Material Safety Data Sheet Spirdane D-60 D-60 MSDS.pdf · General Response Procedure Eliminate all sources of ignition. Increase ventilation. Do not touch or walk through spilled

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Chemical Name

Chemical Formula

Chemical Family

Other Names

New Zealand

Product Name

Uses

Spirdane D-60

Manufacture of substance, Distribution of substance, Formulation & (re)packing of substances and mixtures, Uses in Coatings, Uses in Cleaning Agents, Lubricant, Metalworking fluid, Rolling oil, Use as binders and release agents, Use as a fuel, Lamp oil, Barbecue lighter , Functional Fluids, Road and construction applications, Other Consumer Uses, Laboratory activities, Polymer processing.

Product Description

No Data Available

No Data Available

Spirdane D-60

A complex and variable combination of paraffinic and cyclic hydrocarbons having a carbon number range predominantly of C10 to C13 and boiling in the range of approximately 160 deg C to 245 deg C. The aromatic content is < 2% .�

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, < 2% aromatics.; Hydrotreated light, steam cracked naphtha residuum, petroleum; Spirdane D-60

Contact Information Organisation Location

Poisons Information Centre

Redox Pty Ltd 2 Swettenham RoadMinto NSW 2566Australia11 Mayo RoadWiri Auckland 2104New Zealand

Westmead NSW

Chemcall

National Poisons Centre

1. IDENTIFICATION

S23 Do not breathe vapour.

S24 Avoid contact with skin.

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

S51 Use only in well ventilated areas.

S43 In case of fire use carbon dioxide (CO2), foam or powder extinguisher. Do NOT use water.

R65 Harmful : may cause lung damage if swallowed.

R66 Repeated exposure may cause skin dryness and cracking.

No Data Available

Xn Harmful

Poisons Schedule (Aust)

Risk Phrases

Safety Phrases

Categories

Non-Dangerous Goods according to the criteria of the Australian Dangerous Goods Code (ADG Code).ADG Code

Hazardous according to the criteria of ASCC [NOHSC:1008(2004)]ASCC Hazard Classification

2. HAZARD IDENTIFICATION

HSNO Hazard Classification 6.1E

Material Safety Data SheetSpirdane D-60

Form 21047, Revision 3, Page 1 of 8, Document 6449314, 24 Apr 2015 4:10 PM

50ANNIVERSARY

TH

1965 – 2015

AustraliaAdelaideBrisbaneMelbournePerthSydney

New ZealandAucklandChristchurchHawke’s Bay

MalaysiaKuala Lumpur

USALos Angeles

PhoneFaxE-mailWebABN

+61 2 9733 3000+61 2 9733 [email protected] com92 000 762 345

Redox Pty LtdCorporate Office SydneyLocked Bag 15 Minto NSW 2566 Australia2 Swettenham Road Minto NSW 2566 AustraliaAll Deliveries: 4 Holmes Road Minto NSW 2566 Australia

This Material Safety Data Sheet may not provide exhaustive guidance for all HSNO Controls assigned to this substance. The EPA (New Zealand) web site should be consulted for a full list of triggered controls and cited regulations.

Chemical Entity Formula CAS Number Proportion

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

No Data Available 64742-48-9 100.00 %

Composition Comments: Notes H And P (Directive 67/548/Eec, Annex 1) Apply: Total Content Of Aromatics, % By Weight: <0.03

No Data Available No Data Available

Ingredients

3. COMPOSITION/INFORMATION ON INGREDIENTS

Description of necessary measures according to routes of exposure

4. FIRST AID MEASURES

Swallowed Seek immediate medical assistance. Risk of product entering the lungs on vomiting after ingestion. In this case, the casualty should be sent immediately to hospital.

Advice to Doctor Treat symptomatically based on judgement of doctor and individual reactions of patient.

Inhaled In case of exposure to intense concentrations of vapours, fumes or spray, remove victim from exposure to fresh air. Avoid becoming a casualty. Seek medical advice if effects persist.

Medical Conditions Aggravated by Exposure

No information available on medical conditions aggravated by exposure to this product.

Eye Immediately flush eyes with plenty of water for 15 minutes, holding eyelids open. In all cases of eye contamination, it is a sensible precaution to seek medical advice.

Skin Remove contaminated clothing. Wash affected area with plenty of soap and water for at least 15 minutes. Wash clothing before reuse. If irritation occurs, seek medical advice.

5. FIRE FIGHTING MEASURES

General Measures Clear fire area of all non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate ignition sources. Move fire exposed containers from fire area if it can be done without risk.

Flammability Conditions Product is a combustible liquid.

Extinguishing Media Foam. Dry powder. Carbon dioxide (CO 2). Water spray. Do NOT use a solid water stream as it may scatter and spread fire. Cool containers / tanks with water spray.

