia & water is undergone for hydrolysis. Then the reaction mass will hydrogenated in presences of catalysts. This reaction mass will react with H2SO4 after filtration we will get crude 2CAP.It will undergone for charcoal treatment and filtration will get wet cake of 2CAP.The wet cake will drying and produce pure 2CAP. CHEMICAL REACTION





MATERIAL BALANCE









6.3 PRODUCT :2,3,4 TFA BRIEF MANUFACTURING PROCESS 2, 3, 4-TFNB, Water& NH3 are hydrogenated in presence of catalyst. Then the reaction mass will filtered. The aqueous layer will further treat and organic layer will distilled under Vacuum. By distillation we will get Pure 2, 3, 4 TFA. CHEMICAL REACTION





MATERIAL BALANCE





7 CHLORINATION 7.1 PRODUCT: 2, 6 DCPNA BRIEF MANUFACTURING PROCESS 1) Wet cake of 2, 6 DCPNA on drying gets dry 2, 6 DCPNA. CHEMICAL REACTION





MATERIAL BALANCE





7.2 PRODUCT: 2, 4, 6 TCA BRIEF MANUFACTURING PROCESS Aniline reacts with Chlorine and Hydrochloric acid in the presence of MCB to form 2, 4, 6 Tri Chloro Aniline. CHEMICAL REACTION





MATERIAL BALANCE





2.5 DETAILS OF SOLVENT RECOVERY SYSTEM & ITS MANAGEMENT Toluene, Acetone, Xylene, MCB and MIBK are the solvent to be used in the

process. TABLE: 2.5 DETAILS OF SOLVENT RECOVERY

Sr. No.

Product Name of Solvent

Condenser Details Primary service Secondary service M2 M2 1 QP ACETONE 6 chill water 1.5 chill

water 2 QP XYLENE 12 cooling water 8 chill

water 3 DCBH TOLUENE 30 cooling water 20 chill

water 4 DCPNA MCB 20 cooling water 10 chill

water 5 PFP MIBK 15 cooling water 10 chill

water 2.6 RESOURCE REQUIREMENT 2.6.1 INFRASTRUCTURE FACILITIES (LAND) Expansion will be carried out at existing plot no. 902,923, Phase-III, GIDC Estate, Vapi-396 195, Dist. Valsad, Gujarat. The land possession document is attached as annexure XII. The total plot area of the unit is 26,271 sq. m. The green belt area is 1943.90 sq. m. The photograph of existing plant area and proposed plant area are attached as annexure- XIII. The plant layout is attached as annexure- IX. Details of infrastructures is covered under following table no. 2.6 Details of breakup of plot area are covered under following Table no. 2.7.





TABLE: 2.6 DETAILS OF INFRASTRUCTURE Sr. No.

Particular Land Area (sq. m.)

Nos. 1. Watchman Cabin 9.30 1 2. Office building 263.41 1 3. D.G. set room 121.00 1 4. Godown 864.00 1 5. Driver room 54.00 1 6. Sanitary block 24.00 1 7. Labour room 59.50 1 8. Engineering work

shop 1012.50 1

9. Ware house 280.00 1 10. Work shop 170.00 1 11. DCS Control room 96.00 1

TABLE: 2.7 LAND USE BREAK UP OF TOTAL PLOT AREA Sr. No.


Land Area in % 1. Watchman Cabin 9.30 0.04 2. Office building 263.41 1.00 3. Bromo plant 393.25 1.50 3 A. Tank farm 140.07 0.53 3 B. Storage yard 147.07 0.56 4. QP & 2HQ Plant 571.10 2.17 4 A. QP Godown 80.00 0.30 5. Flouro plant 521.13 1.98





Sr. No.


Land Area in % 6. Storage yard 144.00 0.55 7. Petroleum storage

tank farm 98.70 0.38

8. D.G. set room 121.00 0.46 9. D.C.B.H.-II 591.30 2.25 10. U/G Tank 360.00 1.37 11. D.C.B.H.-IV 256.00 0.97 12. D.C.B.H.-III 532.90 2.03 13. DCBH Godown 613.58 2.34 14. Godown 864.00 3.29 15. Spin flash dryer 136.00 0.52 16. Hydrogenation Plant 389.50 1.48 17. DCP-DCNB Plant 532.00 2.03 18. DFB Plant 380.00 1.45 19. Tank Farm 169.63 0.65 20. Residue ST.Yard 121.78 0.46 21. ST. Tank Farm 220.00 0.84 22. Catalyst incinerator 161.04 0.61 23. Hydrogen shed 108.00 0.41 24. Driver room 54.00 0.21 25. Sanitary block 24.00 0.09 26. Salt Solution Plant 256.00 0.97 27. ETP 951.89 3.62 27 A. ETP-2 1128.40 4.30 28. Labour room 59.50 0.23





Sr. No.


Land Area in % 29. Engineering work

shop 1012.50 3.85

30. Ware house 280.00 1.07 31. Work shop 170.00 0.65 32. MEE Plant 65.70 0.25 33. DCS Control room 96.00 0.37 34. Green Belt Area 1943.90 7.40 35. Open Area 12304.35 46.84 Total 26271.00 100.00

2.6.2 WATER REQUIREMENT Water consumption is primarily for processing, washing, boiler, cooling, DM plant, gardening and domestic purpose. The existing fresh water requirement for domestic and industrial purpose is met through GIDC water supply. GIDC has its own water reservoir and distribution network throughout the GIDC Estate. A letter from GIDC stating that the proposed additional quantity of water will be provided is attached as annexure-XII The unit will also use recovered water from R.O. system and MEE plant as the unit has proposed zero liquid discharge unit. Average daily fresh water consumption of the unit is about 404 KL/day. The unit will use additional fresh water of 195 KL/day for proposed expansion. Unit will also use recovered water of 268 KL/day. So, total water consumption will be 867 KL/day (599 KL/day of fresh water + 268 KL/day of recycled water) after proposed expansion. Stream wise bifurcation of water consumption is covered in following Table. 2.7.





TABLE: 2.8 DETAILS OF WATER CONSUMPTION Sr. No.

Section Water Consumption KL/Day Existing as per CCA no.AWH-53342

Water Consumption as per Proposed Expansion

Total

1. Domestic 30 40 70 2. Industrial 2.1 Process 129 198 (Fresh) +

20(Recovered) 327 (Fresh) + 20(Recovered)

2.2 Washing 10 20 30 2.3 DM plant 0 15 15 2.4 Cooling 215 -58 (Fresh)

+ 268 (Recovered)

157 (Fresh) + 268(Recovered)

2.5 Gardening 20 -20 0 Total (Industrial) 374 155 (Fresh)

+ 288 (Recovered)

529 (Fresh) + 288(Recovered)

Total( Domestic+ Industrial)

404 195 (Fresh) + 288 (Recovered)

599 (Fresh) + 288 (Recovered)





FIGURE: 2.1 WATER BALANCE DIAGRAM (EXISTING)

GIDC supply 404 KL/Day Water from Reaction & Raw material 35.14 KL/Day

Process 129 KL/Day

Effluent From washing

10 KL/Day

To Incinerator 2.44 KL/Day

62.55 KL/Day

Neutral 62.3 KL/Day

Neutralization 62.55 KL/Day

Sewage 20 KL/Day

Cooling tower Blow down 6.7 KL/Day

ETP 99 KL/Day

Treated effluent is sent to CETP 99 KL/Day

Water going to spent Sulphuric acid

99.15 KL/Day

Domestic 30 KL/Day

Gardening 20 KL/Day

Cooling tower 215 KL/Day

Washing 10 KL/Day Effluent

64.99 KL/Day





FIGURE: 2.2 WATER BALANCE DIAGRAM (PROPOSED EXPANSION) 30 KL/Day

Use for gardening purpose

STP

RO- 2 75 KL/Day

RO-1 Permeate 117KL/Day

Treated effluent Send to RO - 1 167 KL/Day

ETP 167 KL/Day

RO-2 Permeate 53 KL/Day

Recovered 68 KL/Day

Effluent From washing

30 KL/Day Cooling tower

Blow down 70 KL/Day

DM Plant 5 KL/Day

Sewage 60 KL/Day

4 KL/Day Rejected Solid will be send to TSDF

RO Reject 72 KL/Day

Effluent to Incinerator

11.7 KL/Day Effluent

137 KL/Day

GIDC supply 599 KL/Day + 268 KL/Day recovered water = 867KL/Day Recovered Water from Process 20 KL/Day

Process 347 KL/Day (20 + 327) Domestic 70 KL/Day

Cooling tower 425 KL/Day

DM Plant 15 KL/Day

Washing 30 KL/Day 268 KL/Day

Effluent 149

KL/Day Water going to spent

Sulphuric acid 197.3 KL/Day

30 KL/Day

238 KL/Day

MEE 72 KL/Day





2.6.3 ENERGY REQUIREMENT The energy requirement in terms of power and fuel for proposed unit is shown in following Table 2.9. TABLE: 2.9 FUEL CONSUMPTION REQUIREMENT

Sr. No.

Name of Fuel

Requirement Source Existing

Quantity As Per Consent No AWH-53342

Proposed Quantity

Total Quantity

1. Diesel 100 Lit/Hr 150Lit/Hr 250 Lit/Hr Local supplier 2. Furnace

Oil 425 Lit/Hr -425 Lit/Hr 000 Lit/Hr Local supplier

3. Energy - Electricity

1200 KVA 800 KVA 2000 KVA DGVCL

2.6.3.1 DETAILS OF ENERGY DISTRIBUTION/UTILISATION Details of energy distribution are covered in below table no. 2.10. TABLE: 2.10 ENERGY REQUIREMENT

Sr. No.

Name of Equipment

Existing Connected Energy in HP

Proposed Connected Energy in HP

Total Connected Energy in HP

1. Reactor 1659 350 2009 2. Cooling Tower 439.5 25 464.5 3. Boiler 0 0 0 4. Dryer 90.5 25 115.5 5. Nutch Filter 50 15 65 6. Centrifuge 439.5 45 484.5 7. Pump & Motor 2662 800 3462 8. Pulvariser 12 5 17 9. Compressor 670 25 695 10. Blender 60 0 60 11. Lift 6 6 12 12. Blower 115 25 140 13. Reactor 1659 350 2009 Total 7862.5 1671 9533.5





2.6.4 UTILITIES For the proposed expansion project the utilities to be installed will be Cooling tower, D.G set, etc. Details of utilities services required for the proposed project are given in following Table 2.11. And Table 2.12. TABLE: 2.11 DETAILS OF EXISTING UTILITIES

Sr. No.

Name of The Utilities

Capacity Nos. MOC

1. Chilling Plant 75 TR 4 CI 2. Chilling Plant 35 TR 1 CI 3. Chilling Plant 150 TR 1 CI 4. Cooling Tower 400 TR 1 PPFRP 5. Cooling Tower 300 TR 5 PPFRP 6. Cooling Tower 300 TR 1 WOODEN 7. Cooling Tower 250 TR 6 PPFRP 8. Cooling Tower 150 TR 1 PPFRP 9. Cooling Tower 100 TR 4 PPFRP 10. Cooling Tower 30 TR 1 PPFRP 11. Air Compressor 60 CFM 2 CI 12. Air Compressor 80 CFM 2 CI

TABLE: 2.12 DETAILS OF PROPOSED UTILITIES Sr. No.

Name of the Utilities

Capacity Nos. MOC

1. Chilling Plant 150 TR 1 CI 2. Cooling Tower 400 2 PPFRP 3. Air Compressor 80 CFM 2 CI





2.6.5 MANPOWER The manpower required for the project as well as during the construction/ commissioning activities will be employed from the local area. TABLE: 2.13 MAN POWER REQUIREMENT Phase of project

Type of Labor

No. of Workers (Existing)

No. of Workers (Proposed Scenario)

No. of Workers (Total)

During construction

Contractual -- -- --

During commissioning

Contractual -- -- -- During operations

Managerial 12 8 20 Skilled 18 20 38 Un-skilled 160 140 300

Total 190 168 358 2.6.6 EQUIPMENTS/MACHINERIES Details of equipment and machineries are given in below table no 2.14.The list is quite comprehensive and provide overall image of the processing area. TABLE: 2.14 DETAILS OF EQUIPMENT AND MACHINERIES Sr. No.

Name of The Equipment

MOC Capacity in KL Nos.

Existing 1. Autoclove SS316 10 - 12 5 2. Fanda Filter SS316 5 -10 m2 5 3. Vessel SS316 2 - 14 8 4. Vent Tank MS 5 - 20 5 5. Storage Tank SS316 17.5 2 6. Tank MS 10 - 17 4 7. Sparkler Filter SS316 2.6 m2 6 8. Polosh Filter SS316 05 m2 5 9. Pump CI 200/25 10 10. Pump SS316 20/25 20 11. Cooling Tower PP/FRP 300 TR 5





Sr. No.



12. Reactor SS316 5 13. Reactor SS316 1.8 - 8 5 14. Reactor GLR 1.6 - 3 4 15. Reactor GLR 10-12.5 2 16. Tank SS316 1 5 17. Tank MS 0.5 5 18. Tank MS 15-20 5 19. Pump CI 100 /25 2 20. Pump SS316 20/25 6 21. Pump CI 25/25 2 22. Condenser GRP 15 m2 3 23. Column MS 300/6000 m 1 24. Condenser SS316 15 m2 1 25. Ejector System SS316 5 TOR 2 26. Cooling Tower PP/FRP 300 TR 1 27. Reactor SS316 1 6 28. Reactor SS316 1.8 - 8 3 29. Reactor GLR 1.6 - 3 2 30. Reactor GLR 10-12.5 5 31. Tank SS316 1 6 32. Tank MS 0.5 6 33. Tank MS 15-20 4 34. Pump CI 100 /25 2 35. Pump SS316 20/25 2 36. Column SS316 600/5000 m 2 37. Ejector System SS316 5 TOR 2 38. Pump PP 20/25 6 39. Reactor HDPE 8.5 6 40. Reactor GLR 12.5 17 41. Reactor GLR 16 2





Sr. No.



42. Reactor PP 21 12 43. Pump CI 250/30 4 44. Pump CI 100/25 7 45. Pump PFA 25/20 7 46. Pump PP 20/20 59 47. Pump SS316 20/20 20 48. Pump PVDF 50/30 4 49. Storage Tank MS 20-30 3 50. Storage Tank HDPE 20/20 18 51. Cooling Tower PP/FRP 100 - 250 5 52. Coloumn SS316 600/7 m 2 53. Condenser SS316 40 2 54. Condenser GRP 10 - 80 m2 5 55. Scrubber HDEP 600/3000 m 3 56. Reactor SS316 3 - 9 10 57. Condenser SS316 4 m2 4 58. Condenser MS I - 6 m2 10 59. Pump CI 20/20 20 60. Pump SS316 20/20 20 61. Tank MS 1.-7 20 62. Storage Tank MS 18.-20 4 63. Storage Tank PP/FRP 20 1 64. Filter MS 5 m2 2 65. Filter MS 5 m2 4 66. Cooling Tower PP/FRP 250 TR 2 67. Chilling Compressor CI 75 TR 3 68. Chilling Compressor CI 35 1 69. Chilling Compressor CI 150 1 70. Chillier Condenser MS 48 m2 10 71. Cooling Tower PP/FRP 250 TR 3





Sr. No.



72. Cooling Tower WOODEN 300 TR 1 73. Oil & Grease Tarp RCC 8.5 3 74. Collection Tank RCC 17.5 1 75. Equalisation Tank RCC 78 2 76. Equalisation Tank RCC 150 1 77. Equalisation Tank RCC 100 2 78. Bioreactor RCC 871 1 79. Bioreactor RCC 150 1 80. Clarifier RCC 85 1 81. Clarifier RCC 31 1 82. Sand Filter MS/RL 1 2 83. Carbon Filter MS/RL 3 1 84. Pump SS316 20/20 28 85. Pump CI 20/20 6 86. Pump PP 20/20 30 87. Tank HDPE 5 - 20 15 88. MEE TI/SS 3 KL / HR 1 89. Stripper SS316 3 KL /HR 1 Proposed 1. Reactor SS316 8 2 2. Reactor SS316 6 1 3. Reactor GLR 12.5 3 4. Reactor GLR 10 1 5. Ejector System SS316 5 TOR 1 6. Cooling Tower PP/FRP 250 TR 2 7. Pump SS316 20 m3/20 MH 12 8. Pump CI 200 m3/30 MH 8 9. Pump CI 20 m3/25 MH 7 10. Pump PP 30 m3/30 MH 10 11. Pump PP 20 m3/20MH 10





Sr. No.



12. Storage tank MS 20 6 13. Storage Tank MS 18 4 14. Storage Tank MS 15 4 15. Storage Tank SS316 1 3 16. Storage Tank SS316 5 1 17. Storage Tank SS316 10 1 18. Storage Tank SS316 20 1 19. Storage Tank HDPE 1 1 20. Storage Tank HDPE 5 1 21. Storage Tank HDPE 10 2 22. Storage Tank HDPE 20 1 23. Scrubber (Water Cir) HDPE 600 DIA

* 3000 H 1

24. Scrubber (Caustic Cir) HDPE 600 DIA * 3000 H

1

2.7 POLLUTION POTENTIAL SCENARIO The details of pollution generation in terms of effluent generation, sewage generation, and flue gas emission, process emission and hazardous waste generation is covered in this section. 2.7.1 EFFLUENT AND SEWAGE GENERATION As per consent, the industrial effluent generation is 79 KL/Day and sewage generation is 20 KL/Day. Concentrated & toxic effluent stream of 11.7 KL/Day is sent for in-house incineration. Existing effluent is treated in ETP having primary, secondary and tertiary treatment. Treated water is sent to CETP. After proposed expansion, total industrial effluent generation will be 242KL/Day (79 KL/Day + 163 KL/Day).After expansion sewage generation will be 60 KL/Day (20 KL/Day + 40 KL/Day).After proposed expansion, concentrated & toxic effluent stream of 11.7 KL/Day is sent to common incineration facility for incineration. Remaining water will be treated in unit’s own treatment plant and recycled back using RO and MEE system.





The details of waste water generation are given in following Table.2.15 TABLE: 2.15 DETAILS OF WASTE WATER GENERATION

Sr. No.

Section Waste Water Generation KL/Day Existing Quantity As per Consent No AWH-53342

Waste water Generation As Per Proposed Expansion

Total

1. Domestic 20 40 60 2. Industrial 2.1 Process 62.3 74.7 137 2.2 Washing 10 20 30 2.3 DM plant 0 5 5 2.4 Cooling 6.7 63.3 70 Total

(Industrial) 79 163 242

Total ( Domestic + Industrial)

99 203 302*

* Unit will become zero liquid discharge. 2.7.2 GASEOUS EMISSION The sources of flue gas emission are two D.G. sets (emergency use only). There will be one additional D.G. stack due to proposed expansion. Process emission is from one stack attached to reactor of 2-Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene. There will be one additional stack attached to chlorinator reactor, one stack of SFD Dryer and one stack attached to Dizo vessels due to proposed expansion. Details of stack height, fuel consumption, air pollution control system etc. are shown in below Table.2.16. TABLE: 2.16 DETAILS OF FLUE GAS EMISSION Stack. No.

Stack Attached To

Stack Height (Meter)

Type of Fuel

Parameter Permissible Limit

As Per Consent No. AWH-53342 1. DG Set

(450 KVA) 11 60 L/Hr

Particulate Matter SO2

150mg/Nm3 100 PPM





Stack. No.

Stack Attached To


Type of Fuel

Parameter Permissible Limit

NOx 50 PPM 2. DG Set

(380 KVA) 11 40 L/Hr Particulate

Matter SO2 NOx

150mg/Nm3 100 PPM 50 PPM

As Per Proposed Expansion 3. DG Set

(750 KVA) 11 150

L/Hr Particulate Matter SO2 NOx

150mg/Nm3 100 PPM 50 PPM

TABLE: 2.17 DETAILS OF PROCESS EMISSION Stack No.

Stack Attached To


APCM Probable Pollutants

Permissible Limit

As Per Consent 1. Reactor of 2-

Bromo 4Flouro Acetanilide/ Di Chloro Bromo Benzene

16 Water Scrubber followed by Alkali Scrubber

Br2 HBr

09mg/Nm3 20 mg/NM3

As Per Proposed Expansion 2. Chlorinator 11 Water

Scrubber followed by Alkali Scrubber

Cl2 HCl

09 mg/Nm3 20 mg/Nm3

3. SFD dryer 11 Water scrubber PM 150 mg/Nm3 4. Dizo vessels 11 Water

Scrubber followed by Alkali Scrubber

NOx HCl

25mg/Nm3 20 mg/Nm3





TABLE: 2.18 DETAILS OF PROCESS GASES SEND TO SCRUBBER Sr. No.

Gases Come out from process Quantity in MT/Day

1. HBr Gas-( Di Chloro Bromo Benzene)

0.9722

2. HCl Gas (2,4,6 TCA)/OR HCl Gas (DCPNA)

8.97/OR6.95

2.7.3 HAZARDOUS WASTE GENERATION The following type of hazardous waste will be generated from the operational activities. All the waste will be stored separately in a designated storage area. TABLE: 2.19 DETAILS OF HAZARDOUS WASTE GENERATION Sr. No.

