-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 1 of 8
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
Sodium hypochlorite 0,1 - 0,6%
1.1. Product identifier
This MSDS covers the following products in all container
sizes:
- REF 15029.xxxxx – Natriumhypochlorit 0,1 %
- REF 15084.xxxxx – Natriumhypochlorit 0,37 %
- REF 12871.xxxxx – Natriumhypochlorit 0,5 %
- REF 13545.xxxxx – Natriumhypochlorit 0,6 %
Further trade names
1.2. Relevant identified uses of the substance or mixture and
uses advised against
Use of the substance/mixture
Use as laboratory reagent. Intended for scientific research and
development.
Any non-intended use.
Uses advised against
1.3. Details of the supplier of the safety data sheet
MORPHISTO GmbHCompany name:
Street: Weismüllerstr. 45
Place: D-60314 Frankfurt am Main
Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400
3019-64
[email protected]:
http://www.morphisto.deInternet:
Poison Information Center Mainz, Germany, Tel:
+49(0)6131/192401.4. Emergency telephone
number:
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
UN-GHS (ST/SG/AC.10/11/Rev.7)
Hazard categories:
Hazardous to the aquatic environment: Aquatic Chronic 3
Hazardous to the aquatic environment: Aquatic Acute 2
Hazard Statements:
Harmful to aquatic life with long lasting effects.
Toxic to aquatic life.
2.2. Label elements
UN-GHS (ST/SG/AC.10/11/Rev.7)
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Hazard statements
P103 Read label before use.
P273 Avoid release to the environment.
P501 Dispose of contents/container to ....
Precautionary statements
SECTION 11: Toxicological information SECTION 12: Ecological
information
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Print date: 03.08.2020GB - ENRevision No: 1,00
mailto:[email protected]://http://www.morphisto.de
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 2 of 8
Hazardous components
QuantityChemical nameCAS No
EC No Index No REACH No
GHS Classification
< 1 %7681-52-9 sodium hypochlorite, solution 0,9 % Cl
active
231-668-3 017-011-00-1
Skin Corr. 1B, Eye Dam. 1, Aquatic Acute 1 (M-Factor = 10),
Aquatic Chronic 1 (M-Factor = 1);
H314 H318 H400 H410 EUH031
< 1 %1310-73-2 sodium hydroxide; caustic soda
215-185-5 011-002-00-6
Skin Corr. 1A; H314
Further Information
Full text of R- and H-phrases: see section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
First aider: Pay attention to self-protection! IF INHALED: If
breathing is difficult, remove victim to fresh air and
keep at rest in a position comfortable for breathing. Take off
immediately all contaminated clothing. If
unconscious place in recovery position and seek medical
advice.
General information
If breathing is irregular or stopped, administer artificial
respiration. No mouth-to-mouth or mouth-to-nose
resuscitation. Use Ambu bag or ventilator. Provide fresh air.
When in doubt or if symptoms are observed, get
medical advice.
After inhalation
Take off contaminated clothing and wash it before reuse. Wash
with plenty of water.
After contact with skin
Rinse immediately carefully and thoroughly with eye-bath or
water. Call a physician immediately.
After contact with eyes
If accidentally swallowed rinse the mouth with plenty of water
(only if the person is conscious) and obtain
immediate medical attention. Rinse mouth immediately and drink
plenty of water. Do NOT induce vomiting. Call
a physician immediately.
After ingestion
4.2. Most important symptoms and effects, both acute and
delayed
SECTION 11: Toxicological information
4.3. Indication of any immediate medical attention and special
treatment needed
Treat symptomatically. No specific antidote known.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Co-ordinate fire-fighting measures to the fire surroundings.
Suitable: Carbon dioxide (CO2), alcohol-resistant
foam, dry extinguishing agent, water spray.Adjust extinguishing
measures to the environment.
Suitable extinguishing media
Unsuitable: Do not use water in full jet.
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture
Non-flammable. Can be released in case of fire: Chlorine (Cl2).
Hydrogen chloride (HCl).
Print date: 03.08.2020GB - ENRevision No: 1,00
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 3 of 8
In case of fire: Wear self-contained breathing apparatus.
