Material Safety Data Sheet - Matsui Colormatsui-color.com/images/Photopia-AQ-inks-MSDS-combined.pdf · 1 of 6 First issue: Nov. 25, 2010 Revised: Jan. 7, 2013 Photopia® Aqualite

1 of 6 First issue: Nov. 25, 2010 Revised: Jan. 7, 2013

Photopia® Aqualite Ink Blue AQ-T / US-0156-01

Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Photopia® Aqualite Ink Blue AQ-T General Use: May be used as coloring ink for textile and paper. Product Description: Water based ink containing photochromic microcapsules MSDS Number: US-0156-01 MANUFACTURER Company Name: Matsui Shikiso Chemical Co., Ltd. Address: 64 Kamikazansakuradani-cho, Yamashina-ku, Kyoto 607-8466, JAPAN Telephone No.: +81 (75) 594-5612 AGENCY Matsui International Co., Inc. Address: 1501 West 178th Street, Gardena, CA 90248, U.S.A. Telephone No.: (310) 767-7812 EMERGENCY TELEPHONE NUMBER: +81 (75) 594-5612 / (310) 767-7812

2. COMPOSITION/INFORMATION ON INGREDIENTS

No Component(s) CAS # Approx. %

A Photochromic microcapsule registered 30-50 B Substituted carboheterocyclic butane tetracarboxylate (generic) 91788-83-9 11 C Non-hazardous and other ingredients below reportable levels N/A Balance

* Component B is included in Component A. OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): This product is not considered to be hazardous under OSHA’s Hazard Communication Standard. SNUR SPECIFIC CHEMICAL SUBSTANCES

Component B is a substance to the reporting requirements of Significant New Use Rule (SNUR) and of 40 CFR section 721.1925 “Substituted carboheterocyclic butane tetracarboxylate (generic).”

3. HAZARDS IDENTIFICATION

HMIS Ratings Health: 1 Flammability: 0 Reactivity: 0 Protection: H (0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe) EMERGENCY OVERVIEW:

May cause respiratory tract, skin, and eye irritation.


Photopia® Aqualite Ink Blue AQ-T / US-0156-01 POTENTIAL HEALTH EFFECTS Systemic Effects:

Substituted carboheterocyclic butane tetracarboxylate (generic) may cause internal organ effects and immune system effects.

Inhalation: Product may cause irritation.

Eye: Product may cause irritation. Skin: Product causes irritation.

Ingestion: May cause discomfort in the stomach and pharynx.

Chronic: Product may cause internal organ effects and immune system effects by prolonged exposure.

Carcinogenicity: NTP: Not listed.

OSHA: Not regulated. IARC: Not listed. ACGIH: Not listed. POTENTIAL ENVIRONMENTAL EFFECTS:

Product may be toxic to aquatic organisms, and cause long-term effects in the aquatic environment.

4. FIRST AID MEASURES

INHALATION: Remove to fresh air. Keep warm and at rest.

EYE: Immediately flush eyes with water for at least 15 minutes. Seek medical attention as needed. SKIN: Wash with mild soap and large amount of water until no evidence of chemical remains.

If symptoms such as itch or irritation develop or persist, refer for medical attention. INGESTION:

Rinse mouth thoroughly with water. Get medical attention Immediately. PROTECTION TO FIRST-AIDERS:

Wear personal protective clothing and equipment. NOTE TO PHYSICIAN: Treat symptomatically.

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES Hazardous Combustion Products: Not available. Flash Point: Not available. Lower Flammable Limit: Not available. Upper Flammable Limit: Not available. Autoignition: Not applicable. Conditions of Flammability: Requires this product be dry. Explosion Data: Impact Sensitivity: Not sensitive to mechanical impact. Static Discharge: Not sensitive to static discharge. EXTINGUISHING MEDIA:

Use water spray, sand, dry chemical, or CO2 gas. (This product is not combustible under normal conditions due to its aqueous property.)

FIRE FIGHTING INSTRUCTIONS: In case of fire, wear respirator.



6. ACCIDENTAL RELEASE MEASURES

LAND SPILL: Wear personal protective clothing and equipment. Ventilate area. For small spill, soak with dry sand, soil, saw dust, or rags. Collect spilled material in container for disposal.

