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K-35660/31501 - IRELAND
Safety Information
Cameo® Max SX®
Herbicide
Contains 250 g/kgtribenuron methyl and250 g/kg thifensulfuronmethylContains Tribenuron-methyl. May produce anallergic reaction
Very toxic to aquatic life with long lasting effects.Collect spillage.Dispose of contents / container to a licensedhazardous-waste disposal contractor or collectionsite except for triple rinsed empty clean containerswhich can be disposed of as non-hazardous waste.
To avoid risks to human health and theenvironment, comply with the instructions for use.
PCS No 03135
SAFETY PRECAUTIONS
Operator Protection
WASH HANDS AND EXPOSED SKIN before eating and drinking and afterwork
Environmental Protection
DO NOT CONTAMINATE SURFACE WATERS OR DITCHES with chemicalor used containerDo not contaminate water with the product or its container (Do not cleanapplication equipment near surface water/Avoid contamination via drainsfrom farmyards and roads).To protect aquatic organisms respect an unsprayed buffer zone of 5m tosurface water bodies.Direct spray away from water
Storage and Disposal
KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe placeTHIS MATERIAL AND ITS CONTAINER must be disposed of in a safe way
Manufactured in the E.U.
Du Pont (U.K.) Limited, Crop Protection Products,
Wedgwood Way, Stevenage, Herts. SG1 4QN. England
Tel: 00 44 1438 734450 or [email protected]
National Poisons Centre : (01) 837 9964 or 01 809 2166
Emergency telephone: (01) 901 4670
For Professional Use only
Contents:180 g
PCS No 03135
A water soluble granule formulation containing250 g/kg tribenuron methyl and 250 g/kgthifensulfuron methyl, both sulfonylureas, for weedcontrol in wheat and barley, oats, rye and triticale.® Registered trademark of E. I. du Pont de Nemours and Company
WARNING
Cameo® Max SX®
CEREAL HERBICIDE
GROUP HERBICIDEB
SX®
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Cameo® Max SX®
cereal herbicide
PCS No 03135
A water soluble granule formulation containing 250 g/kg tribenuron methyl and250 g/kg thifensulfuron methyl, both sulfonylureas, for weed control in wheatand barley, oats, rye and triticale.
Manufactured in the E.U.
Du Pont (U.K.) Limited,
Crop Protection Products,
Wedgwood Way, Stevenage, Herts. SG1 4QN. England
Tel: 00 44 1438 734450 or
National Poisons Centre : (01) 837 9964 or 01 809 2166
Emergency telephone: (01) 901 4670
For Professional Use only
® Registered trademark of E. I. du Pont de Nemours and CompanyAll other trademarks are duly acknowledged.
IMPORTANT INFORMATION
Field of Use: FOR USE ONLY AS AN AGRICULTURAL HERBICIDE
Crops: Winter Wheat, spring wheat, winter barley, springbarley, oats, rye and triticale.
Maximum single dose: 60 g/ha
Maximum no of application at aSingle dose: One per crop
Latest time of application: Up to and including flag leaf ligule/collar justvisible (GS 39)
Maximum total dose: 60 g product/ha
Method of application: Tractor mounted sprayer / knapsack
READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT ISINCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OFPRACTICE FOR USING PLANT PROTECTION PRODUCTS
DIRECTIONS FOR USE
IMPORTANT: This information is approved as part of the Product Label. Allinstructions within this section must be read carefully in order to obtain safeand successful use of this product.
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Restrictions• Do not apply to any crop suffering from stress as a result of drought, water-
logging, low temperatures, pest or disease attack, nutrient or lime deficiencyor other factors reducing crop growth.
• Do not apply to crops undersown with grass, clover or other legumes or anyother broad-leaved crop.
• Do not apply more than once to any cereal crop.• Do not apply within seven days of rolling the crop.• Contract agents should be consulted before using on crops grown for seed.• Due to the high level of activity of the herbicide, special care must be taken
to avoid damage by drift onto broad-leaved plants outside the target area, oronto ponds, waterways or ditches. Thorough cleansing of equipment is alsovery important - see below.
