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1 Metamorphic Rocks Metamorphic Rocks and Metamorphic Processes and Metamorphic Processes Metamorphic Rocks Metamorphic Rocks Metamorphic rocks form from pre Metamorphic rocks form from pre - - existing rocks existing rocks Metamorphic rocks change with increasing Metamorphic rocks change with increasing temperature (and pressure to a lesser extent) temperature (and pressure to a lesser extent) due to chemical reactions between minerals due to chemical reactions between minerals Metamorphic reactions are Metamorphic reactions are isochemical isochemical The minerals present in a given metamorphic The minerals present in a given metamorphic rocks will depend both on its composition and rocks will depend both on its composition and the conditions under which it was the conditions under which it was metamrophosed metamrophosed (P and T) (P and T) Typical Composition of Rocks Typical Composition of Rocks 0.05 0.05 0.24 0.24 3.96 3.96 4.30 4.30 1.10 1.10 0.34 0.34 K K 2 2 O O 0.03 0.03 0.07 0.07 1.13 1.13 3.55 3.55 2.91 2.91 0.49 0.49 Na Na 2 2 O O 32.87 32.87 53.06 53.06 3.50 3.50 1.14 1.14 9.47 9.47 5.05 5.05 CaO CaO 21.88 21.88 1.59 1.59 2.82 2.82 0.39 0.39 6.73 6.73 31.24 31.24 MgO MgO 0.05 0.05 0.07 0.07 0.25 0.25 0.06 0.06 0.20 0.20 0.41 0.41 MnO MnO 0.60 0.60 1.15 1.15 5.69 5.69 1.59 1.59 10.92 10.92 11.19 11.19 FeO FeO 0.13 0.13 0.98 0.98 17.00 17.00 13.27 13.27 15.74 15.74 4.23 4.23 Al Al 2 2 O O 3 3 0.41 0.41 3.64 3.64 64.70 64.70 72.82 72.82 49.20 49.20 42.26 42.26 SiO SiO 2 2 Dolostone Dolostone Limestone Limestone Shale Shale Granite Granite Gabbro Gabbro Peridotite Peridotite What elements are ESSENTIAL to describe each rock? Typical Composition of Rocks Typical Composition of Rocks 0.05 0.05 0.24 0.24 3.96 3.96 4.30 4.30 1.10 1.10 0.34 0.34 K K 2 2 O O 0.03 0.03 0.07 0.07 1.13 1.13 3.55 3.55 2.91 2.91 0.49 0.49 Na Na 2 2 O O 32.87 32.87 53.06 53.06 3.50 3.50 1.14 1.14 9.47 9.47 5.05 5.05 CaO CaO 21.88 21.88 1.59 1.59 2.82 2.82 0.39 0.39 6.73 6.73 31.24 31.24 MgO MgO 0.05 0.05 0.07 0.07 0.25 0.25 0.06 0.06 0.20 0.20 0.41 0.41 MnO MnO 0.60 0.60 1.15 1.15 5.69 5.69 1.59 1.59 10.92 10.92 11.19 11.19 FeO FeO 0.13 0.13 0.98 0.98 17.00 17.00 13.27 13.27 15.74 15.74 4.23 4.23 Al Al 2 2 O O 3 3 0.41 0.41 3.64 3.64 64.70 64.70 72.82 72.82 49.20 49.20 42.26 42.26 SiO SiO 2 2 Dolostone Dolostone Limestone Limestone Shale Shale Granite Granite Gabbro Gabbro Peridotite Peridotite

Metamorphic Rocks Typical Composition of Rocksacademic.brooklyn.cuny.edu/geology/powell/courses/geol640...Metamorphic Rocks and Metamorphic Processes ... 2.91 0.49 Na 2 O 32.87 53.06

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Metamorphic Rocks

Metamorphic Rocks

and M

etamorphic Processes

and M

etamorphic Processes

Metamorphic Rocks

Metamorphic Rocks

��Metamorphic rocks form

from pre

Metamorphic rocks form

from pre-- existing rocks

existing rocks

��Metamorphic rocks change with increasing

Metamorphic rocks change with increasing

temperature (and pressure to a lesser extent)

temperature (and pressure to a lesser extent)

due to chemical reactions between m

inerals

due to chemical reactions between m

inerals

��Metamorphic reactions are

Metamorphic reactions are isochemical

isochemical

��The m

inerals present in a given m

etamorphic

The m

inerals present in a given m

etamorphic

rocks will depend both on its composition and

rocks will depend both on its composition and

the conditions under which it was

the conditions under which it was

metamrophosed

metamrophosed(P and T)

