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    Brazing materials

    Roll clad aluminium productsor heat exchanger applications

    Competence in Aluminium

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    THE COMPANY

    AMAG Ranshoen the integrated location or specialised, innovative solutions

    2 AMAG | Brazing materials | 10.2012

    During the production o coil, sheet and plate, AMAG can

    rely on more than 70 years o experience o working with

    aluminium. Austrias leading aluminium group is positioned

    in the heart o Europe and constitutes an exceptionally

    exible specialist with concentrated competence at its

    location in Ranshoen that ranges rom casting and semis

    technologies to recycling. The companys production tech-

    nologies are state-o-the-art and its product programme

    is constantly being enhanced and expanded by means o

    ongoing process optimization and investments.

    AMAGs enormous innovation potential emanates rom

    its highly motivated and excellently trained workorce, the

    availability o the latest casting, rolling and heat treatment

    technologies, the extensive use o technological synergies

    between the various product groups, and networking with

    external research institutes and development partners. In

    addition, the concentration o competences at one inte-

    grated location ensures great versatility and short reaction

    times or the optimum ulfllment o increasingly testing

    customer demands.

    AMAGs quality assurance systems meet the stringent

    technological requirements o the aerospace and automo-

    tive industries. All the expertise required or the compre-

    hensive examination o material properties and parame-

    ters o environmental relevance are concentrated in the

    companys own accredited testing laboratory, which con-

    orms with the international EN ISO/IEC 17025 standard

    recognized by the aerospace industry. Moreover, AMAG

    naturally possesses all the main quality and environmental

    certifcates o relevance (please see www.amag.at).

    AMAGs corporate culture encompasses a readiness to

    take decisions, long-term customer partnerships and

    daily endeavours aimed at improved perormance. The

    workorce plays a central role in this regard, its high levelso motivation being based on quality consciousness,

    innovative strength and productivity-oriented thinking.

    Every year, the exceptional commitment o every emplo-

    yee with regard to the continuous improvement process

    (CIP) results in numerous ideas and suggestions, the

    implementation o which makes a considerable contributi-

    on to company success. AMAGs leading role in this area

    is confrmed by the repeated top positions achieved during

    external benchmarking. The interplay o these ramework

    conditions results in a high degree o exibility, as well

    as the ability to answer customer needs with individual

    consulting and precisely targeted solutions.

    As a result, AMAG constitutes a most competent partner

    or every matter relating to aluminium.

    Innovative expertise or

    rolled aluminium products

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    Environmental synergies between smelter,

    cast house and rolling mill

    In recent years, the reduction o greenhouse gases has

    become an issue o growing importance to the metallurgi-

    cal industry. Using the very latest technologies and exten-

    sive synergy eects available along the entire processing

    chain, the AMAG group has succeeded in achieving very

    low CO2

    emissions and energy consumption.

    Very low CO2

    emissions during

    AMAGs ingot production

    AMAG casting employs post-consumer material, in-house

    scrap and primary aluminium or the production o roll-

    ing ingots. Its primary aluminium base is secured by the

    participation in the Aluminerie Alouette Inc. smelter in

    Canada, which numbers among the most efcient in theworld. Electricity emanating exclusively rom hydropower

    sources keeps CO2

    emissions at a signifcantly low level.

    Manuacturing o aluminium alloys via the recycling route

    saves up to 95 per cent o the energy required or primary

    production. Moreover, as the latest scrap preparation

    methods, melting technologies and casting processes are

    applied at the Ranshoen location, sizeable amounts o

    correctly sorted post consumer scrap can be employed in

    the production o aluminium brazing materials. Both core

    alloys and fller materials contain considerable secondary

    raw material content.

    Resource protection by process optimisation

    In addition to the selection o raw materials with regard

    to energy consumption and CO2

    emissions, AMAG is

    constantly working on improvements o its production

    processes. Optimized manuacturing parameters and pro-

    cessing acilities e.g. or heat treatment, cut energy con-

    sumption and thereore CO2

    emissions. Innovative urnace

    concepts incorporating great exibility and an optimum use

    o capacity levels also make a considerable contribution to

    resource conservation.

    AMAGs enhanced recycling technologies and optimized

    processes acilitate energy savings and thus provide a

    signifcant reduction in both CO2

    emissions and impact on

    the atmosphere and water reserves.