Type of Hazardous Waste

Cat. No.

Quantity as Per Consent (MT/Year)

Quantity as Per Proposed Expansion (MT/Year)

Treatment And Disposal

1. ETP Waste 34.3 1090 5760 Collection, Storage, transportation, disposal at TSDF site.

2. MEE Salt 34.3 0 1440 Collection, Storage, transportation, disposal at TSDF site.

3. Distillation Residue

26.1 481.2 3675.12 Collection, storage, Transportation, disposal by sending to Common Incineration. /co processing site.

4. Discarded Containers

33.3 8

16

Collection, Storage, Decontamination and reuse





Sr. No.


Cat. No.




Bags/ Liners 39.8 80 or sold to actual reuses. 5. Used Oil 5.1 0.6

KL/Year 2.4 KL/Year

Collection ,storage, Transportation, Disposal by selling registered re processors

6. Spent Catalyst

--- 8.4 850.92 Collection, Storage, Transportation, disposal at registered regenerators.

7. Spent Solvent 20.2 1.2 1.2 Collection, storage, Transportation, disposal by sending to Common Incineration./ co processing site.

8. Spent Filter Cloth

35.1 700 Nos./Year

1500 Nos./Year

Collection, Storage, Transportation, disposal at TSDF site.

9.

Date Expired Pesticide

29.3 2 4 Collection, storage, Transportation, disposal by sending to Common Incineration. / Co processing site.

10. Spent Carbon 35.3 0 83 Collection, storage, Transportation, disposal by sending to Common Incineration. / Co processing site.

11. Gypsum 34.3 0 2640 Collection, Storage, Transportation, disposal at





Sr. No.


Cat. No.




TSDF site/cement industry.

12. Insulation Waste

-- 0 4 Collection, Storage, Transportation, disposal at TSDF site.



ENVIRONMENT IMPACT ASSESSMENT REPORT M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI.

M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.1

Chapter – 3 BASELINE ENVIRONMENT STATUS

3.1 INTRODUCTION It is essential to monitor the environment quality prevailing in the surrounding area before implementation of the proposed project for assessing the environmental impacts from proposed project. The Environment status within the study area could be used for identification of significant environmental issues to be addressed in the impact assessment study. The impact from an existing industrial project on its surrounding environment are mainly regulated by, The nature of the pollutants, Their quantities discharged to the environment, Existing environment quality Assimilative capacity of the surrounding environment and Topography and terrain of the project site. In order to identify and establish the extent of likely impacts, it is necessary to gather information on existing environmental quality relating to various components of the environment. Primary data were collected for baseline collection. Secondary data were also gathered for remaining information like meteorological data, Socio-economic data, Ecological data and Land use data. For the purpose of collection of primary data, study area was selected within 10 km radius taking as project site as a center which also included towns and villages. The main factor of local, sub-regional and regional meteorology that influence the air quality in area of the proposed project are diurnal and seasonal wind pattern and wind direction, humidity ,temperature etc. Vapi is a very important industrial center having the advantage of close proximity to Mumbai, the commercial capital of India. Due to NH-8 and Vapi railway station, GIDC is well connected by road and rail to rest parts of the country. Communication facility available in the area is good. Water is available from GIDC.



Vapi is large industrial estate with a number of chemical plants, paper mill, textile processing plants and other allied industries totaling to about more than 705 units. Lists of major industries in the Vapi are given in Table no. 3.1 TABLE: 3.1 LIST OF MAJOR INDUSTRIES IN THE VAPI Sr. No.

Name Of The Company Type Of Industry

1. K.V. Arochem Limited Organic chemicals 2. Aegis Chemicals Limited Chemical 3. Amantech Chemicals Pvt. Limited Chemical 4. Arochem Industries Chemical 5. Bhageria Dye-Chem Limited Chemical 6. Brighton Inorganic Pvt. Limited Chemical 7. Manglam organics Limited Chemical 8. Phthalo colours & chemicals Pvt. Limited

(Unit-1) Pigment

9. Sarna Chemicals Pvt. Limited Dye intermediates 10. Hindustan inks and organics pigments

Limited Chemicals

11. Phthalo Colours & Chemicals (I) Pvt. Limited (Unit II)

Pigments

12. Mangalam drugs Limited Bulk drugs and intermediated

13. Dhiraj Intermediates Pvt. Limited (Unit II) Dyes Intermediates 14. Dhiraj Intermediates Pvt. Limited(Unit I) Pigments 15. Makwell Plasticizer Pvt. Limited Chemical 16. Makwell Organics Pvt. Limited Chemical 17. Mitsu Limited Agrochemicals 18. Nascent Chemicals Limited Chemical 19. Nath Industrial hem Limited Chemical 20. Numet Industries Chemical 21. Pidilite Industries Chemical



Sr. No.


22. Rishiroop Organics Pvt. Limited Chemical 23. Supreet Chemicals Pvt. Limited Chemical 24. United Phosphorous Limited Agrochemicals 25. Vadilal Chemicals Chemical 26. Perstorp Aegis Limited Chemical 27. Amoli Organics Limited Bulk drugs 28. Essel Mining and industries Chemicals 29. Duphar interfran Limited Pharmaceutical 30. MM Labs Pharmaceutical 31. Sun Pharmaceuticals Ind. Ltd. Pharmaceutical 32. Umedica Laboratories Limited Pharmaceutical 33. Supreme Non wovens Limited Roof liners 34. Daman Ganga Boards Limited Paper 35. Nathani Paper Mills Limited Paper 36. NR Paper Mills Limited Paper 37. Ruby Macons Limited Paper 38. Shah Paper Mills Limited Paper 39. Prayag tex prints Limited Textiles 40. Navin Chemicals Dyes 41. Techno Colour Corporation Dyes 42. Pramanik tex fab Pvt. Ltd. Textile 43. Gujarat Axles and forgins pvt. Ltd. Engineering 44. Gujarat Electromag Industries Pvt. Ltd. Engineering 45. Kabra Extru- Technics Limited Engineering 46. Pragati Engineering Engineering 47. Bilag Industries Agrochemicals 48. Micro Inks Inks & Organic

Pigments 49. Themis Medicare Limited. Pharmaceutical 50. Ritcher Themis Ltd. Pharmaceutical



Sr. No.


51. Perstrop Industries Ltd. Agrochemicals 52. Heranba Industries Ltd. Agrochemicals 53. Rotam India Ltd. Agrochemicals

M/s. Aarti Industries Ltd. (Alchemie Organics Division) is located in GIDC Estate, Vapi. The location aspects of the site are provided in Table no.1.5 in Chapter 1. For Baseline Study, the monthly meteorological data for study period from March 2014 to May 2014 is shown at below Table no.3.2. Meteorological data like hourly wind speed, hourly wind direction, hourly temperature, hourly relative humidity and monthly rainfall of Valsad station are attached as annexure-XV. 3.2 WINDROSE Based on the meteorological data, wind rose have been prepared for the summer season period between the March 2014 to May 2014. The wind rose prepared from same data is shown at Figure 3.1 TABLE: 3.2 METEOROLOGICAL DATA (Data from Indian Meteorological Department, Ahmadabad, Station:-VALSAD) Month -- Temp.

(°C) Relative Humidity (%)

Wind Speed km/hr

Rainfall mm

March-14 Min 12.8 24 0 0.0 Max 33.6 85 15 Average 23.2 54.5 7.5

Apr-14 Min 19.2 33 0 0.0 Max 40 84 27.8 Average 29.6 58.5 13.8

May-14 Min 19.2 39 0 0.0 Max 36.6 81 16.7 Average 27.9 60 8.35



FIGURE: 3.1 WIND ROSE DIAGARM FOR PEROID OF MARCH TO MAY 2014



FIGURE: 3.2 WIND CLASS FREQUENCY DISRTIBUTION

3.3. AIR ENVIRONMENT 3.3.1 AMBIENT AIR QUALITY (AAQ) The basic objective of collection of base line data for air environment is to identify project specific air pollutants being released into atmosphere, which will have significant impact on air environment of immediate locality of the proposed project site. For assessment of the baseline data it is important to specify the study area in respect of the location of the proposed project. It was decided to the study ambient air quality at 8 locations in the different direction in probable impact zone including the project site. 3.3.1.1 LOCATION OF AAQ MONITORING STATIONS Ambient air quality stations were chosen considering the various factors like the most prevailing wind direction, pockets of habitation, available infrastructure facilities like power supply, accessibility etc. The location of AAQ monitoring stations are shown in Figure no.3.3 and Table no. 3.3.



TABLE: 3.3 DETAILS OF SAMPLING LOCATION OF AMBIENT AIR QUALITY MONITORING Sr. No.

Location Direction from the site

Distance in Km District

1. Project Site (A1) -- -- Valsad 2. Karvad (A2) SE 1.59 Valsad 3. Khacharva (A3) ENE 2.72 Valsad 4. Chanod (A4) SW 2.24 Valsad 5. Dungrifalia (A5) S 1.61 Valsad 6. Chharwada (A6) NNW 2.5 Valsad 7. Rata (A7) NE 2.8 Valsad 8. Balitha(A8) NW 3.93 Valsad 9. Vankachi(A9) ESE 4.04 Valsad

FIGURE: 3.3 LOCATION OF AMBIENT AIR QUALITY MONITORING STATIONS

N



3.3.1.2 BASE LINE DATA The ambient air quality monitoring was carried out during period of March, 2015 to May, 2015. Monitoring details like location, monitoring date, concentration of pollutants are attached as annexure-XVI. The frequency of monitoring was twice in a week for a period of 12 weeks to assess the existing the sub regional air quality status. All the sampling locations were monitored for PM2.5, PM10, SO2 and NOx, HCl, HBr and Br2 on 24 hr basis to enable the comparison with ambient air quality standards prescribed by the Central Pollution Control Board (CPCB). Based on the data obtained through ambient air quality survey statement showing maximum, minimum average concentration values of different monitoring location in the study area have been computed and presented at Table no.3.4. TABLE: 3.4 AMBIENT AIR QUALITY STATUS OF STUDY AREA

PM 10 µg/m3 (Permissible Limit : 100 µg/m3) Location Min. Value Max. Value Avg. Value Project Site (A1) 90.7 97.8 93.12 Karvad(A2) 89.5 95.8 92.45 Khacharva(A3) 86.5 95.2 91.01 Chanod(A4) 88.5 97 92.7 Dungrifalia(A5) 75.8 94.5 85.90 Chharwada(A6) 85 95 90.04 Rata(A7) 86.3 95.2 91.32 Balitha(A8) 87.5 94.5 90.28 Vankachi(A9) 89.2 95.8 92.12

PM 2.5 µg/m3 (Permissible Limit : 60 µg/m3) Location Min. Value Max. Value Avg. Value Project Site (A1) 48.4 57.7 53.03 Karvad(A2) 45 48.5 46.48 Khacharva(A3) 43 55.6 48.19



Location Min. Value Max. Value Avg. Value Chanod(A4) 40.5 56 48.55 Dungrifalia(A5) 42.5 50 45.54 Chharwada(A6) 40 50 44.25 Rata(A7) 38.6 54.2 46.92 Balitha(A8) 42.5 52.3 46.7 Vankachi(A9) 41 53 45.75

SO2 µg/m3(Permissible Limit :80 µg/m3) Location Min. Value Max. Value Avg. Value Project Site (A1) 30.3 33.9 31.92 Karvad(A2) 22 32 27 Khacharva(A3) 28.6 34.5 31.20 Chanod(A4) 28.6 35.0 32.10 Dungrifalia(A5) 28.8 35 31.54 Chharwada(A6) 25.5 32.5 28.81 Rata(A7) 28.8 33.9 31.35 Balitha(A8) 21.5 32.5 27.38 Vankachi(A9) 22.0 30.5 25.72

NOX µg/m3 (Permissible Limit : 80 µg/m3) Location Min. Value Max. Value Avg. Value Project Site (A1) 39.4 47.7 43.33 Karvad(A2) 35.0 48 40.87 Khacharva(A3) 38.5 44.2 41.03 Chanod(A4) 35.5 47.5 40.86 Dungrifalia(A5) 38.9 47.7 43.27 Chharwada(A6) 38.5 47.5 42.54 Rata(A7) 38.1 42.8 40.44 Balitha(A8) 37.5 46.2 42.45



Location Min. Value Max. Value Avg. Value Vankachi(A9) 35 49 43.04

HCl µg/m3 Location Min. Value Max. Value Avg. Value Project Site (A1) BDL BDL BDL Karvad(A2) BDL BDL BDL Khacharva(A3) BDL BDL BDL Chanod(A4) BDL BDL BDL Dungrifalia(A5) BDL BDL BDL Chharwada(A6) BDL BDL BDL Rata(A7) BDL BDL BDL Balitha(A8) BDL BDL BDL Vankachi(A9) BDL BDL BDL

VOC Location Min. Value Max. Value Avg. Value Project Site (A1) 3.2 5.0 4.10 Karvad(A2) 2 3.8 2.68 Khacharva(A3) 0 6 3.0 Chanod(A4) 4.7 6.2 5.16 Dungrifalia(A5) 3.5 5.0 4.21 Chharwada(A6) 3 5.9 4.35 Rata(A7) <1 <1 <1 Balitha(A8) 3.1 6.4 4.7 Vankachi(A9) 0 6 3.44

NH3 (µg/m3) Location Min. Value Max. Value Avg. Value Project Site (A1) 1.4 3.8 2.62 Karvad(A2) 1.9 3.2 2.52 Khacharva(A3) 1.2 3.5 2.50 Chanod(A4) 1.43 3.2 2.55 Dungrifalia(A5) 1.7 3.2 2.43



Location Min. Value Max. Value Avg. Value Chharwada(A6) 1.4 3.2 2.56 Rata(A7) 1.8 3.5 2.66 Balitha(A8) 1.9 3.6 2.5 Vankachi(A9) 1.9 3.5 2.61

Chlorine Location Min. Value Max. Value Avg. Value Project Site (A1) <0.1 <0.1 <0.1 Karvad(A2) <0.1 <0.1 <0.1 Khacharva(A3) <0.1 <0.1 <0.1 Chanod(A4) <0.1 <0.1 <0.1 Dungrifalia(A5) <0.1 <0.1 <0.1 Chharwada(A6) <0.1 <0.1 <0.1 Rata(A7) <0.1 <0.1 <0.1 Balitha(A8) <0.1 <0.1 <0.1 Vankachi(A9) <0.1 <0.1 <0.1

CO (mg/m3) Location Min. Value Max. Value Avg. Value Project Site (A1) 815 990 903 Karvad(A2) 712 889 798 Khacharva(A3) 608 789 703 Chanod(A4) 714 876 796 Dungrifalia(A5) 756 867 804 Chharwada(A6) 714 889 795 Rata(A7) 600 789 701 Balitha(A8) 604 789 713 Vankachi(A9) 734 891 798

HBr Location Min. Value Max. Value Avg. Value Project Site (A1) BDL BDL BDL Karvad(A2) BDL BDL BDL



Location Min. Value Max. Value Avg. Value Khacharva(A3) BDL BDL BDL Chanod(A4) BDL BDL BDL Dungrifalia(A5) BDL BDL BDL Chharwada(A6) BDL BDL BDL Rata(A7) BDL BDL BDL Balitha(A8) BDL BDL BDL Vankachi(A9) BDL BDL BDL

Br2 Location Min. Value Max. Value Avg. Value Project Site (A1) BDL BDL BDL Karvad(A2) BDL BDL BDL Khacharva(A3) BDL BDL BDL Chanod(A4) BDL BDL BDL Dungrifalia(A5) BDL BDL BDL Chharwada(A6) BDL BDL BDL Rata(A7) BDL BDL BDL Balitha(A8) BDL BDL BDL Vankachi(A9) BDL BDL BDL

*BDL: Below Detectable Limit Based on data obtained, it could be stated that, during the study period the value of PM10 at monitored locations is ranged between 75.8 - 93.12 μg/m3 while the value PM2.5 fluctuates in the range of 38.6 - 57.7 μg/m3. The value of SO2 and NOx were observed to be in the range of 21.5-35 μg/m3 and 35-49 μg/m3 respectively. The values of HCl, HBr and Br2 were found Below Detectable Limit. The average concentration of PM10, PM2.5, SO2 and NOx are within prescribed limit at all locations. These concentrations at all AAQM locations were primarily caused by local phenomena including vehicular movement and natural dusting due to human activities and wind movement.



3.4 WATER ENVIRONMENT There are two categories of water environment: 1) Ground water: - accumulation in deeper strata of ground and 2) Surface water: - river, drains, canals, ponds etc. Five locations were selected for ground water sampling and eight locations were selected for surface water sampling. Collected samples were analyzed for drinking water quality parameters like physic-chemical parameters and heavy metals. During study period, the sampling was done for one time. The map viewing location for sampling points is shown at Figure 3.4 and Figure 3.5. The analysis results are presented at Table no.3.8 and Table no.3.9. FIGURE: 3.4 LOCATION OF GROUND WATER QUALITY MONITORING STATIONS



TABLE: 3.5 DETAILS OF GROUND WATER MONITORING LOCATIONS Sr. No.

Sampling locations Sample ID

Distance & Direction w.r.t project site

Type of Area

1. GIDC water supply (Project Site)

GW1 -- Industrial

2. Khacharva GW2 2.72 Km, ENE Residential Area 3. Chanod GW3 2.24 Km, SW Residential Area 4. Rata GW4 2.8 Km, NE Residential Area 5. Balitha GW5 3.93 Km, NW Residential Area

FIGURE: 3.5 LOCATION OF SURFACE WATER QUALITY MONITORING STATIONS



TABLE: 3.6 DETAILS OF SURFACE WATER MONITORING LOCATIONS Sr. No.

Sampling locations Sample ID

Distance & Direction w.r.t project site

Type of Area

1. GIDC water supply (Project Site)

SW1 -- Industrial

2. Khacharva SW2 2.72 Km, ENE Residential Area 3. Chanod SW3 2.24 Km, SW Residential Area 4. Rata SW4 2.8 Km, NE Residential Area 5. Balitha SW5 3.93 Km, NW Residential Area

Sampling Method The samples were collected as per Indian standard (IS: 3025 (part-1) for ground water and surface water quality assessment. Analysis Method The analysis method followed for the measuring different parameters to evaluate water quality is given in Table no. 3.7. TABLE: 3.7 METHOD OF ANALYSIS

Sr. No.

Parameters Applicable Standard Method of Analysis

Detection Limit

1. Color in Pt. Co. Sc. APH (22nd Edition) Spectrophotometer (analogous to APHA 2120 C) (Platinum Cobalt Method)

1

2. pH APHA(22nd Edition) 4500 H+ B Electrometric Method

0.01 3. Total hardness

(as CaCO3) in mg/l APHA(22nd Edition) 2340 C: Page 2 – 37 EDTA Titrimetric Method

2 4. Chloride (as Cl) in

mg/l APHA(22nd Edition) 4500-Cl-B-Argentometric method

1 5. TDS in mg/l APHA (22nd Edition) 2540 C Total

Dissolved Solid Dried at 180˚C 4



Sr. No.

