Luprintol Multifunction SL-S MSDS

8/17/2019 Luprintol Multifunction SL-S MSDS

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Safety Data Sheet in accordance withRegulation (EU) No.453/2010

Luprintol Multifunction SL-S Page 1(13)

Substance key: B0174 Revision Date: 25.06.2015

Version : 1 - 1 / EU Date of printing : 16.11.2015

SECTION 1: Identification of the substance/mixture and of the

company/undertaking

1.1. Product identifier

Trade name

Luprintol Multifunction SL-S

Material number: 281301

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses of the substance or mixture

Industry sector : Textile processing industryType of use : Auxiliary for the textile industry

1.3. Details of the supplier of the safety data sheet

Identification of the company Archroma Management GmbH

Neuhofstrasse 114153 Reinach, SwitzerlandTelephone no. : +41 61 716 3401

Information about the substance/mixtureProduct Stewardship +41 61 716 3401e-mail: [email protected]

1.4. Emergency telephone number

+44 (0) 1235 239 670 (24 h)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)

Not a dangerous substance according to GHS.

2.2. Label elements

Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)Not a dangerous substance according to GHS.

Sensitizing components / contains :

FormaldehydeMay produce an allergic reaction.

2.3. Other hazards

No additional hazards are known except those derived from the labelling.


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SECTION 3: Composition/information on ingredients

3.2. Mixtures

Chemical characterizationin aqueous/organic dispersion

PolycondensedNonionic surfactants

Hazardous ingredients

Diethylene glycol Concentration : >= 1 - < 3 %CAS number : 111-46-6

EC number: 203-872-2 Index Number 603-140-00-6

Classification hazard substance EC

Xn Harmful R22

GHS classification EC

Acute toxicity Category 4 H302

Specific target organ

toxicity - repeatedexposure

Category 2 H373

Propan-2-ol

Concentration : >= 0,1 - < 1 %CAS number : 67-63-0EC number: 200-661-7 Index Number 603-117-00-0


F Highly flammable R11

Xi Irritant R36

R67


Flammable liquids Category 2 H225Eye irritation Category 2 H319

Specific target organtoxicity - single exposure

Category 3 H336

Methanol

Concentration : > 0,1 - < 1 %CAS number : 67-56-1EC number: 200-659-6

Index Number 603-001-00-X


F Highly flammable R11

T Toxic R23/24/25

R39/23/24/25


Flammable liquids Category 2 H225


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Specific target organtoxicity - single exposure

Category 1 H370

Formaldehyde

Concentration : < 0,1 %CAS number : 50-00-0EC number: 200-001-8

Index Number 605-001-00-5


Carc.Cat.3 Carcinogenic Category 3 R40

T Toxic R23/24/25

C Corrosive R34

R43





Skin corrosion Category 1B H314

Skin sensitisation Category 1 H317Carcinogenicity Category 2 H351

The text of the R-phrases is shown in section 16.

The text of the H-phrases is shown in section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information

Remove/Take off immediately all contaminated clothing.

After inhalationRemove person to fresh air. If signs/symptoms continue, get medical attention.

After contact with skin After contact with skin, wash immediately with plenty of soap and water.

Get medical attention immediately if irritation persists.

After contact with eyesIn case of contact, immediately flush eyes with plenty of water for at least 15 minutes.If eye irritation persists, consult a specialist.

After ingestion

Rinse out mouth and give plenty of water to drink.

4.2. Most important symptoms and effects, both acute and delayed


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SymptomsThe possible symptoms known are those derived from the labelling (see section 2).

No symptoms known currently.

HazardsNo additional hazards are known except those derived from the labelling.

4.3. Indication of any immediate medical attention and special treatment needed

TreatmentThere is no specific antidote available.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing mediaWater spray

Dry powderFoam

5.2. Special hazards arising from the substance or mixtureIn case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)Carbon dioxide (CO2)

Nitrogen oxides (NOx)

5.3. Advice for firefighters

Further informationThe degree of risk is governed by the burning substance and the fire conditions

Extinguishing water is to be disposed of in accordance with local authority regulations

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective equipment.Self-contained breathing apparatus

6.2. Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

6.3. Methods and material for containment and cleaning up

Pump up larger quantities.

