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Print Date 29-Jul-2013 Revision date 29-Jul-2013
MATERIAL SAFETY DATASHEET
Revision Number 3
Irritating to respiratory system.
F041-0001
Manufacturer
INGESTION MAY BE HARMFUL IF SWALLOWED. Do not induce vomiting: may contain petroleumdistillates and/or aromatic solvents. Aspiration may cause pulmonary edema andpneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic Effects
Emergency Telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential Health Effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
common name NO. 1 THINNER
Aggravated Medical Conditions central nervous system. Kidney disorders. Skin disorders. Respiratory disorders.
Principle Routes of Exposure Eye Contact, inhalation, Skin Contact.
2. Hazards Identification
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
ACUTE EFFECTS
Potential Environmental Effects See Section 12 for additional Ecological Information.
EYES Moderately irritating to the eyes.
EMERGENCY OVERVIEW
______________________________________________________________________________________________
skin Irritating to skin.
Product Code
Page 1 / 6
inhalation
COMBUSTIBLE LIQUID AND VAPORHARMFUL IF INHALED
HARMFUL OR FATAL IF SWALLOWEDMAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
WARNING
______________________________________________________________________________________________Revision date 29-Jul-2013
-THINNER CLEARF041-0001
Hazardous Components
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. Solventvapors are heavier than air and may spread along floors. Flash back possible over considerable distance.
4. First aid measures
Target organ effects
INHALATION: Move to fresh air. Oxygen or artificial respiration if needed
6. Accidental release measures
component
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
CAS-No
5. Fire-fighting measures
Weight %
Eye contact:
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
Rinse thoroughly with plenty of water for at least 15 minutes.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Flammable properties Combustible material.
SOLVENT NAPHTHA
OTHER INFORMATION not applicable
64742-88-7
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
Skin contact:
7. Handling and Storage
Wash off immediately with soap and plenty of water
60 - 100
central nervous system, EYES, kidney, respiratory system, skin
Hazardous Decomposition Products
______________________________________________________________________________________________
Oxides of carbon, hydrocarbons.
3. Composition/information on Ingredients
Page 2 / 6
Ingestion:
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
If swallowed, do not induce vomiting. Get medical attention immediately.
______________________________________________________________________________________________THINNER CLEARF041-0001
Revision date 29-Jul-2013-
volatile organic compounds (VOC) content 6.460 lbs/gal
General Hygiene Considerations
Volatile by weight 100.0000 %
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
Engineering measures
Volatile by volume 100.0000 %
Ensure adequate ventilation, especially in confined areas
StorageClose container after each use. Keep away from heat, sparks and flame Use only in an area containing flame proof equipment.Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
10. Stability and Reactivity
9. Physical and Chemical Properties
HandlingAvoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice Remove andwash contaminated clothing before re-use. Do not eat, drink or smoke when using this product When used in a mixture, read thelabels and safety data sheets of all components. Wash thoroughly after handling
Exposure guidelines
Personal protective equipment
Flash Point 38 °C / 100.0 °FBoiling range 271 - 271.000 °C / 519 - 520 °F
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Upper explosion limit No information available
Skin Protection
11. Toxicological Information
Lightweight protective clothing, Apron, Impervious gloves
Lower explosion limit No information available
Acute Toxicity
Evaporation Rate No information available
Component Information
Eye/face Protection
vapor pressure
component LD50 Oral LD50 Dermal LC50 Inhalation
No information available
Safety glasses with side-shields
SOLVENT NAPHTHA 5000 mg/kg ( Rat ) 3000 mg/kg ( Rabbit ) 5.28 mg/L ( Rat ) 4 h
Vapor Density No information availableSpecific gravity .77630 g/cm3
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
density 6.45999 lbs/gal
______________________________________________________________________________________________
Strong oxidizing agents.Chemical stability Stable Conditions to Avoid
Page 3 / 6
Heat, flames and sparks.Possibility of HazardousReactions
None under normal processingIncompatible products
______________________________________________________________________________________________
-THINNER CLEARF041-0001
Revision date 29-Jul-2013
12. Ecological Information
Mutegenicity No information available.
14. Transport Information
irritation No information available
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
ecotoxicity
Reproductive Effects No information available.
Proper Shipping Name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
Chronic Toxicity
15. Regulatory information
Developmental Effects No information available.
sensitization
International Inventories
No information available.
component Toxicity to algae Toxicity to fish
TSCA Complies
Toxicity toMicroorganisms
Toxicity to daphnia
DSL/NDSL Does not comply
Teratogenicity No information available.
EINECS/ELINCS Complies
SOLVENT NAPHTHA EC50 = 450 mg/L 96 h
China Complies
LC50= 800 mg/LPimephales promelas 96 h
ENCS Complies
EC50 > 100 mg/L 48 h
carcinogenicity
KECL Complies
The table below indicates whether each agency has listed any ingredient as a carcinogen.
PICCS Complies
Target organ effects central nervous system, EYES, kidney, respiratory system, skin.
AICS Complies
13. Disposal Considerations
corrosivity No information available.
United States of America Federal Regulations
Endocrine Disruptor Information No information available
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
______________________________________________________________________________________________
Page 4 / 6
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
______________________________________________________________________________________________Revision date 29-Jul-2013
-THINNER CLEARF041-0001
SARA 313
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
United States of America State Regulations
Fire hazard Yes
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
California Prop. 65This product contains the following Proposition 65 chemicals:
Sudden release of pressure hazard No
LegendNPRI - National Pollutant Release Inventory
16. Other information
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Reactive Hazard No
Revision date 29-Jul-2013
Chronic Health Hazard No
State Right-to-Know
Revision note No information available
component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
SARA 311/312 Hazardous Categorization
SOLVENT NAPHTHA X
Other international regulations
Acute health hazard
CERCLA
______________________________________________________________________________________________
Yes
CANADA
Page 5 / 6
flammability 2 reactivity 1HEALTH 2HMIS (Hazardous MaterialInformation System)
______________________________________________________________________________________________THINNER CLEARF041-0001
Revision date 29-Jul-2013-
End of MSDS
Page 6 / 6
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
______________________________________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 2 THINNERProduct code F041-0002Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Kidney disorders. Liver disorders. Skindisorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratorysystem, Skin
_____________________________________________________________________________________________
Page 1 / 7
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 28-Jun-2011
Material Safety Data Sheet
Revision Date 28-Jun-2011 Revision Number 3
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %XYLENE 1330-20-7 60 - 100ETHYL BENZENE 100-41-4 10 - 30
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 7
Revision Date 28-Jun-2011F041-0002 - THINNER CLEAR
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)XYLENE : 100 ppm TWA : 150
ppm STEL: 100 ppm TWA; 435
mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 150ppm STEV; 651 mg/m3
STEV
TWA: 100 ppm TWASTEL: 150 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
ETHYL BENZENE : 20 ppm TWA : 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 125ppm STEV; 543 mg/m3
STEV
TWA: 100 ppm TWASTEL: 125 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 26°C / 78.0°FBoiling range 135 - 142°C / 275.0 - 288.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure 0.8 - 1.2 kPa @ 20°CVapor density No information availableSpecific Gravity .87100 g/cm3Density 7.24800 lbs/galVolatile organic compounds (VOC) content 7.248 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
Page 3 / 7
Revision Date 28-Jun-2011F041-0002 - THINNER CLEAR
_____________________________________________________________________________________________
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationXYLENE 4300 mg/kg ( Rat ) >1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h 47635 mg/L (
Rat ) 4 hETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
ETHYL BENZENE A3 Group 2B X
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratory
system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
_____________________________________________________________________________________________
Page 4 / 7
Incompatible products Strong oxidizing agents.
F041-0002 - THINNER CLEAR
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
Revision Date 28-Jun-2011
Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaXYLENE LC50 13.4 mg/L Pimephales
promelas 96 h LC50 2.661-4.093 mg/L Oncorhynchus
mykiss 96 h LC50 13.5-17.3mg/L Oncorhynchus mykiss 96
h LC50 13.1-16.5 mg/LLepomis macrochirus 96 h
LC50 19 mg/L Lepomismacrochirus 96 h LC50 7.711-
9.591 mg/L Lepomismacrochirus 96 h LC50 23.53-
29.97 mg/L Pimephalespromelas 96 h LC50 780 mg/LCyprinus carpio 96 h LC50>
>780 mg/L Cyprinus carpio 96h LC50 30.26-40.75 mg/L
Poecilia reticulata 96 h
EC50 = 0.0084 mg/L 24 h EC50 3.82 mg/L 48 h LC500.6 mg/L 48 h
ETHYL BENZENE EC50 4.6 mg/L 72 h EC50 >>438 mg/L 96 h EC50 2.6 -
11.3 mg/L 72 h EC50 1.7 - 7.6mg/L 96 h
LC50 11.0-18.0 mg/LOncorhynchus mykiss 96 h
LC50 4.2 mg/L Oncorhynchusmykiss 96 h LC50 7.55-11
mg/L Pimephales promelas 96h LC50 32 mg/L Lepomis
macrochirus 96 h LC50 9.1-15.6 mg/L Pimephales
promelas 96 h LC50 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1307,XYLENES,3,PGIII,ERG 130
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentXYLENEETHYL BENZENE
_____________________________________________________________________________________________
Page 5 / 7
Revision Date 28-Jun-2011F041-0002 - THINNER CLEAR
_____________________________________________________________________________________________
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
XYLENE 1330-20-7 60 - 100 1.0 % de minimisconcentration
ETHYL BENZENE 100-41-4 10 - 30 0.1 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
XYLENE 100 lb RQ XETHYL BENZENE 1000 lb RQ X X X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65ETHYL BENZENE 100-41-4 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandXYLENE X X X X X
ETHYL BENZENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
Component NPRIXYLENE Part 1, Group 1 Substance; Part 5 Substance
_____________________________________________________________________________________________
Page 6 / 7
F041-0002 - THINNER CLEAR Revision Date 28-Jun-2011
_____________________________________________________________________________________________
ETHYL BENZENE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 28-Jun-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 7 / 7
Health 2 Flammability 3 Reactivity 1
F041-0002 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 28-Jun-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 3 THINNERProduct code F041-0003Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Kidney disorders. Liver disorders. Skindisorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratorysystem, Skin
_____________________________________________________________________________________________
Page 1 / 7
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL OR FATAL IF SWALLOWED.
HARMFUL IF INHALED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date 28-Jun-2011
Material Safety Data Sheet
Revision Date 28-Jun-2011 Revision Number 3
WARNING!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %AROMATIC HYDROCARBON MIXTURE 64742-95-6 30 - 601,2,4-TRIMETHYLBENZENE 95-63-6 30 - 601,3,5-TRIMETHYLBENZENE 108-67-8 5 - 10DIETHYLBENZENE 25340-17-4 1 - 5XYLENE 1330-20-7 1 - 5CUMENE (SKIN) 98-82-8 1 - 5ETHYL BENZENE 100-41-4 0.1 - 1
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
_____________________________________________________________________________________________
Page 2 / 7
Revision Date 28-Jun-2011F041-0003 - THINNER CLEAR
_____________________________________________________________________________________________
7. HANDLING AND STORAGEHandlingAvoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and washcontaminated clothing before re-use. Do not eat, drink or smoke when using this product. When used in a mixture, read the labelsand safety data sheets of all components. Wash thoroughly after handling.
StorageClose container after each use. Keep away from heat, sparks and flame. Use only in an area containing flame proof equipment.Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)1,2,4-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
123 mg/m3TWA: 25 ppm TWA:
123 mg/m3TWA: 125 mg/m3 TWA:
25 ppm STEL: 170mg/m3 STEL: 35 ppm
1,3,5-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:123 mg/m3
TWA: 25 ppm TWA:123 mg/m3
TWA: 125 mg/m3 TWA:25 ppm STEL: 170
mg/m3 STEL: 35 ppmXYLENE : 100 ppm TWA : 150
ppm STEL: 100 ppm TWA; 435
mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 150ppm STEV; 651 mg/m3
STEV
TWA: 100 ppm TWASTEL: 150 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
CUMENE (SKIN) : 50 ppm TWA : 50 ppm TWA; 245mg/m3 TWA Skin
TWA: 50 ppm TWAEV;246 mg/m3 TWAEV
TWA: 50 ppm TWA : 50 ppm TWA; 245mg/m3 TWA : 75 ppm
STEL; 365 mg/m3 STELETHYL BENZENE : 20 ppm TWA : 100 ppm TWA; 435
mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 125ppm STEV; 543 mg/m3
STEV
TWA: 100 ppm TWASTEL: 125 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 42°C / 108.0°FBoiling range 138 - 153°C / 280.0 - 307.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure 0.2 - 1.3 kPa @ 20°CVapor density No information availableSpecific Gravity .87373 g/cm3
_____________________________________________________________________________________________
Page 3 / 7
F041-0003 - THINNER CLEAR Revision Date 28-Jun-2011
_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIESDensity 7.27077 lbs/galVolatile organic compounds (VOC) content 7.271 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationAROMATIC HYDROCARBON
MIXTURE8400 mg/kg ( Rat ) >2000 mg/kg ( Rabbit ) >5.2 mg/L ( Rat ) 4 h 3400 ppm ( Rat
) 4 h1,2,4-TRIMETHYLBENZENE 3400 mg/kg ( Rat ) >3160 mg/kg ( Rabbit ) 18 g/m3 ( Rat ) 4 h1,3,5-TRIMETHYLBENZENE 5000 mg/kg ( Rat ) 24 g/m3 ( Rat ) 4 h
XYLENE 4300 mg/kg ( Rat ) >1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h 47635 mg/L (Rat ) 4 h
CUMENE (SKIN) 1400 mg/kg ( Rat ) >3160 mg/kg ( Rabbit ) 39000 mg/m3 ( Rat ) 4 hETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
ETHYL BENZENE A3 Group 2B X
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratory
system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
_____________________________________________________________________________________________
Page 4 / 7
Incompatible products Strong oxidizing agents. Acids.Alkalines.
F041-0003 - THINNER CLEAR
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
Revision Date 28-Jun-2011
Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaAROMATIC HYDROCARBON
MIXTURELC50 9.22 mg/L
Oncorhynchus mykiss 96 hEC50 6.14 mg/L 48 h
1,2,4-TRIMETHYLBENZENE LC50 7.72 mg/L Pimephalespromelas 96 h LC50 7.19-8.28mg/L Pimephales promelas 96
h
EC50 6.14 mg/L 48 h
1,3,5-TRIMETHYLBENZENE LC50 3.48 mg/L Pimephalespromelas 96 h LC50 7.72 mg/L
Pimephales promelas 96 h
EC50 50 mg/L 24 h
XYLENE LC50 13.4 mg/L Pimephalespromelas 96 h LC50 2.661-4.093 mg/L Oncorhynchus
mykiss 96 h LC50 13.5-17.3mg/L Oncorhynchus mykiss 96
h LC50 13.1-16.5 mg/LLepomis macrochirus 96 h
LC50 19 mg/L Lepomismacrochirus 96 h LC50 7.711-
9.591 mg/L Lepomismacrochirus 96 h LC50 23.53-
29.97 mg/L Pimephalespromelas 96 h LC50 780 mg/LCyprinus carpio 96 h LC50>
>780 mg/L Cyprinus carpio 96h LC50 30.26-40.75 mg/L
Poecilia reticulata 96 h
EC50 = 0.0084 mg/L 24 h EC50 3.82 mg/L 48 h LC500.6 mg/L 48 h
CUMENE (SKIN) EC50 2.6 mg/L 72 h LC50 6.04-6.61 mg/LPimephales promelas 96 h
LC50 4.8 mg/L Oncorhynchusmykiss 96 h LC50 2.7 mg/LOncorhynchus mykiss 96 h
LC50 5.1 mg/L Poeciliareticulata 96 h
EC50 = 0.89 mg/L 5 min EC50= 1.10 mg/L 15 min EC50 =
1.48 mg/L 30 min EC50 = 172mg/L 24 h
EC50 0.6 mg/L 48 h EC507.9 - 14.1 mg/L 48 h
ETHYL BENZENE EC50 4.6 mg/L 72 h EC50 >>438 mg/L 96 h EC50 2.6 -
11.3 mg/L 72 h EC50 1.7 - 7.6mg/L 96 h
LC50 11.0-18.0 mg/LOncorhynchus mykiss 96 h
LC50 4.2 mg/L Oncorhynchusmykiss 96 h LC50 7.55-11
mg/L Pimephales promelas 96h LC50 32 mg/L Lepomis
macrochirus 96 h LC50 9.1-15.6 mg/L Pimephales
promelas 96 h LC50 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
_____________________________________________________________________________________________
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F041-0003 - THINNER CLEAR Revision Date 28-Jun-2011
_____________________________________________________________________________________________
15. REGULATORY INFORMATIONInternational Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentXYLENECUMENE (SKIN)ETHYL BENZENE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
1,2,4-TRIMETHYLBENZENE 95-63-6 30 - 60 1.0 % de minimisconcentration
XYLENE 1330-20-7 1 - 5 1.0 % de minimisconcentration
CUMENE (SKIN) 98-82-8 1 - 5 1.0 % de minimisconcentration
ETHYL BENZENE 100-41-4 0.1 - 1 0.1 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
XYLENE 100 lb RQ XETHYL BENZENE 1000 lb RQ X X X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65CUMENE (SKIN) 98-82-8 Carcinogen
ETHYL BENZENE 100-41-4 Carcinogen
_____________________________________________________________________________________________
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F041-0003 - THINNER CLEAR Revision Date 28-Jun-2011
_____________________________________________________________________________________________
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island1,2,4-TRIMETHYLBENZENE X X X X X1,3,5-TRIMETHYLBENZENE X X X X X
DIETHYLBENZENE XXYLENE X X X X X
CUMENE (SKIN) X X X X XETHYL BENZENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2A Very toxic materials
Component NPRIAROMATIC HYDROCARBON MIXTURE Part 5 Substance
1,2,4-TRIMETHYLBENZENE Part 1, Group 1 Substance; Part 5 SubstanceXYLENE Part 1, Group 1 Substance; Part 5 Substance
CUMENE (SKIN) Part 1, Group 1 SubstanceETHYL BENZENE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 28-Jun-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 7 / 7
Health 2 Flammability 2
Revision Date 28-Jun-2011
Reactivity 1HMIS (Hazardous MaterialInformation System)
F041-0003 - THINNER CLEAR
Print Date 25-Jan-2013 Revision Date 25-Jan-2013
Material Safety Data Sheet
Revision Number 3
Product code
Inhalation Irritating to respiratory system.
F041-0004
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
United States: 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT:816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO. 4 THINNER
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Kidney disorders. Liver disorders. Skindisorders. Respiratory disorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effectsEyes
______________________________________________________________________________________________
Moderately irritating to the eyes.
Emergency Overview
Page 1 / 7
Skin Irritating to skin.
DANGER!FLAMMABLE LIQUID AND VAPOR
HARMFUL IF INHALEDHARMFUL OR FATAL IF SWALLOWED
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEAMAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
______________________________________________________________________________________________
F041-0004Revision Date 25-Jan-2013
-THINNER CLEAR
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
30 - 60
See Section 12 for additional Ecological Information.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Hazardous decomposition products Oxides of carbon, hydrocarbons.
3. COMPOSITION/INFORMATION ON INGREDIENTS
XYLENE 1330-20-7
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
30 - 60
Skin contact: Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes.
Hazardous Components
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
N-BUTANOL (SKIN) 71-36-3
6. ACCIDENTAL RELEASE MEASURES
Ingestion: Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Drink 1or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poisoncontrol center IMMEDIATELY. Treat symptomatically.
10 - 30
Potential environmental effects
Personal precautions Ensure adequate ventilation.
Component
ETHYL BENZENE
Inhalation:
Environmental precautions Prevent further leakage or spillage if safe to do so.
Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult,administer oxygen. If breathing has stopped give artificial respiration. Consult a physician.
100-41-4 5 - 10
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
CAS-No Weight %
5. FIRE-FIGHTING MEASURES
______________________________________________________________________________________________
4. FIRST AID MEASURES
Flammable properties Flammable.
Page 2 / 7
METHYL ISOBUTYL KETONE 108-10-1
______________________________________________________________________________________________
F041-0004Revision Date 25-Jan-2013
-THINNER CLEAR
Engineering measures Ensure adequate ventilation, especially in confined areas
StorageKeep containers tightly closed in a cool, well-ventilated place.
Component
Personal Protective Equipment
ACGIH TLV OSHA PEL
Skin protection Wear protective gloves/clothing
Quebec TWAEV Ontario TWAEV
Eye/face protection If splashes are likely to occur, wear Goggles.
Mexico OEL (TWA)
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
METHYL ISOBUTYLKETONE
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 20 ppmSTEL: 75 ppm
TWA: 50 ppm TWA:205 mg/m3
STEL: 75 ppm STEL:300 mg/m3
TWA: 100 ppm TWA:410 mg/m3
TWA: 50 ppm TWA:205 mg/m3
STEL: 75 ppm STEL:307 mg/m3
TWA: 20 ppmSTEL: 75 ppm
9. PHYSICAL AND CHEMICAL PROPERTIES
TWA: 50 ppm TWA:205 mg/m3
STEL: 75 ppm STEL:307 mg/m3
HandlingHandle in accordance with good industrial hygiene and safety practice.
