MATERIAL SAFETY DATA SHEET West System Inc.rrs.union.rpi.edu/doc/2016/RRS_USLI_MSDS_2016.pdfmaterial safety data sheet west system inc. msds#403-13a last revised: 10oct13 1. chemical

MATERIAL SAFETY DATA SHEET

West System Inc.

MSDS406-13a Last Revised: 26APR13

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ............................................. WEST SYSTEM® 406 Colloidal Silica.

PRODUCT CODE: ............................................. 406

CHEMICAL FAMILY: ......................................... Silicon.

CHEMICAL NAME: ........................................... Silicon dioxide (amorphous).

FORMULA: ........................................................ SiO2

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS:

West System Inc. Transportation 102 Patterson Ave. CHEMTREC: .................... 800-424-9300 (U.S.) Bay City, MI 48706, U.S.A. 703-527-3887 (International) Phone: 866-937-8797 or 989-684-7286 Non-transportation www.westsystem.com Poison Hotline: ................. 800-222-1222

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

CAUTION May pose a static ignition hazard. Avoid excessive breathing of airborne dust. White, fluffy powder with no odor.

PRIMARY ROUTE(S) OF ENTRY: ..................................................... Inhalation.

POTENTIAL HEALTH EFFECTS:

ACUTE INHALATION: ........................................................................ If exposure limits are exceeded, the respiratory tract may become irritated.

May cause shortness of breath, coughing, and/or chest tightness due to temporarily physically overloading the lungs.

CHRONIC INHALATION: ................................................................... May aggravate existing respiratory conditions. May cause dryness of

mucous membranes of the respiratory tract.

ACUTE SKIN CONTACT: ................................................................... May cause irritation and dryness.

CHRONIC SKIN CONTACT:............................................................... Repeated exposure may cause dermatitis due to drying of the skin.

EYE CONTACT: ................................................................................. May cause irritation, redness and tearing.

INGESTION: ....................................................................................... No known health effects.

SYMPTOMS OF OVEREXPOSURE: .................................................. Coughing, shortness of breath or irritation of the respiratory tract. Dry,

chapped or irritated skin. Irritated or tearing eyes.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Skin and respiratory conditions, such as dermatitis and asthma.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS# CONCENTRATION (%)

Fumed Amorphous Silica 112945-52-5 100

4. FIRST AID MEASURES

FIRST AID FOR EYES: ...................................................................... Flush adequately with water to remove particles. If discomfort persists,

seek medical advice.

FIRST AID FOR SKIN: ....................................................................... Wash with soap and water. Apply moisturizing cream to replenish

moisture in the skin if necessary.

FIRST AID FOR INHALATION: .......................................................... Remove to fresh air if effects occur. If effects persists, seek medical

advice.

FIRST AID FOR INGESTION: ............................................................ No specific information.

West System Inc. Page 2 of 4 WEST SYSTEM® 406


5. FIRE FIGHTING MEASURES

FLASH POINT: ................................................................................... Greater than 535F (COC, ASTM D-92).

EXTINGUISHING MEDIA: .................................................................. Water, dry chemical, halon or foam.

SPECIAL FIRE FIGHTING PROCEDURES: ....................................... No specific information.

6. ACCIDENTAL RELEASE MEASURES

SPILL OR LEAK PROCEDURES: ...................................................... Sweep and shovel or use properly grounded vacuum equipment. Do so in

a manner that minimizes airborne dust.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): .......................................... 0°F (-17°C)/100°F (38°C)

STORAGE: ......................................................................................... Keep dry.

HANDLING PRECAUTIONS: ............................................................. Avoid handling that will unnecessarily generate airborne dust. Properly

ground all material handling equipment to prevent static discharge.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

EYE PROTECTION GUIDELINES: ..................................................... Safety glasses or goggles are recommended, depending on the expected

level of exposure.

SKIN PROTECTION GUIDELINES:.................................................... Areas expected to have repeated exposure, such as hands, may need to

be protected by an impervious material to prevent dryness. Barrier creams can be used effectively.

RESPIRATORY/VENTILATION GUIDELINES: .................................. Work environments should be maintained below applicable exposure level

through the use of engineering controls, such as dilution and exhaust ventilation. If this is not feasible, use a NIOSH approved dust mask/respirator for nuisance dust.

ADDITIONAL PROTECTIVE MEASURES:......................................... Practice good industrial hygiene by washing with soap and water after

each use. Apply moisturizing cream to replenish moisture if necessary. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ............................................. This product should be treated as a nuisance dust. Refer to OSHA’s

Permissible Exposure Level (PEL) or the ACGIH Guidelines for information on specific ingredients.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM .............................................................................. Powder.

COLOR ............................................................................................... White.

ODOR ................................................................................................. Odorless.

BOILING POINT ................................................................................. No data.

MELTING POINT/FREEZE POINT ..................................................... No data.

pH ....................................................................................................... No data.

SOLUBILITY IN WATER .................................................................... Insoluble.

SPECIFIC GRAVITY ........................................................................... 2.2

BULK DENSITY ................................................................................. 0.33 pounds/gallon.

VAPOR PRESSURE ........................................................................... Not Applicable.

VAPOR DENSITY ............................................................................... Not Applicable.

% VOLATILE BY WEIGHT ................................................................. 0.0 (0.0 g/L)

10. STABILITY AND REACTIVITY

STABILITY: ........................................................................................ Stable.

HAZARDOUS POLYMERIZATION: .................................................... Will not occur.

INCOMPATIBILITIES: ........................................................................ A chemical reaction is possible with strong bases or hydrofluoric acid.

DECOMPOSITION PRODUCTS: ........................................................ Can include carbon monoxide (CO) and carbon dioxide (CO2).

11. TOXICOLOGICAL INFORMATION

Oral: ................................................................... LD50 >5000 mg/kg (rats) Inhalation: .......................................................... LD50 > 2.08 mg/L 4hr.



Dermal: .............................................................. LD50 >5000 mg/kg (rabbits) Data from chronic inhalation of treated and untreated silicas are currently under review.

CARCINOGENICITY:

NTP ............................................................................................ No. IARC........................................................................................... No. OSHA ......................................................................................... No.

No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or IARC.

12. ECOLOGICAL INFORMATION

No information.

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: This material is determined not to be a hazardous waste as per RCRA standards, either by listing or

characteristics. Disposer must comply with all federal, state and local laws. Waste product may be sent to a landfill.

14. TRANSPORTATION INFORMATION

DOT Non-Bulk

SHIPPING NAME: .............................................................................. Not regulated. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ............................................................................... Not applicable. U.N./N.A. NUMBER: ........................................................................... Not applicable. PACKING GROUP: ............................................................................. Not applicable.

ICAO/IATA

SHIPPING NAME: .............................................................................. Not regulated. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ............................................................................... Not applicable. U.N. NUMBER: ................................................................................... Not applicable. PACKING GROUP: ............................................................................. Not applicable.

IMDG


15. REGULATORY INFORMATION

OSHA STATUS: ................................................................................. Nuisance dust.

TSCA STATUS: .................................................................................. All components are listed on TSCA inventory or otherwise comply with

TSCA requirements.

Canada WHMIS Classification:......................................................... Not a WHMIS controlled substance.

CEPA Chemical Inventory Status: ................................................... All components are listed or are otherwise compliant with CEPA

requirements.

SARA TITLE III:

SECTION 313 TOXIC CHEMICALS ........................................... None.

STATE REGULATORY INFORMATION:

The following chemicals are specifically listed or otherwise regulated by individual states. For details on your regulatory requirements you should contact the appropriate agency in your state.

COMPONENT NAME

/CAS NUMBER STATE CODE

Amorphous Silica 112945-52-5 MA, NJ, RI

16. OTHER INFORMATION

REASON FOR ISSUE: ....................................................................... Changes made in Sections 3, 11, 14 & 15.

PREPARED BY: ................................................................................. G. M. House



APPROVED BY: ................................................................................. G. M. House

TITLE: ................................................................................................ Health, Safety & Environmental Manager

APPROVAL DATE: ............................................................................ April 26, 2013

SUPERSEDES DATE: ........................................................................ February 6, 2011

MSDS NUMBER: ................................................................................ 406-13a

This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of West System Inc. The data on this sheet is related only to the specific material designated herein. West System Inc. assumes no legal responsibility for use or reliance upon these data.


West System Inc.

MSDS#403-13a Last Revised: 10OCT13


PRODUCT NAME: ............................................. WEST SYSTEM® 403 Microfibers.

PRODUCT CODE: ............................................. 403

CHEMICAL FAMILY: ......................................... Cotton flock.

CHEMICAL NAME: ........................................... Blend.

FORMULA: ........................................................ No information.




EMERGENCY OVERVIEW

WARNING Nuisance dust. Avoid excessive inhalation of airborne dust. White powder, no odor.

PRIMARY ROUTE(S) OF ENTRY: ..................................................... Inhalation.


ACUTE INHALATION: ........................................................................ If exposure limits are exceeded, the respiratory tract may become irritated.

May cause shortness of breath, coughing, and/or chest tightness due to temporarily physically overloading the lungs.

CHRONIC INHALATION: ................................................................... Repeated excessive inhalation could cause drying of the mucous

membranes of the respiratory tract.

ACUTE SKIN CONTACT: ................................................................... May cause temporary irritation and drying of the skin.

CHRONIC SKIN CONTACT:............................................................... Prolonged contact may cause dermatitis due to drying of the skin.

EYE CONTACT: ................................................................................. May cause irritation seen as redness and tearing.

INGESTION: ....................................................................................... No information.

SYMPTOMS OF OVEREXPOSURE: .................................................. Irritation of the respiratory tract, sneezing, coughing. Dry, chapped skin.

Redness and tearing of the eyes.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: ............... Skin or respiratory conditions, such as asthma and dermatitis.


INGREDIENT NAME CAS# CONCENTRATION (%)

Cotton flock (natural substance) NA 70-90 Fumed Amorphous Silica 112945-52-5 10-30


FIRST AID FOR EYES: ...................................................................... Flush adequately with water to remove particles. If discomfort persists,

seek medical advice.

FIRST AID FOR SKIN: ....................................................................... Wash with soap and water. Apply moisturizing cream to replenish

moisture in the skin if necessary.

FIRST AID FOR INHALATION: .......................................................... Remove to fresh air if effects occur. If effects persists, seek medical

advice.

FIRST AID FOR INGESTION: ............................................................ No specific information.




FLASH POINT: ................................................................................... No data.

EXTINGUISHING MEDIA: .................................................................. Water, dry powder or carbon dioxide (CO2).

SPECIAL FIRE FIGHTING PROCEDURES: ....................................... When excessive flock dust becomes airborne, a moderate explosion

hazard is created. Ignitable. Once ignited, builds pressure at a substantial rate.


SPILL OR LEAK PROCEDURES: ...................................................... Sweep and shovel or use properly grounded vacuum equipment. Do so in

a manner that minimizes airborne dust.


STORAGE TEMPERATURE (min./max.): .......................................... 0°F (-17°C)/100°F (38°C)

STORAGE: ......................................................................................... Keep dry.

HANDLING PRECAUTIONS: ............................................................. Avoid generating excessive airborne material when handling. Properly

ground all material handling equipment to prevent static discharge.


EYE PROTECTION GUIDELINES: ..................................................... Safety glasses or goggles are recommended, depending on the expected

level of exposure.

SKIN PROTECTION GUIDELINES:.................................................... Areas expected to have repeated exposure, such as hands, may need to

be protected by an impervious material to prevent dryness. Barrier creams can be used effectively.

RESPIRATORY/VENTILATION GUIDELINES: .................................. Work environments should be maintained below applicable exposure level

through the use of engineering controls, such as dilution and exhaust ventilation. If this is not feasible, use a NIOSH approved dust mask/respirator for nuisance dust.

ADDITIONAL PROTECTIVE MEASURES:......................................... Practice good industrial hygiene by washing with soap and water after

each use. Apply moisturizing cream to replenish moisture to skin if necessary. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ............................................. This product should be treated as a nuisance dust. Refer to OSHA’s

Permissible Exposure Level (PEL) or the ACGIH Guidelines for information on specific ingredients.


PHYSICAL FORM .............................................................................. Powder.

COLOR ............................................................................................... Off-white.

ODOR ................................................................................................. Odorless.

BOILING POINT ................................................................................. No data.


pH ....................................................................................................... No data.

SOLUBILITY IN WATER .................................................................... Insoluble.



VAPOR PRESSURE ........................................................................... Not applicable.

VAPOR DENSITY ............................................................................... Not applicable.

% VOLATILE BY WEIGHT ................................................................. Zero.




INCOMPATIBILITIES: ........................................................................ None known. This product is inert.

DECOMPOSITION PRODUCTS: ........................................................ Can include carbon monoxide (CO) and carbon dioxide (CO2).


No toxic effects are expected from this product.



CARCINOGENICITY:

NTP ............................................................................................ No. IARC........................................................................................... No. OSHA ......................................................................................... No. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or IARC.


No specific information.


WASTE DISPOSAL METHOD: This material is determined not to be a hazardous waste as per RCRA standards, either by listing or

characteristics. Disposer must comply with all federal, state and local laws. Landfill is the preferred disposal method.


DOT Non-Bulk:

SHIPPING NAME: .............................................................................. Not regulated. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ............................................................................... Not applicable U.N./N.A. NUMBER: ........................................................................... Not applicable PACKING GROUP: ............................................................................. Not applicable

ICAO/IATA


IMDG


15. REGULATORY INFORMATION:

OSHA STATUS: ................................................................................. Hazardous. Nuisance dust. Ignitable explosion hazard in airborne dust/air

mixtures.

TSCA STATUS: .................................................................................. All components of this product are in compliance with TSCA Inventory

requirements.

Canada WHMIS Classification:......................................................... No data.

SARA TITLE III:

SECTION 313 TOXIC CHEMICALS ........................................... None.



COMPONENT NAME

/CAS NUMBER CONCENTRATION (%) STATE CODE

Amorphous Silica 112945-52-5 MA, NJ, RI


REASON FOR ISSUE: ....................................................................... Changes made in Sections 3.




APPROVAL DATE: ............................................................................ October 10, 2013




MSDS NUMBER: ................................................................................ 403-13a



West System Inc.

MSDS #206-13a Last Revised: 26APR13


PRODUCT NAME: ............................................. WEST SYSTEM® 206 Slow Hardener

PRODUCT CODE: ............................................. 206

CHEMICAL FAMILY: ......................................... Amine.

CHEMICAL NAME: ........................................... Modified aliphatic polyamine.

FORMULA: ........................................................ Not applicable.




EMERGENCY OVERVIEW

DANGER Causes burns to eyes and skin. Harmful if swallowed. Harmful if absorbed through the skin. May be harmful if inhaled. Can cause allergic reaction. Aspiration hazard. Clear liquid with ammonia odor.

PRIMARY ROUTE(S) OF ENTRY: ..................................................... Skin and eye contact, inhalation.


ACUTE INHALATION: ........................................................................ Excessive exposure to vapor or mist is irritating to the upper respiratory

tract, causing nasal discharge, coughing, and discomfort in eyes, nose, throat and chest. Severe cases may cause difficult breathing and lung damage.