Parameters Applicable Standard Method of Analysis

Detection Limit

6. TSS in mg/l APHA (22nd Edition) 2540-D-Total Suspended Solids Dried at 103-1050C

4 7. Calcium (as Ca) in

mg/l APHA (22nd Edition) 3500- Ca : B Page 3 – 65 EDTA Titrimetric Method

2 8. Magnesium(as Mg) in

mg/l APHA(22nd Edition) – 3500 - Mg : B Page 3 – 84 Calculation Method

2 9. Sulphate (as SO4) in

mg/l APHA (22nd Edition) 4500–SO4-2 E: Page 4-188 Turbid metric Method/ IS 3025 (Part 24) 1986 (Reaffirmed 1986) Gravimetric Method

1

10. Alkalinity (as CaCO3) in mg/l

APHA (22nd Edition) – 2320 B: Page 2 – 27 Titration Method

2 11. COD in mg/l APHA(22nd Edition)– 5220 B Open

Reflux Method 4

12. BOD in mg/l IS: 3025 (Part – 44) 1993 (Reaffirmed 1999)

1 13. MPN Coliform

Count APHA -9221 C --

14. E.coli APHA- 9221 D (Presence Absence Test) -- 15. Nitrate in mg/l Spectrophotometer 1 16. Iron (as Fe) in mg/l By NOVA 60 spectrophotometer

(Triazine) 0.01

17. Fluoride (as F) in mg/l By NOVA 60 spectrophotometer 0.1 18. Residual Free

Chlorine in mg/l Iodometric method 1

19. Sodium in mg/l Flame photo meter -- 20. Potassium in mg/l Flame photo meter -- 21. Ammonical Nitrogen

in mg/l APHA-4500 N ORGBnC macro and semi-micro KJELDHAL

2.8



TABLE: 3.8 WATER QUALITY PARAMETERS (GROUNDWATER SOURCES)

Parameter Unit IS 10500 : 1991 Desirable Limit

Permissible Limit

Project site (GW1)

Khacharva (GW2)

Chanod (GW3)

Rata (GW4)

Balitha (GW5)

pH --- 6.5 – 8.5 6.5 –8.5 7.58 7.98 7.6 7.35 7.56 Color Pt.

co.sc 5 25 5 5 5 5 5

TDS mg/L 500 2000 892 1988 434 595 1056 Total hardness (as CaCO3)

mg/L 300 600 495 1059 225 375 745 Chloride (as Cl) mg/L 250 1000 190 865 194 236 213 Calcium (as Ca)

mg/L 75 200 138 232 55 375 126 Magnesium (as Mg)

mg/L 30 100 46 120 38 240 49 Iron (as Fe) mg/L 0.3 1 0.55 0.50 0.5 0.17 0.21 Fluoride (as F) mg/L 1 1.5 0.45 0.72 0.85 0.8 0.34 Sodium (as Na) mg/L -- -- 126 350 31 66 67 Potassium (as K) mg/L -- -- 26 85 18 30 27 Sulphate (as SO4)

mg/L 200 400 203 5 5 4 6 Nitrate mg/L 45 45 0.3 3.8 1.4 0.69 2.4 Alkalinity(as CaCO3)

mg/L 200 600 356 537 240 238 345 COD mg/L -- -- <4 <4 <4 <4 <4 BOD mg/L -- -- <4 <4 <4 <4 <4 Free Residual Chlorine

mg/L -- -- ND ND ND ND ND



Parameter Unit IS 10500 : 1991 Desirable Limit

Permissible Limit

Project site (GW1)

Khacharva (GW2)

Chanod (GW3)

Rata (GW4)

Balitha (GW5)

MPN Coli form Count

mg/L 1 10 ND ND ND ND ND E. coli mg/L Absent -- Absent Absent Absent Absent Absent

*ND-Not Detected Detectable limit for COD- 4 mg/l BOD- 1 mg/l Free Residual Chlorine- 1 mg/l



TABLE: 3.9 WATER QUALITY PARAMETERS (SURFACE WATER SOURCES)

Parameter Unit IS 10500: 1991 Sampling location Desirabl

e Limit

Permissible

Limit SW1

Khacharva

SW2 Rata

SW3 Karvad

SW4 Balitha

Colour Pt.co.sc

5 25 2 5 5 3 Odour --- Unobject

ionable -- Unobject

ionable Unobjectionabl

e Unobjectionable

Unobjectionable

pH --- 6.5 -8.5 6.5-8.5 7.29 7.6 7.11 7.50 Total hardness (as CaCO3)

mg/L 300 600 143 181 123 155

Chloride (as Cl)

mg/L 250 1000 33 38 34 50 TDS mg/L 500 2000 171 258 179 215 Calcium (as Ca)

mg/L 75 200 44 50 42 41 Magnesium (as Mg)

mg/L 30 100 9 11 8 10 Iron mg/L 0.3 1 0.54 0.5 0.5 0.30 Fluoride mg/L 1 1.5 0.9 0.9 0.8 0.05 Na mg/L -- -- 21 18 20 18 K mg/L -- -- 6 7 5 6 Sulphate (as SO4)

mg/L 200 400 6 4 3 5 Nitrate mg/L 45 45 1.7 1.6 1.89 1.55 Alkalinity (as CaCO3)

mg/L 200 600 134 136 139

150 COD mg/L -- -- 14 10 13 15 BOD mg/L -- -- 4 4 4.2 5.8 MPN Coli form Count

mg/L 1 10 <1.8 CFU/100 ML

E. coli mg/L Absent -- Absent

Absent Absent Absent



3.5 NOISE ENVIRONMENT To estimation of background noise level, noise measurement was done within the study area using the sound level meter. The locations where noise level measurements were done are shown at Figure 3.6. FIGURE: 3.6 LOCATION OF NOISE MONITORING STATIONS

TABLE: 3.10 CPCB RECOMMENDATIONS FOR COMMUNITY NOISE EXPOSURE (1989) Category of area Leq. (dBA)

(Day time) (06:00 to 21:00 hrs.)

Leq. (dBA) (Night time) (21:00 to 06:00 hrs.)

Industrial area 75 70 Commercial Area 65 55 Residential Area 55 45 Silence Zone 50 40



TABLE: 3.11 NOISE LEVEL DATA Sr. No.

Location Area Category LEQ (dB (A)) Day Time Night Time

1. Project Site (A1) Industrial 53-72 45-53 2. Karvad(A2) Residential 53-61 42-52 3. Kocharva(A3) Residential 52-59 41-51 4. Chanod(A4) Residential 48-55 37-47 5. Dungrifalia(a5) Residential 49-57 44-49 6. Chharwada(A6) Residential 53-59 45-51 7. Rata(A7) Residential 50-55 42-50 8. Balitha(A8) Residential 48-53 41-45 9 Vankachh(A9) Residential 50-53 42-46

OBSERVATION & DISCUSSION The noise levels during daytime varied from 48-53 dB (A)Leq to 53-72 dB (A) Leq in the study area. The noise level in the study area is within the permissible Limits as per Noise rules 2000. The night time noise level in the study area is in the range of 41-45 dB (A) Leq to 45-53 dB (A) Leq. The night time noise was also within stipulated standards of CPCB. 3.6 SOIL 3.6.1 BASELINE DATA Description of soil environment has become vital particularly when the treated effluent is to be discharge on land for disposal or treatment. The soil environment is usually described by determining the physical and chemical characteristics of soil samples collected from site with the help of auger/spade. The composite soil sample was collected from project site and the villages Within 10 km radius. The samples were collected to determine physical and chemical characteristic of soil. The selected soil sampling locations are given in Table no. 3.12 and shown in Figure no. 3.6.



TABLE: 3.12 LOCATIONS OF SOIL QUALITY MONITORING WITH RESPECT TO THE PROJECT SITE Sr. No.

Location Direction from the site

Distance in Km

District

1. Project Site (S1) -- -- Valsad 2. Vapi (S2) WNW 4.4 Valsad 3. Chirri (S3) NE 3.9 Valsad 4. Karwad (S4) E 4 Valsad 5. Dungri falia (S5) E 4.53 Valsad 6. Chandor (S6) WS 1.32 Valsad

FIGURE: 3.7 LOCATION OF SOIL MONITORING STATIONS



TABLE: 3.13 PARTICLE SIZE DISTRIBUTION OF SOIL SAMPLES Sr. No.

Parameters Unit Sampling Locations Project site (S1)

Vapi(S2)

Chirri(S3)

Karwad (S4)

Dungra(S5)

Chandor(S6)

1. pH (5%) -- 7.85 8 8.10 8.75 7.62 8.15 2. EC Us 428 528 392 565 250 262 3. Sodium ppm 284 265 325 328 292 250 4. Potassium ppm 345 347 288 248 190 200 5. Nitrogen mg/100g

m 1.58 1.82 1.65 1.50 1.33 1.45

3.7 LAND USE PATTERNS The land use pattern of the study area has been studied by satellite imaginary picture of National Remote Sensing Centre, Govt. of India. Details are covered in Table No. 3.14. TABLE: 3.14 LAND USE STATISTICS OF THE STUDY AREA Sr. No.

Class Name Area (Hectares)

Area(Sq. m) Area (%) 1. Water Body 102.963 1.03 0.33 2. Open/Barren Land 15589.9 155.90 49.58 3. Agriculture Land 5789.85 57.90 18.41 4. Fallow Land 1973.51 19.74 6.28 5. Open/Degraded

vegetation 3713.25 37.13 11.81

6. Vegetation Medium Density

150.393 1.50 0.48 7. Vegetation High

density 14.6075 0.15 0.05

8. Plantation/orchards 959.952 9.60 3.05 9. Grass Land 0.9675 0.01 0.00 10. Scrubs 0 0.00 0.00 11. Ravenous/Gullied Land 0 0.00 0.00 12. River & Canal 797.23 7.97 2.54 13. Marshy Land 252.507 2.53 0.80



Sr. No.

Class Name Area (Hectares)

Area(Sq. m) Area (%) 14. Salt affected Land 0 0.00 0.00 15. Settlement &

Habitation 880.655 8.81 2.80

16. Mud flat 24.05 0.24 0.08 17. Sand/Beach 47.185 0.47 0.15 18. Jetty 0 0.00 0.00 19. Salt pans 4.28 0.04 0.01 20. Mangrove (Sparse) 10.1325 0.10 0.03 21. Mangrove (Dense) 0 0.00 0.00 22. Marshy Vegetation 6.9975 0.07 0.02 23 Mines 44.8375 0.45 0.14 24 Stony waste/Rocky

Area 0 0.00 0.00

25 Industrial Area 870.558 8.71 2.77 26 Miscellaneous 0 0.00 0.00 27 Sea 30.0825 0.30 0.10 28 Snow 0 0.00 0.00 29 River Bed 115.473 1.15 0.37 30 Seasonal Water Body 66.625 0.67 0.21 Total 314446.01 314.46 100



FIGURE: 3.8 LAND COVER MAP WITH VILLAGE LOCATION



3.8 BIOLOGICAL ENVIRONMENT & SOCIO –ECONOMIC ENVIRONMENT 3.8.1 ECOLOGICAL INFORMATION The study of the environmental components like flora and fauna is required to assess the biological diversity of the region. Flora and fauna can be used for biological surveillance in assessing the environmental status. The ecological interpretation of study area is based on secondary sources of information. Water is the basic and essential resource for the survival of flora and fauna. The flora being the primary producer influences the fauna of the region. The characteristic flora existing in a region depends upon the existing conditions such as intensity of sunlight, type of soil, quality of air, including the quality and quantity of water available, etc. 3.8.2 FOREST There are patches of reserved forest and protected forests within 10 kms radial periphery of the study area. The map of reserved forest is shown in Figure No.3.8. The entire zone of Valsad district that comprises of maritime coastal environment and also the upland forest in the North-East has been classified as Tropical Moist Deciduous Forest. The reserved forest is having also maritime climate and the habitat serves as an ecological niche several plant species of terrestrial realm, and form important nature conservation sites. 3.8.3 FLORA The list of flora found during field survey is given in Table no. 3.15. TABLE: 3.15 LIST OF FLORA Sr. No.

Scientific Name Common Name 1. Psilostachya seriea --- 2. Lannea coromandelica Wodier 3. Mangifera indica Aam 4. Calotropis procera Ak 5. Nerium indicum Kaner 6. Rauvolfia tetrafylla Bara Chand 7. Tabernaemontana coronaria Tagar



Sr. No.

Scientific Name Common Name 8. Vernonia anthelmintica Kaliziri 9. Millingtonia hortensis Akashneem 10. Bombax ceiba Silk cotton 11. Casuarina equisetifolia Saru 12. Garcinia xanthochymus Bottle brush 13. Anogeissus latifolia Axle wood 14. Terminalia arjuna Arjun 15. Terminalia bellerica Behda 16. Terminalia catappa Desshibadam 17. Terminalia tomentosa --- 18. Terminalia paniculata Flowering murdah 19. Cyperus esculentus Yellow nustsedge 20. Diospyros chloroxylon Ninai 21. Diospyros melanoxylum Tendu 22. Ricinus communis Eranda 23. Acacia auriculiformis Australian acacia 24. Acacia catechu Khair 25. Acacia nilotica Babul 26. Alibizia lebbeck Shirish 27. Bauhinita tomentosa Kachnar 28. Cassia fistula Amaltash 29. Cassia siamea Karamala 30. Dalbergia latifolia Pahari sheesham 31. Dalbergia sissoo Sheesham 32. Delonix elata Gamhar 33. Desmodium heterocarpum --- 34. Ougeinia dalbergioides Tiwas 35. Pithecellobium Saman Raintree 36. Pongamia pinnata Kanji 37. Prosopis juliflora Vilayati babul 38. Pterocarpus marsupium Indian Kino tree 39. Saraca indica Asoka 40. Tamarindus indica Imli 41. Vitex nequndo Shivarii 42. Parkinsonia aculeata Keerar 43. Lagerstroemia parviflora Dhuara 44. Hibiscus sabdariffa Lalambadi 45. Hibiscus schizopetalus Jaswand 46. Thespesia populnea Jaswand 47. Azadirachta indica Neem 48. Mimosa hamata --- 49. Pithacellobium duice Jangli Jilebi 50. Artocarpus heterophyllus Jacktree 51. Ficus bengalensis Bargad 52. Ficus religiosa Peepal



Sr. No.

Scientific Name Common Name 53. Moringa oleifera Shevga 54. Eucalyptus Nilgiri 55. Syzygium cumini Jamun 56. Boerhavia diffusa Lalsata 57. Bougainvillea glabra Bougainvillea 58. Oxalis corniculata Nalvari 59. Emblica officinalis Amla 60. Bambusa arundinaceae Bamboo 61. Dendro calamus strictus Bans 62. Zizyphus mauritiana Ber 63. Adina cordifolia Haldu 64. Mitragyna parvifolia Phaldu 65. Madhuca indica Mahua 66. Lindernia hyssopioides --- 67. Ailanthus excels Ajan 68. Physalis longifolia --- 69. Tamarix trupii Jhavnujhada 70. Typha angustata Patera 71. Gmelina arborea Shivan 72. Tectona grandis Sagwan 73. Borassus sp. Tad/Asian Palmyra

palm 74. Phoenix sp. Khajoori/Date Palm



FIGURE: 3.9 MAP OF RESERVED FOREST

Reference: - EIA report of Vertellus Specialty Materials (India) Pvt. Ltd., Vapi, Gujarat.



3.8.4 FAUNA Some of the fauna found in study area is listed in Table no.3.16. TABLE: 3.16 LIST OF FAUNA Sr. No.

Common Name Scientific Name Family Reptiles 1. Common cobra Naja naja Elapidae 2. Common Krait Bungarus caeruleus Elapidae 3. Land monitor Varanus albigularis Varanidae 4. Python Python molrus bivittatus Pythonidae 5. Russell s viper Daboia russelii Viperidae 6. Saw scaled viper Echis carinatus Viperidae 7. Garden lizard Catotes versicolor Agamidae 8. Rat snake Zamenis longissimus Colubridae 9. Indian chameleon Chameleon zeylanicus Chamaeleonidae 10. House qecko Hemidactylus frenatus Gekkonidae Aves 11. Cattle egret Bubulcus ibis Ardeidae 12. Common crane Gruidae Gruiformes --- 13. Common peafowl Pavo cristatus Phasianidae 14. Crow pheasant Centropus sinensis Cuculidae 15. House Sparrow Passer domesticus Passeridae 16. Gold backed

woodpecker Brachypternus aurantius Picidae

17. Green pigeon Treron phoenicoptera Columbidae 18. Grey partridge Perdix perdix Phasianhdae 19. Hoopoo Upupa epops Upupidae 20. Inian myna Acridotheres tristis Sturnidae 21. Jungle bush quail Perdicula asiatica Phasianidae 22. Jungle crow Corvus macrohynchos Corvidae 23. Red vented bulbul Red wattled lapwing Pycnonotidae 24. Red wattled lapwing Vanellus Indicus Charadriidae 25. Small Green Bee-

eater Merops orientalis Meropidae

26. Spotted dove Streptopelia chinensis Corvidae 27. Spotted owlet Athene brama Strigidae 28. Jungle owlet Glaucidium radiatum Strigidae 29. Large egret Ardea Alba Ardeidae 30. Little egret Egretta garzetta Ardeidae 31. Pond heron Ardeola grayii Ardeidae 32. Whitenecked stork Cicinia episcopus Ciconiidae 33. Black ibis Pseudibis papillosa Threskiornithidae 34. Common barbbler Turdoides caudata Timaliidae 35. Marsh harrier Circus aeruginosus Acciptridae



Sr. No.

Common Name Scientific Name Family 36. Pied crested cuckoo Clamator jacobinus Cuculidae 37. Sugari/Tailor Bird Ortotomus sutorius Sylviidae 38. Vulture Diurnilis Neophron Accipitridae 39. Samadi Milvus migrans Accipitridae 40. Duck Anatidae Anseriformes Anatidae 41. Barking deer Muntiacus Cervidae 42. Langur Semnopithecus entellus Cercopithecidae 43. Jackal Canis aures Canidae 44. Panther Panthera Pardus Felidae 45. Porcupine Hystrix indicus Hystricidae 46. Sambar Rusa unicolor Cervidae 47. Wild Boar Sus scrofa Suidae 48. Wild dog Lycaon pictus Canidae 49. Fox Vulpes vulpes Canidae 50. Bonnet macaque Macaca radiata Cercopithecidae 51. Common Mongoose Herpestes edwardsii Herpestinae 52. Squirrel Rodentia Sciurus Sciuridae 53. Rat Rattus Muridae 54. Indian hare Lepus nigricollis Leporidae 55. Indian bush rat Golunda ellioti Muridae 56. Indian field mouse Mus booduga Muridae

3.9 SOCIO-ECONOMIC ENVIRONMENT As assessment of socio-economic environment forms an integral part of an EIA study, baseline information for the same was collected during the study period. The baseline socio-economic data collected for the study region, before the proposed expansion is operational, has been identified for the four major indicators viz. demography ,civic amenities, economy and social culture. The baseline status of the above indicators is compiled in forthcoming sections. SETTLEMENTS AND DEMOGRAPHIC PATTERN 3.9.1DEMOGRAPHIC DATA WITHIN THE REGION OF INTEREST Demography covers the information related to population density sex ratio and literacy level of the public in the study area. Table no.3.17 provides the data on inhabitations of the Pardi Taluka.



TABLE: 3.17 DEMOGRAPHIC DATA Sr.No.

Rural /Urban Area

Name of area of Pardi Taluka

No. of Households

Total Population

Total Male

Total Female

1. Rural Pardi (M) 120933 518814 282572 236242 2. Rural Umarsadi 3566 16454 8296 8158 3. Rural Balda 868 3621 1888 1733 4. Rural Kumbhariya 313 1406 728 678 5. Rural Sondhalwada 577 2566 1274 1292 6. Rural Parvasa 630 2902 1459 1443 7. Rural Kachwal 314 1415 710 705 8. Rural Mota

Waghchhipa 666 2841 1448 1393

9. Rural Nana Waghchhipa

442 2061 1018 1043 10. Rural Sukhesh 1120 5019 2577 1120 11. Rural Borlai 193 821 429 193 12. Rural Sukhlav 532 2416 1190 532 13. Rural Velparva 351 1659 822 351 14. Rural Khadki 718 3126 1611 718 15. Rural Motiwada 886 3871 2076 886 16. Rural Palsana 800 3350 1666 800 17. Rural Kalsar 521 2153 1071 521 18. Rural Udwada 1447 6303 3191 1447 19.. Rural Kolak 1013 4646 2281 2365 20. Rural Kikarla 526 2332 1203 1129 21. Rural Rentlav 1029 4590 2257 2333 22. Rural Dungri 1128 4967 2563 2404 23. Rural Dashwada 121 462 241 221 24. Rural Amli 473 2253 1123 1130 25. Rural Sonwada 592 2517 1274 1243 26. Rural Varai 148 631 315 316 27. Rural Nimkhal 192 837 424 413 28. Rural Panchlai 715 3312 1661 1651 29. Rural Lakhmapor 91 432 217 215 30. Rural Nevri 390 1831 885 946 31. Rural Rabdi 350 1566 777 789 32. Rural Asma 398 1715 862 853 33. Rural Tarmaliya 488 2096 1025 1071 34. Rural Khuntej 351 1536 761 775 35. Rural Sarodhi 425 1766 887 879 36. Rural Tarakpardi 177 701 431 270



Sr.No.

Rural /Urban Area


No. of Households

Total Population

Total Male

Total Female

37. Rural Saran 338 1579 782 797 38. Rural Vatar 788 3230 1748 1482 39. Rural Kunta 1036 4019 2346 1673 40. Rural Morai 547 2192 1486 706 41. Rural Bagwada 251 1152 587 565 42. Rural Tighara 526 2254 1104 1150 43. Rural Paria 1750 7596 3853 3743 44. Rural Rohina 1274 5833 2940 2893 45. Rural Samarpada 421 1987 1028 959 46. Rural Dhagadmal 346 1601 791 810 47. Rural Daheli 551 2755 1352 1403 48. Rural Chival 786 3806 1912 1894 49. Rural Arnala 418 2015 1026 989 50. Rural Pati 233 1119 542 577 51. Rural Goima 1629 7484 3786 3698 52. Rural Barai 345 1612 831 781 53. Rural Dumalav 797 3808 1929 1879 54. Rural Tukwada 1308 5430 2873 2557 55. Rural Ambach 1558 7236 3705 3531 56. Rural Kherlav 350 1596 779 817 57. Rural Pandor 458 2091 1091 1000 58. Rural Rata 1295 5399 3078 2321 59. Rural Chharwada 2170 8806 5146 3660 60. Rural Chandor 538 2389 1215 1174 61. Rural Kocharva 540 2247 1205 1042 62. Rural Vankachh 110 523 273 250 63. Rural Koparli 932 4450 2272 2178 64. Rural Kaval 262 1293 643 650 65. Rural Karaya 749 3497 1750 1747 66. Rural Nani Tambadi 823 3790 1943 1847 67. Rural Degam 419 1968 962 1006 68. Rural Moti Tambadi 1051 5028 2508 2520 69. Rural Karamkhal 831 3525 2093 1432 70. Rural Chibhad

Kachchh 398 1919 971 948

71. Urban Pardi (M) 6278 28495 14648 13847 72. Urban Pardi (M)

ward no.-0001 1059 4660 2358 2302



Sr.No.

