CanonieEnvironmenta SDMS DocID 531673

Canonie Environmental Services Corp. 800 Canonie Drive

December 2, 1988 Porter, Indiana 46304

Phone 219-926-8651

87-072

Mr. Michael Jasinski Remedial Project Manager U.S. Environmental Protection Agency S«perfund Records Center , Waste Management Division SITE

Mail Code HSP-CAN2 = U^s^Chi^sd 90 Canal Street

BREAK: ^ Z t f ~Boston, MA 02203-2211

OTHER: ZZZJJjJjT^Z Ms. Cynthia Kuhns Project Coordinator Maine Department of Environmental Protection State House, Station 17 Augusta, ME 04333

Monthly Status Report No. 12 Union Chemical Site South Hope, Maine

Dear Mr. Jasinski and Ms. Kuhns:

Canonie Environmental Services Corp. (Canonie), on behalf of the Poten­t i a l l y Responsible Parties (PRPs) to the Union Chemical Site, submits this monthly,status report in compliance with the directive of Paragraph 45 of the Administrative Order by Consent.

Review of November 1988 Work

Remedial investigation activities, consistent with the In i t i a l Site Charac­terization Work Plan, continued during the month of November 1988. Investigation activities completed during November 1988, may be summarized as follows:

1. The Ini t i a l Site Characterization Report was submitted to the United States Environmental Protection Agency (U.S. EPA) and the Maine Department of Environmental Protection (MDEP) on November 18, 1988.

2. The draft Baseline Risk Assessment and draft I n i t i a l Screening of Remedial Alternatives report were submitted to U.S. EPA and MDEP on November 21, 1988.

3. Preparation of the Phase IB Work Plan and the Interim Remedial Measure Feasibility Study Report for the Union Chemical Site continued.

Mr. Michael Jasinski, et a l . 2 December 2, 1988

Anticipated Work During December 1988

Canonie anticipates that during the month of December 1988, the following tasks will be completed:

1. The preparation of the work plans for the Phase IB Remedial Investigation and Post-Screening Field Investigation will be completed, and after review by the PRPs will be delivered to the agencies.

2. The preparation of the Interim Remedial Measure Feasibility Study Report will be completed and may be submitted to the agencies after review by the PRPs.

3. Receipt of comments from agency staff on submitted reports and preparation of responses or revised drafts.

Canonie will continue to inform the U.S. EPA and the MDEP of site activities and sampling and analyses that are conducted or proposed, as well as any problems which may arise. Copies of the remaining quality assurance/quality control analytical results for sampling conducted at the site in September 1988 are enclosed. Also enclosed is a copy of the final report for dioxin/furan analysis conducted by Radian Corporation.

Canonie believes that this report correctly relates the current status of the Union Chemical Site RI/FS. If you have any questions or comments, please do not hesitate to call.

Respectfully submitted,

W. David Harding'; P.E. Project Engineer

WDH/pr

Enclosures

cc: James Green, Northeast Solvents, Inc. Terry Hughes, Mearl Corp. Randy Smith, Nashua Corp. Douglas Anderson, Canonie Environmental Services Corp. Steven Gerken, Canonie Environmental Services Corp. John Grocki, Canonie Environmental Services Corp.

(ScSim®M®Environmental

CANONIE ENVIRONMENTAL SERVICES CORP. LABORATORY QUALITY ASSURANCE/QUALITY CONTROL DATA PACKAGES

LP. #4472 (LAB ID NO. 813963 ONLY) LP. #5284

C&itoMeEnvironmenfal

COVEJTPAGF oate_ INORGANIC ANALYSES OATA PACKAGE 10/-&\/8V

Canonie Environmental Project Naae: Union Cheaical LP. » MMTL

Sample Numbers

Client No. Lab ID No. Client No. Lab ID No.

rvubc^ i <g\$w

JvywvH ftl?>W

Comments:

FORM (1)

Sample Sfo-U

Date /sf \KYir>

INORGANIC ANALYSES DATA SHEET Canonie Environmental Project Name: Union Chemical Lab Sample ID. No. <Slitaf„ Lab Receipt Date

Elements Identified and Measured, Matrix: Water Soil Sludge S Other

ug/L or^/kg_as received baTjT>,(Circle One)

1.Aluminum_ 2.Antimony_ 3. Arsenic_ 4. Barium 5. Berylliun_ 6. Cadmium 7. Calcium 8. Chromium_ 2-,\[t,Q

9. Cobalt 10.Copper_ 11.Iron 12. Lead Cyanide

Comments:

13. Magnesium 14. Manganese 15. Mercury 16. Nickel 17.Potassium_ 18.Selenium_ 19.Silver 20.Sodium 21. Thallium_ 22. Vanadium_ 23. Zinc Percent Soils

INORGANIC ANALYSES DATA PACKAGE Canonie Environmental Project Name: Union Cheaical LP. »

Sample Numbers

Client No. Lab 10 No. Client No. Lab ID No.

MM-ii M*)'ii nii&i Ml*)-/*­ & Mu-<4 ft <ft>?7 MM'* Srx/// n Mw-t tl

ST IL L 100^3 f i B7gg

STILL Aw I %/ ZJfo l / j a d , 3 g/ g<?72­

2A/CM/. t ilJlZ*/?*' l ± k ^ J _ Si 3<?*><? _ _ STiu RboM 2 8/3<?8<T k-HCP") • Si

B~9 tJ-> $Za3L<t3

MV-t $1

M^-I\ p $i<?£ss-

A*^-£ 9/<7Y9^

MM-*! ^/^S~Qi>

K St^W

3-9(1) 120*4? ACQ t*c?z<r

Comments:

FORM (1) Sample MM-IP

Date lo~n~%% INORGANIC ANALYSES DATA SHEET

Canonie Environmental Project Name: Union Chemical Lab Sample ID. No. foil i f Lab Receipt Date

Elements Identified and Measured Matrix: Water \ / Soil Sludge Other

(Jug/L ormg/kg as received basis. (Circle One)

1. Aluminum_ 13. Magnesium 2. Antimony_ 2 2. 14.Manganese_ 3. Arsenic_ 2,5 IA 15. Mercury 0>~7> LA C\)AA

4. Barium 16. Nickel 5. Berylliun 17.Potassium_ 6. Cadmium 1.t> & ? 18.Selenium_ 7. Calcium 19.Silver 5"./ 8.Chromium_ 5", / LA 20.Sodium 9. Cobalt 21. Thallium_ H.o tU F 10.Copper_ ILA LL 22. Vanadium_ 11.Iron 23. Zinc 12.Lead 0^1 Percent Soils Cyanide

Comments:

FORM (1) Sample MUJ ~)t

Oate io-n-%% INORGANIC ANALYSES DATA SHEET

Canonie Environmental Project Name: Union Chemical Lab Sample ID. No. Lab Receipt Date r-to-tf

Elements Identified and Measured Matrix: Water ^ Soil Sludge Other

jjg/yor mg/kg as received basis. (Circle One)

1.Aluminu*_ 13.Magnesium__ 2. Antimony u. P 14.Manganese_ 3. Arsenic M F 15.Mercury 0.7sr u c\J*A 4. Barium 16.Nickel ?,s~ u ? 5. Bery11iun p.? u ? 17.Potassium 6. Cadmium 3,L U ? 18.Selenium ?.C U p 7. Calcium —th 19.Silver 5*, I u ? 8. Chromium 5*,! IA P 20. Sodium 9-Cobalt_ 21.Thallium H,o u F 10.Copper Ih IA P 22. Vanadium H.Iron_ 23. Zinc ? 12.Lead \ L H ! F Percent Soils Cyanide

Comments:

FORM (1)

Sample Mi\j W2~

Date 10- i INORGANIC ANALYSES DATA SHEET

Canonie Environmental Project Name: Union Chemical Lab Sample ID. No. Lab Receipt Date 8-/0^

Elements Identified and Measured Matrix: Water ^ Soil Sludge Other

(ug/por"mg/kg as received basis. (Circle One)

1- Aluminum 13. Magnesium 2.Antimony 2 x LA P 14. Manganese 3. Arsenic H p 15.Mercury o.lf IA tvM 4. Barium 16.Nickel fill P 5. Beryl1iun g LA P 17.Potassium 6. Cadmium 3, to LA P 18.Selenium 3.0 M F 7. Calcium 19.Silver 5~, 1 LA ? 8. Chromium <P, / lA P 20.Sodium 9. Cobalt 21.Thal1ium 1,c lA F 10. Copper LA P 22.Vanadium ll.Iron__ 23.Zinc L\98l ? 12.Lead ft. o l p Percent Soils_ Cyanide_

Comments:

FORM (1)

Sample Mu) -g

Date /e-n-98 INORGANIC ANALYSES DATA SHEET

Canonie Environmental Project Name: Union Chemical Lab Sample ID. No. Z ^ / l l O Lab Receipt Date X~/t> -Eg

Elements Identified and Measured Matrix: Water Soil Sludge Other

1ig/L)or mg/kg as received basis. (Circle One)

1. Aluminum 13.Magnesium

2. Antimony 2 x Lj f 14.Manganese 3. Arsenic 2,S LA P 15.Mercury l.H cuM 4. Barium 16.Nickel <R.S LA P 5-Berylliun Q,^ LA P 17.Potassium

6. Cadmium 3.L H P 18.Selenium 3,o LA F 7. Calcium 19.Silver \ LA P 8. Chromium j>, I LA ? 20.Sodium

9. Cobalt 21.Thallium H.o LA F 10. Copper I 2> LA ? 22.Vanadium 11-Iron 23.Zinc £/2.~] 12.Lead f /, Cl F Percent Soils Cyanide

Comments:

FORM (2) Inst.££f"*>

INITIAL AND CONTINUING CALIBRATION VERIFICATION Canonie Environmental Project Name: Union Cheoicel

Date iD-M-tfc Day 72/e Units: A CompoundMetals: 1. Aluminum 2. Antimony 3. Arsenic 4. Barium 5. Beryllium 6. Cadmium 7. Calcium 8. Chromium 9. Cobalt 10. Copper 11.Iron 12. Lead 13. Magnesium 14. Manganese 15. Mercury 16. Nickel 17. Potassium 18.Selenium 19.Silver 20.Sodium 21. Thallium 22. Vanadium 23. Zinc Other: Cyanide

Initial Calib. 1 Continuing Calib. 2 True Value Found VR True Value Found VR

j f o 22. <& If

xfo ifA /of

i f o toy 2f0 j f l JL

2 f o Ji.f 11 jf.o loo

Initial Calibration Source J - Q ( > t t ' I Continuing Calibration Source 1 'QCtt-QZ ( Indicate Anaytical Method Used : P-ICP; A-Flame AA; F-Furnace AA

ft) lust. T T X - u * *

INITIAL AND CONTINUING CALIBRATION VERIFICATION Ctnonle Environment*! Project Nine: Union Chemlcel

Pate_/o-<7- OivTti^A^ Units: /, Compound Initial Calib. 1 Continuing Calib. 2 Hetals: True Value Found %R True Value Found %R 1. Aluminum

11 1032. Antimony Sr>o Mo 3. Arsenic 4. Barium 5. Beryllium £~e o 1L sTco 9LO 92.

