MATERIAL SAFETY DATA SHEETS SP2R CX and SE Spiker …

MATERIAL SAFETY DATA SHEETS

SP2R, CX and SE Spiker Machines

MANUFACTURER PRODUCT

Henkel .............................................................................................. Loctite Blue 242

Exxon Mobil ................................................................. Mobilux EP 2 Lithium Grease

Exxon Mobil ....................................................... Mobilube HD Plus 80W‐90 Gear Oil

Exxon Mobil .................................................................................. Fleet 15W‐40 Oil*

Valvoline ........................................................................ Premium Blue 15W‐40 Oil*

John Deere (RecoChem) ..................................... Cool Gard II Pre‐mix 50/50 Coolant

Petro Canada ....................................................... Hydrex XV All Season Hydraulic Oil

CRC Industries Inc. ......................................... SP‐400 Corrosion Inhibitor (Brush On)

CRC Industries Inc. ......................................... SP‐400 Corrosion Inhibitor (Spray On)

Dow Corning .............................................. Molykote G‐n Assembly Lubricant Paste

* Engine ships from Cummins with Valvoline Oil. Oil is topped off at Nordco with

Mobil Oil prior to shipment.

Disclaimer: The Material Safety Data Sheets apply to the machine “as‐shipped”.

Nordco is not responsible for the maintenance of these sheets once the machine

is in your possession. It is assumed that the types of lubricants will change as

needed.

Safety Data Sheet

Revision Number: 008.0 Issue date: 08/21/2014

IDH number: 209728 Product name: LOCTITE 242 MS TL known as LOC 6ML 242BLUE TLOCKER H 12PG Page 1 of 6

1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE 242 MS TL known as LOC

6ML 242BLUE TLOCKER H 12PG IDH number: 209728

Product type: Anaerobic Sealant Item number: 24200 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067

Telephone: +1 (800) 624-7767 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

WARNING: CAUSES SKIN AND EYE IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.

HAZARD CLASS HAZARD CATEGORY

SKIN IRRITATION 2

EYE IRRITATION 2B

SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work

clothing should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.

Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local

governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*

Polyglycol dimethacrylate Proprietary 60 - 100

Polyglycol oleate Proprietary 10 - 30

Saccharin 81-07-2 1 - 5


Silica, amorphous, fumed, crystal-free 112945-52-5 1 - 5

Cumene hydroperoxide 80-15-9 1 - 5

Propane-1,2-diol 57-55-6 1 - 5

Cumene 98-82-8 0.1 - 1

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove

contaminated clothing and footwear. Wash clothing before reuse. Get medical attention.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray.

Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in

explosions or rupture of storage containers.

Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.

6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to

prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.


7. HANDLING AND STORAGE

Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8.

Storage: For safe storage, store between 0 °C (32°F) and 32 °C (89.6 °F)

Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

Polyglycol dimethacrylate None None None None

Polyglycol oleate None None None None

Saccharin None None None None

Silica, amorphous, fumed, crystal-free

10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA

Respirable fraction.

20 MPPCF TWA 0.8 mg/m3 TWA

None None

Cumene hydroperoxide None None 1 ppm (6 mg/m3)

TWA (SKIN)

None

Propane-1,2-diol None None 10 mg/m3 TWA

Aerosol. None

Cumene 50 ppm TWA 50 ppm (245 mg/m3)

PEL (SKIN)

None None

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below

exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should

be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an

apron or body suit to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid Color: Blue Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 5 mm hg (27 °C (80.6 °F)) Boiling point/range: > 149 °C (> 300.2 °F) Melting point/ range: Not available. Specific gravity: 1.1 at 23.9 °C (75.02 °F) Vapor density: Not available. Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup Flame projection: Not applicable Flammable/Explosive limits - lower: 2.6 % (propylene glycol) Flammable/Explosive limits - upper: 12.5 % (propylene glycol)


Autoignition temperature: Not determined Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.56 %; 6.17 g/l Viscosity: Not available. Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials.

Hazardous decomposition products:

Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.

Incompatible materials: Strong oxidizing agents. Free radical initiators. Strong reducing agents. Alkalis. Oxygen

scavengers. Other polymerization initiators. Copper. Iron. Zinc. Aluminum. Rust.

Reactivity: Not available.

Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes eye irritation. Ingestion: May cause gastrointestinal tract irritation if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects

Polyglycol dimethacrylate None Allergen, Irritant Polyglycol oleate None Irritant Saccharin None No Target Organs Silica, amorphous, fumed, crystal-free None Nuisance dust

Cumene hydroperoxide None Allergen, Central nervous system, Corrosive,

Irritant, Mutagen

Propane-1,2-diol Oral LD50 (RABBIT) = 18 g/kg

Oral LD50 (RAT) = 30 g/kg Irritant

Cumene Oral LD50 (RAT) = 2.91 g/kg

Oral LD50 (RAT) = 1,400 mg/kg Inhalation LC50 (RAT, 4 h) = 8000 ppm

Central nervous system, Irritant, Lung

Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen

(Specifically Regulated)

Polyglycol dimethacrylate No No No

Polyglycol oleate No No No

Saccharin No No No

Silica, amorphous, fumed, crystal-free No No No

Cumene hydroperoxide No No No

Propane-1,2-diol No No No

Cumene No Group 2B No


12. ECOLOGICAL INFORMATION

Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

International Air Transportation (ICAO/IATA)


Water Transportation (IMO/IMDG)


15. REGULATORY INFORMATION United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of

section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Saccharin (CAS# 81-07-2). Cumene hydroperoxide (CAS# 80-15-9).

CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.


Prepared by: Sheila Gines, Regulatory Affairs Specialist

Issue date: 08/21/2014

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

Product Name: MOBILUX EP 2 Revision Date: 16 Mar 2015 Page 1 of 10 ______________________________________________________________________________________________________________________

SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT

Product Name: MOBILUX EP 2 Product Description: Base Oil and Additives Product Code: 2015A0208050, 641274-00, 970717 Intended Use: Grease

COMPANY IDENTIFICATION

Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX. 77389 USA

24 Hour Health Emergency 609-737-4411 Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC Product Technical Information 800-662-4525 MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS

No significant hazards. HEALTH HAZARDS

High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation.

ENVIRONMENTAL HAZARDS

No significant hazards.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.


SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes PHOSPHORIC ACID ESTERS, AMINE SALT 61188-14-5 0.1 - < 1% H318, H401, H411 ZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5% H315, H318, H401,

H411

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph (i). SECTION 4 FIRST AID MEASURES INHALATION

Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT

Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

EYE CONTACT

Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION

First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA

Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to


protect personnel. Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulfur oxides, Incomplete combustion products

FLAMMABILITY PROPERTIES

Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802.

PROTECTIVE MEASURES

Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Allow spilled material to solidify and scrape up with shovels into a suitable container for recycle or disposal. Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS

Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE


HANDLING

Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.

STORAGE

Do not store in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:

No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:

No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or


manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.

ENVIRONMENTAL CONTROLS

Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION

Physical State: Solid Form: Semi-fluid Color: Brown Odor: Characteristic Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 °C): 0.92 Flammability (Solid, Gas): Flash Point [Method]: >204°C (400°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = 1): N/D Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 150 cSt (150 mm2/sec) at 40 °C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material.


SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material.

Minimally Toxic. Based on assessment of the components.

Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material.


Skin Acute Toxicity: No end point data for material.


Skin Corrosion/Irritation: No end point data for material.

Negligible irritation to skin at ambient temperatures. Based on assessment of the components.

Eye Serious Eye Damage/Irritation: No end point data for material.

May cause mild, short-lasting discomfort to eyes. Based on assessment of the components.

Sensitization Respiratory Sensitization: No end point data for material.

Not expected to be a respiratory sensitizer.

Skin Sensitization: No end point data for material.

Not expected to be a skin sensitizer. Based on assessment of the components.

Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material.

Germ Cell Mutagenicity: No end point data for material.

Not expected to be a germ cell mutagen. Based on assessment of the components.

Carcinogenicity: No end point data for material.

Not expected to cause cancer. Based on assessment of the components.

Reproductive Toxicity: No end point data for material.

Not expected to be a reproductive toxicant. Based on assessment of the components.

Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material.

Not expected to cause organ damage from a single exposure.

Repeated Exposure: No end point data for material.

Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components.


OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land.

Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may

reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.


DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport

LAND (TDG): Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

Marine Pollutant: No

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.


SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5% The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 18 ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19

--REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):

H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- Internal Use Only


MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2009877XUS (539035) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Exxon Mobil Corporation, All rights reserved

Product Name: MOBILUBE HD LS 80W-90 Revision Date: 16 Mar 2015 Page 1 of 10 ______________________________________________________________________________________________________________________


Product Name: MOBILUBE HD LS 80W-90 Product Description: Base Oil and Additives Product Code: 20152050D010, 510438-00, 977636 Intended Use: Gear oil











SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes OLEFIN SULFIDE 68937-96-2 1 - < 5% H227, H317, H413 PHOSPHORIC ACID ESTERS, AMINE SALT

CONFIDENTIAL

1 - 2.5% H226, H302, H317, H318, H401, H411


Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT


EYE CONTACT






FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides


Flash Point [Method]: 230°C (446°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D



PROTECTIVE MEASURES


SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.



Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE HANDLING

Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator.

STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS





No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.




SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION

Physical State: Liquid Color: Brown Odor: Characteristic Odor Threshold: N/D


Relative Density (at 15.6 °C): 0.898 Flammability (Solid, Gas): N/A Flash Point [Method]: 230°C (446°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Decomposition Temperature: N/D Vapor Density (Air = 1): > 2 at 101 kPa [Estimated] Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated]


Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 141 cSt (141 mm2/sec) at 40 °C | 14.5 cSt (14.5 mm2/sec) at 100 Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material.














Aspiration: Data available. Not expected to be an aspiration hazard. Based on


physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material.










OTHER INFORMATION For the product itself: Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract. Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components or similar formulations. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. The following ingredients are cited on the lists below: None.


Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable


BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may


SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants.








SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, ENCS, KECI, PICCS, TSCA EPCRA SECTION 302: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: None.


H226: Flammable liquid and vapor; Flammable Liquid, Cat 3 H227: Combustible liquid; Flammable Liquid, Cat 4 H302: Harmful if swallowed; Acute Tox Oral, Cat 4 H317: May cause allergic skin reaction; Skin Sensitization, Cat 1 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H413: May cause long lasting harmful effects to aquatic life; Chronic Env Tox, Cat 4 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:


Updates made in accordance with implementation of GHS requirements. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- Internal Use Only


Product Name: MOBIL FLEET 15W-40 Revision Date: 16 Mar 2015 Page 1 of 11 ______________________________________________________________________________________________________________________


Product Name: MOBIL FLEET 15W-40 Product Description: Base Oil and Additives Product Code: 201520105010, 444620-00, 97AX14 Intended Use: Engine oil











SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes ORGANO MOLY-SULFUR COMPLEX 0.1 - < 1% H315, H317, H402,

H412 SOLVENT DEWAXED HEAVY PARAFFINIC DISTILLATE 64742-65-0 5 - < 10% H304 TETRAPROPENYL PHENOL 121158-58-5 0.1 - < 1% H315, H319(2A),

H360(1B)(F), H400(M factor 10), H410(M factor 10)

ZINC ALKYL DITHIOPHOSPHATE 113706-15-3 1 - < 2.5% H303, H315, H318, H401, H411


Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT


EYE CONTACT






FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Sulfur oxides, Oxides of carbon, Incomplete combustion products, Smoke, Fume


Flash Point [Method]: >200°C (392°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D



PROTECTIVE MEASURES


SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material;


however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.


Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE HANDLING

Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator.

STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit / Standard NOTE Source ORGANO MOLY-SULFUR COMPLEX Inhalable

fraction. TWA 10 mg/m3 N/A ACGIH

ORGANO MOLY-SULFUR COMPLEX Respirable fraction.

TWA 3 mg/m3 N/A ACGIH

SOLVENT DEWAXED HEAVY PARAFFINIC DISTILLATE

Mist. TWA 5 mg/m3 N/A OSHA Z1


TWA 2000 mg/m3

500 ppm N/A OSHA Z1


Mist. TWA 5 mg/m3 N/A ACGIH

Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated.


ENGINEERING CONTROLS




No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.




SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only


and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION

Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D


Relative Density (at 15 °C): 0.88 Flammability (Solid, Gas): N/A Flash Point [Method]: >200°C (392°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = 1): > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 109 cSt (109 mm2/sec) at 40 °C | 14.5 cSt (14.5 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A Pour Point: -30°C (-22°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation


Acute Toxicity: No end point data for material.














Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material.

Germ Cell Mutagenicity: No end point data for material.










OTHER INFORMATION For the product itself: Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Tetrapropenyl phenol (TPP). TPP was tested in a rat oral gavage one-generation reproductive toxicity study and a rat dietary two-generation reproductive toxicity study. Results from the one-generation study included reduced ovary weights and changes in male reproductive accessory organs. Results from the two-generation study included prolonged estrous cyclicity, reduced ovary weights, accelerated sexual maturation, decreased mean live litter size, decreased fertility rates, hypospermia, and reduced weights of male reproductive accessory organs. A Specific Concentration Limit (SCL) for reproductive effects of 1.5 wt% TPP was derived by the supplier based on the NOAEL


(15 mg/kg/day) from the rat dietary two-generation study and was confirmed in supporting studies with other substances containing TPP as an impurity. The following ingredients are cited on the lists below: None.


Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may


NOTE: One or more components of this material contain an impurity (branched alkylphenol) that is highly toxic to aquatic organisms. The components containing the impurity were tested by the supplier and found to be no more than minimally toxic to aquatic organisms. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the


environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants.







SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: DSL, KECI, TSCA Special Cases:

Inventory Status AICS Restrictions Apply IECSC Restrictions Apply

EPCRA SECTION 302: This material contains no extremely hazardous substances.


SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: Chemical Name CAS Number Typical Value ZINC ALKYL DITHIOPHOSPHATE

113706-15-3 1 - < 2.5%

The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations DIPHENYLAMINE 122-39-4 18 ZINC ALKYL DITHIOPHOSPHATE

113706-15-3 13, 15, 17, 19


H303: May be harmful if swallowed; Acute Tox Oral, Cat 5 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H317: May cause allergic skin reaction; Skin Sensitization, Cat 1 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H319(2A): Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2A H360(1B)(F): May damage fertility; Repro Tox, Cat 1B (Fertility) H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H402: Harmful to aquatic life; Acute Env Tox, Cat 3 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements. -----------------------------------------------------------------------------------------------------------------------------------------------------


The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- Internal Use Only


Page: 1

SAFETY DATA SHEET Revision Date: 05/22/2015

Print Date: 7/1/2015

SDS Number: 000000040441

Premium Blue™ CLASSIC SAE 15W-40 CI-4PLUS DIESEL ENGINE OIL 591838

Version: 1.0

1 / 12

29 CFR 1910.1200 (OSHA HazCom 2012)

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product identifier Trade name : Premium Blue™ CLASSIC SAE 15W-40 CI-4PLUS

DIESEL ENGINE OIL

Recommended use of the chemical and restrictions on use

Details of the supplier of the safety data sheet Ashland P.O. Box 2219 Columbus, OH 43216 United States of America EHS Customer [email protected]

Emergency telephone number 1-800-ASHLAND (1-800-274-5263) Regulatory Information Number 1-800-325-3751 Product Information 614-790-3333

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012).

GHS Label element

This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012).

Other hazards

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

: Mixture

Chemical nature

: Defatter

Hazardous components

Chemical Name CAS-No. Classification Concentration (%)

HYDROTREATED LIGHT PARAFFINIC DISTILLATE

64742-55-8 Asp. Tox. 1; H304

1.65

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ZINC COMPOUNDS 68649-42-3 Skin Irrit. 2; H315

1.58

SECTION 4. FIRST AID MEASURES

General advice

: No hazards which require special first aid measures.

If inhaled

: If breathed in, move person into fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.

In case of skin contact

: Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use.

In case of eye contact

: Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist.

If swallowed

: Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

Most important symptoms and effects, both acute and delayed

: Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways)

Notes to physician

: No hazards which require special first aid measures.

Page: 3



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SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media

: High volume water jet

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products

: carbon dioxide and carbon monoxide Hydrocarbons hydrogen sulfide zinc oxide oxides of sulfur, nitrogen and phosphorus Amines

Specific extinguishing methods

:

Product is compatible with standard fire-fighting agents.

Further information : Standard procedure for chemical fires.

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed.

Environmental precautions

: Prevent further leakage or spillage if safe to do so.

Methods and materials for containment and cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

Other information

: Comply with all applicable federal, state, and local regulations.

SECTION 7. HANDLING AND STORAGE

Page: 4



SDS Number: 000000040441


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Advice on safe handling

: Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations.

Conditions for safe storage

: Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis


64742-55-8 REL 5 mg/m3 Mist.

NIOSH/GUIDE

STEL 10 mg/m3 Mist.

NIOSH/GUIDE

PEL 5 mg/m3 Mist.

OSHA_TRANS

Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects.

Personal protective equipment

Hand protection Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves.

Eye protection : Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes.

Skin and body protection : Wear as appropriate: impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear resistant gloves (consult your safety equipment supplier).

Hygiene measures : Wash hands before breaks and at the end of workday.

Page: 5



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When using do not eat or drink. When using do not smoke.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state

: liquid

Odour

: No data available

Odour Threshold

: No data available

pH

: No data available

: No data available

: No data available

Flash point

: > 390 °F / > 199 °C Method: Cleveland open cup

Evaporation rate

: No data available

Flammability (solid, gas)

: No data available

Upper explosion limit

: No data available

Lower explosion limit

: No data available

Vapour pressure

: 0.0133333 hPa (21.11 °C) Calculated Vapor Pressure

Relative vapour density

: No data available

Relative density

: 0.879 (15.6 °C)

Density

: 0.879 g/cm3 (15.6 °C)

Solubility(ies) Water solubility

: No data available

Solubility in other solvents

: No data available

Partition coefficient: n-octanol/water

: No data available

Thermal decomposition

: No data available

Viscosity Viscosity, dynamic

: No data available

Page: 6



SDS Number: 000000040441


Version: 1.0

6 / 12

Viscosity, kinematic

: No data available

Oxidizing properties

: No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

: No decomposition if stored and applied as directed.

Chemical stability

: Stable under recommended storage conditions.

Possibility of hazardous reactions

: Product will not undergo hazardous polymerization.

Conditions to avoid

: excessive heat

Incompatible materials

: Strong acids Strong oxidizing agents

Hazardous decomposition products

carbon dioxide and carbon monoxide Hydrocarbons

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation Skin contact Eye Contact Ingestion

Acute toxicity Not classified based on available information. Components: ZINC COMPOUNDS: Acute oral toxicity

: LD 50 (Rat): > 2,000 - 5,000 mg/kg

Acute dermal toxicity

: LD 50 (Rabbit): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS.

Skin corrosion/irritation Not classified based on available information. Product: Result: Repeated exposure may cause skin dryness or cracking. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Mildly irritating to skin

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ZINC COMPOUNDS: Result: Severely irritating to skin Serious eye damage/eye irritation Not classified based on available information. Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Mildly irritating to eyes ZINC COMPOUNDS: Result: Possibly irritating to eyes Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: May be fatal if swallowed and enters airways. Further information Product: Remarks: No data available Carcinogenicity: IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

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SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

ZINC COMPOUNDS: Ecotoxicology Assessment Acute aquatic toxicity

: Toxic to aquatic life.

Chronic aquatic toxicity

: Toxic to aquatic life with long lasting effects.

Persistence and degradability No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

Product:

Additional ecological information

: No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Dispose of in accordance with all applicable local, state and federal regulations.

Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International transport regulations

REGULATION

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SDS Number: 000000040441


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ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS

SUBSIDIARY HAZARDS

PACKING GROUP

MARINE POLLUTANT / LTD. QTY.

U.S. DOT - ROAD

Not dangerous goods

U.S. DOT - RAIL

Not dangerous goods

U.S. DOT - INLAND WATERWAYS

Not dangerous goods

TRANSPORT CANADA - ROAD

Not dangerous goods

TRANSPORT CANADA - RAIL

Not dangerous goods

TRANSPORT CANADA - INLAND WATERWAYS

Not dangerous goods

INTERNATIONAL MARITIME DANGEROUS GOODS

Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO

Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER

Not dangerous goods

MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES

Not dangerous goods

*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Marine pollutant no

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Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards

: No SARA Hazards

SARA 313 Component(s) ZINC C1 - C14

ALKYLDITHIOPHOSPHATE

68649-42-3 1.58 %

Pennsylvania Right To Know

HEAVY PARAFFINIC DISTILLATE

64742-54-7 70.00 - 90.00 %

HIGHLY REFINED MINERAL OIL (C15-C50)

Not Assigned 5.00 - 10.00 %

LUBRICANT ADDITIVE



64742-55-8 1.00 - 5.00 %

New Jersey Right To Know

HEAVY PARAFFINIC DISTILLATE

64742-54-7 70.00 - 90.00 %

HIGHLY REFINED MINERAL OIL (C15-C50)


LUBRICANT ADDITIVE



64742-55-8 1.00 - 5.00 %

CONTENTS PARTIALLY UNKNOWN


ZINC COMPOUNDS

68649-42-3 1.00 - 5.00 %

California Prop 65 Proposition 65 warnings are not required for this product

based on the results of a risk assessment. The components of this product are reported in the following inventories: TSCA

: On TSCA Inventory

DSL

: All components of this product are on the Canadian DSL.

AUSTR

: Not in compliance with the inventory

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NZIOC


ENCS


KECL

: On the inventory, or in compliance with the inventory

PICCS

: On the inventory, or in compliance with the inventory

IECSC


Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information Revision Date: 05/22/2015

NFPA: HMIS III:

NFPA Flammable and Combustible Liquids Classification

Combustible Liquid Class IIIB Full text of H-Statements referred to under sections 2 and 3. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation.