    AMAG greenaluminium

    products

    Environment-riendly aluminium melting urnace

    Cost eective hood-type annealing urnace

    State o the art cast technology

    ENvirONMENT-friENdlY PrOduCTiON

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    AluMiNiuM BrAZiNG

    Brazing

    process

    Advantages o aluminium brazing

    The use o aluminium alloys in heat exchanger applica-

    tions has steadily increased over the last two decades and

    because o the continuing drive or lightweight design and

    cost reductions, aluminium has virtually replaced copper

    and brass.

    Manuacturers have derived ull advantage rom the prop-

    erties o aluminium brazing material concerning strength,

    weight, thermal conductivity, ormability and corrosion

    resistance. Thereore brazed aluminium heat exchang-

    ers have become quite common in radiators, oil coolers,

    condensers, evaporators, intercoolers and air condition-

    ing equipment. And this success is directly linked to the

    development o joining processes.

    History

    At the beginning o the 1970s aluminium heat exchangers

    were mechanically assembled; then in the middle o this

    decade the uxless vacuum brazing (VAC) process was

    introduced into large scale production. Subsequently, theimproved, ux-based controlled atmosphere brazing (CAB)

    technique developed in the early 1980s, led to a steady

    increase in the use o aluminium brazing material or heat

    exchanger applications.

    VAC-CAB process

    As aluminium alloys orm a stable and high melting oxide

    flm, all the brazing methods include the Al-oxide layer

    penetration step. The uxless vacuum brazing process

    (VAC) and the ux based controlled atmosphere brazing

    (CAB) overcome this problem by means o two diering

    procedures.

    In vacuum brazing the fller alloy contains 1.0-2.0% mag-

    nesium, which diuses on the surace during the brazing

    cycle and then vaporizes at 600C due to low pressure o

    10-5 mbar. The Mg-vapour disrupts the oxide layer and thus

    enables the fller alloy to ow. This Mg-vapour deposits on

    the cold urnace walls during vacuum brazing and must be

    regularly removed to ensure efcient urnace operation.

    In controlled atmosphere brazing a non corrosive, non

    hygroscopic ux is employed to dissolve and break up the

    oxide layer beore the fller alloy melts. A Mg-content o

    over 0.3% in the molten clad reduces the perormance o

    the ux due to the ormation o high melting K-Mg-F-com-

    pound. These compounds reduce the viscosity o the liquid

    fller and results in poor brazing results.

    Controlled atmosphere aluminium brazing system

    Illustration o grain size and brazing joint

    Typical brazing joint

    Vacuum brazing urnace

    1 mm

    303.9 m

    330.0 m

    4 AMAG | Brazing materials | 10.2012

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    Aluminium brazing

    material production

    Complex assemblies can be turned into single unit by just

    one pass through a brazing urnace. Aluminium brazing a-

    cilitates the joining o parts with a near-eutectic Al-Si fller

    alloy, the liquidus temperature which is about 50C lower

    than that o the core. In serial heat exchanger productionthe fller alloy is supplied via a thin clad on a core alloy.

    Compound Material

    Aluminium brazing material is a sophisticated multi layer

    compound consisting o a core alloy which provides the

    strength and lie cycle requirements o the heat exchanger

    and a clad brazing fller. A one-sided protection layer can also

    be clad, in order to prevent water-side radiator corrosion.

    During brazing, only the clad brazing alloy melts, while the

    core alloys remain solid. The design and the applied ma-

    terials o the heat exchanger are adjusted to optimize the

    brazing result regarding the required post braze mechani-

    cal properties as well as the corrosion resistance.

    Roll cladding

    Today, two basic cladding techniques, roll bonding and

    cast cladding, have become established industrially. Roll

    cladding is a solid-state welding process, which is used

    to join similar and dissimilar aluminium alloys, and repre-

    sents the primary method o manuacturing uselage skin

    sheet or aircrat, bright products and brazing sheet or

    automotive applications. The cladding layers are attached

    to the core slab by welding and metallurgical bonding

    using hot rolling. The cast cladding technique is based

    on a conventional direct chill mould modifed in order to

    allow multiple metal streams to be casted into one singlealuminium ingot.

    Cladding thickness

    AMAGs well established, roll bonding process guarantees

    tight cladding thickness tolerances, which are essential or

    ensuring stable brazing results. Extremely thin clad layers

    o 1.5% can be manuactured, as well as brazing materi-

    als with a cladding thickness o 20%.

