15
Metamorphic Rock Of Darab Related To Uranium Mineralization * Retno Witjahjati, Soeprapto T., Manto W Nuclear Minerals Development Centre, BATAN Abstract Metamorphic Rock of Darab Related to Uranium Mineralization. Metamorphic rock of Darab is surrounded and intruded by granitic rocks, which is composed of medium to fine pained, it identified as phyllite interbedded with quartzite. Milimetric to decimetric vein structures which determinated as biotite, quartz-biotite, andalusite, quartz -apatite, biotite-apatite, gypsum, tour- maline, quartz-orthoclase, and quartz have been found within the metamorphic rock. Metamorphic grade of the rock is medium at near contact zone, while low grade metamomhism has been idp.n- tified away from the contact, it may indicate retrogade process has exist. Uranium mineralizations occurred in granite and metamorphic rock as well, as brecia fillings or veins at the contact vici- nities. Radioactive minerals have been identified as uraninite and monazite, they are mostly asso- ciated with magnetite, ilmenite, molybdenite, ilmenorutile, sphalerite, pyrite, arsenophyrite, biotite, tourmaline'oapatite, tnd quartz. Formation of the mineralization were interpreted to be mesothermal at 300 C to 600 C with granite as the bearer. INTRODUCTION This paper is a result of a mineralogical study on Metamorphic Septa of Darab, West Kalimantan. Knowledge were obtained from the study is expected to explain how the metamorphism process contributes to the uranium accumulations. The know- ledge would support someways in developing exploration programmes of Schwaner region. Geological data has been gained from those study includes morphology, lithology, structure and radioactivity of outcrops which measured by scintillometer SPP2-NF is around (400-15000) count per second (cps). Metamorphic rocks which have been discovered in Darab was intruded by granitic rocks. The intrusion is probably occured in Cretaceous magmatic period [1]. Field observation shows that metamorphic rocks consist of fine grained materials which exhibite some relict of sedimentary structures, i.e. lamination and bedding planes. Uranium mineralization veins were discovered mostly as tectonic breccia filling or sulphide associated veins within granite and metamorphic rocks. * Presented in Joint Indonesia - German Seminar on Uranium Exploration, Geology and Extration, Jakarta, October, 16 - 18,1989. 13

Metamorphic Rock Of Darab Related To Uranium …digilib.batan.go.id/atom-indonesia/fulltex/v17-n1-1-91/Retno-W.pdfMetamorphic Rock Of Darab Related To Uranium Mineralization * Retno

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Metamorphic Rock Of Darab Related To Uranium Mineralization *

Retno Witjahjati, Soeprapto T., Manto W

Nuclear Minerals Development Centre, BATAN

Abstract

Metamorphic Rock of Darab Related to Uranium Mineralization. Metamorphic rock of Darabis surrounded and intruded by granitic rocks, which is composed of medium to fine pained, itidentified as phyllite interbedded with quartzite. Milimetric to decimetric vein structures whichdeterminated as biotite, quartz-biotite, andalusite, quartz -apatite, biotite-apatite, gypsum, tour­maline, quartz-orthoclase, and quartz have been found within the metamorphic rock. Metamorphicgrade of the rock is medium at near contact zone, while low grade metamomhism has been idp.n­

tified away from the contact, it may indicate retrogade process has exist. Uranium mineralizationsoccurred in granite and metamorphic rock as well, as brecia fillings or veins at the contact vici­nities. Radioactive minerals have been identified as uraninite and monazite, they are mostly asso­ciated with magnetite, ilmenite, molybdenite, ilmenorutile, sphalerite, pyrite, arsenophyrite,biotite, tourmaline'oapatite, tnd quartz. Formation of the mineralization were interpreted to bemesothermal at 300 C to 600 C with granite as the bearer.

INTRODUCTION

This paper is a result of a mineralogical study on Metamorphic Septa of Darab,West Kalimantan. Knowledge were obtained from the study is expected to explainhow the metamorphism process contributes to the uranium accumulations. The know­ledge would support someways in developing exploration programmes of Schwanerregion.

Geological data has been gained from those study includes morphology, lithology,structure and radioactivity of outcrops which measured by scintillometer SPP2-NF isaround (400-15000) count per second (cps).