• Only the following sulfonylurea and other ‘ALS inhibiting’ herbicides can beapplied in sequence with Cameo® Max SX®:- Lexus Class- Pacifica
Weed ControlCameo® Max SX® contains thifensulfuron-methyl and tribenuron-methyl,sulfonylurea (ALS inhibitor) herbicides that work predominantly by foliar actionwith some root activity. It controls a wide range of broad-leaved weeds and ismost effective if applied when the weeds are small and actively growing. Goodspray cover of weeds must be obtained and since larger weeds often become
less susceptible, it is important to note the size of each weed at the time ofapplication. Susceptible plants cease growth almost immediately after post-emergence treatment and symptoms can be seen about two weeks after springapplication. It is also important to identify the weeds occurring in the crop andrefer to the weed table to ensure that the weeds present are those susceptibleto Cameo® Max SX®. The susceptibility ratings of weeds in the following tablerefer to good spray cover and good growing conditions.
Weed ResistanceWhen herbicides with the same mode of action are used repeatedly overseveral years in the same field, selection of resistant biotypes can take place.These can propagate and may become dominating. A weed species isconsidered resistant to a herbicide if it survives a correctly-applied treatmentat the recommended dose.
Development of resistance within a weed species can be avoided or delayedby sequencing or tank-mixing with suitable products having a different mode ofaction. For control of Corn Marigold or Chickweed this product must always beapplied with an alternative mode of action product at recommended rates.
A strategy for preventing and managing resistance should be adopted. Furtherdetails and advice on how to implement such a strategy may be obtained fromyour crop advisor or chemical supplier. The Herbicide Resistance ActionCommittee (HRAC) also produces guidelines which may be consulted foradditional information.
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Susceptible WeedsThe susceptibility ratings of weeds in the following table refer to good spraycover and good growing conditions.
Plants up to Plants up to Plants up toWeed Species 2 expanded 6 expanded 15 cm
true leaves true leaves across/high
Black-bindweed S S MSCharlock* S S SChickweed, Common* S S SDead-nettle, Red* S S MSBroad-leaf dock‡ S S SFat-hen S S MSForget-me-not* S S MSFumitory* S S RHemp-nettle, Common S S —Mayweed* S S SPoppy, Common* S S RRedshank S S MSShepherd’s-purse* S S MS
S = Susceptible MS = Moderately Susceptible MR = Moderately Resistant R = Resistant * Controlled by autumn or spring applications up to six leaves.‡ Curled docks (Rumex crispus) are not controlled by Cameo® Max SX®. Broad-leaved docks germinatingafter application are not controlled.
Soil and weatherCameo® Max SX® can be used on all soil types. Weed control may be reducedwhen conditions are very dry.
Volume and applicationBEFORE USING CAMEO® MAX SX®, SPRAYING EQUIPMENT MUST BE CLEANAND FREE FROM CONTAMINATION WITH OTHER PESTICIDES.Application should be made in 200 litres of water per hectare using suitableground equipment to give good spray cover of the weeds. Use a conventionalfield crop sprayer at a pressure of 2 - 3 bars and apply as a MEDIUM spray (asdefined by BCPC). Care should be taken not to overlap spray swaths.
MixingQuarter fill the spray tank with clean water, start the agitation and add therequired quantity of Cameo® Max SX® directly to the tank without priorcreaming. Continue agitation while topping up the tank and while spraying.
CompatibilityIn any tank-mix add Cameo® Max SX® to the tank first and ensure it is fullydispersed before adding the partner product. Products should only be tank-mixed if each product can be applied within the label recommendations for itsuse. For further information contact your DuPont distributor.
CropsCameo® Max SX® can be used on all varieties of winter and spring wheat andbarley, oats, rye and triticale.
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TimingCameo® Max SX® should be applied from the three-leaf stage up to andincluding the flag leaf ligule/collar just visible (GS 39).