Sources of key data used to compile the Safety Data Sheet Ashland internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport.

Flammability

Health

Insta

bility

1

1

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

0

1

Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

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The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System

Page 1 of 3 ISSUE: 3 ISSUE DATE: 24/06/2011

MATERIAL SAFETY DATA SHEET SECTION 1 IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name: JOHN DEERE COOL GARD II LONG LIFE ANTIFREEZE/ANTIBOIL COOLANT 50%

PREMIX Company: Recochem Engine Coolants (Tianjin) Co., Ltd Address: No.5 Factory Building, Chuang Ye Road South, Hai Fang Road, Standard Factory Park, Nan Gang Industrial Area, Bin Hai New Area, Tianjin, China Phone: 86-022-63116148 Fax: 86-022-63117175 Other Names: Glycol Coolant, Antifreeze Manufacturer’s Product Code: 19785 Recommended Use: Radiator Antifreeze, Coolant

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFIED AS HAZARDOUS ACCORDING TO CRITERIA OF WORKSAFE AUSTRALIA NOT A DANGEROUS GOODS ACCORDING TO THE CRITERIA OF THE ADG CODE Symbol: Xn - Harmful Risk Phrases: R22 - Harmful if swallowed Safety Phrases: S2 - Keep out of the reach of children

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Ingredients Chemical Entity CAS Number Proportion (%) Ethylene Glycol 107-21-1 45 - 55

SECTION 4 FIRST AID MEASURES

FIRST AID TREATMENT Swallowed: If swallowed, do NOT induce vomiting. Have conscious person drink several glasses of water or milk. SEEK

IMMEDIATE MEDICAL ATTENTION. Eye: If in eyes, hold eyes open, flood with water for at least 15 minutes. If irritation persists seek medical attention. Skin: If skin contact occurs, wash skin thoroughly with water and follow by washing with soap if available. If irritation

persists, seek medical attention. Inhaled: Remove victim from exposure if safe to do so. If rapid recovery does not occur, transport to nearest medical

facility for additional treatment. First Aid facilities: Potable water should be available to rinse eyes or skin. Provide eye baths and safety showers. Advice to Doctor: Treat symptomatically. Additional Information: None available.

SECTION 5 FIRE FIGHTING MEASURES

Suitable Extinguishing Media: For a small fire use dry chemicals, carbon dioxide, water spray or foam. For large fires use water spray or fog. Do not use water jet.

Hazards from combustion products: Carbon dioxide and carbon monoxide. Precautions for Fire Fighters and Special Protective Equipment: Wear full protective clothing and self-contained breathing

apparatus. Additional Information: When heated to decomposition, emits acrid smoke and irritating fumes. Not a product presenting

risks of explosion.

Product: JOHN DEERE COOL GARD II LONG LIFE ANTIFREEZE/ANTIBOIL COOLANT 50% PREMIX


SECTION 6 ACCIDENTAL RELEASE MEASURES

Observe all local and national regulations. Spills and Disposal, Methods and Materials for Containment and Clean Up Procedures: For small spills, dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. For large spills, absorb with an inert material and put the spilled material in an appropriate waste disposal container. Dispose of in accordance with regional regulations.

SECTION 7 HANDLING AND STORAGE

Precautions for Safe Handling and Storage: Avoid contact with eyes, skin and clothing. DO NOT ingest. Avoid breathing vapour and mist, keep container closed. Keep container in a cool, well-ventilated area, away from strong oxidisers, and use only with adequate ventilation. Avoid all possible sources of ignition. Wash thoroughly after handling. Before eating, drinking or smoking, remove contaminated clothing. Do not eat, drink or smoke in contaminated areas.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Standards: National Occupational Health & Safety Commission (NOHSC) Worksafe Australia has set an exposure standard of 52mg/m3 (20ppm) TWA (vapour), 104mg/m3 (40ppm) STEL (vapour) and 10mg/m3 TWA (particulate). Biological Limit Values: No biological limit allocated. Personal Protective Equipment: Respiratory Protection: Wear appropriate respirator when ventilation is inadequate. Hand Protection: Use solvent resistant gloves (nitrile, PVC or neoprene). Eye Protection: Wear safety goggles. Protective Clothing: No special protection is ordinarily required beyond standard issue work clothes. Engineering Controls: Ensure that adequate ventilation is provided. Maintain air concentrations below recommended exposure standards. Avoid generating and inhaling mists.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL DESCRIPTION / CHEMICAL PROPERTIES Appearance Orange viscous liquid Odour None pH: 7.5 to 8.5 (1% in water) Vapour Pressure (mmHg @ 20°C): 0.06 Vapour Density (air = 1) 2.1 Boiling Point (°C): 107 - 8 Freezing/Melting Point (°C): -37 Solubility in Water Soluble in water, methanol, diethyl ether Specific Gravity (g/ml @ 15°C): 1.07 - 1.08 Flashpoint (°C): N/A Flammability Limits (%): N/A Auto Ignition Temperature (°C): N/A Percent Volatiles 0

SECTION 10 STABILITY AND REACTIVITY

Chemical Stability: Stable under normal conditions of use. Conditions to Avoid: No additional remark. Incompatible Materials: Strong oxidising agents, acids, alkalis. Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide.

SECTION 11 TOXICOLOGICAL INFORMATION

HEALTH EFFECTS Acute: Swallowed: Hazardous in case of ingestion (approx. 100ml can be fatal). Eye: Contact may cause eye irritation. Skin: Irritant – prolonged contact may cause dermatitis.

Product: JOHN DEERE COOL GARD II LONG LIFE ANTIFREEZE/ANTIBOIL COOLANT 50% PREMIX


Inhaled: Inhalation should be minimal since vapours are unlikely due to physical properties. Inhalation may cause irritation to lung.

Chronic: Toxic to kidneys and liver. Toxicity to Animals:

Acute oral toxicity (LD50): 4700mg/kg (Rat). Acute dermal toxicity (LD50): 9530 mg/kg (Rabbit).

SECTION 12 ECOLOGICAL INFORMATION

Ecotoxicity: Fish : Low toxicity: LC/EC/IC50 > 100mg/l

Aquatic Invertebrates : Low toxicity: LC/EC/IC50 > 100mg/l Algae : Low toxicity: LC/EC/IC50 > 100mg/l

Microorganisms : Low toxicity: LC/EC/IC50 > 100mg/l Mobility: Miscible with water. Persistance/degradability: Biodegradable.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal Methods: Ensure waste disposal conforms to local waste disposal regulations.

SECTION 14 TRANSPORT INFORMATION

UN Number: Non Regulated Proper Shipping Name: N/A Class: N/A Subsidiary Risk: N/A Packing Group: N/A Hazchem Code: N/A Special Precautions for User:

None

SECTION 15 REGULATORY INFORMATION

Poisons Schedule : 5 AICS : Listed Dangerous Goods Initial Emergency Response Guide (SAA/SNZ HB76:2010) : N/A

SECTION 16 OTHER INFORMATION

Further Information may be obtained by contacting Recochem on (07) 3308 5200 The information sourced for the preparation of this document was correct and complete at the time or writing to the best of the writer’s knowledge. The document represents the commitment to the company’s responsibilities surrounding the supply of this product, undertaken in good faith. This document should be taken as a safety guide for the product and its recommended uses but is in no way an absolute authority. Please consult the relevant legislation and regulations governing the use and storage of this type of product.

Material Safety Data Sheet

HYDREX TM XV ALL SEASON

000003001240

Version 2.0 Revision Date 2015/02/06 Print Date 2015/02/06

Internet: lubricants.petro-canada.ca/msds Page: 1 / 8 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : HYDREX TM

XV ALL SEASON Product code : HDXASP5R, HDXASP20, HDXASIBC, HDXASDRR,

HDXASDRM, HDXASDCT, HDXASC16, HDXAS, HDXASBLK

Manufacturer or supplier's details Petro-Canada Lubricants Inc. 2310 Lakeshore Road West

Mississauga ON L5J 1K2 Canada Emergency telephone number

Suncor Energy: +1 403-296-3000; Poison Control Centre: Consult local telephone directory for emergency number(s).

Recommended use of the chemical and restrictions on use

Recommended use : Hydrex XV All Season hydraulic oil is a premium hydraulic oil designed for year round use in hydraulic systems that are exposed to wide temperature extremes. It is specifically recommended for woodland, mining, construction, public utility and marine operations eliminating the need for seasonal changeovers.

Prepared by : Product Safety: +1 905-804-4752

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance

viscous liquid

Colour

Bright, pale yellow.

Odour

Mild petroleum oil like.

Potential Health Effects

Primary Routes of Entry

: Eye contact Ingestion Inhalation Skin contact

Aggravated Medical Condition

: None known.

Carcinogenicity:

IARC No component of this product present at levels greater than or



000003001240



equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

: Mixture

Hazardous components

No hazardous ingredients

SECTION 4. FIRST AID MEASURES

If inhaled

: Artificial respiration and/or oxygen may be necessary. Move to fresh air. Seek medical advice.

In case of skin contact

: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice.

In case of eye contact

: Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.

If swallowed

: Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice.

Most important symptoms and effects, both acute and delayed

: First aider needs to protect himself.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.



000003001240



Unsuitable extinguishing media

: No information available.

Specific hazards during firefighting

: Cool closed containers exposed to fire with water spray.

Hazardous combustion products

: Carbon oxides (CO, CO2), sulphur oxides (SOx), phosphorus oxides (POx), calcium oxides (CaOx), zinc oxides (ZnOx), smoke and irritating vapours as products of incomplete combustion.

Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions.

Environmental precautions

: Do not allow uncontrolled discharge of product into the environment.

Methods and materials for containment and cleaning up

: Prevent further leakage or spillage if safe to do so. Remove all sources of ignition. Soak up with inert absorbent material. Non-sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling

: For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Use only with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Do not ingest. Keep away from heat and sources of ignition. Keep container closed when not in use.

Conditions for safe storage

: Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sunlight.



000003001240



SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Personal protective equipment

Respiratory protection

: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Filter type

: organic vapour filter

Hand protection Material : neoprene, nitrile, polyvinyl alcohol (PVA), Viton(R). Remarks

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Eye protection

: Wear face-shield and protective suit for abnormal processing problems.

Skin and body protection

: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.

Protective measures

: Wash contaminated clothing before re-use. No special protective equipment required.

Hygiene measures

: Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash face, hands and any exposed skin thoroughly after handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : viscous liquid

Colour : Bright, pale yellow.

Odour : Mild petroleum oil like.

Odour Threshold : No data available

pH : No data available

Pour point : -48 °C (-54 °F)



000003001240



Boiling point/boiling range : No data available

Flash point : 245 °C (473 °F) Method: Cleveland open cup

Fire Point : No data available

Auto-Ignition Temperature : No data available

Evaporation rate : No data available

Flammability : Low fire hazard. This material must be heated before ignition will occur.