S~e>o I t 6. Cadmium 7. Ca1ciutn

HL 1> 9Z £~£>Q 92.8. Chromium 9. Cobalt

10 310. Copper S~oo Hit is 11.1ron

See12. Lead

13. Magnesium

14. Manganese ^ c ft>8 ILL15. Mercury

to 9 512 lo$16. Nickel

17. Potassium

18.Selenium o 991 9819.Silver

20.Sodiutr,

21 . Thallium

22. Vanadium Sc<=> H<iO 98 SCO irof /oi23. Zinc

Other:

Cyanide

2 ' ^ n - 0 J 9 i-ILtif Z'OCfiX'O/^ 3'/iff

I n i t i a l Calibration Source uP l o t ? Continuing Calibration Source * J P tc lS~

Indicate Anaytical Method Used : P-ICP; A-Flame AA; F-Furnace AA

Form (3)

BLANKS

Canonie Environmental Project Name: Union Chemical Date IQ >if'Day kjU+^Jc^ Units: M^/t-

Compound „ Initial Continuing, Calibration Preparation Blanks on Blank Value Matrix: Matrix: ue 1

1 Metals:

1. Aluminum *2- LA 2UL2. Antimony LA 3. Arsenic 4. Barium SAIL5. Beryllium ?. 4 lA LkJL6. Cadmium 7. Calcium S.I (A 9.1 u 8. Chromium 9. Cobalt I?, LA LLk.10. Copper 11.Iron 1.0 LA I.o IA 12. Lead 13. Magnesium 14. Manganese

on? a15. Mercury 7.r LA

16. Nickel 17. Potassium

5,0 14 3.0 LA 18.Selenium

I u19.Silver 20.Sodium

Ho LA 21. Thallium 22. Vanadium

1.2 LA 1.2 IA 23. Zinc Other:

Cyanide

1. Reporting Units: Aqueous ug/L; SoiId mg/kg

FORM (4) ICP INTERFERENCE CHECK SAMPLE

Canonie Environmental Project Name: Union Chemical Date 10-im Dav 7W«^ Check Sample I . D. l r- O<Ki-0i7

Check Sample Source j L t ^ Units: ug/L

Compound Control Limits 1 True 2 Initial Final Mean Std. Dev. Observed %Rec. Observed %Rec

Metals:

1.Aluminum

2.Antimony too2.1 £IH111. ILL3.Arsenic

4.Barium 5.Beryllium V73 5c o H2i> ^0 HlH 6.Cadmium 910 n

31- I t>co °iol .21 7.Calcium

8.Chromium HHH 9.D SCO 111­ 31. 39L> 31

9.Cobalt

10.Copper H90 HI. $co 77 11.1 ron

12.Lead 991 31. 12* 13.Magnesium

14.Manganese

15.Mercury

16.Nickel 933 HI. looo l i t 142. 3L17.Potassium

18.Selenium

19.Silver 20.Sodium

21.Thallium

22. Vanadium 23. Zinc 9H9 HI. H°lloco 3fLOther:

1 Mean vaule based on n * 7 .

2 True vaule of EPA ICP Interference Check Sample on contractor standard.

SURE ICOVCRY

Canonic environment*! Project Rane: Union Chemical

Date /o~it-&8 Sample Ro. rt^-t

lab Sample ID Ro. ? a / v o

Matrix: uy^i^­ Units:

Compound Control Un i t Spiked Sample Sample Spiked

Result(SSR) Result (SR) Added(SA) %R

Metals:

1.Aluminum

2.Antimony 3.Arsenic 7«T- 2±LLA.

4.Barium

5.Beryllium •7<r­6.Cadmium 7 5 - ­ A 2 r ? r 7.Calcium 8.Chromium 7 3 ' - / 9.Cobalt

10.Copper 11.1ron

12.Lead i f * fO 13.Magnesium

14.Manganese

15.Mercury 7 5~­ JS.S% 16.Nickel

17.Potassium

18.Selenium 3,0 J f 0 19.Silver 7 5 " ­ / A S - ? . 20.Sodium 21.Thallium i f . o 22.Vanadium

23 Zinc Other:

1 %R ­ [(SSR-SR)/SA] x 100

•R" ­ Out of control

•HR" ­ Not Required

Comments:

SPIKE SAMPLPJECOVERY

Canonie Environmental Project Rame: Union Chemical Date lo-H-$% Sample Ro.

Lab Sample ID No._££_V2£7

Matrix: u^JCZ Units:

Compound Control Limit Spiked Sample Result(SSR)

Sample Result (SR)

Spiked Added(SA) VR

Metals:

1.Aluminum 2.Antimony 3.Arsenic

4.Barium l5'-/ZiT%

5.Beryllium

6.Cadmium 7.Calcium

7S~­7fP-

?* 2

e>. o 110

8.Chromium

9.Cobalt 75~­ JZF% e>. o 9?

10.Copper

11.1ron 7S~­ /25l. i or

12.Lead

13.Magnesium

14.Manganese

15.Mercury

16.Nickel

17.Potassium 7 j T - / ; i < r ?. 7/ ? u±

18.Selenium

19.Silver

20.Sodium

7> ­

7S~­

l^iT*?*

/ X t T l 2 73 e>. o 3 ' ^

21.Thallium

22.Vanadium 15-­ / I f ? .

23 Zinc

Other: 7 J T - fcn> 117,

1 %R = [(SSR-SR)/SA] x 100

"N" ­ Out of control

"NR" ­ Not Required

Comments

SPIKE ISfipU RCCOVCKT

Canonic Environmental Project Name: Union Chemical Date to ­ 11'*$ Sample Ro. Mw-n

lab Sample ID Ro. te/ii*

Matrix: Units: > » A -Compound Control Limit Spiked Sample Sample Spiked

Result(SSR) Result (SR) AddedlSA) %R

Metals:

1.Aluminum

2.Antimony 7? ­ US'?. 3.Arsenic 7S--/2ST'?. 4.Barium

5.Beryllium 75"­ /A??. 6.Cadmium IS-­ /AS 9. 7.Calcium

6.Chromium 7£T -/2S% 9.Cobalt

10.Copper •7<T-/AS'Vo 11.Iron

12.Lead

13.Magnesium

14.Manganese

15 .Mercury 1S~­ 5.11 &. o / / 3 16.Nickel 7 S ~ - / a g ? . 17.Pot as si urn

18.Selenium I S ­ ­ ASS"? . 19.Silver 1S~ ­ /*-S"7. 20.Sodium 21.Thallium 1ST- /2S~ -?* 22.Vanadium

23 Zinc 75~­ /^S % Other:

1 %R « [(SSR-SR)/SA] x 100

"N" ­ Out of control

"NR" ­ Not Required

Comments:

5S/2 ­ Qf=(sdQ y /GO

DU

Canonie Environmental Project Name: Union Cheaical Date /c-/9'8<6 Sample No.

Lab Sample ID No.JL^y^f7

Units: A Matrix UH&M.

Compound Control Limits 1 s p a c e

Sample (S) SPllL.6 ^$rr*pi£

Duplicate (D) KPP, 1.

Metals: 1.Aluminum

2.Antimony 1 2o<?> % 99 3.Arsenic 1 20?* 4.Barium 5.Beryllium 1 ZD% -75-0 •7S~3 6.Cadmium 7.Calcium

121

8.Chromium

9.Cobalt ? 20% i l l e>./3

10.Copper 1 2o% 25~Z 11.1ron

12.Lead Z 20% 13.Magnesium

14.Manganese 15 .Mercury if 2-0 -?. 16.Nickel

17.Potassium 1 xo% °l/3 1*L

18.Selenium 1 2-0% 19.Silver

20.Sod i urn 1 2.0% 2 7 3 ^ 7 / an­

i l .Thallium 1 22.Vanadium

23.Zinc lot. Other:

* Out of Control

1 2

To be added at a later date RPD * [ I S -D | / ( (S • D)/2)] x 100

NC - Non calculable RPD due to value(s) less than CRDL

iMtts Canonie Environment*! Project Name: Union Cheaical Date /o-/y-^T Saaple Wo. Ptu/-€

Lab Sample ID Wo. Z2./VQ Units:

Matrix ^ /•<

Compound Control Limits 1

Sample (S) Duplicate (D)

Metals:

1.Aluminum

2.Antimony t 20*7. 3.Arsenic 1 20 7. 4.Barium 5.Beryllium 1 20% 6.Cadmium

7.Calcium 1 ^g?.

8.Chromium 1 2o% 9.Cobalt

10.Copper 1 2o% 11.1ron

12.Lead 1 20% aL3 12. 13.Magnesium

14.Manganese

15 .Mercury 1 3-0% 16.Nickel 1 2-0% 17.Potassium

18.Selenium 1 2Q% 21.? 3. I

19.Silver 1 2Q% 20.Sodium

21.Thallium 1 20-% 2?Z 2 6.(? 3*0 22.Vanadium 23.Zinc

Other:

* Out of Control

1 2

To be added at a later date RPD = [ | S ­D |/((S • D)/2)] x 100

NC - Non calculable RPD due to value(s) less than CRDL

Ml

Canonie Environmental Project Name: Union Cheaical Date Saaple Wo. Mw-n

lab Saaple ID Wo. Units: Jy^/c

Matrix

Compound Control liaits 1 Sample (S) Duplicate (0) fippt n.

