MATERIAL SAFETY DATA SHEET - US Environmental … · Shipley Company, Inc., Newton, Massachusetts, 02162 PRODUCT NAME! PREPOSIT(R) ETCH 746 ^?^ r Page 6 GAS # Chemical Name Percent

M A T E R I A L S A F E T Y D A T A S H E E T;,,::;-,, r ,: , v ,..,,.;, . ' r M •:••.<:; 'vs..;-:<•• - v,-; -- ' -'• - •••--:•• -. - ,-•:-•-: M'^

SHIPLEY COMPANY, INC.2300 Washington Street

Newton, Massachusetts 02162

Emergency Phone: (617)969-5500 Chemtrec Number: (800)424-9300

PRODUCT NAME: CUPOSIT(R) 328 Q COPPER MIX CONCENTRATE

PRODUCT CLASS: Copper Plating Solution

EFFECTIVE DATE: 15 March 1990

MSDS | PC-00076 SUPERSEDES: 03-03-1989 PREPARED BY: T.,Blakeslee

ACGIH TLV OSHA PELCOMPONENT CAS # WEIGHT% ppm(rocf/m3) ppm(mq/m3)

Sodium Hydroxide 1310-73-2 5 (2) (2)Aryl mercury compound 7439-97-6 <0.01 N.A. N.A.as MercuryNon-HazardousIngredients N.A. 23 N.A. N.A.Water . N.A. 73 N.A. N.A.

ICARCINOGENIC STATUS: Not considered carcinogenic by NTP, IARC and OSHA.

EXPOSURE LIMITS: Not established. Keep vapor concentrations belowcomponent TLV's.

PC76

100040

Shlpley Company, Inc., Newton, Massachusetts, 02162x' -• - - ' " '- - • - • -.--".-PRODUCT &AME t CUPOSIT (R) 328 Q COPPER MIX CONCENTRATE r--> - Page '2

ROUTES OF ENTRY: Inhalation of mists or vapors, eye and skin contact,ingestion, skin absorption.

ACUTE EFFECTS: Corrosive to all body tissues. Eye and skin contact,inhalation and ingestion can cause severe irritation andburns. Onset of symptoms may be delayed.

CHRONIC EFFECTS: Prolonged, repeated contact with skin can cause drying,cracking, defatting, dermatitis.

EMERGENCY FIRST AID PROCEDURES:

INGESTION: Do not induce vomiting. Give large amounts of water. Nevergive anything by mouth to an unconscious person. Contactphysician at once.

EYE CONTACT: Flush immediately with plenty of water for at least 15minutes. Contact physician.

SKIN CONTACT: Flush immediately with plenty of water for at least 15minutes. Remove contaminated clothing. Contact physician.Wash clothing before reuse.

INHALATION: Move into fresh air. If not breathing, give artificialrespiration. If breathing is difficult, give oxygen.Contact physician at once.

NOTE TO PHYSICIAN: There is no specific antidote. Treatment of overexposureshould be directed at the control of symptoms and the clinical condition.

NOTE: Mercury gives delayed second-degree burns. If blisters develop, therewill be a high concentration of mercury in the fluid. Medical treatmentrequires prompt drainage of any blisters that form.

PC76

100041

Shipley Company, Inc., Newton, Massachusetts, 02162

«:•••?; PRODUCT NAME: PREPOSIT(R) ETCH 746 i N - *j ^ page 3

BOILING POINT: > 212* FpH: < 1VAPOR PRESSURE(KMHg) : N.A.

FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: Non-flammableMETHOD USED: N.A.EXTINGUISHING MEDIA: For fires in area use water, carbon dioxide, drychemicals.

FIRE FIGHTING PROCEDURES: Wear full protective clothing whenof acid contact exists. Use self contained breathing

apparatus.UNUSUAL FIRE AND EXPLOSION HAZARDS: Adding water to acids generates heatand may cause spattering. Sulfuric acid solutions react with most metalsto emit flammable hydrogen gas.

REACTIVITY DATA

STABILITY: StableCONDITIONS TO AVOID: Do not store near organic materials, reducing agentsor alkaline materials. Avoid leaks or spills.INCOMPATIBILITY: Organic materials, reducing agents, alkaline materialsDECOMPOSITON PRODUCTS: Neutralization produces heat. When heated todecomposition may emit toxic fumes, including sulfur oxides.HAZARDOUS POLYMERIZATION: Will not occur.

ACTION TO TAKE FOR SPILL:

Spills may be absorbed with appropriate absorbent material for acid

PC38100042


PRODUCT NAME: JPI*EPOS£T (R) ETCH .746.-.:, v. - ;,,: - ,.p,v, .-.-;• Page 4

solutions and placed in a suitable container for disposal. To cleancontaminated floors, flush with abundant quantities of water into seweror waste treatment system if permitted by federal, state and localregulations. If not, collect water and treat.