XYLENE
Flash point 18 °C / 64.0 °F
TWA: 100 ppmSTEL: 150 ppm
TWA: 100 ppm TWA:435 mg/m3
STEL: 150 ppm STEL:655 mg/m3
Boiling range 114 - 142.000 °C / 237.0 - 288.0 °F
TWA: 100 ppm TWA:434 mg/m3
STEL: 150 ppm STEL:651 mg/m3
TWA: 100 ppmSTEL: 150 ppm
Upper explosion limit No information available
TWA: 100 ppm TWA:435 mg/m3
STEL: 150 ppm STEL:655 mg/m3
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Lower explosion limit No information available
Other information
N-BUTANOL (SKIN)
Evaporation rate No information available
TWA: 20 ppm SkinCeiling: 50 ppm
Ceiling: 150 mg/m3
TWA: 100 ppm TWA:300 mg/m3
Vapor pressure No information available
Ceiling: 50 ppmCeiling: 152 mg/m3
Skin
TWA: 20 ppm
Vapor density No information available
Ceiling: 50 ppmCeiling: 150 mg/m3
Specific Gravity .83124 g/cm3
ETHYL BENZENE TWA: 20 ppm TWA: 100 ppm TWA:435 mg/m3
STEL: 125 ppm STEL:545 mg/m3
TWA: 100 ppm TWA:434 mg/m3
STEL: 125 ppm STEL:543 mg/m3
______________________________________________________________________________________________
TWA: 20 ppm TWA: 100 ppm TWA:435 mg/m3
STEL: 125 ppm STEL:545 mg/m3
Not applicable
Page 3 / 7
7. HANDLING AND STORAGE
Exposure Guidelines
______________________________________________________________________________________________THINNER CLEARF041-0004
Revision Date 25-Jan-2013-
100.0000 %
10. STABILITY AND REACTIVITY
Chronic toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Volatile organic compounds (VOC) content 6.917 lbs/gal
Component ACGIH IARC NTP OSHA Mexico
Component Information
METHYL ISOBUTYLKETONE
A3 Group 2B X
ETHYL BENZENE A3 Group 2B X
Component LD50 Oral LD50 Dermal LC50 Inhalation
Mutegenicity No information available.Reproductive effects No information available.
METHYL ISOBUTYL KETONE 2080 mg/kg ( Rat )
Developmental effects No information available.
16000 mg/kg ( Rabbit ) 8.2 mg/L ( Rat ) 4 h
Teratogenicity No information available.
Volatile by volume 100.0000 %
Target Organ Effects No information available.
XYLENE 4300 mg/kg ( Rat )
Endocrine Disruptor Information No information available
1700 mg/kg ( Rabbit ) 47635 mg/L ( Rat ) 4 h 5000 ppm (Rat ) 4 h
Density
12. ECOLOGICAL INFORMATION
N-BUTANOL (SKIN) 790 mg/kg ( Rat ) 3400 mg/kg ( Rabbit ) 8000 ppm ( Rat ) 4 h 17.7 mg/L (Rat ) 4 h
Ecotoxicity
6.91720 lbs/gal
11. TOXICOLOGICAL INFORMATION
ETHYL BENZENE 3500 mg/kg ( Rat )
Component Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
METHYL ISOBUTYLKETONE
EC50 = 400 mg/L 96 h LC50 496 - 514 mg/LPimephales promelas 96 h
EC50 = 79.6 mg/L 5 min EC50 = 170 mg/L 48 h
Irritation No information availableCorrosivity No information available.
Volatile by weight
Sensitization No information available.
Acute toxicity
______________________________________________________________________________________________
Possibility of hazardousreactions
None under normal processingIncompatible products Strong oxidizing agents.
Page 4 / 7
Chemical stability Stable. Conditions to avoid Heat, flames and sparks.
______________________________________________________________________________________________THINNER CLEARF041-0004
Revision Date 25-Jan-2013-
EC50 > 500 mg/L 96 h EC50> 500 mg/L 72 h
LC50 100000 - 500000 µg/LLepomis macrochirus 96 h
LC50 1730 - 1910 mg/LPimephales promelas 96 h
LC50= 1740 mg/LPimephales promelas 96 h
LC50= 1910000 µg/LPimephales promelas 96 h
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
EC50 = 2041.4 mg/L 5 minEC50 = 2186 mg/L 30 minEC50 = 4400 mg/L 17 hEC50 = 3980 mg/L 24 h
EC50 1897 - 2072 mg/L 48h EC50 = 1983 mg/L 48 h
Waste disposal methods
15. REGULATORY INFORMATION
Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
LC50 13.1 - 16.5 mg/LLepomis macrochirus 96 h
LC50 13.5 - 17.3 mg/LOncorhynchus mykiss 96 hLC50 2.661 - 4.093 mg/L
Oncorhynchus mykiss 96 hLC50 23.53 - 29.97 mg/L
Pimephales promelas 96 hLC50 30.26 - 40.75 mg/L
Poecilia reticulata 96 h LC507.711 - 9.591 mg/L Lepomis
macrochirus 96 h LC50=13.4 mg/L Pimephales
promelas 96 h LC50= 19mg/L Lepomis macrochirus
96 h LC50= 780 mg/LCyprinus carpio 96 h LC50>780 mg/L Cyprinus carpio 96
h
EC50 = 0.0084 mg/L 24 h
International Inventories
ETHYL BENZENE EC50 = 4.6 mg/L 72 h EC50> 438 mg/L 96 h EC50 2.6 -11.3 mg/L 72 h EC50 1.7 -
7.6 mg/L 96 h
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
TSCA Complies
LC50 11.0 - 18.0 mg/LOncorhynchus mykiss 96 h
LC50 7.55 - 11 mg/LPimephales promelas 96 h
LC50 9.1 - 15.6 mg/LPimephales promelas 96 hLC50= 32 mg/L Lepomis
macrochirus 96 h LC50= 4.2mg/L Oncorhynchus mykiss
96 h LC50= 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
DSL/NDSL Complies
EC50 1.8 - 2.4 mg/L 48 h
LC50 = 0.6 mg/L 48 h EC50= 3.82 mg/L 48 h
14. TRANSPORT INFORMATION
XYLENE
______________________________________________________________________________________________
Page 5 / 7
N-BUTANOL (SKIN)
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
13. DISPOSAL CONSIDERATIONS
______________________________________________________________________________________________THINNER CLEARF041-0004
Revision Date 25-Jan-2013-
Sudden Release of Pressure Hazard no
SARA 313
Reactive Hazard no
EINECS/ELINCS Complies
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances
Component HAPS Data
XYLENE 1330-20-7 ( 30 - 60 )
100 lb X
Component CAS-No
ETHYL BENZENE 100-41-4 ( 5 - 10 )
1000 lb X X X
Weight % SARA 313 - ThresholdValues
PICCS Complies
CERCLA
METHYL ISOBUTYL KETONE 108-10-1 30 - 60 1.0
Component Hazardous Substances RQs CERCLA EHS RQs
METHYL ISOBUTYL KETONE
METHYL ISOBUTYL KETONE 5000 lb
XYLENE 1330-20-7
XYLENE 100 lb
30 - 60 1.0
N-BUTANOL (SKIN) 5000 lb
ENCS Complies
ETHYL BENZENE 1000 lb
N-BUTANOL (SKIN) 71-36-3
United States of America State Regulations
10 - 30 1.0
XYLENE
California Prop. 65This product contains the following Proposition 65 chemicals:
ETHYL BENZENE 100-41-4 5 - 10 0.1
Component CAS-No California Prop. 65
AICS Complies
METHYL ISOBUTYL KETONE 108-10-1 Carcinogen
SARA 311/312 Hazardous Categorization
ETHYL BENZENE
ETHYL BENZENE 100-41-4 Carcinogen
CHINA Complies
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Chronic Health Hazard yes
United States of America Federal Regulations
Acute Health Hazard
______________________________________________________________________________________________
yes
KECL
Page 6 / 7
Fire Hazard yes
Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
______________________________________________________________________________________________Revision Date 25-Jan-2013
-THINNER CLEARF041-0004
ETHYL BENZENE X
N-BUTANOL (SKIN) Part 1, Group 1 Substance
X X
ETHYL BENZENE Part 1, Group 1 Substance
X
LegendNPRI - National Pollutant Release Inventory
State Right-to-Know
Other international regulations
16. OTHER INFORMATION
METHYL ISOBUTYLKETONE
X X
Revision Date 25-Jan-2013
X
Canada
X
Revision Note No information available
Component Massachusetts
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
XYLENE X X X
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
X
New Jersey Pennsylvania
DisclaimerTo the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health and/or environmental hazards and should be used with caution.
N-BUTANOL (SKIN) X
End of MSDS
X X
Component NPRIMETHYL ISOBUTYL KETONE Part 1, Group 1 Substance; Part 5 Substance
______________________________________________________________________________________________
Illinois Rhode Island
XYLENE Part 1, Group 1 Substance; Part 5 Substance
Page 7 / 7
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 3 Reactivity 1
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 9 THINNERProduct code F041-0009Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Kidney disorders. Liver disorders. Skindisorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratorysystem, Skin
_____________________________________________________________________________________________
Page 1 / 7
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 02-May-2011
Material Safety Data Sheet
Revision Date 02-May-2011 Revision Number 1
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %XYLENE 1330-20-7 30 - 60METHYL ETHYL KETONE 78-93-3 30 - 60ETHYL BENZENE 100-41-4 10 - 30
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 7
Revision Date 02-May-2011F041-0009 - THINNER CLEAR
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)XYLENE : 100 ppm TWA : 150
ppm STEL: 100 ppm TWA; 435
mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 150ppm STEV; 651 mg/m3
STEV
TWA: 100 ppm TWASTEL: 150 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
METHYL ETHYL KETONE : 200 ppm TWA : 300ppm STEL
: 200 ppm TWA; 590mg/m3 TWA : 300 ppmSTEL; 885 mg/m3 STEL
TWA: 50 ppm TWAEV;150 mg/m3 TWAEV
STEL: 100 ppm STEV;300 mg/m3 STEV
TWA: 200 ppm TWASTEL: 300 ppm STEL
: 200 ppm TWA; 590mg/m3 TWA : 300 ppmSTEL; 885 mg/m3 STEL
ETHYL BENZENE : 100 ppm TWA : 125ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 125ppm STEV; 543 mg/m3
STEV
TWA: 100 ppm TWASTEL: 125 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 9°C / 49.0°FBoiling range 78 - 142°C / 172.0 - 288.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .84945 g/cm3Density 7.06869 lbs/galVolatile organic compounds (VOC) content 7.069 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
_____________________________________________________________________________________________
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F041-0009 - THINNER CLEAR Revision Date 02-May-2011
_____________________________________________________________________________________________
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationXYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h 47635 mg/L (
Rat ) 4 hMETHYL ETHYL KETONE 2737 mg/kg ( Rat ) 6480 mg/kg ( Rabbit )
ETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
ETHYL BENZENE A3 Group 2B X
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratory
system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
_____________________________________________________________________________________________
Page 4 / 7
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
F041-0009 - THINNER CLEAR
Conditions to avoid Heat, flames and sparks.
Revision Date 02-May-2011
Incompatible products Strong oxidizing agents.
_____________________________________________________________________________________________
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaXYLENE LC50= 13.4 mg/L Pimephales
promelas 96 h LC50 2.661-4.093 mg/L Oncorhynchus
mykiss 96 h LC50 13.5-17.3mg/L Oncorhynchus mykiss 96
h LC50 13.1-16.5 mg/LLepomis macrochirus 96 hLC50= 19 mg/L Lepomis
macrochirus 96 h LC50 7.711-9.591 mg/L Lepomis
macrochirus 96 h LC50 23.53-29.97 mg/L Pimephales
promelas 96 h LC50= 780mg/L Cyprinus carpio 96 hLC50> 780 mg/L Cyprinus
carpio 96 h LC50 30.26-40.75mg/L Poecilia reticulata 96 h
EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50= 0.6 mg/L 48 h
METHYL ETHYL KETONE LC50 3130-3320 mg/LPimephales promelas 96 h
EC50 = 3426 mg/L 5 minEC50 = 3403 mg/L 30 min
EC50 4025 - 6440 mg/L 48 hEC50 = 5091 mg/L 48 h EC50
> 520 mg/L 48 hETHYL BENZENE EC50 = 4.6 mg/L 72 h EC50 >
438 mg/L 96 h EC50 2.6 -11.3 mg/L 72 h EC50 1.7 - 7.6
mg/L 96 h
LC50 11.0-18.0 mg/LOncorhynchus mykiss 96 h
LC50= 4.2 mg/LOncorhynchus mykiss 96 h
LC50 7.55-11 mg/LPimephales promelas 96 hLC50= 32 mg/L Lepomis
macrochirus 96 h LC50 9.1-15.6 mg/L Pimephales
promelas 96 h LC50= 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
_____________________________________________________________________________________________
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Revision Date 02-May-2011F041-0009 - THINNER CLEAR
_____________________________________________________________________________________________
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentXYLENEETHYL BENZENE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
XYLENE 1330-20-7 30 - 60 1.0 % de minimisconcentration
METHYL ETHYL KETONE 78-93-3 30 - 60 1.0ETHYL BENZENE 100-41-4 10 - 30 0.1 % de minimis
concentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
XYLENE 100 lb RQ XETHYL BENZENE 1000 lb RQ X X X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65ETHYL BENZENE 100-41-4 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandXYLENE X X X X X
METHYL ETHYL KETONE X X X X XETHYL BENZENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
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F041-0009 - THINNER CLEAR Revision Date 02-May-2011
_____________________________________________________________________________________________
Component NPRIXYLENE Part 1, Group 1 Substance; Part 5 Substance
METHYL ETHYL KETONE Part 1, Group 1 Substance; Part 5 SubstanceETHYL BENZENE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 02-May-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 7 / 7
Health 2 Flammability 3 Reactivity 1
F041-0009 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 02-May-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 12 THINNERProduct code F041-0012Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Kidney disorders. Liver disorders. Skin disorders. Respiratorydisorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 30-Mar-2011
Material Safety Data Sheet
Revision Date 30-Mar-2011 Revision Number 1
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %TOLUENE 108-88-3 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0012 - THINNER CLEAR Revision Date 30-Mar-2011
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)TOLUENE : 20 ppm TWA : 100 ppm TWA; 375
mg/m3 TWA : 150 ppmSTEL; 560 mg/m3 STEL
: 200 ppm TWA : 300ppm Ceiling
TWA: 50 ppm TWAEV;188 mg/m3 TWAEV
Skin
TWA: 20 ppm TWA : 50 ppm TWA; 188mg/m3 TWA
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 6°C / 42.0°FMethod Pensky Martens - Closed CupBoiling range 110 - 112°C / 230.0 - 233.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .87124 g/cm3Density 7.25000 lbs/galVolatile organic compounds (VOC) content 7.250 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
Page 3 / 6
F041-0012 - THINNER CLEAR
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
Revision Date 30-Mar-2011
Conditions to avoid Heat, flames and sparks.
Incompatible products Strong oxidizing agents.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationTOLUENE 636 mg/kg ( Rat ) 8390 mg/kg ( Rabbit ) 12124 mg/kg (
Rat )12.5 mg/L ( Rat ) 4 h 26700 ppm (
Rat ) 1 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaTOLUENE EC50 > 433 mg/L 96 h EC50 =
12.5 mg/L 72 hLC50 11.0-15.0 mg/L Lepomismacrochirus 96 h LC50 14.1-
17.16 mg/L Oncorhynchusmykiss 96 h LC50 15.22-19.05mg/L Pimephales promelas 96
h LC50 5.89-7.81 mg/LOncorhynchus mykiss 96 h
LC50 50.87-70.34 mg/LPoecilia reticulata 96 h LC50=
12.6 mg/L Pimephalespromelas 96 h LC50= 28.2
mg/L Poecilia reticulata 96 hLC50= 5.8 mg/L
Oncorhynchus mykiss 96 hLC50= 54 mg/L Oryzias latipes
96 h
EC50 = 19.7 mg/L 30 min EC50 5.46 - 9.83 mg/L 48 hEC50 = 11.5 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
_____________________________________________________________________________________________
Page 4 / 6
Revision Date 30-Mar-2011F041-0012 - THINNER CLEAR
_____________________________________________________________________________________________
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1294,TOLUENE,3,PGII,ERG 130
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentTOLUENE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
TOLUENE 108-88-3 60 - 100 1.0 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
TOLUENE 1000 lb RQ X X X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65TOLUENE 108-88-3 Developmental Female Reproductive
_____________________________________________________________________________________________
Page 5 / 6
Revision Date 30-Mar-2011F041-0012 - THINNER CLEAR
_____________________________________________________________________________________________
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandTOLUENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
Component NPRITOLUENE Part 1, Group 1 Substance; Part 5 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 30-Mar-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2 Flammability 3
F041-0012 - THINNER CLEAR
Reactivity 1
Revision Date 30-Mar-2011
HMIS (Hazardous MaterialInformation System)
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 15 THINNERProduct code F041-0015Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Liver disorders. Skin disorders. Kidneydisorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Liver, Reproductive System,Respiratory system, Skin, Kidney
_____________________________________________________________________________________________
Page 1 / 7
FLAMMABLE LIQUID AND VAPOR.HARMFUL OR FATAL IF SWALLOWED.
HARMFUL IF INHALED.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
POISON, MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED.
Print Date 07-Jun-2011
Material Safety Data Sheet
Revision Date 07-Jun-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %ETHANOL 64-17-5 60 - 100METHANOL (SKIN) 67-56-1 1 - 5ETHYL ACETATE 141-78-6 1 - 5METHYL ISOBUTYL KETONE 108-10-1 1 - 5
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
_____________________________________________________________________________________________
Page 2 / 7
F041-0015 - THINNER CLEAR Revision Date 07-Jun-2011
_____________________________________________________________________________________________
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)ETHANOL : 1000 ppm STEL : 1000 ppm TWA; 1900
mg/m3 TWATWA: 1000 ppm
TWAEV; 1880 mg/m3
TWAEV
STEL: 1000 ppm STEL : 1000 ppm TWA; 1900mg/m3 TWA
METHANOL (SKIN) : 200 ppm TWA Skin :250 ppm STEL
: 200 ppm TWA; 260mg/m3 TWA : 250 ppmSTEL; 325 mg/m3 STEL
Skin
TWA: 200 ppmTWAEV; 262 mg/m3
TWAEV STEL: 250ppm STEV; 328 mg/m3
STEV Skin
TWA: 200 ppm TWASTEL: 250 ppm STEL
Skin
: 200 ppm TWA; 260mg/m3 TWA : 250 ppmSTEL; 310 mg/m3 STEL
ETHYL ACETATE : 400 ppm TWA : 400 ppm TWA; 1400mg/m3 TWA
TWA: 400 ppmTWAEV; 1440 mg/m3
TWAEV
TWA: 400 ppm TWA : 400 ppm TWA; 1400mg/m3 TWA
METHYL ISOBUTYLKETONE
: 20 ppm TWA : 75 ppmSTEL
: 50 ppm TWA; 205mg/m3 TWA : 75 ppm
STEL; 300 mg/m3 STEL: 100 ppm TWA; 410
mg/m3 TWA
TWA: 50 ppm TWAEV;205 mg/m3 TWAEV
STEL: 75 ppm STEV;307 mg/m3 STEV
TWA: 50 ppm TWASTEL: 75 ppm STEL
: 50 ppm TWA; 205mg/m3 TWA : 75 ppm
STEL; 307 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 7°C / 45.0°FBoiling range No information availableUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .79377 g/cm3Density 6.60533 lbs/gal
_____________________________________________________________________________________________
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F041-0015 - THINNER CLEAR Revision Date 07-Jun-2011
_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIESVolatile organic compounds (VOC) content 6.605 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationETHANOL 7060 mg/kg ( Rat ) 124.7 mg/L ( Rat ) 4 h
METHANOL (SKIN) 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L (Rat ) 4 h
ETHYL ACETATE 5620 mg/kg ( Rat ) 20 mL/kg ( Rabbit ) 18000 mg/kg (Rabbit )
METHYL ISOBUTYL KETONE 2080 mg/kg ( Rat ) 16000 mg/kg ( Rabbit ) 8.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA MexicoETHANOL A3 Group 1 X
METHYL ISOBUTYLKETONE
A3
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Liver, Reproductive System,
Respiratory system, Skin, Kidney.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
_____________________________________________________________________________________________
Page 4 / 7
Conditions to avoid Heat, flames and sparks.
F041-0015 - THINNER CLEAR
Incompatible products Strong oxidizing agents. Acids.Alkalines. Amines.
