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CCPI Europe Limited CCPI Europe Limited Low drift Type K and N Mineral Insulated thermocouples for high temperature applications Dr. Michele Scervini Trevor D Ford Department of Materials Science and Metallurgy

Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Page 1: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe LimitedCCPI Europe Limited

Low drift Type K and N Mineral Insulated thermocouples for high temperature

applications

Dr. Michele ScerviniTrevor D Ford

Department of Materials Science and Metallurgy

Page 2: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Agenda• Introduction to Low Drift thermocouples

• Thermocouple Life v Thermocouple Effective Life

• Summary of Cambridge tests and initial CCPI tests

• Latest CCPI tests on dual wall MI cable

• Other tests (EMPRESS)

• The next step: Alternative geometry

Department of Materials Science and Metallurgy

Page 3: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe LimitedCCPI Europe Limited

Mineral Insulated Metal Sheathed (MIMS) thermocouples

Page 4: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

An example of tolerance bands

-8.00

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0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

+7.00

+8.00

0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300

Corre

ction

value

s in °C

Temperature in °C

Temperature Correction Curve for Coil 14047

Mean BAC 5621 Tol ASTM E230 Special Tolerances IEC 60584-1 Class 1

Department of Materials Science and Metallurgy

Page 5: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Thermocouple Drift (1)

-8.00

-7.00

-6.00

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-3.00

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0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

+7.00

+8.00

0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300

Corre

ction

value

s in °C

Temperature in °C

Temperature Correction Curve for Coil 14047

Mean BAC 5621 Tol ASTM E230 Special Tolerances IEC 60584-1 Class 1

After several hours of operation

Department of Materials Science and Metallurgy

Page 6: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Temp = 500°C

Thermocouple Drift (2)

nEEEdxdxdTSEmf ∆++∆+=⋅⋅= ∫ ...10

Ideal thermocouple output

Time dependent metallurgical modifications:• Oxidation

• Short range ordering

• Depletion/change in composition

• Other physical/chemical changes

Department of Materials Science and Metallurgy

Page 7: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Challenge to reduce DriftA-A

A-AWire 1

Wire 2

Sheath

Mineral Insulator (Powder)

• Conventional MIMS (Mineral Insulated Metal Sheathed) TCs experience significant drift above 1000 °C

• Improved temperature measurements are much needed for industrial applications: this led to a detailed investigation in to the specific causes of drift in mineral insulated thermocouples at the University of Cambridge.

• From this investigation a new design of thermocouple cable has been developed at the University of Cambridge

Department of Materials Science and Metallurgy

Page 8: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

The new thermocouple

Outer wallInner wall

Thermoelements

• Contamination from the sheath to the thermoelements is the major cause of drift in conventional MIMS

• The new sensor is based on new sheath

• Minimise contamination from sheath to thermoelements

• Thermoelements: flexibility to use type K, type N,…

• Patent issued & pending

Department of Materials Science and Metallurgy

Page 9: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

The life of TCsDepartment of Materials Science and Metallurgy

Page 10: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

The life of TCs: Effective LifeDepartment of Materials Science and Metallurgy

Page 11: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Drift tests:AISI310 - 1200°CDepartment of Materials Science and Metallurgy

Page 12: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Drift tests:AISI310 - 1300°CDepartment of Materials Science and Metallurgy

Page 13: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Drift tests AISI310: SummaryTotal Drift

1200°C – 400h(conventional TC)

-15 °C

1200 °C – 400h(new TC)

-2.5 °C

1300°C – 150h(conventional TC)

-31 °C

1300 °C –150h(new TC)

-2.5 °C

1200 °C:Over 80% drift reduction

1300 °C:Over 90% drift reduction

• Validation of the concept the new sensor is based on

• Path for reliable Ni based sensor working up to 1300 °C

Department of Materials Science and Metallurgy

Page 14: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Drift tests:INC600 - 1200°CDepartment of Materials Science and Metallurgy

Page 15: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Drift tests:INC600 – 1300 °CDepartment of Materials Science and Metallurgy

Page 16: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Type N Drift tests: SummaryTotal Drift

1200 °C – 400h(conventional TC)

-6 °C

1200 °C – 400h(new TC)

Within +1°C

1300 °C – 100h(conventional TC)

-2 °C

1300 °C –100h(new TC)

-14 °C

1200 °C:Over 80% drift reduction

1300 °C: Over 85% drift reduction

• Validation of the concept the new sensor is based on

• No dependence on the diameter for the New thermocouple

Department of Materials Science and Metallurgy

Page 17: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

• Results of thermal cycling tests conducted in the CCPI Europe ISO 17025 accredited calibration laboratory.