Pick up rest with absorbent material (e.g. sand, sawdust).Dispose of absorbed material in accordance with the regulations.

6.4. Reference to other sections

Additional informationInformation regarding Safe handling, see chapter 7.


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SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

No special measures necessary if stored and handled as prescribed.

Hygiene measuresDo not eat, drink or smoke when using this product.

7.2. Conditions for safe storage, including any incompatibil ities

Requirements for storage areas and containersKeep containers tightly closed in a cool, well-ventilated place.Should not be released into the environment.

Advice on storage compatibility

Keep away from food, drink and animal feeding stuffs.

Further information on storage conditionsKeep tightly closed in a dry, cool and well-ventilated place.

Storage stabilityStorage temperature: 5 - 40 °C

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 isto be observed.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limit valuesmethanolEC number: 200-659-6

CAS number : 67-56-1

Regulatory basis / Regulatory list Revision Type of value Values RemarksEurope. Indicative occupational exposurelimit valuesEU. Commission Directive 2006/15/EC

2006-02-09 Limit Value -eight hours

260 mg/m3200 ppm

DNEL/DMEL values

FormaldehydeEC number: 200-001-8 CAS number : 50-00-0

Route of exposure Personnel Exposure time/Effect Value Remarks

Inhalation Workers Acute system ic effects 1 mg/m30,8 ppm

DNEL

Inhalation Workers Acute local effects 1 mg/m3

0,8 ppm

DNEL

Inhalation Workers Long-term systemic effects 0 mg/m30,4 ppm

DNEL


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Inhalation Workers Long-term local effects 0 mg/m30,4 ppm

DNEL

Dermal Workers Long-term systemic effects 240 mg/kg DNEL

Dermal Consumers Long-term systemic effects 102 mg/kg DNEL

Oral Consumers Long-term systemic effects 4,1 mg/kg DNEL

Dermal Consumers Long-term local effects 0,012 mg/cm2 DNEL

Inhalation Consumers Long-term systemic effects 3,2 mg/l DNEL

Inhalation Consumers Long-term local effects 0,1 mg/m3 DNEL

PNEC values

FormaldehydeEC number: 200-001-8

CAS number : 50-00-0

Environmentalcompartment

Personnel/Exposure time/Effect Value

Fresh water 0,47 mg/l

salt water 0,47 mg/l

Water (intermittentrelease)

4,7 mg/l

Fresh watersediment

2,44 mg/l

Marine sediment 2,44 mg/l

Soil 0,21 mg/l

Sewage treatmentplant

0,19 mg/l

8.2. Exposure controls

Respiratory protection : Protection necessary if aerosols or vapors should develop.

P2 filter

Hand protection : Chemical resistant glovesTake note of the information given by the producer concerningpermeability and break through times, and of special

workplace conditions (mechanical strain, duration of contact).

Eye protection : Safety glasses with side-shields conforming to EN166

Body protection : The choice of skin protection should be based on the jobactivity and potential for exposure to the skin.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : liquid ( 20 °C )

Form : liquid

Particle size : not applicable

Colour : white yellowish

Odour : Product specific

Odour threshold : not applicable


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pH value : approx. 8 - 10 (20 °C)(undiluted)

Melting point : not applicable

Boiling point : not determined

Sublimation point : not applicable

Flash point : > 100 °C

Method : DIN 51758

Evaporation rate : Value can be approximated from Henry's Law Constant or

vapor pressure.

Flammability : The product is not flammable.Method : Flash point

Lower explosion limit : Not relevant

The lower explosion point may be 5 - 15 °C below the flashpoint.

Upper explosive limit : Not relevant

Combustion number : not applicable

Minimum ignition energy : not tested.

Vapour pressure : not applicable

Solubility in water : soluble

Octanol/water partitioncoefficient (log Pow) :

Study scientifically not justified.

Ignition temperature : not determined

Self-ignition temperature : not auto-flammable

Thermal decomposition : No decomposition if used as directed.