Rural /Urban Area


No. of Households

Total Population

Total Male

Total Female

73. Urban Pardi (M) WARD NO.-0002

1174 5536 2838 2698


840 4043 2180 1863


712 3165 1584 1581

76. Urban Pardi (M) ward no.-0005

551 2235 1167 1068 77. Urban Pardi (M)

WARD NO.-0006

1076 5006 2519 2487


866 3850 2002 1848

79. Urban Vapi (M) 39575 163630 94105 69525 80. Urban Vapi (M)

WARD NO.-0001

2891 11382 6513 4869

81. Urban Vapi (M) WARD NO.-0002

3547 14192 7711 6481


3691 15571 8228 7343


2220 10783 5651 5132


2847 11821 7252 4569


2026 7587 4463 3124


2693 12727 7568 5159


2420 9828 5957 3871


2301

10426 5507 4919



Sr.No.

Rural /Urban Area


No. of Households

Total Population

Total Male

Total Female


2784 11786 6539 5247


2251 9609 5270 4339


3445 11904 7889 4015

92. Urban Vapi (M) ward no.-0013

2751 11731 6587 5144 93. Urban Vapi (M)

ward no.-0014 3708 14283 8970 5313

94. Urban Vapi (INA) 7809 34162 18151 16011 95. Urban Vapi (INA)

WARD NO.-0001

7809 34162 18151 16011

96. Urban Orvad (CT) 1237 5420 2909 2511 97. Urban Orvad (CT)

WARD NO.-0001

1237 5420 2909 2511

98. Urban Balitha (CT) 3098 12380 7077 5303 99. Urban Balitha (CT)

WARD NO.-0001

3098 12380 7077 5303

100. Urban Salvav (CT) 1191 5486 2933 2553 101. Urban Salvav (CT)

WARD NO.-0001

1191 5486 2933 2553

102. Urban Chhiri (CT) 4757 18829 11702 7127 103. Urban Chhiri (CT)

WARD NO.-0001

4757 18829 11702 7127

104. Urban Chanod (CT) 4738 18776 10800 7976 105. Urban Chanod (CT)

WARD NO.-0001

4738 18776 10800 7976

106. Urban Karvad (CT) 1229 5746 3023 2723 107. Urban Karvad (CT)

WARD NO.-0001

1229 5746 3023 2723

108. Urban Lavachha (CT)

2186 8549 4997 3552 109. Urban Lavachha 2186 8549 4997 3552



Sr.No.

Rural /Urban Area


No. of Households

Total Population

Total Male

Total Female

(CT) WARD NO.-0001

(Source: Census-2011 for Valsad District) 3.9.2 LITERACY RATE The literacy rate is a major factor, which influences the socio-cultural condition of a particular place. Details of literacy rate in percentage in district Valsad and Taluka Pardi are given in Table no. 3.18. TABLE: 3.18 LITERACY RATE WITHIN 10 KM RADIAL DISTANCE OF STUDY AREA Sr. No.

Village Name CD Block Name

Total Population

Population < 06 Years

Population Literate

Literacy (%)

1. Umarsadi Pardi 16454 1449 13436 89.54 2. Balda Pardi 3621 319 2922 88.49 3. Kumbhariya Pardi 1406 121 1203 93.61 4. Sondhalwaa Pardi 2566 269 1936 84.28 5. Parvasa Pardi 2902 282 2215 84.54 6. Kachwal Pardi 1415 163 1008 80.51 7. Mota

Waghchhipa Pardi 2841 253 2287 88.36

8. Nana Waghchhipa

Pardi 2061 189 1553 82.95 9. Sukhesh Pardi 5019 487 3889 85.81 10. Borlai Pardi 821 59 684 89.76 11. Sukhlav Pardi 2416 243 1784 82.09 12. Velparva Pardi 1659 152 1322 87.72 13. Khadki Pardi 3126 329 2436 87.09 14. Motiwada Pardi 3871 400 2904 83.66 15. Palsana Pardi 3350 285 2406 78.49 16. Kalsar Pardi 2153 232 1636 85.16 17. Udwada Pardi 6303 549 5084 88.35 18. Kolak Pardi 4646 330 4014 93.00 19. Kikarla Pardi 2332 222 1876 88.91 20. Rentlav Pardi 4590 428 3832 92.07 21. Dungri Pardi 4967 484 3861 86.12 22. Dashwada Pardi 462 45 356 85.37 23. Amli Pardi 2253 258 1794 89.92 24. Sonwada Pardi 2517 264 1926 85.48



Sr. No.


Total Population


Population Literate

Literacy (%)

25. Varai Pardi 631 64 504 88.88 26. Nimkhal Pardi 837 74 651 85.32 27. Panchlai Pardi 3312 360 2549 86.34 28. Lakhmapor Pardi 432 48 320 83.33 29. Nevri Pardi 1831 222 1310 81.41 30. Rabdi Pardi 1566 145 1183 83.25 31. Asma Pardi 1715 193 1307 85.87 32. Tarmaliya Pardi 2096 167 1691 87.66 33. Khuntej Pardi 1536 150 1252 90.33 34. Sarodhi Pardi 1766 196 1318 83.94 35. Saran Pardi 1579 146 1245 86.88 36. Tarakpardi Pardi 701 73 578 92.03 37. Vatar Pardi 3230 301 2625 89.62 38. Kunta Pardi 4019 526 3186 91.21 39. Morai Pardi 2192 192 1756 87.8 40. Bagwada Pardi 1152 165 924 93.61 41. Tighara Pardi 2254 214 1607 78.77 42. Paria Pardi 7596 748 5578 81.45 43. Rohina Pardi 5833 603 4436 84.81 44. Samarpada Pardi 1987 199 1528 85.45 45. Dhagadmal Pardi 1601 212 1064 76.60 46. Daheli Pardi 2755 346 1990 82.60 47. Chival Pardi 3806 478 2531 76.05 48. Arnala Pardi 2015 263 1527 87.15 49. Pati Pardi 1119 128 856 86.37 50. Goima Pardi 7484 843 5391 81.17 51. Barai Pardi 1612 152 1267 86.78 52. Dumalav Pardi 3808 394 2956 86.58 53. Tukwada Pardi 5430 649 3986 83.37 54. Ambach Pardi 7236 762 5210 80.47 55. Kherlav Pardi 1596 183 1269 89.80 56. Pandor Pardi 2091 211 1538 81.80 57. Rata Pardi 5399 798 3666 79.67 58. Chharwada Pardi 8806 1221 6947 91.58 59. Namdha Pardi 1938 208 1495 86.41 60. Chandor Pardi 2389 253 1735 81.22 61. Kocharva Pardi 2247 222 1789 88.34 62. Vankachh Pardi 523 58 418 89.89 63. Koparli Pardi 4450 462 3132 78.53 64. Kaval Pardi 1293 158 847 74.62 65. Karaya Pardi 3497 421 2272 73.86



Sr. No.


Total Population


Population Literate

Literacy (%)

66. Nani Tambadi Pardi 3790 405 2792 82.48 67. Degam Pardi 1968 209 1337 76.00 68. Moti Tambadi Pardi 5028 678 3175 72.98 69. Karamkhal Pardi 3525 440 2669 86.51 70. Chibhad

Kachchh Pardi 1919 219 1280 75.29

71. Pardi (M) Pardi 28495 2704 22463 87.09 72. Pardi (M)

WARD NO.-0001

Pardi 4660 425 3794

89.58

73. Pardi (M) WARD NO.-0002

Pardi 5536 560 4447 89.36


Pardi 4043 394 2910 79.74


Pardi 3165 235 2679 91.43


Pardi 2235 166 2003 96.81


Pardi 5006 532 3686 82.38


Pardi 3850 392 2944 85.13

79. Vapi (M) Pardi 163630 21235 126726 88.99 80. Vapi (M)

WARD NO.-0001

Pardi 11382 1170 9403 92.07

81. Vapi (M) WARD NO.-0002

Pardi 14192 1745 11620 93.35


Pardi 15571 1688 13102 94.37


Pardi 10783 1340 8940 94.67


Pardi 11821 1789 8305 82.78



Sr. No.


Total Population


Population Literate

Literacy (%)


Pardi 7587 1116 5446 84.16


Pardi 12727 2037 9160 85.68


Pardi 9828 1297 7569 88.72


Pardi 10426 1211 8547 92.53


Pardi

11786 1516 8776 85.45


Pardi 9609 1118 7425 87.44


Pardi 11904 1582 8813 85.38


Pardi 11731 1696 8577 85.47


Pardi 14283 1930 11043 89.39

94. Vapi (INA) Pardi 34162 3981 28695 95.07 95. Vapi (INA)

WARD NO.-0001

Pardi 34162 3981 28695 95.07

96. Orvad (CT) Pardi 5420 629 4252 88.74 97. Orvad (CT)

WARD NO.-0001

Pardi 5420 629 4252 88.74

98. Balitha (CT) Pardi 12380 1802 9117 86.18 99. Balitha (CT)

WARD NO.-0001

Pardi 12380 1802 9117 86.18

100. Salvav (CT) Pardi 5486 616 4229 86.83 101. Salvav (CT)

WARD NO.-0001

Pardi 5486 616 4229 86.83

102. Chhiri (CT) Pardi 18829 2981 13988 88.26



Sr. No.


Total Population


Population Literate

Literacy (%)

103. Chhiri (CT) WARD NO.-0001

Pardi 18829 2981 13988 88.26

104. Chanod (CT) Pardi 18776 2819 14665 91.90 105. Chanod (CT)

WARD NO.-0001

Pardi 18776 2819 14665 91.90

106. Karvad (CT) Pardi 5746 769 4431 89.02 (Source: Census-2011 for Valsad District) 3.9.3 OCCUPATIONAL STRUCTURE In economic development of the region its geographical location, natural resources, business and employment, industries and manpower play vital role. Table no.3.19 provides the occupational patterns in all villages of Pardi Taluka.



TABLE: 3.19 OCCUPATIONAL STRUCTURE

Sr. No.

Name of Area

Total Population

Worker Population Total Non worker population

Employment Ratio% Total

Worker

Main Worker

Marginal Worker

1. Pardi Taluka 518814

224618

194641

29977

294196

43.29

2. Umarsadi 1645 7059 6286 773 9395 42.90 3. Balda 3621 1643 1338 305 1978 45.37 4. Kumbhariya 1406

928

500

428

478

66.00

5. Sondhalwada 2566

1076

961

115

1490

41.93

6. Parvasa 2902 1589 1198 391 1313 54.76 7. Kachwal 1415 705 457 248 710 49.82 8. Mota

Waghchhipa 2841

1256

1138

118

1585

44.21

9. Nana

Waghchhipa 2061

776

685

91

1285

37.65

10. Sukhesh 5019 2013 1763 250 3006 40.11 11. Borlai 821 344 338 6 477 41.90 12. Sukhlav 2416 1300 760 540 1116 53.81 13. Velparva 1659 616 516 100 1043 37.13 14. Khadki 3126 1425 1308 117 1701 45.59 15. Motiwada 3871 1967 1537 430 1904 50.81 16. Palsana 3350 1714 1694 20 1636 51.16 17. Kalsar 2153 831 708 123 1322 38.60 18. Udwada 6303 2331 2096 235 3972 36.98 19. Kolak 4646 1827 1649 178 2819 39.32 20. Kikarla 2332 915 889 26 1417 39.24 21. Rentlav 4590 1673 1582 91 2917 36.45 22. Dungri 4967 2010 1883 127 2957 40.47 23. Dashwada 462 281 253 28 181 60.82 24. Amli 2253 1350 664 686 903 59.92 25. Sonwada 2517 1014 877 137 1503 40.29 26. Varai 631 347 316 31 284 54.99 27. Nimkhal 837 413 248 165 424 49.34 28. Panchlai 3312 1492 1034 458 1820 45.05 29. Lakhmapor 432 276 130 146 156 63.89 30. Nevri 1831 1219 752 467 612 66.58 31. Rabdi 1566 842 702 140 724 53.77



Sr. No.

Name of Area

Total Populati

on Worker Population Total

Non worker populati

on

Employment

Ratio% Total Worke

r Main

Worker

Marginal Worker

\32. Asma 1715 1096 958 138 619 63.91 33. Tarmaliya 2096 942 871 71 1154 44.94 34. Khuntej 1536 908 827 81 628 59.11 35. Sarodhi 1766 798 737 61 968 45.19 36. Saran 1579 661 618 43 918 41.86 37. Tarakpardi 701 408 402 6 293 58.20 38. Vatar 3230 1573 1279 294 1657 48.70 39. Kunta 4019 2026 1968 58 1993 50.41 40. Morai 2192 1275 1267 8 917 58.17 41. Bagwada 1152 441 403 38 711 38.28 42. Tighara 2254 998 811 187 1256 44.28 43. Paria 7596 4045 3066 979 3551 53.25 44. Rohina 5833 2722 1731 991 3111 46.67 45. Samarpada 1987 1205 458 747 782 60.64 46. Dhagadmal 1601 880 632 248 721 54.97 47. Daheli 2755 1116 742 374 1639 40.51 48. Chival 3806 2271 1557 714 1535 59.67 49. Arnala 2015 1066 947 119 949 52.90 50. Pati 1119 487 458 29 632 43.52 51. Goima 7484 4029 2624 1405 3455 53.83 52. Barai 1612 978 669 309 634 60.67 53. Dumalav 3808 2005 1013 992 1803 52.65 54. Tukwada 5430 2669 2446 223 2761 49.15 55. Ambach 7236 3319 2619 700 3917 45.87 56. Kherlav 1596 963 490 473 633 60.34 57. Pandor 2091 1002 844 158 1089 47.92 58. Rata 5399 2369 2292 77 3030 43.88 59. Chharwada 8806 3628 3302 326 5178 41.20 60. Namdha 1938 911 738 173 1027 47.01 61. Chandor 2389 973 888 85 1416 40.73 62. Kocharva 2247 936 853 83 1311 41.66 63. Vankachh 523 175 167 8 348 33.46 64. Koparli 4450 1699 1485 214 2751 38.18 65. Kaval 1293 734 343 391 559 56.77 66. Karaya 3497 1284 1237 47 2213 36.72 67. Nani Tambadi 3790 1492 960 532 2298 39.37 68. Degam 1968 1061 1010 51 907 53.91 69. Moti Tambadi 5028

2886 1790 1096 2142 57.40



Sr. No.

Name of Area

Total Populati


Non worker populati

on

Employment

Ratio% Total Worke

r Main

Worker

Marginal Worker

70. Karamkhal 3525 1748 1521 227 1777 49.59 71. Chibhad

Kachchh 1919

848 632 216 1071 44.19

72. Pardi (M) 28495 12145 10030 2115 16350 42.62 73. Pardi (M)

WARD NO.-0001

4660

1941 1684 257 2719 41.65


5536

2305 1855 450 3231 41.64


4043 1691 1590 101 2352 41.83


3165

1394 1149 245 1771 44.04


2235

853 778 75 1382 38.17


5006

2297 1403 894 2709 45.88


3850

1664 1571 93 2186 43.22

80. Vapi (M) 163630 67289 62379 4910 96341 41.12 81. Vapi (M)

WARD NO.-0001

11382

5219 4719 500 6163 45.85


14192

5410 4880 530 8782 38.12


15571

5588 5297 291 9983 35.89

84. Pardi (M) ward no.-0006

10783

3473 3196 277 7310 32.21 85. Pardi (M)

ward no.-0007 11821 4911 4584 327 6910 41.54 86. Vapi (M) 163630 67289 62379 4910 96341 41.12 87. Vapi (M)

WARD NO.-0001

4660

1941 1684 257 2719 41.65



Sr. No.

Name of Area

Total Populati


Non worker populati

on

Employment

Ratio% Total Worke

r Main

Worker

Marginal Worker


5536

2305 1855 450 3231 41.64


15571

5588 5297 291 9983 35.89


10783

3473 3196 277 7310 32.21


11821

4911 4584 327 6910 41.54


7587

3183 3058 125 4404 41.95


9828 4333 3941 392 5495 44.09


10426

3874 3681 193 6552 37.16


11786

5109 4620 489 6677 43.35


9609

3964 3783 181 5645 41.25


11904

6519 6228 291 5385 54.76


11731

4341 4019 322 7390 37.00


14283

6571 5827 744 7712 46.01

101. Vapi (INA) 34162

11357 10436 921 22805 33.24 102. Vapi (INA)

WARD NO.-0001

34162

11357 10436 921 22805 33.24

103. Orvad (CT) 5420 2076 2009 67 3344 38.30 104. Orvad (CT)

WARD NO.-0001

5420 2076 2009 67 3344 38.30



(Source: Census-2011 for Valsad District) Main worker: Who has worked last year for six month or more? Marginal worker: Who has worked last year for less than six months? Non-worker: Who did not work at all during the reference period of one year? Distribution of main worker and marginal worker into further following four categories are shown in Table no. 3.19. Cultivators Agricultural labors Household industry Others worker

105. Balitha (CT) 12380 5396 5158 238 6984 43.59 Sr. No.

Name of area

Total Populati


Non worker populati

on

Employment

Ratio% Total Worke

r Main

Worker

Marginal Worker

106. Balitha (CT) WARD NO.-0001

12380 5396 5158 238 6984 43.59

107. Salvav (CT) 5486 2270 2012 258 3216 41.38 108. Salvav (CT)

WARD NO.-0001

5486

2270 2012 258 3216 41.38

109. Chhiri (CT) 18829 8564 8224 340 10265 45.48 110. Chhiri (CT)

WARD NO.-0001

18829

8564 8224 340 10265 45.48

111. Chanod (CT) 18776 7384 6952 432 11392 39.33 112. Chanod (CT)

WARD NO.-0001

18776

7384 6952 432 11392 39.33

113. Karvad (CT) 5746 2396 1754 642 3350 41.70 114. Karvad (CT)

WARD NO.-0001

5746

2396 1754 642 3350 41.70

115. Lavachha (CT) 8549

3882 3770 112 4667 45.41

116. Lavachha (CT) WARD NO.-0001

8549

3882 3770 112 4667 45.41

117. Kaprada 258888 120788 67871 52917 138100 46.66 118. Umbergaon 296964 119836 104942 14894 177128 40.35



TABLE: 3.19 DISTRIBUTION OF WORKERS Sr. No.

Area Name

Main worker Marginal worker Cultivators

Agricultural Labours

Household Industry

Others Cultivators Agricultural Labours

Household Industry

Others Pardi Taluka 1. Pardi 19516 14929 2991 157205 4302 11084 1004 13587 2. Umarsadi 287 984 56 4959 43 210 12 508 3. Badla 85 266 19 968 25 131 10 139 4. Kumbhariya 176 56 80 188 162 199 32 35 5. Sondhalwada 298 196 17 450 16 71 1 27 6. Parvasa 352 298 32 516 34 290 18 49 7. Kachwal 147 16 2 292 31 185 0 32 8. Mota

Waghchhipa 302 362 19 455 31 23 1 63

9. Nana Waghchhipa

306 189 19 171 33 36 6 16 10. Sukhesh 546 442 25 750 60 147 3 40 11. Borlai 116 50 1 171 6 0 0 0 12. Sukhlav 196 126 7 431 125 309 4 102 13. Velparva 130 47 11 328 14 41 1 44 14. Khadki 82 52 2 1172 18 11 2 86 15. Motiwada 119 183 58 1177 26 198 8 198 16. Palsana 174 609 29 882 7 2 0 11 17. Kalsar 35 59 3 611 15 86 0 22 18. Udwada 95 192 9 1800 22 16 5 192 19. Kolak 65 34 8 1542 29 78 11 60



Sr. No.

Area Name



Household Industry


Household Industry

Others 20. Kilkara 94 121 2 672 4 1 1 20 21. Rentlav 57 20 22 1483 6 25 4 56 22. Dungri 356 529 10 988 11 80 1 35 23. Dashwada 23 72 0 158 0 6 1 21 24. Amli 138 111 1 414 342 306 0 38 25. Sonwada 381 150 3 343 9 123 0 5 26. Varai 44 103 1 168 2 24 1 4 27. Nimkhal 106 71 1 70 14 134 3 14 28. Panchlai 602 150 0 282 203 186 2 67 29. Lakhmapor 63 20 3 44 89 31 5 21 30. Nevri 298 281 41 132 38 357 26 46 31. Rabdi 275 230 2 195 82 47 0 11 32. Asma 527 165 55 211 16 107 1 14 33. Tarmaliya 256 325 4 286 9 19 1 42 34. Khuntej 323 196 12 296 8 36 0 37 35. Sarodhi 106 268 22 341 12 38 2 9 36. Saran 117 87 13 401 12 24 1 6 37. Tarakpardi 10 58 1 333 2 4 0 0 38. Vatar 80 89 30 1080 26 48 22 198 39. Kunta 22 3 14 1929 7 5 3 43 40. Morai 15 32 9 1211 0 1 0 7 41. Bagwada 17 3 1 382 3 9 0 26 42. Tighara 59 264 39 449 10 136 11 30 43. Paria 492 903 33 1638 108 502 10 359 44. Rohina 754 624 15 338 106 610 68 207



Sr. No.