DoseApply Cameo® Max SX® at 60 g/ha.
Following CropsCereals, field beans or oilseed rape may be sown in the same calendar year asharvest of a cereal crop treated with Cameo® Max SX®. Before sowing, soilshould be ploughed and cultivated to a depth of at least 15 cm. In the event of acrop failure for any reason, sow only a cereal crop within three months ofapplication of Cameo® Max SX® After three months field beans and oilseedrape may also be sown.
WARNINGSEXTREME CARE SHOULD BE TAKEN TO AVOID DAMAGE BY DRIFT OF SPRAYONTO BROAD-LEAVED PLANTS OUTSIDE THE TARGET AREA OR ONTO SURFACEWATERS OR DITCHES OR LAND INTENDED FOR CROPPING. SPRAYINGEQUIPMENT SHOULD NOT BE DRAINED OR FLUSHED ONTO LAND PLANTED WITHOR INTENDED FOR PLANTING WITH TREES OR CROPS OTHER THAN CEREALS.POOR CLEANOUT PRACTICES AND INSUFFICIENT WATER VOLUMES USEDFOR THE RINSE PROCEDURE MAY RESULT IN INADEQUATE REMOVAL OFPRODUCT DEPOSITS. SUBSEQUENT USE OF APPLICATION EQUIPMENT INTHESE CIRCUMSTANCES MAY RESULT IN DAMAGE TO NON-CEREAL CROPS.
SPRAY TANK CLEAN-OUTTO AVOID SUBSEQUENT DAMAGE TO CROPS OTHER THAN CEREALS,IMMEDIATELY AFTER SPRAYING CAMEO® MAX SX® THOROUGHLY CLEAN ALLSPRAY EQUIPMENT, INCLUDING INSIDE AND OUTSIDE OF LID, USING THEFOLLOWING PROCEDURE:
Always start with a clean tank and spray system. Clean spray equipmentthoroughly immediately after use. 1. Thoroughly and completely rinse all interior tank surfaces (including lid) with
water (use at least 10% of the tank capacity), taking care to remove anyvisible deposits. Flush pump, filters and boom after removing in-linestrainers, nozzle tips and screens (clean these parts separately). Drain theremainder of the rinsate from the tank.
2. Repeat the rinse, flush and drain.
GENERAL NOTES: Consult label tank cleanup procedures for all tank mix partners and be sure touse the most rigorous procedure recommended.
NOTICE TO BUYERAll goods supplied by us are of a high grade and we believe them to be suitable forany purpose for which we expressly supply them, but as we cannot exercise controlover their mixing or use, all conditions and warranties, statutory or otherwise, as tothe quality or fitness for any purpose of our goods are excluded and no responsibilitywill be accepted by us for any damage or injury whatsoever arising from theirstorage, handling, application or use.
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SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 and 453/2010
Version 5.0 Revision Date 28.11.2013 Ref. 130000027529
This Safety Data Sheet adheres to the standards and regulatory requirements of the Republic of Ireland andmay not meet the regulatory requirements of other countries.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name : CAMEO® MAX SX
Synonyms : B12014143DPX-GBF92 50SG
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture : Herbicide
1.3. Details of the supplier of the safety data sheet
Company : Du Pont (UK) LimitedWedgwood WayStevenage, Herts. SG1 4QN United Kingdom
Telephone : +44 (0) 1438 734 000
E-mail address : [email protected]
1.4. Emergency telephone number
Emergency telephone number : +353 (0) 1901 4670
SECTION 2: Hazards identification
2.1. Classification of the substance or mixtureAcute aquatic toxicity, Category 1 H400: Very toxic to aquatic life.Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects.Dangerous for the environment R50/53: Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
2.2. Label elements
H410Very toxic to aquatic life with long lasting effects.
Special labelling of certain substances and mixtures
EUH401: To avoid risks to human health and the environment, complywith the instructions for use.,
Contains: Tribenuron methyl / EUH208: May produce an allergicreaction.,
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposalplant.