CHRONIC INHALATION: ................................................................... May cause lung damage. May cause respiratory sensitization in

susceptible individuals. Repeated exposures may cause internal organ damage.

ACUTE SKIN CONTACT: ................................................................... Corrosive. Prolonged contact may cause skin damage with burns and

blistering. Wide spread contact may result in material being absorbed in harmful amounts.

CHRONIC SKIN CONTACT:............................................................... May cause persistent irritation or dermatitis. Repeated contact may cause

allergic reaction/sensitization and possible tissue destruction. Can be absorbed through the skin in amounts that can cause internal organ damage.

EYE CONTACT: ................................................................................. Corrosive. May cause blurred vision. May cause irritation with corneal

injury resulting in permanent vision impairment or even blindness.

INGESTION: ....................................................................................... Moderately toxic. May cause gastrointestinal irritation or ulceration. May

cause burns of the mouth and throat. Aspiration hazard.

SYMPTOMS OF OVEREXPOSURE: .................................................. Skin irritation, burns and blistering. Irritation of the nose and throat,

possible headache. Eye irritation and blurred vision.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: ............... Existing respiratory conditions, such as asthma and bronchitis. Existing

skin conditions.


INGREDIENT NAME CAS # CONCENTRATION (%)

Polyoxypropylenediamine 9046-10-0 30-50 Polymer of epichlorohydrin, bisphenol-A, and diethylenetriamine 31326-29-1 10-30 Tetraethylenepentamine 112-57-2 10-30 Diethylenetriamine 111-40-0 5-20 Reaction products of triethylenetetramine and propylene oxide 26950-63-0 5-20 Triethylenetetramine 112-24-3 1-10


West System Inc. Page 2 of 4 WEST SYSTEM® 206 Hardener


FIRST AID FOR EYES: ...................................................................... Immediately flush with water for at least 15 minutes. Get prompt medical

attention.

FIRST AID FOR SKIN: ....................................................................... Remove contaminated clothing. Immediately wash skin with soap and

water. Do not apply greases or ointments. Get medical attention if severe exposure.

FIRST AID FOR INHALATION: .......................................................... Move to fresh air and consult physician if effects occur.

FIRST AID FOR INGESTION: ............................................................ Give conscious person at least 2 glasses of water. Do not induce

vomiting. Aspiration hazard. If vomiting should occur spontaneously, keep airway clear. Get medical attention.


FLASH POINT: ................................................................................... > 200°F (Open Cup)

EXTINGUISHING MEDIA: .................................................................. Dry chemical, alcohol foam. carbon dioxide (CO2), dry sand, limestone

powder.

FIRE AND EXPLOSION HAZARDS: .................................................. Burning can generate toxic fumes. Products of combustion may include,

but not liminted to: oxides of nitrogen, volatile amines, ammonia, nitric acid, nitrosamines. When mixed with sawdust, wood chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. If hardener is spilled into or mixed with sawdust, heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Use full-body protective gear and a self-contained breathing apparatus.

Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.


SPILL OR LEAK PROCEDURES: ...................................................... Stop leak without additional risk. Wear proper personal protective

equipment. Dike and contain spill. Ventilate area. Large spill - dike and pump into appropriate container for recovery. Small spill - recover or use inert, non-combustible absorbent material (e.g., sand, clay) and shovel into suitable container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as the possibility for spontaneous combustion exists. Wash spill residue with warm, soapy water if necessary.


STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 90°F (32°C).

STORAGE: ......................................................................................... Store in cool, dry place with adequate ventilation.

HANDLING PRECAUTIONS: ............................................................. Use only with adequate ventilation. Do not breath vapors or mists from

heated material. Avoid contact with skin and eyes. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.


EYE PROTECTION GUIDELINES: ..................................................... Chemical splash goggles, full-face shield or full-face respirator.

SKIN PROTECTION GUIDELINES:.................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,

butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY/VENTILATION GUIDELINES: .................................. General mechanical or local exhaust ventilation. With inadequate

ventilation, use a NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge. Note: West System, Inc. has conducted an air sampling study using this product or similarly formulated products. The results indicate that the components sampled for (amines) were either so low that they were not detected at all or they were well below OSHA’s permissible exposure levels.

ADDITIONAL PROTECTIVE MEASURES:......................................... Use where there is immediate access to safety shower and emergency eye

wash. Provide proper wash/cleanup facilities for proper hygiene. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ............................................. Not established for product as whole. Refer to OSHA’s Permissible

Exposure Level (PEL) or the ACGIH Guidelines for information on specific ingredients.


PHYSICAL FORM .............................................................................. Liquid.



COLOR ............................................................................................... Light-yellow.

ODOR ................................................................................................. Ammonia-like.

BOILING POINT ................................................................................. > 480°F.


pH ....................................................................................................... 11.4

SOLUBILITY IN WATER .................................................................... Appreciable.



VAPOR PRESSURE ........................................................................... < 1 mmHg @ 20°C.

VAPOR DENSITY ............................................................................... Heavier than air.

VISCOSITY......................................................................................... 200 cPs

% VOLATILE BY WEIGHT ................................................................. ASTM 2369-07 was used to determine the Volatile Matter Content of

mixed epoxy resin and hardener. 105 Resin and 206 Hardener, mixed together at 5:1 by weight, has a density of 1176 g/L (9.81 lbs/gal). The combined VOC content for 105/206 is 9.59 g/L (0.08 lbs/gal).




INCOMPATIBILITIES: ........................................................................ May react violently when in contact with oxidizing materials, acids or

halogenated compounds such as methylene chloride. Reactions may be slow initially, then may rapidly generate heat and vapor pressure.

DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned. Decomposition products may

include, but not liminted to: oxides of nitrogen, volatile amines, ammonia, nitric acid, nitrosamines.


No specific oral, inhalation or dermal toxicology data is known for this product. Oral: ................................................................... Expected to be moderately toxic. Inhalation: .......................................................... Expected to be moderately toxic. Dermal: .............................................................. Expected to be moderately toxic.

CARCINOGENICITY:



In the non-cured liquid form this product may be harmful if released to the environment. Do not allow into sewers, on the ground or in any body of water.


WASTE DISPOSAL METHOD: .......................................................... Evaluation of this product using RCRA criteria shows that it is not a

hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.


DOT Non-Bulk

SHIPPING NAME: .............................................................................. Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Polyoxypropylenediamine. HAZARD CLASS: ............................................................................... Class 8 U.N./N.A. NUMBER: ........................................................................... UN 2735 PACKING GROUP: ............................................................................. PG II

ICAO/IATA

SHIPPING NAME: .............................................................................. Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Polyoxypropylenediamine HAZARD CLASS: ............................................................................... Class 8 U.N. NUMBER: ................................................................................... UN 2735 PACKING GROUP: ............................................................................. PG II MARINE POLLUTANT: ....................................................................... No



IMDG

SHIPPING NAME: .............................................................................. Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Polyoxypropylenediamine HAZARD CLASS: ............................................................................... Class 8 U.N. NUMBER: ................................................................................... UN 2735 PACKING GROUP: ............................................................................. PG II EmS: ................................................................................................... F-A, S-B MARINE POLLUTANT: ....................................................................... No


OSHA STATUS: ................................................................................. Corrosive; possible sensitizer.

TSCA STATUS: .................................................................................. All components are listed on TSCA inventory or otherwise comply with

TSCA requirements.

CANADA WHMIS CLASSIFICATION: ................................................ D2A – Very toxic material causing other toxic effects. E – Corrosive.


requirements.

SARA TITLE III:

SECTION 313 TOXIC CHEMICALS: .......................................... None.



COMPONENT NAME STATE CODE

Tetraethylenepentamine 112-57-2 RI, MA, NJ, PA Tetraethylenetriamine 112-24-3 RI, MA, NJ, PA Diethylenetriamine 111-40-0 RI, MA, NJ, PA


REASON FOR ISSUE: ....................................................................... Changes made in Section 2, 3 and 14.






MSDS NUMBER: ................................................................................ 206-13a



West System Inc.



PRODUCT NAME: ............................................. WEST SYSTEM® 205 Fast Hardener

PRODUCT CODE: ............................................. 205

CHEMICAL FAMILY: ......................................... Amine.

CHEMICAL NAME: ........................................... Modified aliphatic polyamine.

FORMULA: ........................................................ Not applicable.




EMERGENCY OVERVIEW

DANGER Causes burns to eyes and skin. Harmful if swallowed. Harmful if absorbed through the skin. May be harmful if inhaled. May cause allergic reaction. Amber colored liquid with ammonia odor.

PRIMARY ROUTE(S) OF ENTRY: ..................................................... Skin contact, eye contact, inhalation.


ACUTE INHALATION: ........................................................................ May cause respiratory tract irritation. Coughing and chest pain may result.

CHRONIC INHALATION: ................................................................... May cause respiratory tract irritation, coughing, sore throat, shortness of

breath or chest pain.

ACUTE SKIN CONTACT: ................................................................... May cause strong irritation, redness. Possible mild corrosion.

CHRONIC SKIN CONTACT:............................................................... Prolonged or repeated contact may cause an allergic reaction and possible

sensitization in susceptible individuals. Large dose skin contact may result in material being absorbed in harmful amounts.

EYE CONTACT: ................................................................................. Moderate to severe irritation with possible tissue damage. Concentrated

vapors can be absorbed in eye tissue and cause eye injury. Contact causes discomfort and possible corneal injury or conjunctivitis.

INGESTION: ....................................................................................... Single dose oral toxicity is moderate. May cause gastrointestinal tract

irritation and pain. Aspiration hazard.

SYMPTOMS OF OVEREXPOSURE: .................................................. Respiratory tract irritation. Skin irritation and redness. Possible allergic

reaction seen as hives and rash. Eye irritation. Possible liver and kidney disorders upon long term skin absorption overexposures.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: ............... Chronic respiratory disease, asthma. Eye disease. Skin disorders and

allergies.


INGREDIENT NAME CAS # CONCENTRATION (%)

Reaction products of triethylnetetramine with phenol/formaldehyde 32610-77-8 40-70 Polyethylenepolyamines 68131-73-7 10-30 Triethylenetetramine 112-24-3 5-20 Hydroxybenzene 108-95-2 1-10 Reaction products of triethylenetetramine and propylene oxide 26950-63-0 1-10 Tetraethylenepentamine 112-57-2 1-10


FIRST AID FOR EYES: ...................................................................... Immediately flush with water for at least 15 minutes. Get prompt medical

attention.

FIRST AID FOR SKIN: ....................................................................... Remove contaminated clothing. Immediately wash skin with soap and

water. Do not apply greases or ointments. Get medical attention if severe exposure.



FIRST AID FOR INHALATION: .......................................................... Move to fresh air and consult physician if effects occur.

FIRST AID FOR INGESTION: ............................................................ Give conscious person at least 2 glasses of water. Do not induce

vomiting. If vomiting should occur spontaneously, keep airway clear. Get medical attention.


FLASH POINT: ................................................................................... >270°F (PMCC)

EXTINGUISHING MEDIA: .................................................................. Dry chemical, alcohol foam. carbon dioxide (CO2), dry sand, limestone

powder.

FIRE AND EXPLOSION HAZARDS: .................................................. During a fire, smoke may contain the original materials in addition to

combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, nitrosamines. When mixed with sawdust, wood chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Use full-body protective gear and a self-contained breathing apparatus.

Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.


SPILL OR LEAK PROCEDURES: ...................................................... Stop leak without additional risk. Wear proper personal protective

equipment. Dike and contain spill. Ventilate area. Large spill - dike and pump into appropriate container for recovery. Small spill - recover or use inert, non-combustible absorbent material (e.g., sand, clay) and shovel into suitable container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as the possibility for spontaneous combustion exists. Wash spill residue with warm, soapy water if necessary.


STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 90°F (32°C).

STORAGE: ......................................................................................... Store in cool, dry place away from high temperatures and moisture. Keep

container tightly closed.

HANDLING PRECAUTIONS: ............................................................. Use with adequate ventilation. Do not breath vapors or mists from heated

material. Avoid exposure to concentrated vapors. Avoid skin contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.


EYE PROTECTION GUIDELINES: ..................................................... Chemical splash-proof goggles or face shield.

SKIN PROTECTION GUIDELINES:.................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,

butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY/VENTILATION GUIDELINES: .................................. Use with adequate general and local exhaust ventilation to meet exposure

limits. In poorly ventilated areas, use a NIOSH/MSHA approved respirator with an organic vapor cartridge. Note: West System, Inc. has conducted an air sampling study using this product or similarly formulated products. The results indicate that the components sampled for (phenol, formaldehyde and amines) were either so low that they were not detected at all or they were well below OSHA’s permissible exposure levels.

ADDITIONAL PROTECTIVE MEASURES:......................................... Use where there is immediate access to safety shower and emergency eye

wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ............................................. Not established for product as whole. Refer to OSHA’s Permissible

Exposure Level (PEL) or the ACGIH Guidelines for information on specific ingredients.


PHYSICAL FORM .............................................................................. Liquid.

COLOR ............................................................................................... Amber.

ODOR ................................................................................................. Ammonia-like.

BOILING POINT ................................................................................. > 440°F.

MELTING POINT/FREEZE POINT ..................................................... Approximately 23°F.

pH ....................................................................................................... Alkaline.



SOLUBILITY IN WATER .................................................................... Appreciable.



VAPOR PRESSURE ........................................................................... < 1 mmHg @ 20°C.

VAPOR DENSITY ............................................................................... Heavier than air.

VISCOSITY......................................................................................... 1,000 cPs

% VOLATILE BY WEIGHT ................................................................. ASTM 2369-07 was used to determine the Volatile Matter Content of

mixed epoxy resin and hardener. 105 Resin and 205 Hardener, mixed together at 5:1 by weight, has a density of 1137 g/L (9.49 lbs/gal). The combined VOC content for 105/205 is 7.91 g/L (0.07 lbs/gal).




INCOMPATIBILITIES: ........................................................................ Avoid excessive heat. Avoid acids, oxidizing materials, halogenated

organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and serious hazard. If such a reaction were to take place in a waste drum, the drum could expand and rupture violently.

DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to

decomposition. Decomposition products may include, but not liminted to: oxides of nitrogen, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines.


No specific oral, inhalation or dermal toxicology data is known for this product. Oral: ................................................................... Expected to be moderately toxic. Inhalation: .......................................................... Expected to be moderately toxic. Dermal: .............................................................. Expected to be moderately toxic. Adsorption of phenolic solutions through the skin may be very rapid and can cause death. Lesser exposures can cause damage to the kidney, liver, pancreas and spleen; and cause edema of the lungs. Chronic exposures can cause death from liver and kidney damage.

CARCINOGENICITY:



In the non-cured, liquid form, this product may be harmful if released to the environment. Do not allow into sewers, on the ground or in any body of water.


WASTE DISPOSAL METHOD: .......................................................... Evaluation of this product using RCRA criteria shows that it is not a

hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.