Protective clothing.
5.3. Advice for firefighters
Collect contaminated fire extinguishing water separately. Do not
allow entering drains or surface water.
Dispose of waste according to applicable legislation.
Additional information
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency
procedures
Use personal protection equipment. Provide adequate ventilation.
Avoid all contact with the substance. Avoid:
generation/formation of aerosols
Do not allow to enter into surface water or drains.6.2.
Environmental precautions
Absorb with liquid-binding material (e.g. sand, diatomaceous
earth, acid- or universal binding agents). Treat the
recovered material as prescribed in the section on waste
disposal.
6.3. Methods and material for containment and cleaning up
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
The usual precautions for handling chemicals should be
considered. Avoid contact with skin, eyes and clothes.
Take off contaminated clothing and wash it before reuse. When
using do not eat, drink, smoke, sniff. Wash
hands before breaks and after work.
Advice on safe handling
No special fire protection measures are necessary.
Advice on protection against fire and explosion
Decomposes when heated, releasing oxygen, dichloroxide, chlorine
or hydrogen chloride.
Further information on handling
7.2. Conditions for safe storage, including any
incompatibilities
Keep container tightly closed. Due to gaseous decomposition
products, overpressure can occur in tightly
sealed containers. No metal containers. Keep only in the
original container at temperature not exceeding 15
°C.
Requirements for storage rooms and vessels
Do not store together with acids.
Hints on joint storage
7.3. Specific end use(s)
Use as laboratory reagent.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits (EH40)
Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin
STEL (15 min)0.5Chlorine7782-50-5 1.5 WEL
STEL (15 min)-Sodium hydroxide1310-73-2 2 WEL
Print date: 03.08.2020GB - ENRevision No: 1,00
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 4 of 8
8.2. Exposure controls
Provide adequate ventilation as well as local exhaustion at
critical locations. Provide washing facilities at the
workplace, provide an eye shower or eyewash bottle and mark
them.
Appropriate engineering controls
Take off contaminated clothing. Wash hands before breaks and
after work. When using do not eat, drink,
smoke, sniff. General protection and hygiene measures - see
section 7.1
Protective and hygiene measures
Wear eye protection/face protection.Safety glasses according to
EN 166.
Eye/face protection
When handling with chemical substances, protective gloves must
be worn with the CE-label including the four
control digits. The quality of the protective gloves resistant
to chemicals must be chosen as a function of the
specific working place concentration and quantity of hazardous
substances. For special purposes, it is
recommended to check the resistance to chemicals of the
protective gloves mentioned above together with the
supplier of these gloves. Protective gloves according to EN
374.Suitable glove material also for longer, direct
contact: PVC (Polyvinyl chloride). NBR (Nitrile rubber). CR
(polychloroprenes, Chloroprene rubber). Butyl
rubber. fluoroelastomer (FKM).Breakthrough time (maximum wearing
time): >480 min.
Hand protection
Use of protective clothing.Lab apron. Personal protective
equipment must be determined according to the
quantity and concentration of hazardous substances at the
workplace. Wear solvent-resistant protective
clothing. Safety shoes according to EN 345-347.
Skin protection
In case of inadequate ventilation wear respiratory
protection.
Respiratory protection
No special measures are necessary.
Environmental exposure controls
colourless slightly yellowish
LiquidPhysical state:
Colour:
9.1. Information on basic physical and chemical properties
SECTION 9: Physical and chemical properties
weak nach Chlorine (Cl2).Odour:
pH-Value (at 20 °C): 11-11,4
Changes in the physical state
not determinedMelting point:
not determinedInitial boiling point and boiling range:
not determinedFlash point:
Flammability
not applicableSolid:
not applicableGas:
The product is not: Explosive.
Explosive properties
not determinedLower explosion limits:
not determinedUpper explosion limits:
Auto-ignition temperature
not applicableSolid:
not applicableGas:
not determinedDecomposition temperature:
Print date: 03.08.2020GB - ENRevision No: 1,00
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 5 of 8
Not oxidising.