Metamorphic rocks which have been discovered in Darab was intruded by graniticrocks. The intrusion is probably occured in Cretaceous magmatic period [1]. Fieldobservation shows that metamorphic rocks consist of fine grained materials whichexhibite some relict of sedimentary structures, i.e. lamination and bedding planes.

Uranium mineralization veins were discovered mostly as tectonic breccia fillingor sulphide associated veins within granite and metamorphic rocks.

*Presented in Joint Indonesia - German Seminar on Uranium Exploration, Geology andExtration, Jakarta, October, 16 - 18,1989.

13

MATERIALS AND METHODS

Mineralized and unmineralized rock samples have been taken from the interestarea, both of igneous and metamorphic rocks (Fig. 2). These samples were analyzedmicroscopically by using petrography, and mineragraphy methods.

Data collected from the analysis include mineral composition, texture, and kindsof the rock. D, Th, Sn, W, and Mo content have been obtained from selected samplesusing Atomic Adsorption Spectrometer, Major oxides content in the rocks are derivedfrom mineral composition of modal analysis which is calculated based on theoriticaloxides content in minerals propose by Deer, et.al [2] , (Table 5).

Relationship between uranium mineralization, host, and the source would be in­

terpreted from the petrograph!c and mineragraphic data and also from their chemicalcompositions.

RESULT AND DISCUSSION

Geological Setting Of Darab

The studied area is a part of the Southern slopes of Schwaner Mountains range.Regionally, it consists of tonalite which supposes to be anatexis origin from gabroicand andesitic tuff formations [I]. Tonalite is overlied by metamorphosed rock whichconsists of sericite schist, biotite-sericite phyllite, volcanic, and often contains carbon­

aceous materials. Migmatitic texture occured in some part of rocks as granitic gneissand migmatitie. Those rocks are probably the transition phase between metamorphicand plutonic stages.

Geological observation of the metamorphic septa of Darab shows that this rockis surrounded by granite, so the structures look like a "roof pendant" of the graniticbatholith or a relict or anatexis metamorphic rocks [3] (Fig. 3).

Metamorphic rocks mostly composed or fine grained, of sandy to silty materialssuch as phyllites with some quartzite interbeds. Milimetric to decimetric veins ofbiotite, tourmaline, quartz, and gypsum have been discovered.

Metamorphic Rocks Of Darab

Lithologically, the metamorphic rocks consist of phyllite and low grade quartzite.

Phyllite

Phyllite covers mostly the studied area. It usually shows light to dark grey colors,0:01 mm - 0.3 mm grain size, and some times a relict of the stratifications and lami­nations. Petrographically, the rocks compose of quartz, sericite, biotite, andalusite,cordierite and opaque minerals. Orthoclase, tourmaline, monazite, apatite, epidote andzircon as accessory minerals have often been found.

Alteration process such as silicification, sericitization, and chloritization has beendetermin~d from mineralized zone samples.

Spotted slate structures are also obserVed in some samples (MW 52, MW 125, SWO97, MW 106 and MW I] 3). The structures conta!n of agregates of sericite, andalusite,cordierite, biotite minerals in quartz and sericite matrix.

14

Severa] veins which were identified microscopically in the thin section consist ofbiotite (SWO 185), quartz-biotite (SWO 89, SWO 97, DW 20), andalusite (MW 70),quartz-apatite (MW 52), biotite-apatite (MW 125) and gypsum (SWO 185).

The occurrences of andalusite and apatite minerals may indicate a high tempera-'ture veins, while the agregation and impregnation textures of tourmaline, biotite,monazite, and opaque minerals indicate metasomatic injection.

Quartzite

Quartzites are exposed in a relatively small area. They show light grey colour,massive structures, compact but some of them show a relict of stratifications.

Petrographically, the quartzite shows granoblastic with equigranular texture,0.0 I nun - 0.2 mm grain size. Mineral composition is quartz, sericite, biotite, tourma­line. a little of epidote, and muscovite. Zircon, monazite, apatite and opaque mineralshave been identified 'as accessory minerals.