Fire and Explosion Hazard Vapors may form explosive mixtures with air.Vapours are heavier than air and may spread near ground level to sources of ignition.

Hazardous Products of Combustion

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly dangerous if inhaled in confined spaces or at high concentration.

Special Fire Fighting Instructions

Do NOT allow fire fighting water to reach waterways, drains or sewers. Store fire fighting water for treatment.

Personal Protective Equipment Fire fighters should wear a positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots and gloves) or chemical splash suit.

Flash Point >63 °C ASTM D93

Lower Explosion Limit 0.6 %

Upper Explosion Limit 7.0 %

Auto Ignition Temperature >230 °C

Hazchem Code No Data Available

6. ACCIDENTAL RELEASE MEASURES

Material Safety Data Sheet Spirdane D-60


http://www.epa.govt.nz/

General Response Procedure Eliminate all sources of ignition. Increase ventilation. Do not touch or walk through spilled product as it may be slippery. Stop leak if safe to do so. Use clean, non-sparking tools and equipment. Stop all work that requires a naked flame, stop all vehicles, stop all machines andequipment that may cause sparks or flames.

Clean Up Procedures Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). When saturated collect material, transfer to suitable, labelled, dry chemical-waste containers and dispose of promptly as hazardous waste.

Containment Stop leak if safe to do so.

Decontamination Wash area down with excess water.

Environmental Precautionary Measures

Do not allow product to reach drains, sewers or waterways. If product does enter a waterway, advise the Environmental Protection Authority or your local Waste Authority.

Evacuation Criteria Evacuate all unnecessary personnel.

Personal Precautionary Measures

Personnel involved in the clean up should wear full protective clothing as listed in section 8.

7. HANDLING AND STORAGE

Handling Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and grounding equipment. Avoid contact with eyes, skin and clothing. Do not breathe vapors or spray mist. Ensure adequate ventilation. Do not spray at high pressure (> 3 bar) . WHILE MOVING THE PRODUCT:. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Do not allow splash loading and ensure that the product is poured slowly, particularly at the beginning of the operation. OPERATE ONLY ON COLD AND DEGASSED TANKS IN VENTILATED PREMISES (TO AVOID RISK OF EXPLOSION). Handle away from any source of ignition (open flame and sparks) and heat (hot manifolds or casings). Do not smoke. Use explosionproof electrical equipment. Take precautionary measures against static discharges. Do not use compressed air for filling, discharging or handling. Design installations (machinery and equipment) to prevent burning product from spreading (tanks, retention systems, interceptors (traps) in drainage systems).

Storage Store in a cool, dry, well-ventilated, fire-proof area. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Design the installations in order to avoid accidental emissions of product (due to seal breakage, for example) onto hot casings or electrical contacts. Storage installations should be designed with adequate bunds so as to prevent ground or water pollution in case of leaks or spills. Use explosion proof electrical equipment. Keep in a bunded area. Keep away from open flames, hot surfaces and sources of ignition. Ground/bond containers, tanks and transfer/receiving equipment. Store at room temperature. Keep containers tightly closed and properly labelled. Avoid strong acids. Oxidizing agents. This product is classified as a 'C1' Combustible Liquid for the purpose of storage and handling in accordance with the requirements of AS1940.

Container Store in original packaging as approved by manufacturer. Packaging material Use material compatible with:. Keep only in the original container or in a suitable container for this kind of product. steel. Stainless steel. Recommended materials for containers, or container linings use mild steel, stainless steel.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

General Advisory OEL CEFIC-HSPA : 1200 mg/m3Derived No Effect Level (DNEL): According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specifiedPredicted No Effect Concentration (PNEC): According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified

Exposure Limits No Data Available

Biological Limits No information available on biological limit values for this product.

Engineering Measures When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Apply technical measures to comply with the occupational exposure limits.

Personal Protection Equipment RESPIRATOR: When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. For rescue and maintenance work in storage tanks use self-contained breathing apparatus. In an emergency or for exceptional short-lasting jobs in an atmosphere polluted by the product, it is necessary to wear protective respiratory equipment. The use of breathing apparatus must comply strictly with the manufacturer's instructions and the regulations governing their choices and uses (AS1715/1716).EYES: Safety glasses with side shields (AS1336/1337).HANDS: Wear Impervious gloves, aliphatic hydrocarbon resistant (AS2161).Repeated or prolonged exposure: Nitrile rubber > 0.3 mm > 480 min. PVA any thickness > 480 min. Fluorinated rubber Viton (R) > 480 min. In case of contact through splashing: Neoprene Chloroprene > 0.7 mm > 60 min .



Nitrile rubber > 0.3 mm > 60 min. CLOTHING: Wear suitable protective clothing and safety footwear (AS3765/2210).