DOT Non-Bulk

SHIPPING NAME: .............................................................................. Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Triethylenetetramine HAZARD CLASS: ............................................................................... Class 8 U.N./N.A. NUMBER: ........................................................................... UN 2735 PACKING GROUP: ............................................................................. PG III MARINE POLLUTANT: ....................................................................... No

ICAO/IATA

SHIPPING NAME: .............................................................................. Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Triethylenetetramine HAZARD CLASS: ............................................................................... Class 8 U.N. NUMBER: ................................................................................... UN 2735 PACKING GROUP: ............................................................................. PG III



MARINE POLLUTANT: ....................................................................... No

IMDG

SHIPPING NAME: .............................................................................. Polyamines, liquid, corrosive, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Triethylenetetramine HAZARD CLASS: ............................................................................... Class 8 U.N. NUMBER: ................................................................................... UN 2735 PACKING GROUP: ............................................................................ PG III EmS Number: .................................................................................... F-A, S-B MARINE POLLUTANT ........................................................................ No


OSHA STATUS: ................................................................................. Corrosive; possible sensitizer.

TSCA STATUS: .................................................................................. All components listed on TSCA inventory or otherwise comply with TSCA

requirements.

Canada WHMIS Classification: ......................................................... D2A – Very toxic material causing other toxic effects; E – Corrosive


requirements.

SARA TITLE III:

SECTION 313 TOXIC CHEMICALS: .......................................... This product contains hydroxybenzene (phenol) and is subject to the

reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.



COMPONENT NAME

/CAS NUMBER CONCENTRATION STATE CODE

Tetraethylenepentamine 112-57-2 MA, NJ, PA Tetraethylenetriamine 112-24-3 MA, NJ, PA Phenol 108-95-2 NJ, RI, PA, MA, IL


REASON FOR ISSUE: ....................................................................... Changes made in Sections 5, 10, 14 & 15.






MSDS NUMBER: ................................................................................ 205-13a



West System Inc.



PRODUCT NAME: ............................................. WEST SYSTEM® 105 Epoxy Resin PRODUCT CODE: ............................................. 105 CHEMICAL FAMILY: ......................................... Epoxy Resin. CHEMICAL NAME:............................................ Bisphenol A based epoxy resin. FORMULA: ........................................................ Not applicable. MANUFACTURER: EMERGENCY TELEPHONE NUMBERS: West System Inc. Transportation 102 Patterson Ave. CHEMTREC: .................... 800-424-9300 (U.S.) Bay City, MI 48706, U.S.A. 703-527-3887 (International) Phone: 866-937-8797 or 989-684-7286 Non-transportation www.westsystem.com Poison Hotline: ................. 800-222-1222


EMERGENCY OVERVIEW

WARNING May cause skin irritation. May cause eye irritation. May cause allergic reaction. Clear, viscous liquid with mild odor.

PRIMARY ROUTE(S) OF ENTRY: ...................................................... Skin contact. POTENTIAL HEALTH EFFECTS: ACUTE INHALATION: ........................................................................ If product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations. CHRONIC INHALATION: ................................................................... Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of developing allergy symptoms to this product. ACUTE SKIN CONTACT: ................................................................... May cause allergic skin response in certain individuals. May cause moderate irritation to the skin such as redness and itching. CHRONIC SKIN CONTACT: ............................................................... May cause sensitization in susceptible individuals. May cause moderate irritation to the skin. EYE CONTACT: ................................................................................. May cause irritation. INGESTION: ....................................................................................... Low acute oral toxicity. SYMPTOMS OF OVEREXPOSURE: .................................................. Possible sensitization and subsequent allergic reactions usually seen as redness and rashes. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: ................ Pre-existing skin and respiratory disorders may be aggravated by exposure to this product. Pre-existing lung and skin allergies may increase the chance of developing allergic symptoms to this product.


INGREDIENT NAME CAS # CONCENTRATION (%) Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-100 Benzyl alcohol 100-51-6 10-30 Phenol-formaldehyde polymer glycidyl ether 28064-14-4 1-10


FIRST AID FOR EYES ........................................................................ Flush immediately with water for at least 15 minutes. Consult a physician. FIRST AID FOR SKIN ......................................................................... Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and water. Consult a physician if effects occur. FIRST AID FOR INHALATION............................................................ Remove to fresh air if effects occur. FIRST AID FOR INGESTION .............................................................. No acute adverse health effects expected from amounts ingested under normal conditions of use. Seek medical attention if a significant amount is ingested.

West System Inc. Page 2 of 4 WEST SYSTEM® 105 Resin



FLASH POINT: ................................................................................... >200°F (Tag Closed Cup) EXTINGUISHING MEDIA: .................................................................. Foam, carbon dioxide (CO2), dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: ....................................... Wear a self-contained breathing apparatus and complete full-body personal protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat. FIRE AND EXPLOSION HAZARDS: .................................................. During a fire, smoke may contain the original materials in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: phenolics, carbon monoxide, carbon dioxide.


SPILL OR LEAK PROCEDURES: ...................................................... Stop leak without additional risk. Dike and absorb with inert material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.


STORAGE TEMPERATURE (min./max.): .......................................... 40°F (4°C) / 120°F (49°C) STORAGE: ......................................................................................... Store in cool, dry place. Store in tightly sealed containers to prevent moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin. HANDLING PRECAUTIONS: ............................................................. Avoid prolonged or repeated skin contact. Wash thoroughly after handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.


EYE PROTECTION GUIDELINES: ..................................................... Safety glasses with side shields or chemical splash goggles. SKIN PROTECTION GUIDELINES: .................................................... Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene, butyl rubber or natural rubber) and full body-covering clothing. RESPIRATORY/VENTILATION GUIDELINES: ................................... Good room ventilation is usually adequate for most operations. Wear a NIOSH/MSHA approved respirator with an organic vapor cartridge whenever exposure to vapor in concentrations above applicable limits is likely. Note: West System, Inc. has conducted an air sampling study using this product or similarly formulated products. The results indicate that the components sampled for (epichlorohydrin, benzyl alcohol) were either so low that they were not detected at all or they were significantly below OSHA’s permissible exposure levels. ADDITIONAL PROTECTIVE MEASURES: ......................................... Practice good caution and personal cleanliness to avoid skin and eye contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions. OCCUPATIONAL EXPOSURE LIMITS: ............................................. Not established for product as whole. Refer to OSHA’s Permissible Exposure Level (PEL) or the ACGIH Guidelines for information on specific ingredients.


PHYSICAL FORM: ............................................................................. Liquid. COLOR: ............................................................................................. Clear. ODOR: ................................................................................................ Mild. BOILING POINT: ................................................................................ > 400°F MELTING POINT/FREEZE POINT: ..................................................... No data. VISCOSITY: ........................................................................................ 1000 (cP) pH: ..................................................................................................... No data. SOLUBILITY IN WATER: ................................................................... Slight. SPECIFIC GRAVITY: .......................................................................... 1.15 BULK DENSITY: ................................................................................ 9.6 (pounds/gallon) VAPOR PRESSURE: .......................................................................... < 1 mmHg @ 20°C. VAPOR DENSITY: .............................................................................. Heavier than air. % VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener's MSDS for information about the total volatile content of the resin/hardener system.





HAZARDOUS POLYMERIZATION: .................................................... Will not occur by itself, but a mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition.


No specific oral, inhalation or dermal toxicology data is known for this product. Specific toxicology information for a bisphenol-A based epoxy resin present in this product is indicated below: Oral: ................................................................... LD50 >5000 mg/kg (rats) Inhalation: .......................................................... No Data. Dermal: .............................................................. LD50 = 20,000 mg/kg (skin absorption in rabbits) TERATOLOGY: ................................................. ………………Diglycidyl ether bisphenol-A (DGEBPA) did not cause birth defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally. REPRODUCTIVE EFFECTS: ............................. ……………….DGEBPA, in animal studies, has been shown not to interfere with reproduction. MUTAGENICITY: ............................................... ………………..DGEBPA in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in others. CARCINOGENICITY:

NTP ............................................................................................ Product not listed. IARC ........................................................................................... Product not listed. OSHA ......................................................................................... Product not listed. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or IARC. Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that DGEBPA is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has concluded that DGEBPA is not classified as a carcinogen. Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence – inadequate; animal evidence – sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance.


In the non-cured liquid form this product may cause long-term harm if released to the environment. Prevent entry into sewers and natural waters. Movement and Partitioning:

Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Kow between 3 and 5). Degradation and Transformation:

Theoretical oxygen demand is calculated to be 2.35 p/p. 20-day biochemical oxygen demand is <2.5%. Ecotoxicology:

Material is moderately toxic to aquatic organisms on an acute basis. LC50/EC50 between 1 and 10 mg/L in most sensitive species.


WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.


DOT Non-Bulk SHIPPING NAME: ............................................................................... Not regulated. TECHNICAL SHIPPING NAME: .......................................................... Not applicable.



HAZARD CLASS: ................................................................................ Not applicable. U.N./N.A. NUMBER:............................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. IMDG SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. U.N. NUMBER: ................................................................................... UN3082. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes ICAO/IATA SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. U.N. NUMBER: ................................................................................... UN3082. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes


OSHA STATUS: ................................................................................. Irritant. TSCA STATUS: .................................................................................. All components are listed on TSCA inventory or otherwise comply with TSCA requirements. Canada WHMIS Classification: ......................................................... D2B - Toxic material causing other toxic effects. CEPA Chemical Inventory Status: .................................................... All components are listed or are otherwise compliant with CEPA requirements. SARA TITLE III: SECTION 313 TOXIC CHEMICALS ........................................... None (deminimus). STATE REGULATORY INFORMATION: The following chemicals are specifically listed or otherwise regulated by individual states. For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT NAME /CAS NUMBER CONCENTRATION STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1CA Benzyl alcohol 100-51-6 MA, PA, NJ

1. These substances are known to the state of California to cause cancer or reproductive harm, or both.


REASON FOR ISSUE:........................................................................ Changes made in Section 14 and 15. PREPARED BY: ................................................................................. G. M. House APPROVED BY: ................................................................................. G. M. House TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ April 26, 2013 SUPERSEDES DATE: ........................................................................ March 9, 2012 MSDS NUMBER: ................................................................................ 105-13a


Material Safety Data Sheet

SECTION 1: Chemical Product and Company Identification Manufacturer: Vi-Jon, Inc. Date: January 2008 One Swan Drive Smyrna, TN 37167 Product: Isopropyl Alcohol (IPA) 50%, 70%, 91% and 99% IPA Telephone: (615) 459-8900 24hr Emergency: (615) 459-8900 ext. 5270 SECTION 2: Composition/Information on Ingredients Name: Isopropanol, CAS#: 67-63-0 Deionized Water CAS# 7732-18-5 SECTION 3: Hazards Identification Colorless, volatile liquid with the odor of rubbing alcohol. Isopropyl Alcohol is a dangerous fire risk. Prolonged exposure to elevated concentrations of vapors may result in irritation of the eyes, nose, and throat and central nervous system (CNS) depression. Prolonged dermal exposure can result in dry, cracking skin. Potential Routes of Exposure: Ingestion, inhalation, dermal contact, eye contact Target Organs: Eyes, skin, respiratory system Symptoms of Overexposure: Inhalation: Mild irritation of eyes, nose and throat. Ingestion: Drowsiness, headache Dermal Contact: Dry, cracking skin Acute Effects: Irritation of skin and/or upper respiratory tract as noted above.

Acute CNS depression may be manifested as giddiness, headache, dizziness and/or nausea.

Chronic Effects: Chronic exposure can result in skin irritation and contact dermatitis Pre-existing disorders of the skin, eyes, and respiratory tract may be exacerbated by exposure to isopropyl alcohol.

HMIS: H=1, F=3, R=0 See Section 8 for PPE information

SECTION 4: First Aid Measures Eye: Flush eyes with copious amount of water for at least 15 minutes Skin: Flush with water. If irritation persists, seek medical attention. Ingestion: Do not induce vomiting if victim is unconscious or drowsy. Seek medical attention or contact the poison control center. Inhalation: Remove victim to fresh air and provided oxygen if breathing is difficult. Seek

Medical attention if breathing continues to be difficult.

Isopropyl Alcohol MSDS Page 1 of 3

SECTION 5: Fire Fighting Measures Extinguishing Media: Use water fog, alcohol foam, dry chemical or CO2 Unusual Fire or Containers exposed to intense heat from fires should be Explosion Hazards: cooled with large amounts of water to prevent buildup of internal pressure

due to vapor generation which could result in container rupture. Recommendations: Clear area of unprotected personnel. Wear complete turnout gear. Cool

containers exposed to fire with water. SECTION 6: Accidental Release Measures

Large Spills: Eliminate all ignition sources. Equipment must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Contain source of spill. Dike or otherwise confine spilled product. Uncontrolled releases to air, land, or water may be reportable to the National Response Center (1-800-424-8802).

Small Spills: Take up with absorbent material and place in non-leaking container; seal tightly. ` Dispose of absorbent (see section 13)

SECTION 7: Handling and Storage Storage Requirements: Store in tightly closed containers in a cool, dry area away from heat and

other possible ignition sources. Handling precautions: Use non-sparking tools to open containers. Maintain appropriate class of

fire extinguishers nearby in case of fire. SECTION 8: Exposure Controls / Personal Protection OSHA PEL=400ppm* OSHA STEL=500ppm* IDLH= 2,000ppm* * 100% Isopropyl Alcohol

Recommended Engineering Controls: Use explosion-proof ventilation equipment as necessary to maintain airborne concentrations below the PEL.

Ground all containers to prevent static sparks during fluid transfers. Recommended Admin Controls: Train employees on the hazards of Isopropyl Alcohol PPE: Goggles, gloves, NIOSH approved respiratory protection required when above PEL/TWA

Recommended Hygiene Practices: Clean PPE and work clothing contaminated prior to reuse. After working with this product, be sure to wash before eating, smoking, drinking, or applying cosmetics.

SECTION 9: Physical and Chemical Properties Appearance: Colorless Liquid UEL: 12.7% LEL: 2% Odor: Mild Rubbing Alcohol Odor Threshold: 43ppm Water solubility: Miscible 50% IPA 70%IPA 91%IPA 99%IPA Vapor Pressure (@ 680F) approx. 29mm 23mm 33mm 33mm Specific Gravity .929 .878 .8185 .785 Boiling Point 176 0 F 176 0 F 180 0 F 181 0 F Flash Point (TAG Open Cup) 74.5 0 F 70.5 0 F 54 0 F 53 0 F Freezing Point -32--50 0 C -32--50 0 C -32--50 0 C -127 0 F Molecular Weight 47.5 47.5 47.5 60.1 Auto Ignition Temperature No Data No Data No Data 750 0 F

Isopropyl Alcohol MSDS Page 2 of 3

SECTION 10: Stability and Reactivity Stability: Stable Polymerization: Will not occur Incompatible Chem: Strong oxidizers, acetaldehyde, chlorine, ethylene oxide, acids, isocyanates Conditions to avoid: Heat, sparks, and open flame. Do not store in aluminum > 120oF Hazardous Products: CO and unidentified organic compounds may be formed of Decomposition SECTION 11: Toxicological Information LD50: 5,840 mg/kg (acute oral - rat); 13,000 mg/kg (acute dermal - rabbit) LD50: 16,000 ppm/8hr (inhalation - rat) Mutagenicity: Not Indicated LDlo : 5,000 mg/kg (oral - rabbit) Reproductive Effects: Not Indicated Carcinogenicity: Not identified as a carcinogen by OSHO, IARC, or NTP SECTION 12: Ecological Information Ecotoxicity: N/A Environmental Fate: N/A Soil Absorption/Mobility: Highly Mobile Environmental Degradation: Should be removed readily from soils and water by volatilization and biodegradation. SECTION 13: Disposal Considerations Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Disposal regulatory Requirements: Follow applicable Federal, state, and local regulations. Consider fuels blending as an alternative to incineration. SECTION 14: Transport Information DOT Shipping Name: Consumer Commodity ORM-D DOT Shipping Name (if Quantities larger than Consumer Commodity limits): Isopropanol DOT Packing Group: II DOT Hazard Class: 3 DOT Label: Flammable Liquid UN ID#: UN 1219 Other Regulated Materials –Domestic (ORM-D) – Not DOT regulated (49 CFR 173.144); Quantities not greater than 1 liter or 0.3 gallons and PGII may be shipped as ORM-D (49 CFR 173.150) as a consumer commodity (49 CFR 171.8).