MicroscopicaJly, several veins also can be identified in thin sections. The veins

consist of tourmaline (SWO 90, SWO 25 B), biotite (SWO 25 B), quartz-biotite(SWO 89), quartz-orthoclase (DW 20), granite (MW 1.15), granodiorite (MW 9) anddypsum (SWO 61).

Metamorphic Origin

Value of A, C, F, A' and K have been calculated from Winkler's formula [4]:A = (A1203 + Fe203) - (Na20 + K20)

C = (CaO - 3.3 x P205)

F = MgO + FeO + MnO

A' = (A1203 + Fe203) - (Na20 + K20 + CaO).K = K20

Based on the position of A, C, F, A I, and K parameters of the rocks which havebeen plotted to ACF and A' KF of Winkler's diagram, origin of the metamorphic rockscould be interpreted.

Calculation of ACF and A' KF values of phyllite and quartzite samples based onthe theoritical oxides content in mineral of rocks (Table 6, 7). These values plotted toACF and A' KF diagrams (Fig. 4), from the sample position plots, can be interpretedthat the phyllite and quartzite are originally from claystone and greywacke sediments.

Metamorphic Type and Grade

Petrological and petrogaphical observations on metamorphic rocks in field and -thelaboratory show granoblastic texture, poor foliation, spotted slate, and some relict oftheir stratifications.

15

Petrographic criteria of Darab metamorphic rock may indicate that thermal fac­tor has higher influenced than pressure factor. According to those, magmatic intru­sion process possibly produces a contact metamorphic zones at the adjacent rock [3] .Andalusite and cordierite minerals which have been found in several parts of rockindicate a contact metamorphism process on medium grade. The reaction are [4] :

Ch!orite + Muscovite + Quartz --:). Cordierite + Biotite + Andalusite + H20

Muscovite + Quartz ~ K. Feldspar + Al2Si05 + H20

Chloritization and serisitization of andalusite and feld spar which usually exist insome samples may indicate that some retrograde metamorphic process has been occu­red. However, metamorphic rocks in the region as overall view is a low grade metamor­phism.

Uranium Mineralization In Darab

Uranium mineralization occured as a mineralized out crops both in granite andmetamorphic which closed to the contact as tectonic breccias filling, veins, or meta­mosmatic contact [5]. Milimetric to decimetric of tectonic breccias are generallycontrolled by N 1300 E to N 1600 E tectonic activity. Radioactivity values of themineralized outcrops are about 400 to 15000 cps SPP 2 - NF.

Mineral paragenesis of mineralized samples are magnetite, ilmenite, ilmenorutile,uraninite, molybdenite, hematite, sphalerite, pyrite, arsenopyrite (Table 2), and itsfollowed by development of brokite, chalcopyrite and bornite-as a second stage theparagenesis (Table 3).

Radioactive minerals in the mineralized rocks are uraninite or may be some tho­rian-uraninite, that exhibit rimed textures of iron sulphides [3,6] . Uranium bearingmonazite and opaque minerals have also been identified and they have caused anoccurence of pleochroic halo structures in associated biotite.

Uranium content of the mineralized zone is quite high, the maximum content isabout 0.2141 %. Th/U ratio relatively low. Molybdenum element exist in almostsamples were analyzed, but stanum and wolfram are un significant (Table 4).

The formation temperature is about 3000 - 6000 C and it was interpreted as

magmatic origin due to their elements and minerals content.

Relationship Between Metamorphism Process And The Mineralization

Uranium mineralizations occurred mostly in West part of Metamorphic Speta of

Darab, they are exposed relatively near the contact between metamorphic rock andgranitic body. Some mineralizations associated with granitic veinlets which commonlydiscovered at along the contact zone. Uranium minerals in them are uraninite, pro­

bably thorian bearing uraninite. Microscopically, the individual uraninite associatedwith iron sulphides and iron oxides.

16

Based on the mineral association and textures, formation of the mineralizations

related to the granitic intrusion and contact metamorphism process.

CONCLUSION

Metamorphic Septa of Darab consists of a low grade metamorphic rockswhich could be determined as phyllite and quarzite. They are originally from clay­

stone and greywacke sediments.Granitic intrusion which has been formed from the magmatic activities

during the Cretaceous period may have strong influenced the metamorphic grade ofthe contact vicinity between intrusion and metamorphic rocks.