Revision Date 07-Jun-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaETHANOL LC50 12.0 - 16.0 mL/L
Oncorhynchus mykiss 96 hLC50 13400 - 15100 mg/LPimephales promelas 96 h
LC50> 100 mg/L Pimephalespromelas 96 h
EC50 = 35470 mg/L 5 minEC50 = 34634 mg/L 30 min
LC50 9268 - 14221 mg/L 48 hEC50 = 10800 mg/L 24 h
EC50 = 2 mg/L 48 h
METHANOL (SKIN) LC50 13500 - 17600 mg/LLepomis macrochirus 96 h
LC50 18 - 20 mL/LOncorhynchus mykiss 96 hLC50 19500 - 20700 mg/LOncorhynchus mykiss 96 h
LC50= 28200 mg/LPimephales promelas 96 h
LC50> 100 mg/L Pimephalespromelas 96 h
EC50 = 43000 mg/L 5 minEC50 = 40000 mg/L 15 minEC50 = 39000 mg/L 25 min
ETHYL ACETATE EC50 = 3300 mg/L 48 h LC50 220-250 mg/LPimephales promelas 96 h
LC50 352-500 mg/LOncorhynchus mykiss 96 h
LC50= 484 mg/LOncorhynchus mykiss 96 h
EC50 = 1180 mg/L 5 minEC50 = 5870 mg/L 15 min
EC50 = 7400 mg/L 2 h EC50 =1500 mg/L 15 min
EC50 = 560 mg/L 48 h
METHYL ISOBUTYLKETONE
EC50 = 400 mg/L 96 h LC50 496-514 mg/LPimephales promelas 96 h
EC50 = 79.6 mg/L 5 min EC50 = 170 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1170,ETHYL ALCOHOL,3,PGII, ERG 127
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentMETHANOL (SKIN)METHYL ISOBUTYL KETONE
United States of America Federal Regulations
_____________________________________________________________________________________________
Page 5 / 7
Revision Date 07-Jun-2011F041-0015 - THINNER CLEAR
_____________________________________________________________________________________________
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
METHANOL (SKIN) 67-56-1 1 - 5 1.0 % de minimisconcentration
METHYL ISOBUTYL KETONE 108-10-1 1 - 5 1.0 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65ETHANOL 64-17-5 Carcinogen Developmental
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandETHANOL X X X X
METHANOL (SKIN) X X X X XETHYL ACETATE X X X X
METHYL ISOBUTYLKETONE
X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
Component NPRIETHANOL Part 5 Substance
METHANOL (SKIN) Part 1, Group 1 Substance; Part 5 SubstanceETHYL ACETATE Part 5 Substance
METHYL ISOBUTYL KETONE Part 1, Group 1 Substance; Part 5 Substance
_____________________________________________________________________________________________
Page 6 / 7
Revision Date 07-Jun-2011F041-0015 - THINNER CLEAR
_____________________________________________________________________________________________
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 07-Jun-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 7 / 7
Health 2 Flammability 3 Reactivity 1
F041-0015 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 07-Jun-2011
Print Date 25-Jan-2013 Revision Date 25-Jan-2013
Material Safety Data Sheet
Revision Number 3
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO. 18 THINNER
Aggravated Medical Conditions No information available.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects No information available.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Eyes Moderately irritating to the eyes.
Emergency Overview
Skin Irritating to skin.
______________________________________________________________________________________________
Product code
Inhalation
Page 1 / 6
Irritating to respiratory system.
F041-0018
WARNING!COMBUSTIBLE LIQUID AND VAPOR
HARMFUL OR FATAL IF SWALLOWEDHARMFUL IF INHALED
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEAMAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
______________________________________________________________________________________________
F041-0018Revision Date 25-Jan-2013
-THINNER CLEAR
Rinse thoroughly with plenty of water for at least 15 minutes.
6. ACCIDENTAL RELEASE MEASURES
60 - 100
5. FIRE-FIGHTING MEASURES
Personal precautions Ensure adequate ventilation.
Component
Environmental precautions Prevent further leakage or spillage if safe to do so.
Flammable properties Combustible material.
Skin contact: Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
CAS-No Weight %
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
Other information Not applicable
4. FIRST AID MEASURES
Hazardous Components
Ingestion:
7. HANDLING AND STORAGE
Hazardous decomposition products Oxides of carbon, hydrocarbons.
HandlingHandle in accordance with good industrial hygiene and safety practice.
If swallowed, do not induce vomiting. Get medical attention immediately.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
______________________________________________________________________________________________
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical attention immediately.
Page 2 / 6
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
108-65-6
Eye contact:
______________________________________________________________________________________________THINNER CLEARF041-0018
Revision Date 25-Jan-2013-
Ontario TWAEV
Specific Gravity .96497 g/cm3
Skin protection Wear protective gloves/clothing
Density 8.03000 lbs/gal
Mexico OEL (TWA)
Volatile organic compounds (VOC) content 8.030 lbs/gal
Eye/face protection
Volatile by weight 100.0000 %
Safety glasses with side-shields
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Volatile by volume 100.0000 %
PROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
10. STABILITY AND REACTIVITY
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 50 ppm TWA:270 mg/m3
StorageKeep containers tightly closed in a cool, well-ventilated place.
9. PHYSICAL AND CHEMICAL PROPERTIES
Exposure Guidelines
Flash point
11. TOXICOLOGICAL INFORMATION
47 °C / 116.0 °FBoiling range
Acute toxicity
139 - 141.000 °C / 283.0 - 285.0 °F
Engineering measures Ensure adequate ventilation, especially in confined areas
Upper explosion limit
Component Information
No information available
Component LD50 Oral LD50 Dermal LC50 Inhalation
Component
Lower explosion limit
PROPYLENE GLYCOLMONOMETHYL ETHER ACETATE
8532 mg/kg ( Rat ) 5000 mg/kg ( Rabbit )
No information available
ACGIH TLV
Evaporation rate No information available
OSHA PEL
Personal Protective Equipment
Vapor pressure No information available
Quebec TWAEV
Vapor density No information available
______________________________________________________________________________________________
Strong oxidizing agents.
Chemical stability Stable. Conditions to avoid
Page 3 / 6
Heat, flames and sparks. Reactswith air to form peroxides.
Possibility of hazardousreactions
None under normal processingIncompatible products
______________________________________________________________________________________________Revision Date 25-Jan-2013
-THINNER CLEARF041-0018
14. TRANSPORT INFORMATION
12. ECOLOGICAL INFORMATION
Mutegenicity No information available.
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Irritation No information available
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
Ecotoxicity
Reproductive effects No information available.
15. REGULATORY INFORMATION
Chronic toxicity
Component
International Inventories
Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
TSCA Complies
Developmental effects No information available.
DSL/NDSL Complies
PROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
EINECS/ELINCS Complies
LC50= 161 mg/LPimephales promelas 96 h
CHINA Complies
EC50 > 500 mg/L 48 h
Sensitization
ENCS Complies
No information available.
KECL Complies
Teratogenicity No information available.
PICCS Complies
13. DISPOSAL CONSIDERATIONS
Carcinogenicity
AICS Complies
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Target Organ Effects
United States of America Federal Regulations
No information available.
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
Corrosivity No information available.
Endocrine Disruptor Information
______________________________________________________________________________________________
No information available
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Page 4 / 6
______________________________________________________________________________________________Revision Date 25-Jan-2013
-THINNER CLEARF041-0018
California Prop. 65This product contains the following Proposition 65 chemicals:
Sudden Release of Pressure Hazard no
Component NPRIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE Part 5 Substance
Chronic Health Hazard
LegendNPRI - National Pollutant Release Inventory
Reactive Hazard
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
16. OTHER INFORMATION
no
yes
Revision Date 25-Jan-2013
SARA 311/312 Hazardous Categorization
State Right-to-Know
Revision Note No information available
Other international regulations
Acute Health Hazard yes
Canada
CERCLA
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
Fire Hazard
United States of America State Regulations
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
______________________________________________________________________________________________
yes
SARA 313
Page 5 / 6
Flammability 2 Reactivity 1Health 1HMIS (Hazardous MaterialInformation System)
______________________________________________________________________________________________THINNER CLEARF041-0018
Revision Date 25-Jan-2013-
End of MSDS
Page 6 / 6
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
______________________________________________________________________________________________
Print Date 02-Dec-2011 Revision Date 02-Dec-2011
Material Safety Data Sheet
Revision Number 3
Inhalation Irritating to respiratory system.
F041-0019
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO. 19 THINNER
Aggravated Medical Conditions Central nervous system. Kidney disorders. Liver disorders. Skin disorders. Respiratorydisorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
Eyes Moderately irritating to the eyes.
______________________________________________________________________________________________
Emergency Overview
Skin Irritating to skin.
Page 1 / 7
Product code
DANGER!FLAMMABLE LIQUID AND VAPOR
HARMFUL IF INHALEDHARMFUL OR FATAL IF SWALLOWED
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEAMAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
______________________________________________________________________________________________
-THINNER CLEARF041-0019
Revision Date 02-Dec-2011
Wash off immediately with soap and plenty of water.
Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
METHYL ISOBUTYL KETONE 108-10-1
Ingestion:
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
If swallowed, do not induce vomiting. Get medical attention immediately.
30 - 60
6. ACCIDENTAL RELEASE MEASURES
Hazardous Components
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Target Organ Effects
4. FIRST AID MEASURES
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
Component
5. FIRE-FIGHTING MEASURES
CAS-No
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Weight %
Flammable properties Flammable.
Other information Not applicable
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
______________________________________________________________________________________________
TOLUENE 108-88-3
Page 2 / 7
30 - 60
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Skin contact:
______________________________________________________________________________________________
F041-0019Revision Date 02-Dec-2011
-THINNER CLEAR
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 100 ppm TWA:375 mg/m3
STEL: 150 ppm STEL:560 mg/m3
TWA: 200 ppmCeiling: 300 ppm
TWA: 50 ppm TWA:188 mg/m3
Skin
TWA: 20 ppm TWA: 50 ppm TWA:188 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
METHYL ISOBUTYLKETONE
TWA: 20 ppmSTEL: 75 ppm
Flash point 5 °C / 41.0 °F
TWA: 50 ppm TWA:205 mg/m3
STEL: 75 ppm STEL:300 mg/m3
TWA: 100 ppm TWA:410 mg/m3
TWA: 50 ppm TWA:205 mg/m3
STEL: 75 ppm STEL:307 mg/m3
Boiling range 110 - 117 °C / 230.0 - 243.0 °F
TWA: 50 ppmSTEL: 75 ppm
TWA: 50 ppm TWA:205 mg/m3
STEL: 75 ppm STEL:307 mg/m3
Upper explosion limit No information available
HandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Lower explosion limit No information availableEvaporation rate No information available
Exposure Guidelines
Vapor pressure No information available
Engineering measures
Vapor density No information available
Ensure adequate ventilation, especially in confined areas
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proofequipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition duringuse and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
Specific Gravity .83639 g/cm3
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Density 6.96000 lbs/gal
Component ACGIH TLV
Volatile organic compounds (VOC) content 6.960 lbs/gal
Personal Protective Equipment
Volatile by weight 100.0000 %
OSHA PEL Quebec TWAEV
Volatile by volume 100.0000 %
Skin protection Lightweight protective clothing, Apron, Impervious gloves
Ontario TWAEV Mexico OEL (TWA)
Eye/face protection
______________________________________________________________________________________________
If splashes are likely to occur, wear Goggles.
7. HANDLING AND STORAGE
Page 3 / 7
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
TOLUENE TWA: 20 ppm
______________________________________________________________________________________________THINNER CLEARF041-0019
Revision Date 02-Dec-2011-
LD50 Oral LD50 Dermal
METHYL ISOBUTYLKETONE
A3
LC50 Inhalation
10. STABILITY AND REACTIVITY
TOLUENE
Mutegenicity No information available.
636 mg/kg ( Rat ) 12124 mg/kg ( Rat ) 8390 mg/kg (Rabbit )
Reproductive effects No information available.
12.5 mg/L ( Rat ) 4 h 26700 ppm (Rat ) 1 h
Developmental effects No information available.
METHYL ISOBUTYL KETONE
Teratogenicity No information available.
2080 mg/kg ( Rat ) 16000 mg/kg ( Rabbit )
Target Organ Effects Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin.
8.2 mg/L ( Rat ) 4 h
Endocrine Disruptor Information No information available
Acute toxicity
Irritation No information available
12. ECOLOGICAL INFORMATION
Corrosivity No information available.
Ecotoxicity
Sensitization No information available.
Component Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
Component Information
Chronic toxicity
TOLUENE EC50 > 433 mg/L 96 h EC50= 12.5 mg/L 72 h
LC50 11.0 - 15.0 mg/LLepomis macrochirus 96 h
LC50 14.1 - 17.16 mg/LOncorhynchus mykiss 96 hLC50 15.22 - 19.05 mg/L
Pimephales promelas 96 hLC50 5.89 - 7.81 mg/L
Oncorhynchus mykiss 96 hLC50 50.87 - 70.34 mg/LPoecilia reticulata 96 h
LC50= 12.6 mg/LPimephales promelas 96 hLC50= 28.2 mg/L Poeciliareticulata 96 h LC50= 5.8
mg/L Oncorhynchus mykiss96 h LC50= 54 mg/L Oryzias
latipes 96 h
EC50 = 19.7 mg/L 30 min EC50 5.46 - 9.83 mg/L 48 hEC50 = 11.5 mg/L 48 h
11. TOXICOLOGICAL INFORMATION
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component
Component ACGIH IARC NTP OSHA Mexico
______________________________________________________________________________________________
Incompatible products Strong oxidizing agents.Chemical stability Stable.
Page 4 / 7
Conditions to avoid Heat, flames and sparks.Possibility of hazardousreactions
None under normal processing
______________________________________________________________________________________________
-THINNER CLEARF041-0019
Revision Date 02-Dec-2011
METHYL ISOBUTYL KETONE
EC50 = 400 mg/L 96 h
14. TRANSPORT INFORMATION
United States of America Federal Regulations
Waste disposal methods
TSCA
SARA 313
CompliesDSL/NDSL
Component CAS-No Weight % SARA 313 - ThresholdValues
Complies
Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
TOLUENE 108-88-3 30 - 60 1.0
LC50 496 - 514 mg/LPimephales promelas 96 h
EINECS/ELINCS
METHYL ISOBUTYL KETONE 108-10-1 30 - 60 1.0
Complies
DOT
SARA 311/312 Hazardous Categorization
Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
CHINA Complies
EC50 = 79.6 mg/L 5 min
Chronic Health Hazard no
ENCS
Acute Health Hazard yes
Complies
Fire Hazard yes
13. DISPOSAL CONSIDERATIONS
KECL
Sudden Release of Pressure Hazard no
Complies
EC50 = 170 mg/L 48 h
Reactive Hazard no
Proper shipping name
PICCS Complies
UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances
Contaminated packaging
AICS
TOLUENE 108-88-3 ( 30 - 60 )
1000 lb X X X
Complies
Empty containers should be taken for local recycling, recovery or waste disposal.
CERCLA
METHYL ISOBUTYLKETONE
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
______________________________________________________________________________________________
Component HAPS Data
Page 5 / 7
TOLUENE
International Inventories
______________________________________________________________________________________________Revision Date 02-Dec-2011
-THINNER CLEARF041-0019
State Right-to-Know
Hazardous Substances RQs
Component Massachusetts
Component NPRI
New Jersey Pennsylvania
TOLUENE Part 1, Group 1 Substance; Part 5 Substance
Illinois Rhode Island
METHYL ISOBUTYL KETONE Part 1, Group 1 Substance; Part 5 Substance
California Prop. 65This product contains the following Proposition 65 chemicals:
CERCLA EHS RQs
LegendNPRI - National Pollutant Release Inventory
TOLUENE X X X
16. OTHER INFORMATION
X X
METHYL ISOBUTYL KETONE
Revision Date 02-Dec-2011
METHYL ISOBUTYLKETONE
X X X
Revision Note No information available
X X
5000 lb
Other international regulations
Component CAS-No California Prop. 65
Canada
Component
TOLUENE 108-88-3 DevelopmentalFemale Reproductive
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
United States of America State Regulations
TOLUENE
______________________________________________________________________________________________
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
1000 lb 1 lb
Page 6 / 7
Flammability 3 Reactivity 1Health 2HMIS (Hazardous MaterialInformation System)
______________________________________________________________________________________________THINNER CLEARF041-0019
Revision Date 02-Dec-2011-
End of MSDS
Page 7 / 7
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
______________________________________________________________________________________________
Print Date 16-Nov-2012 Revision Date 16-Nov-2012
Material Safety Data Sheet
Revision Number 4
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CONVERTER
See Section 11 for additional Toxicological information.
Common name NO. 22 THINNER
Aggravated Medical Conditions No information available.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects No information available.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Eyes Moderately irritating to the eyes.
Emergency Overview
Skin Irritating to skin.
______________________________________________________________________________________________
Product code
Inhalation
Page 1 / 6
Irritating to respiratory system.
F041-0022
WARNING!COMBUSTIBLE LIQUID AND VAPOR
HARMFUL IF INHALEDHARMFUL OR FATAL IF SWALLOWED
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEAMAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
______________________________________________________________________________________________THINNER CONVERTERF041-0022
Revision Date 16-Nov-2012-
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
6. ACCIDENTAL RELEASE MEASURES
60 - 100
5. FIRE-FIGHTING MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Component
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
Flammable properties Combustible material.
Skin contact: Wash off immediately with soap and plenty of water.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
CAS-No Weight %
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
Other information Not applicable
4. FIRST AID MEASURES
Hazardous Components
Ingestion:
7. HANDLING AND STORAGE
Hazardous decomposition products Oxides of carbon, hydrocarbons.
HandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
If swallowed, do not induce vomiting. Get medical attention immediately.
______________________________________________________________________________________________
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
Page 2 / 6
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
108-65-6
______________________________________________________________________________________________THINNER CONVERTERF041-0022
Revision Date 16-Nov-2012-
Vapor density No information available
OSHA PEL Quebec TWAEV
Specific Gravity .96310 g/cm3
Skin protection
Density 8.01444 lbs/gal
Lightweight protective clothing, Apron, Impervious gloves
Ontario TWAEV
Volatile organic compounds (VOC) content 7.692 lbs/gal
Mexico OEL (TWA)
Volatile by weight 95.9800 %
Eye/face protection Safety glasses with side-shields
Volatile by volume 95.7940 %
Respiratory protection
10. STABILITY AND REACTIVITY
Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
PROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 50 ppm TWA:270 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
11. TOXICOLOGICAL INFORMATION
Flash point 47 °C / 116.0 °F
Exposure Guidelines
Acute toxicity
Boiling range 139 - 141 °C / 283.0 - 285.0 °F
Engineering measures
Component Information
Upper explosion limit No information available
Component LD50 Oral LD50 Dermal LC50 Inhalation
Ensure adequate ventilation, especially in confined areas
Lower explosion limit No information availableEvaporation rate No information available
Component ACGIH TLV
Vapor pressure No information available
Personal Protective Equipment
______________________________________________________________________________________________
Stable. Conditions to avoid Heat, flames and sparks. Reactswith air to form peroxides.
Possibility of hazardousreactions
Page 3 / 6
None under normal processingIncompatible products Strong oxidizing agents.
Chemical stability
______________________________________________________________________________________________Revision Date 16-Nov-2012
-THINNER CONVERTERF041-0022
Corrosivity No information available.
Endocrine Disruptor Information No information available
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
PROPYLENE GLYCOLMONOMETHYL ETHER ACETATE
14. TRANSPORT INFORMATION
8532 mg/kg ( Rat )
12. ECOLOGICAL INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Sensitization No information available.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
Ecotoxicity
Mutegenicity No information available.
15. REGULATORY INFORMATION
Irritation No information available
International Inventories
Reproductive effects No information available.
TSCA Complies
Component
DSL/NDSL Complies
Toxicity to algae Toxicity to fish
EINECS/ELINCS Complies
Toxicity tomicroorganisms
Toxicity to daphnia
CHINA Complies
Developmental effects No information available.
ENCS Complies
PROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
KECL Complies
LC50= 161 mg/LPimephales promelas 96 h
PICCS Complies
EC50 > 500 mg/L 48 h
5000 mg/kg ( Rabbit )
AICS Complies
Teratogenicity No information available.
13. DISPOSAL CONSIDERATIONS
______________________________________________________________________________________________
Chronic toxicity
Page 4 / 6
Target Organ Effects No information available.
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
______________________________________________________________________________________________THINNER CONVERTERF041-0022
Revision Date 16-Nov-2012-
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
yes
SARA 313
United States of America State Regulations
SARA 311/312 Hazardous Categorization
Fire Hazard yes
Component NPRI
California Prop. 65This product contains the following Proposition 65 chemicals:
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE Part 5 SubstanceLegendNPRI - National Pollutant Release Inventory
Sudden Release of Pressure Hazard
16. OTHER INFORMATION
no
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Revision Date 16-Nov-2012
Reactive Hazard
Revision Note No information available
no
State Right-to-KnowOther international regulations
Chronic Health Hazard no
Canada
United States of America Federal Regulations
CERCLA
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
______________________________________________________________________________________________
Acute Health Hazard
Page 5 / 6
Reactivity 1Health 1HMIS (Hazardous MaterialInformation System)
Flammability 2
______________________________________________________________________________________________THINNER CONVERTERF041-0022
Revision Date 16-Nov-2012-
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
Page 6 / 6
End of MSDS
______________________________________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 24 THINNERProduct code F041-0024Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin
3. COMPOSITION/INFORMATION ON INGREDIENTS
_____________________________________________________________________________________________
Page 1 / 6
17-Oct-2011
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSHazardous ComponentsComponent CAS-No Weight %METHYL N-AMYL KETONE 110-43-0 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0024 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)METHYL N-AMYL KETONE : 50 ppm TWA : 100 ppm TWA; 465
mg/m3 TWATWA: 50 ppm TWAEV;
233 mg/m3 TWAEVTWA: 25 ppm TWA;
115 mg/m3 TWA: 50 ppm TWA; 235
mg/m3 TWA : 100 ppmSTEL; 465 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 39°C / 102.0°FBoiling range 147 - 154°C / 297.0 - 309.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .81716 g/cm3Density 6.79999 lbs/galVolatile organic compounds (VOC) content 6.800 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
_____________________________________________________________________________________________
Page 3 / 6
F041-0024 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 17-Oct-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable. Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATIONComponent Information
Component LD50 Oral LD50 Dermal LC50 InhalationMETHYL N-AMYL KETONE 1670 mg/kg ( Rat ) 12600 µL/kg ( Rabbit )
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaMETHYL N-AMYL KETONE LC50 126 - 137 mg/L
Pimephales promelas 96 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL Complies
_____________________________________________________________________________________________
Page 4 / 6
Revision Date 17-Oct-2011F041-0024 - THINNER CLEAR
_____________________________________________________________________________________________
PICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
METHYL N-AMYL KETONE X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
_____________________________________________________________________________________________
Page 5 / 6
HMIS (Hazardous MaterialInformation System)
F041-0024 - THINNER CLEAR
Health 2
Revision Date 17-Oct-2011
Flammability 2 Reactivity 1
_____________________________________________________________________________________________
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
F041-0024 - THINNER CLEAR Revision Date 17-Oct-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO.26 THINNERProduct code F041-0026Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactive effects No information available
Potential environmental effects See Section 12 for additional Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %
_____________________________________________________________________________________________
Page 1 / 6
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date 17-Oct-2011
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSETHYLENE GLYCOL MONOPROPYL ETHER(SKIN)
2807-30-9 30 - 60
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 6
Revision Date 17-Oct-2011F041-0026 - THINNER CLEAR
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)ETHYLENE GLYCOL
MONOPROPYL ETHER(SKIN)
TWA: 25 ppm TWA;110 mg/m3 TWA Skin
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 57°C / 135.0°FMethod Pensky Martens - Closed CupBoiling range 100 - 154°C / 212.0 - 310.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .96406 g/cm3Density 8.02245 lbs/galVolatile organic compounds (VOC) content 7.600 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationWATER 90 mL/kg ( Rat )
_____________________________________________________________________________________________
Page 3 / 6
Conditions to avoid Heat, flames and sparks.