SP 1 Do not contaminate water with the product or its container (Do not clean application equipment nearsurface water/Avoid contamination via drains from farmyards and roads).
2.3. Other hazardsThis mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
SECTION 3: Composition/information on ingredients
3.1. Substances not applicable
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WARNING
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3.2. Mixtures
Tribenuron methyl (CAS-No.101200-48-0) (EC-No.401-190-1)
Thifensulfuron methyl (CAS-No.79277-27-3)
Sodium carbonate (CAS-No.497-19-8) (EC-No.207-838-8)
Trisodium phosphate dodecahydrate (CAS-No.10101-89-0)
The above products are REACH compliant; Registration number(s) may not be provided because substance(s)are exempted, not yet registered under REACH or are registered under another regulatory process (biocideuses, plant protection products), etc.For the full text of the R-phrases mentioned in this Section, see Section 16.For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice : Never give anything by mouth to an unconscious person. Forspecialist advice contact the National Poisons InformationService. Healthcare Professionals: (01) 809 2566 or (01) 837 9964(24h per day – 365 days per year). Public Poisons InformationLine: (01) 809 2166 (8am-10pm).
Inhalation : Move to fresh air. Consult a physician after significant exposure.Artificial respiration and/or oxygen may be necessary.
Skin contact : Take off contaminated clothing and shoes immediately. Washoff immediately with soap and plenty of water. In the case of skinirritation or allergic reactions see a physician. Washcontaminated clothing before re-use.
Eye contact : If easy to do, remove contact lens, if worn. Hold eye open andrinse slowly and gently with water for 15-20 minutes. If eyeirritation persists, consult a specialist.
Ingestion : Obtain medical attention. DO NOT induce vomiting unlessdirected to do so by a physician or poison control center. If victimis conscious: Rinse mouth with water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms : No cases of human intoxication are known and the symptoms ofexperimental intoxication are not known.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Water spray, Dry chemical, Foam, Carbon dioxide (CO2)
Extinguishing media which shall not be used for safety reasons : High volume water jet, (contamination risk)
5.2. Special hazards arising from the substance or mixture
Specific hazards during firefighting : Hazardous decomposition products formed under fire conditions.Carbon dioxide (CO2) nitrogen oxides (NOx)
5.3. Advice for firefighters
Special protective equipment for firefighters : Wear full protective clothing and self-contained breathing
apparatus.
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Registration number Classificationaccording Directive67/548/EEC
Classification according toRegulation (EU) 1272/2008(CLP)
Concentration
R43N;R50/53
Skin Sens. 1; H317Aquatic Acute 1; H400Aquatic Chronic 1; H410
25 %
N;R50/53 Aquatic Acute 1; H400Aquatic Chronic 1; H410
25 %
01-2119485498-19 Xi;R36 Eye Irrit. 2; H319 >= 10 - < 15 %
01-2119489800-32 C;R34 Skin Corr. 1C; H314Eye Dam. 1; H318
>= 5 - < 10 %
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Further information : Prevent fire extinguishing water from contaminating surfacewater or the ground water system. Collect contaminated fireextinguishing water separately. This must not be discharged intodrains. Fire residues and contaminated fire extinguishing watermust be disposed of in accordance with local regulations.
: (on small fires) If area is heavily exposed to fire and if conditionspermit, let fire burn itself out since water may increase the areacontaminated. Cool containers / tanks with water spray.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions : Control access to area. Avoid dust formation. Avoid breathingdust. Use personal protective equipment. Refer to protectivemeasures listed in sections 7 and 8.
6.2. Environmental precautions
Environmental precautions : Prevent further leakage or spillage if safe to do so. Useappropriate container to avoid environmental contamination. Donot flush into surface water or sanitary sewer system. Do notallow material to contaminate ground water system. Localauthorities should be advised if significant spillages cannot becontained. If the spill area is porous, the contaminated materialmust be collected for subsequent treatment or disposal. If theproduct contaminates rivers and lakes or drains informrespective authorities.