Viscosity (dynamic) : not determined

Explosive properties : Explosive according to EU supply regulations : Not explosive

Explosive according transport regulation : Not explosive

Oxidizing properties : Type of oxidizing effect : not oxidizing

9.2. Other information

Density : approx. 1,1 g/cm3 (20 °C)

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reaction known under conditions of normal use.

10.2. Chemical stabilityStable under normal conditions.

10.3. Possibility of hazardous reactions


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No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid

Avoid Heat, Open Flames And Sparks.

10.5. Incompatible materials

Strong acidsStrong bases

Strong oxidizing agents

10.6. Hazardous decomposition products

No hazardous decomposition products are known.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information related to the product itself:

Acute oral toxicity : LD50 > 2.000 mg/kg (rat)

Acute dermal toxicity : not tested.

Acute inhalation toxicity : not tested.

Irritant effect on skin : No skin irritation (rabbit)

Method : OECD Test Guideline 404

Irritant effect on eyes : No eye irritation (rabbit)

Method : OECD Test Guideline 405

Sensitization : not tested.

Repeated dose toxicity: not tested.

Genetic toxicity in vitro : not tested.

Assessment of mutagenicity : Based on the ingredients, there is no suspicion of a mutagenic

effect.

Assessment ofcarcinogenicity :

The whole of the information assessable provides noindication of a carcinogenic effect.

Specific target organ toxicity(STOT) - repeated exposure :

According to experience and to the information available, theproduct has no harmful effects on health if used correctly and

for the intended purpose.The product has not been tested. The information is derivedfrom the properties of the individual components.

Aspiration hazard :

No aspiration toxicity classification

RemarksThe product has not been tested. The information is derived from the properties of theindividual components.


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Information related to the component: Propan-2-ol

Acute oral toxicity : LD50 5.280 mg/kg (rat)

Acute dermal toxicity : LD50 12.800 mg/kg (rabbit)

Acute inhalation toxicity : LC50 72,6 mg/l (4 h, rat)

Information related to the component: Methanol

Acute oral toxicity : LD0 428 mg/kg (Humans) Acute toxicity estimate 100 mg/kg

Method : Converted acute toxicity point estimateAcute dermal toxicity : Acute toxicity estimate 300 mg/kg

Method : Converted acute toxicity point estimate

Information related to the component: Formaldehyde

Acute oral toxicity : LD50 800 mg/kg (rat)

Acute toxicity estimate 100 mg/kgMethod : Converted acute toxicity point estimate

SECTION 12: Ecological information

12.1. Toxicity


Fish toxicity : LC50 > 100 mg/l (96 h, Leuciscus idus (Golden orfe))

Daphnia toxicity : not tested.

Algae toxicity : not tested.

Bacteria toxicity : not tested.


Fish toxicity : Test data for the substance are not available.

Information related to the component:

Methanol

Fish toxicity : LC50 19.000 mg/l (96 h, Oncorhynchus mykiss (rainbowtrout))

Daphnia toxicity : LC50 > 10.000 mg/l (24 h)

Bacteria toxicity : IC50 > 1.000 mg/l (3 h, activated sludge)

12.2. Persistence and degradabil ity


Biodegradabili ty : 20 - 70 % (28 d)Moderately/partially eliminated from water.

Method : Zahn-Wellens Test



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Biodegradabili ty : 95 %Readily biodegradable.


Biodegradabili ty : 99 % (28 d)Method : OECD Test Guideline 301D

12.3. Bioaccumulative potential


Bioaccumulation: not tested.


Bioaccumulation: Test data for the substance are not available.


Bioaccumulation: Due to the low logPow bioaccumulation is not expected

12.4. Mobility in soil


Behaviour in environmental compartments

no data available


Transport and distributionbetween environmental

compartments :

Test data for the substance are not available.

12.5. Results of PBT and vPvB assessment


According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration,

Evaluation, Authorisation and Restriction of Chemicals (REACH):The product does not

contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or t he vPvB(very persistent/very bioaccumulative) criteria.


no data available

12.6. Other adverse effects



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Additional ecotoxicological remarksProduct must not be released into water without pre-treatment.If handled correctly it causes no disturbance in treatment plants.