F041-0026 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 17-Oct-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATIONETHYLENE GLYCOL
MONOPROPYL ETHER (SKIN)3089 mg/kg ( Rat ) 960 µL/kg ( Rabbit )
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects No information availableEndocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS Does not ComplyKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
_____________________________________________________________________________________________
Page 4 / 6
Revision Date 17-Oct-2011F041-0026 - THINNER CLEAR
_____________________________________________________________________________________________
ComponentETHYLENE GLYCOL MONOPROPYL ETHER (SKIN)
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
ETHYLENE GLYCOL MONOPROPYL ETHER (SKIN) 2807-30-9 30 - 60 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
ETHYLENE GLYCOLMONOPROPYL ETHER
(SKIN)
X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
_____________________________________________________________________________________________
Page 5 / 6
Revision Date 17-Oct-2011F041-0026 - THINNER CLEAR
_____________________________________________________________________________________________
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2 Flammability 2
Revision Date 17-Oct-2011
Reactivity 1HMIS (Hazardous MaterialInformation System)
F041-0026 - THINNER CLEAR
Print Date 09-Oct-2012 Revision Date 07-Jun-2011
Material Safety Data Sheet
Revision Number 2
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO. 39 THINNER
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin
Eyes Moderately irritating to the eyes.
Emergency Overview
Skin Irritating to skin.
______________________________________________________________________________________________
Product code
Inhalation
Page 1 / 6
Irritating to respiratory system.
F041-0039
COMBUSTIBLE LIQUID AND VAPORHARMFUL OR FATAL IF SWALLOWED
HARMFUL IF INHALEDMAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
WARNING!
______________________________________________________________________________________________Revision Date 07-Jun-2011
-THINNER CLEARF041-0039
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
CAS-No
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
Weight %
4. FIRST AID MEASURES
Inhalation:
6. ACCIDENTAL RELEASE MEASURES
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical attention immediately.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Personal precautions Ensure adequate ventilation.
5. FIRE-FIGHTING MEASURES
METHYL N-AMYL KETONE
Environmental precautions Prevent further leakage or spillage if safe to do so.
110-43-0
Eye contact:
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Rinse thoroughly with plenty of water for at least 15 minutes.
Flammable properties Combustible material.
30 - 60
Hazardous Components
Other information Not applicable
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
7. HANDLING AND STORAGE
ETHYL 3-ETHOXYPROPIONATE
Skin contact: Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes.
763-69-9
______________________________________________________________________________________________
Hazardous decomposition products Oxides of carbon, hydrocarbons.
30 - 60
Page 2 / 6
Component
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
______________________________________________________________________________________________THINNER CLEARF041-0039
Revision Date 07-Jun-2011-
Exposure Guidelines
Lower explosion limit No information availableEvaporation rate No information available
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Vapor pressure No information available
Engineering measures Ensure adequate ventilation, especially in confined areas
Vapor density No information available
Component
Specific Gravity .88074 g/cm3
ACGIH TLV
Density 7.32909 lbs/gal
OSHA PEL
Personal Protective Equipment
Volatile organic compounds (VOC) content 6.265 lbs/gal
Quebec TWAEV
Volatile by weight 85.4780 %
Ontario TWAEV
Volatile by volume 86.2688 %
Skin protection Wear protective gloves/clothing
Mexico OEL (TWA)
10. STABILITY AND REACTIVITY
Eye/face protection Safety glasses with side-shields
METHYL N-AMYL KETONE
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
TWA: 50 ppm TWA: 100 ppm TWA:465 mg/m3
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 50 ppm TWA:233 mg/m3
TWA: 25 ppm TWA:115 mg/m3
TWA: 50 ppm TWA:235 mg/m3
STEL: 100 ppm STEL:465 mg/m3
11. TOXICOLOGICAL INFORMATION
9. PHYSICAL AND CHEMICAL PROPERTIES
StorageKeep containers tightly closed in a cool, well-ventilated place.
ETHYL3-ETHOXYPROPIONATE
Acute toxicity
Flash point 48 °C / 118.0 °F
TWA: 50 ppm TWA:300 mg/m3
Boiling range 147 - 165.000 °C / 297.0 - 329.0 °F
HandlingHandle in accordance with good industrial hygiene and safety practice.
Upper explosion limit No information available
______________________________________________________________________________________________
Heat, flames and sparks.Possibility of hazardousreactions
None under normal processingIncompatible products
Page 3 / 6
Strong oxidizing agents.Chemical stability Stable. Conditions to avoid
______________________________________________________________________________________________
F041-0039Revision Date 07-Jun-2011
-THINNER CLEAR
Toxicity to daphnia
Chronic toxicity
METHYL N-AMYL KETONE LC50 126 - 137 mg/LPimephales promelas 96 h
ETHYL 3-ETHOXYPROPIONATE 3200 mg/kg ( Rat )
ETHYL3-ETHOXYPROPIONATE
LC50= 62 mg/L Pimephalespromelas 96 h
EC50 = 970 mg/L 48 h
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
10 mL/kg ( Rabbit )
13. DISPOSAL CONSIDERATIONS
Component LD50 Oral
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
Mutegenicity No information available.
DEFOAMER 17 g/kg ( Rat )
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Reproductive effects No information available.
2 g/kg ( Rabbit )
14. TRANSPORT INFORMATION
Developmental effects No information available.
LD50 Dermal LC50 Inhalation
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Teratogenicity No information available.
Irritation No information available
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system,Skin.
Component Information
15. REGULATORY INFORMATION
Endocrine Disruptor Information No information available
Corrosivity No information available.
International Inventories
METHYL N-AMYL KETONE 1670 mg/kg ( Rat )
12. ECOLOGICAL INFORMATION
TSCA Complies
Sensitization No information available.
DSL/NDSL CompliesEINECS/ELINCS Complies
12600 µL/kg ( Rabbit )
Ecotoxicity
______________________________________________________________________________________________
Page 4 / 6
Component Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
______________________________________________________________________________________________
F041-0039Revision Date 07-Jun-2011
-THINNER CLEAR
Fire Hazard
State Right-to-Know
yes
AICS
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Does not Comply
METHYL N-AMYL KETONE X X X
Sudden Release of Pressure Hazard no
Other international regulations
SARA 313
Reactive Hazard
Canada
no
KECL Complies
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationD2B Toxic materials
ENCS
CERCLA
SARA 311/312 Hazardous Categorization
Does not Comply
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
LegendNPRI - National Pollutant Release Inventory
United States of America State Regulations
PICCS Does not Comply
16. OTHER INFORMATION
Chronic Health Hazard
California Prop. 65This product contains the following Proposition 65 chemicals:
Revision Date 07-Jun-2011
no
United States of America Federal Regulations
CHINA
______________________________________________________________________________________________
Acute Health Hazard yes
Page 5 / 6
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Complies
______________________________________________________________________________________________THINNER CLEARF041-0039
Revision Date 07-Jun-2011-
Revision Note
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
______________________________________________________________________________________________
No information available
End of MSDS
Page 6 / 6
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 2 Reactivity 1
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 42 THINNERProduct code F041-0042Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
FLAMMABLE LIQUID AND VAPOR.HARMFUL OR FATAL IF SWALLOWED.
HARMFUL IF INHALED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 07-Jun-2011
Material Safety Data Sheet
Revision Date 07-Jun-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %METHYL ETHYL KETONE 78-93-3 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0042 - THINNER CLEAR Revision Date 07-Jun-2011
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)METHYL ETHYL KETONE : 200 ppm TWA : 300
ppm STEL: 200 ppm TWA; 590
mg/m3 TWA : 300 ppmSTEL; 885 mg/m3 STEL
TWA: 50 ppm TWAEV;150 mg/m3 TWAEV
STEL: 100 ppm STEV;300 mg/m3 STEV
TWA: 200 ppm TWASTEL: 300 ppm STEL
: 200 ppm TWA; 590mg/m3 TWA : 300 ppmSTEL; 885 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Use chemical resistant coveralls or apron to protect against skin and clothing contamination.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point -5°C / 23°FBoiling range 78 - 80°C / 172 - 176.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .80635 g/cm3Density 6.71001 lbs/galVolatile organic compounds (VOC) content 6.710 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
_____________________________________________________________________________________________
Page 3 / 6
Conditions to avoid Heat, flames and sparks.
F041-0042 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 07-Jun-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationMETHYL ETHYL KETONE 2737 mg/kg ( Rat ) 6480 mg/kg ( Rabbit )
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Eyes, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaMETHYL ETHYL KETONE LC50 3130-3320 mg/L
Pimephales promelas 96 hEC50 = 3426 mg/L 5 minEC50 = 3403 mg/L 30 min
EC50 4025 - 6440 mg/L 48 hEC50 = 5091 mg/L 48 h EC50
> 520 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1193,METHYL ETHYL KETONE,3,PGII,ERG 127
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS Complies
_____________________________________________________________________________________________
Page 4 / 6
F041-0042 - THINNER CLEAR Revision Date 07-Jun-2011
_____________________________________________________________________________________________
CHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
METHYL ETHYL KETONE 78-93-3 60 - 100 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
METHYL ETHYL KETONE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2B Toxic materials
Component NPRIMETHYL ETHYL KETONE Part 1, Group 1 Substance; Part 5 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 07-Jun-2011
_____________________________________________________________________________________________
Page 5 / 6
Revision Date 07-Jun-2011F041-0042 - THINNER CLEAR
_____________________________________________________________________________________________
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2 Flammability 3
Revision Date 07-Jun-2011
Reactivity 1HMIS (Hazardous MaterialInformation System)
F041-0042 - THINNER CLEAR
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 45 THINNERProduct code F041-0045Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Liver disorders. Skin disorders. Kidneydisorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Liver, Reproductive System,Respiratory system, Skin, Kidney
_____________________________________________________________________________________________
Page 1 / 7
FLAMMABLE LIQUID AND VAPOR.POISON, MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED.
HARMFUL IF INHALED.HARMFUL OR FATAL IF SWALLOWED.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date 30-Mar-2011
Material Safety Data Sheet
Revision Date 30-Mar-2011 Revision Number 1
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %PROPYLENE GLYCOL MONOMETHYLETHER ACETATE
108-65-6 30 - 60
ETHANOL 64-17-5 30 - 60ETHYLENE GLYCOL MONOPROPYL ETHER(SKIN)
2807-30-9 1 - 5
METHANOL (SKIN) 67-56-1 1 - 5ETHYL ACETATE 141-78-6 1 - 5METHYL ISOBUTYL KETONE 108-10-1 0.1 - 1
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
_____________________________________________________________________________________________
Page 2 / 7
F041-0045 - THINNER CLEAR Revision Date 30-Mar-2011
_____________________________________________________________________________________________
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)PROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
TWA: 50 ppm TWA;270 mg/m3 TWA
ETHANOL : 1000 ppm STEL : 1000 ppm TWA; 1900mg/m3 TWA
TWA: 1000 ppmTWAEV; 1880 mg/m3
TWAEV
STEL: 1000 ppm STEL : 1000 ppm TWA; 1900mg/m3 TWA
ETHYLENE GLYCOLMONOPROPYL ETHER
(SKIN)
TWA: 25 ppm TWA;110 mg/m3 TWA Skin
METHANOL (SKIN) : 200 ppm TWA Skin :250 ppm STEL
: 200 ppm TWA; 260mg/m3 TWA : 250 ppmSTEL; 325 mg/m3 STEL
Skin
TWA: 200 ppmTWAEV; 262 mg/m3
TWAEV STEL: 250ppm STEV; 328 mg/m3
STEV Skin
TWA: 200 ppm TWASTEL: 250 ppm STEL
Skin
: 200 ppm TWA; 260mg/m3 TWA : 250 ppmSTEL; 310 mg/m3 STEL
ETHYL ACETATE : 400 ppm TWA : 400 ppm TWA; 1400mg/m3 TWA
TWA: 400 ppmTWAEV; 1440 mg/m3
TWAEV
TWA: 400 ppm TWA : 400 ppm TWA; 1400mg/m3 TWA
METHYL ISOBUTYLKETONE
: 20 ppm TWA : 75 ppmSTEL
: 50 ppm TWA; 205mg/m3 TWA : 75 ppm
STEL; 300 mg/m3 STEL: 100 ppm TWA; 410
mg/m3 TWA
TWA: 50 ppm TWAEV;205 mg/m3 TWAEV
STEL: 75 ppm STEV;307 mg/m3 STEV
TWA: 50 ppm TWASTEL: 75 ppm STEL
: 50 ppm TWA; 205mg/m3 TWA : 75 ppm
STEL; 307 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 16°C / 61.0°FBoiling range 64 - 154°C / 147.0 - 310.0°FUpper explosion limit No information available
_____________________________________________________________________________________________
Page 3 / 7
F041-0045 - THINNER CLEAR Revision Date 30-Mar-2011
_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIESLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .88699 g/cm3Density 7.38111 lbs/galVolatile organic compounds (VOC) content 7.329 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationPROPYLENE GLYCOL
MONOMETHYL ETHER ACETATE8532 mg/kg ( Rat ) 5000 mg/kg ( Rabbit )
ETHANOL 7060 mg/kg ( Rat ) 124.7 mg/L ( Rat ) 4 hETHYLENE GLYCOL
MONOPROPYL ETHER (SKIN)3089 mg/kg ( Rat ) 960 µL/kg ( Rabbit )
METHANOL (SKIN) 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L (Rat ) 4 h
ETHYL ACETATE 5620 mg/kg ( Rat ) 20 mL/kg ( Rabbit ) 18000 mg/kg (Rabbit )
METHYL ISOBUTYL KETONE 2080 mg/kg ( Rat ) 16000 mg/kg ( Rabbit ) 8.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA MexicoETHANOL A3 Group 1 X
METHYL ISOBUTYLKETONE
A3
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Liver, Reproductive System,
Respiratory system, Skin, Kidney.Endocrine Disruptor Information No information available
_____________________________________________________________________________________________
Page 4 / 7
Conditions to avoid Heat, flames and sparks. Reactswith air to form peroxides.
F041-0045 - THINNER CLEAR
Incompatible products Strong oxidizing agents. Acids.Alkalines. Amines.
Revision Date 30-Mar-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaPROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
LC50= 161 mg/L Pimephalespromelas 96 h
EC50 > 500 mg/L 48 h
ETHANOL LC50 12.0 - 16.0 mL/LOncorhynchus mykiss 96 hLC50 13400 - 15100 mg/LPimephales promelas 96 h
LC50> 100 mg/L Pimephalespromelas 96 h
EC50 = 35470 mg/L 5 minEC50 = 34634 mg/L 30 min
LC50 9268 - 14221 mg/L 48 hEC50 = 10800 mg/L 24 h
EC50 = 2 mg/L 48 h
METHANOL (SKIN) LC50 13500 - 17600 mg/LLepomis macrochirus 96 h
LC50 18 - 20 mL/LOncorhynchus mykiss 96 hLC50 19500 - 20700 mg/LOncorhynchus mykiss 96 h
LC50= 28200 mg/LPimephales promelas 96 h
LC50> 100 mg/L Pimephalespromelas 96 h
EC50 = 43000 mg/L 5 minEC50 = 40000 mg/L 15 minEC50 = 39000 mg/L 25 min
ETHYL ACETATE EC50 = 3300 mg/L 48 h LC50 220-250 mg/LPimephales promelas 96 h
LC50 352-500 mg/LOncorhynchus mykiss 96 h
LC50= 484 mg/LOncorhynchus mykiss 96 h
EC50 = 1180 mg/L 5 minEC50 = 5870 mg/L 15 min
EC50 = 7400 mg/L 2 h EC50 =1500 mg/L 15 min
EC50 = 560 mg/L 48 h
METHYL ISOBUTYLKETONE
EC50 = 400 mg/L 96 h LC50 496-514 mg/LPimephales promelas 96 h
EC50 = 79.6 mg/L 5 min EC50 = 170 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA Complies
_____________________________________________________________________________________________
Page 5 / 7
F041-0045 - THINNER CLEAR Revision Date 30-Mar-2011
_____________________________________________________________________________________________
ENCS Does not ComplyKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentETHYLENE GLYCOL MONOPROPYL ETHER (SKIN)METHANOL (SKIN)METHYL ISOBUTYL KETONE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
ETHYLENE GLYCOL MONOPROPYL ETHER (SKIN) 2807-30-9 1 - 5 1.0METHANOL (SKIN) 67-56-1 1 - 5 1.0 % de minimis
concentrationMETHYL ISOBUTYL KETONE 108-10-1 0.1 - 1 1.0 % de minimis
concentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65ETHANOL 64-17-5 Carcinogen Developmental
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandETHANOL X X X X
ETHYLENE GLYCOLMONOPROPYL ETHER
(SKIN)
X X X
METHANOL (SKIN) X X X X XETHYL ACETATE X X X X
METHYL ISOBUTYLKETONE
X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
_____________________________________________________________________________________________
Page 6 / 7
Revision Date 30-Mar-2011F041-0045 - THINNER CLEAR
_____________________________________________________________________________________________
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
Component NPRIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE Part 5 Substance
ETHANOL Part 5 SubstanceMETHANOL (SKIN) Part 1, Group 1 Substance; Part 5 SubstanceETHYL ACETATE Part 5 Substance
METHYL ISOBUTYL KETONE Part 1, Group 1 Substance; Part 5 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 30-Mar-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 7 / 7
Health 2 Flammability 3 Reactivity 1
F041-0045 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 30-Mar-2011
Print Date 08-Feb-2013 Revision Date 08-Feb-2013
Material Safety Data Sheet
Revision Number 2
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO 48 THINNER
Aggravated Medical Conditions No information available.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects No information available.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Eyes Moderately irritating to the eyes.
Emergency Overview
Skin Irritating to skin.
______________________________________________________________________________________________
Product code
Inhalation
Page 1 / 5
Irritating to respiratory system.
F041-0048
WARNING!COMBUSTIBLE LIQUID AND VAPOR
HARMFUL IF INHALEDHARMFUL OR FATAL IF SWALLOWED
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEAMAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
______________________________________________________________________________________________THINNER CLEARF041-0048
Revision Date 08-Feb-2013-
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
6. ACCIDENTAL RELEASE MEASURES
60 - 100
5. FIRE-FIGHTING MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Component
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
Flammable properties Combustible material.
Skin contact: Wash off immediately with soap and plenty of water.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
CAS-No Weight %
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
Other information Not applicable
4. FIRST AID MEASURES
Hazardous Components
Ingestion:
7. HANDLING AND STORAGE
Hazardous decomposition products Oxides of carbon, hydrocarbons.
HandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
If swallowed, do not induce vomiting. Get medical attention immediately.
______________________________________________________________________________________________
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
HEXYL ACETATE
Page 2 / 5
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
88230-35-7
______________________________________________________________________________________________THINNER CLEARF041-0048
Revision Date 08-Feb-2013-
Quebec TWAEV
Specific Gravity .87364 g/cm3
Skin protection
Density 7.26998 lbs/gal
Lightweight protective clothing, Apron, Impervious gloves
Ontario TWAEV
Volatile organic compounds (VOC) content 7.270 lbs/gal
Mexico OEL (TWA)
Volatile by weight 100.0000 %
Eye/face protection Safety glasses with side-shields
Volatile by volume 100.0000 %
Respiratory protection
10. STABILITY AND REACTIVITY
Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
HEXYL ACETATE
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 50 ppm TWA:294 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
11. TOXICOLOGICAL INFORMATION
Flash point 57 °C / 134.0 °F
Exposure Guidelines
Acute toxicity
Boiling range No information available
Engineering measures
Component Information
Upper explosion limit No information available
Irritation No information available
Ensure adequate ventilation, especially in confined areas
Corrosivity No information available.
Lower explosion limit No information available
Sensitization No information available.
Evaporation rate No information available
Component ACGIH TLV
Vapor pressure No information available
Personal Protective Equipment
Vapor density No information available
OSHA PEL
______________________________________________________________________________________________
Strong oxidizing agents.Alkalines.