    EffectiveCladdingThickness[%]

    cladding thickness in %

    1.5

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    AMAG TopClad

    non-heat-treatable alloysAMAG TopClad LL

    long lie alloysAMAG TopClad HS

    heat-treatable alloysAMAG TopClad UHS

    Yield strength Rp0,2

    o AMAG heat exchanger materials

    Rp02

    sot temper

    Rp02 ater CAB-brazing and 8 days age hardening

    YieldstrengthRp0.2[MPa]

    PrOduCTS ANd SOluTiONS

    Tailor made heat

    exchanger materials

    The development o aluminium alloys to meet the varied re-

    quirements o heat exchanger manuacturers has advanced

    in step with the growing use o aluminium brazing material.

    Optimized material selection involves criteria as there are

    ormability, strength, corrosion resistance, atigue resistance

    and suitability or brazing.

    AMAGs cladding process ensures tight metallurgical bond-

    ing o the fller material onto the core ingot and thus top

    quality o the brazing material.

    AMAG TopClad

    Typically, non heat-treatable Al-Mn based alloys o the 3xxx

    series are used or the core material o aluminium brazing

    compounds.

    AMAG TopClad LL (LongLife)

    In order to meet the demands or higher strength and

    improved corrosion resistance, AMAG developed modifed

    3xxx materials which are well known as LongLie alloys.

    Special chemistries and thermo-mechanical processingserve to improve the corrosion resistance levels oered by

    conventional 3xxx alloys.

    AMAG TopClad HS (High strength)

    Higher mechanical strength ater brazing can be obtained

    by the heat treatable 6xxx alloys as the EN AW-6063

    (AlMgSi) or the EN AW-6951 (AlMgSiCu) by means o

    solid solution and precipitation hardening. During brazing,

    Mg2Si particles are dissolved and the elements are kept in a

    solid solution by means o rapid cooling. The strength o the

    material is enhanced by small precipitates which are ormed

    aterwards at room temperature.

    AMAG TopClad UHS (Ultra high strength)

    AMAGs speciality in the feld o heat exchanger materi-

    als is the adapted EN AW-7020 alloy to which a urther

    barrier layer has to be applied in order to prevent diusion

    phenomena.

    EN-AW 7020 core material belongs to the heat treatable

    alloys which in addition to high static strength, is char-

    acterised by excellent weldability and high welded seam

    strength. The combination o zinc and magnesium results in

    heat treatment ability and thus in strengths that ar exceed

    those o standard brazing alloys. Parallel to joining during

    the brazing process, solution annealing also occurs at braz-

    ing temperature. In sot temper AMAG TopClad UHS 7020

    achieves an Rp0.2

    yield strength o 65 MPa, which

    ater brazing can rise to over 140 MPa due to room

    temperature ageing.

    While in order to achieve optimum strength, the majority

    o heat treatable aluminium alloys have to be subjected to

    solution annealing within a relatively narrow temperature

    range, this does not apply to AMAG TopClad UHS 7020.

    The cooling speed ollowing brazing can be varied to a

    high degree without aecting subsequent age hardening

    at room temperature. AMAG TopClad UHS is an excellent

    material or base plates. Due to the hardness o 55 HB in

    sot temper the high strength material possesses excel-

    lent resistance against mechanical deects in sot temper.

    Indeed, AMAG TopClad UHS is a premium solution when-

    ever high scratch resistance is required.

    Customized heat exchanger material

    0

    25

    50

    75

    100

    125

    150

    3003

    3004

    3103

    3105

    LL-350

    3

    LL-350

    5

    LL-353

    5

    LL-930

    03

    LL-930

    05

    6063

    6951

    7020

    6 AMAG | Brazing materials | 10.2012

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    Progress by

    innovation

    AMAG MultiClad Material

    The characteristics o multilayer material compounds

    can be modifed in a wide range o properties including

    strength, ormability and corrosion resistance. Functional

    interlayers or improving the orming behaviour, the corro-

    sion protection or the diusion resistance orm a material

    package which meets customer specifc needs.

