MATERIAL SAFETY DATA SHEET PRODUCT NAME

AKPEROX AAP Prepared according to Regulation (EC) No. 1907/2006

SECTION 1 - IDENTIFICATION OF THE PRODUCT AND THE COMPANY

PRODUCT NAME AKPEROX AAP

CHEMICAL NAME ACETYLACETONE PEROXIDE

CHEMICAL FORM Liquid Mixture

CAS NO 37187-22-7

MANUFACTURER AKPA Kimya ve Ambalaj San.Tic.Ltd.Şti.

ADDRESS Beşyol Mah. Birlik Cad. No:12 34295 Küçükçekmece / İstanbul / Türkiye

TELEPHONE +90 212 580 55 59 (pbx)

FAX +90 212 580 55 21

e-mail info@akpakimya.com

SECTION 2 - HAZARD IDENTIFICATION OF THE PREPARATION

Risk advice to man and the environment

Symbol(s) : Xi Irritant

O Oxidizing

R-phrase(s) : R36/38 Irritating to eyes and skin.

R43 May cause sensitization by skin contact.

R7 May cause fire.

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Description Acetyl Acetone Peroxide in solvent mixture.

Chemical Name

CAS-No. EC-No. Symbol(s)

R-phrase(s) Concentration

4-hydroxy-4-methylpentan-2-one (diacetone alcohol)

123-42-2 204-626-7 Xi R36 36- <41

Acetylacetone peroxide

37187-22-7 253-384-9 O, Xi R7 R36/38 R43 36- <41

N-methyl-2- Pyrrolidone

872-50-4 212-828-1 Xi R36/38 12,5- <16

Hydrogen peroxide

7722-84-1 231-765-0 O, C R5 R8 R35 R20/22 2- <4

2,4-pentadione (acetylacetone)

123-54-6 204-634-0 Xn R10 R22 1,5- < 3

SECTION 4 - FIRST-AID MEASURES

General advice

Take off all contaminated clothing immediately. Never give anything by mouth to an unconscious person. Remove from exposure, lie down. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Inhalation Remove to fresh air. Get medical attention if symptoms occur.

Skin contact Wash off immediately with soap and plenty of water. Get medical attention if symptoms occur.

Eye contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Get medical attention if irritation persists.

Ingestion

Clean mouth with water and drink afterwards plenty of water. If a person vomits when Iying on his back, place him in the recovery position. Do not induce vomiting. If swallowed, seek medical advice immediately and show this container or label.

SECTION 5 - FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Hazardous decomposition / combustion products

CO2, Carbon monoxide. Acetylacetone, Mixture of aliphatic and aromatic hydrocarbon solvents.

Extinguishing media which shall not be used for safety reasons

High volume water jet.

Specific hazards during fire fighting

Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.

Special protective equipment for fire-fighters

Use personal protective equipment.

Further information Evacuate all non-essential personnel. Extinguish a small fire with powder or carbon dioxide then apply water to prevent re-ignition. Cool closed containers with water. Fire residues and contaminated with local regulations. After a fire, ventilate thoroughly the area and soak with water, clean the walls and metallic surfaces. In case of fire and/or explosion do not breathe fumes.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Personal precautions

Wear respiratory protection. Wear personal protective equipment.

Environmental precautions

Avoid subsoil penetration. Do not allow material to contaminate ground water system. Do not contaminate water. If the product contaminates rivers and lakes or drains inform respective authorities.

Do not let product enter drains.

Methods for cleaning up

Remove mechanically and with care (e.g. with clean polyethylene plastic shovel). Contain and collect spillage with non-combustible absorbent material,(e.g. sand, diatomaceous earth, vermiculite) and place in container for disposal according to local/ national regulations.

SECTION 7 - HANDLING AND STORAGE

HANDLING Advice on safe handling

Never weigh out in the storage room. When using do not eat, drink or smoke. Do not breathe fumes/vapor. Handle in well ventilated areas. For personal protection see section 8.

Fire and explosion prevention Use explosion protected equipment. Keep away from sources of ignition - No smoking. Use non-sparking tools in areas where explosive vapor air mixtures may occur.

STORAGE Requirements for storage areas and containers Further information on storage conditions Advice on common storage

Electrical installations/working materials must comply with the technical safety standards. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed. No smoking. Avoid impurities (e.g. rust, dust, ash), risk of decomposition. Store apart from other dangerous and incompatible substances.

Storage temperature Remarks

5-25°C Liquid up to -5°C

SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION

Components

Cas-no

Control Parameters

4-hydroxy-4-methylpentan-2-one(diacetone alcohol)

123-42-2 96 mg/m3

20 ppm

N-methyl-2-pyrrolidone 872-50-4 80 mg/m3

19 ppm

Engineering measures General advice Provide ventilation. Personal protective equipment Hand production Skin should be washed after contact. Glove should be used. Eye protection Tightly fitting safety glasses.