Area Name



Household Industry


Household Industry

Others 45. Samarpada 305 18 0 135 332 350 3 62 46. Dhagadmal 178 274 8 172 69 130 10 39 47. Daheli 456 149 15 122 60 292 1 21 48. Chival 1085 224 6 242 49 608 44 13 49. Arnala 528 154 11 254 31 74 2 12 50. Pati 197 74 0 187 5 20 0 4 51. Goima 1498 563 11 552 376 856 13 160 52. Barai 354 157 13 145 49 231 2 27 53. Dumalav 364 51 13 585 170 504 105 213 54. Tukwada 267 335 6 1838 11 31 0 181 55. Ambach 1219 376 33 991 206 180 16 298 56. Kherlav 264 40 30 156 154 210 36 73 57. Pandor 88 263 11 482 2 146 0 10 58. Rata 166 97 213 1816 15 8 11 43 59. Chharwada 94 30 33 3145 23 163 17 123 60. Namdha 49 36 6 647 7 93 3 70 61. Chandor 70 111 5 702 17 42 1 25 62. Kocharva 164 25 0 664 10 32 0 41 63. Vankachh 72 1 0 94 2 0 0 6 65. Kaval 100 141 5 97 14 374 1 2 66. Karaya 213 503 3 518 17 27 0 3 67. Nani Tambadi 214 127 17 602 63 238 1 230 68. Degam 391 164 2 453 21 14 0 16 69. Moti Tambadi 530 199 15 1046 304 730 1 61 70. Karamkhal 96 112 23 1290 79 29 2 117



Sr. No.

Area Name



Household Industry


Household Industry

Others 71. Chibhad Kachchh 147 24 26 435 33 28 1 154 72. Pardi (M) 136 417 366 9111 78 409 1 1433 73. Pardi (M) WARD

NO.0001 22 17 11 1634 10 19 195 220


9 12 52 1782 9 2 8 432 75. Pardi (M) WARD

NO.-0003 16 140 13 1421 2 2 7 91


12 3 41 1093 3 0 6 96 77. Pardi (M) WARD

NO.-0005 7 4 5 762 10 27 146 37


51 152 105 1095 40 352 17 485 79. Pardi (M) WARD

NO.-0007 19 89 139 1324 4 7 10 72

80. Vapi (M) 485 337 815 60742 135 154 187 4434 81. Vapi (M) WARD

NO.0001 24 43 71 4581 22 15 38 425


39 13 20 4808 4 13 8 505 83. Vapi (M) WARD

NO.-0003 25 5 14 5253 16 1 10 264


12 5 61 3118 30 4 2 241 85. Vapi (M) WARD

NO.-0005 160 22 244 4158 21 9 35 262



(Source: Census-2011 for Valsad District)

Sr. No.

Area Name



Household Industry


Household Industry

Others 86. Vapi (M) WARD

NO.-0006 9 10 61 2978 1 0 11 113

87. Vapi (M) Ward no.-0007

19 17 44 4466 0 0 2 246



3.10 EARTHQUAKE VULNERABILITY Map of Earthquake vulnerability is shown in below figure.3.10. FIGURE: 3.10 EARTHQUAKE VULNERABILITY MAP

3.11 WIND AND CYCLONE VULNERABILITY Map of Wind and cyclone vulnerability is shown in below figure.3.11. FIGURE: 3.11 WIND AND CYCLONE VULNERABILITY MAP



ENVIRONMENT IMPACT ASSESSMENT REPORT M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI.


Chapter - 4 IDENTIFICATION & ASSESSMENT OF IMPACT 4.1 IDENTIFICATION OF IMPACT The proposed expansion project will result in environmental consequences during d manufacturing activities alone. The unit has proposed to install additional machinery into existing building only. There will not be any additional construction activity. This chapter covers identification of impacts, quantification and evaluation of impacts during operation phase. The network method (Cause - effect) is adopted to identify potential impact of the proposed activity. It includes step wise study of relationship between an activity and its environmental parameters. This method involves in the “Road Map” type of approach to the identification of second and third order effect. The basic idea is to account for the project activity and identify the type of impact that could initially occur followed by the identification of secondary and tertiary impact. The type of identified potential impacts on various environmental components i.e. Air, Noise, Water and Land are presented in Figure no. 4.1 to Figure no. 4.6. It should be noted that in these illustration the lines are to be read as “might have an effect on”.



FIGURE: 4.1 IMPACT NETWORK ON AIR ENVIRONMENT

Activity

Primary Impact

Secondary Impact

Tertiary Impact

Project

Operational Phase

Release of Heat

Climatic Changes

Impact on Human, Flora and Fauna

Release of Air Pollutants

Change in Air Quality Impact on

Visibility

Aesthetic Impact

Particulates Deposition on Water, Land

Impact on Agricultural produce Impact on Human,

flora & fauna

Impact on Economic Output Impact on Socio –

Cultural Environment



FIGURE: 4.2 IMPACT NETWORK ON NOISE ENVIRONMENT

Noise Emission

Change in Ambient Noise Level

Health Risks

Impact on Work Output & Efficiency

Impact on fauna & population

Impact on Economic Output

Impact on Socio-cultural Environment

Operational Phase

Activity

Primary Impact

Secondary Impact

Tertiary Impact

Project



FIGURE: 4.3 IMPACT NETWORK ON WATER ENVIRONMENT

Activity Primary Impact Secondary Impact Tertiary Impact

Project

Operation Phase

Release of wastewater

Abstraction of Water

Impact on Hydraulics of Water Courses

Impact on Hydraulic Water Courses

Impact on Aquatic Life

Cost of Water Treatment

Impact on Amenity / Recreation


Impact on Socio-Cultural Environment

Environmental health And Aesthetic Risk



FIGURE: 4.4 IMPACT NETWORK ON GROUND WATER ENVIRONMENT


Release of wastewater on land

Project

Operation Phase

Disturbance of soil

Impact on Flora and Fauna

Impact on agricultural production



Abstraction of water

Change in Ground water Regime: Soil Moisture / water level/ Flow Pattern/ Salt water instruction

Impact on landscape

Impact on Soil Biota

Impact on livestock

Change in structure of Soil: Ground level

Addition /Removal of substances or Heat to /form the soil



FIGURE: 4.5 IMPACT NETWORK ON SOCIO-ECONOMIC AND CULTURAL ENVIRONMENT

Activity Primary Impact

Tertiary Impact

Secondary Impact

Effect on Human Health

Project Operational

Phase

Net Income output

Air, Water, Land, Noise pollution

Change in Economic Base of the

region

Effect on visual Environment

Economic input Capital/O&M Cost

Economic output

Product Cost

Development of Ancillary Industries

Better product

availability Employment opportunity Aesthetic

Risk

Effect on Agriculture & fisheries

Effect on Buildings Materials Monuments

Saving foreign Exchange



FIGURE: 4.6 IMPACT NETWORK ON LAND ENVIRONMENT


Disposal of waste water & Sludge on Land

Toxic Substances on Land, Particulate Deposition on Land

Impact on flora & fauna

Impact on Agricultural Produce

Impact on Landscape



Project

Operational Phase

Disturbance of land

Abstraction of water

Change in ground Water Regime /Salt Water intrusion

Change in soil Texture & Permeability

Soil Salinity

Impact on Live stock



4.2 PREDICTION AND ASSESSMENT OF IMPACT The predication and assessment of impact on the environmental parameters have been carried out. For assessing the impact, the baseline data of environmental status were considered. The change in the environmental parameters due to manufacturing activities of the industry has been superimposed on the status data. 4.2.1 WATER ENVIRONMENT 4.2.1.1 OPERATIONAL PHASE IMPACTS The average daily water requirements after proposed expansion will be 404 KL/Day. The unit will use 195 KL/day of fresh water and 268 KL/day of recovered water. Fresh water will be met by GIDC water supply scheme. There will be no extraction of ground water, so that no direct impact is found on ground water availability. Existing effluent generation is 64.99 KL/day. After proposed expansion, total effluent generation will be 99 KL/day from different sources i.e. process, washing, boiler, cooling, DM plant and domestic at full production capacity. Mitigative measures The unit has ETP having primary, secondary and tertiary treatment. The effluent is treated inept. Treated water will be further treated in R.O. followed by MEE. The condensate water from MEE and permeate water from RO is reused and the residue from MEE is send to TSDF site. The unit will be zero liquid discharge for industrial effluent. Sewage will be treated separately in STP and treated water will be used for gardening purpose and reused in cooling tower. 4.2.2 AIR ENVIRONMENT 4.2.2.1 OPERATION PHASE IMPACTS There is already flue gas emission from two D.G. stacks. There will be increase in flue gas emission due to two D.G stacks. Diesel, Furnace oil and Energy- Electricity are used as fuel in two existing D.G.set. For proposed D.G. set also diesel, Furnace oil and Energy- Electricity will be used as fuel. There is process emission from one stack attached to Reactor of Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene, one stack attached to Chlorinator, one stack attached to SFD dryer and one stack attached to Dizo vessels.



Mitigative measure The unit is using Diesel as fuel in stack and adequate stack height is provided. There is provision of Water scrubber followed by alkali scrubber to control emission of HBr and Br2 from stack attached to Reactor of 2-Bromo 4 Flouro acetanilide/ Di Chloro Bromo Benzene. There is provision of water scrubbers followed by alkali scrubber to control emission of HCl and Cl2 from stack attached to Chlorinator. There is provision of Water scrubber followed by alkali scrubber to control emission of PM from stack attached to the SFD dryer. There is provision of Water scrubber followed by alkali scrubber to control emission of NOx and HCl from stack attached to Dizo vessels. The air quality impacts of source are evaluated by use of model. The model stimulates the relationship between air pollutants emission, meteorology and air chemistry, all of which are determined by formulating impact scenario. MODELING DETAILS The dispersion of pollutants in the atmosphere is a function of several meteorological parameters like temperature, wind speed and direction, mixing depths, inversion level etc. The air quality impacts of source or collection of sources is evaluated by use of models. The model stimulates the relationship between air pollutants emission, meteorology and air chemistry, all of which are determined by formulating impact scenario. Estimation of emissions from the plant has been made by Industrial Source Complex – Short Term (ISC-ST3) model developed by United States Environment Protection Agency (USEPA). ISC-ST is based on a modified steady state Gaussian Plume equation, and it has been recommended for use in EIA studies by Ministry of Environment & Forests (MoEF) in EIA manual. Maximum GPCB permissible limits were used for carrying out atmospheric dispersion modeling studies. Based on the modeling results, the concentration of PM summarized in the Table no. 4.2., concentration of NOx summarized in the Table no. 4.3. And concentration of HCl & HBr is summarized in the Table no. 4.4 & Table no.4.5.



DISPERSION MODEL TABLE: 4.1 DETAILS OF PROCESS EMISSION Sources Of Gaseous Emissions

Reactor Of 2-Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene

Chlorinator SFD Dryer Dizo Vessels

Fuel used -- -- -- -- Quantity of fuel -- -- -- -- Type of emissions

HBr, Br2 HCl, Cl2 PM NOX, HCl Stack height 16 m 11 m 11 m 11 m Stack diameter at the top

150 mm 150 mm 800 mm 250 mm Stack gas exit temperature

40 oC 50 oC 55 oC 50 oC Stack gas exit velocity

6.5 m/s 6.5 m/s 6.5 m/s 6.5 m/s APCM Water scrubber

followed by Alkali scrubber

Water scrubber followed by Alkali scrubber



Emissions: PM Concentration -- -- < 150 mg/Nm3 - NOx Concentration -- -- - < 25 mg/Nm3 HCl Concentration

-- <20 mg/Nm3 -- < 20 mg/Nm3 Cl2 Concentration

-- < 09 mg/Nm3 -- -- HBr Concentration

<20 mg/Nm3 -- -- -- Br2 Concentration

< 09 mg/Nm3 -- -- --



TABLE: 4.2 CONCENTRATION OF PM

TABLE: 4.3 CONCENTRATION OF NOx Highest Values

Incremental Increase In Concentration (µg/m3)

X Co-Ord (mts)

Y Co-Ord (mts)

NOx 1 0.352 0 1000 2 0.318 0 1000 3 0.283 1000 0 4 0.259 0 1000 5 0.258 0 1000 6 0.253 0 1000 7 0.243 0 1000 8 0.242 1000 -1000 9 0.242 1000 0 10 0.24 0 1000

Highest Values


X Co-Ord ( mts)

Y Co-Ord (mts)

PM 1 0.944 0 1000 2 0.889 0 1000 3 0.868 1000 -1000 4 0.857 0 1000 5 0.817 1000 0 6 0.781 1000 1000 7 0.764 0 1000 8 0.72 1000 1000 9 0.705 0 1000 10 0.695 1000 -1000



TABLE: 4.4 CONCENTRATION OF HCl AND Cl2 Highest Values


X Co-ord (mts)

Y Co-ord (mts)

HCL Cl2 1 0.806 0.235 0 1000 2 0.719 0.206 0 1000 3 0.642 0.185 1000 0 4 0.587 0.169 0 1000 5 0.58 0.167 0 1000 6 0.576 0.164 0 1000 7 0.554 0.161 0 1000 8 0.551 0.161 0 1000 9 0.549 0.158 1000 0 10 0.54 0.151 1000 -1000

TABLE: 4.5 CONCENTRATION OF HBr AND Br Highest Values


X Co-ord (mts)

Y Co-ord (mts)

HBr Br 1 0.177 0.177 0 1000 2 0.169 0.169 0 1000 3 0.144 0.144 1000 0 4 0.137 0.137 0 1000 5 0.132 0.132 0 1000 6 0.129 0.129 0 1000 7 0.126 0.126 0 1000 8 0.125 0.125 1000 -1000 9 0.125 0.125 0 1000 10 0.123 0.123 1000 0

Based on the modeling results, isopleths for incremental increase in concentrations isopleths were drawn and were superimposed on an aerial view of the site using maps from Google Earth which are shown below:



FIGURE: 4.7 ISOPLETHS OF NOx (SITE COORDINATES 0, 0)



FIGURE: 4.8 ISOPLETHS OF PM (SITE COORDINATES 0, 0)



FIGURE: 4.9 ISOPLETHS OF HCL (SITE COORDINATES 0, 0)



FIGURE: 4.10 ISOPLETHS OF CL2 (SITE COORDINATES 0, 0)



FIGURE: 4.11 ISOPLETHS OF HBr (SITE COORDINATES 0, 0)



FIGURE: 4.12 ISOPLETHS OF Br (SITE COORDINATES 0, 0)

Observations from dispersion modeling studies From the dispersion modeling studies conducted, it was observed that the maximum ground level concentration occurs in the North & North east direction. The maximum incremental increase in concentration for PM and NOx is 0.944 µg/m3 and 0.352 µg/m3 respectively at a distance of about 1 km in the North direction. Whereas, the maximum incremental increase in concentration for HCl & Cl2 is 0.806µg/m3 & 0.235µg/m3 respectively and for HBr & Br is 0.177µg/m3 each at a distance of about 1 km in the North direction.



4.2.3 NOISE ENVIRONMENT 4.2.3.1 OPERATIONAL PHASE IMPACTS The sources of noise pollution will be D.G. sets and other noise generating units. Vehicular movements during operation phase for loading/unloading of raw materials and finished products and other transportation activity may also increase noise level. Mitigative measures Adequate noise control measures such as mufflers, silencers at the air inlet/outlet, anti vibration pad for equipment with high vibration etc. is already provided. Housing/casing shall be provided for all noise generating machines. Job rotation will reduce exposure to some extent. More ever, PPE like earmuff and ear plugs is provided to the operators/worker exposed to high noise. The green belt is further helpful in reducing the ambient noise level. The above control measures will be continuously followed after proposed expansion. 4.2.4 LAND ENVIRONMENT 4.2.4.1 OPERATIONAL PHASE IMPACTS If the raw materials and hazardous wastes are not handled properly, it can pose danger of land contamination and can affect land system adversely. Transportation is one of the most important areas of concern associated with handling and spillage of raw materials and HW because of the packaging and method of transporting HW will prevent the likelihood that an accident or spill would occur. Mitigative measures The unit has closed hazardous waste storage area with impervious flooring. Transportation of hazardous waste to the TSDF site is governed as per the Hazardous Waste (Management, Handling and Transboundary Movement) Rules. Separate collection system is provided for collection of spillage material. Impervious layer, RCC roads and flooring is provided to area, where the chemical storage and handling activities will be involved. Separate storm water collection system is provided to prevent contamination of soil through contaminated water.



Hence, there will be no significant adverse impact on land environment due to handling of hazardous solids waste. The unit is following Standard Operating Procedure (SOP) for storing and handling of hazardous wastes. SOP is attached as annexure-XVII. 4.2.5 ECOLOGICAL ENVIRONMENT The impact due to the proposed expansion on ecological parameters like natural vegetation, cropping pattern, fisheries and aquatic life, forest land species diversity are briefly summarized below: 4.2.5.1 OPERATIONAL PHASE IMPACTS The green belt will be developed by the unit outside the premises having different species of flora, which will lead to beneficial impact on ecological environment. There is necessary environmental protection measures which have been planned under air pollution control system designed to take care of release of the gaseous pollutants like PM, Br, NOx, HCl & HBr. The waste water generated from the process and domestic activity will be properly treated and reused in cooling tower. There will be no impact on fisheries and aquatic life as it is zero discharge unit. Raw material and hazardous waste will be transported by road and will be stored in plant premises. Hence, no adverse impact on this account is anticipated. 4.2.6 INFRASTRUCTURE AND SERVICES 4.2.6.1 OPERATION PHASE IMPACTS The plant is located in a GIDC, Vapi having all essential facilities such as water, power, post, and telecommunication. The GIDC Vapi has four lanes internal roads with separate parking areas at different locations. At present there are no traffic issues in the project area. Due to proposed expansion of 1448.18 MT/Month, there will be additional 30-35 truck / tanker moments will be increase. This will not results in any traffic issues. Also, the unit has made parking arrangement of 50 Vehicles within the premises. The packing for staff and worker’s vehicle is also available within the premises. This will have almost negligible impact on road network.



The power requirement of proposed project of 800 KVA will be fulfilled from DGVCL. DGVCL is having large amount of electricity production thus due to extra consumption of electricity no adverse impact of electricity supply is predicted. The unit is using water from GIDC water supply scheme. Also, the treated water will be used for cooling tower to conserve fresh water. As a result of development of GIDC, Vapi, the neighboring areas will be developed for commercial use. The infrastructure services e.g. roads, post and telegraph, communication, medical facilities, education; housing will get improved in surrounding area. 4.2.7 SOCIO-ECONOMIC IMPACT 4.2.7.1 OPERATION PHASE IMPACTS During operation phase some additional jobs for operation and maintenance of project and for operating and maintaining various facilities like water supply, power supply, roads, gardens, transportation etc will be available. The migration of employees in addition to the local ones will lead to a faster growth rate of economical and social status of the local area. Emission, if uncontrolled from process and utility stacks may cause discomfort to people in the down wind direction. This may be caused due to the failure of control equipment / process. Mitigative measure Provision of adequate APC and maintenance of APC will prevent any accidental emission from stacks and reduce risk to the health of the people in the vicinity of the project. As a result the project activities there will not be adverse impacts on sanitation, communication and community health as sufficient measures have been proposed in EMP. 4.3 IMPACT MATRIX The parameter discussed are presented in the form of a matrix in Table no. 4.6.There will be both construction and operation phases. The quantification of impact is done using numerical scores 0 to 5 as per the following criteria.



Score Severity criteria 0 No Impact 1 No damage 2 Slight/short term effect 3 Occasional reversible effect 4 Irreversible /Long –term effect 5 Permanent damage



TABLE : 4.6 ENVIRONMENT IMPACT MATRIX (WITH MITIGATION MEASURES)

Activity

Activities During Construction Phase

Air Quality

Water Quality

Noise & Odour

Land Quality

Infra- Structure /Services

Ecological Environment

Socio-Economic Status

Opera

tion Ph

ase Material Storage/handling/

Transport 2 0 2 1 2 2 2

Utilities 2 0 2 1 1 1 1 Gaseous Emissions 2 1 1 1 1 1 1 Fugitive Emissions 2 0 1 0 0 0 1 Solid/hazardous Waste Disposal

2 1 2 2 2 1 1 Spills & Leaks 2 1 2 1 1 1 1 Plant Operations 2 0 2 1 2 1 2 Equipment Failures/ Shutdown/ Startup

2 0 2 1 2 1 2

Transport of workers/ Movement of vehicles

2 0 2 0 2 2 2 Cumulative score 18 3 16 8 13 10 13



TABLE: 4.7 CUMULATIVE IMPACT CHART

Environmental Parameter

Total Cumulative

Air Quality 18 Water Quality 3 Noise and Odor 16 Land Quality 8 Infrastructure/ Service 13 Ecological environment 10 Socio Economic Status 13

Conclusion: Due to proposed expansion project, identified impacts are as under: The source of water is GIDC water supply scheme; there is no extraction of ground water. The unit is using recovered water for cooling tower. So, there will be no deterioration of surface and ground water quality. Even though after provision of APCM, there will be minor increase in ground level concentration of HCl & HBr in ambient air due to operational activities of proposed project. The unit will take adequate measure for storage, handling and disposal of hazardous waste. Hence, there will be no significant adverse impact on land environment. Engineering control, use of PPE, restriction of construction activity during 9 p.m. to 6 a.m., and green belt will reduce impact of noise pollution due to construction work, vehicular movement and noise generating equipment. There will be minor increase in ambient noise level and impact is insignificant. The unit is located in GIDC, Vapi. There will be not significant impact on crops & vegetation as the proposed APCM will take care of flue gas emission and process emission. There will be no discharge of effluent, so no impact on fisheries and aquatic life. Hence, no adverse impact on this account is anticipated.