Metals:

1.Aluminum 2.Antimony 2 2 0 3.Arsenic 1 ZQ 7» 4.Barium 5.Beryllium 1 20% 6.Cadmium 7.Calcium 8.Chromium 1 2o% 9.Cobalt 10.Copper 1 2o% 11.Iron 12.Lead 1 20% 13.Magnesium 14.Manganese 15 .Mercury 1 2.0% 16.Nickel - xo% 17.Potassium 18.Selenium 1 2Q% 19.Silver 1 2Q% 20.Sodium 21.Thallium 1 20-X 22.Vanadium 23.Zinc 2o Other:

* Out of Control

To be added at a later date RPD * [ | S -D |/((S • D)/2)] x 100 NC - Non calculable RPD due to value(s) less than CRDL

1

Canonie Environmental

fom (10) MOLDING TIMES

Project Name: Union Chemical

Ltsre-D 8* LP h/weem

Date Mercury Mercury CN Prep L P No Matrix Received Prep Date Holding Til Date

Hoi

unit* id£JL n

Holding time is defined as number of days between the date received and the sample preparation date.

•

Tom (II)

INSTRUMENT DETECTION LIMITS Canonie Environmental Date Ol/ .ofo „

^Tcj) Flame AA ( Circle One ) Model Humberts fei Furnace AA Number

Element (igV) Element Wavelength

1. Aluminum 13.Magnesium

2. Antimony 22 ? 14.Manganese

3. Arsenic 4. Barium m i l 3,5 f 15.Mercury

16.Nickel SLS 3 B 73l.feC>M

5. Beryllium 17.Potassium

6. Cadmium 7. Calcium

3,4 9 18.Selenium 19.Silver

6.oF­5J P

8.Ch mm 20.Sodium 9.Cobalt 21.Thallium

10.Copper ^ ? 22.Vanadium

U.Iron 23.Zinc 12.Lead 7T0 2>S3 7.H ?

Footnotes: . Indicate the instrument for which the IDL applies with a -P" (for ICP an "A" (for Flame AA) . or an "F' (for Furnace AA) behind the value

. Indicate elements commonly run with background correction (AA) with a

•B" behind the analytical wavelength.

. If more than one ICP/Flame or Furnace AA is used, submit separate forms

XI-XI11 for each instrument.

for. (12) ,CP 1nter«le«*nt Correction f*c

CinoMe Environment*! ICP Model T.3A 11

TnUreleaent Correction f*cton 0*te Ctfjiok*

R A D I A N C O R P O R A T I O N

23 November 1988

Dave Harding Canonie Labs 800 Canonie Drive Porter, IN 46304

Dear Mr. Harding:

Enclosed i s the f i n a l report on your samples submitted for dioxins/furans, as reworked to meet the late s t EPA report format. As we discussed, I am also sending a copy d i r e c t l y to Mary Ann Becker of EPA Region 1.

Please c a l l i f you have any questions.

Very t r u l y yours, _

Fred L. Shore, Ph.D. Technical Director

FLS:st

cc: G. T. Demos J. Martin

Enclosure

8501 Mo-Pac Blvd./P.O. Box 201088/Austin, TX 78720-1088/(512) 454-4797

R A D I A N

FORM 1 QUANTITATION REPORT

A808009­01A

A808009­02A

A808009­03A

Sampling Location Sample Number Traffic Report Remarks Cl ient ID

2,3.7,8-TCDD Non-2.3.7.8-TCDD 1.2.3.7.8-PeCDD non-1.2.3.7.8-PeCDD x,x.2.3,7.8-HxCDD Non-x,x.2.3.7.8-HxCDD 1.2.3.4.6.7.8-HpCDD 1.2.3.4.6.7.9-HpCDD OCDD

<38995

X33CX 17 REG

ND* 1.6 ND*

0.19 1.1*

1.8 2.1* 3.4 26

MPC 0.02

0.02

<38996

ng/g XDA993

1.6 1.4 ND ND ND ND ND ND ND

MPC

0.10 0.10 0.08 0.08 0.06 0.06 0.06

<38997

n g / 8 MDC788

MPC ND 0.06 ND 0.06 ND 0.08 ND 0.08 ND 0.05 ND -"0.05 ND 0.03 ND 0.03 ND 0.03

2.3.7 .8-TCDF Non-2.3.7.8-TCDF x.2 .3 .7 ,8-PeCDF Non-2t 3.7.8-PeCDF x ,x ,2 t 3 .7 .8 -HxCDF N o n - x . x ^ . S ^ . S - H x C D F x ,x ,x ,2 ,3 .7 ,8-HpCDF x .x .x .2 .3 .7 ,9-HpCDF OCDF

ND* ND ND* ND ND* ND ND* ND ND*

0.02 0.02 0.02 0.02 0.02 0.02 0.07 0.07 0.03

ND ND ND ND ND ND ND ND ND

0.04 0.04 0.03 0.03 0.04 0.04 0.11 0.11 0.05

ND ND ND ND ND ND ND ND ND

0.07 0.07 0.03 0.03 0.03 0.03 0.06 0.06 0.03

TEF 0.229 ND ND

Concentration/Dilution Factor Date received by lab

(mass spec) Date sample extracted Date of analysis Instrument used for analysis

8/15/88

8/9/88 8/22/88 HP5987

8/15/88

8/9/88 8/22/88 HP5987

8/15/88

8/9/88 8/22/88 HP5987

*ND = 2nd (SP 2331) column confirmation. = Not detected.

FORM 1 QUANTITATION REPORT

A808009­04A

A808019­02A

A808019­01A

Sampling Location Sample Number Traffic Report Remarks Cl i ent ID

<38998

ng/g Reagent

Blank

<39002

ng/g N270 E300

<389003

ng/g N300

E60

2,3,7,8-TCDD Non-2.3.7.8-TCDD 1.2.3.7.8-PeCDD non-1.2.3.7,8-PeCDD x,x,2,3.7,8-HxCDD Non-x.x.2,3.7,8-HxCDD 1.2.3.4.6.7.8-HpCDD 1.2.3.4.6.7.9-HpCDD OCDD

ND ND ND ND ND ND ND ND ND

MPC 0.04 0.04 0.11 0.11 0.09 0.09 0.06 0.06 0.07

ND ND ND ND ND ND ND ND ND

MPC 0.05 0.05 0.11 0.11 0.08 0.08 0.05 0.05 0.05

ND ND ND ND ND ND ND ND ND

MPC 0.02 0.02 0.07 0.07 0.06

"0.06 0.04 0.04 0.03

2.3.7 .8-TCDF Non-2.3.7,8-TCDF x,2 ,3 ,7 .8-PeCDF Non-2,3.7.8-PeCDF x.x .2 ,3 .7 ,8-HxCDF Non-x.x.2.3.7,8-HxCDF x . x . x ^ . S ^ . S - H p C D F x .x .x ,2 .3 .7 ,9-HpCDF OCDF

ND ND ND ND ND ND ND ND ND

0.05 0.05

0.04

0.04 0.12 0.12 0.06

ND ND ND ND ND ND ND ND ND

0.07 0.07 0.04 0.04 0.04 0.04 0.09 0.09 0.04

ND ND ND ND ND ND ND ND ND

0.02 0.02 0.02 0.02 0.02 0.03 0.07 0.07 0.03

TEF ND ND ND

Concentration/Dilut ion Factor Date received by lab

(mass spec) Date sample extracted Date of ana lys i s Instrument used for ana lys i s

8/15/88

8/8/88 8/22/88 HP5987

8/15/88

8/9/88 8/22/88 HP5987

8/15/88

8/8/88 8/22/88 HP5987

* = 2nd (SP 2331) column confirmation. ND = Not detected.

R A D I A N

FORM 1 QUANTITATION REPORT

A808019­01A DUP

A808019­04A

IA808019­05A

Sampling Location Sample Number T r a f f i c Report Remarks Cl i ent ID

2.3.7.8-TCDD Non-2.3.7.8-TCDD 1.2.3.7.8-PeCDD non-1,2.3.7.8-PeCDD x.x.2,3.7.8-HxCDD Non-x.x.2.3.7.8-HxCDD 1.2.3.4.6,7.8-HpCDD 1.2.3.4.6.7,9-HpCDD OCDD

<39004

ng/g N300

E60

ND ND ND ND ND ND ND ND ND

MPC 0.02 0.02 0.07 0.07 0.06 0.06 0.04 0.04 0.03

<39011

n 8 / g N60

E480

ND ND ND ND ND ND ND ND ND

MPC 0.01 0.01 0.04 0.04 0.04 0.04 0.03 0.03 0.02

<39012

"g/g MW-12

ND ND ND ND ND ND ND ND ND

MPC 0.03 0.03 0.07 0.07 0.06

'0.06 0.04 0.04 0.04

2.3.7 .8-TCDF Non-2.3.7.8-TCDF x,2 .3 .7 .8-PeCDF Non-2.3.7.8-PeCDF x.x .2 .3 .7 .8-HxCDF Non-x ,x»2.3 ,7 ,8-HxCDF x ,x ,x .2 ,3 .7 .8-HpCDF x ,x ,x .2 .3 t 7 .9 -HpCDF OCDF

ND ND ND ND ND ND ND ND ND

0.03 0.03 0.02 0.02 0.03 0.03 0.07 0.07 0.03

ND ND ND ND ND ND ND ND ND

0.01 0.01 0.01 0.01 0.02 0.02 0.05 0.05 0.02

ND ND ND ND ND ND ND ND ND

0.03 0.03 0.02 0.02 0.03 0.03 0.08 0.08 0.04

TEF ND ND ND

Concentrat ion/Dilut ion Factor Date received by lab

(mass spec) Date sample extracted Date of ana lys i s Instrument used for ana lys i s

8/15/88

8/8/88 8/22/88 HP5987

8/15/88

8/8/88 8/23/88 HP5987

8/15/88

8/9/88 8/23/88 HP5987

*ND =

= 2nd (SP 2331) Not detected.

column confirmation.

R A D I A N

FORM 1 QUANTITATION REPORT

1:10 e c ;Date i p ^ L ^ f f i ^ ,8/15/88 s a m p

8/15/88 Date ot analysis ~" 8/9/88 ,8/8/88 Instrument uged ^ ^ 8/23/88 t o r a n T 8/23/88 HP5987 HP5987

FORM 2 INTERNAL STANDARD RECOVERY

Lab ID

EPA ID *C-TCDD *C-PeCDD *C-HxCDD *C-HpCDD *C-OCDD

A808009-01A

A808009-02A A808009-03A A808009-04A

A808019-02A

A808019-01A

A808019-01ADUP

A808019-04A

A808019-05A A808019-06A

A808019-03A

A808019-02AMS

A808019-02AMSD

>38995

>38996 >38997 >38998

>39002

>39003

>39004

>39011

>39012 >39015

>39016

>39000

>39001

X33CX 17 REG

XDA-993 MDC-788 Reagent

Blank N270 E300 N300

E60 N300

E60 N60

E480 MW-12

Secondary Scrubber

N60 E240 N270 E300 N270 E300

74 36 18

28

28

62

58

79 36

92

50

59

45

77 50 51

39

50

73

71

77 48

118

54

69

70

68 49 66

39

57

68

67

69 46

114

55

65

73

67 49 68

37

61

67

68

77 48

117

53

61

73

61 40 57

29

53

60

66

71 41

91

43

50

59

•C-TCDD: Carbon 13 labeled 2.3.7,8-tetrachlorodibenzodioxin. *C-PeCDD: Carbon 13 labeled 1.2.3.7.8-Pentachlorodibenzodioxin. *C-HxCDD: Carbon 13 labeled 1.2,3.4.7,8-Hexachlorodibenzodioxin. *C-HpCDD: Carbon 13 labeled 1.2,3.4.6.7,8-Heptachlorodibenzodioxin. *C-OCDD: Carbon 13 labeled Octachlorodibenzodioxin.

