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Material Health and Green ChemistryNorthwest Green Chemistry Roundtable
Lauren Heine Ph.D.Co-Director Clean Production Action
Director GreenScreen ProgramTechnical Advisor, Northwest Green Chemistry
October 28 2014
Material Health in LEED v4
MRcredits: Building Product Disclosure & Optimization – Material Ingredients
Material Ingredient Optimization• GreenScreen List Translator + No Benchmark 1• GreenScreen Full Assessment + No Benchmark 1• Cradle to Cradle Certified
- v3 Silver, Gold, Platinum- v2 Gold & Platinum
• REACH – International Compliance Path
Option 2
Material Ingredient Reporting• Health Product Declaration (HPD)• Manufacturer’s Inventory with GreenScreen• Cradle to Cradle Certified - all levels except v3 Basic
Option 1
Critical Steps to Determine Material Health
• Inventory and Disclosure – What’s in it?– Depth of inventory
• Hazard Screening – GS List Translator– Identify known hazards, RSLs, etc.
• Full Hazard Assessment - GS and C2C– What are the potential impacts of the ingredients?
• Optimization – designing to pose no hazards or risks– Reformulate, innovate
Inventory Screen OptimizeAssess
Material Assessment
Chemical Hazard Full Assessment
Chemical Hazard List Screening
Product Content Inventory
Inventoried to 100 PPM and...
OP 2 I00% BM1 using GS LT (can document with
HPD)OP 2 150%; No BM1 using full
GreenScreen method
Inventoried to 1,000 PPM and...
OP 1 HPD with GS LT for allOP 1 MI disclose all ingredients or hazards based on GS LT
Gett ing Credi t in LEED v4
OP 1 All levels but v3 BasicOP 2 100% v2 Gold, v3 SilverOP 2 150%: v2 Platinum
v3 Gold/Platinum
A method for Chemical Hazard Assessment (CHA) developed by Clean Production Action
– Fully transparent– Scientifically based– Simplifies complex information– Applies to chemicals, materials and
products– Freely downloadable*– Becoming a global standard
GreenScreen® for Safer Chemicals
*All supporting resources at: www.greenscreenchemicals.org
Green chemistry is “the design of
products and processes that
reduce or eliminate the
use or generation of
hazardous substances.”
#3 Less hazardous chemical syntheses#4 Design safer chemicals and products#5 Use safer solvents and auxiliaries#10 Design chemicals and products to degrade after use#12 Minimize the potential for accidents
Green/Sustainable Chemistry Defined by 12 Principles: reduce risk by reducing inherent hazard
Risk = (Hazard, Exposure)
GS List Translator– High level review using hazard lists only– Doesn’t require toxicology expertise– Automated tools
• Pharos• HPD Builder• GreenWERCS with GS List Translator
• Full GreenScreen– Comprehensive review– Can identify safer chemicals– Requires technical expertise such as
Licensed Profilers (toxicologists)
GreenScreen (GS) Tools
Full GreenScreen Assessments Always Trump GS List Translator Results
• Maps chemicals on GS specified lists to hazards and overall scores
• Identifies known “bad actor” chemicals using hazard lists
What GreenScreen List Translator Is
Benchmark 1
Avoid – Chemical of High Concern
• Provides a quick and useful screen for reviewing formulations
• Aided by software automation
• It does NOT include a full assessment of data
• It does NOT represent a comprehensive review
What the GreenScreen List Translator Is Not
Benchmark 4
Prefer – Safer Chemical
A full GreenScreen always trumps results from GreenScreen List Translator
• It does NOT review transformation products
• It does NOT identify safer chemicals
Pharos Chemical and Material Library (CML)
The Wercs GreenWERCS
Automation of the GS List Translator: Software Partners
13
GreenScreen® Assessment
1. Assess and classify hazards
2. Apply the Benchmarks
3. Make informed decisions
GreenScreen Hazard Endpointsitalic – not typically in DfE AA Table
Human Health Group I
Human Health Group II and II*
Environmental Toxicity & Fate
Physical Hazards
Carcinogenicity Acute Toxicity Acute Aquatic Toxicity (3 species) Reactivity
Mutagenicity & Genotoxicity
Systemic Toxicity & Organ Effects
Chronic Aquatic Toxicity (3 species)
Flammability
Reproductive Toxicity
Neurotoxicity Other Ecotoxicity studies when
available
Developmental Toxicity
Skin Sensitization PersistenceRespiratory Sensitization
Endocrine Activity Skin Irritation BioaccumulationEye Irritation
Assess & Classify Hazards
• Literature review• Test Data• Analogs/Surrogates• Q/SAR Models• Hazard Lists
Step 1: Populate Hazard Summary Table
Level of Concern: • vH = very High L = Low • H = High vL =
very Low • M = Moderate DG = Data
Gap
Level of Confidence: • Bold = High confidence• Italics = Low confidence
Green Screen Hazard Ratings
Group I Human Group II and II* Human Ecotox Fate Physical
Carcinogenici
ty
Mutagenicit
y
Reproductiv
e Toxicity
Developmental
Toxicity
Endocrine
Activity
Acute
Toxicity
Systemic Toxicity
Neurotoxicity
Skin Sensitization
*
Respiratory
Sensitization
*
Skin Irritatio
n
Eye Irritatio
n
Acute
Aquatic Toxicity
Chronic
Aquatic Toxicity
Persistence
Bioaccumulatio
n
Reactivity
Flammabili
ty
single repeated* single repeated
* * *
L L L M M L L L vH H L DG L L H H vL L M L
Step 2: Apply GreenScreen Benchmarks
Aligned with Regulatory Drivers
Benchmark U = Undetermined due to insufficient data
Step 3: Make Informed Decisions
• Simple integer score (1-4) supports taking action
• Drives adoption of preferred materials
• Drives innovation of new materials
Benchmark 4
Prefer – Safer Chemical
Benchmark 3
Use but Still Opportunity for Improvement
Benchmark 1
Avoid – Chemical of High Concern
Benchmark 2
Use but Search for Safer Substitutes
Benchmark U = Undetermined due to insufficient data
GreenScreen Inside
1. State Regulations
2. Alternatives Assessment
3. Materials Procurement
4. Product Development
5. Corporate Policies
6. Software Tools
7. Standards, Scorecards and Ecolabels
Summary of GS
• GreenScreen for Safer Chemicals
Method for Chemical Hazard Assessment
Use to evaluate individual chemical hazards &
assess alternatives
Evaluates chemicals in materials and products
Supports range of activities from product design,
development, procurement, alternatives
assessment, regulations, standards and ecolabels