SECTION 15: Regulatory Information RCRA Hazardous Waste Number/ Classification:D001 CERCLA Substance: N/A HAZARDOUS AIR POLUTANT (CAA): No

SARA 311/312 Codes: N/A SARA Toxic Chemical: Yes, (Strong manufacturing only) CERCLA Reportable Quantity: 10,000 lbs (Default) TSCA: The ingredients of this product are on the TSCA inventory. SECTION 16: Other Information Prepared by: Vi-Jon, Inc. Sources of Information: 29 CFR1910.1000; NIOSH Pocket Guide to Chemical Hazards; Occupational Health Guidelines for Chemical Hazards; NFPA Pocket Guide to Hazardous Materials. Disclaimer: While reasonable care has been taken to ensure the accuracy and completeness of the information regarding the material described herein, it is the purchaser’s responsibility to ensure the suitability of such information as it applies to the purchaser’s intended use of the material. Isopropyl Alcohol MSDS Page 3 of 3

Safety Data Sheet

Revision Number: 001.3 Issue date: 10/13/2014

IDH number: 1071248 Product name: Loctite Epoxy Heavy Duty Resin Page 1 of 5

1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite Epoxy Heavy Duty Resin IDH number: 1071248 Product type: 2-Component epoxy adhesive Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067

Telephone: +1 (800) 624-7767 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887


EMERGENCY OVERVIEW

WARNING: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY

SKIN IRRITATION 2

EYE IRRITATION 2A

SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work

clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves.

Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.

Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local

governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*

Epichlorohydrin-4,4'-isopropylidene diphenol resin

25068-38-6 > 90


* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.


Inhalation: Move to fresh air. If symptoms develop and persist, get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothes. If symptoms develop and persist, get medical attention.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15

minutes, and seek immediate medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. If symptoms develop and persist, get medical attention.

Symptoms: See Section 11.

Notes to physician: Treat symptomatically and supportively.


Extinguishing media: Water Spray

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray. Closed containers may

rupture (due to build up of pressure) when exposed to extreme heat.

Hazardous combustion products: Oxides of carbon. Irritating organic fragments.

6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental precautions: Wear appropriate protective equipment and clothing during clean-up. Prevent

further leakage or spillage if safe to do so. Do not allow product to enter sewer or waterways.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for

disposal. Dispose of according to Federal, State and local governmental regulations.


Handling: Do not breathe gas/fumes/vapor/spray. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container closed.

Storage: Store in original container until ready to use. Keep in a cool, well ventilated

area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


None None None None

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below

exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists.

Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Chemical resistant, impermeable gloves.


Physical state: Liquid Color: Translucent, Clear Odor: None Odor threshold: Not available. pH: Not available. Vapor pressure: 0.03 mm hg Boiling point/range: > 260.2 °C (> 500.4 °F) Melting point/ range: Not available. Specific gravity: 1.17 Vapor density: Not available. Flash point: > 249 °C (> 480.2 °F) Pensky Martens closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.10 % (value for resin and hardener together) Viscosity: Not available. Decomposition temperature: Not available.


Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition products:

Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.

Incompatible materials: Strong oxidizing agents. Strong bases. Strong acids. Amines.

Reactivity: Not available.

Conditions to avoid: Excessive heat. Store away from incompatible materials.


Relevant routes of exposure: Skin, Inhalation, Eyes


Potential Health Effects/Symptoms

Inhalation: Mild respiratory tract irritation. Skin contact: Allergic skin reaction. Moderate skin irritation. Itching. Redness. Eye contact: Moderate eye irritation. Redness. Ingestion: Not expected under normal conditions of use.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects


None Allergen, Irritant

Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen

(Specifically Regulated)


No No No


Ecological information: Harmful to aquatic organisms.


Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

International Air Transportation (ICAO/IATA)

Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrin resin)

Hazard class or division: 9 Identification number: UN 3082 Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin)

Hazard class or division: 9 Identification number: UN 3082 Packing group: III Marine pollutant: Bisphenol-A Epichlorhydrin resin

15. REGULATORY INFORMATION United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis


CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This

product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.


This safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.

Prepared by: Donna Houston, Regulatory Affairs Specialist

Issue date: 10/13/2014

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

Safety Data Sheet

Revision Number: 004.1 Issue date: 10/14/2014

IDH number: 1137985 Product name: Loctite Epoxy Heavy Duty Hardener Page 1 of 6

1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite Epoxy Heavy Duty Hardener IDH number: 1137985 Product type: Epoxy Hardener Item number: 193468 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067

Telephone: +1 (800) 624-7767 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887


EMERGENCY OVERVIEW

DANGER: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION.

HAZARD CLASS HAZARD CATEGORY

SKIN CORROSION 1B

SERIOUS EYE DAMAGE 1

SKIN SENSITIZATION 1

PICTOGRAM(S)


Prevention: Do not breathe vapors, mist, or spray. Wash thoroughly after handling. Contaminated work

clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection.

Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Immediately call a poison control center or physician. If skin irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse.

Storage: Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local

governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*


Poly[oxy(methyl-1,2-ethanediyl)], a-hydro-w-hydroxy-, ether with 2,2-bis(hydroxymethyl)-1,3-propanediol (4:1), 2-hydroxy-3-mercaptop

72244-98-5 60 - 100

N-Aminoethylpiperazine 140-31-8 5 - 10

Aliphatic Amines Unknown 5 - 10

2,4,6-Tris(dimethylaminomethyl)phenol 90-72-2 1 - 5

Silica, amorphous, fumed, crystal-free 112945-52-5 1 - 5

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.


Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove

contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get

medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Get medical attention.

Symptoms: See Section 11.

Notes to physician: Treat symptomatically and supportively.


Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray.

Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Amines.

6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental precautions: Remove all sources of ignition. Wear appropriate protective equipment and

clothing during clean-up. Prevent further leakage or spillage if safe to do so. Do not allow product to enter sewer or waterways.

Clean-up methods: Store in a closed container until ready for disposal. Absorb spill with inert

material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations.



Handling: Keep away from heat, spark and flame. Keep container closed. Avoid breathing vapors or mists of this product. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.

Storage: For safe storage, store at or below 37.8 °C (100°F)

Store in original container until ready to use. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


None None None None

N-Aminoethylpiperazine None None None None

Aliphatic Amines None None None None

2,4,6-Tris(dimethylaminomethyl)phenol None None None None

Silica, amorphous, fumed, crystal-free

10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA

Respirable fraction.

20 MPPCF TWA 0.8 mg/m3 TWA None None

Engineering controls: Use local ventilation if general ventilation is insufficient to maintain vapor

concentration below established exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists.

Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Chemical resistant, impermeable gloves.


Physical state: Liquid Color: Amber, Clear Odor: Amine, Mercaptan Odor threshold: Not available. pH: Not available. Vapor pressure: Not available. Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.04 Vapor density: Not available. Flash point: > 93 °C (> 199.4 °F) Tagliabue closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slightly soluble Partition coefficient (n-octanol/water): Not available. VOC content: 0.38 %; 3.7 g/l EPA Method 24 Viscosity: Not available. Decomposition temperature: Not available.



Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition products:

Oxides of nitrogen. Oxides of carbon. Amines.

Incompatible materials: This product may react with strong acids, bases and oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Excessive heat. Store away from incompatible materials.


Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: Respiratory tract burns. May cause respiratory tract irritation. May cause irritation to nose and throat. Lung damage.

Skin contact: May cause skin burns. Allergic skin reaction. May be harmful if absorbed through skin. Rash. Redness. Tissue damage.

Eye contact: Burns. Severe eye irritation. Redness. Tissue damage. Ingestion: May be harmful if swallowed. May cause burns of mouth and throat if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects


None No Records

N-Aminoethylpiperazine None Irritant, Corrosive, Allergen Aliphatic Amines None No Data

2,4,6-Tris(dimethylaminomethyl)phenol None Irritant, Allergen Silica, amorphous, fumed, crystal-free None Nuisance dust

Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen

(Specifically Regulated)


No No No

N-Aminoethylpiperazine No No No

Aliphatic Amines No No No

2,4,6-Tris(dimethylaminomethyl)phenol No No No

Silica, amorphous, fumed, crystal-free No No No


Ecological information: Not available.



Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: This product, if discarded directly, would be a characteristic RCRA corrosive waste (D002).

14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Amines, liquid, corrosive, n.o.s. (Aminoethylpiperazine, Aliphatic amines) Hazard class or division: 8 Identification number: UN 2735 Packing group: II

International Air Transportation (ICAO/IATA)

Proper shipping name: Amines, liquid, corrosive, n.o.s. (Aminoethylpiperazine, Aliphatic amines) Hazard class or division: 8 Identification number: UN 2735 Packing group: II

Water Transportation (IMO/IMDG)

Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (Aminoethylpiperazine, Aliphatic amines) Hazard class or division: 8 Identification number: UN 2735 Packing group: II

15. REGULATORY INFORMATION United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis

California Proposition 65: No California Proposition 65 listed chemicals are known to be present.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.


This safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.

Prepared by: Gary Pierson, Manager, Regulatory Affairs

Issue date: 10/14/2014


DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

SAFETY DATA SHEET

Issuing Date 11-Nov- 2014 Revision Date 11-Nov-2014 Revision Number 1

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Product identifier

Product SDS Name Steel Reinforced Epoxy Resin – Twin Tubes - Part A

J-B Weld FG SKU Part Numbers Covered

8265, 8265F, 8276, 8276F, 8265S, 8265A, 8265H, 8272, 8272F, 8280, 8280F, 8281, 80165, 7265S, 7280,

8276A, 8273H, 8270, 8270F, 8271, 80176, 7276, 7270

J-B Weld Product Names Covered

J-B Weld™ (all Twin Tubes), KwikWeld™ (all Twin Tubes), MarineWeld™ (Twin Tubes Only)

J-B Weld Product Type

Steel Reinforced Epoxy

Recommended use of the chemical and restrictions on use

Recommended Use General Purpose Adhesive

Uses advised against No information available

Details of the supplier of the safety data sheet

Supplier Name J-B WELD COMPANY,LLC Supplier Address 1130 COMO ST

SULPHUR SPRINGS, TX 75482 USA

Emergency Telephone Numbers Transportation Emergencies: Chemtrec (24 hour transportation emergency response info): 800-424-9300 or 703-527-3887

Poison/Medical Emergencies: Poison Control Centers (24 hour emergency poison / medical response info): 800-222-1222

Supplier Email Supplier Phone Number

[email protected] 903-885-7696

2. HAZARDS IDENTIFICATION OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200). Classification of the substance or mixture GHS label elements

SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B SKIN SENSITIZATION - Category 1

Hazard pictograms Signal word Warning! Hazard statements

Causes skin and eye irritation. May cause an allergic skin reaction.

mailto:[email protected]

_____________________________________________________________________________________________

Page 2 / 11

Precautionary statements Prevention Wear protective gloves. Wear eye or face protection. Avoid breathing dust. Wash

hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage Not applicable.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture Mixture

Ingredient name % by weight CAS number

reaction product: bisphenol-A-(epichlorhydrin); epoxy resin 10 - 30 25068-38-6 crystalline silica non-respirable 0.1 - 1 14808-60-7 carbon black respirable 0.1 - 1 1333-86-4

Occupational exposure limits, if available, are listed in Section 8.

4. FIRST AID MEASURES Description of necessary first aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is

irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be

dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse

health effects persist or are severe. If unconscious, place in recovery position and get medical attention

immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing

thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical

attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean

shoes thoroughly before reuse.

Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove

any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position

comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small

quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce

vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that

vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give

anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention


Most important symptoms/effects, acute and delayed

Potential acute health effects

Inhalation No known significant effects or critical hazards.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Eye contact Causes serious eye irritation.

Ingestion Irritating to mouth, throat and stomach.

_____________________________________________________________________________________________

Page 3 / 11

Over-exposure signs/symptoms Inhalation No specific data.

Skin contact Adverse symptoms may include the following: irritation redness

Eye contact Adverse symptoms may include the following: pain or irritation watering redness

Ingestion No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have

been ingested or inhaled.

Specific treatments No specific treatment.

See toxicological information (Section 11)

5. FIRE-FIGHTING MEASURES Extinguishing media

Suitable extinguishing

media

Unsuitable extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

None known.

Specific hazards arising No specific fire or explosion hazard. from the chemical

National Fire Protection Association (U.S.A.)

Flammability

Instability/Reactivity

Special Hazardous thermal

decomposition products

Special protective actions

for fire-fighters

Special protective equipment for fire-fighters

Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds metal oxide/oxides

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

0 1

2 Health

_____________________________________________________________________________________________

Page 4 / 11


Personal precautions, protective

equipment and emergency procedures

For non-emergency personnel

For emergency responders

Environmental precautions

Methods and materials for containment and cleaning up

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Small spill

Large spill

Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.


Conditions for safe storage, including

any incompatibilities

Precautions for safe handling

Protective measures

Advice on general occupational hygiene

Do not store below the following temperature: 35°C (95°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

_____________________________________________________________________________________________

Page 5 / 11


Control parameters

Occupational exposure limits

Ingredient name CAS # Exposure limits

crystalline silica non-respirable 14808-60-7 OSHA PEL Z3 (United States, 9/2005). Notes: 250/(%SiO2+5) TWA: 250 MPPCF / (%SiO2+5) 8 hours. Form: Respirable OSHA PEL Z3 (United States, 9/2005). Notes: 10/(SiO2+2) TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form: Respirable ACGIH TLV (United States, 3/2012). TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 1/2013). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust OSHA PEL Z3 (United States, 9/2005). Notes: 30/(%SiO2+2) TWA: 30 MG/M3 / (%SiO2+2) 8 hours. Form: Total dust.

carbon black respirable 1333-86-4 OSHA PEL 1989 (United States, 3/1989). TWA: 3.5 mg/m³ 8 hours. ACGIH TLV (United States, 6/2013). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013).

TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 3.5 mg/m³ 8 hours.

Appropriate engineering controls

No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Skin protection

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

_____________________________________________________________________________________________

Page 6 / 11

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases, or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.


Physical state

Color

Odor

Odor threshold

pH

Melting point

Boiling point

Flash point

Evaporation rate

Solid.

Black. [Dark]

Ethereal. [Slight]

Not available.

Not available. Not available.

Not available.

Closed cup: >93.3°C (>199.9°F) [Setaflash.] [Product does not sustain combustion.] Not available.

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Vapor pressure

Vapor density

Relative density

Solubility

Solubility in water

Auto-ignition temperature

Decomposition temperature

Viscosity VOC (% content)

Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. Non-flammable in the presence of the following materials or conditions: heat, shocks and mechanical impacts, oxidizing materials, reducing materials, combustible materials, organic materials, metals, acids, alkalis and moisture.

Not available.

Not available.

Not available. 1.927

Insoluble in the following materials: cold water and hot water.

Not available.

Not available.

>220°C (>428°F) Not available. <1%


Reactivity No specific test data related to reactivity available for this product or its ingredients.

Chemical stability The product is stable.

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid No specific data

Incompatible materials No specific data

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

_____________________________________________________________________________________________

Page 7 / 11


Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure

carbon black respirable LD50 Oral Rat >15400 mg/kg -

Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation

reaction product: bisphenol-A(epichlorhydrin); epoxy resin

Eyes - Mild irritant Rabbit - 100 milligrams

-

Skin - Moderate irritant Rabbit - 24 hours 500 microliters

-

Skin - Severe irritant Rabbit - 24 hours 2 milligrams

-

Sensitization

No specific data.

Mutagenicity

No specific data.

Carcinogenicity

No specific data.

Classification Product/ingredient name OSHA IARC NTP

crystalline silica nonrespirable

- 1 Known to be a human carcinogen.

carbon black respirable - 2B -

Reproductive toxicity

No specific data.

Teratogenicity

No specific data.

Specific target organ toxicity (single exposure)

No specific data.

Specific target organ toxicity (repeated exposure)

No specific data.

Aspiration hazard

No specific data.

Information on the likely Not available.

routes of exposure


Eye contact Causes serious eye irritation.

Inhalation No known significant effects or critical hazards.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Ingestion Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

_____________________________________________________________________________________________

Page 8 / 11

Eye contact Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Skin contact

Ingestion

No specific data.

Adverse symptoms may include the following: irritation redness No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects Not available.

Potential delayed effects Not available.

Long term exposure



Potential chronic health effects No specific data.

General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

Carcinogenicity No known significant effects or critical hazards.

Mutagenicity No known significant effects or critical hazards.

Teratogenicity No known significant effects or critical hazards.

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates No specific data.


Toxicity No specific data.

Persistence and degradability No specific data.

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential

reaction product: bisphenol-A(epichlorhydrin); epoxy resin 2.64 to 3.78 31 low

Mobility in soil

Soil/water partition coefficient (KOC) Not available.

Other adverse effects No known significant effects or critical hazards.


_____________________________________________________________________________________________

Page 9 / 11

Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

RCRA classification Not available.

14. TRANSPORT INFORMATION

Special precautions for user Transport within user’s premises: always transport in closed containers that are

upright and secure. Ensure that persons transporting the product know what to do in

the event of an accident or spillage.


U.S. Federal regulations TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica

TSCA 9(a) CDR Exempt/partial exemption: Not determined

United States Inventory (TSCA 8b): All components are listed or exempted.

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Not listed

Clean Air Act Section 602 Class I Substances Not listed

Clean Air Act Section 602 Class II Substances Not listed

SARA 302/304

Composition/information on ingredients No products were found.

SARA 304 RQ Not applicable

-

-

-

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -

DOT Classification

IMDG IATA

UN Number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.

TDG Classification

Not regulated.

-

-

-

No.

-

Mexico Classification

Not regulated.

-

-

-

No.

-

_____________________________________________________________________________________________

Page 10 / 11

SARA 311/312

Classification Immediate (acute) health hazard

Composition / information on ingredients

Name % Fire

hazard

Sudden

release

of

pressure

Reactive Immediate

(acute)

health

hazard

Delayed

(chronic)

health

hazard

reaction product: bisphenol-A-

(epichlorhydrin); epoxy resin

10-30 No. No. No. Yes. No.

crystalline silica non-respirable 0.1-1 No. No. No. No. Yes

carbon black respirable 0.1-1 No. No. No. No. Yes.

State regulations

Massachusetts The following components are listed: CALCIUM CARBONATE

New York None of the components are listed.

New Jersey The following components are listed: CALCIUM CARBONATE; LIMESTONE, SILICA,

QUARTZ; QUARTZ (SiO2); CARBON BLACK

Pennsylvania The following components are listed: LIMESTONE; QUARTS (SiO2); CARBON BLACK

Minnesota Hazardous Substances None of the components are listed.

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

Ingredient Name Cancer Reproductive No significant

risk level

Maximum acceptable

dosage level

crystalline silica non-respirable Yes. No. No. No.

carbon black respirable Yes. No. No. No.

Canada inventory All components are listed or exempted. International regulations International lists Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZloC): Not determined. Phillipines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): Not determined. Substances of very high concern

None of the components are listed.

16. OTHER INFORMATION Key to abbreviations ATE = Acute Toxicity Estimate

_____________________________________________________________________________________________

Page 11 / 11

BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

NON-WARRANTY: The information presented in this publication is based upon the research and experience of J-

B Weld Company. No representation or warranty is made, however, concerning the accuracy or completeness of

the information presented in this publication. J-B Weld Company makes no warranty or representation of any

kind, express or implied, including without limitation any warranty of merchantability or fitness for any particular

purpose, and no warranty or representation shall be implied by law or otherwise. Any products sold by J-B Weld

Company are not warranted as suitable for any particular purpose to the buyer. The suitability of any products

for any purpose particular to the buyer is for the buyer to determine. J-B Weld Company assumes no

responsibility for the selection of products suitable to the particular purposes of any particular buyer. J-B Weld

Company shall in no event be liable for any special, incidental, or consequential damages.

SAFETY DATA SHEET

Issuing Date 11-Nov- 2014 Revision Date 11-Nov-2014 Revision Number 1

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Product identifier

Product SDS Name Steel Reinforced Epoxy Hardener – Slow Cure – Twin Tubes - Part B

J-B Weld FG SKU Part Numbers Covered

8265, 8265F, 8265S, 8265A, 8265H, 8272, 8272F, 8280, 8280F, 8281, 80165, 7265S, 7280

J-B Weld Product Names Covered

J-B Weld™ (Twin Tubes), MarineWeld™ (Twin Tubes Only)

J-B Weld Product Type

Steel Reinforced Epoxy

Recommended use of the chemical and restrictions on use

Recommended Use General Purpose Adhesive

Uses advised against No information available

Details of the supplier of the safety data sheet

Supplier Name J-B WELD COMPANY,LLC Supplier Address 1130 COMO ST

SULPHUR SPRINGS, TX 75482 USA

Emergency Telephone Numbers Transportation Emergencies: Chemtrec (24 hour transportation emergency response info): 800-424-9300 or 703-527-3887

Poison/Medical Emergencies: Poison Control Centers (24 hour emergency poison / medical response info): 800-222-1222

Supplier Email Supplier Phone Number

[email protected] 903-885-7696

2. HAZARDS IDENTIFICATION OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200). Classification of the substance or mixture GHS label elements

ACUTE TOXICITY: ORAL - Category 4 ACUTE TOXICITY: INHALATION – Category 4

Hazard pictograms Signal word Warning! Hazard statements

Harmful if swallowed or if inhaled.

mailto:[email protected]

_____________________________________________________________________________________________

Page 2 / 11

Precautionary statements Prevention Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Do not eat, drink

or smoke when using this product. Wash hands thoroughly after handling.

Response IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth.

Storage Not applicable.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture Mixture

Ingredient name % by weight CAS number

benzyl alcohol 1-5 100-51-6

titanium dioxide 1-5 13463-67-7 2,4,6-tris(dimethylaminomethyl)phenol 1-5 90-72-2 Occupational exposure limits, if available, are listed in Section 8.

4. FIRST AID MEASURES Description of necessary first aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are

still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing,

if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if

adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention

immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of

inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be

kept under medical surveillance for 48 hours.

Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if

symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove

any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position

comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small

quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce

vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that

vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give

anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention


Most important symptoms/effects, acute and delayed


Inhalation Harmful if inhaled. Exposure to decomposition products may cause a health hazard.

Serious effects may be delayed following exposure.

Skin contact No known significant effects or critical hazards.

Eye contact No known significant effects or critical hazards.

Ingestion Harmful if swallowed.

_____________________________________________________________________________________________

Page 3 / 11

Over-exposure signs/symptoms Inhalation No specific data.

Skin contact No specific data.

Eye contact No specific data.

Ingestion No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed

person may need to be kept under medical surveillance for 48 hours.

Specific treatments No specific treatment.

See toxicological information (Section 11)

5. FIRE-FIGHTING MEASURES Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing media

Use an extinguishing agent suitable for the surrounding fire.

None known.

Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst from the chemical

National Fire Protection Association (U.S.A.)

Flammability

Instability/Reactivity

Special Hazardous thermal

decomposition products

Special protective actions

for fire-fighters

Special protective equipment for fire-fighters

Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides sulfur oxides metal oxide/oxides

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

0 1

2 Health

_____________________________________________________________________________________________

Page 4 / 11


Personal precautions, protective

equipment and emergency procedures

For non-emergency personnel

For emergency responders

Environmental precautions

Methods and materials for containment and cleaning up

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Small spill

Large spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations 9see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose some hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

_____________________________________________________________________________________________

Page 5 / 11


Conditions for safe storage, including

any incompatibilities

Precautions for safe handling

Protective measures

Advice on general occupational hygiene

Do not store below the following temperature: 35°C (95°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.


Control parameters

Occupational exposure limits

Ingredient name CAS # Exposure limits

benzyl alcohol 100-51-6 AIHA WEEL (United States, 10/2011). TWA: 10 ppm 8 hours.

titanium dioxide 13463-67-7 ACGIH TLV (United States, 3/2012). TWA: 10 mg/ m³ 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/ m³ 8 hours. Form: Total dust.

OSHA PEL (United States, 6/2010). TWA: 15 mg/ m³ 8 hours. Form: Total dust.

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

_____________________________________________________________________________________________

Page 6 / 11

Skin protection

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases, or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.


Physical state

Color

Odor

Odor threshold

pH

Melting point

Boiling point

Flash point

Evaporation rate

Liquid.

White.

Amine-like.

Not available.

Not available. Not available.

Not available.

Closed cup: >93.3°C (>199.9°F) [Setaflash.] [Product does not sustain combustion.] Not available.

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Vapor pressure

Vapor density

Relative density

Solubility

Solubility in water

Auto-ignition temperature

Decomposition temperature

Viscosity VOC (% content)

Flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. Not available.

Not available.

Not available. 1.955

Not available.

Not available.

Not available.

>220°C (>392°F) Not available. <1%


Reactivity No specific test data related to reactivity available for this product or its ingredients.

Chemical stability The product is stable.

_____________________________________________________________________________________________

Page 7 / 11

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid No specific data

Incompatible materials No specific data

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.


Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure

Benzyl alcohol LD50 Oral Rat 1230 mg/kg -

2,4,6-tris (dimethylaminomethyl)phenol

LD50 Dermal LD50 Oral

Rat Rat

1280 mg/kg 1200 mg/kg

- -

Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation

benzyl alcohol Skin – mild irritant Skin – Moderate irritant Skin – Moderate irritant

Man Pig Rabbit

- - -

48 hours 16 milligrams 100 Percent 24 hours 100 milligrams

- - -

titanium dioxide Skin – Mild Irritant

Human -

72 hours 300 Micrograms Intermittent

-

2,4,6-tris (dimethylaminomethyl)phenol

Eyes – Severe irritant Skin – mild irritant Skin – Severe irritant Skin – Severe irritant

Rabbit Rat Rat Rabbit

- - - -

24 hours 50 Micrograms 0.025 Mililiters 0.25 Mililiters 24 hours 2 milligrams

- - - -

Sensitization

No specific data.

Mutagenicity

No specific data.

Carcinogenicity

No specific data.

Classification Product/ingredient name OSHA IARC NTP

titanium dioxide - 2B -

Reproductive toxicity

No specific data.

Teratogenicity

No specific data.

Specific target organ toxicity (single exposure)

No specific data.

_____________________________________________________________________________________________

Page 8 / 11

Specific target organ toxicity (repeated exposure)

No specific data.

Aspiration hazard

No specific data.

Information on the likely Not available.

routes of exposure


Eye contact No known significant effects or critical hazards.

Inhalation Harmful if inhaled. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact No known significant effects or critical hazards.

Ingestion Harmful if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Inhalation

Skin contact Ingestion

No specific data.

No specific data. No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure



Long term exposure



Potential chronic health effects No specific data.

General No known significant effects or critical hazards.

Carcinogenicity No known significant effects or critical hazards.

Mutagenicity No known significant effects or critical hazards.

Teratogenicity No known significant effects or critical hazards.

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

Route ATE value

Oral 1969.5 mg/kg

Dermal 8745 mg/kg

Inhalation (dusts and mists) 3.551 mg/l

_____________________________________________________________________________________________

Page 9 / 11


Toxicity

Product/ingredient name Result Species Exposure

benzyl alcohol Acute LC50 460000µg/l Fresh water Fish – Pimephales, promelas – Juvenile (Fledgling, Hatchling, Weanling)

96 hours

titanium dioxide Acute LC50 1000000µg/l Marine water Fish – Fundulus heteroclitus 96 hours

Persistence and degradability No specific data.

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential

benzyl alcohol 0.87 - low

titanium dioxide - 352 low

2,4,6-tris 9dimethylaminomethyl) phenol 0.219 - low

Mobility in soil

Soil/water partition coefficient (KOC) Not available.

Other adverse effects No known significant effects or critical hazards.


Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

RCRA classification Not available.

_____________________________________________________________________________________________

Page 10 / 11

14. TRANSPORT INFORMATION

Special precautions for user Transport within user’s premises: always transport in closed containers that are

upright and secure. Ensure that persons transporting the product know what to do in

the event of an accident or spillage.


U.S. Federal regulations TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica

TSCA 9(a) CDR Exempt/partial exemption: Not determined

United States Inventory (TSCA 8b): All components are listed or exempted.

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Not listed

Clean Air Act Section 602 Class I Substances Not listed

Clean Air Act Section 602 Class II Substances Not listed

SARA 302/304

Composition/information on ingredients No products were found.

SARA 304 RQ Not applicable

SARA 311/312

Classification Immediate (acute) health hazard

Composition / information on ingredients

Name % Fire

hazard

Sudden

release

of

pressure

Reactive Immediate

(acute)

health

hazard

Delayed

(chronic)

health

hazard

benzyl alcohol 1-5 No. No. No. Yes. No.

titanium dioxide 1-5 No. No. No. No. Yes

2,4,6-tris (dimethylaminomethyl)phenol 1-5 No. No. No. Yes. No.