This will be a beneficial impact on the local socio-economic environment as increase in demand for essential utilities and employment during both construction and operational phase. This will be no impact on the local infrastructure services. E.g. roads post and telegraph, communication, medical facilities, education, housing will be improved in surrounding area. There is a well laid down broad roads already existing in GIDC, Vapi. At the full capacity of production, there will be 32-35 trucks per day for transportation of raw material and finished good products.



Chapter – 5 ENVIRONMENTAL MONITORING PROGRAM 5.1 POLLUTION MONITORING AND SURVEILLANCE SYSTEM Regular monitoring of important parameters is of immense importance to assess the status of environment during plant operation. With the knowledge of baseline conditions, a properly planned monitoring program can serve as an indicator for assessment of any deterioration in environment conditions. This will facilitate undertaking suitable measures to mitigate adverse impact during the operation of the plant and further help to protect the environment in the area. The main attributes for which monitoring shall be carried out are: Ambient Air Quality Stack Emission Wastewater Quality Noise Level The characteristics of the ambient air, water, waste water and noise from the plant will be maintained so as to meet the requirements of the State Pollution Control Board. Details of emission monitoring plan is given in Table 5.1 TABLE: 5.1 EMISSION MONITORING PLAN Sr. No.

Description Location Parameter To Be Monitored

Frequency of Monitoring

1. Flue gas emission monitoring plan

Two existing D.G. stacks, One proposed D.G. stacks,

SO2,NOx and PM D.G set are available. Monitoring will be done by internal centralized facility. Whenever it will be in running condition.

2. Process emission monitoring plan

One existing stack attached to Reactor of

Br2 &HCl Quarterly by internal centralized monitoring facility.



Sr. No.



Bromo 4Flouro Acetanilide/ Di Chloro Bromo Benzene

One proposed stack attached to Chlorinator

HCl &Cl2

One proposed stack attached to SFD dryer

PM

One proposed stack attached to reactor Dizo vessels

HCl & NOx

3. Fugitive emission monitoring plan

Process area & storage area

Relevant solvent Acetone, Xylene, Toluene, MCB, MIBK

Quarterly by internal centralized monitoring facility.

4. Ambient air monitoring plan

ETP, Process area ,storage area and one location in downwind direction

PM10 ,PM 2.5, SO2, NOx, HCl, HBr, Br2

Quarterly by internal centralized monitoring facility.

5. Noise monitoring Nine location within company premises

- Six monthly by self-analytical facility

6. Water quality monitoring

Eight location for Ground water and Eight location for surface Water

physic-chemical parameters and heavy metals

During study period, the sampling was done for one time.



Sr. No.



6.1 Effluent quality after primary treatment

Primary equalization tank

TDS, pH, COD, TSS, ammonical nitrogen, chlorides, sulphates,

Daily by self-analytical facility

6.2 Effluent quality after Secondary treatment

Secondary clarifier

TDS, pH, COD, TSS, ammonical nitrogen, chlorides, sulphates,

Daily by self-analytical facility

6.3 Effluent quality after R.O. treatment

R.O. permeate

For TDS, pH Daily by self-analytical facility

TDS, pH Daily by self-analytical facility

7. Hazardous waste monitoring

Sludge storage area

pH, COD, Chloride Alkalinity, organic content

Comprehensive analysis every 2 year.

Chapter 6: Risk Assessments and Disaster Management Plan Is Uploaded Separately.


M/s.JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 7. 1

Chapter – 7 PROJECT BENEFITS The project has multiple benefits. The large number of product will be exported to various countries. These will results in foreign exchange earning. Also the proposed products are Dye/Dye intermediates & Pesticides. Thus new generation drugs will be available in India. The project will give direct employment to another around 168 people. Also there will be indirect/ supporting business development. Thus will results in increase social upliftman of the community. The company is committed for contribution of funds and provides the services for the upliftment of local community in the nearby villages. The different activities to be undertaken by the company are mentioned in this chapter. The unit is part of Aarti group. The group is known for several corporate social responsibility activities. It is already providing educational, medicinal and community welfare facilities. The group will discuss with local government administration and Vapi industries association for identifying various projects. The unit has planned to spend 5 % of the total cost of the project (Rs.10716 lacs) over a period of five years towards CSR activity. 7.1 SOCIO ECONOMIC ACTIVITIES Programs for environmental education and public participation shall be developed

with the help of visual aids to create awareness about the activities. It has been planned to sponsor to the educational institutes. The proponents have also planned to provide training to the ladies for livelihood

enhancement projects. Proper awareness campaign shall be organized by the project proponent for water

conservation. Periodic health check up camps shall be organized by the project authority for

workers families and surrounding localities. In order to increase the aesthetic environment, road side plantation program shall

be carried out.



Annual get –together and rewards for school children from identified villages who have shown brilliance in education, sports, cultural activities etc. will be arranged.

7.2 OTHER TANGIBLE BENEFITS The unit does contribute towards improving their quality of life since the end users of products are industries ranging from agrochemicals and dyes to specialty chemicals and pharmaceuticals - markets that are critical to long-term sustainability. By supplying high quality and good value products to customers, the unit indirectly helps people to have access to better medicines, fertilizers and diverse items of daily use. 7.3 EMPLOYMENT POTENTIAL There will be increase in the employment facilities due to the upcoming project like There will be employment opportunity for local people during construction and

operation phase. The Unit will use latest STATE OF ART technology. Thus man power will be

exposed to new technology. There will be employment opportunity for local people during construction and

operation phase. 7.4 ACTION PLAN TABLE: 7.1 ACTION PLAN Sr. No.

Activity Fund Earmarked For Activity

Time Schedule

1. Training to unskilled workers Rs. 20 Lacs 5 Years 2. Training to the ladies for livelihood

enhancement projects. Rs. 10 Lacs 5 Years

3. Encouraging school children by way of rewards/scholarships& Sponsorship for Educational Institute’s

Rs. 15 Lacs 5 Years

4. Road side tree plantation and garden development

Rs. 12 Lacs 5 Years



5. Health awareness and support to needed people

Rs. 13 Lacs 5 Years

6. Proper awareness campaign shall be organized by the project proponent for water conservation.

Rs. 5 Lacs 5 Years

7.5 BUDGETARY ALLOCATION The budgetary allocation of 5 years for socio economic activity 1st Year : 15 Lacs 2nd Year : 15 Lacs 3rd Year : 15 Lacs 4th Year : 15 Lacs 5th Year : 15 Lacs



Chapter – 8 ENVIRONMENTAL MANAGEMENT PLAN 8.1 INTRODUCTION Environmental protection is an issue that no organization can neglect and hope to survive. The key to the success of the integrated approach to pollution prevention and control is the management and operation of the organization. Effective committed management delivers a successful industry. A total commitment to the environment, not just for compliance with legal or regulatory compliance will be the essence of environment management of an industry. Many companies have recognized the benefits of implementing an effective environmental management system. 8.2 AIM AND OBJECTIVE The aim of environment management plan is to conserve natural resources and water, to prevent pollution of environment, to ensure effectiveness of control measures and monitoring programme, to ensure safety, welfare and good health of worker, to minimize generation of waste. The objectives of EMP are as under: Pollution will be prevented or reduced at the source, Pollution that can not be prevented will be recycled in to the system, Pollution that can not be prevented or recycled will be subjected for recovery of chemicals

using best technologies, Pollution that can not be prevented or recycled or recovered will be treated in

environmentally safe manner, and Disposal and other releases into the environment will be used “only as a last resort” and will

be conducted in an environmentally safe manner.



8.3 ENVIRONMENTAL MANAGEMENT CELL M/s. Aarti Industries Ltd. (Alchemie Organics Division) has assigned responsibility to officers from various disciplines to co-ordinate the activities concerned with management and implementation of environmental control measures. Environment management cell is shown in below figure 8.1. FIGURE: 8.1 FLOW DIAGRAM OF ENVIRONMENTAL MANAGEMENT CELL

General Manager (EHS Corporate)

Manager (EHS)

Officer (EHS)

Director (Technical)

Shift supervisor (ETP)

Shift operator (ETP)

Vice President

Site head



The unit has planned to revise environment policy based on following points to fulfill corporate environment responsibility. The copy of environment policy is attached as annexure XVIII. PROPOSED CORPORATE ENVIRONMENT POLICY: 1. We will abide by the conditions laid down in Environment Clearance. 2. We will follow regulatory frame work of environment rules and regulations. 3. The focus will be for sustainable development. This will be ensured by adopting cleaner

production technology, recycling all waste water, conserving resources and utilization of Green operations.

4. The stack holders of the company- employees, suppliers, share holders, final product users, financial institutes and local residents will be regularly informed the environment performance of the company. Their suggestions and involvement in environment issues will be encouraged.

5. A manager level person will be employed to supervise day to day operations of pollution control equipments and related area. The manager will directly report to the Vice President. The daily performance report will be circulated amongst in charges of production, maintenance, quality control and HR department besides executive Director. Any deviations noticed will be immediately circulated with Red mark highlighted report. Prompt actions will be sought from all departments.

8.4 ENVIRONMENT MANAGEMENT PLAN Since there will not be any construction activity, the EMP for operational phase has been prepared. 8.4.1 OPERATIONAL PHASE M/s. Aarti Industries Ltd. (Alchemie Organic division) has proposed Environment Management Plan to keep the pollution potential to a minimum level in the operation phase. 8.4.2. (A) AIR ENVIRONMENT The sources of air pollution are in form of flue gas emission , process emission and fugitve emission.



FLUE AS EMISSION AND PROCESS EMISSION The sources of flue gas emission are two D.G. sets. (for emergency use only). The unit is getting steam from neighbouring industry namely M/s. Aarti industries Ltd., plot no 801/23, Phase-III, GIDC Estate, Vapi. The unit has proposed one additional D.G. sets for proposed expansion. The details are given in Table no.8.2 The source of existing process emission is one process stacks only. Old incinerator stack is dismantled. There will be three additional stacks of process emissions due to proposed expansion. Details of height, Air pollution control system, parameter etc. are given in Table no.8.2.A drawing of water scrubber followed by alkali scrubber is attached as annexure- XIX. The control measures of flue gas emission and process emission are as under. TABLE: 8.2 DETAILS OF CONTROL MEASURES FOR FLUE GAS EMISSION AND PROCESS EMISSION Sr. No.

Source Waste Type/Pollution

Control Measures Existing Flue gas emission 1. Two stacks of two DG

sets (Stand by) Air pollutant (PM, SOx, NOx)

Adequate stack height Proposed Flue gas emission 1. One stack of DG set

(Stand by) Air pollutant (PM, SOx, NOx)

Adequate stack height Existing process emission 1. Stack attached to reactor

of 2-Broromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene

Br2,HBr Water scrubber followed by Alkali Scrubber

Proposed process emission 1. Stack attached to

chlorinator reactor Cl2,HCl Water scrubber followed

by Alkali Scrubber 2. Stack attached to Dizo

vessels NOx, HCl Water scrubber followed

by Alkali Scrubber 3. Stack attached to SFD

dryer PM Water scrubber



Regular ambient air quality monitoring will be carried out within premises and near by area for PM10, PM 2.5, SOX, NO2, Cl2, HCl, HBr, Br2 and VOC in the downwind directions as well as where maximum ground level concentration are anticipated and record of the same shall be maintained. Work area ambient air quality monitoring will be carried out as per Gujarat Factories Rules. FUGITIVE EMISSION Now a day as industrial growth increases, concerns of fugitive emission also increases. Percentage of contribution of fugitive emission to air pollution and climate change will also increase. Probable source of fugitive emission are raw material handling, storage tank of acid, storage tank of solvent, leakage from valves, flange joints of pipeline, pump & motors, reactor, loading & unloading area etc. General control measures like routine & regular inspection to identify leakage, preventive maintenance and operational maintenance, provision of leak detection and repair system (LDAR) and potable instrument for measurement of VOC etc. are already implemented by the unit. The same with additional equipments will be continued. TABLE: 8.3 DETAILS OF CONTROL MEASURES FOR FUGITIVE EMISSION Sr. No.


Control Measures

1. Storage tank of acid

Air pollutant (Acid fumes)

Close handling system Carry out work place monitoring to

find out concentration level in ambient air

2. Solvent storage tank

Air pollutant (VOC)

Under ground MS storage tank for solvent having low boiling point

Carry out work place area monitoring to find out concentration level in ambient air

Close handling system Provision of breather valve cum

flame arrester. 3. Solvent

recovery system Air pollutant (VOC)

There will be installations of new reactors with heat exchangers. At the



Sr. No.


Control Measures

reactors itself the solvent will be recovered. At the end of heat exchangers, the water scrubbers are provided to arrest pollutants. The same scrubbers will also stop VOC going into atmosphere. There will be recovery of more than 95% solvent.

4. Handling of raw material bags in storage area

Air pollutant (PM)

Provision of exhaust ventilation Provision of PPE Provision of Job rotation to reduce

exposure 5. Flange joints of

pipeline, pump & motors

Air pollutant (VOC)

Routine & periodic inspection to check leakage

Preventive maintenance, follow SOP for maintenance

Pumps & motors are mechanical seal type

LDAR program is followed. 6. Solid raw

material transferring to reactor

Air pollutant (PM)

Hopper are provided with powder transfer system

7. Liquid raw

material transferring to reactor

Air pollutant (VOC, acid fumes)

Feeding of liquid raw material is carried out by closed pipeline and mechanical seal pump.

8. Loading /unloading at storage area

Air pollutant (VOC)

Unloading through pipeline to tank in a close system.

8.4.2. (B) WATER ENVIRONMENT The unit will use 887 KL/Day water after proposed expansion. The unit will use 599 KL/Day of fresh water from GIDC water supply system and 288 KL/Day will be recycled water. Extra water required for the proposed expansion of project will be fulfilled by GIDC water supply system.



Total waste water generation will be 302 KL/Day. This waste water includes waste water coming out from process (137 KL/Day), washing (30 KL/Day), DM plant regeneration (5 KL/Day), cooling tower blow down (70 KL/Day), and sewage (60 KL/Day). Concentrated & Toxic effluent stream of 11.7 KL/Day will be sent to common incinerator facility. 137 KL/Day of effluent from process and 30 KL/Day effluent from washing will be sent to unit’s own Effluent Treatment Plant comprising of primary, secondary & tertiary treatment facilities. Treated effluent from ETP will be sent to R.O. system-1. Cooling tower blow down of 70 KL/Day and 5 KL/Day DM plant will be subjected to R.O. system-2. This unit has proposed for zero liquid discharge for industrial effluent. To achieve zero liquid discharge, R.O. reject of 50 KL/Day from R.O. system-1 and R.O. reject of 22 KL/Day from R.O. system-2 will be subjected to MEE. R.O.permeate of 117 KL/Day from R.O. system-1, R.O.permeate of 53 KL/Day from R.O. system-2 and MEE condensate of 68 KL/Day will be reused. Residue from MEE of 4 KL/Day will be sent to landfill site. Sewage of 60 KL/Day will be treated in Sewage treatment plan and treated water will be used for gardening purpose and in cooling tower. The description of effluent treatment process is given as under. 8.4.2.1 DETAILS OF EFFLUENT TREATMENT PLANT Existing Effluent Treatment Scheme The company is generating two types of effluents i.e. highly concentrated effluent stream and dilute effluent stream. The concentrated effluent stream alkaline in nature is separately collected in collection tank and directly incinerated in incineration system of 500 liters per hour capacity. The dilute effluent from the process plant is collected in a collection sump from which it is taken to oil & grease trap for separation, oil and grease is skimmed off from the top. Effluent is then pumped to neutralization tank where pH is neutralized between 7 to 8 and compressed air is used for agitation. Then it is transferred to decanter for sludge dewatering then it is taken to equalization tank after that effluent is pumped to primary settling tank where suspended solids are settled and the sludge



is taken into sludge drying bed. Leachate is collected and sent back to equalization cum neutralization tank. Dried sludge is stored in a sludge storage tank. Clear water from settling tank is taken into aeration tank no. 1. In this tank, extended type aeration system is adopted. Biological treatment is given to the effluent. Overflow is taken into primary lamella separator for excess sludge settling, Biomass is re circulated in aeration tank if required or sent to SDB. Then further it is taken into second stage bioreactor and second stage settling tank. Overflow from secondary settling tank is passed through two stage activated carbon filter and then drain into underground effluent drainage line to CETP, Vapi. Proposed Effluent Treatment Scheme The unit is having effluent treatment plant consisting of primary, secondary, and tertiary treatment. The effluent is treated in ETP. Treated water will be further treated in RO followed by MEE. The condensate water from MEE and permeate water from RO is reused and the residue from MEE is send to TSDF site. The unit will be zero liquid discharge for industrial effluent. Sewage will be treated separately in STP and treated water will be used for gardening purpose and reused in cooling tower.



EXISTING EFFLUENT TREATMENT PLANT FLOW DIAGRAM



EFFLUENT TREATMENT PLANT FLOW DIAGRAM (PROPOSED EXPANSION)

Process Effluent

Existing ETP

Utility Blow down

RO-1

RO-2

MEE

Cooling Tower

RO Permeate

RO Permeate

RO Reject

RO Reject TO TSDF Site

Nutch Filter

ENVIRONMENT IMPACT ASSESSMENT REPORT M/S. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI.


Details of existing ETP units are shown in following Table no. 8.4. TABLE: 8.4 DETAILS OF EXISTING ETP UNITS

Sr.No.

Name of the Unit Dimensions in m

Capacity in m3

No. Total Capacity m3

MOC

1. Inlet Sump 2x2x2 8 3 24 RCC 2. Oil/grease trap-1 1x1x2.5 2.5 3 7.5 RCC 3. Collection sump 3.6x1.75x2.

8 17.6 1 17.6 RCC

4. Equalization tank – 1 3.2x8.2x3.0 78 1 78 RCC 5. Equalization tank – 2 3.2x8.2x3.0 78 1 78 RCC 6. Equalization tank – 3 6.4x8.2x3.0 157 1 157 RCC 7. Holding Tank – 1 3.4x6.0x5.0 102 1 102 RCC 8. Holding Tank – 5 3.4x6.0x5.0 102 1 102 RCC 9. Mixing Tank 2.0dia x 1.6 5 1 5 HDPE 10. Primary Lamella

settling tank 4.0x4.0x(1.7+0.5) 28 1 28 RCC

11. 1st stage Bioreactor 13.2x13.2x5.0 871 1 871 RCC

12. 1st stage secondary settling tank 7.0dia. x 2.5 85 1 85 RCC

13. 2nd stage Bioreactor 7.0x7.0x4.0 160 1 160 RCC 14. 2nd stage secondary

settling tank 4.0dia. x 2.5 31 1 31 RCC 15. Sand filter 0.625 dia. x

2.5 0.766 1 0.766 MS 16. Sand filter 1.1 dia. x

1.3 1.23 1 1.23 MS 17. Activated Carbon

filter 1.4 dia. x 2.0 3.0 1 3.0 MS

18. Sludge drying beds 5.0x5.0x1.3 32.5 m2 4 130 m2 RCC 19. Sludge drying beds 3.3x3.2x1.3 13.72 m2 3 41.18 m2 RCC 20. Neutralization tank 3.9dia. x

1.75 21 2 42 RCC 21. Neutralization tank 4.1 dia. x

2.0 26 2 52 RCC 22. Filter Press 1.2x1.2 62 1 62 PP 23. Filter Press 1.2x1.2 48 1 48 PP 24. MEE - 75 KL 1 75 KL



The existing ETP is adequate to treat proposed additional quantity of effluent. As the unit has proposed zero liquid discharge for industrial effluent, the unit has proposed expansion in existing ETP and details are as under. Details of proposed ETP units are shown in following Table. TABLE: 8.5 DETAILS OF PROPOSED ETP UNITS Sr. No.