(P and T)

Typical Composition of Rocks

Typical Composition of Rocks

0.05

0.05

0.24

0.24

3.96

3.96

4.30

4.30

1.10

1.10

0.34

0.34

KK22OO

0.03

0.03

0.07

0.07

1.13

1.13

3.55

3.55

2.91

2.91

0.49

0.49

Na

Na22OO

32.87

32.87

53.06

53.06

3.50

3.50

1.14

1.14

9.47

9.47

5.05

5.05

CaO

CaO

21.88

21.88

1.59

1.59

2.82

2.82

0.39

0.39

6.73

6.73

31.24

31.24

MgO

MgO

0.05

0.05

0.07

0.07

0.25

0.25

0.06

0.06

0.20

0.20

0.41

0.41

MnO

MnO

0.60

0.60

1.15

1.15

5.69

5.69

1.59

1.59

10.92

10.92

11.19

11.19

FeO

FeO

0.13

0.13

0.98

0.98

17.00

17.00

13.27

13.27

15.74

15.74

4.23

4.23

AlAl 22OO33

0.41

0.41

3.64

3.64

64.70

64.70

72.82

72.82

49.20

49.20

42.26

42.26

SiOSiO

22

Dolostone

Dolostone

Limestone

Limestone

Shale

Shale

Granite

Granite

Gabbro

Gabbro

Peridotite

Peridotite

What ele

ments

are

ES

SE

NTIA

L to d

escribe e

ach rock?

Typical Composition of Rocks

Typical Composition of Rocks

0.05

0.05

0.24

0.24

3.96

3.96

4.30

4.30

1.10

1.10

0.34

0.34

KK22OO

0.03

0.03

0.07

0.07

1.13

1.13

3.55

3.55

2.91

2.91

0.49

0.49

Na

Na22OO

32.87

32.87

53.06

53.06

3.50

3.50

1.14

1.14

9.47

9.47

5.05

5.05

CaO

CaO

21.88

21.88

1.59

1.59

2.82

2.82

0.39

0.39

6.73

6.73

31.24

31.24

MgO

MgO

0.05

0.05

0.07

0.07

0.25

0.25

0.06

0.06

0.20

0.20

0.41

0.41

MnO

MnO

0.60

0.60

1.15

1.15

5.69

5.69

1.59

1.59

10.92

10.92

11.19

11.19

FeO

FeO

0.13

0.13

0.98

0.98

17.00

17.00

13.27

13.27

15.74

15.74

4.23

4.23

AlAl 22OO33

0.41

0.41

3.64

3.64

64.70

64.70

72.82

72.82

49.20

49.20

42.26

42.26

SiOSiO

22

Dolostone

Dolostone

Limestone

Limestone

Shale

Shale

Granite

Granite

Gabbro

Gabbro

Peridotite

Peridotite

2

Essential Components of Rocks

Essential Components of Rocks

CaO

CaO

KK22OO

CaO

CaO

CaO

CaO

KK22OO

CaO

CaO

FeO

FeO

Na

Na22OO

FeO

FeO

MgO

MgO

MgO

MgO

Al

Al 22OO33

Al

Al 22OO33

Al

Al 22OO33

FeO

FeO

SiOSiO

22SiOSiO

22SiOSiO

22SiOSiO

22SiOSiO

22

Carbonate

Carbonate

Rock

Rock

Shale

Shale

Granite

Granite

Gabbro

Gabbro

Peridotite

Peridotite

Chemographic

Chemographic

Analysis:

Analysis:

SiO

SiO

22-- C

aO

CaO-- M

gO Diagrams

MgO Diagrams

Chemographic

Chemographic

Analysis:

Analysis:

ACF Diagrams

ACF Diagrams

Chemographics

Chemographics

��What minerals (pink dots) would you need to have to in a

What minerals (pink dots) would you need to have to in a

rock with composition X? Y?

rock with composition X? Y?