-

-

-

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -

DOT Classification

IMDG IATA

UN Number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.

TDG Classification

Not regulated.

-

-

-

No.

-

Mexico Classification

Not regulated.

-

-

-

No.

-

_____________________________________________________________________________________________

Page 11 / 11

State regulations

Massachusetts The following components are listed: BARIUM SULFATE; BENZYL ALCOHOL;

TETRAETHYLENE PENTAMINE; CALCIUM CARBONATE; TITANIUM DIOXIDE

New York None of the components are listed.

New Jersey The following components are listed: BARIUM SULFATE; SULFURIC ACID; BARIUM SALT

(1:1); PROPYLENE GLYCOL; 1,2-PROPANEDIOL; TETRAETHYLENEPENTAMINE; 1,2-

ETHANEDIAMINE, N-(2-AMINOETHYL)N’-[2-[(2-AMINOETHYL)AMINO]ETHYL]-; CALCIUM

CARBONATE; LIMESTONE; TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2)

Pennsylvania The following components are listed: BARIUM SULFATE; 1,2-PROPANEDIOL;

BENZENEMETHANOL; 1,2-ETHANEDIAMINE, N-(2-AMINOETHYL)-N’[2-[(2-

AMINOETHYL)AMINO]ETHYL]-; LIMESTONE; TITANIUM OXIDE (TiO2)

Minnesota Hazardous Substances None of the components are listed.

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

Ingredient Name Cancer Reproductive No significant

risk level

Maximum acceptable

dosage level

titanium dioxide Yes. No. No. No.

crystalline silica non-respirable Yes. No. No. No.

Canada inventory All components are listed or exempted. International regulations International lists Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZloC): All components are listed or exempted. Phillipines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): Not determined. Substances of very high concern

None of the components are listed.

16. OTHER INFORMATION Key to abbreviations ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

NON-WARRANTY: The information presented in this publication is based upon the research and experience of J-B Weld

Company. No representation or warranty is made, however, concerning the accuracy or completeness of the information

presented in this publication. J-B Weld Company makes no warranty or representation of any kind, express or implied,

including without limitation any warranty of merchantability or fitness for any particular purpose, and no warranty or

representation shall be implied by law or otherwise. Any products sold by J-B Weld Company are not warranted as suitable

for any particular purpose to the buyer. The suitability of any products for any purpose particular to the buyer is for the buyer

to determine. J-B Weld Company assumes no responsibility for the selection of products suitable to the particular purposes

of any particular buyer. J-B Weld Company shall in no event be liable for any special, incidental, or consequential damages.

Material Name: BAYTEC ENC 5003 Article Number: 5210674

Page: 1 of 11 Report version: 2.9


1. Product and Company Identification

Product Name: BAYTEC ENC 5003

Material Number: 5210674

Chemical Family: Aromatic Isocyanate

Chemical Name: Diphenylmethane Diisocyanate (MDI)

2. Hazards Identification

Emergency Overview

Warning Color: Brown, Clear Form: liquid Odor: musty.

Toxic gases/fumes may be given off during burning or thermal decomposition. Closed container may

forcibly rupture under extreme heat or when contents have been contaminated with water. Use cold water

spray to cool fire-exposed containers to minimize the risk of rupture. Causes respiratory tract irritation.

May cause allergic respiratory reaction. Harmful if inhaled. Respiratory sensitizer. Lung damage and

respiratory sensitization may be permanent. Causes skin irritation. May cause allergic skin reaction. Skin

sensitizer. Animal tests and other research indicate that skin contact with MDI can play a role in causing

isocyanate sensitization and respiratory reaction. Causes eye irritation. May cause lung damage.

Potential Health Effects

Primary Routes of Entry: Skin Contact, Inhalation, Eye Contact

Medical Conditions Aggravated by

Exposure: Asthma, Respiratory disorders, Skin Allergies, Eczema

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE

Inhalation

Acute Inhalation For Product: BAYTEC ENC 5003

Diisocyanate vapors or mist at concentrations above the TLV or PEL can irritate (burning sensation) the

mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing,

chest discomfort, shortness of breath and reduced lung function (breathing obstruction). Persons with a

preexisting, nonspecific bronchial hyperreactivity can respond to concentrations below the TLV or PEL

with similar symptoms as well as asthma attack or asthma-like symptoms. Exposure well above the TLV

or PEL may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in lungs). Chemical or

Bayer MaterialScience LLC

Product Safety & Regulatory Affairs

100 Bayer Road

Pittsburgh, PA 15205-9741

USA

TRANSPORTATION EMERGENCY

CALL CHEMTREC: (800) 424-9300 INTERNATIONAL: (703) 527-3887

NON-TRANSPORTATION

Emergency Phone: Call Chemtrec Information Phone: (800) 662-2927



hypersensitivity pneumonitis, with flu-like symptoms (e.g., fever, chills), has also been reported. These

symptoms can be delayed up to several hours after exposure. These effects are usually reversible.

Chronic Inhalation For Product: BAYTEC ENC 5003

As a result of previous repeated overexposures or a single large dose, certain individuals may develop

sensitization to diisocyanates (asthma or asthma-like symptoms) that may cause them to react to a later

exposure to diisocyanates at levels well below the TLV or PEL. These symptoms, which can include chest

tightness, wheezing, cough, shortness of breath or asthmatic attack, could be immediate or delayed up to

several hours after exposure. Extreme asthmatic reactions can be life threatening. Similar to many non-

specific asthmatic responses, there are reports that once sensitized an individual can experience these

symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist for

weeks and in severe cases for several years. Sensitization can be permanent. Chronic overexposure to

diisocyanates has also been reported to cause lung damage (including fibrosis, decrease in lung function)

that may be permanent.

Skin

Acute Skin For Product: BAYTEC ENC 5003

Causes skin irritation with symptoms of reddening, itching, and swelling. Persons previously sensitized can

experience allergic skin reaction with symptoms of reddening, itching, swelling, and rash. Cured material is

difficult to remove. Contact with MDI can cause discoloration.

Chronic Skin For Product: BAYTEC ENC 5003

Prolonged contact can cause reddening, swelling, rash, and, in some cases, skin sensitization. Animal tests

and other research indicate that skin contact with MDI can play a role in causing isocyanate sensitization

and respiratory reaction. This data reinforces the need to prevent direct skin contact with isocyanates.

Eye

Acute Eye For Product: BAYTEC ENC 5003

Causes irritation with symptoms of reddening, tearing, stinging, and swelling. May cause temporary

corneal injury. Vapor or aerosol may cause irritation with symptoms of burning and tearing.

Chronic Eye For Product: BAYTEC ENC 5003

Prolonged vapor contact may cause conjunctivitis.

Ingestion

Acute Ingestion For Product: BAYTEC ENC 5003

May cause irritation; Symptoms may include abdominal pain, nausea, vomiting, and diarrhea.

Carcinogenicity:

No carcinogenic substances as defined by IARC, NTP and/or OSHA

3. Composition/Information on Ingredients

Hazardous components

Weight percent Components CAS-No.



40 - 50% 4,4'-Diphenylmethane Diisocyanate

(MDI)

101-68-8

30 - 40% Diphenylmethane Diisocyanate (MDI)

Mixed Isomers

26447-40-5

15 - 25% Polymeric Diphenylmethane

Diisocyanate (pMDI)

9016-87-9

4. First aid measures

Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Use lukewarm water

if possible. Use fingers to ensure that eyelids are separated and that the eye is being irrigated. Get medical

attention.

Skin contact Immediately remove contaminated clothing and shoes. Wash off with soap and water. Use lukewarm water

if possible. Wash contaminated clothing before reuse. For severe exposures, immediately get under safety

shower and begin rinsing. Get medical attention if irritation develops.

Inhalation Move to an area free from further exposure. Get medical attention immediately. Administer oxygen or

artificial respiration as needed. Asthmatic symptoms may develop and may be immediate or delayed up to

several hours. Extreme asthmatic reactions can be life threatening.

Ingestion Do NOT induce vomiting. Wash mouth out with water. Do not give anything by mouth to an unconscious

person. Get medical attention.

Notes to physician Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic/steroid preparation as

needed. Workplace vapors could produce reversible corneal epithelial edema impairing vision. Skin: This

compound is a skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burn. Ingestion:

Treat symptomatically. There is no specific antidote. Inducing vomiting is contraindicated because of the

irritating nature of the compound. Inhalation: Treatment is essentially symptomatic. An individual having

a dermal or pulmonary sensitization reaction to this material should be removed from further exposure to

any diisocyanate.

5. Firefighting measures

Suitable extinguishing media: Dry chemical, Carbon dioxide (CO2), Foam, water spray for large

fires.

Special Fire Fighting Procedures Firefighters should wear NFPA compliant structural firefighting protective equipment, including self-

contained breathing apparatus and NFPA compliant helmet, hood, boots and gloves. Avoid contact with

product. Decontaminate equipment and protective clothing prior to reuse. During a fire, isocyanate vapors

and other irritating, highly toxic gases may be generated by thermal decomposition or combustion.

Exposure to heated diisocyanate can be extremely dangerous.

Unusual Fire/Explosion Hazards Closed container may forcibly rupture under extreme heat or when contents are contaminated with water

(CO2 formed). Use cold-water spray to cool fire-exposed containers to minimize the risk of rupture. Large

fires can be extinguished with large volumes of water applied from a safe distance, since reaction between



water and hot diisocyanate can be vigorous.

6. Accidental release measures

Spill and Leak Procedures Implement site emergency response plan. Evacuate non-emergency personnel. The magnitude of the

evacuation depends upon the quantity released, site conditions, and the ambient temperature. Isolate the

area and prevent access of unauthorized personnel. Notify management. Call CHEMTREC at 1-800-424-

9300 for assistance and advice.

Wear necessary personal protective equipment (PPE) as specified in the SDS or the site emergency

response plan. Ventilate and remove ignition sources. Control the source of the leak. Contain the released

material by damming, diking, retaining, or diverting into an appropriate containment area. Absorb or pump

off as much of the spilled material as possible. When using absorbent, completely cover the spill area with

suitable absorbent material (e.g., vermiculite, kitty litter, Oil-Dri®, etc…). Allow for the absorbent

material to absorb the spilled liquid. Shovel the absorbent material into an approved metal container (i.e.,

55-gallon salvage drum). Do not fill the container more than 2/3 full to allow for expansion, and do not

tighten the lid on the container. Repeat application of absorbent material until all liquid has been removed

from the surface.

Decontaminate the spill surface area using a neutralization solution (see list of solutions on the SDS);

scrubbing the surface with a broom or brush helps the decontamination solution to penetrate into porous

surfaces. Wait at least 15 minutes after first application of the neutralization solution. Cover the area with

absorbent material and shovel this into an approved metal container. Check for residual surface

contamination using Swype® test kits, available from Colorimetric Laboratories, Inc. (CLI) at 847-803-

3737. If the Swype® test pad demonstrates that isocyanate remains on the surface (red color on pad),

repeat applications of neutralization solution, with scrubbing, followed by absorbent until the surface is

decontaminated (no color change on Swype® pad). Apply lid loosely to metal waste container (do not

tighten the lid because carbon dioxide gas and heat can be generated from the neutralization process). With

the lid still loosely in place, move the container to an isolated, well-ventilated area to allow release of

carbon dioxide. After 72 hours, seal the container, and properly dispose of the waste material and any

contaminated equipment (i.e., broom or brush) in accordance with existing federal, state and local

regulations.

Additional Spill Procedures/Neutralization Products or product mixtures that have been shown to be effective neutralization solutions for

decontaminating surfaces, tools, or equipment that have been in contact with an isocyanate includes:

Products available through industrial suppliers:

· Spartan Chemical Company: 1-800-537-8990:

o Spartan® ShineLine Emulsifier Plus

o Spartan® SC-200 Heavy Duty Cleaner

· Colorimetric Laboratories, Inc. (CLI): 1-847-803-3737

o Isocyanate Decontamination Solution

· A mixture of 80% water, 20% non-ionic surfactant (e.g. Plurafac SL-62, Tergitol TMN-10).

· Mix equal amounts of the following:

o Mineral spirits (80%), VM&P Naphtha (15%), and household detergent (5%), and

o A 50-50 mixture of monoethanolamine and water

In a separate container, blend the two solutions in a 1:1 ratio by volume. Immediately prior to applying this

blended neutralization solution onto the contaminated surface area, mix or agitate the container to help

ensure uniform mixing of the ingredients.

If the above products are not available, the following products can be obtained through retail outlets:



· ZEP® Commercial Heavy-Duty Floor Stripper

· Greased Lightning® Super Strength Cleaner and Degreaser

· EASY OFF® Grill and Oven Cleaner or EASY OFF® Fume Free Oven Cleaner

· A mixture of 50% Simple Green® Pro HD Heavy-Duty Cleaner and 50% household ammonia

· A mixture of 90% Fantastic® Heavy Duty All Purpose Cleaner and 10% household ammonia.

Note: Always wear proper PPE when cleaning up an isocyanate spill and using a neutralization solution. It

may take two or more applications of the neutralization solution to decontaminate the surface. Check for

residual surface contamination using a surface wipe method such as the CLI Swype® pad.

7. Handling and storage

Storage temperature:

minimum: 21.11 °C (70 °F)

maximum: 30 °C (86 °F)

Handling/Storage Precautions Do not breathe vapors, mists, or dusts. Use adequate ventilation to keep airborne isocyanate levels below

the exposure limits. Wear respiratory protection if material is heated, sprayed, used in a confined space, or

if the exposure limit is exceeded. Warning properties (irritation of the eyes, nose and throat or odor) are

not adequate to prevent overexposure from inhalation. This material can produce asthmatic sensitization

upon either single inhalation exposure to a relatively high concentration or upon repeated inhalation

exposures to lower concentrations. Individuals with lung or breathing problems or prior allergic reactions

to isocyanates must not be exposed to vapor or spray mist. Avoid contact with skin and eyes. Wear

appropriate eye and skin protection. Wash thoroughly after handling. Do not breathe smoke and gases

created by overheating or burning this material. Decomposition products can be highly toxic and irritating.

Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is

suspected.

Further Info on Storage Conditions Employee education and training in the safe use and handling of this product are required under the OSHA

Hazard Communication Standard 29 CFR 1910.1200.

8. Exposure controls/personal protection

4,4'-Diphenylmethane Diisocyanate (MDI) (101-68-8) US. ACGIH Threshold Limit Values

Time Weighted Average (TWA): 0.005 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Ceiling Limit Value: 0.02 ppm, 0.2 mg/m3

Industrial Hygiene/Ventilation Measures Local exhaust should be used to maintain levels below the TLV whenever MDI is heated, sprayed, or

aerosolized. Standard reference sources regarding industrial ventilation (e.g., ACGIH Industrial Ventilation

Manual) should be consulted for guidance about adequate ventilation. To ensure that published exposure

limits have not been exceeded, monitoring for airborne diisocyanate should become part of the overall

employee exposure characterization program. NIOSH, OSHA, Bayer, and others have developed sampling

and analytical methods. Bayer methods can be made available, upon request.