<

FORM 2 INTERNAL STANDARD RECOVERY

Lab EPA ID ID *C-TCDF *C-PeCDF

A808009-01A >38995 X33CX 17 REG 81 78

A808009-Q2A >38996 XDA-993 39 46A808009-03A >38997 MDC-788 20 36A808009-04A >38998 Reagent

Blank 31 36A808019-02A >39002 N270

E300 30 44A808019-01A >39003 N300

E60 66 71A808019-01ADUP >39004 N300

E60 62 69A808019-04A >39011 N60

E480 86 78A808019-05A >39012 MW-12 37 45A808019-06A >39015 Secondary

Scrubber 98 90A808019-03A >39016 N60

E240 52 54A808019-02AMS >39000 N270

E300 62 65A808019-02AMSD >39001 N270

E300 48 63

*C-TCDF: Carbon 13 labeled 2.3,7,8-tetrachlorodibenzofuran. *C-PeCDF: Carbon 13 labeled 1,2,3,7.8-Pentachlorodibenzofuran. *C-HxCDF: Carbon 13 labeled 1.2.3.4,7,8-Hexachlorodibenzofuran. *C-HpCDF: Carbon 13 labeled 1,2,3,4,6,7,8-Heptachlorodibenzofuran. •C-OCDF: Carbon 13 labeled Octachlorodibenzofuran.

*C-HxCDF

71 47 63

39

56

71

70

82 56

94

56

69

75

*C-HpCDF *C-OCDF

65 69 44 46 62 64

35 34 ~~

58 58

64 68

68 72 ~~~

75 72 47 ~42

86 89

50 45 ~ ~ ~

61 56

69 69

FORM 3 INITIAL CALIBRATION SUMMARY

Instrument-HP5987

Cone, (ppm)

Time

STD.ID.

(K2

5/5/88

>3825A

CK2

5/5/88

>38258

(K2

5/6/88

>38265

0 5

5/5/88

>38255

(K5

5/6/88

>38266

(K5

5/6/88

>38270

1_ 0 1.0

5/5/88 5/5/88

>38256 >38261

Compound RF RF RF RF RF RF RF RF

TCDD 1.079 1.150 1.127 1.048 1.031 1.000 1.084 1.065

PeCDD

HxCDD1

1.195

1.086

1.355

1.089

1.222

1.057

1.160

0.996

1.196

0.981

1.192

0.957

1.226 1.221

1.049 1.063

HpCDD

TCDF

PeCDF2

HxCDF3

HpCDF4

OCDF

1.176

1.061

1.281

1.035

1.150

1.081

1.205

1.039

1.277

1.053

1.162

1.102

1.187

1.025

1.286

1.060

1.164

1.131

1.019

0.959

1.288

0.954

1.050

1.185

1.058

0.944

1.168

0.977

1.037

1.114

1.091

0.969

1.207

0.949

0.962

1.064

1.111 1.127

1.016 1.009

1.276 1.278

1.024 1.090

1.114 1.023

1.062 1.128

Average of 1,2.3.4.7.8; 1.2,3.6,7.8; and 1,2,3,7,8,9. 2 Average of 1,2,3,7,8 and 2,3.4.7,8.

3Average of 1,2,3.4.7.8; 1,2,3,6,7.8; 1.2,3.7,8.9 and 2,3.4,6.7.8. 4 Average of 1,2,3,4.6,7,8 and 1,2,3.4,7,8.9.

FORM 3 INITIAL CALIBRATION SUMMARY

Instrument-HP5987

Cone, (ppm)

Time

STD.ID.

1.0

5/6/88

>38267

2.5

5/5/88

>38257

2.5

5/5/88

>38262

2.5

5/6/88

>38268

5.0

5/5/88

>38258

5.0

5/6/88

>28264

5.0

5/6/88

>28269

Compound RF RF RF RF RF RF RF RF %RSD

2.3.7,8-TCDD

1.2.3.7.8-PeCDD

HxCDD

1.2.3.4.6.7.8-HpCDD

OCDD

2,3.7.8-TCDD

PeCDF2

HxCDF3

HpCDF4

OCDF

1.126

1.220

1.054

1.148

1.023

1.274

1.084

1.128

1.125

1.242

1.066

1.128

1.031

1.283

1.029

1.057

1.052

1.075

1.231

1.026

1.153

1.029

1.273

0.955

1.068

1.054

1.153

1.253

1.052

1.144

1.016

1.315

1.059

1.115

1.110

1.078

1.190

1.051

1.139

1.020

1.255

1.037

1.071

1.032

1.184

1.266

1.146

1.161

1.049

1.340

1.104

1.189

1.052

1.051

1.147

1.047

0.997

1.279

1.066

1.086

1.002

1.092

1.220

1.048

1.13 2

1.055

1.013

1.272

1.032

1.089

1.082

4.7

4.0

4.4

4.4

2.8*

3.3

3.2

4.9

5.8

4.3

*calculated from:

1.0 ppm 2.0 ppm

>387867/18/881.057

>38836 7/26/88

1.058

>38853 7/27/88

1.102

>388557/27/881.025

>38866 8/1/88

1.035

^Average^Average^Average

of of of

1 .2 .3 .4 .7 .8 : 1 .2 .3 .6 .7 .8 ; 1 .2 .3 .7 .8 and 2 . 3 . 4 . 7 . 8 . 1 .2 .3 .4 .7 .8 ; 1 .2 .3 .6 .7 .8 ;

and 1 .2 .3 .7 .8 .9 .

1 .2 .3 .7 .8 .9 and 2 .3 .4 .6 .7 ,8 , Average of 1 ,2 ,3 .4 .6 ,7 ,8 and 1 .2 .3 ,4 .7 ,8 ,9 .

R A D I A N

FORM 4 CONTINUING CALIBRATION SUMMARY

Instrument HP5987

I n i t i a l Cont. Cont. Cont. Curve Calib. Calib. Calib. (RF) (RF) %D (RF) %D (RF) %D

CONC. ­ 1.0 ppm 0.5 ppm 0.5 ppm

DATE/TIME 5/5-6/88 8/22/88 8/22/88 8/23/88

STD.ID. 8280 8280 8280 8280

2.3.7.8-TCDD 1.092 1.080 1.1 1.004 8.3 1.00 8.4

1.2.3.7.8-PeCDD 1.220 1.216 0.4 1.146 6.2 1.20 1.6

HxCDD 1.048 1.057 0.9 1.009 3.8 1.00 . 4.6

1.2.3.4.6.7.8-HpCDD 1.132 1.147 1.3 1.060 6.6 1.039 8.2

QCDD 1.055 .987 6.7 1.018 3.6 .967 8.7

2.3.7.8-TCDF 1.013 1.018 0.5 0.951 6.3 0.95 6.2

PeCDF 1.272 1.188 6.8 1.124 12 1.14 10

HxCDF 1.032 1.012 2.0 0.947 8.6 0.958 7.2

HpCDF 1.089 1.055 3.1 0.979 11 0.975 9.9

OCDF 1.082 1.056 2.4 1.019 6.0 1.053 2.7

R A D I A N

FORM 4 CONTINUING CALIBRATION SUMMARY

Instrument HP5987

I n i t i a lCurve(RF)

Cont. Calib.

(RF) %D

Cont. Calib.

(RF) %D

Cont. Calib.

(RF) %D

CONC.

DATE/TIME

STD. ID.

5/5-6/88

8280

0.5 ppm

8/23/88

8280

2.3.7.8-TCDD 1.092 1.002 8.6

1.2.3.7.8-PeCDD

HxCDD

1.2.3.4.6.7.8-HpCDD

0CDD

1.220

1.048

1.132

1.055

1.101

0.969

1.022

0.885

10

7.8

10

17

2.3.7 ,8-TCDF

PeCDF

HxCDF

HpCDF

OCDF

1.013

1.272

1.032

1.089

1.082

0.940

1.113

0.923

0.955

1.027

7.5

13

11

13

5.2

DATE INJ TIME STD ID COLUMN INST ID : J 2 3 5 £

13C-1234-TCDD

13C-2378-TCDD**

2378-TCDD*

12378-PeCDD*

13C-123789-HXCDD

13C-123678-HxCDD**#

2378-HxCDD*

1234678-HpCDD*

13C-OCDD***

OCDD*

13C-2378-TCDF**

2378-TCDF^

_2378-PeCDF^

2378-RxCDF^

13C-1234 678-HpCDF***

2378-HpCDF*

OCDF*

POSH S STANDARD WORKSHEET

ftX

A/0 Mb

31 31

HO.HS

A/D

A/D A&

IflH AREA ION

(334

32)/4cl&| (334

20) (322

58) (356

04) (S"3Sa?< '(402

04)/^24i (402

92)_ (390

26) (424

70) 0231 (472

5 8 ) U 2 ^ I (460

i6)agftsb (318

04) (306

42) (340

76) (374

«) qatar (420

(408 10)

(444 42)

W A * AREA/AREA* CONC RRF

I21GSL .%Q Ag7» ATI

/a/7477 , 3L

* - Ion used for quanitation ** - Quanitation based on 130-1,2,3,4-TCDD ***- Quanitation based on 13C-1,2,3,7,8,9-HxCDD

,7,8-HxCDD

NOTlt I f aore than one ratio i s required please writs ratios directly oa

note*, etxcvk C-cey^&c <*fova ffcs d>c^A (6be. led S~tcl "far

R A D I A N

COLUMN: 40 V)j > " INST ID: ( I f CURVE/STDS: COMMENTS:

RT

13C-1.2.3.4-TCDD 13C-2.3.7.8-TCDD 2,3.7.8-TCDD AiP Total-TCDD 1.2.3.7.8-PeCDD NO. Total-PeCDD 130-1.2,3,7.8.9 ­

HxCDD 3 3 . 3 0130-1.2,3.6.7,8 ­

HxCDD x,x,2.3,7,8-HxCDD « -Total-HxCDD • ? l - ^ Q1.2.3,4.6.7.8­

HpCDD Tot al-HpCDD 13C-0CDD OCDD HOW 13C-2.3.7.8-TCDF 2,3.7.8-TCDF A/6 Total-TCDF NO x,2,3,7,8-PeCDF /V Total-PeCDF AJ x,x,2,3,7,8-HxCDF A/D Total-HxCDF 13C-1,2,3,4,6,7,8 ­

HpCDF x x x92»3 »798*" t v

HpCDF Total-HpCDF OCDF A/D

*Ion used for quantitation.

