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Petroleum Recovery Research Center A Division of New Mexico Institute of Mining and Technology 801 Leroy Place Socorro, NM 87801 Address Service Requested M Non-Profit Organization U.S. Postage Paid SOCORRO, NM PERMIT NO. 9 New Mexico Institute of Mining and Technology Daniel H. López, President Board of Regents Ex Officio Susana Martinez, Governor of New Mexico Dr. Jose J. Garcia, Secretary of Higher Education Appointed Richard N. Carpenter, Santa Fe, President, Santa Fe Jerry A. Armijo, Socorro Deborah Peacock, Corrales Deborah Hicks, Hobbs Israel Rodriguez-Rios, Student Regent, Socorro Petroleum Recovery Research Center A Division of New Mexico Tech The PRRC is a state-supported center that conducts research on improving methods of recovering crude oil and natural gas and that transfers petroleum technology to domestic oil producers. Funding for the PRRC comes from three sources: the State of New Mexico, the federal government (Department of Energy), and private industry. PRRC Oil price data from PRRC's OCTANE web- site. Prices are NYMEX, through June 30, 2013. PRRC Biannual Newsletter Volume 28, No. 2: FALL 2013 The Petroleum Recovery Research Center is a division of the New Mexico Institute of Mining and Technology (cont'd, p. 2) PRRC CCUS PROJECT MOVING FORWARD Led by the PRRC, a large-scale re- search project in an active Texas enhanced oil recovery operation is moving forward with field activi- ties. The Southwest Regional Part- nership on Carbon Sequestration’s (SWP) carbon capture, utilization, and storage (CCUS) deployment phase (Phase III) recently had its project site approved by DOE and a contract signed between the prime, the New Mexico Institute of Mining and Technology, and its new indus- of the injection and movement of large amounts of CO 2 in an ongo- ing enhanced oil recovery project. Project goals include storage ca- pacity verification and storage per- manence. Selection of this field site was in response to DOE/NETL’s CCUS program objectives, which desire an existing CO 2 –EOR project in the Southwest Region, one of seven re- gions designated by the DOE in its carbon sequestration program. The SWP sought an active CO 2 -EOR site for Phase III that would essentially be a field lab for evaluating the efficacy of monitor- ing technologies and for testing and refining forecasts of CO 2 be- havior underground. With its new industrial partner, the SWP will gain expert feedback from an ex- perienced company who offers tan- gible insight into industry priori- ties and concerns with CCUS. The SWP is verifying technologies that will support our industry partner's ability to predict and confirm CO 2 storage capacity in geologic forma- tions. The SWP commends the environmentally-conscious CO 2 - EOR work of CELLC; in particu- lar, CELLC is using anthropogenic CO 2 for EOR in the FWU. In this project, CO 2 that is an industrial byproduct from an ethanol plant in trial partner, Chaparral Energy, LLC (CELLC). Chaparral Energy is an inde- pendent oil and gas producer and operator headquartered in Oklaho- ma City with field offices through- out the south-central US. Chaparral began operating in 1988 and has grown steadily. The company is ex- perienced in CO 2 -EOR in mature fields. The primary objectives of this project comprise a broadly-defined range of testing and monitoring Researchers visit the Farnsworth Unit Project site in the Texas panhandle during the SWP Project Review on November 20, 2013. The Unit is part of an active CO2-EOR site operated by SWP's industrial partner, Chaparral Energy, LLC. Photo courtesy of Mark White, Pacific Northwest National Laboratory.