For large spill, dike with sandbags and prevent from contaminating soil. WATER SPILL:

Wear suitable personal protective equipment as needed. Avoid releasing spilled material into rivers and/or lakes, and drains. If material is released to public water, advice local authority.

7. HANDLING AND STORAGE

HANDLING: Wear suitable protective equipment and clothing as needed to prevent the material from contacting skin and eyes. Local exhaust ventilation or general ventilation is recommended during indoor operation.

STORAGE: Store in a cool and dark place away from high temperature, humidity, and direct sunlight. Avoid freezing. Keep container tightly closed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

EXPOSURE LIMIT VALUES: Not established. EXPOSURE CONTROLS Occupational Exposure Controls Engineering Controls:

Local exhaust ventilation or general ventilation is recommended during indoor operation. Human Health Hazard Precaution When using this substance: Avoid skin contact.

Avoid breathing substance. Avoid ingestion. Use respiratory protection. Use skin protection.

Personal Protection Respiratory Protection:

When processing fumes/haze are not adequately controlled, use respirator approved by NIOSH for protection from organic vapors and particulate matter. When dust or powder from secondary operations such as grinding, sanding or sawing, are not adequately controlled use respirator approved by NIOSH for protection from dust.

Hand Protection: Wear rubber or plastic gloves.

Eye Protection: Wear safety glasses or chemical goggles.

Skin Protection: Wear long sleeves, long pants and/or boots when applicable.

Environmental Exposure Controls: Not available.



9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colored liquid. (represents reversible photochromism) Odor: Almost odorless pH: 9 - 10 Boiling Point: Not available. Melting Point: Not available. Decomposition Temperature: Not available. Flash Point: Not available. Auto-Ignition Temperature: Not applicable. Flammability: If this product is dry, it may be flammable. Explosive Properties: Not applicable. Oxidizing Properties: Not applicable. Vapor Pressure: Not available. Specific Gravity (water = 1): 1.03 ± 0.05 Solubility Water: Miscible. Partition Coefficient (n-octanol/water): Not available. Viscosity: 500 - 3,000 mPa.s Vapor Density: Not available. Evaporation Rate: Not available.

10. STABILITY AND REACTIVITY

CONDITIONS TO AVOID: None. STABILITY: Stable under recommended conditions of storage and handling. MATERIALS TO AVOID: Oxidizer, peroxide, strong oxide, strong base. HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS: Not available.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity: < component B >

Oral LD50 (rat) 1,123 mg/kg

Dermal LD50 (rat) > 2,000 mg/kg Eye Irritaion: Not available. Skin Irritation: Not available. Sensitization: Not available. Repeated Dose Toxicity: < component B >

90-day repeated oral toxicity study (rats): NOEL < 5 mg/kg /day Chronic Toxicity: Not available. Mutagenicity: Not available. Carcinogenicity: Not applicable. Reproductive and Developmental Toxicity: Not available.



12. ECOLOGICAL INFORMATION

ECOTOXICITY: < component B >

48 hr EC50 (for daphnia) 0.121 mg/L MOBILITY: Not available. PERSISTENCE AND BIODEGRADABILITY: Not available. BIOACCUMULATIVE POTENTIAL: Not available. OTHER ADVERSE EFFECTS: Not available.

13. DISPOSAL INFORMATION

Comply with all federal, state and local regulations. Do not dump this product into sewers, on the ground or into any body of water.

14. TRANSPORT INFORMATION

US DEPARTMENT OF TRANSPORTATION (DOT) Hazardous Materials: YES. Hazardous Materials Description and Proper Shipping Name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Hazard Class or Division: 9 Identification Number: 3082 Packing Group: III Label(s) Required: 9 SEA TRANSPORT IMDG Class: 9 Packing Group (PG): III UN Number: 3082 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S Marine Pollutant: Not applicable. AIR TRANSPORT ICAO/IATA Class: 9 Packing Group (PG): III UN Number: 3082 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S



15. REGULATORY INFORMATION

OSHA STATUS: This product is not considered to be hazardous under 29 CFR 1910.1200. TSCA STATUS: All components on TSCA INVENTORY. CERCLA REPORTABLE QUANTITY (40 CFR 117, 302):