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : No data available

Relative vapour density : No data available

Density : 0.8482 kg/l (15 °C / 59 °F)

Solubility(ies)

Water solubility : insoluble

Partition coefficient: n-octanol/water

: No data available

Viscosity

Viscosity, kinematic : 43.2 cSt (40 °C / 104 °F)

10.54 cSt (100 °C / 212 °F)

Explosive properties : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

SECTION 10. STABILITY AND REACTIVITY

Possibility of hazardous reactions

: Hazardous polymerisation does not occur. Stable under normal conditions.

Conditions to avoid

: No data available

Incompatible materials

: Reactive with oxidising agents and acids.

Hazardous decomposition products

: May release COx, H2S, aldehydes, methacrylate monomers, alkyl mercaptans, sulfides, smoke and irritating vapours when heated to decomposition.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Eye contact



000003001240



exposure Ingestion Inhalation Skin contact

Acute toxicity

Product:

Acute oral toxicity

: Remarks: No data available

Acute inhalation toxicity


Acute dermal toxicity


Skin corrosion/irritation

Product:

Remarks: No data available

Serious eye damage/eye irritation

Product:

Remarks: No data available

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Toxicity to fish : Remarks: No data available



000003001240



Toxicity to daphnia and other aquatic invertebrates


Toxicity to algae


Toxicity to bacteria


Persistence and degradability

Product:

Biodegradability


Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non-recyclable solutions to a licensed disposal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation

IATA-DGR

Not regulated as a dangerous good

IMDG-Code

Not regulated as a dangerous good

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

49 CFR Not regulated as a dangerous good TDG Not regulated as a dangerous good



000003001240



Special precautions for user

Not applicable

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : Not Rated

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.

The components of this product are reported in the following inventories: DSL On the inventory, or in compliance with the inventory TSCA All chemical substances in this product are either listed on the

TSCA Inventory or are in compliance with a TSCA Inventory exemption.

IECSC On the inventory, or in compliance with the inventory EINECS On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

SAFETY DATA SHEET

1. Identification

Product identifier SP-400™ Corrosion Inhibitor

Other means of identification

Product code 03286, 03288

Recommended use Long term corrosion inhibitor

Recommended restrictions None known.

Manufacturer/Importer/Supplier/Distributor information

Manufactured or sold by:

Company name CRC Industries, Inc.

Address 885 Louis Dr.

Warminster, PA 18974 US

Telephone

General Information 215-674-4300

Technical

Assistance

800-521-3168

Customer Service 800-272-4620

24-Hour Emergency 800-424-9300 (US)

(CHEMTREC) 703-527-3887 (International)

Website www.crcindustries.com

2. Hazard(s) identification

Category 3Flammable liquidsPhysical hazards

Category 2Skin corrosion/irritationHealth hazards

Category 2Serious eye damage/eye irritation

Category 3 narcotic effectsSpecific target organ toxicity, single exposure

Category 2Specific target organ toxicity, repeatedexposure

Category 1Aspiration hazard

Category 2Hazardous to the aquatic environment, acutehazard

Environmental hazards

Not classified.OSHA defined hazards

Label elements

Signal word Danger

Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.Causes serious eye irritation. May cause drowsiness or dizziness. May cause damage to organs(skin, eyes, central nervous system, respiratory system) through prolonged or repeated exposure.Toxic to aquatic life.

Precautionary statement

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightlyclosed. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge. Use with adequate ventilation. Open doors and windows oruse other means to ensure a fresh air supply during use and while product is drying. If youexperience any symptoms listed on this label, increase ventilation or leave the area. Do notbreathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/eyeprotection/face protection. Avoid release to the environment.

1 / 9

Material name: SP-400™ Corrosion Inhibitor

03286, 03288 Version #: 02 Revision date: 12-01-2014 Issue date: 11-13-2014

SDS US

Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If skin irritationoccurs: Get medical attention. If on skin (or hair): Take off immediately all contaminated clothing.Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable forbreathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water forseveral minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical attention. Wash contaminated clothing before reuse. In case of fire:Do not use water jet as an extinguisher, as this will spread the fire.

Storage Store in a well-ventilated place. Keep cool. Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national regulations.

Hazard(s) not otherwise

classified (HNOC)None known.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

8052-41-3Stoddard Solvent 40 - 50

64742-47-8Distillates (petroleum), hydrotreatedlight

10 - 20

8009-03-8Petrolatum, Micro Soft Wax < 0.3

Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.

Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritationoccurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Most important

symptoms/effects, acute and

delayed

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may causepulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolongedexposure may cause chronic effects.

Indication of immediate

medical attention and special

treatment needed

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. Keep victim under observation.Symptoms may be delayed.

General information Take off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore reuse.

5. Fire-fighting measures

Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from

the chemical

Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a sourceof ignition and flash back. During fire, gases hazardous to health may be formed.

Special protective equipment

and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire-fighting

equipment/instructionsIn case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.

General fire hazards Flammable liquid and vapor.

2 / 9



SDS US

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor.Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Methods and materials for

containment and cleaning up

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Use a non-combustible material likevermiculite, sand or earth to soak up the product and place into a container for later disposal.Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.Prevent entry into waterways, sewer, basements or confined areas.

Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoiddischarge into drains, water courses or onto the ground. Inform appropriate managerial orsupervisory personnel of all environmental releases.

7. Handling and storage

Precautions for safe handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protectmaterial from direct sunlight. When using do not smoke. Explosion-proof general and local exhaustventilation. Take precautionary measures against static discharges. All equipment used whenhandling the product must be grounded. Use non-sparking tools and explosion-proof equipment.Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Wear appropriatepersonal protective equipment. Wash hands thoroughly after handling. Avoid release to theenvironment. Observe good industrial hygiene practices. Use care in handling/storage. For productusage instructions, please see the product label.

Conditions for safe storage,

including any incompatibilities

Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by usingcommon bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Storein original tightly closed container. Store in a well-ventilated place. Keep in an area equipped withsprinklers. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents FormType

PEL 5 mg/m3 Mist.Petrolatum, Micro Soft Wax(CAS 8009-03-8)

PEL 2900 mg/m3Stoddard Solvent (CAS8052-41-3)

500 ppm

US. ACGIH Threshold Limit Values


TWA 5 mg/m3 Inhalable fraction.Petrolatum, Micro Soft Wax(CAS 8009-03-8)

TWA 100 ppmStoddard Solvent (CAS8052-41-3)

US. NIOSH: Pocket Guide to Chemical Hazards


TWA 100 mg/m3Distillates (petroleum),hydrotreated light (CAS64742-47-8)

STEL 10 mg/m3 Mist.Petrolatum, Micro Soft Wax(CAS 8009-03-8)

TWA 5 mg/m3 Mist.

3 / 9



SDS US



Ceiling 1800 mg/m3Stoddard Solvent (CAS8052-41-3)

TWA 350 mg/m3

Biological limit values No biological exposure limits noted for the ingredient(s).

Appropriate engineering

controls

Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this product.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection

Hand protection Wear protective gloves such as: Nitrile. Neoprene.

Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.

Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use aNIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-containedbreathing apparatus in confined spaces and for emergencies. Air monitoring is needed todetermine actual employee exposure levels.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Liquid.

Form Liquid.

Color Dark amber.

Odor Petroleum.

Odor threshold Not available.

pH Not available.

Melting point/freezing point -94 °F (-70 °C) estimated

Initial boiling point and boiling

range

302 °F (150 °C) estimated

Flash point 119 °F (48.3 °C) Tag Closed Cup

Evaporation rate Slow.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

0.7 % estimated

Flammability limit - upper

(%)

6 % estimated

Vapor pressure 1.9 hPa estimated

Vapor density > 1 (air = 1)

Relative density 0.87

Solubility (water) Insoluble.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature 410 °F (210 °C) estimated

Decomposition temperature Not available.

Viscosity (kinematic) Not available.

4 / 9



SDS US

Percent volatile 50.2 % estimated

10. Stability and reactivity

Reactivity Not available.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid Avoid temperatures exceeding the flash point. Heat, flames and sparks. Contact with incompatiblematerials.

Incompatible materials Strong oxidizing agents. Acids. Fluorine.

Hazardous decomposition

products

Carbon oxides. Aldehydes.

11. Toxicological information


Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May causedrowsiness and dizziness. Headache. Nausea, vomiting.

Skin contact Causes skin irritation.

Eye contact Causes serious eye irritation.

Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat.Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause rednessand pain.

Information on toxicological effects

Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects.

Test ResultsProduct Species

SP-400™ Corrosion Inhibitor

LD50 Rabbit

Dermal

Acute

2797.2341 mg/kg estimated

LC50 Rat

Inhalation

12.0898 mg/l estimated

LD50 Rat

Oral


* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Causes skin irritation.

Serious eye damage/eye

irritation

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Stoddard Solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.

Reproductive toxicity This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity -

single exposure

May cause drowsiness and dizziness.


repeated exposure

May cause damage to organs through prolonged or repeated exposure: Skin. Eyes. Centralnervous system. Respiratory system.

Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,may cause chemical pneumonia, pulmonary injury or death.

5 / 9



SDS US

Chronic effects Prolonged exposure may cause chronic effects. May cause damage to organs through prolongedor repeated exposure.

12. Ecological information

Ecotoxicity Toxic to aquatic life.

Product Test ResultsSpecies


Aquatic

Acute

LC50Fish 2207 mg/l, 96 hours estimatedFish

Components Test ResultsSpecies


Distillates (petroleum), hydrotreated light (CAS 64742-47-8)

Aquatic

Acute

LC50Fish 45 mg/l, 96 hoursFathead minnow (Pimephales promelas)

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow)

Stoddard Solvent 3.16 - 7.15

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal of waste from

residues / unused products

If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim ordispose in sealed containers at licensed waste disposal site. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose in accordance with all applicable regulations.

Hazardous waste code D001: Waste Flammable material with a flash point <140 F

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.

14. Transport information

DOT

Not regulated as dangerous goods by ground.

DOT

UN1993UN number

Air

Flammable liquids, n.o.s. (Stoddard Solvent, Petroleum distillates)UN proper shipping name

3Class

Transport hazard class(es)

-Subsidiary risk

3Label(s)

IIIPacking group

Read safety instructions, SDS and emergency procedures before handling.Special precautions for user

B1, B52, IB3, T4, TP1, TP29Special provisions

150Packaging exceptions

203Packaging non bulk

242Packaging bulk

DOT

UN1993UN number

Maritime

Flammable liquids, n.o.s. (Stoddard Solvent, Petroleum distillates)UN proper shipping name

3Class


6 / 9



SDS US

-Subsidiary risk

3Label(s)

IIIPacking group


B1, B52, IB3, T4, TP1, TP29Special provisions


203Packaging non bulk

242Packaging bulk

IATA

UN1993UN number

Flammable liquid, n.o.s. (Stoddard Solvent, Petroleum distillates)UN proper shipping name

3Class


-Subsidiary risk

IIIPacking group

No.Environmental hazards

3LERG Code


Allowed.Passenger and cargo

aircraft

Other information

Allowed.Cargo aircraft only

IMDG

UN1993UN number

FLAMMABLE LIQUID, N.O.S. (Stoddard Solvent, Petroleum distilates)UN proper shipping name

3Class


-Subsidiary risk

IIIPacking group

No.Marine pollutant


F-E, S̲-E̲EmS


15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

SARA 304 Emergency release notification

Not regulated.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

Not listed.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

CERCLA Hazardous Substances: Reportable quantity

Not listed.