• The test was conducted using 4 type K MI thermocouples. 2 of conventional design and 2 of the New Design. Then the test repeated using 4 type N MI thermocouple. 2 of conventional design and 2 of the New Design.

• All conductors from same batch for the respective thermocouple combinations

• The type K thermocouple were tested over 91 cycles and results taken at cycles 1, 16, 31, 46, 61, 76 and 91

• The type N were tested over 90 cycles and results taken at cycles 1, 30, 60 and 90

• The results are shown in the form of correction graphs indicating the changing measured output in Degrees Celsius.

Department of Materials Science and Metallurgy

Page 18: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

Type K conventional results

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0.00

+2.00

+4.00

+6.00

+8.00

+10.00

+12.00

+14.00

+16.00

+18.00

+20.00

650 850 1050 1250

Corr

ectio

n in

Degr

ees C

Test Temperature in Degrees C

Type K 3.0mm Single wall calibration results on cycle 1

13222/F2 3mm Single Wall cycle 1 13222/B2 3mm Single Wall cycle 1 IEC 60584 Class 1 Tolerances

-8.00-6.00-4.00-2.000.00

+2.00+4.00+6.00+8.00

+10.00+12.00+14.00+16.00+18.00+20.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.0mm Single wall calibration results on cycle 1 and cycle 16

13222/F2 3mm Single Wall cycle 1 13222/B2 3mm Single Wall cycle 1 13222/F2 3mm Single Wall cycle 1613222/B2 3mm Single Wall cycle 16 IEC 60584 Class 1 Tolerances

-6.00-4.00-2.000.00

+2.00+4.00+6.00+8.00

+10.00+12.00+14.00+16.00+18.00+20.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.0mm Single wall calibration results on cycle 1, 16 and cycle 31

13222/F2 3mm Single Wall cycle 1 13222/B2 3mm Single Wall cycle 1 13222/F2 3mm Single Wall cycle 1613222/B2 3mm Single Wall cycle 16 13222/F2 3mm Single Wall cycle 31 13222/B2 3mm Single Wall cycle 31IEC 60584 Class 1 tolerances

-6.00-4.00-2.000.00

+2.00+4.00+6.00+8.00

+10.00+12.00+14.00+16.00+18.00+20.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.0mm Single wall calibration results on cycle 1, 16, 31 and cycle 46

13222/F2 3mm Single Wall cycle 1 13222/B2 3mm Single Wall cycle 1 13222/F2 3mm Single Wall cycle 1613222/B2 3mm Single Wall cycle 16 13222/F2 3mm Single Wall cycle 31 13222/B2 3mm Single Wall cycle 31IEC 60584 Class 1 tolerances 13222/F2 3mm Single Wall Cycle 46 13222/B2 3mm Single Wall Cycle 46

-6.00-4.00-2.000.00

+2.00+4.00+6.00+8.00

+10.00+12.00+14.00+16.00+18.00+20.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.0mm Single wall calibration results on cycle 1, 16, 31, 46 and cycle 61

13222/F2 3mm Single Wall cycle 1 13222/B2 3mm Single Wall cycle 1 13222/F2 3mm Single Wall cycle 1613222/B2 3mm Single Wall cycle 16 13222/F2 3mm Single Wall cycle 31 13222/B2 3mm Single Wall cycle 31IEC 60584 Class 1 tolerances 13222/F2 3mm Single Wall Cycle 46 13222/B2 3mm Single Wall Cycle 4613222/F2 3mm Single Wall Cycle 61 13222/B2 3mm Single Wall Cycle 61

-6.00-4.00-2.000.00

+2.00+4.00+6.00+8.00

+10.00+12.00+14.00+16.00+18.00+20.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.0mm Single wall calibration results on cycle 1, 16, 31, 46, 61, 76 and cycle 91

13222/F2 3mm Single Wall cycle 1 13222/B2 3mm Single Wall cycle 1 13222/F2 3mm Single Wall cycle 16 13222/B2 3mm Single Wall cycle 16

13222/F2 3mm Single Wall cycle 31 13222/B2 3mm Single Wall cycle 31 13222/F2 3mm Single Wall Cycle 46 13222/B2 3mm Single Wall Cycle 46