Dispose of contaminated product and materials used in cleaning up spills andleaks in a manner approved for this material.

DISPOSAL:

Due to the nature of this product, disposal of it, or residues therefromshould be made in compliance with federal, state and local environmentallaws.

Contact your Shipley Technical Representative for more information. It isyour responsibility to verify that any recommended procedures comply withf eral, Estate and local regulations for wastewater discharge.

RESPIRATORY PROTECTION: The specific respirator selected must be based on theairborne concentration found in the workplace and must not exceed theworking limits of the respirator. The respirator must be approved by theNational Institute for Occupational Safety and Health for the substance ofconcern.

*

EYE PROTECTION: Chemical goggles.

PROTECTIVE CLOTHING: Chemical resistant gloves and suitable protectiveclothing to prevent skin contact.

WORK PRACTICES: Avoid skin contact. Practice good personal hygiene to preventaccidental exposure.

VENTILATION: Provide good general (mechanical) room ventilation. Speciallocal exhaust ventilation is recommended at points where vapors can bereleased into the workplace air.

PC38

100043

Shipley Company, Inc., Newton, Massachusetts, 02162-. . .... ,- • - .,,- ,•,.._<;,.„„„. ; ...... . .:,.,„,..,

PRODUCT NAME: PREPOSlT(R)' ETCH- 46 ^ Page 5

PRECAUTIONS TO TAKE IN HANDLING AND STORAGE: WARNING 1 Corrosive acidliquid. Store in closed original container in a cool, dry area at50-90* F. Store away from organic materials, reducing agents, alkalinematerials. Do not store in direct sunlight.

DOT PROPER SHIPPING NAME: Sulfuric Acid SolutionDOT HAZARD CLASSIFICATION: Corrosive MaterialDOT HAZARD IDENTIFICATION NUMBER: UN1830

TSCA STATUS:i

The products listed and their components have been manufactured in accordancewith the inventory listing and premanufacture notice requirements of theToxic Substance Control Act.

MA RIGHT TO KNOW LAW:

All components have been checked for inclusion on the MassachusettsSubstance List.

CALIFORNIA Proposition, 65:

This product does not contain materials which the State of California hasfound to cause cancer, birth defects or other reproductive harm.

HAZARD CATEGORIES UNDER CRITERIA OFOF SARA TITLE III RULES (40 CFR 370): Immediate

THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTINGREQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372:

PC38

100044


PRODUCT NAME! PREPOSIT(R) ETCH 746 ^?^ r Page 6

GAS # Chemical Name Percent by Weight

7864-93-9 Sulfuric Acid 50

N.A. denotes no applicable information was found

THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT SHIPLEY COMPANYBELIEVES TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITHREGARD TO THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION,SUCH DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCHF" ">DUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF SHIPLEY(L PANY IS AUTHORIZED TO VARY ANY OF SUCH DATA. SHIPLEY COMPANY AND ITSAGENTS DISCLAIM ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCEUPON SUCH OATA.

PC38

M A T E R I A L S A F E T Y D A T A S H E E T


Newton. Massachusetts 02162* \Emergency Phone: (617)969-5500 Chemtrec Number: (800)424-9300

PRODUCT NAME: NEUTRA-CLEAN(R) 7

PRODUCT CLASS: Cleaning Compound


MSDS # PC-00036 SUPERSEDES: 11-15-1985 PREPARED BY: T. Blakeslee

ACGIH TLV OSHA PELCOMPONENT CAS £ WEIGHT% ppm(mq/m3) ppm(mq/m3)

Boric Acid 10043-35-3 25 N.A. N.A.Non-hazardousIngredients N.A. 75 N.A. N.A.

CARCINOGENIC STATUS: Not considered carcinogenic by NTP, IARC and OSHA.

EXPOSURE LIMITS: Not established. Avoid contact with material.

ROUTES OF ENTRY: Inhalation of dusts, eye and skin contact,ingestion.

...............................................................................................PC36 100046

Shipley Company, Inc., Newton, Massachusetts, 02162• '

PRODUCT NAME: NEUTRA-CLEAN(R) 7 ; v Page 2

ACUTE EFFECTS: Contact with eyes can cause irritation and burns.Contact with skin can cause irritation, dryness anderuptions. Ingestion can cause irritation.

Boric acid is readily absorbed by the skin through wounds.

CHRONIC EFFECTS: None known.


INGESTION: Contact physician at once.

EYE CONTACT: Flush immediately with plenty of water for at least 15minutes. Contact physician at once.

LKIN CONTACT: Flush immediately with plenty of water for at least 15minutes. Remove contaminated clothing. Contact physician.Wash clothing before reuse.