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the NationalResponse Center (800-424-8802) and to your Local Emergency Planning Committee.

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

7 / 9



SDS US

Safe Drinking Water Act

(SDWA)

Not regulated.

Food and Drug

Administration (FDA)

Not regulated.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312

Hazard categories

Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely

hazardous substance

No

US state regulations

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not listed.

US. New Jersey Worker and Community Right-to-Know Act

Stoddard Solvent (CAS 8052-41-3)

US. Massachusetts RTK - Substance List


US. Pennsylvania Worker and Community Right-to-Know Law


Petrolatum, Micro Soft Wax (CAS 8009-03-8)


US. Rhode Island RTK

None.

US. California Proposition 65

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.

Volatile organic compounds (VOC) regulations

EPA

VOC content (40 CFR

51.100(s))

50.2 %

Consumer products

(40 CFR 59, Subpt. C)

Not regulated

State

Consumer products Not regulated

VOC content (CA) 50.2 %

VOC content (OTC) 50.2 %

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

NoNew Zealand New Zealand Inventory

NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

8 / 9



SDS US

16. Other information, including date of preparation or last revision

Issue date 11-13-2014

Revision date 12-01-2014

Prepared by Allison Cho

Version # 02

Further information CRC # 523B

HMIS® ratings Health: 2*Flammability: 2Physical hazard: 0Personal protection: B

NFPA ratings Health: 2Flammability: 2Instability: 0

NFPA ratings

02

2

Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information contained in thisdocument applies to this specific material as supplied. It may not be valid for this material if it isused in combination with any other materials. This information is accurate to the best of CRCIndustries' knowledge or obtained from sources believed by CRC to be accurate. Before using anyproduct, read all warnings and directions on the label. For further clarification of any informationcontained on this (M)SDS consult your supervisor, a health & safety professional, or CRCIndustries.

9 / 9



SDS US

SAFETY DATA SHEET

1. Identification

Product identifier SP-400™ Corrosion Inhibitor

Other means of identification

Product code 03282

Recommended use Corrosion inhibitor

Recommended restrictions None known.

Manufacturer/Importer/Supplier/Distributor information

Manufactured or sold by:

Company name CRC Industries, Inc.

Address 885 Louis Dr.

Warminster, PA 18974 US

Telephone

General Information 215-674-4300

Technical

Assistance

800-521-3168

Customer Service 800-272-4620

24-Hour Emergency 800-424-9300 (US)

(CHEMTREC) 703-527-3887 (International)

Website www.crcindustries.com

2. Hazard(s) identification

Category 1Flammable aerosolsPhysical hazards

Liquefied gasGases under pressure

Category 2Skin corrosion/irritationHealth hazards

Category 2ASerious eye damage/eye irritation

Category 2Reproductive toxicity (fertility)

Category 3 narcotic effectsSpecific target organ toxicity, single exposure

Category 2Specific target organ toxicity, repeatedexposure

Category 1Aspiration hazard

Category 2Hazardous to the aquatic environment, acutehazard


Category 2Hazardous to the aquatic environment,long-term hazard

Not classified.OSHA defined hazards

Label elements

Signal word Danger

Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal ifswallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May causedrowsiness or dizziness. Suspected of damaging fertility. May cause damage to organs (centralnervous system, respiratory system, eyes, skin) through prolonged or repeated exposure. Toxic toaquatic life. Toxic to aquatic life with long lasting effects.

1 / 10


03282 Version #: 01 Issue date: 12-02-2014

SDS US

Precautionary statement

Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Do not apply while equipment is energized.Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lightsand heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation;maintain ventilation during use and until all vapors are gone. Open doors and windows or useother means to ensure a fresh air supply during use and while product is drying. If you experienceany symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas. Donot breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protectiveclothing/eye protection/face protection. Avoid release to the environment.

Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Washwith plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothingand wash before reuse. If inhaled: Remove person to fresh air and keep comfortable forbreathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water forseveral minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical attention. If exposed or concerned: Get medical attention. Collectspillage.

Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose totemperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.

Disposal Dispose of contents/container in accordance with local/regional/national regulations.

Hazard(s) not otherwise

classified (HNOC)Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

68476-86-8Liquefied Petroleum Gas 20 - 30

107-83-52-Methylpentane 10 - 20

64742-49-0Naphtha (petroleum), hydrotreatedlight

10 - 20

8052-41-3Stoddard Solvent 10 - 20

34590-94-8Dipropylene glycol monomethylether

3 - 5

64742-47-8Distillates (petroleum), hydrotreatedlight

3 - 5

110-54-3n-Hexane < 1

8009-03-8Petrolatum, Micro Soft Wax < 0.2

Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.

Skin contact Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medicaladvice/attention. Wash contaminated clothing before reuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Most important

symptoms/effects, acute and

delayed

Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Aspirationmay cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may includestinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Prolonged exposure may cause chronic effects.

Indication of immediate

medical attention and special

treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.

General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance.

2 / 10



SDS US

5. Fire-fighting measures

Suitable extinguishing media Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth maybe used for small fires only.

Unsuitable extinguishing

media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from

the chemical

Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Thisproduct is a poor conductor of electricity and can become electrostatically charged. If sufficientcharge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulationmay be significantly increased by the presence of small quantities of water or other contaminants.Material will float and may ignite on surface of water. During fire, gases hazardous to health maybe formed.

Special protective equipment

and precautions for firefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Fire-fighting

equipment/instructionsIn case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so withoutrisk. Containers should be cooled with water to prevent vapor pressure build up.

General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture whenexposed to heat or flame.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Remove all possible sources of ignition in the surrounding area. Many gases areheavier than air and will spread along ground and collect in low or confined areas (sewers,basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do notbreathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathingequipment. Do not touch damaged containers or spilled material unless wearing appropriateprotective clothing. Ventilate closed spaces before entering them. Use appropriate containment toavoid environmental contamination. Local authorities should be advised if significant spillagescannot be contained. For personal protection, see section 8 of the SDS.

Methods and materials for

containment and cleaning up

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this iswithout risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry intowaterways, sewer, basements or confined areas.

Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoiddischarge into drains, water courses or onto the ground. Inform appropriate managerial orsupervisory personnel of all environmental releases. Use appropriate containment to avoidenvironmental contamination.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Minimize fire risks from flammable and combustible materials (includingcombustible dust and static accumulating liquids) or dangerous reactions with incompatiblematerials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray buttonis missing or defective. Do not spray on a naked flame or any other incandescent material. Do notsmoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind,or expose containers to heat, flame, sparks, or other sources of ignition. Use caution aroundenergized equipment. The metal container will conduct electricity if it contacts a live source. Thismay result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor.Do not breathe gas. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding womenmust not handle this product. Should be handled in closed systems, if possible. Use only inwell-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughlyafter handling. Avoid release to the environment. Observe good industrial hygiene practices. Forproduct usage instructions, please see the product label.

Conditions for safe storage,

including any incompatibilities

Level 3 Aerosol.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. This material can accumulate static charge which may causespark and become an ignition source. Avoid spark promoters. These alone may be insufficient toremove static electricity. Store in a well-ventilated place. Store away from incompatible materials(see Section 10 of the SDS).

3 / 10



SDS US

8. Exposure controls/personal protection

Occupational exposure limits



PEL 600 mg/m3Dipropylene glycolmonomethyl ether (CAS34590-94-8)

100 ppm

PEL 1800 mg/m3n-Hexane (CAS 110-54-3)

500 ppm

PEL 5 mg/m3 Mist.Petrolatum, Micro Soft Wax(CAS 8009-03-8)

PEL 2900 mg/m3Stoddard Solvent (CAS8052-41-3)

500 ppm

US. ACGIH Threshold Limit Values


STEL 1000 ppm2-Methylpentane (CAS107-83-5)

TWA 500 ppm

STEL 150 ppmDipropylene glycolmonomethyl ether (CAS34590-94-8)

TWA 100 ppm

TWA 50 ppmn-Hexane (CAS 110-54-3)

TWA 5 mg/m3 Inhalable fraction.Petrolatum, Micro Soft Wax(CAS 8009-03-8)

TWA 100 ppmStoddard Solvent (CAS8052-41-3)



Ceiling 1800 mg/m32-Methylpentane (CAS107-83-5)

510 ppm

TWA 350 mg/m3

100 ppm

STEL 900 mg/m3Dipropylene glycolmonomethyl ether (CAS34590-94-8)

150 ppm

TWA 600 mg/m3

100 ppm

TWA 100 mg/m3Distillates (petroleum),hydrotreated light (CAS64742-47-8)

TWA 180 mg/m3n-Hexane (CAS 110-54-3)

50 ppm

STEL 10 mg/m3 Mist.Petrolatum, Micro Soft Wax(CAS 8009-03-8)

TWA 5 mg/m3 Mist.

Ceiling 1800 mg/m3Stoddard Solvent (CAS8052-41-3)

TWA 350 mg/m3

Biological limit values

ACGIH Biological Exposure Indices

ValueComponents Determinant Specimen Sampling Time

0.4 mg/l 2,5-Hexanedion, withouthydrolysis

Urine *n-Hexane (CAS 110-54-3)

* - For sampling details, please see the source document.

4 / 10



SDS US

Exposure guidelines

US - California OELs: Skin designation

Dipropylene glycol monomethyl ether (CAS 34590-94-8) Can be absorbed through the skin.

n-Hexane (CAS 110-54-3) Can be absorbed through the skin.

US - Tennessee OELs: Skin designation


US ACGIH Threshold Limit Values: Skin designation


n-Hexane (CAS 110-54-3) Can be absorbed through the skin.

US NIOSH Pocket Guide to Chemical Hazards: Skin designation




Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Eyewash facilities and emergency shower must be available when handling this product.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection

Hand protection Wear protective gloves such as: Neoprene. Nitrile.

Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.

Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use aNIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-containedbreathing apparatus in confined spaces and for emergencies. Air monitoring is needed todetermine actual employee exposure levels.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Liquid.

Form Aerosol.

Color Dark amber.

Odor Petroleum.

Odor threshold Not available.

pH Not available.

Melting point/freezing point -244.7 °F (-153.7 °C) estimated

Initial boiling point and boiling

range

118.4 °F (48 °C) estimated

Flash point < 0 °F (< -17.8 °C) Tag Closed Cup

Evaporation rate Fast.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

0.7 % estimated

Flammability limit - upper

(%)

14 % estimated

Vapor pressure 1437.2 hPa estimated

Vapor density > 1 (air = 1)

Relative density 0.72 estimated

Solubility (water) Negligible.

5 / 10



SDS US

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature 404.6 °F (207 °C) estimated

Decomposition temperature Not available.

Viscosity (kinematic) Not available.