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Petroleum Recovery Research Center A Division ofNew Mexico Institute of Mining and Technology801 Leroy PlaceSocorro, NM 87801

Address Service Requested

MNon-Profit Organization

U.S. PostagePaid

Socorro, NMPERMIT NO. 9

New Mexico Institute of Mining and TechnologyDaniel H. López, President

Board of RegentsEx Officio

Susana Martinez, Governor of New MexicoDr. Jose J. Garcia, Secretary of Higher Education

AppointedRichard N. Carpenter, Santa Fe, President, Santa Fe

Jerry A. Armijo, SocorroDeborah Peacock, Corrales

Deborah Hicks, HobbsIsrael Rodriguez-Rios, Student Regent, Socorro

Petroleum Recovery Research CenterRobert Lee, Director

Senior StaffRobert Balch, Research ScientistJill S. Buckley, Senior Scientist

Martha Cather, Industrial Technology CoordinatorReid B. Grigg, Senior Engineer

Ning Liu, Research ScientistRandall S. Seright, Senior Engineer

PRRC Publications OfficeLiz Bustamante, Editor

This newsletter is produced by the PRRC Publications Office. Views expressed are those of the PRRC staff. Submissions and letters to the editor are welcome. Reprints from the PRRC Review are permitted, provided that credit is given to the New Mexico PRRC. Please send two copies of the publication containing the reprint to Liz Bustamante, PRRC, New Mexico Tech, 801 Leroy Place, Socor ro, NM 87801. PHONE: (575) 835-5406. FAX (575) 835-6031. EMAIL: [email protected]. WEBSITE: http://baervan.nmt.edu

Petroleum Recovery Research CenterA Division of New Mexico Tech

The PRRC is a state-supported center that conducts research on improving methods of recovering crude oil and natural gas and that transfers petroleum technology to domestic oil producers. Funding for the PRRC comes from three sources: the State of New Mexico, the federal government (Department of Energy), and private industry.

PRRC

Oil price data from PRRC's OCTANE web-site. Prices are NYMEX, through June 30, 2013.

PRRC Biannual NewsletterVolume 28, No. 2: FALL 2013

The Petroleum Recovery Research Center is a division of the New Mexico Institute of Mining and Technology

(cont'd, p. 2)

PRRC CCUS PROJECT MOVING FORWARD

Led by the PRRC, a large-scale re-search project in an active Texas enhanced oil recovery operation is moving forward with field activi-ties. The Southwest Regional Part-nership on Carbon Sequestration’s (SWP) carbon capture, utilization, and storage (CCUS) deployment phase (Phase III) recently had its project site approved by DOE and a contract signed between the prime, the New Mexico Institute of Mining and Technology, and its new indus-

of the injection and movement of large amounts of CO2 in an ongo-ing enhanced oil recovery project. Project goals include storage ca-pacity verification and storage per-manence. Selection of this field site was in response to DOE/NETL’s CCUS program objectives, which desire an existing CO2–EOR project in the Southwest Region, one of seven re-gions designated by the DOE in its carbon sequestration program. The SWP sought an active CO2-EOR site for Phase III that would essentially be a field lab for evaluating the efficacy of monitor-ing technologies and for testing and refining forecasts of CO2 be-havior underground. With its new industrial partner, the SWP will gain expert feedback from an ex-perienced company who offers tan-gible insight into industry priori-ties and concerns with CCUS. The SWP is verifying technologies that will support our industry partner's ability to predict and confirm CO2 storage capacity in geologic forma-tions. The SWP commends the environmentally-conscious CO2-EOR work of CELLC; in particu-lar, CELLC is using anthropogenic CO2 for EOR in the FWU. In this project, CO2 that is an industrial byproduct from an ethanol plant in

trial partner, Chaparral Energy, LLC (CELLC). Chaparral Energy is an inde-pendent oil and gas producer and operator headquartered in Oklaho-ma City with field offices through-out the south-central US. Chaparral began operating in 1988 and has grown steadily. The company is ex-perienced in CO2-EOR in mature fields. The primary objectives of this project comprise a broadly-defined range of testing and monitoring

Researchers visit the Farnsworth Unit Project site in the Texas panhandle during the SWP Project Review on November 20, 2013. The Unit is part of an active CO2-EOR site operated by SWP's industrial partner, Chaparral Energy, LLC. Photo courtesy of Mark White, Pacific Northwest National Laboratory.

