34
By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep.

Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

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Page 1: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

By

Mo

ha

mm

ed

S S

ale

em

Sa

ud

i E

lect

rici

ty C

om

pa

ny /

EO

A

Ge

ne

rati

on

Te

chn

ica

l su

pp

ort

De

p.

Page 2: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Co

nte

nts

Intr

od

uct

ion

�W

hat

is

Sca

le E

xfo

liat

ion

�S

cale

Gen

erat

ion

�S

cale

Exf

oli

atio

n M

ech

anis

m

�S

cale

Acc

um

ula

tio

n

�S

cale

Acc

um

ula

tio

n m

on

ito

rin

g

�S

cale

exf

oli

atio

ns

Dam

ages

�M

easu

res

to b

e ta

ken

wh

en s

cale

exf

oli

atio

n

Occ

ur

�Q

PP

Exf

oli

atio

n P

rob

lem

s

�C

on

clu

sio

n

Page 3: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Intr

od

uct

ion

QP

P h

ad e

xper

ien

ced

tu

be

fail

ure

s in

th

e 2r

ySH

, 3r

ySH

an

d

2ryR

H a

nd

ou

tlet

leg

th

at i

s at

trib

ute

d t

o t

ub

e ex

tern

al

exfo

liat

ion

.

� �T

he

ori

gin

of

the

pro

ble

m i

n b

oth

3ry

SH

an

d 2

ryR

H i

s d

ue

to

hig

her

th

an e

xpec

ted

tu

be

met

al t

emp

erat

ure

. T

he

2ryS

H

pro

ble

m i

s at

trib

ute

d t

o u

nco

ntr

oll

ed d

esu

per

hea

ter

spra

y d

uri

ng

sta

rt-u

p.

�U

nd

er c

erta

in c

on

dit

ion

s, o

xid

e sc

ale

that

fo

rms

on

th

e o

ut

sid

ean

d i

nsi

de

surf

aces

of

sup

erh

eate

rtu

bes

an

d p

ipes

may

bre

ak

loo

se a

nd

exf

oli

ates

. I

t al

so s

usp

ecte

d t

hat

an

exc

essi

ve i

nte

rnal

o

xid

e sc

ale

exfo

liat

ion

wh

ich

cau

se c

om

ple

te o

r p

arti

al p

lugg

ing

of

the

stea

m f

low

pat

h.

Page 4: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Wh

at

is S

cale

Exf

oli

ati

on

�H

igh

tem

per

atu

re s

team

rea

cts

wit

h i

nte

rnal

met

al

surf

aces

to

fo

rm a

har

d t

enac

iou

s sc

ale.

�sc

ale

gro

wth

rat

e is

a f

un

ctio

n o

f m

ater

ial

of

con

stru

ctio

n,

tem

per

atu

re,

un

it s

tart

-up

an

d s

hu

tdo

wn

cyc

les.

�B

ecau

se o

f th

e d

iffe

ren

ce o

f co

effi

cien

ts o

f th

erm

al

exp

ansi

on

, ex

pan

sio

n a

nd

co

ntr

acti

on

du

rin

g s

tart

-up

s lo

ose

ns

the

scal

e ca

usi

ng

it

to e

xfo

liat

e (f

lak

es)

�T

he

exfo

liat

ion

pro

cess

is

a m

ech

anic

al p

roce

ss a

nd

du

e o

f so

me

stre

ss e

ffec

t

Page 5: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Sca

le G

en

era

tio

n

�A

fter

sta

rtin

g th

e b

oil

er o

per

atio

n ,

oxi

des

sca

les

gen

erat

es a

nd

sta

rt g

row

ing

�H

2O+

2e-

H2

+O

2-

�F

e++

+ O

2-F

e Y

O

�O

ute

r la

yer

is g

ener

ated

by

the

dif

fusi

on

of

Fe+

+ t

o

stea

m s

ide

(mag

net

ite

(Fe3

O4

) a

nd

hem

atit

e (F

e2O

3)

�In

ner

lay

er i

s ge

ner

ated

by

the

dif

fusi

on

of

O2-

mag

net

ite

, hem

atit

e an

d o

ther

ch

emic

al e

lem

ents

w

hic

h a

re i

ngr

edie

nts

of

ori

gin

al m

ater

ial.

Page 6: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Sca

le E

xfo

lia

tio

n M

ech

an

ism

�T

her

e is

no

str

ess

and

no

cra

ck i

n s

cale

du

rin

g b

oil

er o

per

atio

n.

�B

oil

er s

hu

t-d

ow

n a

nd

sta

rt-u

p ,t

her

mal

str

ess

aris

e at

th

e sc

ale

–met

al b

ou

nd

ary

du

e to

th

e d

iffe

ren

ce o

f th

erm

al e

xpan

sio

n c

oef

fici

ent

bet

wee

n s

cale

an

d m

etal

.

