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MLXZ Classification for Organometallics
Christopher C. Cummins
Massachusetts Institute of Technology
ccc MLXZ Classification
Outline
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
Professor Ged Parkin of Columbia University Click here tovisit Ged’s web page
Key concept number 1: CBC or Covalent Bond Classificationmethod
Practice finding the [MLlXxZz ] classification for a metalcomplex
Some important definitions
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
Professor Ged Parkin of Columbia University Click here tovisit Ged’s web page
Key concept number 1: CBC or Covalent Bond Classificationmethod
Practice finding the [MLlXxZz ] classification for a metalcomplex
Some important definitions
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
Professor Ged Parkin of Columbia University Click here tovisit Ged’s web page
Key concept number 1: CBC or Covalent Bond Classificationmethod
Practice finding the [MLlXxZz ] classification for a metalcomplex
Some important definitions
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
Professor Ged Parkin of Columbia University Click here tovisit Ged’s web page
Key concept number 1: CBC or Covalent Bond Classificationmethod
Practice finding the [MLlXxZz ] classification for a metalcomplex
Some important definitions
ccc MLXZ Classification
Three Basic Types of Interaction2-, 1-, and 0-electron neutral ligands
ccc MLXZ Classification
Some Examples of Ligand ClassificationSome standard organometallic ligands
ccc MLXZ Classification
Further Examples of Ligand ClassificationSome standard organometallic ligands
ccc MLXZ Classification
Classifying Some Organometallic MoleculesLooking at the species as a whole
ccc MLXZ Classification
Classifying Some Organometallic MoleculesLooking at the species as a whole
ccc MLXZ Classification
Convert Charged Species to Corresponding Neutral ClassFor comparison purposes neutral classes are used
ccc MLXZ Classification
Important Definitions in the CBC Method
ccc MLXZ Classification
Example of an MLXZ Plot for Iron
ccc MLXZ Classification
Summary of Favored MLXZComparison across the transition series
ccc MLXZ Classification
Examination of TrendsThe 18 electron rule is more of a guideline
ccc MLXZ Classification
Trends in Valence and Ligand Bond NumberGroups 3-5
ccc MLXZ Classification
Trends in Valence and Ligand Bond NumberGroups 6-8
ccc MLXZ Classification
Trends in Valence and Ligand Bond NumberGroups 9-10
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
This web link lets you evaluate trends for the various d-blockelements. Click here for mlxz plots
Plots of [MLlXxZz ]
Electron Counts
Valence distribution
Ligand Bond Number distribution
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
This web link lets you evaluate trends for the various d-blockelements. Click here for mlxz plots
Plots of [MLlXxZz ]
Electron Counts
Valence distribution
Ligand Bond Number distribution
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
This web link lets you evaluate trends for the various d-blockelements. Click here for mlxz plots
Plots of [MLlXxZz ]
Electron Counts
Valence distribution
Ligand Bond Number distribution
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
This web link lets you evaluate trends for the various d-blockelements. Click here for mlxz plots
Plots of [MLlXxZz ]
Electron Counts
Valence distribution
Ligand Bond Number distribution
ccc MLXZ Classification
Visit the Web Page of Ged Parkin
This web link lets you evaluate trends for the various d-blockelements. Click here for mlxz plots
Plots of [MLlXxZz ]
Electron Counts
Valence distribution
Ligand Bond Number distribution
ccc MLXZ Classification