Chemical stability Stable. Conditions to avoid
Page 3 / 5
Heat, flames and sparks.Possibility of hazardousreactions
None under normal processingIncompatible products
______________________________________________________________________________________________THINNER CLEARF041-0048
Revision Date 08-Feb-2013-
No information available.
13. DISPOSAL CONSIDERATIONS
Mutegenicity No information available.
TSCA CompliesDSL/NDSL Complies
Endocrine Disruptor Information No information available
EINECS/ELINCS Does not Comply
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
CHINA Complies
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
ENCS Does not ComplyKECL Complies
Reproductive effects
Contaminated packaging
PICCS Complies
Empty containers should be taken for local recycling, recovery or waste disposal.
No information available.
AICS Complies
12. ECOLOGICAL INFORMATION
Chronic toxicity
United States of America Federal Regulations
14. TRANSPORT INFORMATION
SARA 313
Developmental effects No information available.
DOT
SARA 311/312 Hazardous Categorization
Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Ecotoxicity
Chronic Health Hazard noAcute Health Hazard yes
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
Fire Hazard yes
Teratogenicity No information available.
______________________________________________________________________________________________
15. REGULATORY INFORMATION
Page 4 / 5
Target Organ Effects
International Inventories
______________________________________________________________________________________________THINNER CLEARF041-0048
Revision Date 08-Feb-2013-
Reactive Hazard
Revision Date 08-Feb-2013
California Prop. 65This product contains the following Proposition 65 chemicals:
no
Canada
Revision Note No information available
CERCLA
no
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Sudden Release of Pressure Hazard
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
United States of America State Regulations
End of MSDS
State Right-to-Know
LegendNPRI - National Pollutant Release Inventory
______________________________________________________________________________________________
Other international regulations
16. OTHER INFORMATION
Page 5 / 5
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 2 Reactivity 1
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 49 THINNERProduct code F041-0049Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactive effects No information available
Potential environmental effects See Section 12 for additional Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %
_____________________________________________________________________________________________
Page 1 / 6
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date 17-Oct-2011
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSP-CHLOROBENZOTRIFLUORIDE 98-56-6 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Chlorine. Fluorine.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingAvoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and washcontaminated clothing before re-use. Do not eat, drink or smoke when using this product. When used in a mixture, read the labelsand safety data sheets of all components. Wash thoroughly after handling.
StorageClose container after each use. Keep away from heat, sparks and flame. Use only in an area containing flame proof equipment.Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 6
Revision Date 17-Oct-2011F041-0049 - THINNER CLEAR
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)P-
CHLOROBENZOTRIFLUORIDE
TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 40°C / 104.0°FBoiling range 139 - 139°C / 282.0 - 282.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity 1.34591 g/cm3Density 11.19996 lbs/galVolatile organic compounds (VOC) content .000 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationP-CHLOROBENZOTRIFLUORIDE 13 g/kg ( Rat ) 2 mg/kg ( Rabbit ) 33 mg/L ( Rat ) 4 h
Irritation No information available
_____________________________________________________________________________________________
Page 3 / 6
Revision Date 17-Oct-2011
Incompatible products Strong oxidizing agents. Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
F041-0049 - THINNER CLEAR
Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
Corrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects No information availableEndocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaP-
CHLOROBENZOTRIFLUORIDE
EC50 = 11.1 mg/L 5 min EC50= 13.4 mg/L 15 min EC50 =
14.3 mg/L 30 min
EC50 = 3.68 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
_____________________________________________________________________________________________
Page 4 / 6
Revision Date 17-Oct-2011F041-0049 - THINNER CLEAR
_____________________________________________________________________________________________
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
P-CHLOROBENZOTRIFLUORIDE X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
P-CHLOROBENZOTRIFLUORI
DE
X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
_____________________________________________________________________________________________
Page 5 / 6
Revision Date 17-Oct-2011
HMIS (Hazardous MaterialInformation System)
Health 1*
F041-0049 - THINNER CLEAR
Flammability 2 Reactivity 1
_____________________________________________________________________________________________
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
F041-0049 - THINNER CLEAR Revision Date 17-Oct-2011
Print Date 08-Feb-2013 Revision Date 08-Feb-2013
Material Safety Data Sheet
Revision Number 3
Irritating to respiratory system.
F041-0050
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO.50 THINNER
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
Eyes Moderately irritating to the eyes.
Emergency Overview
______________________________________________________________________________________________
Skin Irritating to skin.
Product code
Page 1 / 6
Inhalation
FLAMMABLE LIQUID AND VAPORHARMFUL IF INHALED
HARMFUL OR FATAL IF SWALLOWEDMAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATIONMAY BE HARMFUL IF ABSORBED THROUGH SKIN.
DANGER!
______________________________________________________________________________________________Revision Date 08-Feb-2013
-THINNER CLEARF041-0050
Hazardous Components
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
4. FIRST AID MEASURES
Target Organ Effects
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
6. ACCIDENTAL RELEASE MEASURES
Component
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
CAS-No
5. FIRE-FIGHTING MEASURES
Weight %
Eye contact:
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
Rinse thoroughly with plenty of water for at least 15 minutes.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Flammable properties Flammable.
METHYL N-PROPYL KETONE
Other information Not applicable
107-87-9
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
Skin contact:
7. HANDLING AND STORAGE
Wash off immediately with soap and plenty of water.
60 - 100
Central nervous system, Eyes, Respiratory system, Skin
Hazardous decomposition products
______________________________________________________________________________________________
Oxides of carbon, hydrocarbons.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Page 2 / 6
Ingestion:
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
If swallowed, do not induce vomiting. Get medical attention immediately.
______________________________________________________________________________________________Revision Date 08-Feb-2013
-THINNER CLEARF041-0050
Lower explosion limit No information available
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Evaporation rate No information availableVapor pressure No information available
Component
Personal Protective Equipment
Vapor density No information available
ACGIH TLV
Specific Gravity .80754 g/cm3
OSHA PEL
Density 6.71998 lbs/gal
Skin protection Lightweight protective clothing, Apron, Impervious gloves
Volatile organic compounds (VOC) content 6.720 lbs/gal
Quebec TWAEV Ontario TWAEV
Volatile by weight 100.0000 %
Eye/face protection
Volatile by volume 100.0000 %
If splashes are likely to occur, wear Goggles.
Mexico OEL (TWA)
10. STABILITY AND REACTIVITY
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
METHYL N-PROPYLKETONE
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
STEL: 150 ppm TWA: 200 ppm TWA:700 mg/m3
STEL: 250 ppm STEL:875 mg/m3
TWA: 150 ppm TWA:530 mg/m3
STEL: 150 ppm
9. PHYSICAL AND CHEMICAL PROPERTIES
TWA: 200 ppm TWA:700 mg/m3
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proofequipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition duringuse and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
11. TOXICOLOGICAL INFORMATION
Flash point 8 °C / 46.0 °F
HandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Boiling range No information available
Exposure Guidelines
Upper explosion limit No information available
Engineering measures Ensure adequate ventilation, especially in confined areas
______________________________________________________________________________________________
Heat, flames and sparks.Possibility of hazardousreactions
None under normal processingIncompatible products
Page 3 / 6
Strong oxidizing agents.Chemical stability Stable. Conditions to avoid
______________________________________________________________________________________________
-THINNER CLEARF041-0050
Revision Date 08-Feb-2013
METHYL N-PROPYLKETONE
LC50 1190 - 1290 mg/LPimephales promelas 96 h
6500 mg/kg ( Rabbit )
Mutegenicity No information available.
13. DISPOSAL CONSIDERATIONS
Acute toxicity
Reproductive effects No information available.
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
Irritation No information available
Developmental effects No information available.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Component Information
Teratogenicity No information available.
14. TRANSPORT INFORMATION
Corrosivity No information available.
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin.
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Endocrine Disruptor Information No information available
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
Sensitization No information available.
Component
15. REGULATORY INFORMATION
LD50 Oral
12. ECOLOGICAL INFORMATION
International Inventories
LD50 Dermal LC50 Inhalation
TSCA Complies
Ecotoxicity
DSL/NDSL Complies
Chronic toxicity
EINECS/ELINCS CompliesCHINA Complies
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
______________________________________________________________________________________________
METHYL N-PROPYL KETONE 1600 mg/kg ( Rat )
Component Toxicity to algae
Page 4 / 6
Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
______________________________________________________________________________________________THINNER CLEARF041-0050
Revision Date 08-Feb-2013-
State Right-to-Know
Sudden Release of Pressure Hazard
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
no
Complies
METHYL N-PROPYLKETONE
X X X
Other international regulations
Reactive Hazard no
Canada
PICCS
SARA 311/312 Hazardous Categorization
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
Complies
United States of America Federal Regulations
CERCLA
WHMIS ClassificationB2 Flammable liquidD2B Toxic materials
KECL Complies
United States of America State Regulations
Chronic Health Hazard
LegendNPRI - National Pollutant Release Inventory
no
AICS
16. OTHER INFORMATION
California Prop. 65This product contains the following Proposition 65 chemicals:
Acute Health Hazard
Revision Date 08-Feb-2013
yes
Complies
SARA 313
______________________________________________________________________________________________
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Fire Hazard yes
Page 5 / 6
ENCS
______________________________________________________________________________________________THINNER CLEARF041-0050
Revision Date 08-Feb-2013-
Revision Note
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
______________________________________________________________________________________________
No information available
End of MSDS
Page 6 / 6
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 3 Reactivity 1
Print Date 16-Nov-2012 Revision Date 16-Nov-2012
Material Safety Data Sheet
Revision Number 3
Irritating to respiratory system.
F041-0051
Manufacturer
Ingestion May be harmful if swallowed.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER ELECTROSTATIC THINNER
See Section 11 for additional Toxicological information.
Common name NO. 51THINNER
Aggravated Medical Conditions Allergies. Skin disorders. Central nervous system. Gastrointestinal tract. Liver disorders.Respiratory disorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
Eyes Moderately irritating to the eyes.
Emergency Overview
______________________________________________________________________________________________
Skin Irritating to skin.
Product code
Page 1 / 6
Inhalation
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIREHARMFUL IF INHALED
HARMFUL OR FATAL IF SWALLOWEDMAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATIONMAY BE HARMFUL IF ABSORBED THROUGH SKIN.
DANGER!
______________________________________________________________________________________________Revision Date 16-Nov-2012
-THINNER ELECTROSTATIC THINNERF041-0051
ISOBUTYL ALCOHOL
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
78-83-1 1 - 5
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
Hazardous Components
6. ACCIDENTAL RELEASE MEASURES
Target Organ Effects
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
Component
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
4. FIRST AID MEASURES
CAS-No Weight %
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
5. FIRE-FIGHTING MEASURES
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Flammable properties Extremely flammable.
Eye contact:
Other information Not applicable
Rinse thoroughly with plenty of water for at least 15 minutes.
2-BUTANONE -
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
______________________________________________________________________________________________
60 - 100
Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinaltract, Liver, Respiratory system, Skin
Skin contact:
Page 2 / 6
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Wash off immediately with soap and plenty of water.
3. COMPOSITION/INFORMATION ON INGREDIENTS
______________________________________________________________________________________________Revision Date 16-Nov-2012
-THINNER ELECTROSTATIC THINNERF041-0051
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 200 ppm TWA:590 mg/m3
STEL: 300 ppm STEL:885 mg/m3
TWA: 50 ppm TWA:150 mg/m3
STEL: 100 ppm STEL:300 mg/m3
TWA: 200 ppmSTEL: 300 ppm
TWA: 200 ppm TWA:590 mg/m3
STEL: 300 ppm STEL:885 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
ISOBUTYL ALCOHOL TWA: 50 ppm
Flash point -7 °C / 20.0 °F
TWA: 50 ppm TWA:150 mg/m3
TWA: 100 ppm TWA:300 mg/m3
TWA: 50 ppm TWA:152 mg/m3
Boiling range 78 - 109 °C / 172.0 - 228.0 °F
TWA: 50 ppm TWA: 50 ppm TWA:150 mg/m3
STEL: 75 ppm STEL:225 mg/m3
Upper explosion limit No information available
HandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Lower explosion limit No information availableEvaporation rate No information available
Exposure Guidelines
Vapor pressure No information available
Engineering measures
Vapor density No information available
Ensure adequate ventilation, especially in confined areas
StorageVapors may ignite explosively. Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an areacontaining flame proof equipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and othersources of ignition during use and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors toachieve cross ventilation.
Specific Gravity .83678 g/cm3
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Density 6.96328 lbs/gal
Component ACGIH TLV
Volatile organic compounds (VOC) content 5.956 lbs/gal
Personal Protective Equipment
Volatile by weight 85.5420 %
OSHA PEL Quebec TWAEV
Volatile by volume 88.7765 %
Skin protection Lightweight protective clothing, Apron, Impervious gloves
Ontario TWAEV
10. STABILITY AND REACTIVITY
Mexico OEL (TWA)
Eye/face protection If splashes are likely to occur, wear Goggles.
______________________________________________________________________________________________
7. HANDLING AND STORAGE
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
Page 3 / 6
2-BUTANONE TWA: 200 ppmSTEL: 300 ppm
General hygiene considerations
______________________________________________________________________________________________
-THINNER ELECTROSTATIC THINNERF041-0051
Revision Date 16-Nov-2012
Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinaltract, Liver, Respiratory system, Skin.
ISOBUTYL ALCOHOL 2460 mg/kg ( Rat )
Endocrine Disruptor Information No information available
2000 mg/kg ( Rabbit ) 6.5 mg/L ( Rat ) 4 h
Acute toxicity
12. ECOLOGICAL INFORMATION
Irritation No information available
Ecotoxicity
Corrosivity No information available.Sensitization No information available.
11. TOXICOLOGICAL INFORMATION
Component Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
2-BUTANONE LC50 3130 - 3320 mg/LPimephales promelas 96 h
EC50 = 3426 mg/L 5 minEC50 = 3403 mg/L 30 min
EC50 4025 - 6440 mg/L 48h EC50 = 5091 mg/L 48 h
EC50 > 520 mg/L 48 h
Component Information
ISOBUTYL ALCOHOL EC50 = 230 mg/L 48 h LC50 1120 - 1520 mg/LOncorhynchus mykiss 96 h
LC50 1370 - 1670 mg/LPimephales promelas 96 h
LC50 1480 - 1730 mg/LLepomis macrochirus 96 h
LC50= 375 mg/LPimephales promelas 96 h
EC50 = 1224.6 mg/L 15 min EC50 1070 - 1933 mg/L 48h EC50 = 1300 mg/L 48 h
Chronic toxicity
13. DISPOSAL CONSIDERATIONS
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component LD50 Oral
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
LD50 Dermal LC50 Inhalation
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Mutegenicity No information available.Reproductive effects No information available.
2-BUTANONE 2737 mg/kg ( Rat )
Developmental effects No information available.
6480 mg/kg ( Rabbit )
Teratogenicity No information available.
______________________________________________________________________________________________
None under normal processingIncompatible products Strong oxidizing agents.Chemical stability
Page 4 / 6
Stable. Conditions to avoid Heat, flames and sparks.Possibility of hazardousreactions
______________________________________________________________________________________________
-THINNER ELECTROSTATIC THINNERF041-0051
Revision Date 16-Nov-2012
yes
Complies
Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Fire Hazard yes
PICCS
Sudden Release of Pressure Hazard no
Complies
Reactive Hazard no
AICS Complies
14. TRANSPORT INFORMATION
TSCA
CERCLA
Complies
United States of America Federal Regulations
15. REGULATORY INFORMATION
Component Hazardous Substances RQs CERCLA EHS RQs
DSL/NDSL
2-BUTANONE 5000 lb
Complies
ISOBUTYL ALCOHOL 5000 lb
SARA 313
United States of America State Regulations
DOT
EINECS/ELINCS
California Prop. 65This product contains the following Proposition 65 chemicals:
Complies
Component CAS-No Weight % SARA 313 - ThresholdValues
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
CHINA
2-BUTANONE
State Right-to-Know
60 - 100 1.0
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Complies
Proper shipping name
2-BUTANONE X X X X
SARA 311/312 Hazardous Categorization
UN1993,FLAMMABLE LIQUID,N.O.S.(METHYL ETHYL KETONE,ISOBUTYLALCOHOL),3,PGII,ERG 128
ENCS Complies
______________________________________________________________________________________________
International Inventories
Chronic Health Hazard no
Page 5 / 6
KECL
Acute Health Hazard
______________________________________________________________________________________________
F041-0051Revision Date 16-Nov-2012
-THINNER ELECTROSTATIC THINNER
Revision Note No information available
Component NPRI
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
X
2-BUTANONE Part 1, Group 1 Substance; Part 5 Substance
X
ISOBUTYL ALCOHOL Part 1, Group 1 SubstanceLegendNPRI - National Pollutant Release Inventory
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
Canada
16. OTHER INFORMATION
End of MSDS
ISOBUTYL ALCOHOL X
Revision Date 16-Nov-2012
______________________________________________________________________________________________
Other international regulations
Page 6 / 6
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 3 Reactivity 1
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 52 THINNERProduct code F041-0052Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Allergies. Skin disorders. Central nervous system. Gastrointestinal tract. Liver disorders.Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract,Liver, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 17-Oct-2011
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %METHYL ETHYL KETONE 78-93-3 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Extremely flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0052 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
StorageVapors may ignite explosively. Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an areacontaining flame proof equipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and othersources of ignition during use and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achievecross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)METHYL ETHYL KETONE : 200 ppm TWA : 300
ppm STEL: 200 ppm TWA; 590
mg/m3 TWA : 300 ppmSTEL; 885 mg/m3 STEL
TWA: 50 ppm TWAEV;150 mg/m3 TWAEV
STEL: 100 ppm STEV;300 mg/m3 STEV
TWA: 200 ppm TWASTEL: 300 ppm STEL
: 200 ppm TWA; 590mg/m3 TWA : 300 ppmSTEL; 885 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point -7°C / 20.0°FBoiling range 78 - 80°C / 172.0 - 176.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .80759 g/cm3Density 6.72032 lbs/galVolatile organic compounds (VOC) content 6.679 lbs/galVolatile by weight 99.3900 %Volatile by volume 99.5430 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
_____________________________________________________________________________________________
Page 3 / 6
Conditions to avoid Heat, flames and sparks.
F041-0052 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 17-Oct-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATIONAcute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationMETHYL ETHYL KETONE 2737 mg/kg ( Rat ) 6480 mg/kg ( Rabbit )
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract,
Liver, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaMETHYL ETHYL KETONE LC50 3130 - 3320 mg/L
Pimephales promelas 96 hEC50 = 3426 mg/L 5 minEC50 = 3403 mg/L 30 min
EC50 > 520 mg/L 48 h EC50 =5091 mg/L 48 h EC50 4025 -
6440 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
_____________________________________________________________________________________________
Page 4 / 6
Revision Date 17-Oct-2011F041-0052 - THINNER CLEAR
_____________________________________________________________________________________________
DSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
METHYL ETHYL KETONE 78-93-3 60 - 100 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
METHYL ETHYL KETONE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
Component NPRIMETHYL ETHYL KETONE Part 1, Group 1 Substance; Part 5 Substance
LegendNPRI - National Pollutant Release Inventory
_____________________________________________________________________________________________
Page 5 / 6
F041-0052 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2
F041-0052 - THINNER CLEAR
Flammability 3 Reactivity 1
Revision Date 17-Oct-2011
HMIS (Hazardous MaterialInformation System)
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 53 THINNERProduct code F041-0053Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Irritating to eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Liver disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Gastrointestinal tract, Eyes, Liver, Reproductive System,Respiratory system
3. COMPOSITION/INFORMATION ON INGREDIENTS
_____________________________________________________________________________________________
Page 1 / 6
16-May-2011
Material Safety Data Sheet
Revision Date 16-May-2011 Revision Number 2
WARNING!
HARMFUL IF INHALED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF SWALLOWED.