page 2 pRRC biannual newsletteR page 3 pRRC biannual newsletteR

a division of the new mexiCo institute of mining and teChnology a division of the new mexiCo institute of mining and teChnology

Publications, PresentationsNew Project (cont'd from p. 1) Kansas and a fertilizer plant in Tex-as is being used.     The  field  site  for  the  SWP’s Phase  III  program  is  CELLC’s Farnsworth Unit  (FWU), Ochiltree County,  in  the Anadarko  Basin  of northern Texas. The FWU, covering over 20 square miles, is located in a sparsely populated, fully developed agricultural area with both dry and irrigated farming, where the surface area  has  been  cultivated  for  many decades.      The FWU started development in  the  mid  1950s;  currently,  it  is part of an existing CO2–EOR proj-ect  that started  injection December 2010  and  will  continue  to  expand for several years.     The Farnsworth EOR target is the  Morrow  formation,  an  incised valley-fill  sandstone  that  extends from eastern Colorado and western Kansas  through Oklahoma into  the Texas  panhandle.  As  of  2005,  the Morrow  had  produced  more  than 100 million  barrels  of  oil  and  500 billion cubic feet of gas. A conserva-tive estimate of  the Morrow’s CO2 storage  capacity  within  the  FWU exceeds 10 million metric tons.     The SWP will examine current-ly  flooded  areas  and  also  establish surface  and  subsurface  monitoring baselines in areas that have not seen CO2; then it will monitor CO2 injec-tion.  In addition to the monitoring, verification, and accounting (MVA) of injected CO2, extensive reservoir characterization and reservoir mod-eling will be performed.     The MVA techniques that will be used include analysis of injection rates;  production  well  rates;  sam-pling of water, oil, and gas; tracers; groundwater chemistry monitoring; 

surface and downhole pressure and temperature;  soil gas  sampling;  re-peat seismic surveys; and other ap-plicable methods.    Some  field  operations  began earlier  in  the  year.  A  3D  surface seismic survey was shot in January and February that covered the entire FWU, for site and reservoir charac-terization,  possible  CO2  identifica-tion, and calibration of instruments for other seismic tests. Pre-process-ing of the data was finished in June 2013 and  interpretation of  the data is ongoing. Baseline water and soil measurements  for monitoring have also begun.

CCUS and CO2-EORCarbon  dioxide  flooding  has  been used by oil producers for enhanced oil recovery (EOR) for the last four decades, using CO2  from both nat-

urally-occurring and anthropogenic sources.    In an effort  to mitigate green-house gases  in  the atmosphere,  the US DOE has implemented a carbon capture and storage (CCS) program that involves the removal and long-term storage of CO2 from the atmo-sphere.  The  SWP  is  one  of  seven Regional  Carbon  Storage  Partner-ships,  established  by  DOE  to  ad-dress  regional  storage  approaches for greenhouse gases.    Recently,  DOE’s  carbon  cap-ture objective has moved to encom-pass carbon capture, utilization and storage (CCUS), which include the added value of an EOR component. In this way, DOE looks forward to future  partnership  with  research organizations  and  industry  in  es-tablishing  techniques  for  the  large-scale capture and storage of CO2.

Balch, R. “Cost-Effective Treat-ment of Produced Water Using Co-Produced Energy Sources: Phase II Field Scale Demonstration and Commercialization,” RPSEA Proj-ect No. 11123-03, presented at the RPSEA Onshore Production Con-ference/ TORP Technology Trans-fer Workshop, Wichita, Kansas, June 27, 2013.

Balch, R. “Field Testing and Diag-nostics of Radial-Jet Well-Stimu-lation for Enhanced Oil Recovery from Marginal Reserves,” RPSEA Project 09123-03, presented at the RPSEA Onshore Production Con-ference/ TORP Technology Trans-fer Workshop, Wichita, Kansas, June 27, 2013.

