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Marine carbon from space Jamie Shutler, University of Exeter, UK [email protected]

Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

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Page 1: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon from spaceJamie Shutler, University of Exeter, UK

[email protected]

Page 2: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

The importance of monitoring the oceans

Page 3: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Passive microwave – key for monitoring marine carbon

1 GHz 200 GHz

salinity(dielectric)

sea surfacetemperature

wind rain watervapour

ice

Parameters important for studying marine carbon and exchange

foam

Highlight further potential of passive microwave measurements.

Page 4: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Passive microwave – key for monitoring marine carbon

1 GHz 200 GHz

salinity(dielectric)

sea surfacetemperature

wind rain watervapour

ice

Parameters important for studying marine carbon and exchange

foam

Highlight further potential of passive microwave measurements.

Page 5: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Page 6: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Visible spectrum ocean colourobservations

Page 7: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Visible spectrum ocean colour observations (but could use passive microwave!)

Page 8: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

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Page 9: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 10: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 11: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Visible spectrum ocean colourobservations

Page 12: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Particulate Inorganic Carbon (PIC)

coccolithophores

Emiliania huxleyi

Visible spectrum ocean colourobservations

Page 13: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Particulate Inorganic Carbon (PIC)

coccolithophores

Emiliania huxleyi

Sensor: SeaWiFS, 1997-2009 accumulated coverage

Visible spectrum ocean colourobservations

Page 14: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Visible spectrum ocean colourobservations

Page 15: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Dissolved organic carbon (DOC)DOC has many components, one is Colored Dissolved Organic Matter (CDOM)DOC correlates with aCDOM in coastal, estuarine and shelf seas.Regional approaches, exploit DOC-aCDOM-salinity linkages.Published methods ocean colour satellite sensors.

Stocks:Del Castillo and Miller, 2008; Mannino et al., 2008; Griffin et al., 2011; López et al., 2012; Liu et al., 2014; Mannino et al., 2016.

Fluxes:Del Castillo and Miller, 2008; López et al., 2012; Mannino et al., 2016

Mannino et al., 2016Liu et al., 2014

Page 16: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

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Page 17: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Ocean acidification (inorganic carbon)

Increasing pCO2 decreases the pH of the water (CO2

reacts with water for form carbonic acid which releases H+ ions and reduces the pH). So, known as ‘the other CO2

problem’.

Page 18: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Ocean acidification (inorganic carbon)

Increasing pCO2 decreases the pH of the water (CO2

reacts with water for form carbonic acid which releases H+ ions and reduces the pH). So, known as ‘the other CO2

problem’.

Determining two parameters along with knowledge of salinity and temperature enables you to resolve whole system.

Page 19: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Ocean acidification (inorganic carbon)

Jiang et al., 2014

Increasing pCO2 decreases the pH of the water (CO2

reacts with water for form carbonic acid which releases H+ ions and reduces the pH). So, known as ‘the other CO2

problem’.

Alkalinity is highly correlated (conserved) with salinity (and temperature).

DIC highly correlated with temperature (and salinity)

Page 20: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

L-band Salinity and thermal infrared temperature from space allows space-based observations of total alkalinity (AT) and DIC.Exploit salinity-alkalinity relationships via regional empirical algorithms

Capability from space identified by:

Land et al., 2015Salisbury et al., 2015

major DICComponent(~85%)

Ocean acidification (inorganic carbon)

Page 21: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

IF of 5.2

Review and forward look

Highlights that L-band salinity

from space enables us to monitor

and study marine carbonate

parameters.

Page 22: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

ESA Pathfinders Ocean Acidification project

GreaterCaribbean

Bay of Bengal

Barents sea

SMOS salinity for October 2010 (blue-red)Sea ice (green)

Amazon Plume

Page 23: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Underlying map from Salisbury et al., 2011

2400

L-band & SST -Total alkalinity time series

Page 24: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Underlying map from Salisbury et al., 2011

SouthAmerica

AT

2400

1400

μmol kg-1

L-band & SST -Total alkalinity time series

Page 25: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 26: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Upwelling: mostly a wind driven effect

Offshore: Ekman pumping

driven by the divergence or convergence of the surface

e.g. the wind stress curl in hurricanes.

Coastal: Ekman transport and pumping

Across most continental shelves, especially eastern

boundaries of ocean basins (forced by wind systems).

Low temperature upwelling waters bring nutrients, but also low pH water to the surface.Low pH can upset food webs, growth, reproduction and energy balances of marine animals.

Identifying regions of upwelling -episodic low pH events

Page 27: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Upwelling: mostly a wind driven effect

Offshore: Ekman pumping

driven by the divergence or convergence of the surface

e.g. the wind stress curl in hurricanes.