INHALATION: Move into fresh air. If not breathing, give artificialrespiration. If breathing is difficult, give oxygen.Contact a physician at once.


APPEARANCE AND ODOR: Brown granules with a slight, irritating odor.% VOLATILE BY WEIGHT: N.A.EVAPORATION RATE: N.A.SPECIFIC GRAVITY: N.A.VAPOR DENSITY(AIR=1): N.A.SOLUBILITY IN WATER: CompleteBOILING POINT: N.A.pH: N.A.

PC36

100047

Shipley Company, Inc., Newton, Massachusetts, 02162w' PRODUCT NAME: NEUTRA-CLEAN(R) 7 Page 3

VAPOR PRESSURE(MMHg): N.A.


FLASH POINT: Non-flammableMETHOD USED: N.A.EXTINGUISHING MEDIA: Water, carbon dioxide, dry chemicalsSPECIAL FIRE FIGHTING PROCEDURES: N.A.UNUSUAL FIRE AND EXPLOSION HAZARDS: If acidified or heated to decomposition,may emit sulfur dioxide fumes.

W REACTIVITY DATA

iSTABILITY: StableCONDITIONS TO AVOID: Do not store near acids or strong oxidants.INCOMPATIBILITY: Acids and strong oxidants.DECOMPOSITON PRODUCTS: Acidification will produce sulfur dioxide gas.HAZARDOUS POLYMERIZATION: Will not occur.


Spills may be absorbed with inert absorbent material and placed in asuitable container for disposal. To clean contaminated floors, flushwith abundant quantities of water into sewer or wastetreatment system ifpermitted by federal, state and local regulations. If not, collect waterand treat.


PC36 100048


PRODUCT NAME: NEUTRA-CLEAN(R) 7 Page 4

DISPOSAL:


Contact your Shipley Technical Representative for more information. It isyour responsibility to verify that any recommended procedures comply withfederal, state and local regulations for wastewater discharge.

RESPIRATORY PROTECTION: The specific respirator selected must be based on theirborne concentration found in the workplace and must not exceed the

forking limits of the respirator. The respirator must be approved by theNational Institute for Occupational Safety and Health for the substance ofconcern. -





PRECAUTIONS TO TAKE IN HANDLING AND STORAGE: CAUTION! Treat as adetergent soak cleaner. Store in closed original container in a cool,dry area at 50-90* F. Do not store in direct sunlight. Keep container

PC36

100049


PRODUCT NAME: NEUTRA-CLEAN(R) 7 - - X ' Page 5

closed when not in use.

DOT PROPER SHIPPING NAME: Not RegulatedDOT HAZARD CLASSIFICATION: Not RegulatedDOT HAZARD IDENTIFICATION NUMBER: Not Regulated

TSCA STATUS:

products listed and their components have been manufactured in accordancewith the inventory listing and premanufacture notice requirements of theToxic Substance Control Act.



CALIFORNIA Proposition 65:


HAZARD CATEGORIES UNDER CRITERIA OFOF SARA TITLE III RULES (40 CFR 370) : Immediate


CAS # Chemical Name Percent by Weight

N.A. N.A. N.A.

PC36

100050


PRODUCT NAME: NEUTRA-CLEAN(R) 7 Page1


THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT SHIPLEY COMPANYBELIEVES TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITHREGARD TO THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION,SUCH DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCHPRODUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF SHIPLEYCOMPANY IS AUTHORIZED TO VARY ANY OF SUCH DATA. SHIPLEY COMPANY AND ITSAGENTS DISCLAIM ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCEUPON SUCH DATA.

PC36

100051





PRODUCT NAME: SOLDER BRIGHTENER 215

PRODUCT CLASS: Cleaning Compound



ACGIH TLV OSHA PELCOMPONENT GAS f WEIGHT% ppm(mq/m3) ppm(mq/m3)

Thiourea 62-56-6 30 N.A. N.A.Aminosulfonic acid 5329-14-6 65 N.A. N.A.Non-HazardousIngredients N.A. 5 N.A. N.A.

CARCINOGENIC STATUS: Listed as carcinogenic by NTP and IARC.

EXPOSURE LIMITS: Not established. Avoid contact with material.

ROUTES OF ENTRY: Inhalation of dusts, eye and skin contact,ingestion.

PC33

100052


PRODUCT NAME: SOLDER BRIGHTENER 215 Page 2

ACUTE EFFECTS: Contact with eyes and skin can cause irritation.Inhalation of dusts can cause coughing and irritationof respiratory tract. Ingestion can cause moderate tosevere toxicity.

CHRONIC EFFECTS: Prolonged, repeated contact with skin can causeirritation and dermatitis.




S^N CONTACT: Flush immediately with plenty of water for at least 15minutes. Remove contaminated clothing. Contact physician.Wash clothing before reuse.