Percent volatile 79.2 % estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials.

Incompatible materials Strong oxidizing agents.

Hazardous decomposition

products

Carbon oxides. Aldehydes.

11. Toxicological information


Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May causedrowsiness and dizziness. Headache. Nausea, vomiting.

Skin contact Causes skin irritation.

Eye contact Causes serious eye irritation.

Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may causepulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging,tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

Information on toxicological effects

Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects.

Test ResultsProduct Species


LD50 Rabbit

Dermal

Acute


LC50 Rat

Inhalation

28.2233 mg/l estimated

LD50 Rat

Oral



Skin corrosion/irritation Causes skin irritation.

Serious eye damage/eye

irritation

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of Carcinogenicity

Stoddard Solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.

Reproductive toxicity Suspected of damaging fertility.


single exposure

May cause drowsiness and dizziness.

6 / 10



SDS US


repeated exposure

May cause damage to organs through prolonged or repeated exposure: Central nervous system.Respiratory system. Skin. Eyes.

Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,may cause chemical pneumonia, pulmonary injury or death.

Chronic effects May cause damage to organs through prolonged or repeated exposure.

12. Ecological information

Ecotoxicity Toxic to aquatic life with long lasting effects.

Product Test ResultsSpecies


Aquatic

Acute

LC50Fish 5189.231 mg/l, 96 hours estimatedFish

Components Test ResultsSpecies

Dipropylene glycol monomethyl ether (CAS 34590-94-8)

Aquatic

Acute

EC50Crustacea > 5000 mg/l, 48 hoursDaphnia



Aquatic

Acute



n-Hexane (CAS 110-54-3)

Aquatic

LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas)

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow)

2-Methylpentane 3.74

n-Hexane 3.9

Stoddard Solvent 3.16 - 7.15

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal of waste from

residues / unused products

If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim ordispose in sealed containers at licensed waste disposal site. Contents under pressure. Do notpuncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do notcontaminate ponds, waterways or ditches with chemical or used container. Dispose in accordancewith all applicable regulations.

Hazardous waste code D001: Waste Flammable material with a flash point <140 F

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.

14. Transport information

DOT

UN1950UN number

Aerosols, flammable, Limited QuantityUN proper shipping name

2.1Class


-Subsidiary risk

7 / 10



SDS US

2.1Label(s)

Not applicable.Packing group


N82Special provisions


NonePackaging non bulk

NonePackaging bulk

IATA

UN1950UN number

Aerosols, flammable, Limited QuantityUN proper shipping name

2.1Class


-Subsidiary risk


No.Environmental hazards

10LERG Code


Allowed.Passenger and cargo

aircraft

Other information

Allowed.Cargo aircraft only

IMDG

UN1950UN number

AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANTUN proper shipping name

2Class


-Subsidiary risk


YesMarine pollutant


Not available.EmS


15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

SARA 304 Emergency release notification

Not regulated.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

Not listed.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

CERCLA Hazardous Substances: Reportable quantity

Not listed.

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the NationalResponse Center (800-424-8802) and to your Local Emergency Planning Committee.

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act

(SDWA)

Not regulated.

8 / 10



SDS US

Food and Drug

Administration (FDA)

Not regulated.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312

Hazard categories

Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - YesReactivity Hazard - No

SARA 302 Extremely

hazardous substance

No

US state regulations

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not listed.

US. New Jersey Worker and Community Right-to-Know Act

2-Methylpentane (CAS 107-83-5)




US. Massachusetts RTK - Substance List




US. Pennsylvania Worker and Community Right-to-Know Law





Petrolatum, Micro Soft Wax (CAS 8009-03-8)


US. Rhode Island RTK


US. California Proposition 65

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.

Volatile organic compounds (VOC) regulations

EPA

VOC content (40 CFR

51.100(s))

79.2 %

Consumer products

(40 CFR 59, Subpt. C)

Not regulated

State

Consumer products Not regulated

VOC content (CA) 79.2 %

VOC content (OTC) 79.2 %

International Inventories


YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

NoNew Zealand New Zealand Inventory

9 / 10



SDS US


NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

16. Other information, including date of preparation or last revision

Issue date 12-02-2014

Prepared by Allison Cho

Version # 01

Further information Not available.

HMIS® ratings Health: 2*Flammability: 4Physical hazard: 0Personal protection: B

NFPA ratings Health: 2Flammability: 4Instability: 0

NFPA ratings

02

4

Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information contained in thisdocument applies to this specific material as supplied. It may not be valid for this material if it isused in combination with any other materials. This information is accurate to the best of CRCIndustries' knowledge or obtained from sources believed by CRC to be accurate. Before using anyproduct, read all warnings and directions on the label. For further clarification of any informationcontained on this (M)SDS consult your supervisor, a health & safety professional, or CRCIndustries.

10 / 10



SDS US

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Nitrogen, compressedSafety Data Sheet P-4631according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.Date of issue: 01/01/1980 Revision date: 06/24/2015 Supersedes: 04/23/2015

EN (English US) SDS ID: P-4631 1/8

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download.Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website.

SECTION: 1. Product and company identification1.1. Product identifierProduct form : SubstanceName : Nitrogen, compressedCAS No : 7727-37-9Formula : N2Other means of identification : Dinitrogen, Refrigerant R728, Nitrogen, Medipure Nitrogen, Extendapak Nitrogen,

Nitrogen - Diving Grade

1.2. Relevant identified uses of the substance or mixture and uses advised againstUse of the substance/mixture : Industrial use

Medical applications.Food applications.Diving Gas (Underwater Breathing)

1.3. Details of the supplier of the safety data sheetPraxair, Inc.39 Old Ridgebury RoadDanbury, CT 06810-5113 - USAT 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146www.praxair.com1.4. Emergency telephone numberEmergency number : Onsite Emergency: 1-800-645-4633

CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887 (collect calls accepted, Contract 17729)

SECTION 2: Hazards identification2.1. Classification of the substance or mixture

Classification (GHS-US)Compressed gas H280

2.2. Label elements

GHS-US labelingHazard pictograms (GHS-US) :

GHS04

Signal word (GHS-US) : WARNINGHazard statements (GHS-US) : H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood

P271+P403 - Use and store only outdoors or in a well-ventilated place.CGA-PG05 - Use a back flow preventive device in the piping.CGA-PG10 - Use only with equipment rated for cylinder pressure.CGA-PG06 - Close valve after each use and when empty.CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F).

2.3. Other hazardsNo additional information available

www.praxair.com




2.4. Unknown acute toxicity (GHS-US)No data available

SECTION 3: Composition/information on ingredients3.1. SubstanceName : Nitrogen, compressedCAS No : 7727-37-9

Name Product identifier %Nitrogen (CAS No) 7727-37-9 99.5 - 100

3.2. MixtureNot applicable

SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures after inhalation : Immediately remove to fresh air. If not breathing, give artificial respiration. If breathing is

difficult, qualified personnel may give oxygen. Call a physician.First-aid measures after skin contact : Adverse effects not expected from this product.First-aid measures after eye contact : Adverse effects not expected from this product. In case of eye irritation: Rinse immediately with

plenty of water. Consult an ophthalmologist if irritation persists.First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayedNo additional information available

4.3. Indication of any immediate medical attention and special treatment neededNone.

SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixtureReactivity : Under certain conditions, nitrogen can react violently with lithium, neodymium, titanium (above

1472°F/800°C), and magnesium to form nitrides. At high temperature, it can also combine with oxygen and hydrogen.

5.3. Advice for firefightersFirefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)

and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.Special protective equipment for fire fighters : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire

fighters.Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat

radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems.

Stop flow of product if safe to do so.

Use water spray or fog to knock down fire fumes if possible.

SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresGeneral measures : Evacuate area. Ensure adequate air ventilation. Wear self-contained breathing apparatus when

entering area unless atmosphere is proven to be safe. Stop leak if safe to do so.




6.1.1. For non-emergency personnelNo additional information available

6.1.2. For emergency respondersNo additional information available

6.2. Environmental precautionsNo additional information available

6.3. Methods and material for containment and cleaning upNo additional information available

6.4. Reference to other sectionsSee also sections 8 and 13.

SECTION 7: Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from

physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g., wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.

Safe use of the product : The suitability of this product as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the physiological effects, methods employed, frequency and duration of use, hazards, side effects, and precautions to be taken.

7.2. Conditions for safe storage, including any incompatibilitiesStorage conditions : Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only

where temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods.

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

7.3. Specific end use(s)None.

SECTION 8: Exposure controls/personal protection8.1. Control parameters

Nitrogen, compressed (7727-37-9)ACGIH Not established

USA OSHA Not established

Nitrogen (7727-37-9)ACGIH Not established

USA OSHA Not established




8.2. Exposure controlsAppropriate engineering controls : Use a local exhaust system with sufficient flow velocity to maintain an adequate supply of air in

the worker's breathing zone. Mechanical (general): General exhaust ventilation may be acceptable if it can maintain an adequate supply of air.

Eye protection : Wear safety glasses with side shields.Skin and body protection : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where

needed. Wear appropriate chemical gloves during cylinder changeout or wherever contact with product is possible. Select per OSHA 29 CFR 1910.132, 1910.136, and 1910.138.

Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable). Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the cartridge must be appropriate for the chemical exposure (e.g., an organic vapor cartridge). For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).

SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical state : Gas

Appearance : Colorless gas.Molecular mass : 28 g/molColor : Colorless.

Odor : No odor warning properties.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) : No data available

Relative evaporation rate (ether=1) : Not applicable.Melting point : -210 °C

Freezing point : No data available

Boiling point : -195.8 °C

Flash point : No data available

Critical temperature : -149.9 °CAuto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 3390 kPaRelative vapor density at 20 °C : No data available

Relative density : No data available

Density : 1.16 kg/m³Relative gas density : 0.97Solubility : Water: 20 mg/l

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other informationGas group : Compressed gasAdditional information : None.




SECTION 10: Stability and reactivity10.1. Reactivity

Under certain conditions, nitrogen can react violently with lithium, neodymium, titanium (above 1472°F/800°C), and magnesium to form nitrides. At high temperature, it can also combine with oxygen and hydrogen.

10.2. Chemical stabilityStable under normal conditions.

10.3. Possibility of hazardous reactionsMay occur.

10.4. Conditions to avoidNone under recommended storage and handling conditions (see section 7).

10.5. Incompatible materialsNone.

10.6. Hazardous decomposition productsNone.

SECTION 11: Toxicological information11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

pH: Not applicable.Serious eye damage/irritation : Not classified

pH: Not applicable.Respiratory or skin sensitization : Not classifiedGerm cell mutagenicity : Not classifiedCarcinogenicity : Not classified

Reproductive toxicity : Not classifiedSpecific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information12.1. ToxicityEcology - general : No ecological damage caused by this product.

12.2. Persistence and degradabilityNitrogen, compressed (7727-37-9)Persistence and degradability No ecological damage caused by this product.

Nitrogen (7727-37-9)Persistence and degradability No ecological damage caused by this product.