Respiratory protection Airborne MDI concentrations greater than the ACGIH TLV-TWA (TLV) or OSHA PEL-C (PEL) can



occur in inadequately ventilated environments when MDI is sprayed, aerosolized, or heated. In such cases,

respiratory protection must be worn. The type of respiratory protection selected must comply with the

requirements set forth in OSHA's Respiratory Protection Standard (29 CFR 1910.134). The type of

respiratory protection available includes (1) an atmosphere-supplying respirator such as a self-contained

breathing apparatus (SCBA) or a supplied air respirator (SAR) in the positive pressure or continuous flow

mode, or (2) an air-purifying respirator (APR). If an APR is selected then (a) the cartridge must be

equipped with an end-of-service life indicator (ESLI) certified by NIOSH, or(b) a change out schedule,

based on objective information or data that will ensure that the cartridges are changed out before the end of

their service life, must be developed and implemented. The basis for the change out schedule must be

described in the written respirator program. Further, if an APR is selected, the airborne diisocyanate

concentration must be no greater than 10 times the TLV or PEL. The recommended APR cartridge is an

organic vapor/particulate filter combination cartridge (OV/P100).

Hand protection Gloves should be worn., Nitrile rubber showed excellent resistance., Butyl rubber, neoprene and PVC are

also effective.

Eye protection When directly handling liquid product, eye protection is required. Examples of eye protection include a

chemical safety goggle, or chemical safety goggle in combination with a full face shield when there is a

greater risk of splash.

Skin and body protection Avoid all skin contact. Depending on the conditions of use, cover as much of the exposed skin area as

possible with appropriate clothing to prevent skin contact., Animal tests and other research indicate that

skin contact with MDI can play a role in causing isocyanate sensitization and respiratory reaction., This

data reinforces the need to prevent direct skin contact with isocyanates.

Medical Surveillance All applicants who are assigned to an isocyanate work area should undergo a pre-placement medical

evaluation. A history of eczema or respiratory allergies such as hay fever, are possible reasons for medical

exclusion from isocyanate areas. Applicants who have a history of adult asthma should be restricted from

work with isocyanates. Applicants with a history of prior isocyanate sensitization should be excluded from

further work with isocyanates. A comprehensive annual medical surveillance program should be instituted

for all employees who are potentially exposed to diisocyanates. Once a worker has been diagnosed as

sensitized to any isocyanate, no further exposure can be permitted. Refer to the Bayer pamphlet (Medical

Surveillance Program for Isocyanate Workers) for additional guidance.

Additional Protective Measures Emergency showers and eye wash stations should be available. Educate and train employees in the safe use

and handling of this product. Follow all label instructions.

9. Physical and chemical properties

Form: liquid

Color: Brown, Clear

Odor: musty

pH: Not Applicable

Freezing Point: < 0 °C (< 32 °F) For the active ingredient.

Boiling point/boiling range: Approximately 208 °C (406.4 °F)

Flash point: > 93.34 °C (200.01 °F)

Vapour pressure: < 0.0001 mmHg @ 25 °C (77 °F)

Specific Gravity: 1.24 @ 25 °C (77 °F)

Solubility in Water: Insoluble - Reacts slowly with water to liberate CO2 gas

Bulk density: 1,234 kg/m3



10. Stability and reactivity

Hazardous Reactions Contact with moisture, other materials that react with isocyanates, or temperatures above 350 F (177 C),

may cause polymerization

Materials to avoid Water, Amines, Strong bases, Alcohols, Copper alloys

Hazardous decomposition products By Fire and High Heat: Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense

black smoke., Isocyanate, Isocyanic Acid, Other undetermined compounds

11. Toxicological information

Toxicity Data for BAYTEC ENC 5003

Toxicity Note Toxicity data based on polymeric MDI.

Acute oral toxicity LD50: > 2,000 mg/kg (rat, Male/Female)

Acute inhalation toxicity LC50: 490 mg/m3, 4 h (rat)

Skin irritation rabbit, Slightly irritating

Repeated dose toxicity 90 Days, inhalation: NOAEL: 1 mg/m3, (rat, Male/Female, 6 hrs/day 5 days/week)

Irritation to lungs and nasal cavity.

2 years, inhalation: NOAEL: 0.2, (rat, Male/Female, 6 hrs/day 5 days/week)


Mutagenicity Genetic Toxicity in Vitro:

Bacterial - gene mutation assay: negative (Salmonella typhimurium, Metabolic Activation: with/without)

Carcinogenicity rat, Male/Female, inhalation, 2 Years, 6 hrs/day 5 days/week,

Exposure to a level of 6 mg/m3 polymeric MDI was related to the occurrence of lung tumors. This level is

significantly over the TLV for MDI.

Developmental Toxicity/Teratogenicity rat, female, inhalation, gestation days 6-15, 6 hrs/day, NOAEL (teratogenicity): 12 mg/m3, NOAEL

(maternal): 4 mg/m3

No Teratogenic effects observed at doses tested., Fetotoxicity seen only with maternal toxicity.

Toxicity Data for 4,4'-Diphenylmethane Diisocyanate (MDI)

Acute inhalation toxicity LC50: 369 mg/m3, 4 h (rat, Male/Female)



LC50: > 2240 mg/m3, 1 h (rat) (OECD Test Guideline 403)

Acute dermal toxicity LD50: > 10,000 mg/kg (rabbit)

Skin irritation rabbit, Draize Test, Slightly irritating Human, irritating

Eye irritation rabbit, Draize, Moderately irritating

Sensitisation dermal: sensitizer (guinea pig, Maximization Test) inhalation: sensitizer (Guinea pig)

Repeated dose toxicity 90 Days, inhalation: NOAEL: 0.3 mg/m3, (rat, Male/Female, 18 hrs/day, 5 days/week)


(Human)


Mutagenicity Genetic Toxicity in Vitro:

Ames: (Salmonella typhimurium, Metabolic Activation: with/without)

Positive and negative results were reported. The use of certain solvents which rapidly hydrolyze

diisocyanates is suspected of producing the positive mutagenicity results.

Genetic Toxicity in Vivo:

Micronucleus Assay: (mouse)

negative

Micronucleus test: negative (rat, male, Inhalative (exposure period: 3x1h/day over 3 weeks))

negative

Carcinogenicity

rat, Female, inhalation, 2 Years, 17 hrs/day, 5 days/week,

negative

Other Relevant Toxicity Information May cause irritation of respiratory tract.

12. Ecological information

Ecological Data for BAYTEC ENC 5003

Biodegradation 0 %, Exposure time: 28 d, i.e. not degradable

Bioaccumulation Oncorhynchus mykiss (rainbow trout), Exposure time: 112 d, < 1 BCF

Does not bioaccumulate.

Acute and Prolonged Toxicity to Fish LC0: > 1,000 mg/l (Danio rerio (zebra fish), 96 h) LC0: > 3,000 mg/l (Oryzias latipes (Orange-red killifish), 96 h)



Acute Toxicity to Aquatic Invertebrates EC50: > 1,000 mg/l (Water flea (Daphnia magna), 24 h)

Toxicity to Aquatic Plants NOEC: 1,640 mg/l, End Point: growth (Green algae (Scenedesmus subspicatus), 72 h)

Toxicity to Microorganisms EC50: > 100 mg/l, (activated sludge, 3 h)

Additional Ecotoxicological Remarks Ecotoxicity data based on polymeric MDI

Ecological Data for 4,4'-Diphenylmethane Diisocyanate (MDI)

Acute and Prolonged Toxicity to Fish LC50: > 500 mg/l (Zebra fish (Brachydanio rerio), 24 h)

Acute Toxicity to Aquatic Invertebrates EC50: > 500 mg/l (Water flea (Daphnia magna), 24 h)

13. Disposal considerations

Waste Disposal Method Waste disposal should be in accordance with existing federal, state and local environmental control laws.

Incineration is the preferred method.

Empty Container Precautions Empty containers retain product residue; observe all precautions for product. Do not heat or cut empty

container with electric or gas torch because highly toxic vapors and gases are formed. Do not reuse without

thorough commercial cleaning and reconditioning. If container is to be disposed, ensure all product

residues are removed prior to disposal.

14. Transport information

Land transport (DOT)

Proper shipping name: Other regulated substances, liquid, n.o.s. (contains 4,4'-

Diphenylmethane Diisocyanate (MDI))

Hazard Class or Division: 9

UN/NA Number: NA3082

Packaging group: III

Hazard Label(s): Class 9

RSPA/DOT Regulated Components: 4,4'-Diphenylmethane Diisocyanate (MDI)

Reportable Quantity: 4930 kg (10869 lb)

Sea transport (IMDG)

Non-Regulated

Air transport (ICAO/IATA)

Non-Regulated



Additional Transportation Information When in individual containers of less than the Product RQ, this material ships as non-regulated.

15. Regulatory information

United States Federal Regulations

OSHA Hazcom Standard Rating: Hazardous

US. Toxic Substances Control Act: Listed on the TSCA Inventory.

US. EPA CERCLA Hazardous Substances (40 CFR 302):

Components 4,4'-Diphenylmethane Diisocyanate

(MDI)

Reportable quantity: 5000 lbs

SARA Section 311/312 Hazard Categories:

Acute Health Hazard, Chronic Health Hazard

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III

Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A):

Components None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III

Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required:

Components 4,4'-Diphenylmethane Diisocyanate (MDI)

Polymeric Diphenylmethane Diisocyanate (pMDI)

US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes

and Appendix VIII Hazardous Constituents (40 CFR 261)

Under RCRA, it is the responsibility of the person who generates a solid waste, as defined in 40 CFR

261.2, to determine if that waste is a hazardous waste.

State Right-To-Know Information The following chemicals are specifically listed by individual states; other product specific health and safety

data in other sections of the MSDS may also be applicable for state requirements. For details on your

regulatory requirements you should contact the appropriate agency in your state.

This product contains a trace (ppm) amount of phenyl isocyanate (CAS# 103-71-9) and

monochlorobenzene (CAS# 108-90-7) as impurities.

Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:

Weight percent Components CAS-No. 40 - 50% 4,4'-Diphenylmethane Diisocyanate

(MDI)

101-68-8

30 - 40% Diphenylmethane Diisocyanate (MDI)

Mixed Isomers

26447-40-5


Diisocyanate (pMDI)

9016-87-9

New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous

Substances Lists:

Weight percent Components CAS-No.



35 - 45% 4,4'-Diphenylmethane Diisocyanate

(MDI)

101-68-8


Diisocyanate (pMDI)

9016-87-9

California Prop. 65:

To the best of our knowledge, this product does not contain any of the listed chemicals, which the state of

California has found to cause cancer, birth defects or other reproductive harm.

Based on information provided by our suppliers, this product is considered “DRC Conflict Free” as defined

by the SEC Conflict Minerals Final Rule (Release No. 34-67716; File No. S7-40-10; Date: 2012-08-22).

16. Other information

NFPA 704M Rating

Health 2

Flammability 1

Reactivity 1

Other

0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme

HMIS Rating

Health 2*

Flammability 1

Physical Hazard 1

0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe

* = Chronic Health Hazard

The method of hazard communication for Bayer MaterialScience LLC is comprised of Product Labels and

Material Safety Data Sheets. HMIS and NFPA ratings are provided by Bayer MaterialScience LLC as a

customer service.

Contact person: Product Safety Department

Telephone: (412) 777-2835

MSDS Number: 112000032863

Version Date: 12/08/2014

Report version: 2.9

This information is furnished without warranty, express or implied. This information is believed to be

accurate to the best knowledge of Bayer MaterialScience LLC. The information in this MSDS relates only

to the specific material designated herein. Bayer MaterialScience LLC assumes no legal responsibility for

use of or reliance upon the information in this MSDS.

Changes since the last version are highlighted in the margin. This version replaces all previous versions.

3M(TM) Scotch-Weld(TM) Epoxy Adhesive 2216 B/A Gray 04/16/15

________________________________________________________________________________________________________Page 1 of 2

Safety Data Sheet

Copyright,2015,3M Company.All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 11-3168-9 Version Number: 11.00Issue Date: 04/16/15 Supercedes Date: 08/05/08

Product identifier3M(TM) Scotch-Weld(TM) Epoxy Adhesive 2216 B/A Gray

ID Number(s):

62-2216-0530-6, 62-2216-0535-5, 62-2216-1430-8, 62-2216-1435-7, 62-2216-5430-4, 62-2216-6430-3, 62-2216-7430-2

Recommended useStructural adhesive

Supplier's details

MANUFACTURER: 3MDIVISION: Industrial Adhesives and Tapes Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USATelephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are:

10-3167-3, 10-3174-9

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

3M(TM) Scotch-Weld(TM) Epoxy Adhesive 2216 B/A Gray 04/16/15

________________________________________________________________________________________________________Page 2 of 2

3M USA SDSs are available at www.3M.com

3M(TM) Scotch-Weld(TM) Epoxy Adhesive 2216 Gray Part B 04/16/15

__________________________________________________________________________________________ Page 1 of 9

Safety Data Sheet



SECTION 1: Identification

1.1. Product identifier3M(TM) Scotch-Weld(TM) Epoxy Adhesive 2216 Gray Part B

Product Identification Numbers62-2216-8530-8, 62-2216-8535-7, 62-2216-9530-7

1.2. Recommended use and restrictions on use


1.3. Supplier’s detailsMANUFACTURER: 3MDIVISION: Industrial Adhesives and Tapes DivisionADDRESS: 3M Center, St. Paul, MN 55144-1000, USATelephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classificationSerious Eye Damage/Irritation: Category 2B.Skin Sensitizer: Category 1.

2.2. Label elementsSignal wordWarning

SymbolsExclamation mark |

Pictograms


__________________________________________________________________________________________ Page 2 of 9

Hazard StatementsCauses eye irritation. May cause an allergic skin reaction.


Prevention:Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.

Response:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Disposal:Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classifiedNone.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by WtEPOXY RESIN 25068-38-6 70 - 80 Trade Secret *KAOLIN 1332-58-7 20 - 30 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get


__________________________________________________________________________________________ Page 3 of 9

medical attention.

If Swallowed: Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing mediaIn case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixtureNone inherent in this product.