Oxidizing properties
Vapour pressure: not determined
Density: not determined
Water solubility: easily soluble
Solubility in other solvents
not determined
not determinedPartition coefficient:
Vapour density: not determined
Evaporation rate: not determined
9.2. Other information
not determinedSolid content:
SECTION 10: Stability and reactivity
10.1. Reactivity
Reaction with: Acid. No hazardous reaction when handled and
stored according to provisions.Decomposes
when heated, releasing oxygen, dichloroxide, chlorine or
hydrogen chloride.
10.2. Chemical stability
The product is stable under storage at normal ambient
temperatures.
10.3. Possibility of hazardous reactions
Exothermic reaction with: Acids Oxidizing agents.
UV-radiation/sunlight.
10.4. Conditions to avoid
Do not mix with: Acids. Information is given in subsection
10.3.
10.5. Incompatible materials
Resulting from the use of the product: Chlorine. Contact with
acids liberates toxic gas. Decomposes when
heated, releasing oxygen, dichloroxide, chlorine or hydrogen
chloride.
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not
met.
Chemical nameCAS No
SourceSpeciesDoseExposure route Method
7681-52-9 sodium hypochlorite, solution 0,9 % Cl active
RatLD50 1100
mg/kgECHA dossieroral
RatLD50 20000
mg/kgECHA dossierdermal
inhalation (1 h) vapour LC50 10,5 mg/l Rat ECHA dossier
Based on available data, the classification criteria are not
met.
Irritation and corrosivity
Sensitising effects
Based on available data, the classification criteria are not
met.
Print date: 03.08.2020GB - ENRevision No: 1,00
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 6 of 8
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not
met.
STOT-single exposure
Based on available data, the classification criteria are not
met.
Based on available data, the classification criteria are not
met.
STOT-repeated exposure
Aspiration hazard
Based on available data, the classification criteria are not
met.
Practical experience
Observations relevant to classification
In case of inhalation May cause respiratory irritation. In case
of ingestion May cause irritation. Following skin
contact Maybe irritating to skin. After eye contact May cause
irritation.
SECTION 12: Ecological information
12.1. Toxicity
Harmful to aquatic life with long lasting effects. Acutely very
toxic to microorganisms. When discharged into
biological sewage treatment plants, depending on local
conditions and existing concentrations, disturbances of
the degradation activity of activated sludge are possible.
CAS No Chemical name
[h] | [d]Aquatic toxicity Dose SourceSpecies Method
sodium hypochlorite, solution 0,9 % Cl active7681-52-9
Acute fish toxicity 96 h GestisLC50 0,032 -
10 mg/l
Acute algae toxicity 72 h GestisErC50 46 mg/l
Acute crustacea toxicity 48 h GestisEC50 0,032 -
56,4 mg/l
12.2. Persistence and degradability
Inorganic product, cannot be eliminated from the water by
biological cleaning processes.The product can be
degraded by abiotic, e.g. chemical or photolytic processes.
Information on stability in water (hydrolysis):
Half-life time: 12hIn water, light-induced degradation occurs in
the near-surface layer.
12.3. Bioaccumulative potential
Bioaccumulation is not expected.
The product has not been tested.
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
not applicable
Adsorbable organic bound halogen (AOX):The mixture does not
contain any organically bound halogen, but
can have a halogenating effect and thuscontribute to AOX.
12.6. Other adverse effects
Do not allow to enter into surface water or drains. Do not allow
to enter into soil/subsoil. Toxic to aquatic life.
Further information
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal recommendations
Do not allow to enter into surface water or drains. Do not allow
to enter into soil/subsoil. Dispose of waste
according to applicable legislation.
Print date: 03.08.2020GB - ENRevision No: 1,00
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 7 of 8
Non-contaminated packages may be recycled. Handle contaminated
packages in the same way as the
substance itself.
Contaminated packaging
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number: No dangerous good in sense of this transport
regulation.
No dangerous good in sense of this transport regulation.14.2. UN
proper shipping name:
No dangerous good in sense of this transport regulation.14.3.
Transport hazard class(es):
14.4. Packing group: No dangerous good in sense of this
transport regulation.
