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Microwave Remote Sensing of Atmospheric Trace Gases. Remote Sensing I Lecture 6 Summer 2006. J. F(J). Rotational Energy Levels. Rotational Transitions. allowed transitions:. Rotational Transitions. Microwave Spectrum of HCl. Microwave Spectrum of ClO. posible orientations. - PowerPoint PPT Presentation
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Microwave Remote Sensing of Atmospheric Trace Gases
Remote Sensing I
Lecture 6
Summer 2006
Rotational Energy Levels
J F(J)
)0()1(~10 JFJFJJ
)0()1(~01 FF
]cm[202~ 101
BB
]cm[426~ 112
BBB
Rotational Transitions
121~1 JBJJJBJJ
JJJJB 22 23
12 JB
Rotational Transitions
12~1 JBJJ
allowed transitions:
1J
Microwave Spectrum of HCl
Microwave Spectrum of ClO
Degeneracies of Rotations
posibleorientations
12 J
J=1
Degeneracies of Rotations
J=2 J=3
Intensities of Rotational Lines
•Probability for transition between level l and level udepends on the number of molecules in level l•In thermal equilibrium given by Boltzmann distribution:
TkEN
NBJ
l
u exp
TkJBhcJ B1exp
(tends to decrease with increasing J)
Intensities of Rotational Lines
•Depends also on degenaracies of the levels:
12 Jg J(tends to increase with increasing J)
Overall proportional to:
TkJBhcJJ B1exp12
Intensities of Rotational Lines
May be used to derivetemperature from observedspectrum
Microwave Spectrum of N2O
The N2O Molecule
NN O
N2O is a linear molecule
Microwave Spectrum of H2O
The Water Molecule
O
H H
0.09578 nm
104.48°
Microwave Spectrum of Ozone
Microwave Limb Sounding:
MLS / UARS
(Source: MLS Website)
Part 1: Airborne Microwave Remote Sensing of Atmospheric Trace Gases.
Airborne Submillimeter Radiometer (ASUR)
ASUR frequency range and primary species
ASUR onboard the NASA DC-8
Part 2: Ground-based Microwave Remote Sensing of Atmospheric Trace Gases.
Observations in Spitsbergen (79°N)
Observations in Spitsbergen (79°N)
Radiometer for Atmospheric Measurements (RAM)
Schematic Overview of the RAM
Measured Microwave Spectrum by the RAM
Pressure Broadening of Spectral Lines
50km / 0.5 hPa
20km / 50 hPa
10km / 200 hPa
Weighting Functions for Ozone Retrieval
Retrieval techniques / Inverse Modelling
xy F
xKy
Assume that the measured spectrum y is a known function of the atmospheric profile x plus some noise ε.
Linearize F (also known as the forward model):
However,
can not be directly inverted (ill-posed problem)
Optimal Estimation
xKy
aTa
Taa KxySKKSKSxx
1ˆ
A-priori profile
A-priori profile covariance matrix
Measurement error covariance matrix
Best guess profile
Best estimate given by Optimal Estimation solution:
Example Ozone Profile: RAM vs. Ozonesonde
Optimal Estimation: Averaging Kernels
aTa
Taa KxySKKSKSxx
1ˆ
1 SKKSKSD T
aT
a
aa xxKDxx̂
DxxAxx aaˆ
DxAIAx a
Optimal estimation solution:
Define:
Then:
Define Averaging Kernel Matrix A = DK:
Averaging Kernel Functions