Work Hygienic Practices Ensure the application of strict rules of hygiene by the personnel exposed to the risk of contact with the product. When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. Do not dry hands with rags that have been contaminated with product. Do not use abrasives, solvents or fuels. Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid

Appearance Liquid

Odour Characteristic of petroleum solvent

Colour Colourless

pH No Data Available

Vapour Pressure 0.38 hPa (@ 20 °C)

Relative Vapour Density No Data Available

Boiling/Melting Point 187 - 219 °C EN ISO 3405

Solubility No Data Available

Freezing Point No Data Available

Specific Gravity No Data Available

Flash Point >63 °C ASTM D93

Auto Ignition Temp >230 °C

Evaporation Rate 191 EtEt = 1 (DIN53170)

Bulk Density No Data Available

Corrosion Rate No Data Available

Decomposition Temperature No Data Available

Density 809 kg/m3 ISO 12185

No Data AvailableSpecific Heat

Molecular Weight No Data Available

Net Propellant Weight No Data Available

Octanol Water Coefficient No Data Available

Particle Size No Data Available

Partition Coefficient No Data Available

Saturated Vapour Concentration No Data Available

Vapour Temperature No Data Available

Viscosity 1.77 mm2/s (@ 25 °C)

Volatile Percent No Data Available

VOC Volume No Data Available

Additional Characteristics Soluble in many common organic solvents.Surface tension 0.0249 N/m @ 25 deg C, Method EN 14370

Potential for Dust Explosion Product is a liquid.

Fast or Intensely Burning Characteristics

No Data Available

Flame Propagation or Burning Rate of Solid Materials

No Data Available

Non-Flammables That Could Contribute Unusual Hazards to a Fire

No Data Available

Properties That May Initiate or Contribute to Fire Intensity

No Data Available

Reactions That Release Gases or Vapours

No Data Available

Release of Invisible Flammable Vapours and Gases

No Data Available



10. STABILITY AND REACTIVITY

General Information Combustible liquid.

Chemical Stability Product is stable under normal conditions of use, storage and temperature.

Conditions to Avoid Heat, flames and sparks. Take precautionary measures against static discharges.

Materials to Avoid Strong acids. Oxidizing agents.

Hazardous Decomposition Products

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.

Hazardous Polymerisation No Data Available

EyeIrritant Contact with eyes may cause irritation.

Ingestion Harmful : may cause lung damage if swallowed. If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious pulmonary lesions (medical survey during 48 hours). Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Abdominal pain. May cause central nervous system depression.

Inhalation The inhalation of vapours or aerosols may be irritating for the respiratory tract and for mucous menbranes. Vapors inhaled in strong concentration have a narcotic effect on the central nervous system.

SkinIrritant Repeated exposure may cause skin dryness and cracking. Redness. Prolonged or repeated contact may dry skin and cause irritation.

11. TOXICOLOGICAL INFORMATION

General Information LD50 > 5000 mg/kg bw (rat - OECD 401)�LD50 (24h) > 2000 mg/kg bw (rat - OECD 402)LC50 (8h) > 5000 mg/m3 (vapour) (rat - OECD 403)�

Sensitization: Not classified as a sensitizer.

Carcinogenicity : This product is not classified carcinogenic.

Mutagenicity: The mutagenic potential of the substance has been extensively studied in a range of in-vivo and in-vitro assays.

Germ Cell Mutagenicity: Genetic toxicity : negative.

Reproductive toxicity: Studies in rats with the substance did not show any effect on reproductive performance.

Developmental Toxicity: Results of guideline developmental toxicity studies on the substance and OECD developmental toxicity screening studies showed no evidence of developmental toxicity in rats.�

Repeated Dose ToxicitySubchronic toxicity: No information available.

Target Organ Effects (STOT)Specific target organ systemic toxicity (single exposure): No known effect based on information supplied. Specific target organ systemic toxicity (repeated exposure): No known effect based on information supplied.Aspiration toxicity: The fluid can enter the lungs and cause damage (chemical pneumonitis, potentially fatal).

Other informationOther adverse effects: Frequent or prolonged skin contact destroys the lipoacid cutaneous layer and may cause dermatitis.