Fig. 26-12.From W

inter (2001) An

Introduction to Igneous and

Metamorphic Petrology. Prentice

Hall.

Y

3

Chemographic

Chemographic

Analysis:

Analysis:

SiO

SiO

22-- C

aO

CaO-- M

gO Diagrams

MgO Diagrams

“Rock A”

What m

inera

ls m

ight you fin

d in a

rock w

ith c

om

positio

n “A

”?

Chemographic

Chemographic

Analysis:

Analysis:

SiO

SiO

22-- C

aO

CaO-- M

gO Diagrams

MgO Diagrams

What m

inera

ls m

ight you fin

d in a

rock w

ith c

om

positio

n “B

”?

“Rock B”

Chemographic

Chemographic

Analysis:

Analysis:

ACF Diagrams

ACF Diagrams

What m

inera

ls m

ight you fin

d in a

rock w

ith c

om

positio

n “C

”?

Rock C

Chemographic

Chemographic

Analysis

Analysis

��There can be m

any combinations of minerals for

There can be m

any combinations of minerals for

a given rock composition that are

a given rock composition that are

chemographically

chemographically

allo

wable

allo

wable……

��Are

they a

ll pro

bable

, or even p

ossib

le?

Are

they a

ll pro

bable

, or even p

ossib

le?

Many a

re, but m

any a

re n

ot. If you u

nders

tand

Many a

re, but m

any a

re n

ot. If you u

nders

tand

the b

asic

s o

f m

eta

morp

hic

pro

cesses y

ou c

an

the b

asic

s o

f m

eta

morp

hic

pro

cesses y

ou c

an

reason s

om

e h

ighly

pro

bable

and h

ighly

re

ason s

om

e h

ighly

pro

bable

and h

ighly

im

pro

bable

com

bin

ations.

impro

bable

com

bin

ations.

4

General Rules of Metamorphism

General Rules of Metamorphism

��Metamorphism is

Metamorphism is isochemical

isochemicalwith respect to non

with respect to non-- volatile

volatile

components(H

components(H

22O and CO

O and CO

22))

��Most metamorphic reactions liberate volatiles (H

Most metamorphic reactions liberate volatiles (H

22O and

O and

CO

CO

22))

��The m

inerals in low

The m

inerals in low-- grade m

etamorphic rocks have m

ore

grade m

etamorphic rocks have m

ore

volatiles than high

volatiles than high-- grade m

etamorphic rocks

grade m

etamorphic rocks

��e.g., m

icas

e.g., m

icas ��

amphiboles

amphiboles ��

pyroxenes

pyroxenes

��Increasing m

etamorphic grade generally corresponds to

Increasing m

etamorphic grade generally corresponds to

increasing grain size

increasing grain size

��e.g., clays

e.g., clays ��

micas

micas

Chemographic

Chemographic

Analysis:

Analysis:

ACF Diagrams

ACF Diagrams

Metamorphic M

ineral Assemblages in

Metamorphic M

ineral Assemblages in

the Field

the Field

Metamorphic Facies

Metamorphic Facies

��A set of metamorphic m

ineral

A set of metamorphic m

ineral

assemblages that are repeatedly

assemblages that are repeatedly

associated in space and tim

e, such that

associated in space and tim

e, such that

there is predictable relation between

there is predictable relation between

mineral assemblage, chemical

mineral assemblage, chemical

composition, and m

etamorphic conditions

composition, and m

etamorphic conditions

5

Metamorphic Facies

Metamorphic Facies

Progressive M

etamorphism of

Progressive M

etamorphism of Metabasites

Metabasites

Chemographic

Chemographic

Analysis:

Analysis:

SiO

SiO

22-- C

aO

CaO-- M

gO Diagrams

MgO Diagrams

Progressive M

etamorphism of Carbonate Rocks

Progressive M

etamorphism of Carbonate Rocks

6

Metamorphic Texture Changes

Metamorphic Texture Changes

Quartz Arenite

Quartzite

Metamorphic Texture Changes

Metamorphic Texture Changes

Quartz Arenite

Quartzite

Lim

estone

Marble

Metamorphic Texture Changes

Metamorphic Texture Changes

Granite

Gneiss

Metamorphic Texture Changes

Metamorphic Texture Changes

Shale

Slate

Schist

Gneiss