Print Date
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSHazardous ComponentsComponent CAS-No Weight %DIOCTYL PHTHALATE 117-81-7 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties No information available.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StoragePrevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 6
F041-0053 - THINNER CLEAR Revision Date 16-May-2011
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)DIOCTYL PHTHALATE : 5 mg/m3 TWA : 5 mg/m3 TWA : 10
mg/m3 STELTWA: 5 mg/m3 TWAEVSTEL: 10 mg/m3 STEV
TWA: 3 mg/m3 TWASTEL: 5 mg/m3 STEL
: 5 mg/m3 TWA : 10mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point Not applicableMethod Pensky Martens - Closed CupBoiling range No information availableUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .98660 g/cm3Density 8.20998 lbs/galVolatile organic compounds (VOC) content 8.210 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationDIOCTYL PHTHALATE 6860 mg/kg ( Rat ) 24500 mg/kg ( Rabbit ) 10.62 mg/L ( Rat ) 4 h 23.67 mg/L (
Rat ) 1 h
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Conditions to avoid Heat, flames and sparks
F041-0053 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 16-May-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
DIOCTYL PHTHALATE A3 Reasonably Anticipated X A3
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Gastrointestinal tract, Eyes, Liver, Reproductive System,
Respiratory system.Endocrine Disruptor Information No information available
Component EU - Endocrine DisruptersCandidate List
EU - Endocrine Disruptors -Evaluated Substances
Japan - Endocrine DisruptorInformation
DIOCTYL PHTHALATE Group III Chemical Group I Chemical High Exposure Concern
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaDIOCTYL PHTHALATE EC50 > 130 mg/L 72 h EC50 >
0.1 mg/L 96 hLC50 0.27 - 0.67 mg/L
Pimephales promelas 96 hLC50> 0.16 mg/L Pimephalespromelas 96 h LC50> 0.200
mg/L Lepomis macrochirus 96h LC50> 0.32 mg/L
Brachydanio rerio 96 h LC50>0.32 mg/L Oncorhynchus
mykiss 96 h LC50> 0.32 mg/LOryzias latipes 96 h LC50>0.32 mg/L Poecilia reticulata
96 h LC50> 0.67 mg/L Oryziaslatipes 96 h LC50> 100 mg/LOncorhynchus mykiss 96 h
EC50 = 800 mg/L 5 min EC50= 800 mg/L 15 min EC50 =
800 mg/L 30 min
LC50 = 9.4 mg/L 48 h EC50 >0.16 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
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F041-0053 - THINNER CLEAR Revision Date 16-May-2011
_____________________________________________________________________________________________
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentDIOCTYL PHTHALATE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
DIOCTYL PHTHALATE 117-81-7 60 - 100 0.1 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard noSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
DIOCTYL PHTHALATE X X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65DIOCTYL PHTHALATE 117-81-7 Carcinogen Developmental Male Reproductive
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandDIOCTYL PHTHALATE X X X X X
Other international regulations
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F041-0053 - THINNER CLEAR Revision Date 16-May-2011
_____________________________________________________________________________________________
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationD2A Very toxic materials
Component NPRIDIOCTYL PHTHALATE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 16-May-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
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Health 1 Flammability 0 Reactivity 0
F041-0053 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 16-May-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 55 THINNERProduct code F041-0055Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes. Risk of serious damage to eyes.Skin Irritating to skin. May cause sensitization by skin contact.Inhalation Irritating to respiratory system. May cause allergic respiratory reaction.Ingestion May be harmful if swallowed.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Eyes, Respiratory system, Skin
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HARMFUL IF INHALED.MAY CAUSE LUNG INJURY.
MAY CAUSE ALLERGIC RESPIRATORY REACTION; EFFECTS MAY BE PERMANENT.MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.COMBUSTIBLE LIQUID AND VAPOR.
Print Date 21-Jun-2011
Material Safety Data Sheet
Revision Date 20-Jun-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %TOLUENE DIISOCYANATE (TID) POL 60 - 100AROMATIC HYDROCARBON MIXTURE 64742-95-6 10 - 301,2,4-TRIMETHYLBENZENE 95-63-6 10 - 301,3,5-TRIMETHYLBENZENE 108-67-8 1 - 5DIETHYLBENZENE 25340-17-4 1 - 5XYLENE 1330-20-7 0.1 - 1TOLUENE DIISOCYANATE (TDI) MONOMER 584-84-9 0.1 - 1ETHYL BENZENE 100-41-4 0.1 - 1
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Hydrogen cyanide.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
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Revision Date 20-Jun-2011F041-0055 - THINNER CLEAR
_____________________________________________________________________________________________
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)1,2,4-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
123 mg/m3TWA: 25 ppm TWA:
123 mg/m3TWA: 125 mg/m3 TWA:
25 ppm STEL: 170mg/m3 STEL: 35 ppm
1,3,5-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:123 mg/m3
TWA: 25 ppm TWA:123 mg/m3
TWA: 125 mg/m3 TWA:25 ppm STEL: 170
mg/m3 STEL: 35 ppmXYLENE : 100 ppm TWA : 150
ppm STEL: 100 ppm TWA; 435
mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 150ppm STEV; 651 mg/m3
STEV
TWA: 100 ppm TWASTEL: 150 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TOLUENE DIISOCYANATE(TDI) MONOMER
: 0.005 ppm TWA : 0.02ppm STEL
: 0.005 ppm TWA; 0.04mg/m3 TWA : 0.02 ppm
STEL; 0.15 mg/m3
STEL : 0.02 ppmCeiling; 0.14 mg/m3
Ceiling
TWA: 0.005 ppmTWAEV; 0.036 mg/m3
TWAEV STEL: 0.02ppm STEV; 0.14 mg/m3
STEV
TWA: 0.005 ppm TWA(designated substanceregulation, listed underIsocyanates, organic
compounds); 0.005 ppmTWA (applies to
workplaces to which thedesignated substance
regulation does notapply) STEL: 0.02 ppmSTEL CEV: 0.02 ppm
Ceiling (designatedsubstances regulation)
: 0.02 ppm TWA; 0.14mg/m3 TWA
ETHYL BENZENE : 100 ppm TWA : 125ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 125ppm STEV; 543 mg/m3
STEV
TWA: 100 ppm TWASTEL: 125 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
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F041-0055 - THINNER CLEAR Revision Date 20-Jun-2011
_____________________________________________________________________________________________
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO
ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. Do not breathevapor or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved)during and after application unless air monitoring demonstrates vapor/mist levels are belowapplicable limits. An airline respirator (TC 19C NIOSH/MSHA) is recommended. A vapor-particulate respirator (TC 23C NIOSH/MSHA) may be appropriate where air monitoringdemonstrates vapors are less than ten times the applicable exposure limits and theisocyanate concentration is less than its applicable exposure limit. The use of an air-suppliedrespirator is mandatory whenever the airborne concentration of isocyanate monomer isunknown.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 39°C / 102.0°FBoiling range No information availableUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .97138 g/cm3Density 8.08334 lbs/galVolatile organic compounds (VOC) content 3.127 lbs/galVolatile by weight 38.6770 %Volatile by volume 43.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationAROMATIC HYDROCARBON
MIXTURE8400 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 3400 ppm ( Rat ) 4 h 5.2 mg/L ( Rat )
4 h1,2,4-TRIMETHYLBENZENE 3400 mg/kg ( Rat ) 3160 mg/kg ( Rabbit ) 18 g/m3 ( Rat ) 4 h1,3,5-TRIMETHYLBENZENE 5000 mg/kg ( Rat ) 24 g/m3 ( Rat ) 4 h
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F041-0055 - THINNER CLEAR
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
Revision Date 20-Jun-2011
Conditions to avoid Heat, flames and sparks.Amines.
Incompatible products Strong oxidizing agents. Acids.Alkalines. Water, alcohols,amines, strong bases, metalcomponents, surface activematerials.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATIONXYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h 47635 mg/L (
Rat ) 4 hTOLUENE DIISOCYANATE (TDI)
MONOMER5800 mg/kg ( Rat ) 16 mL/kg ( Rabbit ) 14 ppm ( Rat ) 4 h 0.1 mg/L ( Rat ) 4
h 13.9 ppm ( Rat ) 4 h 66 ppm ( Rat )1 h
ETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
TOLUENE DIISOCYANATE(TDI) MONOMER
Group 2B X
ETHYL BENZENE A3 Group 2B X
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Eyes, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaAROMATIC HYDROCARBON
MIXTURELC50= 9.22 mg/L
Oncorhynchus mykiss 96 hEC50 = 6.14 mg/L 48 h
1,2,4-TRIMETHYLBENZENE LC50 7.19-8.28 mg/LPimephales promelas 96 h
LC50= 7.72 mg/L Pimephalespromelas 96 h
EC50 = 6.14 mg/L 48 h
1,3,5-TRIMETHYLBENZENE LC50= 3.48 mg/L Pimephalespromelas 96 h LC50= 7.72
mg/L Pimephales promelas 96h
EC50 = 50 mg/L 24 h
XYLENE LC50= 13.4 mg/L Pimephalespromelas 96 h LC50 2.661-4.093 mg/L Oncorhynchus
mykiss 96 h LC50 13.5-17.3mg/L Oncorhynchus mykiss 96
h LC50 13.1-16.5 mg/LLepomis macrochirus 96 hLC50= 19 mg/L Lepomis
macrochirus 96 h LC50 7.711-9.591 mg/L Lepomis
macrochirus 96 h LC50 23.53-29.97 mg/L Pimephales
promelas 96 h LC50= 780mg/L Cyprinus carpio 96 hLC50> 780 mg/L Cyprinus
carpio 96 h LC50 30.26-40.75mg/L Poecilia reticulata 96 h
EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50= 0.6 mg/L 48 h
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F041-0055 - THINNER CLEAR Revision Date 20-Jun-2011
_____________________________________________________________________________________________
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaETHYL BENZENE EC50 = 4.6 mg/L 72 h EC50 >
438 mg/L 96 h EC50 2.6 -11.3 mg/L 72 h EC50 1.7 - 7.6
mg/L 96 h
LC50 11.0-18.0 mg/LOncorhynchus mykiss 96 h
LC50= 4.2 mg/LOncorhynchus mykiss 96 h
LC50 7.55-11 mg/LPimephales promelas 96 hLC50= 32 mg/L Lepomis
macrochirus 96 h LC50 9.1-15.6 mg/L Pimephales
promelas 96 h LC50= 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS Does not ComplyCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentXYLENETOLUENE DIISOCYANATE (TDI) MONOMERETHYL BENZENE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
1,2,4-TRIMETHYLBENZENE 95-63-6 10 - 30 1.0 % de minimisconcentration
XYLENE 1330-20-7 0.1 - 1 1.0 % de minimisconcentration
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F041-0055 - THINNER CLEAR Revision Date 20-Jun-2011
_____________________________________________________________________________________________
TOLUENE DIISOCYANATE (TDI) MONOMER 584-84-9 0.1 - 1 0.1 % de minimisconcentration 1.0 % deminimis concentration
(includes only those chemicalsthat are specifically listed,Chemical Category N120)
ETHYL BENZENE 100-41-4 0.1 - 1 0.1 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
XYLENE 100 lb RQ XETHYL BENZENE 1000 lb RQ X X X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQsTOLUENE DIISOCYANATE (TDI) MONOMER 100 lb EPCRA RQ
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65TOLUENE DIISOCYANATE (TDI) MONOMER 584-84-9 Carcinogen
ETHYL BENZENE 100-41-4 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island1,2,4-TRIMETHYLBENZENE X X X X X1,3,5-TRIMETHYLBENZENE X X X X X
DIETHYLBENZENE XXYLENE X X X X X
TOLUENE DIISOCYANATE(TDI) MONOMER
X X X X X
ETHYL BENZENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2A Very toxic materials
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Revision Date 20-Jun-2011F041-0055 - THINNER CLEAR
_____________________________________________________________________________________________
Component NPRIAROMATIC HYDROCARBON MIXTURE Part 5 Substance
1,2,4-TRIMETHYLBENZENE Part 1, Group 1 Substance; Part 5 SubstanceXYLENE Part 1, Group 1 Substance; Part 5 Substance
ETHYL BENZENE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 20-Jun-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
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Health 3*
Revision Date 20-Jun-2011
Flammability 2 Reactivity 1HMIS (Hazardous MaterialInformation System)
F041-0055 - THINNER CLEAR
Print Date 09-Oct-2012 Revision Date 30-Mar-2011
Material Safety Data Sheet
Revision Number 1
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO. 56 THINNER
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin
Eyes Moderately irritating to the eyes.
Emergency Overview
Skin Irritating to skin.
______________________________________________________________________________________________
Product code
Inhalation
Page 1 / 6
Irritating to respiratory system.
F041-0056
COMBUSTIBLE LIQUID AND VAPORHARMFUL IF INHALED
HARMFUL OR FATAL IF SWALLOWEDMAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
WARNING!
______________________________________________________________________________________________Revision Date 30-Mar-2011
-THINNER CLEARF041-0056
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
CAS-No
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
Weight %
4. FIRST AID MEASURES
Inhalation:
6. ACCIDENTAL RELEASE MEASURES
Move to fresh air. Oxygen or artificial respiration if needed.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
5. FIRE-FIGHTING MEASURES
P-CHLOROBENZOTRIFLUORIDE
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
98-56-6
Eye contact:
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Rinse thoroughly with plenty of water for at least 15 minutes.
Flammable properties Combustible material.
60 - 100
Hazardous Components
Other information Not applicable
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
7. HANDLING AND STORAGE
METHYL N-AMYL KETONE
Skin contact: Wash off immediately with soap and plenty of water.
110-43-0
______________________________________________________________________________________________
Hazardous decomposition products Oxides of carbon, hydrocarbons. Chlorine. Fluorine.
10 - 30
Page 2 / 6
Component
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
______________________________________________________________________________________________
-THINNER CLEARF041-0056
Revision Date 30-Mar-2011
TWA: 50 ppm TWA:235 mg/m3
STEL: 100 ppm STEL:465 mg/m3
HandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Upper explosion limit No information available
Exposure Guidelines
Lower explosion limit No information availableEvaporation rate No information available
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Vapor pressure No information available
Engineering measures Ensure adequate ventilation, especially in confined areas
Vapor density No information available
Component
Specific Gravity 1.17154 g/cm3
ACGIH TLV
Density 9.74899 lbs/gal
OSHA PEL
Personal Protective Equipment
Volatile organic compounds (VOC) content 4.203 lbs/gal
Quebec TWAEV
Volatile by weight 89.0830 %
Ontario TWAEV
Volatile by volume 86.2688 %
Skin protection Lightweight protective clothing, Apron, Impervious gloves
Mexico OEL (TWA)
10. STABILITY AND REACTIVITY
Eye/face protection Safety glasses with side-shields
P-CHLOROBENZOTRIFLUORIDE
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
TWA: 2.5 mg/m3
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 2.5 mg/m3 TWA: 2.5 mg/m3
11. TOXICOLOGICAL INFORMATION
9. PHYSICAL AND CHEMICAL PROPERTIES
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
METHYL N-AMYL KETONE TWA: 50 ppm TWA: 100 ppm TWA:465 mg/m3
Flash point 42 °C / 107.0 °F
TWA: 50 ppm TWA:233 mg/m3
TWA: 25 ppm TWA:115 mg/m3
Boiling range 139 - 154.000 °C / 282.0 - 309.0 °F
______________________________________________________________________________________________
Heat, flames and sparks.Possibility of hazardousreactions
None under normal processingIncompatible products
Page 3 / 6
Strong oxidizing agents.Chemical stability Stable. Conditions to avoid
______________________________________________________________________________________________THINNER CLEARF041-0056
Revision Date 30-Mar-2011-
Sensitization No information available.
P-CHLOROBENZOTRIFLUORIDE 13 g/kg ( Rat )
Component Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
Chronic toxicity
P-CHLOROBENZOTRIFLUORIDE
EC50 = 11.1 mg/L 5 minEC50 = 13.4 mg/L 15 minEC50 = 14.3 mg/L 30 min
EC50 = 3.68 mg/L 48 h
2 mL/kg ( Rabbit ) 33 mg/L ( Rat ) 4 h
METHYL N-AMYL KETONE LC50 126 - 137 mg/LPimephales promelas 96 h
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Acute toxicity
13. DISPOSAL CONSIDERATIONS
METHYL N-AMYL KETONE 1670 mg/kg ( Rat )
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
Mutegenicity No information available.
12600 µL/kg ( Rabbit )
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Reproductive effects No information available.
Component Information
14. TRANSPORT INFORMATION
Developmental effects No information available.
DEFOAMER 17 g/kg ( Rat )
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Teratogenicity No information available.
2 g/kg ( Rabbit )
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGIII,ERG 128
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system,Skin.
15. REGULATORY INFORMATION
Endocrine Disruptor Information No information available
Irritation No information available
Component LD50 Oral
______________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Corrosivity No information available.
Page 4 / 6
LD50 Dermal LC50 Inhalation
Ecotoxicity
______________________________________________________________________________________________
F041-0056Revision Date 30-Mar-2011
-THINNER CLEAR
TSCA
EINECS/ELINCS
California Prop. 65This product contains the following Proposition 65 chemicals:
PICCS
SARA 311/312 Hazardous Categorization
Does not Comply
Complies
Complies
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
AICS
Chronic Health Hazard no
State Right-to-Know
Does not Comply
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Acute Health Hazard
P-CHLOROBENZOTRIFLUORIDE
X X
yes
CHINA
METHYL N-AMYL KETONE X X X
Other international regulations
Fire Hazard yes
Complies
International Inventories
Canada
Sudden Release of Pressure Hazard no
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
DSL/NDSL
Reactive Hazard no
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
ENCS
United States of America Federal Regulations
Does not Comply
Complies
______________________________________________________________________________________________
CERCLA
KECL
SARA 313
Page 5 / 6
Complies
United States of America State Regulations
______________________________________________________________________________________________THINNER CLEARF041-0056
Revision Date 30-Mar-2011-
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
Revision Date 30-Mar-2011
16. OTHER INFORMATION
End of MSDS
Revision Note No information available
______________________________________________________________________________________________
LegendNPRI - National Pollutant Release Inventory
Page 6 / 6
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 2 Reactivity 1
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 57 THINNERProduct code F041-0057Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin. Repeated or prolonged skin contact may cause allergic reactions with
susceptible persons.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Kidney disorders. Liver disorders. Skindisorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
_____________________________________________________________________________________________
Page 1 / 8
Revision Number 3
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 17-Oct-2011
Material Safety Data Sheet
Revision Date 17-Oct-2011
_____________________________________________________________________________________________
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratorysystem, Skin
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %AROMATIC HYDROCARBON MIXTURE 64742-95-6 30 - 601,2,4-TRIMETHYLBENZENE 95-63-6 10 - 30ALDIMINE 54914-37-3 10 - 30DIETHYLENE GLYCOL MONOBUTYL ETHERACETATE
124-17-4 5 - 10
1,3,5-TRIMETHYLBENZENE 108-67-8 5 - 10DIETHYLBENZENE 25340-17-4 1 - 5CUMENE (SKIN) 98-82-8 1 - 5XYLENE 1330-20-7 1 - 5ETHYL BENZENE 100-41-4 0.1 - 1
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
_____________________________________________________________________________________________
Page 2 / 8
F041-0057 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)1,2,4-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
123 mg/m3TWA: 25 ppm TWA:
123 mg/m3TWA: 125 mg/m3 TWA:
25 ppm STEL: 170mg/m3 STEL: 35 ppm
1,3,5-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:123 mg/m3
TWA: 25 ppm TWA:123 mg/m3
TWA: 125 mg/m3 TWA:25 ppm STEL: 170
mg/m3 STEL: 35 ppmCUMENE (SKIN) : 50 ppm TWA : 50 ppm TWA; 245
mg/m3 TWA SkinTWA: 50 ppm TWAEV;
246 mg/m3 TWAEVTWA: 50 ppm TWA : 50 ppm TWA; 245
mg/m3 TWA : 75 ppmSTEL; 365 mg/m3 STEL
XYLENE : 100 ppm TWA : 150ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 150ppm STEV; 651 mg/m3
STEV
TWA: 100 ppm TWASTEL: 150 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
ETHYL BENZENE : 20 ppm TWA : 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 125ppm STEV; 543 mg/m3
STEV
TWA: 100 ppm TWASTEL: 125 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 43°C / 110.0°F
_____________________________________________________________________________________________
Page 3 / 8
Revision Date 17-Oct-2011F041-0057 - THINNER CLEAR
_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIESBoiling range 113 - 153°C / 235.0 - 307.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .88237 g/cm3Density 7.34265 lbs/galVolatile organic compounds (VOC) content 6.161 lbs/galVolatile by weight 83.9060 %Volatile by volume 83.6998 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationAROMATIC HYDROCARBON
MIXTURE8400 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 5.2 mg/L ( Rat ) 4 h 3400 ppm ( Rat )
4 h1,2,4-TRIMETHYLBENZENE 3400 mg/kg ( Rat ) 3160 mg/kg ( Rabbit ) 18 g/m3 ( Rat ) 4 h
DIETHYLENE GLYCOLMONOBUTYL ETHER ACETATE
6500 mg/kg ( Rat ) 14500 mg/kg ( Rabbit ) 73.7 mg/L ( Rat ) 4 h
1,3,5-TRIMETHYLBENZENE 5000 mg/kg ( Rat ) 24 g/m3 ( Rat ) 4 hCUMENE (SKIN) 1400 mg/kg ( Rat ) 3160 mg/kg ( Rabbit ) 39000 mg/m3 ( Rat ) 4 h
XYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h 47635 mg/L (Rat ) 4 h
ETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
ETHYL BENZENE A3 Group 2B X
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Respiratory
system, Skin.Endocrine Disruptor Information No information available
_____________________________________________________________________________________________
Page 4 / 8
Chemical stability Stable.
F041-0057 - THINNER CLEAR
Conditions to avoid Heat, flames and sparks.
Revision Date 17-Oct-2011
Incompatible products Strong oxidizing agents. Acids.Water. Alkalines.