6.3. Methods and materials for containment and cleaning up
Other information : Never return spills in original containers for re-use. Dispose of inaccordance with local regulations.
6.4. Reference to other sections
For personal protection see section 8., For disposal instructions see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling : Use only according to our recommendations. Use only cleanequipment. Avoid contact with skin, eyes and clothing. Do notbreathe dust or spray mist. Wear personal protective equipment.For personal protection see section 8. Prepare the workingsolution as given on the label(s) and/or the user instructions. Useprepared working solution as soon as possible - Do not store.Provide appropriate exhaust ventilation at places where dust isformed. Wash hands before breaks and immediately afterhandling the product. Remove and wash contaminated clothingbefore re-use. Avoid exceeding of the given occupationalexposure limits (see section 8).
Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Avoid dust
formation in confined areas. During processing, dust may formexplosive mixture in air.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers : Store in original container. Keep in properly labelled containers.
Keep containers tightly closed in a dry, cool and well-ventilatedplace. Store in a place accessible by authorized persons only.Keep out of the reach of children.
Advice on common storage : No special restrictions on storage with other products.
Other data : Stable under recommended storage conditions.
7.3. Specific end use(s)
Plant protection products subject to Regulation (EC) No 1107/2009.
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SECTION 8: Exposure controls/personal protection
8.1. Control parameters
If sub-section is empty then no values are applicable.
8.2. Exposure controls
Engineering measures : Ensure adequate ventilation, especially in confined areas.Provide for appropriate exhaust ventilation and dust collection atmachinery. Contains no substances with occupational exposurelimit values.
Eye protection : Safety glasses with side-shields conforming to EN166
Hand protection : Material: Nitrile rubberGlove thickness: 0.3 mmGlove length: Standard glove type. Protection index: Class 6Wearing time: > 480 minThe selected protective gloves have to satisfy the specificationsof EU Directive 89/686/EEC and the standard EN 374 derived fromit. Please observe the instructions regarding permeability andbreakthrough time which are provided by the supplier of thegloves. Also take into consideration the specific local conditionsunder which the product is used, such as the danger of cuts,abrasion, and the contact time. The suitability for a specificworkplace should be discussed with the producers of theprotective gloves. Gloves must be inspected prior to use. Glovesshould be discarded and replaced if there is any indication ofdegradation or chemical breakthrough. Gauntlets shorter than35 cm long shall be worn under the combination sleeve. Beforeremoving gloves clean them with soap and water.
Skin and body protection : Manufacturing and processing work: Full protective clothingType 5 (EN 13982-2) Mixer and loaders must wear: Full protective clothing Type 5 + 6(EN ISO 13982-2 / EN 13034) Rubber apron Rubber or plastic bootsSpray application - outdoor: Tractor / sprayer with hood: Nopersonal body protection normally required.
Tractor / sprayer without hood: Low application (horticulture,field crops): Full protective clothing Type 4 (EN 14605) Rubber orplastic bootsBackpack / knapsack sprayer: Low application (horticulture, fieldcrops): Full protective clothing Type 4 (EN 14605) Rubber orplastic bootsWhen exceptional circumstances require an access to thetreated area before the end of re-entry periods, wear fullprotective clothing Type 6 (EN 13034), nitrile rubber gloves class3 (EN 374) and nitrile rubber boots (EN 13832-3 / EN ISO 20345).To optimize the ergonomy it may be recommended to use cottonunderwear when wearing some fabrics. Take advice fromsupplier. Garment materials that are resistant to both watervapour and air will maximise wearing comfort. Materials shouldbe robust to maintain the integrity and barrier in use. Thepermeation resistance of the fabric must be verifiedindependently of the « type » protection recommended, to ensurean appropriate performance level of the material adequate to thecorresponding agent and type of exposure.