13222/F2 3mm Single Wall Cycle 61 13222/B2 3mm Single Wall Cycle 61 13222/F2 3mm Single Wall Cycle 76 13222/B2 3mm Single Wall Cycle 76

13222/F2 3mm Single Wall Cycle 91 13222/B2 3mm Single Wall Cycle 91 IEC 60584 class 1 tolerances

Department of Materials Science and Metallurgy

Page 19: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Type K New Dual Wall results

-6.00-5.00-4.00-3.00-2.00-1.000.00

+1.00+2.00+3.00+4.00+5.00+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.2mm Double wall calibration results on cycle 1 and cycle 16

13168/F2 3.2mm Double Wall cycle 1 13168/B2 3.2mm Double Wall cycle 113168/F2 3.2mm Double Wall cycle 16 13168/B2 3.2mm Double Wall cycle 16

-6.00

-4.00

-2.00

0.00

+2.00

+4.00

+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.2mm Double wall calibration results on cycle 1, 16 and cycle 31

13168/F2 3.2mm Double Wall cycle 1 13168/B2 3.2mm Double Wall cycle 1 13168/F2 3.2mm Double Wall cycle 1613168/B2 3.2mm Double Wall cycle 16 13168/F2 3.2mm Double Wall cycle 31 13168/B2 3.2mm Double Wall cycle 31IEC 60584 Class 1 tolerances

-6.00-5.00-4.00-3.00-2.00-1.000.00

+1.00+2.00+3.00+4.00+5.00+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.2mm Double wall calibration results on cycle 1, 16, 31 and cycle 46

13168/F2 3.2mm Double Wall cycle 1 13168/B2 3.2mm Double Wall cycle 1 13168/F2 3.2mm Double Wall cycle 1613168/B2 3.2mm Double Wall cycle 16 13168/F2 3.2mm Double Wall cycle 31 13168/B2 3.2mm Double Wall cycle 3113168/F2 3.2mm Double Wall Cycle 46 13168/B2 3.2mm Double Wall Cycle 46 IEC 60584 Class 1 tolerances

-6.00

-5.00

-4.00

-3.00

-2.00

-1.00

0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.2mm Double wall calibration results on cycle 1, 16, 31, 46 and cycle 61

13168/F2 3.2mm Double Wall cycle 1 13168/B2 3.2mm Double Wall cycle 1 13168/F2 3.2mm Double Wall cycle 1613168/B2 3.2mm Double Wall cycle 16 13168/F2 3.2mm Double Wall cycle 31 13168/B2 3.2mm Double Wall cycle 3113168/F2 3.2mm Double Wall Cycle 46 13168/B2 3.2mm Double Wall Cycle 46 13168/F2 3.2mm Double Wall Cycle 6113168/B2 3.2mm Double Wall Cycle 61 IEC 60584 Class 1 tolerances

-6.00

-5.00

-4.00

-3.00

-2.00

-1.00

0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.2mm Double wall calibration results on cycle 1, 16, 31, 46, 61 and cycle 76

13168/F2 3.2mm Double Wall cycle 1 13168/B2 3.2mm Double Wall cycle 1 13168/F2 3.2mm Double Wall cycle 16 13168/B2 3.2mm Double Wall cycle 16

13168/F2 3.2mm Double Wall cycle 31 13168/B2 3.2mm Double Wall cycle 31 13168/F2 3.2mm Double Wall Cycle 46 13168/B2 3.2mm Double Wall Cycle 46

13168/F2 3.2mm Double Wall Cycle 61 13168/B2 3.2mm Double Wall Cycle 61 13168/F2 3.2mm Double Wall Cycle 76 13168/B2 3.2mm Double Wall Cycle 76

IEC 60584 Class 1 tolerances

-6.00

-5.00

-4.00

-3.00

-2.00

-1.00

0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type K 3.2mm Double wall calibration results on cycle 1, 16, 31, 46, 61, 76 and cycle 91