Not applicable. SARA TITLE III Section 302 (40 CFR 355) – Extremely hazardous substance:

Not applicable. Section 311/312 (40 CFR 370) – Hazard categories: Not applicable. Section 313 (40 CFR 372) – Toxic chemical: Not applicable. CONEG – Typical Metals present in ppm: Cadmium (Cd) N Hexavalent Chromium (Cr(VI)) N Lead (Pb) N Mercury (Hg) N ENCS (Japan): Components listed. Please refer to any other federal, state and local regulations. For specific questions please call to Matsui International Co., Inc. USA 3107677812.

16. OTHER

ABBREVIATIONS OSHA: The Occupational Safety and Health Administration NTP: National Toxicology Program IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists, Inc. IMDG: International Maritime Dangerous Goods ICAO: International Civil Aviation Organization IATA: International Air Transport Association TSCA: Toxic Substances Control Act CERCLA:Comprehensive Environmental Response, Compensation and Liability Act of 1980 SARA: Superfund Amendments and Reauthorization Act of 1986 CONEG: the Coalition of Northeastern Governors ENCS: Existing and New Chemical Substances PHOTOPIA is a registered trademark of MATSUI SHIKISO CHEMICAL CO., LTD. New and updated MSDS are presented in the ANSI Z400.1-1998 Sixteen-section format. All available information is included in systematic update. This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge of MATSUI SHIKISO CHEMICAL CO., LTD. It relates only to the specific product designated herein, and does not relate to use in combination with any other material or in any process. MATSUI SHIKISO CHEMICAL CO., LTD. assumes no legal responsibility for use of or reliance upon this information.


Photopia® Aqualite Ink Purple AQ-R / US-0155-01

Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Photopia® Aqualite Ink Purple AQ-R General Use: May be used as coloring ink for textile and paper. Product Description: Water based ink containing photochromic microcapsules MSDS Number: US-0155-01 MANUFACTURER Company Name: Matsui Shikiso Chemical Co., Ltd. Address: 64 Kamikazansakuradani-cho, Yamashina-ku, Kyoto 607-8466, JAPAN Telephone No.: +81 (75) 594-5612 AGENCY Matsui International Co., Inc. Address: 1501 West 178th Street, Gardena, CA 90248, U.S.A. Telephone No.: (310) 767-7812 EMERGENCY TELEPHONE NUMBER: +81 (75) 594-5612 / (310) 767-7812



A Photochromic microcapsule registered 30-50 B Substituted carboheterocyclic butane tetracarboxylate (generic) 91788-83-9 25 C Non-hazardous and other ingredients below reportable levels N/A Balance

* Component B is included in Component A. OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): This product is not considered to be hazardous under OSHA’s Hazard Communication Standard. SNUR SPECIFIC CHEMICAL SUBSTANCES

Component B is a substance to the reporting requirements of Significant New Use Rule (SNUR) and of 40 CFR section 721.1925 “Substituted carboheterocyclic butane tetracarboxylate (generic).”


HMIS Ratings Health: 1 Flammability: 0 Reactivity: 0 Protection: H (0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe) EMERGENCY OVERVIEW:

May cause respiratory tract, skin, and eye irritation.


Photopia® Aqualite Ink Purple AQ-R / US-0155-01 POTENTIAL HEALTH EFFECTS Systemic Effects:

Substituted carboheterocyclic butane tetracarboxylate (generic) may cause internal organ effects and immune system effects.

Inhalation: Product may cause irritation.

Eye: Product may cause irritation. Skin: Product causes irritation.

Ingestion: May cause discomfort in the stomach and pharynx.

Chronic: Product may cause internal organ effects and immune system effects by prolonged exposure.

Carcinogenicity: NTP: Not listed.

OSHA: Not regulated. IARC: Not listed. ACGIH: Not listed. POTENTIAL ENVIRONMENTAL EFFECTS:

Product may be toxic to aquatic organisms, and cause long-term effects in the aquatic environment.

4. FIRST AID MEASURES

INHALATION: Remove to fresh air. Keep warm and at rest.