Name of the Unit

Dimensions in m

Capacity in m3

No. Total Capacity m3

MOC

1. MEE PLANT 4.5 X 12 29 1 29 SS316 2. ATFD 4 X 4 6 1 6 SS316 3. HPRO -1 7.5 X 7.5 141 1 141 Membrane 4. HPRO -2 7.5 X 7.5 42 1 42 Membrane 5. SP RO 7.5 X 5.7 138 1 138 Membrane 6. DESILICA

AREA 5 X 11 141 1 141 HDPE

7. COOLING TOWER

4 X 4 400 TR 1 400 PPFRP TABLE: 8.6 DETAILS OF POWER COSUMPTION Sr. No.

Material Power Requirement KW HP

1. PT RO - 136KLD 24 32 2. HP RO - 41KLD 11 15 3. SP RO – 111KLD 10 13 4. Desilication System 13 17 5. MEE – 50KLD 43.6 58 6. Transferring Pumps 30 40 7. Cooling System 29.8 40 Total 161.4 216



TABLE: 8.7 DETAILS OF ETP TANKS Sr.No.

Tank list MOC Capacity (KL)

Size Qty. (Nos.) Dia.mm Height mm

1. Effluent Water Collection Tank

MS 50 3500 5200 2 2. Treated Water

(or) RO Feed Collection Tank

HDPE 20 2400 4500 1

3. HP RO Feed Collection Tank

HDPE 5 1600 2500 2 4. SP RO Permeate

Collection Tank HDPE 15 2400 3200 1

5. HP RO Reject Collection Tank

HDPE 5 1600 2500 2 6. MEE Bottom

Draining Tank HDPE 5 1600 2500 1

7. MEE Condensate Collection Tank

MS 5 1600 2500 1 Total 10

TABLE: 8.8 DETAILS OF ETP PUMPS Sr.No.

Material Description

Transferring Pumps Effluent Water Transferring Pumps

Desilication Systems Feed Pumps

PT RO Feed Transferring Pumps

HP RO Feed Transferring Pumps

MEE Feed Pumps

MEE Condensate Transferring Pumps

1. Flow Rate (m3/hr)

15 15 10 4 3 2 2. Head (m) 35 35 35 35 20 30 3. Temperatur

e(deg C) 40 40 40 40 40 80

4. Viscosity (Cp)

1 1 1 1 1 1 5. Density(kg/

m3) 1100 1100 1100 1100 1100 1000

6. MOC CI CI CI CI SS SS 7. Quantity

(Nos) 2 2 2 2 2 2



The Characteristics of the effluent before and after treatment are given in below Table. TABLE: 8.11 EXISTING CHARACTERISTICS OF WASTEWATER BEFORE TREATMENT & AFTER TREATMENT Sr. No.

Parameter Before Treatment After Treatment 1. pH 5-9 6.5-8.5 2. COD (mg/L) 3000-4000 300-500 3. TDS (mg/L) 18000-22000 15000-18000 4. TSS (mg/L) 250-350 150-270 5. Ammonical Nitrogen (mg/L) 35-45 20-25 6. Chloride (mg/L) 5000-6000 5000-6000 7. Sulphate (mg/L) 2500-3000 2500-3000

TABLE: 8.12 EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE TREATMENT & AFTER TREATMENT Sr. No.

Parameter Before Treatment After Treatment

1. pH 6-9 7-8 2. COD (mg/L) 3000-5000 300-800 3. TSS (mg/L) 150-300 20-50 4. TDS (mg/L) 10000-12000 9000-12000 5. Ammonical Nitrogen

(mg/L) 20-40 5-20

8.4.2.2 DETAILS OF SEWAGE TREATMENT PLANT TABLE: 8.13 DETAILS OF DIFFERENT STP UNITS Sr. No.

Description Nos. Capacity in m3

1. Equalization tank 1 28 2. Aeration tank 1 18



Sr. No.

Description Nos. Capacity in m3

3. Settling tank 1 8 4. Clarified water

tank 1 4

5. Treated water tank 1 22 6. Sludge tank 1 16

FIGURE: 8.5 FLOW DIAGRAM OF STP



TABLE: 8.14 DETAILS OF CONTROL MEASURES FOR EFFLUENT AND SEWAGE GENERATION

Sr. No.


Control Measures

1. Process, washing, scrubber, utility,

Effluent Adequate Effluent treatment plant having primary, secondary and tertiary treatment. Treated waste water will be subjected to R.O. and MEE to achieve zero liquid discharge.

Proper house keeping preventing contamination of ground water & storm water drainage.

Record of hazardous waste generation during the treatment of waste water and its disposal.

Water conservation measures will be taken to explore possibility of reuse/recycle of water.

Process optimization, reduction, reuse and recycle of water will be carried out to minimize the impact.

Record of water consumption will be maintained for each usage in future.

2. Domestic uses

Sewage Adequate Sewage treatment plant. Treated sewage will be used for

gardening purpose and in cooling tower.



8.4.2. (C) NOISE ENVIRONMENT The sources of noise generation will be transportation activities, D.G. set, cooling tower, plant machinery etc. The unit will take following measures to control noise pollution. TABLE: 8.15 DETAILS OF CONTROL MEASURES FOR NOISE POLLUTION Sr. No.


Control Measures

1. Transportation activities

Noise pollution Green belt Restriction on transportation

between 10 p.m. to 6 a.m. Maintain vehicle in good

condition. 2. D.G.set Noise pollution Engineering control,

Provision of PPE, Green belt, 3. Plant/process

area Noise pollution Maintain equipment & machines in

good working condition. Isolated noisy area from other area

by distance and if it is not possible than by physical separation or noise proof valve.

Provide silencer to safety valve, relief valve

Provision of PPE, Green belt, Record noise level monitoring of

different places within and outside premises,

Periodically Audio metric test., Rotation of work to minimize

exposure.



8.4.2. (D) LAND ENVIRONMENT RAW MATERIAL & PRODUCT STORAGE AREA The unit will take following control measures to prevent land contamination from raw material storage and handling. Raw materials will be stored in M.S tanks, S.S tank and HDPE Carboys, HDPE

bags,etc in sepereate storage room. All the raw effluent storage tanks will be covered with RCC slab.

Separate collection system is provided for collection of spillage material. Impervious layer, RCC roads and flooring is provided to area, where the chemical storage and handling activities is involved.

Hazardous flammable substances are separately stored in (solvent) tank farm area within premises. Solvent transfer is done by pumps. Reactor & solvent handling pump have mechanical seal.

The acid tanks are provided with dyke wall to control spread of leakages. HAZARDOUS WASTE DISPOSAL The hazardous wastes generated from the industry are ETP waste from ETP, distillation residue, spent solvents, spent catalyst, spent filter cloth, date expired pesticides, spent carbon, gypsum from process, discarded containers/ bags /liners from raw material handling and used oil from maintenance of engineering unit. The details of quantity of hazardous waste generated and disposal mode are given in below table. A copy of membership certificate of Landfill site and common incinerator facility is attached as annexure-XX. Forklift is used in shifting, loading and unloading operation for hazardous waste to minimize manual handling of hazardous waste. ETP sludge, spent filter cloth and gypsum will be sent to approve landfill site. Distillation residue, spent solvent, date expired pesticide, spent carbon will be sent to approve common incinerator facility. Spent catalyst will be sent to registered regenerators. Used oil will be sell to register reprocessor.Discarded containers/bag will be reuse or sold to actual reusers. It has been planned to use high calorific waste like distillation residue, spent solvent, date expired pesticide, spent carbon to send for co-incineration at cement industries.



That will result in reducing load on incinerator. Also there will be energy conservation at cement industries and reduction in green house gases. There are facilities coming up in this region for collection, storage and premixing of high calorific value waste and send to cement industries. The unit will become member of that facility. TABLE: 8.16 DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL MODE Sr. No.


Cat. No.




1. ETP Waste 34.3 1090 5760 Collection, Storage, transportation, disposal at TSDF site.

2. MEE Salt 34.3 0 1440 Collection, Storage, transportation, disposal at TSDF site.

3. Distillation Residue

26.1 481.2 3675.12 Collection, storage, Transportation, disposal by sending to Common Incineration. /co processing site.

4.

Discarded Containers

33.3 8

16

Collection, Storage, Decontamination and reuse or sold to actual reuses. Bags/ Liners 39.8 80

5. Used Oil 5.1 0.6 KL/Year

2.4 KL/Year

Collection ,storage, Transportation, Disposal by selling registered re processors



Sr. No.


Cat. No.




6. Spent Catalyst

--- 8.4 850.92 Collection, Storage, Transportation, disposal at registered regenerators.

7. Spent Solvent 20.2 1.2 1.2 Collection, storage, Transportation, disposal by sending to Common Incineration./ co processing site.

8. Spent Filter Cloth

35.1 700 Nos./Year

1500 Nos./Year

Collection, Storage, Transportation, disposal at TSDF site.

9.

Date Expired Pesticide

29.3 2 4 Collection, storage, Transportation, disposal by sending to Common Incineration. / Co processing site.

10. Spent Carbon 35.3 0 83 Collection, storage, Transportation, disposal by sending to Common Incineration. / Co processing site.

11. Gypsum 34.3 0 2640 Collection, Storage, Transportation, disposal at TSDF site/cement industry.

12. Insulation Waste

-- 0 4 Collection, Storage, Transportation, disposal at TSDF site.



TABLE: 8.17 DETAILS OF HAZARDOUS WASTE STORAGE Sr. No.

Type of Hazardous Waste Category No. Storage Area In sq. m.

1. ETP Waste 34.3 270 2. Distillation residue 29.1 76 3. Spent catalyst --- 16 4. Spent solvent 20.2 16 5. Spent filter cloth 35.1 4 6. Date expired pesticides 29.3 16 7. Spent carbon 35.3 4 8. Gypsum 34.3 270 9. Discarded containers/bags 33.3 25 10. Used oil 5.1 4 11. Insulation waste 36.2 4

8.4.2. (E) GREEN BELT DEVELOPMENT The main objective of green belt is to provide a barrier between source of pollution and surrounding area by filtering the air particulate and interacting with gaseous pollutants before it reaches to the ground. The company has existing green belt area of 2346 sq m. There are 700 trees in existing green belt area. Trees like Neem (Azadirachta indica), Ashoka, Peeplo (Fecus.relogiosa), Coconut etc. are already present in existing green belt area. 8.4.2. (F) VEHICULAR POLLUTION CONTROL All vehicles are maintained in well condition by regular preventive maintenance to

reduce the exhaust level. Drivers of all vehicles used in the transportation will be trained in transportation of

Hazardous chemicals to prevent any accident. Fitness and training test certificate approved by R.T.O to be maintained on the vehicle at all times to ensure transport worthiness.



All vehicles must comply the vehicular pollution norms and it must have Pollution under Control (P.U.C) certificate.

Checking of PUC certificate for validity and emission level in exhaust of all entering vehicles.

8.4.2. (G) ENERGY CONSERVATION PROGRAMME Presently, the unit do not have boiler for steam generation. The unit is using steam from neighbouring industry namely M/s. Aarti Industries Ltd., located at plot no 801/23 ,phase-III,GIDC Estate, Vapi. After proposed expansion also, the unit will use steam from sister concern. 8.4.2. (H) BUDGETORY PROVISION PROPOSED FOR ENVIRONMENT POLLUTION CONTROL MEASURES Description of capital cost and recurring cost for environment control measures for different type of activities like environment monitoring, green belt, effluent treatment plant and hazardous waste storage and disposal is given below: TABLE: 8.18 CAPITAL COST AND RECURRING COST FOR ENVIRONMENT CONTROL MEASURES Sr. No.

Activities Capital Cost In Lacs for proposed expansion (Approx)

Recurring Cost In lacs /Annum (Approx)

1. Environment monitoring 50 3 2. Green belt 30* 3 3. Effluent treatment plant 800 360 4. Hazardous waste storage

and disposal 30 360

5. Air pollution control measures (Part of plant & machinery)

10 5 Total 920 731

* The cost is proposed for green belt development within premises and outside premises.



8.4.2. (I) HEALTH AND SAFETY Occupational health impact and mitigation measures to avoid health hazard are as under All reasonably practical measures is adopted by the unit to minimize the risk of

accidents within a chemical manufacturing unit All building plans and installations are as per relevant laws and approved by

competent authority Training is imparted to all workers for all the hazardous process operations within

the plant and is supervised by experienced supervisors Suitable personnel protective equipments and fire extinguishers at strategic

locations and suitable personal protective equipments are provided Flame proof electrical fittings, flame arrestors etc are installed All the raw materials & solvents are stored in designated storage area equipped

with necessary safety features. Physical and chemical properties of raw materials and products are available in

MSDS and they are attached as annexure XXI. The solvent storage area is restricted for unauthorized persons. Proper earthling is

provided in all electrical equipment whenever solvent handling is done. Flame arrester cum breather valve and flame proof fitting is provided at tank farm.

Periodic inspection & testing of pressure vessels, equipments, and machineries will be done.

Good housekeeping is ensured within the factory premises All designated staff & workers are trained for the fire fighting, work permit

system, first aid and safe handballing of hazardous chemicals. Incident/accident reporting system are developed and all the employees are made

aware for the same Suitable notices/boards are displayed at designated locations indicating

appropriate hazard warnings. Antidotes as well as MSDS for all the chemicals will be made available within the

factory premises.



Pre-employment medical check up at the time of employment is carried out. In order to safe guard the health of the employees, all the employees undergo periodic health checkup at every six month.



CHAPTER -9 COMPLIANCE OF ENVIRONMENTAL CONDITIONS 9.1 INTRODUCTION The unit has been asked in the additional ToR to prepare a separate chapter for status of compliance of environmental condition granted by state / centre to be provided. As per circular dated This is as per circular dated 30th may, 2012 issued by MoEF, a certified report by RO, MoEF on status of compliance of conditions on existing unit to be provided in EIA-EMP report. In this chapter all the details are provided. The certified report by RO, MoEF Bhopal is attached as Annexure XXII. The unit has received show cause notices/direction in last five years. All are attached as annexure XXIII. The details of each notice/direction is as under, 9.1.1 Show cause notice Ref. no. 1- GPCB/CCA-VSD-32/ID: 22980/119661 dated 27/07/12. The unit had made application for change of product mix. GPCB interpreted that the unit is installing new process stack on the reactor. The unit submitted the clarification that they are not installing any new stack. The GPCB granted the product mix application. Submitted reply to GPCB is also attached for your reference. (Annexure XXIII) 9.1.2 Show cause notice Ref. no. 2-SCN-132094 dated 11/12/12. During regular visit of GPCB, incinerator was found not in operation. Also it was noted that around 350 Ton of ETP waste was lying in the premises. The unit submitted the clarification that during monsoon landfill site was closed. So ETP waste was not dispatched. The unit promised to dispatch waste. For incinerator unit had no sufficient material to incinerate. So unit had decided to put incinerator for maintenance. The GPCB accepted the explanation and no action was taken against the unit.Submitted reply to GPCB is also attached for your reference. (Annexure- XXIII)



9.1.3 Show cause notice Ref. no. 3- SCN-144490 dated 20/04/2013. During regular visit of GPCB, temperature of secondary chamber of incinerator was 8000C, which was interpreted as the incineration was not operating efficiently. The unit provided the explanation that the unit was operating the incinerator only in the day shift. Unit was in the process of stopping the incinerator when officers visited their unit. In the presence of them they started the operation and within 15 minutes the secondary chamber temperature was reached 1200 0C. Submitted reply to GPCB is also attached for your reference. (Annexure- XXIII) 9.1.4 Show cause notice Ref. no. 4- SCN-156271 dated 10/08/2013. During regular visit of GPCB, approximately 200 MT of ETP waste was observed in the premises. The unit provide the explanation that Vapi waste & Effluent Management Co. Limited was not lifting hazardous waste due to monsoon. Hence they stored the waste. After that unit shifted the entire waste to TSDF site. Submitted reply to GPCB is also attached for your reference. (Annexure- XXIII) 9.1.5 Show cause notice Ref. no. 5- SCN-160419 dated 21/09/2013. During regular visit of GPCB, fugitive emission of HCl was observed. Leakages / spillages at various places observed. Large nos. of drums was lying on open land. The unit stopped all leakages. Drums were filled with incineration material. They were sent to common incineration. Submitted reply to GPCB is also attached for your reference. (Annexure- XXIII) 9.1.6 Show cause notice Ref. no. 6- GPCB/VSD/ID-22980/211658 dated 29/04/2014 Due to NGT order, all industries of Vapi were issued notices and asked to create own treatment facility and stop sending effluent to CETP. Vapi Industries Association approached Hon. Gujarat High Court and obtained stay order. Submitted reply to GPCB is also attached for your reference. (Annexure- XXIII) 9.1.7 Show cause notice Ref. no. 8- SCN-221272 dated 05/08/2014. During regular visit of GPCB, MEE was found not in operation during visit. You have not provided leachate collection system & proper hazardous waste storage area for solid waste. MEE was under maintenance and due to that production was also stopped. Proof of leachate collection system was provided. Submitted reply to GPCB is also attached for your reference. (Annexure- XXIII).

ENVIRONMENT IMPACT ASSESSMENT REPORT M/s. AARTI INDUSTRIES LTD. (CUSTOM SYNTHESIS DIVISION), GIDC, VAPI.


Chapter – 10 EXECUTIVE SUMMARY & CONCLUSION 10.1 INTRODUCTION M/s. Aarti Industries Ltd. (Alchemie Organics Division) is located at plot no.902, 923, GIDC Estate, Phase-III, Vapi, and District: Valsad, Gujarat. The unit has valid CCA order AWH-53342, issue on dated 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. Existing manufacturing involves unit operations like hydrogenation, diazotization, bromination, condensation and chlorination products. Total existing production capacity is 5595 MT/Year. The unit has proposed expansion for manufacturing of products by hydrogenation, diazotization, bromination, condensation and chlorination. Also, the unit has proposed new products based on hydrolysis. After expansion, total production capacity will be 17378.17 MT/Year. The unit has proposed expansion of existing unit. The products proposed by the unit fall in the schedule attached to the EIA Notification, i.e. Project No. 5(b) &5(f), Dye/Dye intermediates & Pesticides products. Since the project is established in industrial Estate, Vapi, and it is located within 10 Km distance from interstate boundary of Gujarat & Union Territories (Daman and Dadar& Nagar haveli) so it is classified as Category A project. Public hearing is not applicable to this expansion project as the unit is located in GIDC notified area. Environment Clearance will be evaluated by the Industrial committee of MoEF, New Delhi. 10.1.1 LOCATION M/s. Aarti Industries Ltd. (Alchemie Organic Division) is located at plot no 902, 923, GIDC Estate, Phase-III, Vapi,Dist.:Valsad, Gujarat. It is approximately 26 km distance from District: Valsad. The approximate geographical positioning of the project site is at Latitude: 20°21’47.26”N and Longitude: 72°54' 49.20” E. The unit is spread over in 11,970 sq.m. area in GIDC Vapi. A railway line is 3.0 Kms away from the project site. The nearest Domestic Airport is Surat, about 90 Km away from the project site. The nearest international Airport is Mumbai, around 152 Km away from the Vapi GIDC Estate.



10.1.2 INVESTMENT Existing investment in plant and machinery, land, building etc. is Rs. 9201 Lacs. The additional investment for proposed expansion will be Rs. 1515 Lacs. It has been classified as Large Scale Industry. 10.1.3 INFRASTRUCTURE FACILITIES The plant will be located in a well-developed industrial zone, which will have all essential facilities such as internal roads, arrangement for supply of water and power to industries etc. 10.2 PROJECT DESCRIPTION 10.2.1 NEED FOR THE PROJECT Any investment decision is done based on techno economic viability of the project. The project has to be technically feasible and financially viable in nature. The existing unit is in export market for several years. They have range of products from various units and catering to the need of industries. The demand for newer molecules used to be regular feature from several countries as well as from India. Moreover, the demand for existing product was constantly fluctuating. There arise competitions from other manufacturers for existing range of products. So as long term planning, the management decided to introduce new range of products. 10.2.2 PRODUCTION AND RAW MATERIAL Existing manufacturing involves unit operations like hydrogenation, diazotization, bromination, condensation and chlorination products. Total existing production capacity is 5595 MT/Year. The unit has proposed expansion for manufacturing of products by hydrogenation, diazotization, bromination, condensation and chlorination. Also, the unit has proposed new products based on hydrolysis. After expansion, total production capacity will be 17378.17 MT/Year. Existing total production capacity of the unit is 5595 MT/Year. The By-product formation is 53723.5 MT/Year. After expansion the total production will be 17378.17 MT/Year and the byproduct formation will be 179123.52 MT/Year.