The product has not been tested. The information is derived from the properties of theindividual components.The product has not been tested. The information is derived from the properties of the

individual components.


Additional ecotoxicological remarksslightly water endangering

SECTION 13: Disposal considerations

13.1. Waste treatment methods

ProductProduct should be be taken to a suitable and authorized waste disposal site inaccordance with relevant regulations and if necessary after consultation with the waste

disposal operator and/or the competent Authorities

Uncleaned packaging

Uncontaminated packaging may be reusedPackaging material which cannot be cleaned is to be disposed of in the same way as

the substance.

SECTION 14: Transport information

Section 14.1. to 14.5.

ADR not restricted

ADN not restricted

RID not restricted

IATA not restricted

IMDG not restricted

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International

Bulk Chemicals Code)

No transport as bulk according IBC - Code.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or

mixture


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Other regulations Apart from the data/regulations specified in this chapter, no further information is availableconcerning safety, health and environmental protection.

15.2. Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for thecomponent substances, contained in this product.

SECTION 16: Other information

Product should be stored, handled and used in accordance with good industrial hygiene practices

and in conformity with legal regulations. The information contained herein is based on the presentstate of our knowledge and is intended to describe our products from the point of view of safetyrequirements. It should therefor not be construed as garanteeing specific properties.

Text of the R-phrases assigned to the ingredients/components mentioned in section 3 :

R11 Highly flammable.

R22 Harmful if swallowed.R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.R34 Causes burns.

R36 Irritating to eyes.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, incontact with skin and if swallowed.

R40 Limited evidence of a carcinogenic effect.R43 May cause sensitisation by skin contact.R67 Vapours may cause drowsiness and dizziness.

List of the text of the hazard statements mentioned section 3 (H-phrases) :

H225 Highly flammable liquid and vapour.H301 Toxic if swallowed.

H302 Harmful if swallowed.H311 Toxic in contact with skin.H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.H331 Toxic if inhaled.

H336 May cause drowsiness or dizziness.H351 Suspected of causing cancer.H370 Causes damage to organs.

H373 May cause damage to organs through prolonged or repeated exposure ifswallowed.

Legend

ADN European Agreement concerning the International Carriage of DangerousGoods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous

Goods by Road AOX Adsorbable organic bound halogensCAS Chemical Abstracts Service

DMEL Derived Minimal Effect Level (genotoxic substances)


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DNEL Derived No Effect LevelEC50 Half maximal effective concentration

GHS Globally Harmonized SystemIATA International Air Transport AssociationIMDG International Maritime Dangerous Goods

LC50 Lethal Concentration 50%LD50 Lethal Dose 50%MARPOL International Convention for the Prevention of Pollution From Ships

NOAEC No Observed Adverse Effect ConcentrationNOAEL No Observed Adverse Effect Level

NOEC Non Observed Effect ConcentrationOEL Occupational Exposure LimitPBT Persistent, Bioaccumulative, ToxicPEC Predicted Environmental Concentration

PNEC Predicted No Effect ConcentrationREACH Registration, Evaluation, Authorisation and Restriction of ChemicalsRID International Rule for Transport of Dangerous Substances by Railway

SVHC Substances of Very High ConcernvPvB very Persis tent and very Bioaccumulative

This information corresponds to the present state of our knowledge and is intended as a generaldescription of our products and their possible applications. Archroma makes no warranties, express or

implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumesno liability in connection with any use of this information. Any user of this product is responsible fordetermining the suitability of Archroma's products for its particular application. Nothing included in thisinformation waives any of Archroma's General Terms and Conditions of Sale, which control unless it

agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Dueto possible changes in our products and applicable national and international regulations and laws, thestatus of our products could change. Material Safety Data Sheets providing safety precautions, that

should be observed when handling or storing Archroma products, are available upon request and areprovided in compliance with applicable law. You should obtain and review the applicable MaterialSafety Data Sheet information before handling any of these products. For additional information,

please contact Archroma.

Documents

Luprintol Multifunction SL-S MSDS