Uranium minerals occurred as uraninite or thorian uraninite which crysta­

llized from highly differenciated granitic magma were deposited in tectonic breccias,granicit veinlets and in metamorphic rocks closed to the contact at 3000 C - 6000 C.

ACKNOWLEDGEMENT

We would like to thank Mr. Djodjo as Head Exploration Divison for providing thefacilities and advices. Also, particularly gratitute to our colleagues in Mineralogy SubDivision. who generaly help until this paper completely written.

REFERENCES

1. COMMISARIAT A L'ENERGIE ATOMIQUE (CEA) - BATAN "Overseas MineralExploration, Indonesia: Project Kalan." RSI 68, (1976)

2. W.A. DEER, R.A. HOWIE, J. ZUSSMAN. "An Introduction to the Rocks For­ming Minerals". The English Language Book Socitey and Longman (1985)

3. SOEPARTO. "Studi Mikroskopik Contoh Batuan Zona Mineralisasi UraniumSektor Darab. Kalimantan Barat". PPBGN-Batan (1985)

4. H.G.F. WINKLER. "Petrogenesis of Metamorphic". Springer-Verlag, Berlin,Heidelberg, New York (1976)

5. PPBGN-BA TAN. "Laporan Prospeksi Superdetail, Sektor Darab, Kalimantan(1988). (unpublished)

6. G. D'ARCY. "Mineralogy Uranium and Thorium Bearing Minerals". Raw materialoperation office, Washington 25 DC. (1949)

7. H. WILLIAMS, F.J, TURNER and C.M.GILBERT." Petrography an Introductionto the Study of Rock in Thin Section". W.H. Freemon and Co, San Francisco(1958)

8. H.G.F.WINKLER." Petrogenesis of Metamorphic". Springer - Verlag, Berlin, Hei­delberg, New York, (1976)

9. A. SPRY. "Metamorphic Texture". Pergamon Press. Oxford, New York, Toronto,Sydney, Paris, Frankfurt. (1976)

17

- 00

Tab

leI.

Pet

rogr

aphi

cA

naly

sisI

of

Met

amor

phic

Roc

k

Sam

ples

No.

SWO

.18

5SW

O.

197

SWO

.18

9SW

O.

206

MW

.70

SWO

.90

SWO

.76

Rad

iom

etry

125

cps

120

cps

500

cps

130

cps

i50cp

s14

0cp

s15

0ep

sR

ock

Nam

eK

MB

BM

QFo

liatio

n-B

QFo

liatio

n-B

MQ

Met

asilt

Met

asilt

Met

asilt

Mic

rosc

opit

I11

I11

II

I11

I11

I

Qua

rtz

15,6

315

.84

6.71

40.3

715

.63

41.6

237

.31

5.03 57

.55

35.6

1B

iotit

e38

.06

36.9

133.

6252

.06

-10.

875.

7712

.52

-8.9

3T

ourm

alin

e-

- 0.35 0.95

-20

.76

56.7

111

.31

Zir

con

-- 0.01 0.

28---

Mon

azite

5.47

0.35

-0.

20-

0.11

-Se

rici

te32

.38

30.4

26.

3839

.96

32.1

3-

20.0

6M

usco

vite

--

37.4

4 -8.

06-

7.16

And

alus

ite-

-4.

03 -15

.43

60.7

1--

Epi

dote

-- 1.17 2.

32---

Alla

nite

--- --

1.23

-A

patit

e1.

506.

022.

02-

--8.

037.

97-

Chl

orite

--

17.3

0-

-3.

1010

.29

10.8

9Pl

agio

clas

e-

-- --5.

05-

Ort

hocl

ase

--

10.9

6-

---M

icro

clin

e-

-- ----O

'paq

ueM

iner

al2.

5335

.76

0.84

5.20

1.31

3.80

1.30

21.7

44.

0625

.03

5.05

Iron

are

--- -- ---

Clin

ozoi

site

--- -- --

Cor

dier

ite-

28.4

15.

42-

- ---N

ote

./.Fo

liatio

n,.1

.'F

Dlia

tiol1

,L

amin

atio

n,m

ag·

Hor

nfel

sU

ndis

tinet

folia

·/.

