496 Organometallics, Vol. 11, No. 1, 1992 Additions and Corrections

Additions and Corrections

Richard D. Adams,* Michael P. Pompeo, and James T. Tanner: Clusters Containing Carbene Ligands. 10. Transformation of an Ynamine into an Aminocarbene Ligand by Unsymmetric Hydrogenation with a Triosmium Cluster Complex. 1991, 10, 1068.

In Table I, /3 for compound 3 should be 91.72 (2)O.

Richard D. Adams* and Gong Chen: Clusters Containing Carbene Ligands. 11. Carbene Ligand Transfer. Reaction of O S ~ ( C O ) ~ ~ [ C ( E ~ ) N M ~ ~ ] with Terminal Alkynes. 1991, 10, 3020.

In Table I, the following data should be added or changed compound 3, in the IR data 2047 s should be 2074 s and in the ‘H NMR data 1.07 (3 H, t, Me, 3JH-H = 7.6 Hz), 0.98 (9 H, s, But) should be added; compound 5, in the IR data 1988 s should be 1998 s and in the ‘H NMR

should be added. data 1.08 (3 H, t, Me, 3 J ~ - ~ = 7.7 Hz), 1.08 (9 H, S, But)

T. van der Graaf, R. M. J. Hofstra, P. G. M. Schilder, M. Rijkhoff, D. J. Stufkens,* and J. G. M. van der Linden*: Metal to Ligand Charge-Transfer Photochemistry of Metal-Metal-Bonded Complexes. 10. Photochemical and Electrochemical Study of the Electron-Transfer Reactions of Mn(CO)3(a-diimine)(L)’ (L = N-, P-Donor) Radicals Formed by Irradiation of (CO)SMnMn(C0)3(a-diimine) Complexes in the Presence of L. 1991,10, 3668.

In Figure 1, bpy’ should be drawn as the 4,4’-dimethyl compound.

Roger Rowseau and Douglas W. Stephan*: Bonding and Conformational Aspects of Thiolato-Bridged Early-Late Heterobimetallics. 1991, 10, 3399.

In the third line of the first paragraph of the Calcula- tions section on page 3400, the formula should read [CpzM(r-SH)zM’(SHz),]+. Rows 4-6 in Table I should read as follows:

compd M-M‘ ref model M-M’ NOP Cp2Ti(p-SMe)2Mo(C0)4 3.321 (2) 24 Cp,Ti(pSH),Mo(CO), 0.025 [ C P ~ N ~ ( ~ - S P ~ ) ~ M O ( C O ) , ~ + 3.116 (2) 8 [CP~N~(~-SH)ZMO(CO),I+ 0.110 [Cp2Ti(p-SCH2CH2PPh2)2Cu]+ 3.024 (1) 5 [ C P ~ T ~ G - S H ) ~ C U ( P H ~ ) ~ I + 0.010