Hazardous Decomposition or By-ProductsSubstance ConditionAldehydes During CombustionCarbon monoxide During CombustionCarbon dioxide During CombustionKetones During Combustion

5.3. Special protective actions for fire-fightersNo special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresEvacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautionsAvoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

6.3. Methods and material for containment and cleaning upContain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handlingFor industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on


__________________________________________________________________________________________ Page 4 of 9

clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilitiesStore away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limitsIf a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.Ingredient C.A.S. No. Agency Limit type Additional CommentsKAOLIN 1332-58-7 ACGIH TWA(respirable fraction):2

mg/m3A4: Not class. as human carcin

KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3

ACGIH : American Conference of Governmental Industrial HygienistsAIHA : American Industrial Hygiene AssociationCMRG : Chemical Manufacturer's Recommended GuidelinesOSHA : United States Department of Labor - Occupational Safety and Health AdministrationTWA: Time-Weighted-AverageSTEL: Short Term Exposure LimitCEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controlsProvide ventilated enclosure for heat curing. Provide appropriate local exhaust ventilation for cutting, grinding, sanding ormachining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevantExposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:Indirect Vented Goggles

Skin/hand protectionSelect and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator


__________________________________________________________________________________________ Page 5 of 9

type(s) to reduce inhalation exposure:Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical propertiesGeneral Physical Form: Liquid Specific Physical Form: Viscous LiquidOdor, Color, Grade: Gray very slight epoxy odor.Odor threshold No Data AvailablepH Not ApplicableMelting point Not ApplicableBoiling Point Not ApplicableFlash Point 248 ºC [Test Method: Pensky-Martens Closed Cup]Evaporation rate Not ApplicableFlammability (solid, gas) Not ApplicableFlammable Limits(LEL) Not ApplicableFlammable Limits(UEL) Not ApplicableVapor Pressure <=0.1 mmHg [@ 25 ºC]Vapor Density Not ApplicableDensity 1.33 g/ml [@ 20 ºC]Specific Gravity 1.33 [@ 20 ºC] [Ref Std: WATER=1]Solubility in Water NilSolubility- non-water No Data AvailablePartition coefficient: n-octanol/ water No Data AvailableAutoignition temperature No Data AvailableDecomposition temperature No Data AvailableViscosity 75,000 - 150,000 centipoise [Test Method: Brookfield]Hazardous Air Pollutants 0 % weight [Test Method: Calculated]VOC Less H2O & Exempt Solvents 3.7 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:

when used as intended with Part A]VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as

supplied]VOC Less H2O & Exempt Solvents < 0.5 % [Test Method: calculated SCAQMD rule 443.1]

[Details: when used as intended with Part A]

SECTION 10: Stability and reactivity

10.1. ReactivityThis material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stabilityStable.

10.3. Possibility of hazardous reactionsHazardous polymerization will not occur.

10.4. Conditions to avoidHeat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic reaction with production of intense heat and smoke.


__________________________________________________________________________________________ Page 6 of 9

10.5. Incompatible materialsStrong acidsStrong oxidizing agents

10.6. Hazardous decomposition productsSubstance ConditionNone known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological DataIf a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute ToxicityName Route Species ValueOverall product Ingestion No data available; calculated ATE > 5,000 mg/kgEPOXY RESIN Dermal Rat LD50 > 1,600 mg/kgEPOXY RESIN Ingestion Rat LD50 > 1,000 mg/kgKAOLIN Dermal LD50 estimated to be > 5,000 mg/kgKAOLIN Ingestion Human LD50 > 15,000 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/IrritationName Species Value

EPOXY RESIN Rabbit Mild irritantKAOLIN Professio No significant irritation


__________________________________________________________________________________________ Page 7 of 9

nal judgement

Serious Eye Damage/IrritationName Species Value

EPOXY RESIN Rabbit Moderate irritantKAOLIN Professio

nal judgement

No significant irritation

Skin SensitizationName Species ValueEPOXY RESIN Human

and animal

Sensitizing

Respiratory SensitizationName Species Value

EPOXY RESIN Human Some positive data exist, but the data are not sufficient for classification

Germ Cell MutagenicityName Route Value

EPOXY RESIN In vivo Not mutagenicEPOXY RESIN In Vitro Some positive data exist, but the data are not

sufficient for classification

CarcinogenicityName Route Species ValueEPOXY RESIN Dermal Mouse Some positive data exist, but the data are not

sufficient for classificationKAOLIN Inhalation Multiple

animal species

Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental EffectsName Route Value Species Test Result Exposure

DurationEPOXY RESIN Ingestion Not toxic to female reproduction Rat NOAEL 750

mg/kg/day2 generation

EPOXY RESIN Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day

2 generation

EPOXY RESIN Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day

during organogenesis

EPOXY RESIN Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day

2 generation

Target Organ(s)

Specific Target Organ Toxicity - single exposureFor the component/components, either no data are currently available or the data are not sufficient for classification.

Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration


__________________________________________________________________________________________ Page 8 of 9

EPOXY RESIN Dermal liver Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 1,000 mg/kg/day

2 years

EPOXY RESIN Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day

13 weeks

EPOXY RESIN Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder

All data are negative Rat NOAEL 1,000 mg/kg/day

28 days

KAOLIN Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure

Human NOAEL NA occupational exposure

KAOLIN Inhalation pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification

Rat NOAEL Not available

Aspiration HazardFor the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methodsDispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.


__________________________________________________________________________________________ Page 9 of 9

SECTION 15: Regulatory information

15.1. US Federal RegulationsContact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

15.2. State RegulationsContact 3M for more information.

15.3. Chemical InventoriesThe components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International RegulationsContact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard ClassificationHealth: 2 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.



3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completenessor accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M


3M™ Scotch-Weld™ Epoxy Adhesive 2216 Gray Part A 04/16/15

__________________________________________________________________________________________ Page 1 of 11

Safety Data Sheet



SECTION 1: Identification

1.1. Product identifier3M™ Scotch-Weld™ Epoxy Adhesive 2216 Gray Part A

Product Identification Numbers62-2217-8530-6, 62-2217-8535-5, 62-2217-9530-5

1.2. Recommended use and restrictions on use


1.3. Supplier’s detailsMANUFACTURER: 3MDIVISION: Industrial Adhesives and Tapes DivisionADDRESS: 3M Center, St. Paul, MN 55144-1000, USATelephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classificationSerious Eye Damage/Irritation: Category 1.Skin Corrosion/Irritation: Category 2.Skin Sensitizer: Category 1.Reproductive Toxicity: Category 1B.Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elementsSignal wordDanger

SymbolsCorrosion | Exclamation mark | Health Hazard |

Pictograms


__________________________________________________________________________________________ Page 2 of 11

Hazard StatementsCauses serious eye damage. Causes skin irritation. May cause an allergic skin reaction. May damage fertility or the unborn child.

Causes damage to organs through prolonged or repeated exposure: respiratory system |


Prevention:Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.

Response:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Get medical advice/attention.

Storage:Store locked up.

Disposal:Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classifiedPersons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.

60% of the mixture consists of ingredients of unknown acute oral toxicity.60% of the mixture consists of ingredients of unknown acute dermal toxicity.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by WtALIPHATIC POLYMER DIAMINE 68911-25-1 30 - 60 Trade Secret *KAOLIN 1332-58-7 30 - 60 Trade Secret *BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL

4246-51-9 1 - 10 Trade Secret *

TOLUENE 108-88-3 < 0.5 Trade Secret *


__________________________________________________________________________________________ Page 3 of 11

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention.

If Swallowed: Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing mediaIn case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixtureNone inherent in this product.

Hazardous Decomposition or By-ProductsSubstance ConditionAmine Compounds During CombustionCarbon monoxide During CombustionCarbon dioxide During CombustionOxides of Nitrogen During Combustion

5.3. Special protective actions for fire-fightersNo special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresEvacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.


__________________________________________________________________________________________ Page 4 of 11

6.2. Environmental precautionsAvoid release to the environment.

6.3. Methods and material for containment and cleaning upContain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handlingFor industrial or professional use only. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilitiesNo special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limitsIf a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.Ingredient C.A.S. No. Agency Limit type Additional CommentsTOLUENE 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human

carcinTOLUENE 108-88-3 CMRG STEL:75 ppm Skin NotationTOLUENE 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppmKAOLIN 1332-58-7 ACGIH TWA(respirable fraction):2

mg/m3A4: Not class. as human carcin

KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3

ACGIH : American Conference of Governmental Industrial HygienistsAIHA : American Industrial Hygiene AssociationCMRG : Chemical Manufacturer's Recommended GuidelinesOSHA : United States Department of Labor - Occupational Safety and Health AdministrationTWA: Time-Weighted-AverageSTEL: Short Term Exposure LimitCEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controlsUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)


__________________________________________________________________________________________ Page 5 of 11

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/faceprotection(s) are recommended:Full Face ShieldIndirect Vented Goggles

Skin/hand protectionSelect and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respiratortype(s) to reduce inhalation exposure:Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical propertiesGeneral Physical Form: Liquid Specific Physical Form: ViscousOdor, Color, Grade: pungent odor, gray.Odor threshold No Data AvailablepH Not ApplicableMelting point Not ApplicableBoiling Point No Data AvailableFlash Point >=201 ºF [Test Method: Closed Cup]Evaporation rate Not ApplicableFlammability (solid, gas) Not ApplicableFlammable Limits(LEL) Not ApplicableFlammable Limits(UEL) Not ApplicableVapor Pressure <=0.1 mmHg [@ 25 ºC]Vapor Density Not ApplicableDensity 1.26 g/ml [@ 20 ºC]Specific Gravity 1.26 [@ 20 ºC] [Ref Std: WATER=1]Solubility in Water NilSolubility- non-water No Data AvailablePartition coefficient: n-octanol/ water No Data AvailableAutoignition temperature No Data AvailableDecomposition temperature No Data AvailableViscosity 40,000 - 80,000 centipoise [@ 20 ºC ] [Test Method: Brookfield]Hazardous Air Pollutants < 1 % weight [Test Method: Calculated]VOC Less H2O & Exempt Solvents 3.7 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:

when used as intended with Part B]VOC Less H2O & Exempt Solvents < 0.5 % [Test Method: calculated SCAQMD rule 443.1]

[Details: when used as intended with Part B]VOC Less H2O & Exempt Solvents 6.12 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:


__________________________________________________________________________________________ Page 6 of 11

as supplied]

SECTION 10: Stability and reactivity

10.1. ReactivityThis material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stabilityStable.

10.3. Possibility of hazardous reactionsHazardous polymerization will not occur.

10.4. Conditions to avoidHeat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic reaction with production of intense heat and smoke.

10.5. Incompatible materialsNone known.

10.6. Hazardous decomposition productsSubstance ConditionNone known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May cause additional health effects (see below).

Skin Contact:Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,


__________________________________________________________________________________________ Page 7 of 11

ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Prolonged or repeated exposure may cause target organ effects:Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.

Reproductive/Developmental Toxicity:Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Toxicological DataIf a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute ToxicityName Route Species ValueOverall product Dermal No data available; calculated ATE > 5,000 mg/kgOverall product Ingestion No data available; calculated ATE > 5,000 mg/kgKAOLIN Dermal LD50 estimated to be > 5,000 mg/kgKAOLIN Ingestion Human LD50 > 15,000 mg/kgBIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Dermal Rabbit LD50 2,500 mg/kgBIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Ingestion Rat LD50 3,160 mg/kgTOLUENE Dermal Rat LD50 12,000 mg/kgTOLUENE Inhalation-

Vapor (4 hours)

Rat LC50 30 mg/l

TOLUENE Ingestion Rat LD50 5,550 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/IrritationName Species Value

Overall product IrritantALIPHATIC POLYMER DIAMINE Rabbit IrritantKAOLIN Professio

nal judgement


BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL Rabbit CorrosiveTOLUENE Rabbit Irritant

Serious Eye Damage/IrritationName Species Value

ALIPHATIC POLYMER DIAMINE similar health hazards

Corrosive

KAOLIN Professional judgement


BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL similar health hazards

Corrosive

TOLUENE Rabbit Moderate irritant


__________________________________________________________________________________________ Page 8 of 11

Skin SensitizationName Species ValueOverall product SensitizingALIPHATIC POLYMER DIAMINE Guinea

pigSensitizing

TOLUENE Guinea pig

Not sensitizing

Respiratory SensitizationFor the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell MutagenicityName Route Value

TOLUENE In Vitro Not mutagenicTOLUENE In vivo Not mutagenic

CarcinogenicityName Route Species ValueKAOLIN Inhalation Multiple

animal species

Not carcinogenic

TOLUENE Dermal Mouse Some positive data exist, but the data are not sufficient for classification

TOLUENE Ingestion Rat Some positive data exist, but the data are not sufficient for classification

TOLUENE Inhalation Mouse Some positive data exist, but the data are not sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental EffectsName Route Value Species Test Result Exposure

DurationTOLUENE Inhalation Some positive female reproductive data

exist, but the data are not sufficient for classification

Human NOAEL Not available

occupational exposure

TOLUENE Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification

Rat NOAEL 2.3 mg/l

1 generation

TOLUENE Ingestion Toxic to development Rat LOAEL 520 mg/kg/day

during gestation

TOLUENE Inhalation Toxic to development Human NOAEL Not available

poisoning and/or abuse

Target Organ(s)

Specific Target Organ Toxicity - single exposureName Route Target Organ(s) Value Species Test Result Exposure

DurationBIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL

Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

NOAEL Not available

TOLUENE Inhalation central nervous system depression

May cause drowsiness or dizziness


TOLUENE Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification


TOLUENE Inhalation immune system Some positive data exist, but the data are not sufficient for classification

Mouse NOAEL 0.004 mg/l

3 hours

TOLUENE Ingestion central nervous system depression

May cause drowsiness or dizziness




__________________________________________________________________________________________ Page 9 of 11

Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test Result Exposure

DurationKAOLIN Inhalation pneumoconiosis Causes damage to organs

through prolonged or repeated exposure

Human NOAEL NA occupational exposure

KAOLIN Inhalation pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification

Rat NOAEL Not available

TOLUENE Inhalation auditory system | nervous system | eyes | olfactory system

Causes damage to organs through prolonged or repeated exposure



TOLUENE Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification

Rat LOAEL 2.3 mg/l

15 months

TOLUENE Inhalation heart | liver | kidney and/or bladder

Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 11.3 mg/l

15 weeks

TOLUENE Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 1.1 mg/l

4 weeks

TOLUENE Inhalation immune system Some positive data exist, but the data are not sufficient for classification

Mouse NOAEL Not available

20 days

TOLUENE Inhalation bone, teeth, nails, and/or hair


Mouse NOAEL 1.1 mg/l

8 weeks

TOLUENE Inhalation hematopoietic system | vascular system



occupational exposure

TOLUENE Ingestion nervous system Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 625 mg/kg/day

13 weeks

TOLUENE Ingestion heart Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 2,500 mg/kg/day

13 weeks

TOLUENE Ingestion liver | kidney and/or bladder


Multiple animal species

NOAEL 2,500 mg/kg/day

13 weeks

TOLUENE Ingestion hematopoietic system


Mouse NOAEL 600 mg/kg/day

14 days

TOLUENE Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification


28 days

TOLUENE Ingestion immune system Some positive data exist, but the data are not sufficient for classification


4 weeks

Aspiration HazardName ValueTOLUENE Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information


__________________________________________________________________________________________ Page 10 of 11

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methodsDispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal RegulationsContact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

15.2. State RegulationsContact 3M for more information.

15.3. Chemical InventoriesThe components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International RegulationsContact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard ClassificationHealth: 3 Flammability: 1 Instability: 1 Special Hazards: None


__________________________________________________________________________________________ Page 11 of 11

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.



3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completenessor accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M


Documents

MATERIAL SAFETY DATA SHEET West System Inc.rrs.union.rpi.edu/doc/2016/RRS_USLI_MSDS_2016.pdfmaterial safety data sheet west system inc. msds#403-13a last revised: 10oct13 1. chemical