Face production equipment. Skin and body protection Protective suit Remove and wash contaminated clothing before re-use. Hygiene measures Wash hands before breaks and immediately after handling the product. Keep away from food, drink and animal feeding stuffs.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form liquid

Color colorless

Safety data

Flash point >110°C Method :ISO 3679, Seta-Flash

Lower explosion limit not applicable

Upper explosion limit not applicable

Vapor pressure at 20°C no data available

Density 1.065 g/cm3 at 20°C

Partition coefficient: n-octanol/water no data available

Solubility in other solvents Medium: Alcohol Mixable

Solubility in other solvents Medium: Phthalates Mixable

Viscosity, dynamic 21 mPa.s at 20°C

Refraction index 1.436 at 20°C

Oxidizing properties No

pH Value Slightly acidic

Active Oxygen content 4,0% - 4,2%

Peroxide content 33%

SADT 60˚C

UN Nr 3107

SECTION 10 - STABILITY AND REACTIVITY

Conditions to avoid

Keep away from heat and sources.

Materials to avoid

Accelerators, strong acids and bases, heavy metal salts, reduction mediums. Avoid impurities (e.g. rust, dust, ash), risk of decomposition.

Hazardous decomposition products

Hazardous decomposition products; Acetyl acetone, Mixture of aliphatic and aromatic hydrocarbon solvents.

Thermal decomposition

>60°C Method: SADT (UN testH.4)

SADT possible at temperatures above approximately 60°C.

Hazardous reactions

General Information: Vapors may from explosive mixture with air. Stability: Stable under recommended storage conditions.

SECTION 11 - TOXICOLOGICAL INFORMATION

Acute oral toxicity

LD50 rat Dose :>2.000 mg/kg Test substance : acetyl acetone peroxide (33%/diethylen glycol/ Diacetone alcohol)

Acute inhalation toxicity

rat Exposure time :1 h Dose :13,1 mg/l Test substance: acetyl acetone peroxide (35%/triethyl phosphate/ N-methyl-2-pyrrolidone/ water /acetic acid)

Acute dermal toxicity

LD0 rat Dose: >2.000 mg/kg Test substance : acetyl acetone peroxide (35%/Diacetone alcohol)

SECTION 12 - ECOLOGICAL INFORMATION

Elimination information (persistence and degradability) Biodegradability : Result: Readily biodegradable. Method: Closed Bottle Test. Ecotoxity effects Acute and prolonged toxicity : EC50 for aquatic invertebrates Species :Daphnia Exposure time :48 h Dose :10.9 mg/l

SECTION 13 - DISPOSAL CONSIDERATIONS

Advice on disposal and : Disposal: dispose of in conjunction with Packaging appropriate waste disposal authorities and in accordance with disposal regulations.

SECTION 14 - TRANSPORT INFORMATION

Land transport *ADR/ GGVS: Class : 5.2 Packaging group : II Classification Code : P1 Hazard identification No : 539 Description of the goods : Organic Peroxide Type E, Liquid ( Acetyl Acetone Peroxide) *RID /GGVE: Class : 5.2 Packaging group : II Classification code : P1 Hazard identification No : 539 UN-Number : 3107 Description of the goods : Organic Peroxide Type E, Liquid (Acetyl Acetone Peroxide)

Sea Transport: *IMDG: Class : 5.2 UN-Number : 3107 EmS : F-J S-R Marine pollutant : no Proper technical name : Organic Peroxide Type E, Liquid ( Acetyl Acetone Peroxide)

Air Transport: *ICAO/IATA: Class : 5.2 UN-Number : 3105 Proper technical name : Organic Peroxide Type D, Liquid

SECTION 15 - REGULATORY INFORMATION Labeling according to EC Directives Hazardous components which must be listed on the label: 37187-22-7 acetyl acetone peroxide Symbol(s) : Xi Irritant O Oxidizing R-phrase(s) :R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R7 May cause fire. S-phrase(s) :S03/07 Keep container tightly closed in a cool place. S14B Keep away from strong acids, bases, heavy metal salts and other reducing substances. S36/37/39 Wear suitable protective clothing, gloves and eye/face Protection. S50D Do not mix with activators and catalyst promoters. Symbols (EU classification)

SECTION 16 - OTHER INFORMATION R-phrases corresponding to the number shown in section 2: R 5 Heating may cause an explosion.

R 7 May cause fire.

R 8 Contact with combustible material may cause fire.

R 10 Flammable.

R 20/22 Harmful by inhalation and if swallowed.

R 22 Harmful if swallowed.

R 35 Causes severe burns.

R 36 Irritating to eyes.

R 36/37 Irritating to eyes and skin.

R 43 May cause sensitization by skin contact.

DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources, which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.