13168/F2 3.2mm Double Wall cycle 1 13168/B2 3.2mm Double Wall cycle 1 13168/F2 3.2mm Double Wall cycle 1613168/B2 3.2mm Double Wall cycle 16 13168/F2 3.2mm Double Wall cycle 31 13168/B2 3.2mm Double Wall cycle 3113168/F2 3.2mm Double Wall Cycle 46 13168/B2 3.2mm Double Wall Cycle 46 13168/F2 3.2mm Double Wall Cycle 6113168/B2 3.2mm Double Wall Cycle 61 13168/F2 3.2mm Double Wall Cycle 76 13168/B2 3.2mm Double Wall Cycle 7613168/F2 3.2mm Double Wall Cycle 91 13168/B2 3.2mm Double Wall Cycle 91 IEC 60584 Class 1 tolerances

Department of Materials Science and Metallurgy

Page 20: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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-8.00

-6.00

-4.00

-2.00

0.00

+2.00

+4.00

+6.00

+8.00

+10.00

+12.00

+14.00

+16.00

+18.00

+20.00

650 850 1050 1250

Corre

ction

in De

grees

C

Test Temperature in Degrees C

Type K 3.2mm Double wall and 3.0mm Single wall results at cycle 91

13222/F2 3mm Single Wall 13222/B2 3mm Single Wall

13168/F2 3.2mm Double Wall 13168/B2 3.2mm Double Wall

Series5 ASTM E230 Special Tolerances (IEC 60584-1 Class 1)

Working within tolerances longerDepartment of Materials Science and Metallurgy

Page 21: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Type N conventional results

-6.00-5.00-4.00-3.00-2.00-1.000.00

+1.00+2.00+3.00+4.00+5.00+6.00+7.00+8.00+9.00

+10.00+11.00+12.00

650 850 1050 1250Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type N 3mm Single wall calibration results on cycle 1 and cycle 30

13047/F Single Wall 1st Cycle 13047/B Single Wall 1st Cycle 13047/F Single Wall 30th Cycle13047/B Single Wall 30th Cycle IEC 60584 2013: Class 1 tolerances

-6.00-5.00-4.00-3.00-2.00-1.000.00

+1.00+2.00+3.00+4.00+5.00+6.00+7.00+8.00+9.00

+10.00+11.00+12.00

650 850 1050 1250Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type N 3mm Single wall calibration results on cycle 1, 30 and cycle 60

13047/F Single Wall 1st Cycle 13047/B Single Wall 1st Cycle 13047/F Single Wall 30th Cycle13047/B Single Wall 30th Cycle 13047/F Single Wall 60 cycles 13047/B Single Wall 60 cyclesIEC 60584 2013: Class 1 tolerances

Department of Materials Science and Metallurgy

Page 22: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Type N New Dual Wall results

-6.00

-5.00

-4.00

-3.00

-2.00

-1.00

0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type N 3.2mm Double wall calibration results on cycle 1 and cycle 30

13167/F Double Wall 1st Cycle 13167/B Double Wall 1st Cycle 13167/F Double Wall 30th Cycle13167/B Double Wall 30th Cycle IEC 60584 Class 1 tolerances

-6.00-5.00-4.00-3.00-2.00-1.000.00

+1.00+2.00+3.00+4.00+5.00+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type N 3.2mm Double wall calibration results on cycle 1, 30 and cycle 60

13167/F Double Wall 1st Cycle 13167/B Double Wall 1st Cycle 13167/F Double Wall 30th Cycle 13167/B Double Wall 30th Cycle13167/F Double Wall 60 cycles 13167/B Double Wall 60 cycles IEC 60584 Class 1 tolerances

-6.00

-5.00

-4.00

-3.00

-2.00

-1.00

0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

650 850 1050 1250

Cor

rect

ion

in D

egre

es C

Test Temperature in Degrees C

Type N 3.2mm Double wall calibration results on cycle 1, 30, 60 and cycle 90

13167/F Double Wall 1st Cycle 13167/B Double Wall 1st Cycle 13167/F Double Wall 30th Cycle

13167/B Double Wall 30th Cycle 13167/F Double Wall 60 cycles 13167/B Double Wall 60 cycles

13167/F Double Wall 90 cycles 13167/B Double Wall 90 cycles IEC 60584 Class 1 tolerances

Department of Materials Science and Metallurgy

Page 23: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Working within tolerances longer

-6.00

-5.00

-4.00

-3.00

-2.00

-1.00

0.00

+1.00

+2.00

+3.00

+4.00

+5.00

+6.00

+7.00

+8.00

+9.00

+10.00

+11.00

+12.00

650 850 1050 1250

Corr

ectio

n in

Degr

ees C

Test Temperature in Degrees C

Type N 3.2 and 3.0mm Double and Single wall calibration results after 60 cycles

13047/F Single Wall 13047/B Single Wall 13167/F Double Wall 13167/B Double Wall IEC 60584-1 Class 1 tolerances

Department of Materials Science and Metallurgy

Page 24: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe LimitedCCPI Europe Limited

Latest CCPI tests on dual wall MI cable

Department of Materials Science and Metallurgy

Page 25: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Latest test data on dual wall MI cable

• Initial tests on the dual wall MI cables have mainly been focused on the sizes recommended for higher temperatures.