Possibility of hazardousreactions
None under normal processing
_____________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaAROMATIC HYDROCARBON
MIXTURELC50= 9.22 mg/L
Oncorhynchus mykiss 96 hEC50 = 6.14 mg/L 48 h
1,2,4-TRIMETHYLBENZENE LC50= 7.72 mg/L Pimephalespromelas 96 h LC50 7.19 -
8.28 mg/L Pimephalespromelas 96 h
EC50 = 6.14 mg/L 48 h
DIETHYLENE GLYCOLMONOBUTYL ETHER
ACETATE
LC50 50 - 70 mg/LBrachydanio rerio 96 h LC50=77 mg/L Pimephales promelas
96 h
LC50 = 665 mg/L 48 h
1,3,5-TRIMETHYLBENZENE LC50= 3.48 mg/L Pimephalespromelas 96 h LC50= 7.72
mg/L Pimephales promelas 96h
EC50 = 50 mg/L 24 h
CUMENE (SKIN) EC50 = 2.6 mg/L 72 h LC50 6.04 - 6.61 mg/LPimephales promelas 96 h
LC50= 4.8 mg/LOncorhynchus mykiss 96 h
LC50= 2.7 mg/LOncorhynchus mykiss 96 h
LC50= 5.1 mg/L Poeciliareticulata 96 h
EC50 = 0.89 mg/L 5 min EC50= 1.10 mg/L 15 min EC50 =
1.48 mg/L 30 min EC50 = 172mg/L 24 h
EC50 = 0.6 mg/L 48 h EC507.9 - 14.1 mg/L 48 h
XYLENE LC50= 13.4 mg/L Pimephalespromelas 96 h LC50 2.661 -4.093 mg/L Oncorhynchus
mykiss 96 h LC50 13.5 - 17.3mg/L Oncorhynchus mykiss 96
h LC50 13.1 - 16.5 mg/LLepomis macrochirus 96 hLC50= 19 mg/L Lepomis
macrochirus 96 h LC50 7.711 -9.591 mg/L Lepomis
macrochirus 96 h LC50 23.53 -29.97 mg/L Pimephales
promelas 96 h LC50= 780mg/L Cyprinus carpio 96 hLC50> 780 mg/L Cyprinus
carpio 96 h LC50 30.26 - 40.75mg/L Poecilia reticulata 96 h
EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50= 0.6 mg/L 48 h
ETHYL BENZENE EC50 = 4.6 mg/L 72 h EC50 >438 mg/L 96 h EC50 2.6 -
11.3 mg/L 72 h EC50 1.7 - 7.6mg/L 96 h
LC50 11.0 - 18.0 mg/LOncorhynchus mykiss 96 h
LC50= 4.2 mg/LOncorhynchus mykiss 96 h
LC50 7.55 - 11 mg/LPimephales promelas 96 hLC50= 32 mg/L Lepomis
macrochirus 96 h LC50 9.1 -15.6 mg/L Pimephales
promelas 96 h LC50= 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
_____________________________________________________________________________________________
Page 5 / 8
F041-0057 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL Does not ComplyPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentDIETHYLENE GLYCOL MONOBUTYL ETHER ACETATECUMENE (SKIN)XYLENEETHYL BENZENE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
1,2,4-TRIMETHYLBENZENE 95-63-6 10 - 30 1.0 % de minimisconcentration
DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 124-17-4 5 - 10 1.0CUMENE (SKIN) 98-82-8 1 - 5 1.0 % de minimis
concentrationXYLENE 1330-20-7 1 - 5 1.0 % de minimis
concentrationETHYL BENZENE 100-41-4 0.1 - 1 0.1 % de minimis
concentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
XYLENE 100 lb RQ XETHYL BENZENE 1000 lb RQ X X X
_____________________________________________________________________________________________
Page 6 / 8
F041-0057 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65CUMENE (SKIN) 98-82-8 Carcinogen
ETHYL BENZENE 100-41-4 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island1,2,4-TRIMETHYLBENZENE X X X X X
DIETHYLENE GLYCOLMONOBUTYL ETHER
ACETATE
X X X
1,3,5-TRIMETHYLBENZENE X X X X XDIETHYLBENZENE X
CUMENE (SKIN) X X X X XXYLENE X X X X X
ETHYL BENZENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
Component NPRIAROMATIC HYDROCARBON MIXTURE Part 5 Substance
1,2,4-TRIMETHYLBENZENE Part 1, Group 1 Substance; Part 5 SubstanceCUMENE (SKIN) Part 1, Group 1 Substance
XYLENE Part 1, Group 1 Substance; Part 5 SubstanceETHYL BENZENE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
_____________________________________________________________________________________________
Page 7 / 8
F041-0057 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 17-Oct-2011
Health 2 Flammability 2 Reactivity 1
_____________________________________________________________________________________________
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 8 / 8
F041-0057 - THINNER CLEAR Revision Date 17-Oct-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 59 THINNERProduct code F041-0059Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Irritating to eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactive effects No information available
Potential environmental effects See Section 12 for additional Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %
_____________________________________________________________________________________________
Page 1 / 6
Material Safety Data Sheet
Revision Date 07-Jun-2011 Revision Number 2
WARNING!
HARMFUL IF INHALED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF SWALLOWED.
Print Date 07-Jun-2011
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSETHYLENE GLYCOL MONOPROPYL ETHER(SKIN)
2807-30-9 10 - 30
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties No information available.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StoragePrevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 6
Revision Date 07-Jun-2011F041-0059 - THINNER CLEAR
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)ETHYLENE GLYCOL
MONOPROPYL ETHER(SKIN)
TWA: 25 ppm TWA;110 mg/m3 TWA Skin
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point Not applicableBoiling range 100 - 154°C / 212.0 - 310.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .97885 g/cm3Density 8.14547 lbs/galVolatile organic compounds (VOC) content 7.601 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationWATER 90 mL/kg ( Rat )
ETHYLENE GLYCOLMONOPROPYL ETHER (SKIN)
3089 mg/kg ( Rat ) 960 µL/kg ( Rabbit )
_____________________________________________________________________________________________
Page 3 / 6
Revision Date 07-Jun-2011
Incompatible products Strong oxidizing agents. Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
F041-0059 - THINNER CLEAR
Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects No information availableEndocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB 2), WATER-BASE,FREEZABLE
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS Does not ComplyKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentETHYLENE GLYCOL MONOPROPYL ETHER (SKIN)
_____________________________________________________________________________________________
Page 4 / 6
F041-0059 - THINNER CLEAR Revision Date 07-Jun-2011
_____________________________________________________________________________________________
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
ETHYLENE GLYCOL MONOPROPYL ETHER (SKIN) 2807-30-9 10 - 30 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
ETHYLENE GLYCOLMONOPROPYL ETHER
(SKIN)
X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 07-Jun-2011
Revision Note No information available
_____________________________________________________________________________________________
Page 5 / 6
HMIS (Hazardous MaterialInformation System)
F041-0059 - THINNER CLEAR
Health 2 Flammability 0
Revision Date 07-Jun-2011
Reactivity 0
_____________________________________________________________________________________________
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
F041-0059 - THINNER CLEAR Revision Date 07-Jun-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 60 THINNERProduct code F041-0060Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratorysystem, Skin
_____________________________________________________________________________________________
Page 1 / 8
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 17-Oct-2011
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %METHYL N-AMYL KETONE 110-43-0 30 - 60N-BUTANOL (SKIN) 71-36-3 10 - 30AROMATIC HYDROCARBON MIXTURE 64742-95-6 10 - 301,2,4-TRIMETHYLBENZENE 95-63-6 10 - 301,3,5-TRIMETHYLBENZENE 108-67-8 1 - 5DIETHYLBENZENE 25340-17-4 1 - 5XYLENE 1330-20-7 0.1 - 1ETHYL BENZENE 100-41-4 0.1 - 1
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
_____________________________________________________________________________________________
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Revision Date 17-Oct-2011F041-0060 - THINNER CLEAR
_____________________________________________________________________________________________
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)METHYL N-AMYL KETONE : 50 ppm TWA : 100 ppm TWA; 465
mg/m3 TWATWA: 50 ppm TWAEV;
233 mg/m3 TWAEVTWA: 25 ppm TWA;
115 mg/m3 TWA: 50 ppm TWA; 235
mg/m3 TWA : 100 ppmSTEL; 465 mg/m3 STEL
N-BUTANOL (SKIN) : 20 ppm TWA Skin : 50 ppm Ceiling;150 mg/m3 Ceiling : 100ppm TWA; 300 mg/m3
TWA
Ceiling: 50 ppm Ceiling;152 mg/m3 Ceiling Skin
TWA: 20 ppm TWA : 50 ppm Peak; 150mg/m3 Peak
1,2,4-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:123 mg/m3
TWA: 25 ppm TWA:123 mg/m3
TWA: 125 mg/m3 TWA:25 ppm STEL: 170
mg/m3 STEL: 35 ppm1,3,5-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
123 mg/m3TWA: 25 ppm TWA:
123 mg/m3TWA: 125 mg/m3 TWA:
25 ppm STEL: 170mg/m3 STEL: 35 ppm
XYLENE : 100 ppm TWA : 150ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 150ppm STEV; 651 mg/m3
STEV
TWA: 100 ppm TWASTEL: 150 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 150 ppmSTEL; 655 mg/m3 STEL
ETHYL BENZENE : 20 ppm TWA : 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
TWA: 100 ppmTWAEV; 434 mg/m3
TWAEV STEL: 125ppm STEV; 543 mg/m3
STEV
TWA: 100 ppm TWASTEL: 125 ppm STEL
: 100 ppm TWA; 435mg/m3 TWA : 125 ppmSTEL; 545 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 37°C / 98.0°FBoiling range 116 - 154°C / 241.0 - 309.0°FUpper explosion limit No information available
_____________________________________________________________________________________________
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F041-0060 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIESLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .83761 g/cm3Density 6.97021 lbs/galVolatile organic compounds (VOC) content 6.970 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationMETHYL N-AMYL KETONE 1670 mg/kg ( Rat ) 12600 µL/kg ( Rabbit )
N-BUTANOL (SKIN) 790 mg/kg ( Rat ) 3400 mg/kg ( Rabbit ) 17.7 mg/L ( Rat ) 4 h 8000 ppm ( Rat) 4 h
AROMATIC HYDROCARBONMIXTURE
8400 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 5.2 mg/L ( Rat ) 4 h 3400 ppm ( Rat )4 h
1,2,4-TRIMETHYLBENZENE 3400 mg/kg ( Rat ) 3160 mg/kg ( Rabbit ) 18 g/m3 ( Rat ) 4 h1,3,5-TRIMETHYLBENZENE 5000 mg/kg ( Rat ) 24 g/m3 ( Rat ) 4 h
XYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h 47635 mg/L (Rat ) 4 h
ETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogenComponent ACGIH IARC NTP OSHA Mexico
ETHYL BENZENE A3 Group 2B X
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory
system, Skin.Endocrine Disruptor Information No information available
_____________________________________________________________________________________________
Page 4 / 8
Chemical stability Stable. Conditions to avoid Heat, flames and sparks.
F041-0060 - THINNER CLEAR
Incompatible products Strong oxidizing agents. Acids.Alkalines.
Revision Date 17-Oct-2011
Possibility of hazardousreactions
None under normal processing
_____________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaMETHYL N-AMYL KETONE LC50 126 - 137 mg/L
Pimephales promelas 96 hN-BUTANOL (SKIN) EC50 > 500 mg/L 96 h EC50 >
500 mg/L 72 hLC50 1730 - 1910 mg/L
Pimephales promelas 96 hLC50= 1740 mg/L Pimephalespromelas 96 h LC50 100000 -
500000 µg/L Lepomismacrochirus 96 h LC50=
1910000 µg/L Pimephalespromelas 96 h
EC50 = 2041.4 mg/L 5 minEC50 = 2186 mg/L 30 min
EC50 = 4400 mg/L 17 h EC50= 3980 mg/L 24 h
EC50 = 1983 mg/L 48 h EC501897 - 2072 mg/L 48 h
AROMATIC HYDROCARBONMIXTURE
LC50= 9.22 mg/LOncorhynchus mykiss 96 h
EC50 = 6.14 mg/L 48 h
1,2,4-TRIMETHYLBENZENE LC50= 7.72 mg/L Pimephalespromelas 96 h LC50 7.19 -
8.28 mg/L Pimephalespromelas 96 h
EC50 = 6.14 mg/L 48 h
1,3,5-TRIMETHYLBENZENE LC50= 3.48 mg/L Pimephalespromelas 96 h LC50= 7.72
mg/L Pimephales promelas 96h
EC50 = 50 mg/L 24 h
XYLENE LC50= 13.4 mg/L Pimephalespromelas 96 h LC50 2.661 -4.093 mg/L Oncorhynchus
mykiss 96 h LC50 13.5 - 17.3mg/L Oncorhynchus mykiss 96
h LC50 13.1 - 16.5 mg/LLepomis macrochirus 96 hLC50= 19 mg/L Lepomis
macrochirus 96 h LC50 7.711 -9.591 mg/L Lepomis
macrochirus 96 h LC50 23.53 -29.97 mg/L Pimephales
promelas 96 h LC50= 780mg/L Cyprinus carpio 96 hLC50> 780 mg/L Cyprinus
carpio 96 h LC50 30.26 - 40.75mg/L Poecilia reticulata 96 h
EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50= 0.6 mg/L 48 h
ETHYL BENZENE EC50 = 4.6 mg/L 72 h EC50 >438 mg/L 96 h EC50 2.6 -
11.3 mg/L 72 h EC50 1.7 - 7.6mg/L 96 h
LC50 11.0 - 18.0 mg/LOncorhynchus mykiss 96 h
LC50= 4.2 mg/LOncorhynchus mykiss 96 h
LC50 7.55 - 11 mg/LPimephales promelas 96 hLC50= 32 mg/L Lepomis
macrochirus 96 h LC50 9.1 -15.6 mg/L Pimephales
promelas 96 h LC50= 9.6 mg/LPoecilia reticulata 96 h
EC50 = 9.68 mg/L 30 minEC50 = 96 mg/L 24 h
EC50 1.8 - 2.4 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
_____________________________________________________________________________________________
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Revision Date 17-Oct-2011F041-0060 - THINNER CLEAR
_____________________________________________________________________________________________
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGIII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):ComponentXYLENEETHYL BENZENE
United States of America Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues
N-BUTANOL (SKIN) 71-36-3 10 - 30 1.0 % de minimisconcentration
1,2,4-TRIMETHYLBENZENE 95-63-6 10 - 30 1.0 % de minimisconcentration
XYLENE 1330-20-7 0.1 - 1 1.0 % de minimisconcentration
ETHYL BENZENE 100-41-4 0.1 - 1 0.1 % de minimisconcentration
SARA 311/312 Hazardous Categorization
Chronic Health Hazard yesAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
XYLENE 100 lb RQ XETHYL BENZENE 1000 lb RQ X X X
CERCLA
United States of America State Regulations
_____________________________________________________________________________________________
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F041-0060 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
California Prop. 65This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65ETHYL BENZENE 100-41-4 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode IslandMETHYL N-AMYL KETONE X X X X
N-BUTANOL (SKIN) X X X X1,2,4-TRIMETHYLBENZENE X X X X X1,3,5-TRIMETHYLBENZENE X X X X X
DIETHYLBENZENE XXYLENE X X X X X
ETHYL BENZENE X X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
Component NPRIN-BUTANOL (SKIN) Part 1, Group 1 Substance
AROMATIC HYDROCARBON MIXTURE Part 5 Substance1,2,4-TRIMETHYLBENZENE Part 1, Group 1 Substance; Part 5 Substance
XYLENE Part 1, Group 1 Substance; Part 5 SubstanceETHYL BENZENE Part 1, Group 1 Substance
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
_____________________________________________________________________________________________
Page 7 / 8
HMIS (Hazardous MaterialInformation System)
Revision Date 17-Oct-2011
Health 2 Flammability 3 Reactivity 1
F041-0060 - THINNER CLEAR
_____________________________________________________________________________________________
End of MSDS
_____________________________________________________________________________________________
Page 8 / 8
F041-0060 - THINNER CLEAR Revision Date 17-Oct-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 61 THINNERProduct code F041-0061Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 17-Oct-2011
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %ACETONE 67-64-1 5 - 10
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0061 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)ACETONE : 500 ppm TWA : 750
ppm STEL: 750 ppm TWA; 1800
mg/m3 TWA : 2400mg/m3 STEL (The
acetone STEL does notapply to the cellulose
acetate fiber industry. Itis in effect for all other
sectors); 1000 ppmSTEL : 1000 ppm TWA;
2400 mg/m3 TWA
TWA: 500 ppmTWAEV; 1190 mg/m3
TWAEV STEL: 1000ppm STEV; 2380 mg/m3
STEV
TWA: 500 ppm TWASTEL: 750 ppm STEL
: 1000 ppm TWA; 2400mg/m3 TWA : 1260 ppm
STEL; 3000 mg/m3
STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 18°C / 64.0°FBoiling range 100°C / 212.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .97990 g/cm3Density 8.15426 lbs/galVolatile organic compounds (VOC) content .000 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
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F041-0061 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationWATER 90 mL/kg ( Rat )
ACETONE 5800 mg/kg ( Rat )
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Eyes, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaACETONE LC50 4.74 - 6.33 mL/L
Oncorhynchus mykiss 96 hLC50 6210 - 8120 mg/L
Pimephales promelas 96 hLC50= 8300 mg/L Lepomis
macrochirus 96 h
EC50 = 14500 mg/L 15 min EC50 10294 - 17704 mg/L 48h EC50 12600 - 12700 mg/L
48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
_____________________________________________________________________________________________
Page 4 / 6
Incompatible products Strong oxidizing agents.
F041-0061 - THINNER CLEAR
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
Revision Date 17-Oct-2011
Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
14. TRANSPORT INFORMATIONDOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other
modes of Transportation.
Proper shipping name UN1090,ACETONE MIXTURE, 3,PGII, ERG 127, FREEZABLE
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS Does not ComplyKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode IslandACETONE X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2B Toxic materials
_____________________________________________________________________________________________
Page 5 / 6
Revision Date 17-Oct-2011F041-0061 - THINNER CLEAR
_____________________________________________________________________________________________
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2 Flammability 3 Reactivity 1
F041-0061 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 17-Oct-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 62 THINNERProduct code F041-0062Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 17-Oct-2011
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %P-CHLOROBENZOTRIFLUORIDE 98-56-6 60 - 100tert-BUTYL ACETATE 540-88-5 10 - 30
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons. Chlorine. Fluorine.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
Revision Date 17-Oct-2011F041-0062 - THINNER CLEAR
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)P-
CHLOROBENZOTRIFLUORIDE
TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3
tert-BUTYL ACETATE : 200 ppm TWA : 200 ppm TWA; 950mg/m3 TWA
TWA: 200 ppmTWAEV; 950 mg/m3
TWAEV
TWA: 200 ppm TWA : 200 ppm TWA; 950mg/m3 TWA : 250 ppm
STEL; 1190 mg/m3
STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 6°C / 42.0°FBoiling range 98 - 139°C / 208.0 - 282.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity 1.24929 g/cm3Density 10.39597 lbs/galVolatile organic compounds (VOC) content .000 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
Page 3 / 6
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
F041-0062 - THINNER CLEAR
Conditions to avoid Heat, flames and sparks.
Revision Date 17-Oct-2011
Incompatible products Strong oxidizing agents. Bases.Acids.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationP-CHLOROBENZOTRIFLUORIDE 13 g/kg ( Rat ) 2 mg/kg ( Rabbit ) 33 mg/L ( Rat ) 4 h
tert-BUTYL ACETATE 4100 mg/kg ( Rat ) 2 g/kg ( Rabbit ) 2230 mg/m3 ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Eyes, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaP-
CHLOROBENZOTRIFLUORIDE
EC50 = 11.1 mg/L 5 min EC50= 13.4 mg/L 15 min EC50 =
14.3 mg/L 30 min
EC50 = 3.68 mg/L 48 h
tert-BUTYL ACETATE LC50 296 - 362 mg/LPimephales promelas 96 h
EC50 = 6.38 mg/L 5 min EC50= 8.04 mg/L 15 min EC50 =
11.1 mg/L 30 min
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
_____________________________________________________________________________________________
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Revision Date 17-Oct-2011F041-0062 - THINNER CLEAR
_____________________________________________________________________________________________
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
P-CHLOROBENZOTRIFLUORIDE Xtert-BUTYL ACETATE X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
P-CHLOROBENZOTRIFLUORI
DE
X X X
tert-BUTYL ACETATE X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2B Toxic materials
_____________________________________________________________________________________________
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F041-0062 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2 Flammability 3
F041-0062 - THINNER CLEAR
Reactivity 1
Revision Date 17-Oct-2011
HMIS (Hazardous MaterialInformation System)
Print Date 08-Feb-2013 Revision Date 08-Feb-2013
Material Safety Data Sheet
Revision Number 5
Manufacturer
Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillatesand/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
1. PRODUCT AND COMPANY IDENTIFICATION
Chronic effects
Emergency telephone
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain andnervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
Trade name
Potential health effects
THINNER CLEAR
See Section 11 for additional Toxicological information.
Common name NO. 63 THINNER
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
2. HAZARDS IDENTIFICATION
Product Class
Interactive effects Use of alcoholic beverages may enhance toxic effects.
PAINT THINNER
Acute effects
Potential environmental effects See Section 12 for additional Ecological Information.
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin
Eyes Moderately irritating to the eyes.
Emergency Overview
Skin Irritating to skin.
______________________________________________________________________________________________
Product code
Inhalation
Page 1 / 6
Irritating to respiratory system.
F041-0063
COMBUSTIBLE LIQUID AND VAPORHARMFUL IF INHALED
HARMFUL OR FATAL IF SWALLOWEDMAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
WARNING!
______________________________________________________________________________________________Revision Date 08-Feb-2013
-THINNER CLEARF041-0063
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
CAS-No
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
Weight %
4. FIRST AID MEASURES
Inhalation:
6. ACCIDENTAL RELEASE MEASURES
Move to fresh air. Oxygen or artificial respiration if needed.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
5. FIRE-FIGHTING MEASURES
2-HEPTANONE
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water orsanitary sewer system.
-
Eye contact:
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Rinse thoroughly with plenty of water for at least 15 minutes.
Flammable properties Combustible material.