12.3. Bioaccumulative potentialNitrogen, compressed (7727-37-9)Log Pow Not applicable.Log Kow Not applicable.Bioaccumulative potential No ecological damage caused by this product.




Nitrogen (7727-37-9)Log Pow Not applicable for inorganic gases.Log Kow Not applicable.Bioaccumulative potential No ecological damage caused by this product.

12.4. Mobility in soilNitrogen, compressed (7727-37-9)Mobility in soil No data available.Ecology - soil No ecological damage caused by this product.

Nitrogen (7727-37-9)Mobility in soil No data available.Ecology - soil No ecological damage caused by this product.

12.5. Other adverse effectsEffect on ozone layer : None.

Effect on the global warming : None.

SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international

regulations. Contact supplier for any special requirements.

SECTION 14: Transport informationIn accordance with DOTTransport document description : UN1066 Nitrogen, compressed, 2.2 UN-No.(DOT) : UN1066Proper Shipping Name (DOT) : Nitrogen, compressedTransport hazard class(es) (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115Hazard labels (DOT) : 2.2 - Non-flammable gas

Additional informationEmergency Response Guide (ERG) Number : 121 (UN1066);120 (UN1977)

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by seaUN-No. (IMDG) : 1066Proper Shipping Name (IMDG) : NITROGEN, COMPRESSEDClass (IMDG) : 2 - GasesMFAG-No : 121

Air transportUN-No.(IATA) : 1066Proper Shipping Name (IATA) : Nitrogen, compressed




Class (IATA) : 2Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

SECTION 15: Regulatory information15.1. US Federal regulations

Nitrogen, compressed (7727-37-9)Listed on the United States TSCA (Toxic Substances Control Act) inventorySARA Section 311/312 Hazard Classes Sudden release of pressure hazard

15.2. International regulationsCANADA

Nitrogen, compressed (7727-37-9)Listed on the Canadian DSL (Domestic Substances List)

Nitrogen (7727-37-9)Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Nitrogen, compressed (7727-37-9)Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

15.2.2. National regulationsNitrogen, compressed (7727-37-9)Listed on the AICS (Australian Inventory of Chemical Substances)Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)Listed on the Korean ECL (Existing Chemicals List)Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

15.3. US State regulationsNitrogen, compressed(7727-37-9)U.S. - California - Proposition 65 - Carcinogens List NoU.S. - California - Proposition 65 - Developmental Toxicity

No

U.S. - California - Proposition 65 - Reproductive Toxicity - Female

No

U.S. - California - Proposition 65 - Reproductive Toxicity - Male

No

State or local regulations U.S. - Massachusetts - Right To Know ListU.S. - New Jersey - Right to Know Hazardous Substance ListU.S. - Pennsylvania - RTK (Right to Know) List

Nitrogen (7727-37-9)U.S. - California - Proposition 65 - Carcinogens List

U.S. - California - Proposition 65 - Developmental Toxicity

U.S. - California - Proposition 65 - Reproductive Toxicity - Female

U.S. - California - Proposition 65 - Reproductive Toxicity - Male

No significance risk level (NSRL)

No No No No

Nitrogen (7727-37-9)U.S. - Massachusetts - Right To Know ListU.S. - New Jersey - Right to Know Hazardous Substance ListU.S. - Pennsylvania - RTK (Right to Know) List




SECTION 16: Other informationRevision date : 6/24/2015 12:00:00 AMOther information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain

and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product.

Praxair asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information.

The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of Praxair, Inc., it is the user's obligation to determine the conditions of safe use of the product.

Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your Praxair sales representative, local distributor, or supplier, or download from www.praxair.com. If you have questions regarding Praxair SDSs, would like the document number and date of the latest SDS, or would like the names of the Praxair suppliers in your area, phone or write the Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247; Address: Praxair Call Center, Praxair, Inc., P.O. Box 44, Tonawanda, NY 14151-0044).

PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair Technology, Inc. in the United States and/or other countries.

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials.

NFPA fire hazard : 0 - Materials that will not burn.NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.

HMIS III RatingHealth : 0 Minimal Hazard - No significant risk to healthFlammability : 0 Minimal HazardPhysical : 3 Serious Hazard

SDS US (GHS HazCom 2012) - Praxair

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

Du Pont Material Safety Data Sheet

Page 1

-------------------------------------------- -------------------------- "SUVA"-134a CEFS134A Revised 9-Mar-11 Printed 03/09/2011 -------------------------------------------- -------------------------- Substance ID :130000024024 -------------------------------------------- -------------------------- CHEMICAL PRODUCT/COMPANY IDENTIFICATION -------------------------------------------- -------------------------- Material Identification Corporate MSDS Number : DU000693 CAS Number : 811-97-2 Formula : CH2FCF3 CAS Name : 1,1,1,2-TETRAFL UOROETHANE Product Use Refrigerant Tradenames and Synonyms TETRAFLUOROETHANE 1,1,1,2-TETRAFLUOROETHANE Refrigerant "SUVA" 134a Refrigerant "SUVA" is a registered trademark of E.I. du Pont de Nemours and Company, and its affiliates. E.I. du Pont Canada Company is a licensee. Company Identification MANUFACTURER/DISTRIBUTOR E.I. du Pont Canada Compan y P.O. Box 2200 Streetsville Mississauga, Ontario L5M 2 H3 PHONE NUMBERS Product Information : 1-800-387-2122 Medical Emergency : 1-800-441-3637 ( 24 hours) -------------------------------------------- -------------------------- COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------- -------------------------- Components Material CA S Number % ETHANE, 1,1,1,2-TETRAFLUORO- 811-97-2 100 % (HFC-134a) -------------------------------------------- -------------------------- HAZARDS IDENTIFICATION -------------------------------------------- -------------------------- Potential Health Effects

Print Date: 3 - 10 - 2011

CEFS134A Du Pont

Material Safety Data Sheet Page 2

Printed on 03/09/2011

INHALATION ETHANE, 1,1,1,2-TETRAFLUORO- Gross overexposure may cause: Central ner vous system depression with dizziness, confusion, incoordination , drowsiness or unconsciousness. Irregular heart beat wi th a strange sensation in the chest, "heart thumping", apprehension , lightheadedness, feeling of fainting, dizziness, weakness, sometimes progressing to loss of consciousness and death. Suffoca tion, if air is displaced by vapors. SKIN CONTACT ETHANE, 1,1,1,2-TETRAFLUORO- Immediate effects of overexposure may inc lude: Frostbite, if liquid or escaping vapor contacts the ski n. EYE CONTACT ETHANE, 1,1,1,2-TETRAFLUORO- "Frostbite-like" effects may occur if the liquid or escaping vapors contact the eyes. ADDITIONAL HEALTH EFFECTS ETHANE, 1,1,1,2-TETRAFLUORO- Increased susceptibility to the effects o f this material may be observed in persons with pre-existing dis ease of the: central nervous system, cardiovascular system. Carcinogenicity Information None of the components present in this mater ial at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. -------------------------------------------- -------------------------- FIRST AID MEASURES -------------------------------------------- -------------------------- First Aid INHALATION If high concentrations are inhaled, immed iately remove to fresh air. Keep person calm. If not breathing , give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT In case of contact, immediately flush ski n with plenty of water for at least 15 minutes, while removing c ontaminated clothing and shoes. Call a physician. Wash contamina ted clothing before

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CEFS134A Du Pont



reuse. Treat for frostbite if necessary by gently warming affected area. EYE CONTACT In case of contact, immediately flush eye s with plenty of water for at least 15 minutes. Call a physicia n. INGESTION Ingestion is not considered a potential r oute of exposure. Notes to Physicians Because of possible disturbances of cardi ac rhythm, catecholamine drugs, such as epinephrine, should only b e used with special caution in situations of emergency life s upport. -------------------------------------------- -------------------------- FIRE FIGHTING MEASURES -------------------------------------------- -------------------------- Flammable Properties Flash Point : No flash point Flammable Limits in Air, % by Volume: LEL : None per ASTM E681 UEL : None per ASTM E681 Autoignition : >743 C(>1369 F) Fire and Explosion Hazards: Cylinders may rupture under fire conditio ns. Decomposition may occur. Contact of welding or soldering torch fla me with high concentrations of refrigerant can result in visible changes in the size and color of torch flames. T his flame effect will only occur in concentrations of prod uct well above the recommended exposure limit, therefore sto p all work and ventilate to disperse refrigerant vapors from the work area before using any open flames. HFC-134a is not flammable in air at tempe ratures up to 100 deg. C (212 deg. F) at atmospheric pr essure. However, mixtures of HFC-134a with high concentrat ions of air at elevated pressure and/or temperature can become combustible in the presence of an ignition source. H FC-134a can also become combustible in an oxygen enri ched environment (oxygen concentrations greater than that in air). Whether a mixture containing HFC-134a and air, or H FC-134a in an oxygen enriched atmosphere become comb ustible depends on

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CEFS134A Du Pont



the inter-relationship of 1) the temperat ure 2) the pressure, and 3) the proportion of oxygen in the mixture. In general, HFC-134a should not be allowed t o exist with air above atmospheric pressure or at high temperatures; or in an oxygen enriched environment. For e xample HFC-134a should NOT be mixed with air under pressu re for leak testing or other purposes. Experimental data have also been reported which indicate combustibility of HFC-134a in the presenc e of certain concentrations of chlorine. Extinguishing Media Use media appropriate for surrounding mat erial. Fire Fighting Instructions Cool tank/container with water spray. Se lf-contained breathing apparatus (SCBA) may be required if cylin ders rupture or release under fire conditions. Water runoff should be contained and neut ralized prior to release. -------------------------------------------- -------------------------- ACCIDENTAL RELEASE MEASURES -------------------------------------------- -------------------------- Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and H ANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clea n-up. Ventilate area, especially low or enclose d places where heavy vapors might collect. Remove open flames . Use self-contained breathing apparatus (SCBA) if large spill or leak occurs. -------------------------------------------- -------------------------- HANDLING AND STORAGE -------------------------------------------- -------------------------- Handling (Personnel) Use with sufficient ventilation to keep e mployee exposure below recommended limits. Handling (Physical Aspects) HFC-134a should not be mixed with air for leak testing or used for any other purpose above atmospheric press ure. See Flammable Properties section. Contact with chlorin e or other strong oxidizing agents should also be avoided.