Raw materials are stored in M.S. Tank, S.S. Tank, and HDPE Carboys, fiber drums, glass bottle and cylinders. Solvents like Toluene, Acetone etc. are stored in MS/SS tank with all precautionary process instrumentation and safety appliances. 10.2.3 RESOURCE REQUIREMENT LAND The total plot area of the unit is 26271 sq. m. The green belt area is 1943.90 sq. m. WATER REQUIREMENT Average daily fresh water consumption of the unit is about 404 KL/Day. The unit will use additional fresh water of 195 KL/Day for proposed expansion. Unit will also use recovered water of 268 KL/Day. So, total water consumption will be 867 KL/Day (599 KL/Day of fresh water + 268 KL/Day of recycled water) after proposed expansion. ENERGY REQUIREMENT The existing connected load is 1200 KVA.The proposed connected load will be 800 KVA.It will be met through Daxin Gujarat Vij Company Ltd. UTILITIES For the proposed expansion project the utilities to be installed will be Cooling tower, Air compressor, and chilling water plant. 10.2.4 POLLUTION POTENTIAL SCENARIO WASTE WATER MANAGEMENT As per consent, the industrial effluent generation is 79 KL/Day and sewage generation is 20 KL/Day. Concentrated & toxic effluent stream of 11.7 KL/Day is sent for in-house incineration. Existing effluent is treated in ETP having primary, secondary and tertiary treatment. Treated water is sent to CETP. After proposed expansion, total industrial effluent generation will be 242KL/Day (79 KL/Day + 163 KL/Day).After expansion sewage generation will be 60 KL/Day (20 KL/Day + 40 KL/Day).After proposed expansion, concentrated & toxic effluent stream of 11.7 KL/Day is sent to common incineration facility for incineration. Remaining water will be treated in unit’s own treatment plant and recycled back using RO and MEE system.



GASEOUS EMISSION The sources of flue gas emission are two D.G. sets (emergency use only). There will be one additional D.G. stack due to proposed expansion. Process emission is from one stack attached to reactor of 2-Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene. There will be one additional stack attached to chlorinator reactor, one stack of SFD Dryer and one stack attached to Dizo vessels due to proposed expansion. HAZARDOUS WASTE GENERATION The existing hazardous waste are ETP Waste (1090 MT/Year), Ash from incineration (160 MT/Year), Distillation residue (481.2 MT/Year), Discarded containers/ (8 MT/Year), Discarded Bags/Liners (39.8), Used oil (0.6 KL/Year), Spent Catalyst (8.4 MT/Year), Spent Solvent (1.2 MT/Year), Spent Filter Cloth (700 Nos. /Year), Date Expired Pesticide (2 MT/Year) . After proposed project activity, additional hazardous waste will be ETP Waste (7200 MT/Year), Distillation residue (3675.12 MT/Year), Discarded containers/ (16 MT/Year), Discarded Bags/Liners (80 MT/Year), Used oil (2.4 KL/Year), Spent Catalyst (850.92 MT/Year), Spent Solvent (1.2 MT/Year), Spent Filter Cloth (1500 Nos. /Year), Date Expired Pesticide (4 MT/Year), Spent Carbon (83 MT/Year), Gypsum (2640 MT/Year), Insulation waste (4 MT/Year). 10.3 BASELINE ENVIRONMENT STATUS 10.3.1 STUDY AREA INCLUDED IN ENVIRONMENTAL SETTING Studies were carried out in about 10 km radius area from the project site with respect to meteorology, flora, fauna, land and socio-economies of the area. Further sampling and analysis of air quality, water quality, noise level and soil quality were carried out. The base line data were monitored for study period of March, 2015 to May, 2015. The study team conducted site surveys and field experiments to gathering the information on air quality, water quality, noise quality and soil quality.



10.3.2 CLIMATE OF THE STUDY AREA Relative Humidity The maximum relative humidity reported around 85% and minimum relative humidity is reported around 24% during period of March,2014 to May,2014. Temperature The maximum temperature is reported 40oC and the minimum temperature is reported 12.8oC during period of March, 2014 to May,2014. Rainfall There was no rain fall during the March, 2014 to May, 2014. Wind As per the metrological data it shows that the predominate wind direction for study period is wind blowing to NE. 10.3.3 AMBIENT AIR QUALITY The ambient air monitoring was carried out for 24 hours a day twice a week for 12 week per location in the study area. Ambient Air Quality Monitoring (AAQM) was carried out at nine locations during period of March, 2015 to May, 2015. The maximum and minimum concentrations for PM10 were recorded as 97.8 µg/m3 and 75.8 µg/m3 respectively. The maximum and minimum concentrations for PM2.5 were recorded as 57.7µg/m3 and 38.6µg/m3 respectively. The maximum and minimum concentration for SO2 was recorded as 35µg/m3 and 21.5µg/m3. The maximum and minimum concentration for NOx was recorded as of 49 µg/m3 and 35 µg/m3. The maximum and minimum concentration for VOC was recorded as of 6 and 0. The maximum and minimum concentration for NH3 was recorded as of 3.8 µg/m3 and 1.2 µg/m3. The maximum and minimum concentration for CO was recorded as of 990 mg/m3 and 600 mg/m3. The values of HCl, Cl and HBr, Br2 were found Below Detectable Limit. 10.3.4 WATER QUALITY Based on data obtained, it could be stated that the value of all parameter were found within the permissible limit of Indian standards for all ground water samples and surface water samples.



10.3.5 NOISE ENVIRONMENT Noise level monitoring was carried out at five locations during period of March to May, 2015. During monitoring period, the LEQ (dB (A)) noise levels varied between 53-72 (dB (A)) and 53-61 (dB(A)) during day time in industrial area and residential area respectively. Noise levels varied between 45-53 (dB (A)) and 37-53 (dB (A)) during night time in industrial area and residential area respectively. 10.3.6 SOIL On data obtained, it is ensured that the soil quality at around site is appropriate and no abnormality in terms of soil contaminants is reported. 10.3.7 LAND USE OF THE STUDY AREA As per satellite imagery, major land use of study area of 10 km is covered by 155.9 sq. m. of open land, 57.9 sq. m. of Agricultural land, 37.13 sq. m. of open/degraded vegetation, 19.74 sq. m. of Fallow land, 9.6 sq. m. of plantation, 8.81 sq. m. of settlement & habitation, 8.71 sq. m. of industrial area, 7.97 sq. m. of River & canal. 10.3.8 BIOLOGICAL ENVIRONMENT The entire zone of valsad district that comprises of maritime coastal environment and also the upland forest in the North-East has been classified as Tropical Moist Deciduous Forest. There are patches of reserved forest and protected forests within 10 kms radial periphery of the study area. 10.4 IDENTIFICATION & ASSESSMENT OF IMPACT 10.4.1 WATER ENVIRONMENT The average daily water requirements after proposed expansion will be 404 KL/Day. The unit will use 195 KL/Day of fresh water and 268 KL/Day of recovered water. Fresh water will be met by GIDC water supply scheme. There will be no extraction of ground water, so that no direct impact is found on ground water availability.



The unit has ETP having primary, secondary and tertiary treatment. The effluent is treated inept. Treated water will be further treated in R.O. followed by MEE. The condensate water from MEE and permeate water from RO is reused and the residue from MEE is send to TSDF site. The unit will be zero liquid discharge for industrial effluent. Sewage will be treated separately in STP and treated water will be used for gardening purpose and reused in cooling tower. 10.4.2 AIR ENVIRONMENT Dust, NOx, SO2, VOC and HC may be slightly released into the local ambient air due to construction activities and vehicular traffic movement in construction activities of proposed project. There is emission of PM, SO2,NOx from DG Set stacks and emission of NOx, HCl, Cl2, HBr and Br2 from process stacks. From the dispersion modeling studies conducted, it was observed that the maximum ground level concentration occurs in the North & North east direction. The maximum incremental increase in concentration for PM and NOx is 0.944 µg/m3 and 0.352 µg/m3 respectively at a distance of about 1 km in the North direction. Whereas, the maximum incremental increase in concentration for HCL & Cl2 is 0.806µg/m3 & 0.235µg/m3 respectively and for HBr & Br is 0.177µg/m3 each at a distance of about 1 km in the North direction. 10.4.3 NOISE ENVIRONMENT Noise will be generated during the intermittent operation of machineries for site clearing and construction work and also during vehicular movement. There will be short term, localized and reversible impact on ambient noise levels during the construction activities. Other sources of noise pollution will be boilers, diesel generator and other noise generating units. Adequate noise control measures such as mufflers, silencers at the air inlet/outlet, anti-vibration pad for equipment with high vibration etc. is already provided. Housing/casing shall be provided for all noise generating machines. Job rotation will reduce exposure to some extent. More ever, PPE like earmuff and ear plugs is provided to the operators/worker exposed to high noise. The green belt is further helpful in reducing the ambient noise level.



10.4.4 LAND ENVIRONMENT It is existing unit and it is already located in GIDC, Vapi. Local workers will be engaged for construction activities, So the construction phase will not involve any temporary housing. The hazardous solid waste generated during construction activity will be stored and disposed properly. The unit has sanitation facility and sewage will be sent to STP for treatment. Hence, there will be no significant adverse impact on land environment due to handling of hazardous solids waste. The unit has closed hazardous waste storage area with impervious flooring. Transportation of hazardous waste to the TSDF site is governed as per the Hazardous Waste (Management, Handling and Trans boundary Movement) Rules. Separate collection system is provided for collection of spillage material. Impervious layer, RCC roads and flooring is provided to area, where the chemical storage and handling activities will be involved. Separate storm water collection system is provided to prevent contamination of soil through contaminated water. The unit is following Standard Operating Procedure (SOP) for storing and handling of hazardous wastes. 10.4.5 ECOLOGICAL ENVIRONMENT The project site is located within the GIDC .The project site is manufacturing unit. Since, the project is established on a non-agriculture land, it will not to alter the crop production of the area. The project site is at a far distance from sanctuaries and national parks. The patches of protected forest and reserved forest are found within study area but it is not affected by the project. The waste water generated from the process and domestic activity will be properly treated and reused in cooling tower. There will be no impact on fisheries and aquatic life as it is zero discharge unit. Hence, no adverse impact on this account is anticipated. 10.4.6 INFRA STRUCTURE AND SERVICES The plant is located in a GIDC, Vapi having all essential facilities such as water, power, post, and telecommunication. There is a well laid down broad roads already existing in GIDC, Vapi. At the full capacity of production, there will be 4-5 trucks per day for transportation of raw material and finished good products. This will have DGVCL is having large amount of electricity production thus due to extra consumption of electricity no adverse impact of electricity supply is predicted. Almost



negligible impact on road network. The project is zero liquid discharge units so; there will be no impact on underground drainage system. 10.4.7 SOCIO-ECONOMIC IMPACT This will be a beneficial impact on the local socio-economic environment as increase in demand for essential utilities and employment during both construction and operational phase. 10.5 ENVIRONMENT MONITORING PROGRAM D.G set are stand by facility. Their monitoring will be done by external monitoring agency whenever it will be in running condition. The unit will carry out quarterly monitoring of ambient air, process emission and fugitive emission. Noise monitoring will be done at the interval of six month. Waste water will be monitored daily. Hazardous waste will be monitored at every 2 years. 10.6 RISK ASSESSMENT AND DISASTER MANAGEMENT PLAN 10.6.1 RISK ASSESSMENT Fire, explosion, toxic release or combinations of them are the hazards associated with industrial plants using hazardous chemicals. The risk assessment study including identification of hazard, consequence analysis ,recommendation based on consequence analysis etc are covered in chapter-6. 10.6.2 DISASTER MANAGEMENT PLAN The unit has developed the emergency management system to tackle the emergency situation. The detail of disaster management system is discussed in the section 6.2. 10.6.3 OCCUPATIONAL HEALTH AND SAFETY MANAGEMENT SYSTEM Details of occupational health and safety are covered in section 6.3. It covers planning at construction & erection stage and operation & maintenance stage. Also, other details like hospital facilities, FMO, OHC, Ambulance van, First aid box, periodical medical examination, work place monitoring plan, safety plan, safety organization, safety circle and safety training.



10.7 PROJECT BENEFITS The company is committed for contribution of funds and provides the services for the upliftment of local community in the nearby villages. The detail of budgetary allocation for socio economic activity is covered in section 7.5. 10.8 ENVIRONMENTAL MANAGEMENT PLAN 10.8.1 ENVIRONMENT MANAGEMENT CELL M/s. Aarti Industries Ltd. (Alchemie Organics Division) has assigned responsibility to officers from various disciplines to co-ordinate the activities concerned with management and implementation of environmental control measures. The unit has planned to revise environment policy to fulfill corporate environment responsibility. 10.8.2 ENVIRONMENTAL MANAGEMENT PLAN A) ENVIRONMENT MANAGEMENT PLAN FOR CONSTRUCTION PHASE Since there will not be any construction activity, the EMP for operational phase has been prepared. B) ENVIRONMENT MANAGEMENT PLAN FOR OPERATIONAL PHASE AIR The sources of flue gas emission are two D.G. sets. (for emergency use only). The unit is getting steam from neighboring industry namely M/s. Aarti industries Ltd., plot no 801/23, Phase-III, GIDC Estate, Vapi. The unit has proposed one additional D.G. sets for proposed expansion. The source of existing process emission is one process stacks only, which is connected to water scrubber by alkali scrubber. Old incinerator stack is dismantled. There will be two additional stacks of process emissions which are attached to water scrubber followed by Alkali scrubber and one additional stack of process emission which is connected to water scrubber due to proposed expansion. The measures like routine & regular inspection to identify leakage, preventive maintenance and operational maintenance, provision of leak detection and repair system and potable instrument for measurement of VOC etc are already implemented



by the unit to control fugitive emissions. The same with additional equipments will be continued. Work area ambient air quality monitoring will be carried out as per Gujarat Factories Rules. Regular ambient air quality monitoring will be carried out within premises and nearby area for PM10, PM 2.5, SOX, NO2, HCl, Cl2, Br2 and HBr in the downwind directions as well as where maximum ground level concentration are anticipated and record of the same shall be maintained. WATER The unit will use 887 KL/Day water after proposed expansion. The unit will use 599 KL/Day of fresh water from GIDC water supply system and 288 KL/Day will be recycled water. Extra water required for the proposed expansion of project will be fulfilled by GIDC water supply system. Total waste water generation will be 302 KL/Day. This waste water includes waste water coming out from process (137 KL/Day), washing (30 KL/Day), DM plant regeneration (5 KL/Day), cooling tower blow down (70 KL/Day), and sewage (60 KL/Day). Concentrated & Toxic effluent stream of 11.7 KL/Day will be sent to common incinerator facility. 137 KL/Day of effluent from process and 30 KL/Day effluent from washing will be sent to unit’s own Effluent Treatment Plant comprising of primary, secondary & tertiary treatment facilities. Treated effluent from ETP will be sent to R.O. system-1. Cooling tower blow down of 70 KL/Day and 5 KL/Day DM plant will be subjected to R.O. system-2. This unit has proposed for zero liquid discharge for industrial effluent. To achieve zero liquid discharge, R.O. reject of 50 KL/Day from R.O. system-1 and R.O. reject of 22 KL/Day from R.O. system-2 will be subjected to MEE. R.O.permeate of 117 KL/Day from R.O. system-1, R.O.permeate of 53 KL/Day from R.O. system-2 and MEE condensate of 68 KL/Day will be reused. Residue from MEE of 4 KL/Day will be sent to landfill site. Sewage of 60 KL/Day will be treated in Sewage treatment plan and treated water will be used for gardening purpose and in cooling tower.



NOISE Audio metric test should be conducted periodically for employees working close to the high noise sources. D.G. set will be sound proof and located in an enclosure. Adequate noise control measures such as mufflers, silencers at the air inlet/outlet, anti-vibration pad for equipment with high vibration, earmuff and ear plugs to the operators, etc. shall be provided. Rotation of work will minimize exposure. LAND Raw materials will be stored in M.S tanks, S.S tank and HDPE Carboys, HDPE bags,etc in sepereate storage room. All the raw effluent storage tanks will be covered with RCC slab. Separate collection system is provided for collection of spillage material. Impervious layer, RCC roads and flooring is provided to area, where the chemical storage and handling activities is involved. The acid tanks are provided with dyke wall to control spread of leakages. The hazardous wastes generated from the industry are ETP waste from ETP, distillation residue, spent solvents, spent catalyst, spent filter cloth, date expired pesticides, spent carbon, gypsum from process, discarded containers/ bags /liners from raw material handling and used oil from maintenance of engineering unit. Which will be properly stored in a hazardous waste storage area and then transported and properly disposed. The unit will take same precautions for the hazardous wastes which will be generated after proposed expansion. It has been planned to use high calorific waste like solvent residue, spent carbon, off specification products etc to send for co-incineration at cement industries. GREEN BELT The company has existing green belt area of 2346 sq. m. There are 700 trees in existing green belt area. ENERGY CONSERVATION PROGRAMME Presently, the unit do not have boiler for steam generation. The unit is using steam from neighboring industry namely M/s. Aarti Industries Ltd., located at plot no 801/23 ,phase-III,GIDC Estate, Vapi. After proposed expansion also, the unit will use steam from sister concern.



BUDGETARY PROVISION PROPOSED FOR ENVIRONMENT POLLUTION CONTROL MEASURES The unit has proposed 920 lacs as capital cost and 731 lacs as recurring cost for environment pollution control measures. HEALTH & SAFETY There will be provision of PPE, antidotes, periodic inspection & testing of pressure vessels, equipment, machineries, pre-employment medical checkup, periodic health checkup, training of firefighting, work permits system, first aid, safe handling of hazardous chemicals and integrating safety. Hazardous processes will be operated by trained workers and will be looked after by qualified & experienced supervisors. CONCLUSION It can be concluded on positive note that after implementation of proper mitigation measures and environment management plan this project will have insignificant impact on environment and economic.



Chapter – 11 DISCLOSURE OF CONSULTANT ENGAGED M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT LTD., established in 1990 by woman entrepreneur Mrs. Hina C. Upasani, is well-equipped analytical laboratory for chemical analysis. It offers following services to various types of industries in general, and Chemical / Pharmaceutical, CETPS, solid waste sites and dyes and dyes intermediate in particular. 11.1 SALIENT FEATURES Spread over 600 m2 plot with about 350 m2 built up area. 1000sq.feet office space purchased at Vadodara for carrying out Climate Change work. Well-equipped laboratory with instrument room, conference room, wet Analysis lab room, microbiology laboratory, Air Analysis Laboratory, Library & computer room etc. Experienced and qualified staff. Approved Testing House by Industries Commissioner, Gujarat Government. Recognized as Environment Auditor by Gujarat Pollution Control Board, Gandhinagar. ISO 9001-2000 Certified by American Quality Assessor, AQA. Since 2002. NABL accreditation for water and Air parameters. Trained for Cleaner Production Assessment by Department of Environment and Forest, Government of Gujarat under World Bank capacity building programme. Computerized testing facility. Consultant to Gujarat Cleaner Production Centre, Gandhinagar for Cleaner



Product Assessment. Service provider to UNIDO, Vienna, Austria for Clean Technology Assessment. Consultancy for EIA reports. 11.2 SERVICES PROVIDED BY THE CENTRE

Analysis of chemicals, dyes and dye intermediates Analysis of bulk drugs and intermediates Analysis of water and waste water Testing of environment samples – water, air, solid waste and soil Trace analysis of chemicals in waste water Environment auditing Cleaner Production Assessment Microbiological analysis of water Clean Technology Assessment Environment Technological Assessment (EnTA) Environment Impact Assessment Climate Change Consultancy Environment consultancy Environment clearance consultancy



11.3 OUTSTANDING ACHIVEMENTS 1) Received Gujarat Cleaner Production Award for CP work at M/s. The Ankleshwar Poly Dyestuff Pvt. Ltd. on 5th June, 2006 from Chief Minister Mr. Narendra Modi. 2) Received contract from UNIDO, Vienna, for writing PDD and developing new methodology for sulphuric acid project. 3) Established demonstration unit FIRST TIME in INDIA of Plasma based hazardous waste destruction facility in collaboration with M/s. PEAT International, USA. Got approval from Central Pollution Control Board, New Delhi. 4) Engaged in creating cluster base recycling unit of spent sulphuric acid to pure sulphuric acid. 5) UNIDO, VIENNA has also assigned work to find out alternative Air oxidation technology in place of nitric acid oxidation technology to reduce Green House gas emission. 6) Clean Technology tie up with following companies: (i) for recovery of sulphuric acid from spent sulphuric acid – M/S Aker Kvaerner Chemetics, Canada. (ii) Destruction of hazardous waste using Plasma Technology, PEAT International, USA (iii) Catalytic Air Oxidation in place of Nitric acid oxidation, M/S Buss Chem Tech AG, Switzerland (iv) CDM consultancy , BSS, Switzerland 7) Received contract from UNIDO, Vienna, for writing PDD and developing new methodology for Air Oxidation Technology. 12) The organisation wrote two methodologies and Project Development Document (PDD) and submitted to UNFCCC. The working committee of UNFCCC approved the methodologies. They are for recovery of sulphuric acid from spent sulphuric acid and substitution of incineration with Plasma Technology. 11.4 STATUS OF NABET ACCREDITATION The organisation has obtained stay order from the Honourable High Court of Gujarat.The copy of the stay order is attached as Annexure-XXIV. It is furthur declared that at the time of submission of EIA report, the stay order is valid.



11.5 DECLARATION BY CONSULTANT: An undertaking regarding the prescribed TOR have been complied with and data submitted in this EIA is factually correct is attached as Annexure XXV. This is as per office memorandum of MoEF and CC dated 04/08/2009.

Documents

M/S. AARTI INDUSTRIES LTD. - environmentclearance.nic.in · environmental impact assessment report of m/s. aarti industries ltd. (al chemie organics division) for manufacturing of