Protective measures : The type of protective equipment must be selected according tothe concentration and amount of the dangerous substance atthe specific workplace. All chemical protective clothing shouldbe visually inspected prior to use. Clothing and gloves should bereplaced in case of chemical or physical damage or ifcontaminated. Only protected handlers may be in the area duringapplication.
Hygiene measures : Handle in accordance with good industrial hygiene and safetypractice. Regular cleaning of equipment, work area and clothing.Keep working clothes separately. Contaminated work clothingshould not be allowed out of the workplace. Wash hands andface before breaks and immediately after handling the product.When using do not eat, drink or smoke. Keep away from food,drink and animal feedingstuffs. For environmental protectionremove and wash all contaminated protective equipment beforere-use. Remove clothing/PPE immediately if material gets inside.Wash thoroughly and put on clean clothing. Dispose of rinsewater in accordance with local and national regulations.
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Respiratory protection : Manufacturing and processing work: Half mask with a particlefilter FFP1 (EN149)Mixer and loaders must wear: Half mask with a particle filter FFP1(EN149) Spray application - outdoor: Tractor / sprayer with hood:No personal respiratory protective equipment normally required.Tractor / sprayer without hood: Half mask with a particle filter P1(EN 143). Backpack / knapsack sprayer: Half mask with a particlefilter P1 (EN 143). Mechanical automatized spray application inclosed tunnel: No personal respiratory protective equipmentnormally required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical propertiesForm : solid, granularColour : light brownOdour : slightOdour Threshold : not determinedpH : 9.4 at 10 g/l ( 20 °C), Method: CIPAC MT 75Melting point/range : Not available for this mixture. Boiling point/boiling range : not applicableFlammability (solid, gas) : Does not sustain combustion. Thermal decomposition : Not available for this mixture. Auto-ignition temperature : 387 °COxidizing properties : The product is not oxidizing. Explosive properties : Not explosiveLower explosion limit/ lower flammability limit : (for a component of this mixture)Upper explosion limit/ upper flammability limit : Not available for this mixture. Vapour pressure : Not available for this mixture. Bulk density : 707 kg/m3 , packedWater solubility : solublePartition coefficient: n-octanol/water : not applicable
Viscosity, dynamic : not applicableRelative vapour density : Not available for this mixture. Evaporation rate : not applicableMinimum ignition energy : > 1,000 mJ
9.2. Other information
Phys.-chem./other information : No other data to be specially mentioned.
SECTION 10: Stability and reactivity
10.1. Reactivity : No hazards to be specially mentioned.
10.2. Chemical stability : The product is chemically stable under recommended conditionsof storage, use and temperature.
10.3. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use.Polymerization will not occur. No decomposition if stored andapplied as directed.
10.4. Conditions to avoid : Exposure to moisture. Decomposes slowly on exposure to water.To avoid thermal decomposition, do not overheat. Under severedusting conditions, this material may form explosive mixtures inair.
10.5. Incompatible materials : No materials to be especially mentioned.
10.6. Hazardous decomposition products : No materials to be especially mentioned.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute oral toxicity LD50 / rat : > 5,000 mg/kgMethod: Fixed Dose MethodThe toxicological data has been taken from products of similarcomposition. Information source: Internal study report
Acute inhalation toxicity Tribenuron methylLC50 / 4 h rat : > 6.0 mg/l
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Thifensulfuron methylLC50 / 4 h rat : > 7.9 mg/l
Acute dermal toxicity LD50 / rat : > 5,000 mg/kgMethod: OECD Test Guideline 402The toxicological data has been taken from products of similarcomposition. Information source: Internal study report
Skin irritation ratResult: No skin irritationMethod: OECD Test Guideline 404The toxicological data has been taken from products of similarcomposition. Information source: Internal study report
Eye irritation rabbitResult: No eye irritationMethod: OECD Test Guideline 405The toxicological data has been taken from products of similarcomposition. Information source: Internal study report
Sensitisation mouse Local lymph node testResult: Animal test did not cause sensitization by skin contact.Method: OECD Test Guideline 429(Data on the product itself) Information source: Internal studyreport
Repeated dose toxicity Tribenuron methylThe following effects occurred at levels of exposure thatsignificantly exceed those expected under labeled usageconditions.