FORM 6 SAMPLE WORKSHEET

ION AREA ION

(332) 156953 (334)(332) /fe<taa< (334)(3 20) (3 22) (320) fwafeHl (322)(358) _ _ _ (356) (358) Ht>S"3 (356)

(404) t y a a ^ (402)

(404) / OQ3& (402) (392) (390)

(392) I S k H I * (390)

(426) (424) (426) (424) (470) 3QT?3 (472) (458) i<-2Cfigf (460) (316) ^SfcSO (318) (304) (306) (304) (306) (342) (340) (342) (340) (376) (374) (376) (374)

(422) g o O S (420)

(410) (408) (410) (408) (442) (444)

DATE: S h a h * * INJ TIME: 1 : H I fif^ CLIENT ID: Ca.^ani^ *3>3c*<7gfc SAMPLE ID: ^Q^OQrl -077T SAMPLE SIZE: «3S.3>^­

AREA* AREA/AREA* OTNC RRF -ar

_ 3oqJ85 ' 7W76 ^VT­

/S-3a»^ .W

-feH 6A*\

j y ^ f c l g .^6

.ITT .*< P - l

T3~ an&ru> 7T3~ .7ST fr-ry>o US f.oSS"

133003

NOTE: Each cogener group has i t s own labeled standard for quantitation.

POSH S STANDARD WORKSHEET

DATE :_v/rzj«l INJ TIME STD ID COLUMN

7,; far 3i/ry INST ID ISM AR£A 1QM AREA* ABEA/AREA* CONC RR£

13C-1234-TCDD 332) /S*/S5?(334) ft6*1? .fr6

13C-2378-TCDD** 332)"?9SY? (334) ^Q/TTj .^7 3 f o (.V?

2378-TCDD* 320) 457?^ (322) VtfZC - 7l> ( Cft7

12378-PeCDD^ A/0 358) (356)

13C-123789-HXCDD 404)_^3^7.(402) W 7 7 1 . l

13C-123678-HXCDD*** 3LTT 2378-HxCDD* A/0 392) (390)

1234678-HpCDD^ A70 426) (424) """

13C-OCDD*** 470)$Q#C (472)

OCDD*7 458) (460)

13C-2378-TCDF** 316) /29t f9 f31Hi<T9^d . »2 3 n 2./3 2378-TCDF^ A/0 304) (306)

_237S-PeCDF^ 342) (340)

2378-HxCDF^ 376) (374)

13C-1234678-HpCDF*** 422) 71366(420) (2g>TCf3

.2378-HpCDF 410) (408)

OCDF* 442) (444)

* - Ion used for quanitation ** - Quanitation based on 13C-1,2,3,4-TCDD ***- Quanitation based on 13C-1,2,3,7,8,9-HxCDD

,7,8-HxCDD

NOTEt I f more than one ratio i s required please write ratios directly on EICP.

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: _4C f^V DATE: INST ID:" INJ TIME:

CURVE/STDS; CLIENT I D : C a ^ r u e A D M W COMMENTS: SAMPLE I D : fYbCfeC&j-

SAMPLE SIZEl

RT ION AREA ION AREA* AREA/AREA* CONC RRF »

13C-1.2.3.4-TCDD 13C-2.3.7.8-TCDD an. i?

(332) (332)

j s i s s s ;7<Q-3V*

(334) (334) 101 (-Y7

2,3,7,8-TCDD Total-TCDD 1,2,3,7,8-PeCDD

(3 20) (320) (358)

kS~<73)1.0(,R

(3 22) (322) (356)

r 7* 351 3.0

Total-PeCDD A/P (358) (356) 13C-1 .2 .3 .7 .8 .9 ­

HxCDD 32-­ (404) 14 6351 (402) *1 ^ 1 1 3 C - 1 . 2 . 3 . 6 . 7 . 8 -

HxCDD x,x,2.3.7,8-HxCDD

SI 7^ ~TUTT

(404)(392)

13H& (402)­(390)

Total-HxCDD (392) (390) 1,2,3.4,6.7.8­

HpCDD Total-HpCDD

A/D A7IT

(426) (426)

(424) (424)

13C-0CDD (470) (472) HCf7& . 7 S T OCDD 13C-2.3.7.8-TCDF

A/D (458) (316)

(460) (318) t S 7 0 3 O

2.3.7.8-TCDF ATP (304) (306)

Total-TCDF x.2,3.7,8-PeCDF Total-PeCDF

/ V P

7fr£

(304) (342) (342)

(306) (340) (340)

x.x,2,3,7.8-HxCDF Total-HxCDF

A/O - £12.

(376) (376)

(374) (374)

130-1.2.3,4.6,7.8­HpCDF 3 0 . (422) - ?Q^60 (420) l7Sr7Y3_ , V 7

x9x,x02v3 ,7»8"* HpCDF iVQ (410) (408)

Total-HpCDF (410) (408) OCDF A / p (442) (444)

*Ion used f o r q u a n t i t a t i o n .

NOTE: cogeEacEachh cogener group has i t s own l abe l ed standard f o r q u a n t i t a t i o n .

rep - #M

FORM S 8TANDAJU) W0RX8HEKT

DATE : Ji INJ TIME; - K a y * STD ID r p 0- "1 COLUMN i fr^^KS INST ID :_EtEM&£_.

AREA 1QH AREA* AREA/AREA* CON£ g££

13C-1234-TCDD [332 334) "L?-%$"66 „<m5 —

13C-2378-TCDD** 2^ [332 fro t y i 0 /_v7

2378-TCDD^ A/D [320 322)

12378-PeCDO* A/0 [358 356)

13C-123789-HXCDD [404 402)^ilif^_J23_ 13C-123678-HXCDD*** 31-73 [404 402) N&^<f 4£?a f f B

2378-HxCDD^ -LL [392 390)

1234678-HpCDD2' [426 4 2 4 ) _ _ ­

13C-OCDD*** [470 4 7 2 ) ^ A& ST?» .75V

OCDD* /vO [458 460)

13C-2378-TCDF** [316 ^(3 318)4^^? .86 API. Z.\1

2378-TCDF* [304 306)

_2378-PeCDF^ (VO [342 340)

2378-RxCDF* [376 374). __

13C-1234678-HpCDF*** [422 420mS~?-frfl .^g (.O)

2378-HpCDFs r [410 408) _____

OCDF5 JVJL [442 444).

* - Ion used for quanitation ** - Quanitat ion based on 13C-1,2,3,4-TCDD * * * - Quanitat ion based on 13C-1,2,3,7,8,9-HxCDD

-4-^- Int Std 13C-2,3,1VLJflDD f\£k:e*< e ^ ' k M w a ^\ps£>p r2^^Tn^^d03C-J^rffl7^ . J „ J

4 -^ini""5M 13C^Yr7"#^^ *-<-^Int Std 13C-l,2.3,4,6T7T8*-HpCDF

NOTEi I f nore than one ratio i s required please write ratios directly on EICP.

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: INST ID: h f ^ ^ S CURVE/STDS: COMMENTS:

m_ DATE: ^la^lte^ INJ TIME: 4:30fl /w CLIENT ID: C a ^ a m g WDC 735 SAMPLE ID : 3% SAMPLE SIZE: «y

RT ION AREA ION AREA* AREA/ AREA* CONC RRF -ec

13C-1.2.3.4-TCDD 13C-2.3.7.8-TCDD

(332)(332)

(334) (334) i s :

.SO /.V7­

2.3.7.8-TCDD Total-TCDD 1,2.3.7.8-PeCDD Total-PeCDD 13C-1.2.3.7.8.9­

_A_JS A/ ft A/A A/O

(3 20)(320)(358)(358)

(3 22) (322) (356) (356)

HxCDD .33J3 (404) H_371 (402) J U k i S 13C-1.2.3.6.7,8­

HxCDD 31-73 (404) //S~05y (402) /*/«Vt»f ,71 447. .IT! x.x.2.3.7.8-HxCDD Total-HxCDD

A/O (392)(392)

(390) (390)

1.2.3.4.6.7,8 ­HpCDD A/O (426) (424)

Tot al-HpCDD (426) (424) JUL 13C-0CDD (470) (472) qq aw ,13 r?*>0 .755"

(458) (460) OCDD AID 13C-2.3.7.8-TCDF (316) (318) 1 ? 3 ^ g .%o <*o7~ "^73

(304) (306) 2.3.7.8-TCDF A/O (304) (306) Total-TCDF A/Q (342) (340) x,2.3.7,8-PeCDF A/L> (342) (340) Total-PeCDF MSL (376) (374) x.x.2.3.7.8-HxCDF MSL (376) (374) Total-HxCDF _A_XL

130-1.2,3.4,6,7,8­HpCDF 3H.3a (422) l.ygM (420) /<£<*&) / H CJ(?. (.67

x,x,x,2,3,7,8­HpCDF A/D (410) (408)

Total-HpCDF ML (410) (408) OCDF (442) (444)

*Ion used for quantitation.