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CEFS134A Du Pont



Storage Store in a clean, dry place. Do not heat above 52 C (126 F). Valve protection caps and valve cutlet th readed plugs must remain in place unless container is secur ed with valve outlet piped to use point. Do NOT drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Never attempt to lift cylinder by its cap . Use a pressure reducing regulator when connecting cylind er to lower pressure (>3000 psig) piping or systems. Do NOT heat cylinder. Use a check valve or trap in t he discharge line to prevent hazardous back flow into the c ylinder. Cylinders should be stored upright and fi rmly secured to prevent falling or being knocked over. S eparate full containers from empty containers. Storag e area temperatures should not exceed 125 deg F (52 deg C) an d should be free of combustible materials. Avoid area where salt or other corrosive materials are present. Avoid e xcessive inventory and storage time. Use a first-in first-o ut system. Keep accurate inventory records. -------------------------------------------- -------------------------- EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------- -------------------------- Engineering Controls Normal ventilation for standard manufactu ring procedures is generally adequate. Local exhaust should be used when large amounts are released. Mechanical ventila tion should be used in low or enclosed places. Refrigerant conc entration monitors may be necessary to determine vapor concentratio ns in work areas prior to use of torches or other open flames, or i f employees are entering enclosed areas. Personal Protective Equipment Impervious gloves and chemical splash gog gles should be used when handling liquid. Under normal manufacturing conditions, no respiratory protection is required when using this product. Self-contained breathing apparatus (SCBA) is required if a large release occurs. # Exposure Guidelines Exposure Limits "SUVA"-134a PEL (OSHA) : None Establish ed TLV (ACGIH) : None Establish ed AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA

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CEFS134A Du Pont



WEEL (AIHA) : 1000 ppm, 8 Hr . TWA * AEL is DuPont's Acceptable Exposure Lim it. Where governmentally imposed occupational exposure limits whic h are lower than the AEL are in effect, such limits shall take pre cedence. -------------------------------------------- -------------------------- PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------- -------------------------- Physical Data Boiling Point : -26.5 C (-15.7 F) @ 736 mm Hg Vapor Pressure : 96 psia @ 25 C (77 F) Vapor Density : 3.6 (Air=1.0) @ 25 C (77 F) % Volatiles : 100 WT% Solubility in Water : 0.15 WT% @ 25 C (77 F) @ 14.7 psia Odor : Ether (slight). Form : Liquified Gas. Color : Colorless. Liquid Density : 1.21 g/cm3 @ 25 C (77 F) Specific Gravity : 1.208 @ 77 F (2 5 C) Evaporation Rate : (CCL4 = 1); greater th an 1 -------------------------------------------- -------------------------- STABILITY AND REACTIVITY -------------------------------------------- -------------------------- Chemical Stability Stable. Conditions to Avoid Avoid open flames and high temperatures. Incompatibility with Other Materials Incompatible with alkali or alkaline eart h metals - powdered Al, Zn, Be, etc. Decomposition Decomposition products are hazardous. Th is material can be decomposed by high temperatures (open fla mes, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride. These materials are toxic and irritating. Contact should be avoided. Polymerization

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CEFS134A Du Pont



Polymerization will not occur. -------------------------------------------- -------------------------- TOXICOLOGICAL INFORMATION -------------------------------------------- -------------------------- Animal Data ETHANE, 1,1,1,2-TETRAFLUORO- EYE: A short duration spray of vapor produced very slight eye irritation. SKIN: Animal testing indicates this material is a slight skin irritant, but not a skin sensitizer. INHALATION: 4 hour, ALC, rat: 567,000 ppm. Single exposure caused: Cardiac sensitiza tion, a potentially fatal disturbance of heart rhythm associated wi th a heightened sensitivity to the action of epinephrine. Lowest-Observed-Adverse-Effect-Level for cardiac sensitization: 75,000 ppm. Single exposure caused: Leth argy. Narcosis. Increased respiratory rates. These effec ts were temporary. Single exposure to near lethal doses caus ed: Pulmonary edema. Repeated exposure caused: Increased adren als, liver, spleen weight. Decreased uterine, prostate weig ht. Repeated dosing of higher concentrations caused: the followi ng temporary effects - Tremors. Incoordination. CARCINOGENIC, DEVELOPMENTAL, REPRODUCTIVE , MUTAGENIC EFFECTS: In a two-year inhalation study, HFC-134a, at a concentration of 50,000 ppm, produced an increase in late- occurring benign testicular tumors, testicular hyperplasia and testicular weight. The no-effect-level for this study was 10 ,000 ppm. Animal data show slight fetotoxicity but only at expo sure levels producing other toxic effects in the adult animal. Reproductive data on male mice show: No change in reproductive performance. Tests have shown that this material does not cause g enetic damage in bacterial or mammalian cell cultures, or in animals. In animal testing, this material has not caused per manent genetic damage in reproductive cells of mammals (has not pr oduced heritable genetic damage). -------------------------------------------- -------------------------- ECOLOGICAL INFORMATION -------------------------------------------- -------------------------- Ecotoxicological Information

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CEFS134A Du Pont



AQUATIC TOXICITY: 48 hour EC50 - Daphnia magna: 980 mg/L. 96 hour LC50 - Rainbow trout: 450 mg/L -------------------------------------------- -------------------------- DISPOSAL CONSIDERATIONS -------------------------------------------- -------------------------- Waste Disposal Contaminated HFC-134a can be recovered by distillation or removed to a permitted waste disposal facility. Comply with Federal, State, and local regulations. -------------------------------------------- -------------------------- TRANSPORTATION INFORMATION -------------------------------------------- -------------------------- Shipping Information DOT/IMO Proper Shipping Name : 1,1,1,2-TETRAFL UOROETHANE Hazard Class : 2.2 UN No. : 3159 DOT/IMO Label : NONFLAMMABLE GA S Shipping Containers Tank Cars. Tank Trucks. Ton Tanks. Cylinders. Shipping Information -- Canada TDG Proper Shipping Name : 1, 1, 1, 2-TETR AFLUOROETHANE TDG Class : 2.2 UN # : 3159 -------------------------------------------- -------------------------- REGULATORY INFORMATION -------------------------------------------- -------------------------- U.S. Federal Regulations TSCA Inventory Status : Reported/Includ ed. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute : Yes Chronic : Yes Fire : No Reactivity : No

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CEFS134A Du Pont



Pressure : Yes HAZARDOUS CHEMICAL LISTS SARA Extremely Hazardous Substance: No CERCLA Hazardous Substance : No SARA Toxic Chemical : No Canadian Regulations WHMIS Classification: CLASS A Compressed Gas This product has been classified in accor dance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. CEPA Status : DSL: REPORTED/I NCLUDED. -------------------------------------------- -------------------------- OTHER INFORMATION -------------------------------------------- -------------------------- NFPA, NPCA-HMIS NPCA-HMIS Rating Health : 1 Flammability : 0 Reactivity : 1 Personal Protection rating to be supplied by user depending on use conditions. Additional Information MEDICAL USE: CAUTION: Do not use in medi cal applications involving permanent implantation in the h uman body. For other medical applications see DuPont CAUTION B ulletin No. H-50102. -------------------------------------------- -------------------------- The data in this Material Safety Data She et relates only to the specific material designated herein and d oes not relate to use in combination with any other material or in any process. Responsibility for MSDS ----------------------- FLUOROPRODUCTS E.I. E.I. du Pont Canada C ompany Company Box 2200, Streetsville Mississauga, Ontario, L5M 2H3 (905) 821-3300. # Indicates updated section. (Continued)

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CEFS134A Du Pont



End of MSDS

Print Date: 3 - 10 - 2011

SUNAIR PAG 46 32OZ Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision date: 06/16/2014 : Version:

16/06/2014 EN (English US) 1/5

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance

Trade name : SUNAIR PAG 46 32OZ

CAS No : Proprietary

Product code : OB6331

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : FOLLOW LABEL DIRECTIONS

Use of the substance/mixture : Lubricant

1.3. Details of the supplier of the safety data sheet

Sunair Products, Inc. 2525 Minnis Dr. Fort Worth, Texas 76117 T 817-831-6301

1.4. Emergency telephone number

Emergency number : CHEMTREC 24 Hour 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (GHS-US)

Not classified

2.2. Label elements

GHS-US labeling

No labeling applicable

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS-US)

No data available

SECTION 3: Composition/information on ingredients

3.1. Substance

Name : POLYALKYLENE GLYCOL ALKYL ETHER

CAS No : Proprietary

Name Product identifier % Classification (GHS-US)

POLYALKYLENE GLYCOL ALKYL ETHER (Main constituent)

(CAS No) Proprietary >= 98 Not classified

Full text of H-phrases: see section 16

3.2. Mixture

Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.

First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.

First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist.

First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.

4.3. Indication of any immediate medical attention and special treatment needed



16/06/2014 EN (English US) 2/5

SECTION 5: Firefighting measures

5.1. Extinguishing media

suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture


5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment : Gloves. Safety glasses.

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment : Dam up the liquid spill.

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use.

Incompatible products : Strong bases. Strong acids.

Incompatible materials : Sources of ignition. Direct sunlight.

7.3. Specific end use(s)

Follow Label Directions.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

SUNAIR PAG 46 32OZ (Proprietary)

DNEL DNEL <

8.2. Exposure controls

Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.

Respiratory protection : Wear appropriate mask.

Other information : Do not eat, drink or smoke during use.


16/06/2014 EN (English US) 3/5

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Liquid.

Color : Amber.

Odor : characteristic.

Odor threshold : No data available

pH : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : > 200 °C Cleveland Open Cup

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 °C : No data available

Relative density : 0.99 @20 C

Solubility : Insoluble in water.

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : 44 mm²/s @40C

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information


SECTION 10: Stability and reactivity

10.1. Reactivity


10.2. Chemical stability

Not established.

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

SUNAIR PAG 46 32OZ ( \f )Proprietary

LD50 oral rat 5000 mg/kg

LD50 dermal rabbit 5000 mg/kg

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classifiedBased on available data, the classification criteria are not met

Carcinogenicity : Not classified


16/06/2014 EN (English US) 4/5

Reproductive toxicity : Not classifiedBased on available data, the classification criteria are not met

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: Not classifiedBased on available data, the classification criteria are not met

Aspiration hazard : Not classifiedBased on available data, the classification criteria are not met

Potential Adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1. Toxicity


12.2. Persistence and degradability


Persistence and degradability Not established.

12.3. Bioaccumulative potential


Bioaccumulative potential Not established.

12.4. Mobility in soil


12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN

US DOT (ground): Not regulated,

ICAO/IATA (air): Not regulated,

IMO/IMDG (water): Not regulated,

Not applicable

14.2. UN proper shipping name

DOT Proper Shipping Name : Not regulated

14.3. Additional information

Other information : No supplementary information available.

Overland transport


Transport by sea


Air transport


SECTION 15: Regulatory information

15.1. US Federal regulations


Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. International regulations

CANADA


Listed on the Canadian DSL (Domestic Substances List) inventory.


16/06/2014 EN (English US) 5/5

EU-Regulations


Classification according to Regulation (EC) No. 1272/2008 [CLP]

Not classified

Classification according to Directive 67/548/EEC or 1999/45/EC

Not classified

15.2.2. National regulations


Listed on the AICS (the Australian Inventory of Chemical Substances) Listed on Inventory of Chemicals and Chemical Substances (PICCS)

15.3. US State regulations


SECTION 16: Other information

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.

NFPA fire hazard : 1 - Must be preheated before ignition can occur.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

HMIS III Rating

Health : 1 Slight Hazard - Irritation or minor reversible injury possible

Flammability : 1 Slight Hazard

Physical : 0 Minimal Hazard

SDS US (GHS HazCom 2012) - Technical Chemical

The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.

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