EYE: Immediately flush eyes with water for at least 15 minutes. Seek medical attention as needed. SKIN: Wash with mild soap and large amount of water until no evidence of chemical remains.

If symptoms such as itch or irritation develop or persist, refer for medical attention. INGESTION:

Rinse mouth thoroughly with water. Get medical attention Immediately. PROTECTION TO FIRST-AIDERS:

Wear personal protective clothing and equipment. NOTE TO PHYSICIAN: Treat symptomatically.



Use water spray, sand, dry chemical, or CO2 gas. (This product is not combustible under normal conditions due to its aqueous property.)





LAND SPILL: Wear personal protective clothing and equipment. Ventilate area. For small spill, soak with dry sand, soil, saw dust, or rags. Collect spilled material in container for disposal.

For large spill, dike with sandbags and prevent from contaminating soil. WATER SPILL:

Wear suitable personal protective equipment as needed. Avoid releasing spilled material into

rivers and/or lakes, and drains. If material is released to public water, advice local authority.



STORAGE: Store in a cool and dark place away from high temperature, humidity, and direct sunlight. Avoid freezing. Keep container tightly closed.



Local exhaust ventilation or general ventilation is recommended during indoor operation. Human Health Hazard Precaution When using this substance: Avoid skin contact.

Avoid breathing substance. Avoid ingestion. Use respiratory protection. Use skin protection.

Personal Protection Respiratory Protection:

When processing fumes/haze are not adequately controlled, use respirator approved by NIOSH for protection from organic vapors and particulate matter. When dust or powder from secondary operations such as grinding, sanding or sawing, are not adequately controlled use respirator approved by NIOSH for protection from dust.

Hand Protection: Wear rubber or plastic gloves.

Eye Protection: Wear safety glasses or chemical goggles.

Skin Protection: Wear long sleeves, long pants and/or boots when applicable.

Environmental Exposure Controls: Not available.




Appearance: Colored liquid. (represents reversible photochromism) Odor: Almost odorless pH: 9 - 10 Boiling Point: Not available. Melting Point: Not available. Decomposition Temperature: Not available. Flash Point: Not available. Auto-Ignition Temperature: Not applicable. Flammability: If this product is dry, it may be flammable. Explosive Properties: Not applicable. Oxidizing Properties: Not applicable. Vapor Pressure: Not available. Specific Gravity (water = 1): 1.03 ± 0.05 Solubility Water: Miscible. Partition Coefficient (n-octanol/water): Not available. Viscosity: 500 - 3,000 mPa.s Vapor Density: Not available. Evaporation Rate: Not available.


CONDITIONS TO AVOID: None. STABILITY: Stable under recommended conditions of storage and handling. MATERIALS TO AVOID: Oxidizer, peroxide, strong oxide, strong base. HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS: Not available.


Acute Toxicity: < component B >

Oral LD50 (rat) 1,123 mg/kg

Dermal LD50 (rat) > 2,000 mg/kg Eye Irritaion: Not available. Skin Irritation: Not available. Sensitization: Not available. Repeated Dose Toxicity: < component B >

90-day repeated oral toxicity study (rats): NOEL < 5 mg/kg /day Chronic Toxicity: Not available. Mutagenicity: Not available. Carcinogenicity: Not applicable. Reproductive and Developmental Toxicity: Not available.




ECOTOXICITY: < component B >

48 hr EC50 (for daphnia) 0.121 mg/L MOBILITY: Not available. PERSISTENCE AND BIODEGRADABILITY: Not available. BIOACCUMULATIVE POTENTIAL: Not available. OTHER ADVERSE EFFECTS: Not available.




US DEPARTMENT OF TRANSPORTATION (DOT) Hazardous Materials: YES. Hazardous Materials Description and Proper Shipping Name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Hazard Class or Division: 9 Identification Number: 3082 Packing Group: III Label(s) Required: 9 SEA TRANSPORT IMDG Class: 9 Packing Group (PG): III UN Number: 3082 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S Marine Pollutant: Not applicable. AIR TRANSPORT ICAO/IATA Class: 9 Packing Group (PG): III UN Number: 3082 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S






Not applicable. Section 311/312 (40 CFR 370) – Hazard categories: Not applicable. Section 313 (40 CFR 372) – Toxic chemical: Not applicable. CONEG – Typical Metals present in ppm: Cadmium (Cd) N Hexavalent Chromium (Cr(VI)) N Lead (Pb) N Mercury (Hg) N ENCS (Japan): Components listed. Please refer to any other federal, state and local regulations. For specific questions please call to Matsui International Co., Inc. USA 3107677812.

