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MnO2 Resin: Concentration of Radium Isotopes
Deok-Soo MoonBill Burnett
Department of OceanographyFlorida State University
Tallahassee, Florida
Applications in Oceanography
Mixing rates between near-shore and offshore waters
Assessment of submarine groundwater discharge
Collection/Processing
“Mn- fiber” concentrates radium: count 223/224Ra via delayed coincidence; 226/228Ra via gamma spect (Dulaiova, 2002)
Ra-223 Distribution Offshore
Distance (km)0 1 2 3 4 5 6
Ln 22
3 Ra
(dpm
/100
L)
1.6
2.0
2.4
2.8
3.2
3.6
Kh = 18±6 m2/sec
slope = -0.200±0.035 km-1
r2 = 0.836n = 9
h
x KxAA
0lnln
hKm
Submarine spring
Mixing coefficient calculated from slope of 223Ra gradient (Moore, 2000)
Scale for Laboratory Use
“MnO2 Resin” Developed by PGRF 80-160 mesh Preconcentration approach in batch,
column, or pump (filtration) modes High adsorption of Ra, trivalent and
tetravalent actinides (Ac, Am, Pu, Th)
MnO2 Resin Experiments
Uptake studies: 133Ba and Ra; batch and column modes; kinetics; optimum conditions
Evaluate difference in chemical behavior, if any, between Ba and Ra
Evaluate use of MnO2 Resin cartridge with pump for processing
Tracers, Analytical Approach
Ba-133 (commercial, nominal activity)
Ra-228 (separated from Th-232 solution)
Ba-133 via -spect (NaI) and LSC Ra-228 via Ac-228 separation
(Diphonix), HEDPA elution, LSC counting
Batch ExperimentsBa-133 spike, adjust pH, react
Mn Resin with measured vol, vary time, resin, pH
Filter using syringe
Measure resin with NaI detector
Measure fluid with LSC
Perform experiments with both deionized water and seawater
Distribution Coefficient
W
V
A
AAD
f
fo
Ao = initial activity solution
Af = final activity solution
V = volume solution
W = weight of resin
Counting Solution & Resin
0 200 400 600 800 10000
500
1000
1500
2000
2500
3000 pH = 3
X0=1067
Y0=3188
Y=3188-2.99*X R=-0.99
133 B
a A
ctiv
ity in
so
lutio
n (
CP
M-L
SC
)
133Ba Activity in MnO2 resin (CPM-NaI)
• pH = 3• Variable mass
ratios• Variable reaction
times
Optimize Amount of Resin
• pH = 3 or 7• Resin =
variable• Solution = 10
mL DDW• Reaction time
= 90 min
0 20 40 60 80 100
200
400
600
800
1000
1200
133 B
a a
ctiv
ity in
Mn
O2
resi
n (
cpm
)
Weight of Mn resin (mg)
pH=3 pH=7
pH Variation
• pH = variable• Resin = 25 mg• Solution = 10
mL• Reaction time
= 90 min
0 2 4 6 8 10 12 14
0
200
400
600
800
1000
1200
DDW SW
133 B
a a
ctiv
ity in
Mn
O2
resi
n (
CP
M)
pH
Column ExperimentsW ater
sam p le1 L
A d d B a & R a trace r1 3 3 22 8
A d ju st p H = 7
M n res inC o lu m n
1 .0 g L eac h w ith 2 M H C l/H O2 2
1 3 3B a Yie ld w ith N aI d e te c to r
A g in g > 3 0 h rs : A c2 2 8
2 M H C l L o ad , R in se 1 M H E D PA 5 .0 m l
D ip h o n ix res in
H E D PA + C o ck ta ilC o u n t L S C A C2 2 8
Column Results
0
2 0
4 0
6 0
8 0
1 0 0
1 2 0
T e s t1 T e s t2
C o lumn E xp e rime nt(F lo w ra te = 1 .0 ml/min, p H = 7 )
Rec
over
y(%
)
BaRa
• pH = 7• Resin = 1 g• Solution = 1
liter DDW• Flow rate 0.65
mL/cm2.min (gravity flow 1 mL/min)
Ba Recovery vs Flow Rate
0 50 100 150 200 250 3000
20
40
60
80
100
120
DDW (pH=7) SW (pH=7)
133 B
a r
eco
very
(%
)
Flow rate (ml/min)
96.22.7%• pH = 7• Resin = 1g• Solution =
1L DDW or SW
• Variable flow
Ra Recovery vs Flow Rate
0 50 100 150 200 250 30020
40
60
80
100
DDW(pH=7) SW (pH=7)
228 R
a r
eco
very
(%
)
Flow rate (ml/min)
• pH = 7• Resin = 1g• Solution =
1L DDW or SW
• Variable flow
95.25.1%
Ba/Ra Recovery Ratio
0 50 100 150 200 250 3000.0
0.2
0.4
0.6
0.8
1.0
1.2
DDW SW
133 B
a/22
8 Ra
re
cove
ry r
atio
Flow rate (ml/min)
• pH = 7• Resin = 1g• Solution =
1L DDW or SW
• Variable flow
1.010.05