APPEARANCE AND ODOR: White powder with no noticible odor.% VOLATILE BY WEIGHT: N.A.EVAPORATION RATE: N.A.SPECIFIC GRAVITY: N.A.VAPOR DENSITY(AIR=1): N.A.SOLUBILITY IN WATER: ModerateBOILING POINT: N.A.pH: N.A.

PC33

100053



VAPOR PRESSURE(MMHg) : N.A.


FLASH POINT: Non-flammableMETHOD USED: N.A.FLAMMABLE LIMITS(% IN AIR): N.A.EXTINGUISHING MEDIA: Water, carbon dioxide, dry chemicalsSPECIAL FIRE FIGHTING PROCEDURES: Check for presence of toxic sulfur oxidefumes. Use self-contained breathing apparatus and full protective clothing,

r "'JSUAL FIRE AND EXPLOSION HAZARDS: If heated to decomposition, toxic sulfurv^cide fumes may be emitted.

REACTIVITY DATA

STABILITY: StableCONDITIONS TO AVOID: Do not store near oxidizing agents.INCOMPATIBILITY: Oxidizing agents.DECOMPOSITON PRODUCTS: If heated to decomposition, toxic sulfur oxidefumes may. be emitted.HAZARDOUS POLYMERIZATION: Will not occur.


Sweep up and place into a suitable container for disposal. To cleancontaminated floors, flush with abundant quantities of water into seweror waste treatment system if permitted by federal, state and localregulations. If not permitted, collect water and treat.

PC33100054



Dispose of contaminated product and materials used in cleaning up spillsand leaks in a manner approved for this material.

DISPOSAL:








PC33

100055



PRECAUTIONS TO TAKE IN HANDLING AND STORAGE:

CAUTION! Treat as an acidic mixture containing thiourea. Store in closedoriginal container in a cool, dry area at 50-90° F. Store away fromstrong oxidants. Do not store in direct sunlight. Keep container closedwhen not in use.

DOT PROPER SHIPPING NAME: Not RegulatedDOT HAZARD CLASSIFICATION: Not RegulatedDOT HAZARD IDENTIFICATION NUMBER: Not Regulated

TSCA STATUS:





This product contains thiourea, which has been found by the State ofCalifornia to be a carcinogen or reproductive hazard.

HAZARD CATEGORIES UNDER CRITERIA OFOF SARA TITLE III RULES (40 CFR 370): Immediate, Delayed

THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING

PC33

100056

t *


PRODUCT NAME: SOLDER BRIGHTENER 215 l Page 6

REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372:


62-56-6 Thiourea 30


THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT SHIPLEY COMPANYBELIEVES TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITH

TO THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION.DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCH

PRODUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF SHIPLEYCOMPANY IS- AUTHORIZED TO VARY ANY OF SUCH DATA. SHIPLEY COMPANY AND ITSAGENTS DISCLAIM ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCEUPON SUCH DATA.

PC33

100057

v '—-«! M A T E R I A L S A F E T Y D A T A S H E E T^ 09 BT



Emsjtgency Phone: (617)969-5500 Chemtrec Number: (800)424-9300

PRODUCT NAME: PREPOSIT(R) ETCH 746

PRODUCT CLASS: Etching Solution



ACGIH TLV OSHA PELCOMPONENT CAS f WEIGHT% ppm(mq/m3) ppm(mq/m3)

Sulfuric acid 7664-93-9 50 (1) (1)Non-hazardousIngredients N.A. 8 N.A. N.A.Water N.A. 42 N.A. N.A.


EXPOSURE LIMITS: Not established. Keep vapor concentrationbelow component TLV's.

&&$f&#fi$if&&f&&&&>&&X2&'c:-lf(£&&:'ji(':

SK-KW»»»K«<WK<«>K-»»»>»W>X«W»*K«4«M« ^ _ _ ._ <KPC38 100058


-- PRODUCT NAME: PREPOSIT(R) ETCH 746 Page 2

ROUTES OF ENTRY: Inhalation of mists or vapors, eye and skin contact,ingestion .

ACUTE EFFECTS: Corrosive to all body tissues. Eye and skin contact,inhalation and ingestion can cause severe irritation andburns .

CHRONIC EFFECTS: Prolonged, repeated contact with skin can cause burns.



"YE CONTACT: Flush immediately with plenty of water for at least 15minutes. Contact physician.