Balch, R., Bell, J., and Will, B. (2013). “Seismic Data Review and Discussion.” Presented at the Southwest Partnership Phase III Kickoff Meeting, April 9-10, 2013, Oklahoma City, Oklahoma.

Esser, R., Liu, N., Grigg, R., and McPherson, B. (2013). “Monitor-ing, Verification and Accounting at the Farnsworth Unit.” Presented at the Southwest Partnership Phase III Kickoff Meeting, Oklahoma City, Oklahoma, April 9–10.

Grigg, R. and McPherson, B. (2013). “Phase III – Deployment Phase, Farnsworth Unit CCUS, Ochiltree, Texas.” Presented at the Southwest Partnership Phase III Kickoff Meet-ing, April 9-10, 2013, Oklahoma City, Oklahoma.

Liu, N. (2013) "Nanoparticle-stabi-lized CO2 Foam for Mobility Control in CO2 EOR." Presented at the 2013 International Symposium on Oilfield Chemistry, Qingdao, China, June 26–28, 2013.

Manichand, R.N., Moe Soe Let, K.P., Gil, L., Quillien, B., and Seright, R.S. (2013). “Effective Propaga-tion of HPAM Solutions through

the Tambaredjo Reservoir during a Polymer Flood.” Paper SPE 164121 presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands,TX. April 8–10. Ye, G. (2013). “A Study of the Ef-fects of Salinity on the Viscosity of a Polymer Solution.” MS thesis, New Mexico Institute of Mining and Tech-nology, Socorro, New Mexico.

Yu, J., Mo, D., Liu, N., and Lee, R. (2013) “The Application of Nanopar-ticle-Stabilized CO2 Foam for Oil Recovery.” Paper SPE 164074 presented at the SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, April 8–10.

Yota, G. (2013) "Carbon Dioxide Sequestration in Deep Saline Aqui-fers." MS thesis, New Mexico Insti-tute of Mining and Technology, So-corro, New Mexico.

    The  project  is  supported  and managed by DOE's National Energy Technology Laboratory. The  Phase III project budget  is approximately $83 million, of which about $57M has  been  committed  by  the  US DOE.  The balance will be provided by the participating organizations.     The  project  is  a multi-faceted effort by a number of entities. New Mexico  Tech  is  the  lead  organiza-tion and prime DOE contractor, with Project Director Dr. Robert Lee, Di-rector of the PRRC. Dr. Reid Grigg of the PRRC and Dr. Brian McPher-son of the University of Utah/NMT 

are  Co-Principal  Investigators  of the project, who will direct project engineering and project science re-spectively.     Other  research  organizations currently  involved  in  this  research project are NETL, Los Alamos Na-tional  Laboratory,  Sandia  National Laboratories,  Pacific  Northwest National  Laboratory,  University  of Utah, the Utah Science, Technology and  Research  (USTAR)  initiative, the  Utah  Geological  Survey,  the University  of  Missouri,  Oklahoma Geological  Survey,  and  Schlum-berger Carbon Services.

Kickoff MeetingSWP  held  the  FWU  Site  Kickoff Meeting in Oklahoma City on April 9–10,  2013.  The  Kickoff  Meeting covered site geology, past and pres-ent  activities,  and  the  future  EOR and  monitoring/risk/characteriza-tion/simulation activities. 

SWP WebsiteThe new public SWP website went online  in  January,  at  http://www.southwestcarbonpartnership.org. The  website  chronicles  the  activi-ties of the SWP and provides links to CCUS resources and FAQs. It is administered through NM Tech.

(cont'd, p. 3)

New Project (cont'd from p. 2)

PRRC graduate students at the Farnsworth Site tour: l to r, Paige Czoski (Geophysics), Sara Gallagher (Earth and Environmental Engineering), and Ashley Hutton (Geophysics). Photo courtesy of Mark White, Pacific North-west National Laboratory.