Gra

nobl

astic

,H

ornf

elsi

cO

.Olm

m-

0.03

mm

porp

hiro

blas

ticm

atic

inje

ctio

nO

.OJm

m-

0.03

mm

tion

.0.

05m

O.3

mm

porp

hiro

blas

tic,

Mus

covi

tera

diar

Lam

inat

ion.

II.

Vie

nw

ithte

x-m

atri

xO

,Olm

m-

11.

Segr

egat

ion

ofQ

uart

zgr

anul

arSe

greg

atio

nbi

o·tu

reho

locr

yst:I

ine

0.03

mm

,po

rfir

o-11

.V

ien

0.06

mm

biot

itetit

ew

ithha

los.

bIas

(0.2

-0.5

)m

mB

iotit

e's

halo

0.5

mm

Chl

orite

vein

cont

act

with

Hal

osin

.bio

tite

Bio

tite

vein

.m

onaz

ite

cont

act

with

mon

azit

e.M

icro

scop

ic

I.B

iotit

ese

rio

I.B

iotit

eco

rdie

·M

igm

atite

Seri

cite

-I.

Seri

cite

quar

tzI.

Qua

rtzi

teSe

rici

te-

cite

phyl

lite

rite

phyl

lite.

quar

tzite

phyl

lite.

quar

tzite

.II

.B

iotit

eve

inII

.A

ndal

usite

II.

Tou

rmal

ine-

Gyp

sum

vein

.ve

in.

vein

.

I

- \0

Tab

le2.

Min

eral

ogra

phic

Ana

lysi

sof

Ore

Sam

ples

ow

swo

swo

swo

swo

swo

ow

ow

SASow

ow

ow

SWOMW

MW

MW

SWOow

SarripleNo.

93

158

24

25A3

27

611547121

25

56115124

131

192

66

Radiometry

9000

1500

3000

1500

3000

2000

7500

2000

1500

140

3500

3000

600

5000

900

4000

3500

4000

Minerals.

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

cps

Mag

netit

e

1--- ·2 5--- 0,5 2--- 1 ---

Ilm

enite

-1

4-- 3 433-1 5-5 -5 -3 -

Hem

atite

"20

12-10 2-------- 12 ---

Ilm

enor

util

--- 2 ------- 1 ------

Rut

il-

--- 1 -1 10.5--- 0.53

0.5-- -

Ura

nini

te-

-- 2 3-3 0.5-- 4 -- 2 -- 4 -

Mol

ybde

nite

----- ----- 12 ----- --

Pyri

te1

-- 15 -- 10 10-- 10 0.5-5 -- 2 10

Phrr

hotit

e

--- ---------- -- 1 -2

Ars

enop

yrite

-2 --------- -- --- 25 -

Spha

leri

te

-2 -- 3 ------ ----- 1 -

Ca1

copy

rite

--- 7 -- 3 -1 ---- 1 -2 -5

Bor

nite

----------------- 0.5

Bro

okite

---------- 0.5 -------

Lig

htM

iner

als

779198747

887 7985.5

98'.5

98.5

64.5

98.5

9489 81.5976582

.5

Table 3. Ore minerals paragenesis of Darab

MineralsPhase IPhase 2

Magnetite

--Ilmenite

--Ilme noru tile

--Rutile

--Uraninite

--Hematite

---Molybdenite

--Sphalerite

--Pyrite

--Arsenopyrite

--Brokite

--Bornite

--Chalcopyrite

--

Table 4. Element Content in Rock.

No.Samples No. UThSnWMoTh/U

I.

SWO-3 0.04390.0973NONO0.10842.240

2

SWO-25/A 0.1157NONONO0.0111 -3.

OW-61 0.17770.0139NO0.00410.08600.080

4.

OW-21 0.21410.0033NONO0.26620.010

5.

MW-115 0.11860.OQ91NONOTD0.070

6.

OW-2 0.000657NONONO0.000667-

7.

OW-42 0.000606NONONO0.000167-

8.

OW-15/AB 0.001364·NONONO0.000333-

9.

SWO-39 0.000657NONONO0.000333-10.

SWO-160 0.000455NONONO0.000333-

II.OW-64/A 0.000550NONONO0.000333-

20

to.) -

Tab

le5.