Each cogener group has its own labeled standard for quantitation. NOTE :

f EP '- HfA

POSH 5 8TANDARD WORKSHEET DATE : %/2z/yer

INJ T I K E : t__j________ STD ID ; / V ^ ^ f ^ / ,

INST ID : n f tfliS

13C-1234-TCDD . (332)l_e^ ( 3 34)_ I ___2£_

13C-2378-TCDD**

2378-TCDDrf - < » < » (322)

12378-PeCDD^ (358) .(356) 13C-123789-HXCDD

-^2_J1 (404)1^^402) .MOMS' 13C-123678-HXCDD**/

- l L 2 _ i _ ( 4 0 4 , i _ _ _ ^ ( 4 0 2 , _ ^ ^ 2378-HxCDD*

—(392) ,(390) 1234 678-HpCDD* A/p _(426) (424) 13C-OCDD** *

OCDD* ^ <4S») ( 4 S 0 )

13C-2378-TCDF**

2378-TCDF* ; » • « , < 8 |3 t

_,2378-PeCDF*' (342) . (340)

, 2378-HxCDF8

__(376) .(374) 13C-1234 678-HpCDF*** 3£L_li (422)M__2(420) _1(t6<tZ

2378-HpCDF* .(410). . (408) OCDF 5

.(442). (444)

* - Ion used for quanitation ** - Quanitat ion based on 13C-1.2 3 4-Tenn

3 IntSJtd-,-T3C*©GQD i J_ J o ' 4 - ^ J n t S t d 1 i r . ? T > l f c « r n i 1^3 s^t-x X 5 J

NOTE . X / i c » . r . t h . B . . . r . t i 0 t . I n „ l M 4 s r u 4 _

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: DATE: V / / g 5

INST I D : t l f S ^ S INJ TIME: ic I t

CURVE/STDS: CLIENT I D : Ctz^enu? K V ^ f f l COMMENTS: SAMPLE I D : /V?6^c*v-C'r / f ­

SAMPLE SIZE: ^ S ~ ^ lo h t s » n

RT ION AREA ION AREA* AREA/AREA* CONC RRF _W

13C-1.2.3.4-TCDD 13C-2.3.7.8-TCDD

(332) (332)

/6&S36 (334) (334) 1? Z f t37

•SI .15" ^^7C ry?

2,3.7.8-TCDD A/O (3 20) (3 22) Total-TCDD A/D (320) (322) 1.2.3.7,8-PeCDD Total-PeCDD

J_0 (358) (358)

(356) (356)

1 3 0 - 1 . 2 , 3 , 7 . 8 . 9 -HxCDD (404) i S " ? (402) JteevSvy •

1 3 C - 1 . 2 , 3 , 6 . 7 , 8 -HxCDD

x.x,2.3,7,8-HxCDD Total-HxCDD . _vo_

A/O

(404) (392) (392)

(402) (390) (390)

is cm

1.2.3.4.6.7.8­HpCDD (426) (424)

Total-HpCDD 13C-0CDD OCDD

A/Q

Am

(426) (470) (458)

(424) (472) (460)

,'i6 ____________$"

13C-2.3.7.8-TCDF 2,3,7,8-TCDF Total-TCDF x.2,3.7,8-PeCDF Total-PeCDF x.x,2,3,7,8-HxCDF Total-HxCDF

_____ __J__

770 j \ _ 0 AHT

(316) (304) (304) (342) (342) (376) (376)

(318) (306) (306) (340) (340) (374) (374)

. so 3(7. ZJJ,

1 3 0 - 1 , 2 , 3 , 4 , 6 . 7 , 8 -HpCDF 3 t f , t < ( (422) (420) 7j_>_2_

x 9 x » x » 2 t 3 » 7 v 8 ~ HpCDF

Total-HpCDF OCDF

A/Q JZ£L

(410) (410) (442)

(408) (408) (444)

*Ion used f o r q u a n t i t a t i o n .

NOTE: Each cogener group has i t s own l abe l ed standard f o r q u a n t i t a t i o n .

re?--N/A

POM S STANDARD WORKSHEET

DATE INJ TIKE STD ID rviao ii COLUMN INST ID

I2& AREA ION ARJA* AREA/AREA* CONC RRF

13C-1234-TCDD 332) ( t m ( 3 3 4

13C-2378-TCDD** 332) ^ 7 3 r 3 3 4

2378-TCDD* 320) (322

12378-PeCDD* M2. 358) (356

13C-123789-HXCDD 4 0 4 ) / ^ W f 402 _1L 13C-123678-HxCDD**# 404)^957 (402 _ l i 577 .777

rv D2378-HxCDD* 392) (390

/VI) 1234678-HpCDD* 426) (424

13C-OCDD*** 470) ^ 6 3 1 (472

OCDDA MD 458) (460

13C-2378-TCDF** 22 SS 316)75^5 ( 3 1 8 ^ 6 &?7_^.i:

2378-TCDF^ Art) 304) (306

A/D_2378-PeCDF* 342) (340

2378-HxCDF^ 376) (374

13C-1234678-HpCDF*** 422)_C!___(420 <?3£7? rJ D2378-HpCDF* 410) (408

OCDF5 A/O 442) (444

* - Ion used for quanitation ** - Quanitat ion based on 13C-1,2,3,4-TCDD * * * - Quanitat ion based on 13C-l ,2 ,3 ,7 ,8 ,9-HxCDD

3 - I n t _ 2 8 ^ S £ S _ 3 c D p _ Kkc s cVS & < ^ J A TL-S 4

NOTBt Zf more than one ratio i s required please vrite ratios directly on EICP.

____

____

R A D I A N

FORM 6 SAMPLE WORKSHEET

DATE: COLUMN: £0 V\ftS" INST ID INJ TIME: / y L CURVE/STDS: CLIENT I D : C & ^ e m e A>'Snc€3£c COMMENTS: SAMPLE I D : f \ f i ( f r C t f -

SAMPLE SIZE: ISM<

RT ION AREA ION AREA* AREA/AREA* CQ_SC RRF .M.

13C-1.2.3.4-TCDD 3.3 5U (332) (334) i_02___ »1S 13C-2.3.7.8-TCDD ______ (332) (334) <yS7<, J.Y7 2,3.7,8-TCDD NO (3 20) (3 22) Total-TCDD MP (320) (322) 1.2.3.7.8-PeCDD _____ (358) (356) Total-PeCDD _____ (358) (356) 130-1,2.3,7.8.9­

HxCDD (404) d i m (402) iSlHSa. 13C-1.2.3.6.7.8­

HxCDD 3.--P (404) UWSt (402) _BL ___?_ m.x,x.2,3,7.8-HxCDD (392) (390) Total-HxCDD N~0 (392) (390) 1.2.3.4,6.7,8­

HpCDD A/D (426) (424) Tot al-HpCDD (426) (424) 13C-0CDD (470) (472) OCDD A/0 (458) (460) 13C-2.3.7.8-TCDF (316) (318) 3<__ 2,3,7,8-TCDF A/D (304) (306) Total-TCDF ____ (304) (306)

x,2,3.7,8-PeCDF A/0 (342) (340) (342) (340) Total-PeCDF _N/D (376) (374) x.x,2,3,7,8-HxCDF (376) (374) Total-HxCDF ____

13C-1.2,3.4.6,7,8­HpCDF (422) f s H l l (420) ^ 3 3 ^

8*™ 9 »7 2»3 x,x,x9

HpCDF (410) (408) Total-HpCDF ____ (410) (408) OCDF (442) (444) __J1

*Ion used for quantitation.

NOTE: Each cogener group has i t s own labeled standard for quantitation.

1EF--N/A

FORM 5 8TANDARD W0RJC8HE8T

DATE INJ TIKE STD ID COLUMN

%Ws«rrINST ID IfiM Aj__A ____ AREA* ARE A/ARE A* RRf

2L 13C-1234-TCDD [332

13C-2378-TCDD** [332 334) i4_,<*r l a g i

A/D 2378-TCDD* [320 322)

12378-PeCDD*' A/Q [358 356)

13C-123789-HXCDD [404 H13SX402) .SO

13C-123678-HXCDD**/ 31.7* [404 402) /a\7W7 /S6 fafifc - 7°1 2 3 7 8 - H X C D D / AID [392 390)

1234678-HpCDD^ [426 424) ' ­

13C-OCDD*** ^0-37 [470 >VQ7 472)<2a.<Sfc . t 6 4AS> 7S ­

OCDOF [458 460)

13C-2378-TCDF** [316 318)__£__L_1 • *1 6-Z 2,13 2378-TCDF^ A/0 [304 306)

2378-PeCDF^ [342 340)

2378-HxCDF A/D [376 374)

13C-1234678-HpCDF*** 30,o% [422 420)/36-/n _M7. IP1

2378-HpCDF1 [410 408)___

»OCDF A/D [442 444)

• - Ion used for quanitation «* - Quanitation based on 13C-1,2,3,4-TCDD ***- Quanitation based on 13C-1,2,3,7,8,9-HxCDD j . I • T "tol^Std 13C-2,3,7,8:_T£PBr Nt><\ ^ S L W C 2 - I n t ^ t T S ^ ^ l ^ ^

4 -^r^l3C-2,3,7T8>WiL_ X 5

•TOO* - Int Std 13C-l,2,3,4,6,7,8-Hp7

NOTIt I f aore than one ratio i s required please vrite ratios directly on EICP.

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: INST ID: CURVE/STDS: COMMENTS:

DATE: INJ TIME: 335" CLIENT ID: ______]______» £1SAMPLE ID: ^ Q ' s O H ^ S m SAMPLE SIZE: 3.S.5 -y

RT ION AREA ION AREA* AREA/AREA* RRF

.0

13C-1.2.3.4-TCDD 13C-2.3.7.8-TCDD 2,3,7,8-TCDD Total-TCDD 1.2.3,7.8-PeCDD Total-PeCDD 130-1.2,3.7,8.9 ­

HxCDD 130-1,2,3.6.7.8-

HxCDD x,x.2,3.7.8-HxCDD Total-HxCDD 1.2.3.4.6.7,8­

HpCDD Total-HpCDD 13C-0CDD OCDD 13C-2.3.7.8-TCDF 2.3.7.8-TCDF Total-TCDF x.2.3.7.8-PeCDF Total-PeCDF x.x,2.3.7.8-HxCDF Total-HxCDF 13C-1.2.3.4.6.7.8­

HpCDF

_A_Q __Vfl

_____

______

ATP

A/Q

A/Q A/0

_V£ __/_X _A_1_

3 6 .

(332) if&m (33 2) iyiy<S" (3 20) (320) (358) (358)

(404) J W E L

(404) g)Q57^(392)(392)

(426)(426)(470)(458)(316) aiU3C1(304)(304)(342)(342)(376)(376) :

(422) m i O l

(334) (334) (3 22) (322) (356) (356)

(402)

(402) (390) (390)

(424) (424) (472) (460)

(318) (306) (306) (340) (340) (374)

(374)

(420)

/so i s :

/? .3 t t .S6

!________ .26

Ii__f_____~__L

flS-MS

437,­ /.V7

£D7. .177

(oCT7. .1SS

x f x » x 2 | 3 » 7 8~ t a

HpCDF A/D (410) (408) Total-HpCDF (410) (408) OCDF A7O (442) (444)

*Ion used f o r quan t i t a t ion .