Inland waterways transport (ADN)
14.1. UN number: No dangerous good in sense of this transport
regulation.
14.2. UN proper shipping name: No dangerous good in sense of
this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of
this transport regulation.
14.4. Packing group: No dangerous good in sense of this
transport regulation.
Marine transport (IMDG)
14.1. UN number: No dangerous good in sense of this transport
regulation.
No dangerous good in sense of this transport regulation.14.2. UN
proper shipping name:
14.3. Transport hazard class(es): No dangerous good in sense of
this transport regulation.
14.4. Packing group: No dangerous good in sense of this
transport regulation.
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: No dangerous good in sense of this transport
regulation.
No dangerous good in sense of this transport regulation.14.2. UN
proper shipping name:
No dangerous good in sense of this transport regulation.14.3.
Transport hazard class(es):
No dangerous good in sense of this transport regulation.14.4.
Packing group:
14.5. Environmental hazards
noENVIRONMENTALLY HAZARDOUS:
14.6. Special precautions for user
No dangerous good in sense of this transport regulation.
14.7. Transport in bulk according to Annex II of Marpol and the
IBC Code
No dangerous good in sense of this transport regulation.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation
specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 3: sodium hypochlorite, solution 0,9 % Cl active
Information according to 2012/18/EU
(SEVESO III):Not subject to 2012/18/EU (SEVESO III)
National regulatory information
Observe restrictions to employment for juveniles according to
the 'juvenile
work protection guideline' (94/33/EC).
Employment restrictions:
2 - obviously hazardous to waterWater hazard class (D):
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were
not carried out.
Print date: 03.08.2020GB - ENRevision No: 1,00
-
according to UN-GHS (ST/SG/AC.10/11/Rev.7)
Safety Data SheetMORPHISTO GmbH
Sodium hypochlorite 0,1 - 0,6%
Revision date: Product code: 15029_collect Page 8 of 8
SECTION 16: Other information
Changes
Rev. 1,00. 06.04.2020 -Initial release
Abbreviations and acronyms
CLP: Classification, labelling and Packaging
REACH: Registration, Evaluation and Authorization of
Chemicals
GHS: Globally Harmonised System of Classification, Labelling and
Packaging of Chemicals
UN: United Nations
CAS: Chemical Abstracts Service
DNEL: Derived No Effect Level
DMEL: Derived Minimal Effect Level
PNEC: Predicted No Effect Concentration
ATE: Acute toxicity estimate
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%
LL50: Lethal loading, 50%
EL50: Effect loading, 50%
EC50: Effective Concentration 50%
ErC50: Effective Concentration 50%, growth rate
NOEC: No Observed Effect Concentration
BCF: Bio-concentration factor
PBT: persistent, bioaccumulative, toxic
vPvB: very persistent, very bioaccumulative
ADR: Accord européen sur le transport des marchandises
dangereuses par Route
(European Agreement concerning the International Carriage of
Dangerous Goods by Road )
RID: Regulations concerning the international carriage of
dangerous goods by rail
ADN: European Agreement concerning the International Carriage of
Dangerous Goods by Inland Waterways
(Accord européen relatif au transport international des
marchandises dangereuses par voies de navigation
intérieures)
IMDG: International Maritime Code for Dangerous Goods
EmS: Emergency Schedules
MFAG: Medical First Aid Guide
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
MARPOL: International Convention for the Prevention of Marine
Pollution from Ships
IBC: Intermediate Bulk Container
SVHC: Substance of Very High Concern
For abbreviations and acronyms, see table at
http://abbrev.esdscom.eu
The information is based on the present level of our knowledge.
It does not, however, give assurance of
product properties and establishes no contract legal rights. The
receiver of our product is singularly responsible
for adhering to existing laws and regulations.
Further Information
(The data for the hazardous ingredients were taken respectively
from the last version of the sub-contractor's safety
data sheet.)