Osi

deC

onsi

sten

tin

Min

eral

(How

ie's

)

Min

eral

com

po

Ort

ho-

To

urm

a-M

ona-

Opa

nue

Qua

rtz

Bio

tite

Seri

cite

Lep

idol

iteC

hlor

itePl

agio

clas

eE

pido

teA

llani

teA

patit

eA

ndal

usite

Cor

dier

iteZ

irco

ncl

ase

line

zite

Oxi

deca

nst.

SiO.

99.5

39.1

448

.42

49.8

025

.61

64.7

163

.66

36.3

61.

4036

.92

30.3

2-

36.7

4 49.4

632

.51

0.27

TiO

,

-4.

27 0.87-

0.88 ----- 0.04 -0.01 0.

01---

A1,

O,

-13

.10

27.1

625

.56

21.1

922

.66

19.3

440

.48

-22

.25

15.1

9-

62.7

0 33.5

80.

210.

21

Pe,0

,

-12

.94 6.

570.

083.

880.140.10-

-15

.21

3.77-0.36 0.

140.

0868

.85

FeO

-5.

05 0.81-

21.5

5 0.17-

3.64 -0.57 10

.81

0.260

.05

2.12-

30.7

8

MnO

-0.

14 -0.38

0.35--

1.05

-0.75

6.06

5.32-0

.08 --

MgO

-12

.75 -0.2

215

.28

0.25-

0.09 -- 0.32 0.040.0

312

.06

0.01

-C

aO'

-1.

64 -- 0.16 3.26 0.50

0.67

-23

.11 4.28

50.3

10.0

20.

030.

22-N

a,O

-0.

70 0.3

50.

40-9.86

0.80

2.20

--- --0.

14 --K,O

-6.

55 11.2

39.67-0.05 15.6

00.

44--- - 0.

07---

F

-1.

11 -6.85 -- - 0.10

---3.

41----

Bz0

,

------

-10

.30 --- -----

Liz

O

-- ----

-1.

27 ---- -- --

PzO

.

-- --

29.2

8 --41

.50-- --

Cez

0,

----- -- -

31.3

8 -------

(La,

Di)

z!;)

---- --

--30

.88 -------

ThO

,

------

--6.

4~ -------

V,O,

------

- ----- -- -

.-

YzO

,

------

----- --- --

Laz

O,

----- -

- -------.--

ZrO

------

--------

67.0

2 -

N N

Tab

le6.

Exa

mpl

eof

Oxi

des

Mol

ecul

eW

eigh

tCal

cula

tion

ofM

etam

orph

icR

ocks

No.

SWO

197

(Cor

dier

ite

biot

ite

phyI

ite)

.

Min

eral

sT

otal

wei

ght

%Q

uart

zB

ioti

teSe

rici

teC

ordi

erit

eO

paqu

eM

iner

alT

otal

wei

ght

(5)

wei

ght

Cor

rect

ion

Mol

ecul

e

Oxi

deco

nst.

(100

%)

SiD

,

99.5

xO.0

67~6

.97

39.1

4xO

.34=

13.3

1.4

8.4

lx.O

.30,

;,14

.53

.49

.46x

O.2

8.",

13..8

50.

27xO

.01~

0.00

248

.662

48.1

68'4

8.16

8:60

~0.8

.03

TiO

,

4.27

xO.3

4=1.

450.

87x0

.30=

0.26

0.0I

xO.2

8=0.

002

-1.

712

1.69

51.

695:

80~0

.021

AI,

O,

13.I

OxO

.34=

4.45

27.1

6x0.

30=

8.15

33.5

8xO

.28=

9.40

0.2I

xO.0

1=

0.00

222

.002

21.7

7921

.779

:10

2=0.

214

Fe,O

,

12.9

4xO

.34=

4.40

6.57

x0.3

0=1.

97O

.14x

O.2

8=0.

0468

.85x

O.0

1=0.

687.

097.

018

3Q'H

XJx7

.018

=21

052.

105:

160~

0.01

3

FeO

5.50

x0.3

4=5.

840.

8Ix0

.30=

0.24

2.12

xO.2

8=6.

5930

.78x

O.0

1=0.