-- 3mm to 6mm diameter

• In practise MI cable of different diameters are used in industry and often the smaller sizes are used in the high temperature region above 1100 °C

• So to conduct this latest set of tests we manufactured a range of different MI cable diameter's in the dual wall configuration.

- Type K 1.5mm- Type N 2mm and 1.5mm

Department of Materials Science and Metallurgy

Page 26: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe Limited

• These latest set of tests were designed to see the short term performance of the varying smaller diameters and thermocouple types under cyclic, high temperature and mid temperature conditions.

• All tests were conducted in the CCPI Europe ISO 17025 accredited calibration laboratory.

• The tests conducted were comparative tests in which the test dual wall thermocouples were matched or compared with conventional design MI cables which had been manufactured from the same original batch materials for both the thermocouple conductors and outer sheathing.

• The results are shown in the form of difference graphs indicating the change in output in Degrees Celsius.

Latest test data on dual wall MI cable

Page 27: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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• The next set of result we are going to be looking at are high temperature range (650 to 1250 °C) for :-

• Type K 1.5mm and type N 2mm and 1.5mm diameter constructions

• For this test we measured the output of :--- 1.5mm diameter Inconel sheathed conventional type K MI construction against 1.5mm Inconel sheathed type K dual wall constructions

&-- 2mm diameter Inconel sheathed conventional type N MI construction against 2mm

Inconel sheathed type N dual wall constructions.&

-- 1.5mm diameter Inconel sheathed conventional type N MI construction against 1.5mm Inconel sheathed type N dual wall constructions

• The test thermocouples were tested over 20 cycles and the following results show the measured difference in Degrees Celsius between the 1st and 20th cycles.

• Immersion depth for test thermocouples was 500mm

Latest test data on dual wall MI cable

Department of Materials Science and Metallurgy

Page 28: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

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Latest test data on dual wall MI cableDepartment of Materials Science and Metallurgy

Page 29: Low drift Type K and N Mineral Insulated …...2017/03/22  · drift in mineral insulated thermocouples at the University of Cambridge. • From this investigation a new design of

CCPI Europe LimitedCCPI Europe Limited

-11.00-10.50-10.00-9.50-9.00-8.50-8.00-7.50-7.00-6.50-6.00-5.50-5.00-4.50-4.00-3.50-3.00-2.50-2.00-1.50-1.00-0.500.00

+0.50+1.00+1.50+2.00+2.50

650 850 1050 1250

Tem

pera

ture

in D

egre

es C

elsi

us

Test Temperature in Degrees Celsius

Type K 1.5mm Conventional v 1.5mm Dual Wall results difference between 1st and 20th cycles

14559/2 1.5mm Con difference between 1st & 20th cycles 14544/B 1.5mm DW difference between 1st & 20th cycles

Department of Materials Science and Metallurgy

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-4.75-4.50-4.25-4.00-3.75-3.50-3.25-3.00-2.75-2.50-2.25-2.00-1.75-1.50-1.25-1.00-0.75-0.50-0.250.00

+0.25+0.50+0.75+1.00+1.25+1.50

650 850 1050 1250

Diff

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n D

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Test temperature in Degrees Celsius

Type N 2mm Conventional v 2mm Dual Wall results difference between 1st and 20th cycles

14484/A 2mm Con difference between 1st & 20th cycle 14541/A 2mm DW difference between 1st & 20th cycle

Department of Materials Science and Metallurgy

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-9.25-9.00-8.75-8.50-8.25-8.00-7.75-7.50-7.25-7.00-6.75-6.50-6.25-6.00-5.75-5.50-5.25-5.00-4.75-4.50-4.25-4.00-3.75-3.50-3.25-3.00-2.75-2.50-2.25-2.00-1.75-1.50-1.25-1.00-0.75-0.50-0.250.00+0.25+0.50+0.75+1.00+1.25+1.50+1.75+2.00+2.25+2.50