Coastal: Ekman transport and pumping

Across most continental shelves, especially eastern

boundaries of ocean basins (forced by wind systems).

Low temperature upwelling waters bring nutrients, but also low pH water to the surface.Low pH can upset food webs, growth, reproduction and energy balances of marine animals.

Identifying regions of upwelling -episodic low pH events

Page 28: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Identifying regions of upwelling -episodic low pH events

Hurricane Igor, 2010 Chuckchi and Beaufort seas

Example are from scatterometer data (active microwave, 25-50 km).

Page 29: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Marine carbon cycle

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Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 30: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Atmosphere

Surface ocean

Deep ocean

F = k (αw pCO2w – αs pCO2a )

F solF bioF mix

pCO2a

pCO2w

Atmosphere-ocean gas fluxes (ocean carbon sink)

Using: Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 31: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Atmosphere

Surface ocean

Deep ocean

F = k (αw pCO2w – αs pCO2a )

F solF bioF mix

pCO2a

pCO2w

Atmosphere-ocean gas fluxes (ocean carbon sink)

Using: Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 32: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Atmosphere

Surface ocean

Deep ocean

F = k (αw pCO2w – αs pCO2a )

F solF bioF mix

pCO2a

pCO2w

Atmosphere-ocean gas fluxes (ocean carbon sink)

Using: Thermal infrared/passive microwave (SST), passive microwave (SSS), passive and active microwave (wind, ice)

Page 33: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Atmosphere-ocean gas fluxes (ocean carbon sink)

Page 34: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Toolbox developed for community use:• Open source license (python and PERL based).

• Standard NetCDF data input and output.

• Net flux tool with traceable land/ocean/basin templates.

• User configurable gas flux calculation.

• Extensively verified using published data.

Shutler, J. D., Piolle, J-F., Land, P., Woolf, D. K., Goddijn-Murphy L.,, Paul, F., Girard-Ardhuin, F., Chapron, B.,

Donlon, C. J., (2016) Flux Engine: A flexible processing system for calculating air-sea carbon dioxide gas fluxes

and climatologies, Journal of Atmospheric and Oceanic Technology.

Example process indicator layer output using

ESA Climate Change Indices chl-aExample mean daily flux output

FluxEngine – gas flux toolbox

Page 35: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Toolbox developed for community use:• Open source license (python and PERL based).

• Standard NetCDF data input and output.

• Net flux tool with traceable land/ocean/basin templates.

• User configurable gas flux calculation.

• Extensively verified using published data.

Shutler, J. D., Piolle, J-F., Land, P., Woolf, D. K., Goddijn-Murphy L.,, Paul, F., Girard-Ardhuin, F., Chapron, B.,

Donlon, C. J., (2016) Flux Engine: A flexible processing system for calculating air-sea carbon dioxide gas fluxes

and climatologies, Journal of Atmospheric and Oceanic Technology.

Example process indicator layer output using

ESA Climate Change Indices chl-aExample mean daily flux output

FluxEngine – gas flux toolbox

Page 36: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Atmosphere-ocean gas fluxes (ocean carbon sink)

Page 37: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Passive microwave – key for monitoring marine carbon

1 GHz 200 GHz

salinity(dielectric)

sea surfacetemperature

ice

Parameters important for studying marine carbon and exchange

wind rainfoamwatervapour

Page 38: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Atmosphere

Surface ocean

Deep ocean

F = k (αw pCO2w – αs pCO2a )

F solF bioF mix

pCO2a

pCO2w

Some sort of turbulence description called the gas transfer velocity

Atmosphere-ocean gas fluxes and exchange (ocean carbon sink)

Page 39: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Gas exchange at the water surface

Page 40: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Gas exchange at the water surface

Page 41: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Gas exchange at the water surface

Page 42: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Gas exchange at the water surface

Page 43: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Gas exchange at the water surface

Page 44: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Gas exchange at the water surface

Page 45: Marine carbon from space - ECMWF · marine carbon. • They are currently being used extensively in synergy with other measurements, both in situ and others from space. • But the

Summary• Monitoring ocean carbon is key to enable us:

– i) to track our progress towards reaching the goals of the historic Paris climate agreement,

– ii) identify and monitor ecosystems at risk of ocean acidification events.

• Passive microwave measurements are key for studying and monitoring marine carbon.

• They are currently being used extensively in synergy with other measurements, both in situ and others from space.

• But the full potential of the use of passive microwave, including L band, for marine carbon research is largely unexplored.

Jamie Shutler, University of Exeter, [email protected]