NOTE: Each cogener group has i t s own labeled standard f o r quan t i t a t ion .

DATE ^bjl'g* IMJ TIME;"3T53>' STD ID : rO$PG fc.65_ COLUMN :___T___DJ_]51 INST ID : nP.<rq 5r A%()%Ofl'6lA OOP

13C-1234-TCDD

13C-237S-TCDD**

2378-TCDD*

12378-PeCDD-?

13C-123789-HXCDD

13C-123678-HXCDD**/

2378-HxCDD^

1234678-HpCDD^

13C-OCDD***

OCDD*

13C-2378-TCDF**

2378-TCDF*

2378-PeCDF1

2378-HxCDF

13C-1234678-HpCDF***

2378-HpCDF*

JOCDF

POEM S STANDARD WORKSHEET

_Oj_ AREA

332) /YV /7V

332)(30____L 320)

AJD 358)

3 2.11 404) 13^/6

31.73 404) ^ I 0 (

A/O 392)

A/D 426) •

470)<<<_y>l

A/l_ 458)

316) /16478

___a 304)

342)

A/Q 376)

S_(_S3 422)//%E&

A/0 410)

A/O 442)

7. £er.5vrr

ISM AR£A1 AREA/APFA* CONC E££

34)/7So7_

34) /S33»V1

22)

56)

Q2)/7.<5>76 /al

02) 111011 ttf> fin 90)

24)

72) 3% HI *t! 447. .75TS 60)

18)__lfa___

06).

40).

74).

20) USSoa .13 t jR 1.07

08).

44).

* - Ion used for quanitation *• - Quanitation based on 13C-1,2,3,4-TCDD ***- Quanitation based on 13C-1,2,3,7,8,9-HxCDD

NOTlt I f aore than one ratio i s required please vrite ratios directly on EICP.

_____

____

_______

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: 10 flfiS" INST ID:" CURVE/STDS: COMMENTS:

13C-1.2.3.4-TCDD 13C-2.3.7.8-TCDD 2.3.7,8-TCDD Total-TCDD 1.2,3.7.8-PeCDD Total-PeCDD 13C-1.2.3.7.8.9­

HxCDD 13C-1.2.3.6.7.8­

HxCDD x.x.2.3.7.8-HxCDD Total-HxCDD 1 . 2 . 3 . 4 . 6 , 7 . 8 ­

HpCDD Total-HpCDD 13C-0CDD OCDD 13C-2.3.7.8-TCDF 2.3.7.8-TCDF Total-TCDF x,2,3,7.8-PeCDF Total-PeCDF x.x,2.3.7.8-HxCDF Total-HxCDF 130-1 .2 ,3 .4 ,6 .7 .8 ­

HpCDF x , x , x , 2 . 3 . 7 , 8 ­

HpCDF Total-HpCDF OCDF

DATE: INJ TIME: 3-*"-"*• CLIENT ID: •v_mg A/366 SAMPLE ID: Y"sQ<«p_"l~0/A DU ^ SAMPLE SIZE: 3,5*.Z - y

AREA* AREA/AREA* CONC RRF J _

—

/7_77fe .^1

mem /&» 47 > .m

_1L

i.e.? (420) lasiog. f\\

RT

AJO A/O /V l j

3 2 . \ l

^ 1.73

/VP

jVp_

77o _A__L

A>0 7V7D

3H.33

ION AREA

(332) mm (332) /__S(Vfe (3 20) (320) (358) _ _ _ (358)

(404)

(404) (392) (392)

(426) (426) (470) ^63 f l / (458) (3i6) no(n% (304) (304) (342) (342) (376) (376) :

(422) n%a_&(410) (408) (410) (408) (442) (444)

ION

(334) (334) (3 22) (322) (356) (356)

(402)

(402) (390) (390)

(424) (424) (472) (460) (318) (306) (306) (340) (340) (374) (3 74)

*Ion used for quantitation.

NOTE: Each cogener group has its own labeled standard for quantitation.

DATE r S c t o / g * INJ TIKE STD ID COLUMN INST ID

13C-1234-TCDD

13C-2378-TCDD**

2378-TCDCr 1

12378-PeCDD^

13C-123789-HXCDD

13C-123678-HxCDD* * /

2378-HxCDC^

1234678-HpCDC-f

13C-OCDD***

OCDD^

13C-2378-TCDF**

2378-TCDF^

_2378-PeCDF0

2378-HxCDF^

13C-1234678-HpCDF***

2378-HpCDF^

OCDF*

FORM S STANDARD WORKS HE BT

Ipj. AR___ ____ AREA* AREA/AREA* CONC

32)/W?g 34^/67» .ftp 32)<__2f___T(

34.^35?2 to yfL IS*

20) 22) . _

58) 5 6 ) _ _

04)ISSTO .n .or 04)/WV? oa.fflao a f t ;_.o&

NO 92) 90)

A/0 26) 24)

70) //3ff* 72)7^3 «to lf% 75T 58). 60)_

18). 53323 04) 06).

A/D 42) 40).

A/O 76) 74).

20) /aftSffi j g *A Lcs /VP 10) 08)

A/D 42) 44)

* - Ion used for quanitation ** - Quanitation based on 130-1,2,3,4-TCDD ***- Quanitation based on 13C-l,2,3,7,8,9-HxCDD

A/ote: E^o> cozener <-ybup ,7,8-HxCDD

NOTE* I f more than one ratio is required please write ratios directly on EICP.

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: 4Q rvv M S " DATE: INST ID: INJ TIME: f--5"7 CURVE/STDS: CLIENT ID: Cgwwut? J"fe0-_«tS COMMENTS: SAMPLE ID: -£VH

SAMPLE SIZE: ^ ' S y

RT ION AREA ION AREA* AREA/AREA* CONC RRF StT

% 6 13C-1.2.3.4-TCDD (332) l ^ T P f t (334) 1H I 0?<i 13C-2.3.7.8-TCDD ^LH .oo (332) J g y f f t - (334) 2,3.7,8-TCDD A/P (3 20) (3 22) Total-TCDD _i_J_ (320) (322) 1,2.3,7.8-PeCDD AT D (358) (356) Total-PeCDD (358) (356) M0_13C-1 .2 .3 .7 .8 .9 ­

HxCDD •_2.o_r (404) I ftSTW (402) 1 3 ^ 4 . I T 1 3 C - 1 . 2 . 3 , 6 . 7 , 8 ­

HxCDD (404) i H C W * (402) x,x.2,3,7.8-HxCDD Art> (392) (390) Total-HxCDD A D (392) (390) 1,2.3,4,6.7.8­

HpCDD A/D (426) (424) Total-HpCDD (426) (424) MSL 13C-0CDD (470) (472) ZLIH3 OCDD (458) (460) 13C-2.3.7.8-TCDF 2-3 ^sr (316) 367o?f? (318) 2,3,7,8-TCDF A/D (304) (306) Total-TCDF (304) (306) MSL x,2,3,7,8-PeCDF A/Q (342) (340) Total-PeCDF A/D (342) (340)

(376) (374) x,x,2,3,7,8-HxCDF (376) (374) Total-HxCDF

130-1,2.3.4.6.7.8­HpCDF 3 f . « U (422) n/i3S- (420) .a<_3<f« .«?3

x9xx»2»3 »7 8*~ t

HpCDF 9

A^D (410) (408) Total-HpCDF (410) (408) OCDF _____ (442) (444)

*Ion used f o r q u a n t i t a t i o n .

NOTE: Each cogener group has i t s own l abe l ed standard f o r q u a n t i t a t i o n .

POSM 5

DATE -I-Ufa INJ TIKE 2 X 5fct f>~\ STD ID A C U - - / *"­COLUMN INST ID

13C-1234-TCDD

13C-2378-TCDD**

2378-TCDD*

12378-PeCDD*

13C-123789-HXCDD

13C-123678-HXCDD**/

2378-HXCDD*

1234678-HpCDD*

13C-OCDD***

OCDO^

13C-2378-TCDF**

2378-TCDF^

_2378-PeCDF5*>

__2378-HxCDF^

13C-1234678-HpCDF***

2378-HpCDF*

OCDF

STANDARD WORKSHEET

7c

SCAMt'c I S * AREJ. ipji AREA* AREA/APEA* CONC RR£

^ • S ^ T (332) / ^ 2 y f 3341 2l?7g3 . _r£>

(332)^15177(334) /^23ft „7i ^ 7 . ^ T V

^ £ i l _ _ ( 3 2 0 ) (322)

/ V P .(358) (356).

33 .6V (404)__7_____(402) ^^^51 .

3 L&, (404)__T__£ (402) No WO .grj> f.6(,

M b (3921 (390)

(426) (424)

H b . l b (470) 4/&VO (472' 4^ygi _____ V/T. nss _ - J £ _ ^ _ _ ( 4 5 8 ) (460)

^ 3 . V 5 (3i6) /SPVfo (318) /*6 ZV0 2-/7

_yjL__(304) (306) A/0 _(342) (340)

A/ft _(376) . (374)

(422) (QQ Zc (420. .O^FCfl /} __ V ? % / . o r

___3£J2___(410) (408)__

/ V P (442) (444)

* - Ion used for quanitation *e - Quanitation based on 13C-1,2,3,4-TCDD

Quanitation based on 130-1,2,3,7,8,9-11x000

NOTE t I f more than one ratio i s required please write ratios directly on EICP*

____

R A D I A N

FORM 6 SAMPLE WORKSHEET

COLUMN: 4 0 ^ jM^*-" DATE INJ TIME: INST I D : M f S ^ ^ t ) CLIENT I D : Ce^^erug ^ t ^ ' / " ­CURVE/STDS: SAMPLE I D : A%Cf|_n-C_*/!)COMMENTS: SAMPLE SIZE: ,3,5.H^V

RT ION AREA ION AREA* AREA/AREA* (X JC RRF »fc

13C-1.2.3.4-TCDD (332) _/_______/ (334) aatrm ^ ­13C-2.3.7.8-TCDD (332) (334) 2.3.7.8-TCDD A/O (3 20) (3 22) Total-TCDD _ _ _ _ _ _ _ (320) (322) 1.2,3.7,8-PeCDD _ _ _ _ _ _ _ (358) (356) Total-PeCDD A/D (358) (356) 13C-1 .2 .3 .7 .8 .9 ­

HxCDD Z9.0H (404) _^_7_y (4 0 2> aa^gs'­1 3 C - 1 . 2 . 3 . 6 . 7 . 8 ­

HxCDD 31- 4C (404) <?flPV3 (402) //cW7 .fro V . ^ f. 0 . x,x.2.3,7,8-HxCDD (392) (390) ML Total-HxCDD A/D (392) (390) 1.2,3.4.6.7.8­

HpCDD A/I. (426) (424)

Tot al-HpCDD (426) (424) (472) 13C-0CDD (470) _£___

OCDD A/D (458) (460)

13C-2.3.7.8-TCDF (316) / S C V _ Q (318) /<k£.T7V .*Q 3T7. X ~ ________L (306) 2.3.7.8-TCDF A/D (304) Total-TCDF (304) (306)

(340) x.2.3.7.8-PeCDF (342) (340) Total-PeCDF ALO. (342)

x.x,2.3.7,8-HxCDF WD (376) (374) (374) Total-HxCDF A/D (376)

13C-1 ,2 ,3 .4 .6 ,7 .8 ­HpCDF 3H.^H (422) /OO^LO (420) / . ^ . V t 3 V97> /•OS'

x , x . x , 2 . 3 . 7 , 8 ­HpCDF (410) (408)

Total-HpCDF (410) (408) OCDF A/ft (442) (444)

*Ion used for quantitation.