650 850 1050 1250

Diff

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ce in

Deg

rees

Cel

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Test temperature in Degrees Celsius

Type N 1.5mm Conventional v 1.5mm Dual Wall results difference between 1st and 20th cycles

14492/A 1.5mm Con difference between 1st & 20th cycle 14540 1.5mm DW difference between 1st & 20th cycle

Department of Materials Science and Metallurgy

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• The next set of result we are going to be looking at are mid temperature range (400 to 1000 °C) for :-

• Type K and type N 1.5mm diameter only with short immersion (200mm)

For this test we measured the output of :--- 1.5mm diameter Inconel sheathed conventional type N MI construction against 1.5mm Inconel sheathed type N dual wall constructions.

&-- 1.5mm diameter Inconel sheathed conventional type K MI construction against 1.5mm Inconel sheathed type K dual wall

constructions

• The type N and K thermocouple were tested this time over 30 thermal cycles and the following results show the measured differences in Degrees Celsius between the 1st and 30th cycles of the test.

Latest test data on dual wall MI cableDepartment of Materials Science and Metallurgy

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Latest test data on dual wall MI cable

0

100

200

300

400

500

600

700

800

900

1000

1100

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400

Tem

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Time in minutes

Mid range Thermal Cycle

Cycle raise and fall

Department of Materials Science and Metallurgy

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-2.500

-2.000

-1.500

-1.000

-0.500

0.000

+0.500

+1.000

+1.500

+2.000

+2.500

+3.000

+3.500

400 600 800 1000

Diff

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Deg

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Test temperature in Degrees Celsius14545/1 DW K 1.5mm difference between 1st & 30th cycles 14559/1 Con K 1.5mm difference between 1st & 30th cycles 1st Cycle

1.5mm type K Dual Wall v 1.5mm type K Conventional (Short Immersion furnace), difference between 1st and 30th cycle

Department of Materials Science and Metallurgy

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0.00+0.10+0.20+0.30+0.40+0.50+0.60+0.70+0.80+0.90+1.00+1.10+1.20+1.30+1.40+1.50+1.60+1.70+1.80+1.90+2.00+2.10+2.20

400 600 800 1000

Diff

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ces i

n °C

Test temperatures in °C

Type N 1.5mm Conventional v 1.5mm Dual Wall results difference between 1st and 30th

14540/B DW 1.5mm N difference between 1st & 30th cycles 14492/B Con 1.5mm N difference between 1st & 30th cycles

Department of Materials Science and Metallurgy

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• Currently under a European funded program (EMPRESS) aimed at enhancing process efficiency through improved temperature measurement. A number of addition tests on this dual wall MI thermocouple cable are being conducted.

• The bulk of the laboratory test under the EMPRESS project on the dual wall MI cable will be conducted under the direction of the University of Cambridge.

• In addition a number of field trial will be conducted, these are currently underway, at industrial sites.

• Two in particular are being conducted at Bodycote heat treatment sites in the UK and Europe. These will involve dual wall MI thermocouples being used as the operational measurement sensors at high temperature under real life operational industrial conditions.

• The results are expected by late 2017.

Other tests (EMPRESS)Department of Materials Science and Metallurgy

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• The test data we have been looking at so far has been all from the larger wall dual wall configuration.

• The dual wall configuration is a much more flexible design compared to single wall conventional thermocouples: by changing the inner wall to outer wall thickness ratio it is possible to tweak or control the drift performance of the double wall thermocouples and their mechanical properties.

• As a result dual wall thermocouples with a wide variety of performance can be designed to suit different and varying applications.

• CCPI is currently working on different inner wall thicknesses as part of the development and optimisation of the dual wall thermocouples. In particular, a reduced wall or thin wall geometry is currently under test.

Different cable geometry 3mm Dual wall thick wall

3mm Single wall (conventional)

3mm Dual wall thin wall

Department of Materials Science and Metallurgy

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Test results for dual wall thin wall coming soon !

Department of Materials Science and Metallurgy

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Finally all the results from testing conducted on the dual wall MI cable has currently only been done under standard atmosphere conditions. During the first half of 2017 addition testing will be conducted under inert and vacuum conditions replicating many customers actual operational environments.

The Next Step

Department of Materials Science and Metallurgy

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Questions

Department of Materials Science and Metallurgy