Oral ratExposure time: 28 dReduced body weight gain
Thifensulfuron methylThe following effects occurred at levels of exposure thatsignificantly exceed those expected under labeled usageconditions.
Oral - feed multiple speciesReduced body weight gain
Mutagenicity assessment Tribenuron methylAnimal testing did not show any mutagenic effects. Tests onbacterial or mammalian cell cultures did not show mutageniceffects.
Thifensulfuron methylTests on bacterial or mammalian cell cultures did not showmutagenic effects.
Carcinogenicity assessment Tribenuron methylNot classifiable as a human carcinogen. An increased incidenceof tumours was observed in laboratory animals. Target(s):Mammary glands
Thifensulfuron methylAnimal testing did not show any carcinogenic effects.
Toxicity to reproduction assessment Tribenuron methylNo toxicity to reproduction
Thifensulfuron methylNo toxicity to reproduction
Assessment teratogenicity Thifensulfuron methylDid not show teratogenic effects in animal experiments. Animaltesting showed effects on embryo-fetal development at levelsequal to or above those causing maternal toxicity.
STOT - single exposure The substance or mixture is not classified as specific targetorgan toxicant, single exposure.
STOT - repeated exposure The substance or mixture is not classified as specific targetorgan toxicant, repeated exposure.
Aspiration hazard The mixture does not have properties associated with aspirationhazard potential.
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SECTION 12: Ecological information
12.1. Toxicity
Toxicity to fish static test / LC50 / 96 h / Oncorhynchus mykiss (rainbow trout): >120 mg/lMethod: OECD Test Guideline 203The toxicological data has been taken from products of similarcomposition. Information source: Internal study report
Toxicity to aquatic plants ErC50 / 72 h / Pseudokirchneriella subcapitata (green algae): 0.16mg/lMethod: OECD Test Guideline 201(Data on the product itself) Information source: Internal studyreport
ErC50 / 168 h / Lemna gibba (duckweed): > 0.0036 mg/lMethod: OECD Test Guideline 221(Data on the product itself) Information source: Internal studyreport
Toxicity to aquatic invertebrates static test / 48 h / Daphnia magna (Water flea): > 120 mg/lMethod: OECD Test Guideline 202The toxicological data has been taken from products of similarcomposition. Information source: Internal study report
Chronic toxicity to fish Tribenuron methylNOEC / 21 d / Oncorhynchus mykiss (rainbow trout): > 560 mg/l
Thifensulfuron methylNOEC / 21 d / Oncorhynchus mykiss (rainbow trout): > 250 mg/l
Chronic toxicity to aquatic Invertebrates Tribenuron methylNOEC / 21 d / Daphnia magna (Water flea): 120 mg/l
Thifensulfuron methylNOEC / 28 d / Americamysis bahia (mysid shrimp): 7.93 mg/l
12.2. Persistence and degradability
Biodegradability Not readily biodegradable. Estimation based on data obtainedon active ingredient.
Tribenuron methylAccording to the results of tests of biodegradability this productis not readily biodegradable.
Thifensulfuron methylAccording to the results of tests of biodegradability this productis not readily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulation Does not bioaccumulate. Estimation based on data obtained onactive ingredient.
Tribenuron methylDoes not bioaccumulate.
Thifensulfuron methylDoes not bioaccumulate.
12.4. Mobility in soil
Mobility in soil : Under actual use conditions, there is no reasonable expectationof any movement of the product from the top soil layer.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment : This mixture contains no substance considered to be persistent,bioaccumulating nor toxic (PBT). / This mixture contains nosubstance considered to be very persistent nor verybioaccumulating (vPvB).
12.6. Other adverse effects
Additional ecological information : No other ecological effects to be specially mentioned Seeproduct label for additional application instructions relating toenvironmental precautions.