16. OTHER

ABBREVIATIONS OSHA: The Occupational Safety and Health Administration NTP: National Toxicology Program IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists, Inc. IMDG: International Maritime Dangerous Goods ICAO: International Civil Aviation Organization IATA: International Air Transport Association TSCA: Toxic Substances Control Act CERCLA:Comprehensive Environmental Response, Compensation and Liability Act of 1980 SARA: Superfund Amendments and Reauthorization Act of 1986 CONEG: the Coalition of Northeastern Governors ENCS: Existing and New Chemical Substances PHOTOPIA is a registered trademark of MATSUI SHIKISO CHEMICAL CO., LTD. New and updated MSDS are presented in the ANSI Z400.1-1998 Sixteen-section format. All available information is included in systematic update. This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge of MATSUI SHIKISO CHEMICAL CO., LTD. It relates only to the specific product designated herein, and does not relate to use in combination with any other material or in any process. MATSUI SHIKISO CHEMICAL CO., LTD. assumes no legal responsibility for use of or reliance upon this information.

1 of 6 First issue: Nov. 26, 2010

Revised: -- Photopia® Aqualite Ink Yellow AQ-G / US-0157

Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Photopia® Aqualite Ink Yellow AQ-G General Use: May be used as coloring ink for textile and paper. Product Description: Water based ink containing photochromic microcapsules MSDS Number: US-0157 MANUFACTURER Company Name: Matsui Shikiso Chemical Co., Ltd. Address: 64 Kamikazansakuradani-cho, Yamashina-ku, Kyoto 607-8466, JAPAN Telephone No.: +81 (75) 594-5612 AGENCY Matsui International Co., Inc. Address: 1501 West 178th Street, Gardena, CA 90248, U.S.A. Telephone No.: (310) 767-7812 EMERGENCY TELEPHONE NUMBER: +81 (75) 594-5612 / (310) 767-7812



A Photochromic microcapsule registered 30-50 B Water and ingredients below reportable levels N/A Balance

OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): This product is not considered to be hazardous under OSHA’s Hazard Communication Standard.


HMIS Ratings Health: 1 Flammability: 0 Reactivity: 0 Protection: C (0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe) EMERGENCY OVERVIEW:

Causes respiratory tract, skin, and eye irritation. POTENTIAL HEALTH EFFECTS Inhalation:

Product may cause irritation. Eye: Product may cause irritation. Skin: Prolonged contact with skin or on people with sensitive skin may cause skin rash or

inflammation. Ingestion:

May cause discomfort in the stomach and pharynx. Chronic:

Not available. Carcinogenicity:

NTP: Not listed. OSHA: Not regulated. IARC: Not listed. ACGIH: Not listed.



POTENTIAL ENVIRONMENTAL EFFECTS:

Not available. 4. FIRST AID MEASURES

INHALATION: If inhale a large quantity, remove to fresh air.

EYE: Immediately flush eyes with water for at least 15 minutes. Seek medical attention as needed. SKIN: Wash with mild soap and water. INGESTION:

Rinse mouth thoroughly with water. Induce vomiting if possible. Seek medical attention as needed.

PROTECTION TO FIRST-AIDERS: Wear personal protective clothing and equipment.

NOTE TO PHYSICIAN: Treat symptomatically.



Use water spray, sand, foam, dry chemical, or CO2 gas. (This product is not combustible under normal conditions due to its aqueous property.)



LAND SPILL: Wear personal protective clothing and equipment. Ventilate area. For small spill, soak with dry sand, soil, saw dust, or rags. Collect spilled material in container for disposal and wipe the remaining up with rag. For large spill, dike with sandbags to prevent from contaminating soil, and collect into container with shovel or vacuum.