Print date: 03.08.2020GB - ENRevision No: 1,00
4.4.0 EuPhraC Qualisys 3.1 2020-08-03 PHRASEN eposNT intern
2020-08-03 STOFFNAME eposNT intern 2020-08-03 QMOVE Qualisys 2020/2
2020-08-03 en GB GB epos Gefahrstoff-Manager® 2020-08-03
15029_collect_GB-en.pdf 2020-08-03 DE181898469 MSDS_TRANS_ENV_SUB
undefined 2020-04-06 1,00 2020-08-03 eposNT intern 15029_collect
Sodium hypochlorite 0,1 - 0,6% This MSDS covers the following
products in all container sizes: - REF 15029.xxxxx –
Natriumhypochlorit 0,1 % - REF 15084.xxxxx – Natriumhypochlorit
0,37 % - REF 12871.xxxxx – Natriumhypochlorit 0,5 % - REF
13545.xxxxx – Natriumhypochlorit 0,6 % Any non-intended use. false
false false Use as laboratory reagent. Intended for scientific
research and development. Manufacturer Manufacturer DE MORPHISTO
GmbH Weismüllerstr. 45 60314 Frankfurt am Main Weismüllerstr. 45
60314 Frankfurt am Main +49 (0) 69 / 400 3019-60 +49 (0) 69 / 400
3019-64 [email protected] http://www.morphisto.de Poison
Information Center Mainz, Germany, Tel: +49(0)6131/19240
15029_collect Aquatic Chronic 3 412 Harmful to aquatic life with
long lasting effects. Calculation method. 412 Harmful to aquatic
life with long lasting effects. 103 Read label before use. 273
Avoid release to the environment. 501 Return contents/container to
the point of sale or to a special waste collection point. 031
Contact with acids liberates toxic gas. 206 Warning! Do not use
together with other products. Mayrelease dangerous gases
(chlorine). SECTION 11: Toxicological information SECTION 12:
Ecological information Mixture water 7732-18-5 231-791-2 H2O
inorganic 18.0148 g/mol le 100 95 % true true false false false
false false liquid 7 100 °C 1 g/cm³ Water 18.0148 g/mol sodium
hypochlorite, solution 0,9 % Cl active 7681-52-9 017-011-00-1
231-668-3 Cl1-Na1-O1 inorganic 74.44 g/mol Skin Corr. 1B 314 Causes
severe skin burns and eye damage. Eye Dam. 1 318 Causes serious eye
damage. Aquatic Acute 1 400 Very toxic to aquatic life. 10 Aquatic
Chronic 1 410 Very toxic to aquatic life with long lasting effects.
1 lt 1 % true true true false false true true Entry 3 WEL 0.5 ml/m³
1.5 mg/m³ liquid 9,7 (0,5 %) 23 hPa 20 °C 1.25 1.2 g/cm³ Water
74.44 g/mol LD50 Oral 1100 mg/kg Rat ECHA dossier LD50 Dermal 20000
mg/kg Rat ECHA dossier LC50 Inhalation(Vapour) 1 h 10.5 mg/l Rat
ECHA dossier 10 0.032 mg/l LC50 96 h Gestis 56.4 0.032 mg/l EC50 48
h Gestis 46 mg/l ERC50 72 h Gestis true true true sodium hydroxide;
caustic soda 1310-73-2 011-002-00-6 215-185-5 H1-Na1-O1 inorganic
40 g/mol Skin Corr. 1A 314 Causes severe skin burns and eye damage.
lt 1 % true true true false false false false WEL 2 mg/m³ solid ca.
14 (50 g/l) 1388 °C 2.13 g/cm³ Water 40 g/mol true true true Full
text of R- and H-phrases: see section 16. First aider: Pay
attention to self-protection! IF INHALED: If breathing is
difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Take off immediately all
contaminated clothing. If unconscious place in recovery position
and seek medical advice. If breathing is irregular or stopped,
administer artificial respiration. No mouth-to-mouth or
mouth-to-nose resuscitation. Use Ambu bag or ventilator. Provide
fresh air. When in doubt or if symptoms are observed, get medical
advice. Take off contaminated clothing and wash it before reuse.
Wash with plenty of water. Rinse immediately carefully and
thoroughly with eye-bath or water. Call a physician immediately. If
accidentally swallowed rinse the mouth with plenty of water (only
if the person is conscious) and obtain immediate medical attention.