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SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product : In accordance with local and national regulations. Must beincinerated in a suitable incineration plant holding a permitdelivered by the competent authorities. Do not contaminateponds, waterways or ditches with chemical or used container.
Contaminated packaging : Do not re-use empty containers.
SECTION 14: Transport information
ADR14.1. UN number: 307714.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Tribenuron methyl, Thifensulfuron-methyl)14.3. Transport hazard class(es): 914.4. Packing group: III14.5. Environmental hazards: Environmentally hazardous14.6. Special precautions for user:
Tunnel restriction code: (E)
IATA_C14.1. UN number: 307714.2. UN proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Tribenuron
methyl, Thifensulfuron-methyl)14.3. Transport hazard class(es): 914.4. Packing group: III14.5. Environmental hazards : Environmentally hazardous14.6. Special precautions for user:
DuPont internal recommendations and transport guidance: ICAO / IATA cargo aircraft only
IMDG14.1. UN number: 307714.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Tribenuron methyl, Thifensulfuron-methyl)
14.3. Transport hazard class(es): 914.4. Packing group: III14.5. Environmental hazards : Marine pollutant14.6. Special precautions for user: no data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codenot applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Other regulations : The product is classified as dangerous in accordance withRegulation (EC) No. 1272/2008.Take note of Dir 94/33/EC on theprotection of young people at work.Take note of Directive98/24/EC on the protection of the health and safety of workersfrom the risks related to chemical agents at work.Take note ofDirective 96/82/EC on the control of major-accident hazardsinvolving dangerous substances.Take note of Directive2000/39/EC establishing a first list of indicative occupationalexposure limit values.
15.2. Chemical Safety Assessment
A Chemical Safety Assessment is not required for this/these productsThe mixture is registered as a plant protection product under Regulation (EC) No. 1107/2009. Refer to the labelfor exposure assessment information.
SECTION 16: Other information
Text of R-phrases mentioned in Section 3
R34 Causes burns. R36 Irritating to eyes.R43 May cause sensitisation by skin contact.
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R50/53 Very toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.
Full text of H-Statements referred to under section 3.
H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.
Other information professional use
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage ofDangerous Goods by Road
ATE Acute toxicity estimateCAS-No. Chemical Abstracts Service numberCLP Classification, Labelling and PackagingEbC50 Concentration at which 50% reduction of biomass is observedEC50 Median effective concentrationEN European NormEPA Environmental Protection AgencyErC50 Concentration at which a 50% inhibition of growth rate is
observedEyC50 Concentration at which 50 % inhibition of yield is observedIATA_C International Air Transport Association (Cargo) IBC International Bulk Chemical CodeICAO International Civil Aviation Organization ISO International Standard Organization IMDG International Maritime Dangerous GoodsLC50 Median Lethal ConcentrationLD50 Median Lethal DoseLOEC Lowest Observed Effect ConcentrationLOEL Lowest observable effect levelMARPOL International Convention for the Prevention of Marine Pollution
from Ships
n.o.s. Not Otherwise SpecifiedNOAEC No Observed Adverse Effect ConcentrationNOAEL No observed adverse effect level NOEC No Observed Effect Concentration NOEL No Observed Effect LevelOECD Organisation for Economic Co-operation and DevelopmentOPPTS Office of Prevention, Pesticides and Toxic SubstancesPBT Persistent, Bioaccumulative and ToxicSTEL Short term exposure limitTWA time weighted averagevPvB very Persistent and very Bioaccumulative
Further information
Take notice of the directions of use on the label.® Registered trademark of E.I. du Pont de Nemours and Company
Significant change from previous version is denoted with a double bar.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guide for safe handling, use,processing, storage, transportation, disposal and release and is not to be considered a warranty or qualityspecification. The above information relates only to the specific material(s) designated herein and may not bevalid for such material(s) used in combination with any other materials or in any process or if the material isaltered or processed, unless specified in the text.
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