NOTE: Each cogener group has its own labeled standard for quantitation.

_ _ _ _ _ _ _ _

POM S STANDARD W0RX8BEIT

DATE :____2____ INJ TIME STD ID COLUMN i__L__ INST ID

ft-, 13C-1234-TCDD

fry 13C-2378-TCDD**

2378-TCDD*

12378-PeCDD*

;S*-j 13C-123789-HXCDD

JT^ 13C-123678-HXCDD**/

2378-HxCDD*

1234678-HpCD_*

&*K 13C-OCDD***

OCD

fry 13C-2378-TCDF**

2378-TCD

_2378-PeCDF<

2378-HxCDF' 4 S"„v>13C-1234678-HpCDF-**

2378-HpCDF^

OCDF^

A/D A/0

3 I/ft __j_J_2_

A D

HC>.H

MA

HO Mb

ISH AREA

(332

(332

(320

(358

(404

(404 > _ _ .

(392

(426

(470 / _ _

(458 _Z_Q_ (316

(304

(342

(376

(422

(410

(442 _ _ _

12M _£__i_ AREA/AREA* CONC RRF

34)364-3 -76 <g_ /.5V

22)

56)

02)_34ll6 .77 //V2 /.Ofc

90)

24)

AO °\n. .7ST 60)7°(Vt/^ .1 J I .V Y.ossr

18) HtoSHZ ^ <ft?_ ^ f l

06)

40) 4.S* 74)

20) i. or

08)

44) 33</J0% .13 A3

* - Ion used for quanitation ** - Quanitat ion based on 13C-1,2,3,4-TCDD * * * . Quanitat ion based on 13C-1,2,3,7,8,9-HxCDD

Zf more than one ratio i s required please write ratios directly on NOTES EICP.

J

R A D I A N

FORM 6 SAMPLE WORKSHEET

DATE: ^ t o l f f gCOLUMN: 4 0 ^ INJ TIME: %'.%Hfi<^INST ID: t H ? - ? ^ ^ CLIENT ID: c l ^ ^ ^ ^ CCURVE/STDS: SAMPLE ID: M__________vTCOMMENTS: SAMPLE SIZE: JST.V *

r.ioOJL RT ION AREA ION AREA* AREA/AREA* CONCONCC RRF ?C

SS*K 13C-1.2.3.4-TCDD (332) ftlHyi (334) S U 13C-2.3.7.8-TCDD (332) -2U (334)

2.3.7.8-TCDD NO (3 20) (3 22) Total-TCDD (320) (322) 1.2.3.7.8-PeCDD (358) (356) Total-PeCDD A/Q (358) (356)

J S K 130-1.2,3.7.8,9 ­• HxCDD 3l.*fl (404) <<\U*< (402) _m %_3i / f l

i V v 130-1.2.3.6.7.8 ­HxCDD (404) _feQ_l> (402) _3-L

x.x.2.3,7.8-HxCDD A/6 (392) (390) Total-HxCDD (392) ">W_t> (390) q/S5C *>.- '.0S~ 1.2.3.4.6.7.8­

HpCDD (426) (424) _ Tot al-HpCDD ~ . S" (426) (424) 12 TJVL

S«\ 13C-0CDD V 6 . / V (470) /vai- (472)

* OCDD d./y (458) (460) S"*\ 13C-2.3.7.8-TCDF 3.Ml (316) _ _ _ _ _ _ (318) 9 & 7.

(306) <ri.2,3.7,8-TCDF (304) (304) (306)Total-TCDF _LJ(342) (340)x,2.3,7.8-PeCDF (342) (340)Total-PeCDF ~-2*"? iO /.27_

x,x.2,3,7,8-HxCDF (376) (374) _______zz___z (376) (3 74) -1^

Total-HxCDF .9 I 1<=\ddHO !_m___Z_____3 „ 130-1.2.3.4.6.7,8 ­0

s

HpCDF (422) n .vo (420) abus* M t.-s x , x , x , 2 , 3 , 7 , 8 ­

HpCDF — (410) (408) Total-HpCDF <~ 3W.T (410) V XoWO (408) 6

A3 <JQ6_OCDF W6/f6 (442) ______aL (444) __L____0_ 3V *Ion used for quantitation.

NOTE: Each cogener group has its own labeled standard for quantitation.

orvnn

DATE INJ TIKE STD ID COLUMN INST ID

13C-1234-TCDD

13C-2378-TCDD**

2378-TCDD?

12378-PeCD_£

13C-123789-HXCDD

13C-123678-HXCDD**/

__2378-HxCDD#

1234678-HpCDl£

13C-OCDD***

OCD£_f

13C-2378-TCDF**

2378-TCDP*

_2378-PeCDfc f >

2378-HxCDF^

13C-1234678-HpCDF-**

2378-HpCDf-*

OCDF5

POSH S STANDARD WORKSHEET

7,

I _ _ AR__ IPJJ AREA* AREA/AREA* CONC Rf_

o23^Q (332) /S^^334l/q/-g? ­

J?^>^5 1332)1 Mil/ f-334Wfr?<SH

A/T) (320) (322)

A / 0 *358) (356)

( 4 0 4 ) ^ / 1 ( 4 0 2 ) 2 / 6 ^

3 ^ (404)__??/¥(402)////1rr

_ _ _ _ _ _ _ _ ( 3 9 2 ) (390)

(426) (424)

ft/ft ( 4 7 0 ) ^ ^ ( 4 7 2 ) 1 ^ ^ 1

^ (458) (460).

_ _ _ _ _ _ _ _ _ ( 3 1 6 ) J 2 ^

A f ^ (304) (306)

_ _ _ _ j _ _ _ ( 3 4 2 ) (340)

Ml .(376). .(374)

. 3 ^ —

,^7 <A7 / CV

. ^ O

fbO ( A

3 3 ^ 3 % fl£

65"

* - Ion used for quanitation ** - Quanitation based on 13C-1,2,3,4-TCDD ***- Quanitation based on 130-1,2,3,7,8,9-11x000

,6,7,8-HxCDD Moire'. E^o^K £&*e*\ec

NOTEi Zf mors than one ratio is required please write ratios directly on 1EICP.

2^1* ti22) I03S7O (420) 1 1 A 5 ~ f.__________ (410) (408)

A/Q (442) ( 4 4 4 ) _

R A D I A N

COLUMN: INST I D : CURVE/STDS: COMMENTS:

40 ^

FORM 6 SAMPLE WORKSHEET

DATE: INJ TIME: "?5><^ CLIENT ID: Ca.yA_>n11? f * Ytf SAMPLE ID: /t"y_)frQ/^-<Q?^ SAMPLE SIZE: ZS. 1 y

RT ION AREA ION AREA* AREA/AREA* C0N.C RRF _*T

13C-1,2,3.4-TCDD 13C-2.3.7.8-TCDD 2,3.7,8-TCDD Total-TCDD 1,2.3,7.8-PeCDD Total-PeCDD 13C-1.2.3.7.8.9­

HxCDD 13C-1.2.3.6.7.8­

HxCDD x,x,2.3.7,8-HxCDD Total-HxCDD 1.2,3.4.6,7,8­

HpCDD Total-HpCDD 13C-0CDD OCDD 13C-2.3.7.8-TCDF 2.3.7,8-TCDF Total-TCDF x,2,3,7.8-PeCDF Total-PeCDF x,x,2,3,7,8-HxCDF Total-HxCDF 13C-1.2,3,4,6,7,8­

HpCDF x9x,x92»3 17 _8~"

HpCDF Total-HpCDF OCDF

ATQ

A/Q _____

3 AO)

_____

_____ _______

3 3- Ho A/P ______

/VP A/Q

/ \ f _>

______ _____

3*.^**

(332) (332) (3 20) (320) (358) (358)

(334) (334) (3 22) (322) (356) (356)

(404) U S ^ d (402)

(404) vnf*< (392) _ (392)

(426) (426) (470) (458) (316) (304) (304) (342) (342) (376) (376)

_ _ _ _ _

Z___4

(402) (390) (390)

(424) (424) (472) (460) (318) (306) (306) (340) (340) (374) (374)

(422) 10 3S/0 (420)

(410) (410) (442)

(408) (408) (444)

%2> S6?. ST

? | Qfr£4 , SO

STS?, LOG

______ __5_T

_I_______T ___2_____L-tf

I IOf- feL _l_r 2_2___L_*

*Ion used for quantitation.

NOTE: Each cogener group has i t s own labeled standard for quantitation.

TF.F--A//A

R A D I A N

FORM 7 QUALITY CONTROL REPORT

CASE NO. SITE EPA SAMPLE ID. N270 E300

MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS

>39000 >39001 A808019-02A-MS A808019-02A-MSD

Compound Sample Spike MS MS Spike MSD MSD Cone. Added %Rec Added Cone. %Rec.

MS Cone, MSD (units) ng/g ng ng ng

ng

TCDD ND 50 46 92 50 41.5 83

PeCDD ND 50 46 92 50 42 84

HxCDD ND 50 51 102 50 46 92

HpCDD ND

OCDD ND

TCDF ND 50 46 92 50 40 80

PeCDF ND 50 48 96 50 42 84

HxCDF ND 50 59 117 50 53 106

ND = Not detected.