Rinse mouth immediately and drink plenty of water. Do NOT induce
vomiting. Call a physician immediately. SECTION 11: Toxicological
information Treat symptomatically. No specific antidote known.
Co-ordinate fire-fighting measures to the fire surroundings.
Suitable: Carbon dioxide (CO2), alcohol-resistant foam, dry
extinguishing agent, water spray.Adjust extinguishing measures to
the environment. Unsuitable: Do not use water in full jet.
Non-flammable. Can be released in case of fire: Chlorine (Cl2).
Hydrogen chloride (HCl). In case of fire: Wear self-contained
breathing apparatus. Protective clothing. Collect contaminated fire
extinguishing water separately. Do not allow entering drains or
surface water. Dispose of waste according to applicable
legislation. Use personal protection equipment. Provide adequate
ventilation. Avoid all contact with the substance. Avoid:
generation/formation of aerosols Do not allow to enter into surface
water or drains. Absorb with liquid-binding material (e.g. sand,
diatomaceous earth, acid- or universal binding agents). Treat the
recovered material as prescribed in the section on waste disposal.
Safe handling: see section 7 Personal protection equipment: see
section 8 Disposal: see section 13 The usual precautions for
handling chemicals should be considered. Avoid contact with skin,
eyes and clothes. Take off contaminated clothing and wash it before
reuse. When using do not eat, drink, smoke, sniff. Wash hands
before breaks and after work. No special fire protection measures
are necessary. Decomposes when heated, releasing oxygen,
dichloroxide, chlorine or hydrogen chloride. Keep container tightly
closed. Due to gaseous decomposition products, overpressure can
occur in tightly sealed containers. No metal containers. Keep only
in the original container at temperature not exceeding .? °C. 15 .?
Do not store together with acids. Use as laboratory reagent.
Provide adequate ventilation as well as local exhaustion at
critical locations. Provide washing facilities at the workplace,
provide an eye shower or eyewash bottle and mark them. In case of
inadequate ventilation wear respiratory protection. Wear eye
protection/face protection. Safety glasses according to EN 166.
When handling with chemical substances, protective gloves must be
worn with the CE-label including the four control digits. The
quality of the protective gloves resistant to chemicals must be
chosen as a function of the specific working place concentration
and quantity of hazardous substances. For special purposes, it is
recommended to check the resistance to chemicals of the protective
gloves mentioned above together with the supplier of these gloves.
Protective gloves according to EN 374. Suitable glove material also
for longer, direct contact: PVC (Polyvinyl chloride). NBR (Nitrile
rubber). CR (polychloroprenes, Chloroprene rubber). Butyl rubber.
fluoroelastomer (FKM). Breakthrough time (maximum wearing time):
>480 min. Use of protective clothing . Lab apron. Personal
protective equipment must be determined according to the quantity
and concentration of hazardous substances at the workplace. Wear
solvent-resistant protective clothing. Safety shoes according to EN
345-347. Take off contaminated clothing. Wash hands before breaks
and after work. When using do not eat, drink, smoke, sniff. General
protection and hygiene measures - see section 7.1 No special
measures are necessary. other Liquid liquid colourless slightly
yellowish weak nach Chlorine (Cl2). 11.4 11 20 °C not determined
not determined not determined not determined not determined not
determined not determined not determined not determined not
determined not applicable not applicable not determined The product
is not: Explosive . Not oxidising. not determined not determined
Reaction with: Acid . No hazardous reaction when handled and stored
according to provisions. Decomposes when heated, releasing oxygen,
dichloroxide, chlorine or hydrogen chloride. The product is stable
under storage at normal ambient temperatures. Exothermic reaction
with: Acids Oxidizing agents. UV-radiation/sunlight. Do not mix
with: Acids . Information is given in subsection 10.3. Resulting
from the use of the product: Chlorine . Contact with acids
liberates toxic gas. Decomposes when heated, releasing oxygen,
dichloroxide, chlorine or hydrogen chloride. In case of inhalation
May cause respiratory irritation. In case of ingestion May cause
irritation. Following skin contact Maybe irritating to skin. After
eye contact May cause irritation. Based on available data, the
classification criteria are not met. Based on available data, the
classification criteria are not met. Based on available data, the
classification criteria are not met. Based on available data, the
classification criteria are not met. Based on available data, the
classification criteria are not met. Based on available data, the
classification criteria are not met. Based on available data, the
classification criteria are not met. Harmful to aquatic life with
long lasting effects. Acutely very toxic to microorganisms. When
discharged into biological sewage treatment plants, depending on
local conditions and existing concentrations, disturbances of the
degradation activity of activated sludge are possible. Inorganic
product, cannot be eliminated from the water by biological cleaning
processes.The product can be degraded by abiotic, e.g. chemical or
photolytic processes. Information on stability in water
(hydrolysis): Half-life time: 12h In water, light-induced
degradation occurs in the near-surface layer. Bioaccumulation is
not expected. The product has not been tested. not applicable
Adsorbable organic bound halogen (AOX):The mixture does not contain
any organically bound halogen, but can have a halogenating effect
and thuscontribute to AOX. Do not allow to enter into surface water
or drains. Do not allow to enter into soil/subsoil. Toxic to
aquatic life. Do not allow to enter into surface water or drains.