�sc

ale

is t

hin

an

d f

ragi

le t

he

ther

mal

str

ess

mak

es

crac

ks

on

ly i

n t

he

scal

e.

�n

um

ber

/si

ze o

f th

e cr

ack

s an

d o

ther

par

amet

ers

infl

uen

ce o

n t

he

adh

eren

ce f

orc

e o

f sc

ale

�sc

ale

exfo

liat

ion

wil

l ta

ke

pla

ce a

fter

man

y th

ou

san

ds

of

ho

urs

of

serv

ices

Page 7: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Sca

le e

xfo

lia

tio

n p

roce

ss p

ara

me

ters

Page 8: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Sca

le A

ccu

mu

lati

on

�S

cale

acc

um

ula

tio

n s

eem

s ra

nd

om

exc

ept

un

der

th

e co

nd

itio

n t

hat

th

ere

are

som

e te

chn

ical

/d

esig

n r

easo

ns

.

�M

ajo

rity

of

scal

e ac

cum

ula

tio

ns

hap

pen

at

the

bo

un

dar

y o

f in

ner

/ou

ter

laye

rs

�N

ew s

cale

gen

erat

ion

sta

rts

on

fre

sh s

urf

aces

aft

er

nex

t st

art

–up

.

Page 9: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Par

amet

ers

of s

cale

acc

umul

atio

n ar

e su

mm

ariz

ed in

the

fo

llow

ing

tabl

e

Page 10: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Sca

le A

ccu

mu

lati

on

mo

nit

ori

ng

�T

her

e ar

e m

ore

th

an o

ne

way

to

mo

nit

or

the

scal

e ac

cum

ula

tio

n r

eco

mm

end

ed :

•U

ltra

son

ic T

hic

kn

ess

exam

inat

ion

by

EM

AT

S

(Ele

ctro

mag

net

ic A

cou

stic

Tra

nsd

uce

r S

yste

m)

•In

eve

ry o

uta

ge

at l

east

10

% O

f th

e S

H/R

H s

ho

uld

R

T (

X-r

ay)

Insp

ecte

d t

o t

he

tren

d o

f sc

ale

Page 11: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Da

ma

ge

s e

xfo

lia

tio

ns

Sca

le

�20

-30

% o

fsc

ales

are

exf

oli

ated

in

on

e sh

ut

do

wn

an

d s

tart

-up

pro

cess

, p

oss

ibil

ity

of

com

ple

te

plu

ggin

g sh

ou

ld b

e co

nsi

der

ed.

�It

can

cau

se l

on

g te

rm o

verh

eati

ng

and

cre

ep

dam

age

�It

can

cau

se l

on

g te

rm o

verh

eati

ng

�F

ire

sid

e co

rro

sio

n b

ecau

se o

f h

igh

er t

ub

e te

mp

erat

ure

.

�In

cas

e o

fR

H t

his

fla

kin

g p

arti

cles

may

go

th

rou

gh t

o i

nte

rmed

iate

tu

rbin

e an

d d

amag

eth

e b

lad

es

Page 12: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Me

asu

res

to b

e t

ak

en

wh

en

sca

le

exf

oli

ati

on

Occ

ur

�T

he

bo

iler

can

be

sub

ject

ed t

o p

urg

ing

op

erat

ion

to

get

re

d o

f th

e sc

ale

flak

es d

uri

ng

th

e sh

ut-

do

wn

per

iod

.

�If

sca

le a

ccu

mu

lati

on

rat

io o

ver

50%

tu

bes

sho

uld

be

clea

ned

ou

t b

y m

ech

anic

al m

ean

s (B

end

tu

bes

to

be

rem

ove

d t

emp

ora

lly

and

rei

nst

alle

d).

�U

pg

rad

e th

e m

ater

ial

to S

A-2

13 T

P34

7FH

G w

ith

sh

ot

pee

nin

gto

res

ist

inte

rnal

sca

le e

xfo

liat

ion

Page 13: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

QP

P E

xfo

lia

tio

n P

rob

lem

s

�Q

PP

Bo

iler

Sp

ecif

icat

ion

�In

199

4,

Qu

rayy

ahP

ow

er P

lan

t U

nit

2 h

ad e

xper

ien

ced

p

rem

atu

re t

ub

e fa

ilu

res

in t

he

3ryS

H a

nd

2ry

RH

o

utl

et l

eg t

hat

is

attr

ibu

ted

to

tu

be

exte

rnal

ex

foli

atio

n

�T

he

ori

gin

of

the

pro

ble

m i

n b

oth

3ry

SH

an

d 2

ryR

H i

s d

ue

to h

igh

er t

han

exp

ecte

d t

ub

e m

etal

tem

per

atu

re

�In

20

02

un

it-4

QP

P h

ad e

xper

ien

ced

tu

be

fail

ure

s in

th

e 2r

ySH

, at

trib

ute

d t

o t

ub

e ex

tern

al e

xfo

liat

ion

.d

esu

per

hea

ter

spra

y d

uri

ng

sta

rt-u

p.