Carcinogen Category 0

12. ECOLOGICAL INFORMATION

Ecotoxicity Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics:Acute aquatic toxicityToxicity to algae:ErL50 (72h) > 1000 mg/l (Pseudokirchneriella subcapitata - OECD 201)EbL50 (72h) > 1000 mg/l (Pseudokirchneriella subcapitata - OECD 201)



NOELR (72h) = 1000 mg/l (Pseudokirchneriella subcapitata - biomass - OECD 201)NOELR (72h) = 1000 mg/l (Pseudokirchneriella subcapitata - growth rate - OECD 201)

Toxicity to daphnia and other aquatic invertebrates. EL50 (48h) > 1000 mg/l (Daphnia magna - OECD 202)

Toxicity to fish:LL50 (96h) > 1000 mg/l (Oncorhynchus mykiss - OECD 203)

Chronic aquatic toxicityToxicity to daphnia and other aquatic invertebrates: NOELR (21d) = 0,18 mg/l (Daphnia magna - QSAR Petrotox). Toxicity to fish: NOELR (28d) = 0,10 mg/l (Oncorhynchus mykiss - QSAR Petrotox)

Measured experimental data on hydrocarbon UVCB substances are not meaningful, since each of the constituents is likely to behave differently.�

No Data AvailablePersistence/Degradability

Mobility Mobility in soil: Substance is a UVCB. Standard tests for this endpoint are not appropriate.

Mobility in air: Volatilisation is dependent on Henry's Constant which is not applicable to UVCB.

Environmental Fate Do NOT let product reach waterways, drains and sewers.

Bioaccumulation Potential PBT and vPvB assessment This substance is considered not to be PBT and vPvB.

Environmental Impact No Data Available

13. DISPOSAL CONSIDERATIONS

General Information Dispose of in accordance with all local, state and federal regulations. All empty packaging should be disposed of in accordance with Local, State, and Federal Regulations or recycled/reconditioned at an approved facility.

Contact a specialist disposal company or the local waste regulator for advice. Empty containers may contain flammable or explosive vapors. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Special Precautions for Land Fill

Air

IATA

Proper Shipping Name Spirdane D-60

Class No Data Available

Subsidiary Risk(s) No Data Available

UN Number No Data Available

Hazchem No Data Available

Pack Group No Data Available

Special Provision No Data Available

Land

Australia: ADG


Class C1 Combustible Liquids - Flash point 61 - 150 °C


No Data Available

14. TRANSPORT INFORMATION

Non-Dangerous Goods according to the criteria of the Australian Dangerous Goods Code (ADG Code).ADG Code







New Zealand: NZS5433




No Data Available





United States of America: US DOT




No Data Available





Sea

IMDG








EMS No Data Available

Marine Pollutant No

EPA (New Zealand)

Hazardous Substances and New Organisms Act (HSNO)

Approval Code: HSR002653

15. REGULATORY INFORMATION

General Information No Data Available

Poisons Schedule (Aust) No Data Available

Naphtha, petroleum, hydrotreated heavyAICS Name



16. OTHER INFORMATION

Revision 2

Revision Date 28 Mar 2013

< Less Than> Greater ThanAICS Australian Inventory of Chemical Substancesatm AtmosphereCAS Chemical Abstracts Service (Registry Number)cm² Square CentimetresCO2 Carbon DioxideCOD Chemical Oxygen Demanddeg C (°C) Degrees CelciusEPA (New Zealand) Environmental Protection Authority of New Zealanddeg F (°F) Degrees Farenheitg Gramsg/cm³ Grams per Cubic Centimetreg/l Grams per LitreHSNO Hazardous Substance and New OrganismIDLH Immediately Dangerous to Life and Healthimmiscible Liquids are insoluable in each other.inHg Inch of MercuryinH2O Inch of WaterK Kelvinkg Kilogramkg/m³ Kilograms per Cubic Metrelb PoundLC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of 50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours.LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals.ltr or L Litrem³ Cubic Metrembar Millibarmg Milligrammg/24H Milligrams per 24 Hoursmg/kg Milligrams per Kilogrammg/m³ Milligrams per Cubic MetreMisc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component present.mm MillimetremmH2O Millimetres of WatermPa.s Millipascals per SecondN/A Not ApplicableNIOSH National Institute for Occupational Safety and HealthNOHSC National Occupational Heath and Safety CommissionOECD Organisation for Economic Co-operation and DevelopmentOz OuncePEL Permissible Exposure LimitPa Pascalppb Parts per Billionppm Parts per Millionppm/2h Parts per Million per 2 Hoursppm/6h Parts per Million per 6 Hourspsi Pounds per Square InchR RankineRCP Reciprocal Calculation ProcedureSTEL Short Term Exposure LimitTLV Threshold Limit Valuetne Tonnetorr Millimetre of MercuryTWA Time Weighted Averageug/24H Micrograms per 24 HoursUN United Nationswt Weight

Key/Legend

Related Product Codes DEMISP6500, DEMISP6600, DEMISP6505, DEMISP6506, DEMISP6510, DEMISP6501



Documents

Material Safety Data Sheet Spirdane D-60 D-60 MSDS.pdf · General Response Procedure Eliminate all sources of ignition. Increase ventilation. Do not touch or walk through spilled