WATER SPILL: Wear suitable personal protective equipment as needed. Avoid releasing spilled material into rivers and/or lakes, and drains. If material is released to public water, advice local authority.





STORAGE: Store in a cool and dark place away from direct sunlight. Avoid freezing.

Keep container tightly closed.



Local exhaust ventilation or general ventilation is recommended during indoor operation. Personal Protection Respiratory Protection:

Not necessary under normal handling condition. Hand Protection:

Wear rubber or plastic gloves. Eye Protection:

Wear safety glasses or chemical goggles. Skin Protection:

Wear long pants, long sleeves, boots, and rubber or plastic gloves when applicable. Environmental Exposure Controls: Not available. 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colored liquid. (represents reversible photochromism) Odor: Slight aromatic odor pH: 7.0 ± 0.5 Boiling Point: Approx. 100°C Melting Point: Approx. 0°C Decomposition Temperature: Not available. Flash Point: Not available. Auto-Ignition Temperature: Not applicable. Flammability: If this product is dry, it may be flammable. Explosive Properties: Not applicable. Oxidizing Properties: Not applicable. Vapor Pressure: Not available. Specific Gravity (water = 1): 1.01 ± 0.05 Solubility Water: Miscible. Partition Coefficient (n-octanol/water): Not available. Viscosity: Not available. Vapor Density: Not available. Evaporation Rate: Not available.




CONDITIONS TO AVOID: None. STABILITY: Stable under recommended conditions of storage and handling. MATERIALS TO AVOID: None. HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS: None.


Acute Toxicity: Oral rat LD50 (14 days) > 5,000 mg/kg Eye Irritation: Complete recovery was observed by 24-48 hours. (Eye irritation test in rabbit) Skin Irritation: Almost negative in SUMP method with open patch test (24 hours application). (Testing article stained silk cotton with this product.) Sensitization: Negative in Magnusson and Kligman test using guinea pig. (Data as photochromic compound) Repeated Dose Toxicity: Not available. Chronic Toxicity: Not available. Mutagenicity: Negative in Ames test using salmonella typhimurium. (Data as photochromic compound) Carcinogenicity: Not applicable. Reproductive and Developmental Toxicity: Not available.


ECOTOXICITY: Fathead Minnow LC50 (96 hours) 920 ppm MOBILITY: Not available. PERSISTENCE AND BIODEGRADABILITY: Not available. BIOACCUMULATIVE POTENTIAL: Not available. OTHER ADVERSE EFFECTS: Not available.






US DEPARTMENT OF TRANSPORTATION (DOT) Hazardous Materials: Not applicable. Hazardous Materials Description and Proper Shipping Name: Not applicable. Hazard Class or Division: Not applicable. Identification Number: Not applicable. Packing Group: Not applicable. Label(s) Required: Not applicable. SEA TRANSPORT IMDG Class: Not applicable. Packing Group (PG): Not applicable. UN Number: Not applicable. Proper Shipping Name: Not applicable. Marine Pollutant: Not applicable. AIR TRANSPORT ICAO/IATA Class: Not applicable. Packing Group (PG): Not applicable. UN Number: Not applicable. Proper Shipping Name: Not applicable.




Not applicable. Section 311/312 (40 CFR 370) – Hazard categories:

Not applicable. Section 313 (40 CFR 372) – Toxic chemical:

Not applicable. CONEG – Typical Metals present in ppm: Cadmium (Cd) N Hexavalent Chromium (Cr(VI)) N Lead (Pb) N Mercury (Hg) N ENCS (Japan): Components listed. Please refer to any other federal, state and local regulations. For specific questions please call to Matsui International Co., Inc. USA 3107677812.