5 - 10
Hazardous Components
Other information Not applicable
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment. Contact with water may cause violent frothing. Use: Carbondioxide (CO2) - Foam - Dry chemical
7. HANDLING AND STORAGE
DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE
Skin contact: Wash off immediately with soap and plenty of water.
124-17-4
______________________________________________________________________________________________
Hazardous decomposition products Oxides of carbon, hydrocarbons.
1 - 5
Page 2 / 6
Component
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathefumes.
______________________________________________________________________________________________Revision Date 08-Feb-2013
-THINNER CLEARF041-0063
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Evaporation rate No information availableVapor pressure No information available
Component
Personal Protective Equipment
Vapor density No information available
ACGIH TLV
Specific Gravity .87915 g/cm3
OSHA PEL
Density 7.31585 lbs/gal
Skin protection Lightweight protective clothing, Apron, Impervious gloves
Volatile organic compounds (VOC) content 6.414 lbs/gal
Quebec TWAEV Ontario TWAEV
Volatile by weight 87.6650 %
Eye/face protection
Volatile by volume 88.3576 %
Safety glasses with side-shields
Mexico OEL (TWA)
10. STABILITY AND REACTIVITY
Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensurefresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and afterapplication. Follow respirator manufacturer's directions for respirator use.
2-HEPTANONE
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
TWA: 50 ppm TWA: 100 ppm TWA:465 mg/m3
TWA: 50 ppm TWA:233 mg/m3
TWA: 25 ppm TWA:115 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
TWA: 50 ppm TWA:235 mg/m3
STEL: 100 ppm STEL:465 mg/m3
StorageClose container after each use. Keep away from heat, sparks and flame. Use only in an area containing flame proof equipment.Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
11. TOXICOLOGICAL INFORMATION
Flash point 57 °C / 134.0 °F
HandlingAvoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove andwash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. When used in a mixture, read thelabels and safety data sheets of all components. Wash thoroughly after handling.
Boiling range No information available
Exposure Guidelines
Upper explosion limit No information available
Engineering measures Ensure adequate ventilation, especially in confined areas
Lower explosion limit No information available
______________________________________________________________________________________________
Strong oxidizing agents. Acids.Alkalines.
Chemical stability Stable. Conditions to avoid
Page 3 / 6
Heat, flames and sparks.Possibility of hazardousreactions
None under normal processingIncompatible products
______________________________________________________________________________________________THINNER CLEARF041-0063
Revision Date 08-Feb-2013-
HEXYL ACETATE 41500 µL/kg ( Rat ) 5 g/kg ( Rabbit )
Chronic toxicity
Component Toxicity to algae Toxicity to fish Toxicity tomicroorganisms
Toxicity to daphnia
Component Information
HEXYL ACETATE LC50 3.7 - 4.4 mg/LPimephales promelas 96 h
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
2-HEPTANONE LC50 126 - 137 mg/LPimephales promelas 96 h
2-HEPTANONE 1670 mg/kg ( Rat )
DIETHYLENE GLYCOLMONOBUTYL ETHER
ACETATE
LC50 50 - 70 mg/LBrachydanio rerio 96 h
LC50= 77 mg/L Pimephalespromelas 96 h
LC50 = 665 mg/L 48 h
12600 µL/kg ( Rabbit )
13. DISPOSAL CONSIDERATIONS
Mutegenicity No information available.
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents inaccordance with local, state and federal regulations.
Reproductive effects No information available.
DIETHYLENE GLYCOLMONOBUTYL ETHER ACETATE
6500 mg/kg ( Rat )
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
Developmental effects No information available.
14500 mg/kg ( Rabbit ) 73.7 mg/L ( Rat ) 4 h
14. TRANSPORT INFORMATION
Teratogenicity No information available.
Component LD50 Oral
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system,Skin.
Irritation No information available
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
Endocrine Disruptor Information No information available
LD50 Dermal LC50 Inhalation
Corrosivity No information available.
______________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Acute toxicity
Page 4 / 6
Sensitization No information available.
Ecotoxicity
______________________________________________________________________________________________THINNER CLEARF041-0063
Revision Date 08-Feb-2013-
Complies
Reactive Hazard no
DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE
ENCS Does not Comply
United States of America Federal Regulations
CERCLA
KECL Complies
United States of America State Regulations
SARA 313
DSL/NDSL Complies
California Prop. 65This product contains the following Proposition 65 chemicals:
PICCS Does not Comply
Component CAS-No
California SCAQMD Rule 443Contains Photochemically Reactive Solvent
Weight % SARA 313 - ThresholdValues
15. REGULATORY INFORMATION
State Right-to-Know
DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 124-17-4
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
1 - 5 1.0
2-HEPTANONE X X X
AICS Does not Comply
DIETHYLENE GLYCOLMONOBUTYL ETHER
ACETATE
X X X
SARA 311/312 Hazardous Categorization
EINECS/ELINCS
Other international regulations
Complies
Canada
Chronic Health Hazard no
International Inventories
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
Acute Health Hazard yes
CHINA Complies
______________________________________________________________________________________________
Fire Hazard yes
Component HAPS Data
Page 5 / 6
Sudden Release of Pressure Hazard no
TSCA
______________________________________________________________________________________________
-THINNER CLEARF041-0063
Revision Date 08-Feb-2013
Revision Note No information available
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company orany of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information containedherein. Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown health hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards which exist.
LegendNPRI - National Pollutant Release Inventory
End of MSDS
Revision Date 08-Feb-2013
______________________________________________________________________________________________
16. OTHER INFORMATION
Page 6 / 6
Health 2HMIS (Hazardous MaterialInformation System)
Flammability 2 Reactivity 1
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 64 THINNERProduct code F041-0064Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Allergies. Skin disorders. Central nervous system. Gastrointestinal tract. Liver disorders.Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract,Liver, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 31-Mar-2011
Material Safety Data Sheet
Revision Date 31-Mar-2011 Revision Number 1
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %ACETONE 67-64-1 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Extremely flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0064 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
StorageVapors may ignite explosively. Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an areacontaining flame proof equipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and othersources of ignition during use and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achievecross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)ACETONE : 500 ppm TWA : 750
ppm STEL: 750 ppm TWA; 1800
mg/m3 TWA : 2400mg/m3 STEL (The
acetone STEL does notapply to the cellulose
acetate fiber industry. Itis in effect for all other
sectors); 1000 ppmSTEL : 1000 ppm TWA;
2400 mg/m3 TWA
TWA: 500 ppmTWAEV; 1190 mg/m3
TWAEV STEL: 1000ppm STEV; 2380 mg/m3
STEV
TWA: 500 ppm TWASTEL: 750 ppm STEL
: 1000 ppm TWA; 2400mg/m3 TWA : 1260 ppm
STEL; 3000 mg/m3
STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point -16°C / 4.0°FBoiling range No information availableUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .79192 g/cm3Density 6.59000 lbs/galVolatile organic compounds (VOC) content .000 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
Page 3 / 6
F041-0064 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationACETONE 5800 mg/kg ( Rat )
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract,
Liver, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaACETONE LC50 4.74 - 6.33 mL/L
Oncorhynchus mykiss 96 hLC50 6210 - 8120 mg/L
Pimephales promelas 96 hLC50= 8300 mg/L Lepomis
macrochirus 96 h
EC50 = 14500 mg/L 15 min EC50 10294 - 17704 mg/L 48h EC50 12600 - 12700 mg/L
48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
_____________________________________________________________________________________________
Page 4 / 6
Revision Date 31-Mar-2011
Conditions to avoid Heat, flames and sparks.
Incompatible products Strong oxidizing agents.
F041-0064 - THINNER CLEAR
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
14. TRANSPORT INFORMATIONDOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other
modes of Transportation.
Proper shipping name UN1090,ACETONE,3,PGII, ERG 127
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode IslandACETONE X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
_____________________________________________________________________________________________
Page 5 / 6
Revision Date 31-Mar-2011F041-0064 - THINNER CLEAR
_____________________________________________________________________________________________
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 31-Mar-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 2 Flammability 3 Reactivity 1
F041-0064 - THINNER CLEAR
HMIS (Hazardous MaterialInformation System)
Revision Date 31-Mar-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 65 THINNERProduct code F041-0065Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders. Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
FLAMMABLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 31-Mar-2011
Material Safety Data Sheet
Revision Date 31-Mar-2011 Revision Number 1
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %tert-BUTYL ACETATE 540-88-5 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0065 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
StorageKeep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until allvapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)tert-BUTYL ACETATE : 200 ppm TWA : 200 ppm TWA; 950
mg/m3 TWATWA: 200 ppm
TWAEV; 950 mg/m3
TWAEV
TWA: 200 ppm TWA : 200 ppm TWA; 950mg/m3 TWA : 250 ppm
STEL; 1190 mg/m3
STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 16°C / 60.0°FBoiling range 98°C / 208.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .86282 g/cm3Density 7.17999 lbs/galVolatile organic compounds (VOC) content .000 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
_____________________________________________________________________________________________
Page 3 / 6
Conditions to avoid Heat, flames and sparks.
F041-0065 - THINNER CLEAR
Incompatible products Strong oxidizing agents. Bases.Acids.
Revision Date 31-Mar-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalationtert-BUTYL ACETATE 4100 mg/kg ( Rat ) 2 g/kg ( Rabbit ) 2230 mg/m3 ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Central nervous system, Eyes, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniatert-BUTYL ACETATE LC50 296-362 mg/L
Pimephales promelas 96 hEC50 = 6.38 mg/L 5 min EC50
= 8.04 mg/L 15 min EC50 =11.1 mg/L 30 min
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1263,PAINT RELATED MATERIAL,3,PGII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS Complies
_____________________________________________________________________________________________
Page 4 / 6
F041-0065 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
CHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
Component CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
tert-BUTYL ACETATE X
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
tert-BUTYL ACETATE X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 31-Mar-2011
_____________________________________________________________________________________________
Page 5 / 6
F041-0065 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 1
F041-0065 - THINNER CLEAR
Flammability 3 Reactivity 1
Revision Date 31-Mar-2011
HMIS (Hazardous MaterialInformation System)
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 66 THINNERProduct code F041-0066Trade name THINNER TEXANOLProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Irritating to eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactive effects No information available
Potential environmental effects See Section 12 for additional Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %
_____________________________________________________________________________________________
Page 1 / 5
Material Safety Data Sheet
Revision Date 11-Apr-2011 Revision Number 1
WARNING!
HARMFUL IF INHALED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF SWALLOWED.
Print Date 11-Apr-2011
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS2,2,4-TRIMETHYL-1,3-PENTANEDIOLMONOISOBUTYRATE
25265-77-4 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties No information available.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StoragePrevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 5
Revision Date 11-Apr-2011F041-0066 - THINNER TEXANOL
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 120°C / 248.0°FMethod Pensky Martens - Closed CupBoiling range 254 - 260°C / 490.0 - 500.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .94935 g/cm3Density 7.90002 lbs/galVolatile organic compounds (VOC) content 7.900 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation2,2,4-TRIMETHYL-1,3-
PENTANEDIOLMONOISOBUTYRATE
3200 mg/kg ( Rat ) 15200 mg/kg ( Rat )
Irritation No information availableCorrosivity No information availableSensitization No information available
_____________________________________________________________________________________________
Page 3 / 5
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable. Conditions to avoid Heat, flames and sparks
F041-0066 - THINNER TEXANOL
Incompatible products Strong oxidizing agents.
Revision Date 11-Apr-2011
_____________________________________________________________________________________________
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects No information availableEndocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia2,2,4-TRIMETHYL-1,3-
PENTANEDIOLMONOISOBUTYRATE
EC50 = 18.4 mg/L 72 h LC50= 30 mg/L Pimephalespromelas 96 h
LC50 > 95 mg/L 96 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
_____________________________________________________________________________________________
Page 4 / 5
F041-0066 - THINNER TEXANOL Revision Date 11-Apr-2011
_____________________________________________________________________________________________
Chronic Health Hazard noAcute Health Hazard noFire Hazard noSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowOther international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 11-Apr-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 5 / 5
Health 1 Flammability 1 Reactivity 0
F041-0066 - THINNER TEXANOL
HMIS (Hazardous MaterialInformation System)
Revision Date 11-Apr-2011
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 68 THINNERProduct code F041-0068Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Allergies. Skin disorders. Central nervous system. Gastrointestinal tract. Liver disorders.Respiratory disorders.
Interactive effects Use of alcoholic beverages may enhance toxic effects.
Potential environmental effects See Section 12 for additional Ecological Information
Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract,Liver, Respiratory system, Skin
_____________________________________________________________________________________________
Page 1 / 6
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Print Date 31-Mar-2011
Material Safety Data Sheet
Revision Date 31-Mar-2011 Revision Number 1
DANGER!
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %METHYL ACETATE 79-20-9 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Extremely flammable.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Ifsplashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
_____________________________________________________________________________________________
Page 2 / 6
F041-0068 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
StorageVapors may ignite explosively. Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an areacontaining flame proof equipment. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and othersources of ignition during use and until all vapors are gone. Prevent build-up of vapors by opening all windows and doors to achievecross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)METHYL ACETATE : 200 ppm TWA : 250
ppm STEL: 200 ppm TWA; 610
mg/m3 TWA : 250 ppmSTEL; 760 mg/m3 STEL
TWA: 200 ppmTWAEV; 606 mg/m3
TWAEV STEL: 250ppm STEV; 757 mg/m3
STEV
TWA: 200 ppm TWASTEL: 250 ppm STEL
: 200 ppm TWA; 610mg/m3 TWA : 250 ppmSTEL; 760 mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection If splashes are likely to occur, wear Goggles.Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point -10°C / 14.0°FBoiling range No information availableUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .93132 g/cm3Density 7.75002 lbs/galVolatile organic compounds (VOC) content .000 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
Page 3 / 6
Revision Date 31-Mar-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable. Conditions to avoid Heat, flames and sparks.
F041-0068 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationMETHYL ACETATE 5000 mg/kg ( Rat ) 2000 mg/kg ( Rat ) 5000 mg/kg (
Rabbit )16000 ppm ( Rat ) 4 h
Irritation No information availableCorrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract,
Liver, Respiratory system, Skin.Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaMETHYL ACETATE EC50 > 120 mg/L 72 h LC50 250-350 mg/L
Brachydanio rerio 96 h LC50295-348 mg/L Pimephales
promelas 96 h
EC50 = 6100 mg/L 30 minEC50 = 6000 mg/L 16 h
EC50 = 1026.7 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name UN1231,METHYL ACETATE,3,PGII,ERG 129
15. REGULATORY INFORMATION
_____________________________________________________________________________________________
Page 4 / 6
F041-0068 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
15. REGULATORY INFORMATIONInternational Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowComponent Massachusetts New Jersey Pennsylvania Illinois Rhode Island
METHYL ACETATE X X X X
Other international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB2 Flammable liquidD2A Very toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 31-Mar-2011
_____________________________________________________________________________________________
Page 5 / 6
F041-0068 - THINNER CLEAR Revision Date 31-Mar-2011
_____________________________________________________________________________________________
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 6 / 6
Health 1
F041-0068 - THINNER CLEAR
Flammability 3 Reactivity 0
Revision Date 31-Mar-2011
HMIS (Hazardous MaterialInformation System)
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 72 THINNERProduct code F041-0072Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactive effects No information available
Potential environmental effects See Section 12 for additional Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %
_____________________________________________________________________________________________
Page 1 / 5
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date 17-Oct-2011
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSDIPROPYLENE GLYCOL MONOMETHYLETHER ACETATE
88917-22-0 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties No information available
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 5
Revision Date 17-Oct-2011F041-0072 - THINNER CLEAR
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)DIPROPYLENE GLYCOLMONOMETHYL ETHER
ACETATE
TWA: 100 ppm TWA;776 mg/m3 TWA STEL:150 ppm STEL; 1164
mg/m3 STEL
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 120°C / 248.0°FMethod Pensky Martens - Closed CupBoiling range No information availableUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .97578 g/cm3Density 8.11998 lbs/galVolatile organic compounds (VOC) content 8.120 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Irritation No information availableCorrosivity No information available
_____________________________________________________________________________________________
Page 3 / 5
Chemical stability Stable. Conditions to avoid Heat, flames and sparks.
F041-0072 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 17-Oct-2011
Possibility of hazardousreactions
None under normal processing
_____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATIONSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects No information availableEndocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
_____________________________________________________________________________________________
Page 4 / 5
F041-0072 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
Chronic Health Hazard noAcute Health Hazard noFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowOther international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 5 / 5
Health 1
Revision Date 17-Oct-2011
Flammability 1 Reactivity 0HMIS (Hazardous MaterialInformation System)
F041-0072 - THINNER CLEAR
1. PRODUCT AND COMPANY IDENTIFICATION
Common name NO. 73 THINNERProduct code F041-0073Trade name THINNER CLEARProduct Class PAINT THINNER
Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372Emergency telephone 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
Potential health effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute effectsEyes Moderately irritating to the eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion May be harmful if swallowed. Do not induce vomiting: may contain petroleum distillates
and/or aromatic solvents. Aspiration may cause pulmonary edema and pneumonitis.
Chronic effectsNOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactive effects No information available
Potential environmental effects See Section 12 for additional Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ComponentsComponent CAS-No Weight %
_____________________________________________________________________________________________
Page 1 / 5
Material Safety Data Sheet
Revision Date 17-Oct-2011 Revision Number 2
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Print Date 17-Oct-2011
_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTSETHYL 3-ETHOXYPROPIONATE 763-69-9 60 - 100
4. FIRST AID MEASURES
Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact: Wash off immediately with soap and plenty of water.
Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable properties Combustible material.
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -Foam - Dry chemical
Hazardous decomposition products Oxides of carbon, hydrocarbons.
Specific hazards arising from the chemicalThermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefightersUse water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away fromheat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier thanair and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove allsources of ignition.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitarysewer system.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminatedabsorbent, container and unused contents in accordance with local, state and federalregulations.
Other information Not applicable
7. HANDLING AND STORAGEHandlingClose container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene andsafety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. Whenused in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
StorageKeep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors byopening all windows and doors to achieve cross ventilation.
_____________________________________________________________________________________________
Page 2 / 5
Revision Date 17-Oct-2011F041-0073 - THINNER CLEAR
_____________________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)ETHYL 3-
ETHOXYPROPIONATETWA: 50 ppm TWA;
300 mg/m3 TWA
Engineering measures Ensure adequate ventilation, especially in confined areas
Personal Protective EquipmentSkin protection Lightweight protective clothing, Apron, Impervious glovesEye/face protection Safety glasses with side-shieldsRespiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache ordizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.Follow respirator manufacturer's directions for respirator use.
General hygieneconsiderations
Handle in accordance with good industrial hygiene and safety practice.Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point 61°C / 142.0°FMethod Pensky Martens - Closed CupBoiling range 164 - 165°C / 328.0 - 329.0°FUpper explosion limit No information availableLower explosion limit No information availableEvaporation rate No information availableVapor pressure No information availableVapor density No information availableSpecific Gravity .95055 g/cm3Density 7.91002 lbs/galVolatile organic compounds (VOC) content 7.910 lbs/galVolatile by weight 100.0000 %Volatile by volume 100.0000 %
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationETHYL 3-ETHOXYPROPIONATE 3200 mg/kg ( Rat ) 10 mL/kg ( Rabbit )
Irritation No information available
_____________________________________________________________________________________________
Page 3 / 5
F041-0073 - THINNER CLEAR
Incompatible products Strong oxidizing agents.
Revision Date 17-Oct-2011
Possibility of hazardousreactions
None under normal processing
Chemical stability Stable. Conditions to avoid Heat, flames and sparks.
_____________________________________________________________________________________________
Corrosivity No information availableSensitization No information available
Chronic toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutegenicity No information availableReproductive effects No information availableDevelopmental effects No information availableTeratogenicity No information availableTarget Organ Effects No information availableEndocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphniaETHYL 3-
ETHOXYPROPIONATELC50= 62 mg/L Pimephales
promelas 96 hEC50 = 970 mg/L 48 h
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Keep container tightly closed. If spilled, contain spilled material and remove with inertabsorbent. Dispose of contaminated absorbent, container and unused contents in accordancewith local, state and federal regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for othermodes of Transportation.
Proper shipping name PAINT & RELATED MATERIAL-(NMFC 149980 SUB2)
15. REGULATORY INFORMATION
International Inventories
TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesCHINA CompliesENCS CompliesKECL CompliesPICCS CompliesAICS Complies
United States of America Federal Regulations
SARA 313
_____________________________________________________________________________________________
Page 4 / 5
F041-0073 - THINNER CLEAR Revision Date 17-Oct-2011
_____________________________________________________________________________________________
SARA 311/312 Hazardous Categorization
Chronic Health Hazard noAcute Health Hazard yesFire Hazard yesSudden Release of Pressure Hazard noReactive Hazard no
CERCLA
United States of America State Regulations
California Prop. 65This product contains the following Proposition 65 chemicals:
State Right-to-KnowOther international regulations
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the informationrequired by the CPR.
WHMIS ClassificationB3 Combustible liquidD2B Toxic materials
LegendNPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date 17-Oct-2011
Revision Note No information available
DisclaimerFor specific information regarding occupational safety and health standards, please refer to the Code of FederalRegulations, Title 29, Part 1910.To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or anyof its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhealth hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards which exist.
End of MSDS
_____________________________________________________________________________________________
Page 5 / 5
Health 2
F041-0073 - THINNER CLEAR
Flammability 2 Reactivity 1
Revision Date 17-Oct-2011
HMIS (Hazardous MaterialInformation System)