316.

986.90

970

{100

x6.9

09=

4386

4.83

6:72

~0.0

67

MnO

0.14

x0.3

4=0.

05-

0.08

xO.2

8=0.

02 -0.

070.

069

0:06

9:71

=0.

00I

MgO

12.7

5x0.

34=

4.34

-12

.06x

O.2

8=3.

38-

I7.

727.

642

7.M

2:40

=0.

191

CaO

.

1.64

x0.3

4=0.

56-

0.03

xO.2

8=0.

008 -

0.56

80.

563

0.56

3:5

6~0.

0I

Na,

O

0.04

x0.3

4=0.

0I

0.35

x0.3

0=0.

10.

14xO

.28=

0.03

-0.

140.

138

0.13

8:62

=0.

002

K,O

6.55

x0.3

4=2.

2311

.23x

O.3

0=3.

370.

30xO

.28"

,0.

10-

5.70

5.64

35.

643:

94~0

.06

I'

I.llx

O.3

4=0.

38-

.-- 0.38

0.3

760.

376:

44~0

.008

P,O

,

A C I' A'

K F

(0.2

14+

0.01

3)-

(0.0

02+

0.06

)=0.

215

==

}o44

(0.0

1-

3.3

x0)

=0.

01=

=}o

20.

191

+0.

001

+0.

067

=0.

259

==

~54

(0.2

14+

0.01

3)-

(0.0

02+

0.06

+0.

01)

=0.

025

=~~

480.

06=

=~

2

0.25

9=

=)

50

\

t.J IN

III

Tab

le7.

AC

Fan

dA

'KF

Val

ue

SWO

197

SWO

97SWO

185MW

70

DW

20

MW

9

A

44

83.7

83

82.9

]8

14

C

20.3 1

1.570

F

54

1616

15.6

7586

A

48

7319

65 100

K216 24

1115

10

F

50

11 57

137590

Fig. 1. Situation map of Darab

24

_____ -,_n_

/

o 0.1 o~ Of> 0.8 1 i<rn,-SWQ. 39

()

•o1'1

Sc air

Somplf' numb~r

roe Ir (lurllpl.l (. rllllll".I,

lrtlo:tllullt," of nl!lri •. vnhl4l11

t-ttn~ral Qrap~;c QnolY5i~

Fig. 2. Location map of sample analysis

25

lliE!:'!J: E!JGrQnth

[=':::1M.• IQ,illE::-:lGrt1nntfinrit.

G'-=';JPhylili.

EJJ.pirtot:Cr onitp

1:::::··0:1

Q.uartziteIh-ITonolih

~qAdO",qllit"

~ 01--9' 0.6Sc oleo

08 1 Km.-

13

Darab_ I~A ~ I _ --_:-.':~_J::. ~.•-::..... _""T .. _ .._._':._ .. ~._... __.no'" •• " _

.... -- , t f,'11 '.1'; lieu.'. MnIMIr.~I. ,.•

~i.ratilicntlo,.. •.......•V .

Foliation \-/

OOl..ll'ldary of liiholoqy

rOillt

1111 e rol ",I',llltll

Anti,II",. (I.ls

Syn'hf'lf' ad"

'.\ ........ _.:, ."

. ~.:. --=-,r. ,....:.''\~\"', ~-=-":II •• -

Fig. 3. Geological map of Darab

26

'J ~I:

~ lonul dc'S

'~ r~((Jno(!i0ri\{':;

..A Lulc - (jll\d[; cJrufl,tt':)

v /',[}..;(!! ~{rC1n ill'S

FI\.:ld of (Jrt') ..'•.•..(Jckt'~

Cloys

•. :J J Cont inc'n\cll c loy~; 0f tr\l,:{rdl~ I((j! bt:! t

.•••o'.!~1(J(;r'L· Cluys

ACFA' KF

1.

SWO197 Clay Clay2.

SWO97 AI-rich ClayClay3.

SWO185 AI-rich ClayClay4.

MW 70 AI-rich ClayClay5.

MW 20 Greywacke6.

MW 9 Greywacke.

Fig. 4. Plot of chemical composition calculated from modal analysis of Darabmetamorphic rocks on ACF and A'KF diagram of winkler

27