Do not allow to enter into soil/subsoil. Dispose of waste according
to applicable legislation. Non-contaminated packages may be
recycled. Handle contaminated packages in the same way as the
substance itself. 0000 0000 0000 0000 No dangerous good in sense of
this transport regulation. No dangerous good in sense of this
transport regulation. No dangerous good in sense of this transport
regulation. No dangerous good in sense of this transport
regulation. No dangerous good in sense of this transport
regulation. No dangerous good in sense of this transport
regulation. No dangerous good in sense of this transport
regulation. No dangerous good in sense of this transport
regulation. Entry 3: sodium hypochlorite, solution 0,9 % Cl active
Observe restrictions to employment for juveniles according to the
'juvenile work protection guideline' (94/33/EC). false Chemical
safety assessments for substances in this mixture were not carried
out. 314 Causes severe skin burns and eye damage. 318 Causes
serious eye damage. 400 Very toxic to aquatic life. 410 Very toxic
to aquatic life with long lasting effects. 412 Harmful to aquatic
life with long lasting effects. The information is based on the
present level of our knowledge. It does not, however, give
assurance of product properties and establishes no contract legal
rights. The receiver of our product is singularly responsible for
adhering to existing laws and regulations. CLP: Classification,
labelling and Packaging REACH: Registration, Evaluation and
Authorization of Chemicals GHS: Globally Harmonised System of
Classification, Labelling and Packaging of Chemicals UN: United
Nations CAS: Chemical Abstracts Service DNEL: Derived No Effect
Level DMEL: Derived Minimal Effect Level PNEC: Predicted No Effect
Concentration ATE: Acute toxicity estimate LC50: Lethal
concentration, 50% LD50: Lethal dose, 50% LL50: Lethal loading, 50%
EL50: Effect loading, 50% EC50: Effective Concentration 50% ErC50:
Effective Concentration 50%, growth rate NOEC: No Observed Effect
Concentration BCF: Bio-concentration factor PBT: persistent,
bioaccumulative, toxic vPvB: very persistent, very bioaccumulative
ADR: Accord européen sur le transport des marchandises dangereuses
par Route (European Agreement concerning the International Carriage
of Dangerous Goods by Road) RID: Regulations concerning the
international carriage of dangerous goods by rail ADN: European
Agreement concerning the International Carriage of Dangerous Goods
by Inland Waterways (Accord européen relatif au transport
international des marchandises dangereuses par voies de navigation
intérieures) IMDG: International Maritime Code for Dangerous Goods
EmS: Emergency Schedules MFAG: Medical First Aid Guide IATA:
International Air Transport Association ICAO: International Civil
Aviation Organization MARPOL: International Convention for the
Prevention of Marine Pollution from Ships IBC: Intermediate Bulk
Container SVHC: Substance of Very High Concern For abbreviations
and acronyms, see table at http://abbrev.esdscom.eu 1,00 Rev. 1,00.
06.04.2020 -Initial release