^ 'p WTWTC'm-rPrircrWTCI'Tm'Wx'S'M&WHfr<£•XoMSX*>'OMs:««»*'>R

APPEARANCE AND ODOR: Orange liquid with slight, non-irritting odor.% VOLATILE BY WEIGHT: N.A.EVAPORATION RATE: N.A.SPECIFIC GRAVITY: Approx. 1.4VAPOR DENSITY(AIR=1): N.A.SOLUBILITY IN WATER: Complete

PC38

100059

Shlpley Company, Inc., Newton, Massachusetts, 02162

PRODUCT NAME: CUPOSIT(R) 328 Q COPPER MIX CONCENTRATE Page 3

APPEARANCE AND ODOR: White water liquid with no noticible odor.% VOLATILE BY WEIGHT: N.A.EVAPORATION RATE: N.A.SPECIFIC GRAVITY: Approx. 1.2VAPOR DENSITY(AIR=1): N.A.SOLUBILITY IN WATER: CompleteBOILING POINT: > 212' FpH: > 12VAPOR PRESSURE(MMHg): N.A.


FLASH POINT: Non-flammableMETHOD USED: N.A.FLAMMABLE LIMITS(% IN AIR): N.A.EXTINGUISHING MEDIA: Water, carbon dioxide, dry chemicalsSPECIAL FIRE FIGHTING PROCEDURES: NoneUNUSUAL FIRE AND EXPLOSION HAZARDS: None known

REACTIVITY DATA

STABILITY: StableCONDITIONS TO AVOID: Store away from strong acids.INCOMPATIBILITY: AcidsDECOMPOSITON PRODUCTS: Neutralization produces heat.HAZARDOUS POLYMERIZATION: Will not occur.


PC76 100060



Spills may be absorbed with appropriate absorbent material for alkalinesolutions and placed in a suitable container for disposal. To cleancontaminated floors, flush with abundant quantities of water into sewer orwaste treatment system if permitted by federal, state and local regulations.If not, collect water and treat.


DISPOSAL:


Contact your Shipley Technical Representative for more information. It isi _>r responsibility to verify that any recommended procedures comply withfederal, state and local regulations for wastewater discharge.






PC76

100061




CAUTION! Corrosive alkaline solution. Store in closed originalcontainer in a cool, dry area at 50-90* F. Keep away from acids.Do not store in direct sunlight.

DOT PROPER SHIPPING NAME: Sodium Hydroxide SolutionDOT HAZARD CLASSIFICATION: Corrosive MaterialDOT HAZARD IDENTIFICATION NUMBER: UN1824

TSCA STATUS:





HAZARD CATEGORIES UNDER CRITERIA OFOF SARA TITLE III RULES (40 CFR 37,0) : Immediate

THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTINGREQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-

PC76 100062



KNOW ACT OF 1986 AND OF 40 CFR 372:


N/A N/A N/A


THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT SHIPLEY COMPANYBELIEVES TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITHREGARD TO THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION.*"*CH DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCHt< ODUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF SHIPLEYCOMPANY IS AUTHORIZED TO VARY ANY OF SUCH DATA. SHIPLEY COMPANY AND ITSAGENTS DISCLAIM ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCEUPON SUCH DATA.

PC76

100063





PRODUCT NAME: NEUTRA-CLEAN(R) 68

PRODUCT CLASS: Cleaning Solution



W«

ACGIH TLV OSHA PELCOMPONENT CAS £ WEIGHT% ppm(mq/m3) ppm(rog/m3)

Sodium meta-bisulfite 7681-57-4 20 (5) ' (5)Nitrilotriacetic acid,trisod um salt mono-hydrate (NTA) 5064-31-3 1 N.A. N.A.Non-ha z ardousIngredients N.A 6 N.A. N.A.Water N.A. 73 N.A. N.A.

CARCINOGENIC STATUS: Listed by NTP.

PC29

«R 100061*


PRODUCT NAME: NEUTRA-CLEAN(R) 68 Page 2


ROUTES OF ENTRY: Inhalation of mists or vapors, eye and skin contact,ingest ion, skin absorption.

ACUTE EFFECTS: Contact with eyes and skin can cause irritation,itching, redness, tearing, burning and inflammation.Inhalation, ingestion and skin absorption can causeirritation, coughing, dizziness, weakness,drowsiness and narcosis.

NTA can cause hypocalcemic tetany with spontaneous recovery, as product is achelating agent.

r"»TE: NTP lists NTA as a suspect human carcinogen.

CHRONIC EFFECTS: Prolonged, repeated contact with skin can causeirritation, cracking, drying, defatting and dermititis.

NOTE: NTA has been shown to cause cancer in laboratory animals.







PC29

100 65


PRODUCT NAME: NEUTRA-CLEAN(R) 68 ' x v Page 3

APPEARANCE AND ODOR: Yellow liquid with a slight, non-irritating odor.% VOLATILE BY WEIGHT: N.A.EVAPORATION RATE: N.A.SPECIFIC GRAVITY: Approx. 1.2VAPOR DENSITY(AIR=1): N.A.SOLUBILITY IN WATER: AppreciableBOILING POINT: N.A.pH: Approx. 7VAPOR PRESSURE(MMHg): N.A.