16. OTHER

ABBREVIATIONS OSHA: The Occupational Safety and Health Administration NTP: National Toxicology Program IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists, Inc. IMDG: International Maritime Dangerous Goods ICAO: International Civil Aviation Organization IATA: International Air Transport Association TSCA: Toxic Substances Control Act CERCLA: Comprehensive Environmental Response, Compensation and Liability Act of 1980 SARA: Superfund Amendments and Reauthorization Act of 1986 CONEG: the Coalition of Northeastern Governors ENCS: Existing and New Chemical Substances PHOTOPIA is a registered trademark of MATSUI SHIKISO CHEMICAL CO., LTD. New and updated MSDS are presented in the ANSI Z400.1-1998 Sixteen-section format. All available information is included in systematic update. This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge of MATSUI SHIKISO CHEMICAL CO., LTD. It relates only to the specific product designated herein, and does not relate to use in combination with any other material or in any process. MATSUI SHIKISO CHEMICAL CO., LTD. assumes no legal responsibility for use of or reliance upon this information.

1 of 6 First issue: Dec. 9, 2011

Revised: -- Photopia Aqualite Ink Magenta AQ-P / US-0195

Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Photopia® Aqualite Ink Magenta AQ-P General Use: May be used as coloring ink for textile and paper. Product Description: Water based ink containing photochromic microcapsules MSDS Number: US-0195 MANUFACTURER Company Name: Matsui Shikiso Chemical Co., Ltd. Address: 64 Kamikazansakuradani-cho, Yamashina-ku, Kyoto 607-8466, JAPAN Telephone No.: +81 (75) 594-5612 AGENCY Matsui International Co., Inc. Address: 1501 West 178th Street, Gardena, CA 90248, U.S.A. Telephone No.: (310) 767-7812 EMERGENCY TELEPHONE NUMBER: +81 (75) 594-5612 / (310) 767-7812



A Photochromic microcapsule registered Approx. 30-50 B Water and ingredients below reportable levels N/A Balance

OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): This product is not considered to be hazardous under OSHA’s Hazard Communication Standard.


HMIS Ratings Health: 1 Flammability: 0 Reactivity: 0 Protection: C (0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe) EMERGENCY OVERVIEW:

Causes respiratory tract, skin, and eye irritation. POTENTIAL HEALTH EFFECTS Inhalation:

Product may cause irritation. Eye: Product may cause irritation. Skin: Prolonged contact with skin or on people with sensitive skin may cause skin rash or

inflammation. Ingestion:

Product may cause irritation. Chronic:

Not available. Carcinogenicity:

NTP: Not listed. OSHA: Not regulated. IARC: Not listed. ACGIH: Not listed.



POTENTIAL ENVIRONMENTAL EFFECTS:

Not available. 4. FIRST AID MEASURES

INHALATION: If inhale a large quantity, remove to fresh air.

EYE: Immediately flush eyes with water for at least 15 minutes. Seek medical attention as needed. SKIN: Wash with mild soap and water. INGESTION:

Rinse mouth thoroughly with water. Induce vomiting if possible. Seek medical attention as needed.

PROTECTION TO FIRST-AIDERS: Wear personal protective clothing and equipment.

NOTE TO PHYSICIAN: Treat symptomatically.



Use water spray, sand, foam, dry chemical, or CO2 gas. (This product is not combustible under normal conditions due to its aqueous property.)



LAND SPILL: Wear personal protective clothing and equipment. Ventilate area. For small spill, soak with dry sand, soil, saw dust, or rags. Collect spilled material in container for disposal and wipe the remaining up with rag. For large spill, dike with sandbags to prevent from contaminating soil, and collect into container with shovel or vacuum.

WATER SPILL: Wear personal protective clothing and equipment. Ventilate area. For small spill, soak with dry sand, soil, saw dust, or rags. Collect spilled material in container for disposal and wipe the remaining up with rag. For large spill, dike with sandbags to prevent from entering sewers or bodies of water, and collect into container with shovel or vacuum.





STORAGE: Store in a cool and dark place away from direct sunlight. Avoid freezing.

Keep container tightly closed.



Local exhaust ventilation or general ventilation is recommended during indoor operation. Personal Protection Respiratory Protection:

Not necessary under normal handling condition. Hand Protection:

Wear rubber or plastic gloves. Eye Protection:

Wear safety glasses or chemical goggles. Skin Protection:

Wear long pants, long sleeves, boots, and rubber or plastic gloves when applicable. Environmental Exposure Controls: Not available.