�A

ug

ust

20

07

, fi

rst

tub

e fa

ilu

re w

as e

xper

ien

ced

at

un

it-3

2r

yRH

an

d o

utl

et l

eg t

hat

is

attr

ibu

ted

to

tu

be

exte

rnal

exf

oli

atio

n.

Page 14: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation
Page 15: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Lap

an

aly

sis

rep

ort

Page 16: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

QP

P E

xfo

lia

tio

n P

rob

lem

s

Page 17: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation
Page 18: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation
Page 19: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation
Page 20: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Co

ncl

usi

on

�S

cale

exf

oli

atio

n c

an b

e a

very

ser

iou

s p

rob

lem

if

no

t m

on

ito

red

.

�M

ain

ten

ance

pro

gra

m s

ho

uld

in

clu

de

a sc

hed

ule

fo

r m

on

ito

rin

g t

he

scal

e ac

cum

ula

tio

n i

n t

he

bo

iler

tu

bes

sp

ecia

lly

for

tho

se b

oil

ers

wo

rkin

g c

on

scio

usl

y o

n

hig

h l

oad

.

�C

lose

mo

nit

ori

ng

to

th

e b

oil

er p

erfo

rman

ce m

ay g

ive

a h

igh

in

dic

atio

n o

f sc

ale

accu

mu

lati

on

rat

e.

�A

flu

shin

g p

roce

du

re s

ho

uld

be

ado

pte

d b

y th

e o

per

atio

n i

n o

rder

to

cle

an t

he

tub

es f

rom

th

e ac

cum

ula

ted

sca

le

Page 21: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation
Page 22: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

�T

he

ou

ter

laye

r is

gen

erat

ed b

y th

e d

iffu

sio

n o

f F

e++

to

the

stea

m s

ide

and

in

ner

gen

erat

ed b

y th

e d

iffu

sio

n o

f

O2-

to t

he

met

al S

ide.

�O

ute

r sc

ale

con

sist

s o

f m

agn

etit

e (F

e3O

4)

and

hem

atit

e

(Fe2

O3)

.

�In

ner

sca

le c

on

sist

s o

f m

agn

etit

e (F

e3O

4)

and

hem

atit

e

(Fe2

O3)

an

d o

ther

ch

emic

al e

lem

ents

wh

ich

are

in

gred

ien

ts o

f o

rigi

nal

mat

eria

l.

Page 23: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

�S

team

sid

e S

cale

exf

oli

atio

n i

n s

team

pla

nts

is

a ve

ry

seve

r p

rob

lem

wh

ish

can

res

ult

s in

sh

ort

-te

rm

ove

rhea

tin

g b

oil

er t

ub

e fa

ilu

res.

�In

ad

dit

ion

th

e so

lid

par

ticl

es c

an c

ause

th

e so

lid

p

arti

cle

ero

sio

n o

f th

e in

let

stag

es o

f th

e st

eam

tu

rbin

es(

inte

rmed

iate

tu

rbin

e st

ages

)

Page 24: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

Acc

um

ula

tio

n R

ate

Page 25: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation
Page 26: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

�In

sca

le w

hic

h h

as g

row

n b

eyo

nd

a c

erta

in t

hic

kn

ess,

th

e o

ute

r la

yer

exfo

liat

es d

ue

to t

he

dif

fere

nce

in

th

erm

al e

xpan

sio

n b

etw

een

th

e tu

be

mat

eria

l an

d t

he

scal

e d

uri

ng

sta

rt a

nd

sto

p o

f th

e b

oil

er

Page 27: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

rate

Page 28: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

pe

en

ing

Ma

teri

al

Up

gra

de

an

d s

ho

t

Page 29: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

QP

P F

ail

ure

Page 30: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

QP

P T

ub

e

fail

ur

Page 31: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

QP

P F

ail

ure

Page 32: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

QP

P 2

YR

h A

nd

3ry

SH

Page 33: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

U3

IP

tu

rbin

e b

lad

es

Gh

azl

an

de

po

sits

Page 34: Mohammed S Saleem Saudi Electricity Company /EOA ... · By Mohammed S Saleem Saudi Electricity Company /EOA Generation Technical support Dep. Contents Introduction What is Scale Exfoliation

U3

IP

tu

rbin

e b

lad

es

Gh

azl

an

da

ma

ge

s