FLASH POINT: Non-flammableMETHOD USED: N.A.FLAMMABLE LIMITS(% IN AIR): N.A.EXTINGUISHING MEDIA: Water, carbon dioxide, dry chemicalsSPECIAL FIRE FIGHTING PROCEDURES: Check for presence of toxic sulfur oxidefumes. Use self contained breathing apparatus and full protective clothing.

UNUSUAL FIRE AND EXPLOSION DATA: If heated to decomposition, toxic sulfuroxide fumes may be emitted.

REACTIVITY DATA

STABILITY: StableCONDITIONS TO AVOID: Do not store near acids or strong oxidizing agents.INCOMPATIBILITY: Acids and strong oxidizing agents.DECOMPOSITON PRODUCTS: If heated to decomposition, toxic sulfur oxide fumesmay be emitted. Acidification produces toxic sulfur dioxide gas.HAZARDOUS POLYMERIZATION: Will not occur.


100066

I•*


- PRODUCT NAME: NEUTRA-CLEAN(R) €8 Page 4

Spills nay be absorbed with inert absorbent material and placed in asuitable container for disposal. To clean contaminated floors, flushwith abundant quantities of water into sewer or wastetreatment system ifpermitted by federal, state and local regulations. If not, collect waterand treat.


DISPOSAL:


your Shipley Technical Representative for more information. It isyour responsibility to verify that any recommended procedures comply withfederal, state and local regulations for wastewater discharge.

RESPIRATORY PROTECTION: The specific respirator selected must be based on theairborne concentration found in the workplace and must not exceed theworking .limits of the respirator. The respirator must be approved by theNational Institute for Occupational Safety and Health for the substance ofconcern.


PROTECTIVE CIOTHING: Chemical resistant gloves and suitable protectiveclothing to prevent skin contact.



PC29

ARI00067


PRODUCT NAME: NEUTRA-CLEAN(R) SB i , ^v - Page 5


CAUTION! Treat as a solution containing sodium bisulfite and NTA. Store inclosed original container in a cool, dry area at 50-90* F. Store away fromstrong oxidants. Do not store in direct sunlight. Keep container closedwhen not in use.

PROPER SHIPPING NAME: Sodium metabisulfite SolutionDOT HAZARD CLASSIFICATION: ORM-BDOT HAZARD IDENTIFICATION NUMBER: NA2693

M&2m&m&&x&f-$?M£88&8&m&m.

TSCA STATUS:






PC29

100068


PRODUCT NAHE: ;'ilEDTIUk I£AN(R) <8'- -v Page 6

HAZARD CATEGORIES UNDER CRITERIA OFOF SARA TITLE III RULES (40 CFR 370): Immediate, Delayed


GAS # Chemical Name Percent by Weight

5064-31-3 Nitrilotriacetic acid 1

N.A. denotes no applicable information was foundi

THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT SHIPLEY COMPANYBELIEVES TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITHREGARD TO THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION,SUCH DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCHPRODUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF SHIPLEYCOMPANY IS AUTHORIZED TO VARY ANY OF SUCH DATA. SHIPLEY COMPANY AND ITSAGENTS DISCLAIM ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCEUPON SUCH DATA.

PC29

100069





PRODUCT NAME: CUPOSIT(R) ACCELERATOR 19

PRODUCT CLASS: Plating Accelerator

EFFECTIVE DATE: 20 June 1989


ACGIH TLV OSHA PELCOMPONENT GAS £ WEIGHT% ppmfmq/m3) ppm(mq/m3)

Fluoroboric acid 16872-11-0 10 N.A. N.A.as Fluoride 16984-48-8 (2.5) (2.5)Non-hazardousIngredients N.A. 5 N.A. N.A.Water N.A. 85 N.A. N.A.



PC72

flRI'00070


PRODUCT NAME: CUPOSIT(R) ACCELERATOR 19 Page 2

ROUTES OF ENTRY: Inhalation of mists or vapors, eye and skin contact,ingestion, skin absorption.

ACUTE EFFECTS: Eye and skin contact can cause irritation and burns.Inhalation, ingestion and skin absorption can causeirritation, burns, headache, nausea, vomiting,dizziness, weakness, drowsiness and narcosis.

Ingestion can result in difficult breathing, stomachpain, and circulatory shock.

Ingestion, inhalation and skin absorption may causesystemic fluoride poisoning.

RONIC EFFECTS: Prolonged, repeated contact with skin can causedermatitis and/or burns.

NOTE: Overexposure can cause systemic fluoride poisoning. Possible chroniceffects are bone, ligament and tendon damage, mottling of teeth, anemia,impaired growth in the young worker, kidney damage, asthma, and symptomsresembling rheumatism.