Appearance: Colored liquid. (represents reversible photochromism) Odor: Odorless. pH: 7.0 ± 0.5 Boiling Point: Approx. 100°C Melting Point: Approx. 0°C Decomposition Temperature: Not available. Flash Point: Not available. Auto-Ignition Temperature: Not applicable. Flammability: If this product is dry, it may be flammable. Explosive Properties: Not applicable. Oxidizing Properties: Not applicable. Vapor Pressure: Not available. Specific Gravity (water = 1): 1.01 ± 0.05 Solubility Water: Not available. Partition Coefficient (n-octanol/water): Not available. Viscosity: Not available. Vapor Density: Not available. Evaporation Rate: Not available.




CONDITIONS TO AVOID: None. STABILITY: Stable under recommended conditions of storage and handling. MATERIALS TO AVOID: Substance that react to contact with water. HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS: None.


Acute Toxicity: Oral rat LD50 (14 days) > 5,000 mg/kg Eye Irritation: Complete recovery was observed by 24-48 hours. (Eye irritation test in rabbit) Skin Irritation: Almost negative in SUMP method with open patch test (24 hours application). (Testing article stained silk cotton with this product.) Sensitization: Negative in Magnusson and Kligman test using guinea pig. (Data as photochromic compound) Repeated Dose Toxicity: Not available. Chronic Toxicity: Not available. Mutagenicity: Negative in Ames test using salmonella typhimurium. (Data as photochromic compound) Carcinogenicity: Not applicable. Reproductive and Developmental Toxicity: Not available.


ECOTOXICITY: Not available. MOBILITY: Not available. PERSISTENCE AND BIODEGRADABILITY: Not available. BIOACCUMULATIVE POTENTIAL: Not available. OTHER ADVERSE EFFECTS: Not available.






US DEPARTMENT OF TRANSPORTATION (DOT) Hazardous Materials: Not applicable. Hazardous Materials Description and Proper Shipping Name: Not applicable. Hazard Class or Division: Not applicable. Identification Number: Not applicable. Packing Group: Not applicable. Label(s) Required: Not applicable. SEA TRANSPORT IMDG Class: Not applicable. Packing Group (PG): Not applicable. UN Number: Not applicable. Proper Shipping Name: Not applicable. Marine Pollutant: Not applicable. AIR TRANSPORT ICAO/IATA Class: Not applicable. Packing Group (PG): Not applicable. UN Number: Not applicable. Proper Shipping Name: Not applicable.




Not applicable. Section 311/312 (40 CFR 370) – Hazard categories:

Not applicable. Section 313 (40 CFR 372) – Toxic chemical:

Not applicable. CONEG – Typical Metals present in ppm: Cadmium (Cd) N Hexavalent Chromium (Cr(VI)) N Lead (Pb) N Mercury (Hg) N ENCS (Japan): Components listed. Please refer to any other federal, state and local regulations. For specific questions please call to Matsui International Co., Inc. USA 3107677812.



16. OTHER

ABBREVIATIONS OSHA: The Occupational Safety and Health Administration NTP: National Toxicology Program IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists, Inc. IMDG: International Maritime Dangerous Goods ICAO: International Civil Aviation Organization IATA: International Air Transport Association TSCA: Toxic Substances Control Act CERCLA: Comprehensive Environmental Response, Compensation and Liability Act of 1980 SARA: Superfund Amendments and Reauthorization Act of 1986 CONEG: the Coalition of Northeastern Governors ENCS: Existing and New Chemical Substances PHOTOPIA is a registered trademark of MATSUI SHIKISO CHEMICAL CO., LTD. New and updated MSDS are presented in the ANSI Z400.1-1998 Sixteen-section format. All available information is included in systematic update. This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge of MATSUI SHIKISO CHEMICAL CO., LTD. It relates only to the specific product designated herein, and does not relate to use in combination with any other material or in any process. MATSUI SHIKISO CHEMICAL CO., LTD. assumes no legal responsibility for use of or reliance upon this information.

Documents

Material Safety Data Sheet - Matsui Colormatsui-color.com/images/Photopia-AQ-inks-MSDS-combined.pdf · 1 of 6 First issue: Nov. 25, 2010 Revised: Jan. 7, 2013 Photopia® Aqualite