EYE CONTACT: Flush immediately with plenty of water for at least 15minutes. Contact physician.



PC72

100071




APPEARANCE AND ODOR: A water white liquid with no noticible odor.% VOLATILE BY WEIGHT: N.A.EVAPORATION RATE: N.A.SPECIFIC GRAVITY: Approx. 1.05VAPOR DENSITY(AIR»1): N.A.SOLUBILITY IN WATER: CompleteBOILING POINT: >212* F

PRESSURE(MMHg): N.A.


FLASH POINT: Non-flammableMETHOD USED: N.A.EXTINGUISHING MEDIA: For fires in area use carbon dioxide, dry chemicals,water spray or foam. Avoid water in a steady stream.SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing whenpossibility of acid contact exists. Use self contained breathing apparatus.Water spray may be applied from a distance to keep fire-exposed containerscool .UNUSUAL FIRE AND EXPLOSION HAZARDS: Fluoroboric acid solutions may react withmetals to evolve flammable, explosive hydrogen gas. Adding water to acidsgenerates heat and may cause splattering.

REACTIVITY DATA

STABILITY: Stable

PC72100072

Shlpley Company, Inc., Newton, Massachusetts, 02162

PRODUCT NAME: COPOSIT(R) ACCELERATOR 19 page 4

CONDITIONS TO AVOID: Avoid leaks or spills.INCOMPATIBILITY: Cyanides, strong alkaline materials, sulfides, carbonates,many metals and water-reactive materials. Material etches glass and cancorrode metal.DECOMPOSITON PRODUCTS: Neutralization produces heat. When heated to theboiling point, emits toxic mist. When heated to decomposition, may emittoxic fumes of boron trifluoride and hydogen fluoride.HAZARDOUS POLYMERIZATION: Will not occur.


may be absorbed with appropriate absorbent material for acidsolutions and placed in a suitable container for disposal. To cleancontaminated floors, flush with abundant quantities of water into seweror waste treatment system if permitted by federal, state and localregulations. If not, collect water and treat.


DISPOSAL:.



PC72

100073

Shipley Company, Inc., Newton, Massachusetts, 02162' •






VENTILATION: Provide good general (mechanical) room ventilation. Special, ocal exhaust ventilation is recommended at points where vapors can beReleased into the workplace air.

PRECAUTIONS TO TAKE IN HANDLING AND STORAGE: WARNING! Corrosive acidicfluoride solution. Corrosive to glass, ceramic and metals, store inclosed original container in a cool, dry area at 50-90* F. Store awayfrom cyanides, alkaline materials. Do not store in direct sunlight.

DOT PROPER SHIPPING NAME: Fluoroboric Acid SolutionDOT HAZARD CLASSIFICATION: Corrosive MaterialDOT HAZARD IDENTIFICATION NUMBER: UN1775

PC72

ARI0007I4


PRODUCT KAMEt CUPOSIT(R) ACCELERATOR 19 Page 6

TSCA STATUS:






CATEGORIES UNDER CRITERIA OFOF SARA TITLE III RULES (40 CFR 370): Immediate, Fire Hazard



N.A. N.A. N.A.


THE DATA CONTAINED HEREIN IS BASED ON INFORMATION THAT SHIPLEY COMPANYBELIEVES TO BE RELIABLE, BUT NO EXPRESSED OR IMPLIED WARRANTY IS MADE WITHREGARD TO THE ACCURACY OF SUCH DATA OR ITS SUITABILITY FOR A GIVEN SITUATION.SUCH DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESCRIBED AND NOT TO SUCHPRODUCTS IN COMBINATION WITH ANY OTHER PRODUCT AND NO AGENT OF SHIPLEY

PC72

ARI00075

Shipley Company, Inc., Newton, Massachusetts, 02162. . . . .


COMPANY IS AUTHORIZED TO VARY ANY OF SUCH DATA. SHIPLEY COMPANY AND ITSAGENTS DISCLAIM ALL LIABILITY FOR ANY ACTION TAKEN OR FOREGONE ON RELIANCEUPON SUCH DATA.

PC72

100076

OHI INTERNATIONAL CORPORATION Page 1 of 221441 Hoover Road. Warren, MI, :48089 24-Hour EMERGENCY *hdne Number

• • • • • • •REVISION: urn/* HATEBIAL,SAFETY DATA SHEET>Urb» m*l » «wplr with O3HA> Hmrt CommunioQoo Sundttd. - ' < « - * n T 5*07229CFK I910.

Product Trade Name: SEL-REX: CUBATH® M Make UP 902128Proprietary Formu1 ation

Hazardous Components Section I I T L V OSHA Listed: NTP/IARC/05HA z/EPACAS No. Percentage ACGIH **•«•«»• «-*.*•»•/«

Sulfurlc Acid______7664-93-9______5 to 15 1 mq/M3 OSHA Z HCopper Sulfate*____7758-98-7______< 10.0 1 mq/M3 OSHA Z

* SUBJECT ro rn UPOETIIG RigtrumiTs or sccnoi 313 or nru in UD or««en 372.^

Physical Data Section IIIAppearance and Odor: ____Light blue liquid with no odor.

Solubility 1n Water: Boiling Point N/ANegligible <0.1X __ Vapor Pressure N/ASlight 0.1-1.0* __ Percent Volatile by Volume N/AModerate 1.0-10.OX __ Evaporation Rate N/AAppreciable >10.0S ~" Specific Gravity 1.159Complete(all proportions) X pH < i.o

Fire and Explosion Hazard Data Section IV

Flash Point None____ Flammable/Explosive Limits LEL N/A UEL N/A(method used)

NFPA Code (0-4) Health 2 Flamrnablllty 0 Reactivity 1

Extinguishing Media Product will not burn. Use media suitable for surrounding fireSpecial Fire- Wear self-contained breathing apparatus and full protective

Fighting Procedures clothing.Unusual F1re and Thermal decomposition may yield toxic oxides of sulfur.Explosion Hazards ________ ________

Health Hazard Data Section V

Threshold.Limit Value None known or established.Effects of Overexposure:Acute: Corrosive to eyes,, skin and mucous membranes.Chronic: __ Corrosive to eves, skin and mucous membranes.Principal Route of Exposure: Skin contact. Inqestion. Inhalation._________

Emergency First Aid Procedures:Eye Flush with a directed stream of water for 15 minutes while forcibly

holding eyelid open. Seek medical attention.Skin Immediately flush with water.Seek medical attention.Inhalatlon Remove to fresh-air. Seek medical attention.

Swallowing Dilute by drinking 3-4 glasses of water. Do not induce vomitInnSeek medical attention, ______- , . . >...... -, ...... -—-.- • ••

:-r^:^r-^:--- : 100077

OMI INTERNATIONAL CORPORATION Page 1 of 221441 Hoover Road, Warren, MI 43089 - 24-Hour EMERGENCY Phone Number

REVISION: --«/*/« MATEBIAL^AFETY DATA SHEET 313'4 9129Sec ic ^ ^ ;

Product Trade Name: SEL-REX: CUBATH® M-HY Addition Agent ______902119Proprietary Formulation

Hazardous Components Section II TlV OSHA Listed: NTP/IAKWU:>HA Z/EPA |CAS No. . Percentage ACGIH :->i-**«•—•*•«•...,..«<**t.».*•**-».. •••„., w

Sulfuric Acid______7664*93-9 2 to 5 __1 mq/M* OSHA Z H

formaldehyde 50-00-0__ < O.I rn ma/M3 TWA OSHA Z-2/H NTP C2.0 ppm 15 m1n. STELC/A-2 suspected human carcinogen

siuicr ro nx upoiriic iignmnrs or SKTIOI 313 or rint in no or u m m.

Physical Data Section IIIAppearance and Odor: Clear liquid with faint, unpleasant odor.

Solubility 1n Water: Boiling Point N/ANegligible <0.1X __ Vapor Pressure N/ASlight 0.1-l.OX __ Percent Volatile by Volume N/AModerate 1.0-10.OX __ Evaporation Rate N/AAppreciable >10.0* Specific Gravity 1.034Comp1ete(all proportions) *T" pH <

F1re and 'Explosion Hazard Data Section IV

Flash Point None____ Flammable/Explosive Limits LEL N/a JEL '^A(method used)

NFPA Code (0-4) Health 2 Flammablllty 0 Reactivity 0extinguishing Media Product will not burn. Use media suitable for surrounding fireSpecial F1re- Wear self-contained breathing apparatus and full prjtect-ve

Fighting Procedures clothing.Unusual F1re and None.Explosion Hazards _____

Health Hazard Data Section VThreshold Limit Value None known or established.Effects of Overexposure:Acute":' Corrosive to eyes, skin and mucous membranes.Chronic: Corrosive to eves, skin and mucous membranes.Principal Route of Exposure:Skin contact, ingestion, inhalation.

Emergency First Aid Procedures:Ey« Flush with a directed stream of water for IS minutes while *:*":•:'.

holding eyelid open. SeelTmedical attention.Skin Immediately flush with water, seek medical attention.Inhalation Remove to fresh air. Seek medical attention.

Dilute by drinking 3-4 glasses of water. Do not Induce vomi*.•*•; _Swallowing Seek medical attention.

100078

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MATERIAL SAFETY DATA SHEET - US Environmental … · Shipley Company, Inc., Newton, Massachusetts, 02162 PRODUCT NAME! PREPOSIT(R) ETCH 746 ^?^ r Page 6 GAS # Chemical Name Percent