    Composition o the fve-layer compound material

    Age hardening at room temperature after CAB-brazing

    Aging Time [h]

    Rm,

    Rp0.2

    [MPa]

    material thickness: 1.6 mm

    0

    50

    100

    150

    200

    250

    300

    0 2 0 4 0 6 0 8 0 1 0 0 12 0 14 0 16 0 18 0 20 0 22 0 24 0

    15

    20

    25

    30

    35

    40

    45

    Rm Rp0.2 A50

    A50

    [%]

    Microscopic picture o the AMAG MultiClad

    UHS

    500 m

    AMAG MultiClad UHS (Ultra high strength)

    In particular, strength issues mean that the demand or

    high-perormance heat exchangers with a reduced volume

    and mass either cannot be met by conventional brazing

    materials, or only to an insufcient extent. In view o this

    problem, AMAG rolling was prompted to develop a high-

    strength, multilayer brazing material.

    High-strength MultiCladUHS brazing material allows the

    production o new and innovative heat exchangers with

    the potential to provide sustainable component and design

    optimization, and a reduction in material thickness with a

    corresponding cut in weight and size.

    AMAG has developed a fve-layer compound material con-

    sisting o a high-strength EN-AW 7020 core, fller material

    and an additional diusion barrier. All standard aluminium-

    silicon alloys can be cladded using both vacuum- and

    uxing agent-based processes. The material compound

    resulting rom the rolling process possesses tight metal-

    lurgical bonding.

    7AMAG | Brazing materials | 10.2012

    MulTiClAd MATEriAl

    Age hardening o AMAG MultiCladUHS

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    COrrOSiON rESiSTANCE

    Corrosion behaviour

    o heat exchangers

    The corrosion resistance o aluminium heat exchang-

    ers depends on the (electro-) chemical interaction o the

    entire system, the microstructure o the core material and

    environmental actors. The microstructure, which is inu-

    enced by the chemical composition and the processing,

    has a signifcant impact on the mechanism o corrosion.

    The severe environmental conditions to which aluminium

    heat exchangers may be exposed have a considerable

    eect on lietime. Both internal corrosion due to heat

    exchanging agents (e.g. rerigerants and coolants) and

    external corrosion relating to the environment (e.g. salt,

    water) can cause perorations and leaks.

    Pitting Corrosion

    Heat exchangers oten suer rom pitting corrosion, as in

    the presence o an electrolyte the surace brazing mate-

    rial is removed at localized points and this results in the

    development o cavities. The primary cause o pitting is a

    dierence in the corrosion potential created by an inhomo-

    geneity either in or on the material surace.

    Waterside Corrosion

    Water-side corrosion on the inner side o a tube can be

    controlled sufciently through the use o the proper cool-

    ing liquid with appropriate inhibitors. When applied to the

    core, water-side clad alloys such as EN AW-1050 or

    EN AW-7072 can improve internal corrosion resistance.

    Air Side Corrosion

    All approaches aimed at enhancing the corrosion prop-

    erties o aluminium brazing materials are intended to

    mitigate the deleterious pitting mechanism into a less

    harmul corrosive attack. AMAG rolling has developed

    AMAG TopClad LL, which incorporates special chemis-tries with tailored thermo-mechanical processing. This well

    designed combination between chemical composition and

    the production route considerably improves the corrosion

    resistance o these LongLie alloys.

    Galvanic Protection

    The principle o galvanic protection is commonly applied

    with regard to the critical components o the heat ex-

    changer: When in contact with an electrolyte, a less no-

    ble (anodic) alloy corrodes preerably in comparison with

    a noble (cathodic) alloy. Corrosion prevention requires

    careul selection o alloy combinations. Depending on the

    electro-chemical potentials o the post-brazed materials

    in use, the corrosion attack on the single components

    can be controlled. Lateral corrosion attack along the precipitate layer

    Modifcation o the Microstructure

    As grain boundaries represent the path along which cor-

    rosion proceeds, elongated grains enhance the LongLie

    perormance o the material. The precipitation o Al-Mn-Si

    particles adjacent to the core/fller interace has a urther

    positive impact on the corrosions resistance. This is

    because the precipitate layer has lower corrosion potential

    than the residual core and thus acts as a sacrifcial layer.

    Material Selection

    The electrochemical potentials o heat exchanger materi-

    als may indicate the corrosiveness but does not include

    the inuence o the microstructure on the corrosion.

    Accelerated corrosion tests (SWAAT-Test) allows AMAGto predict the durability o heat exchangers.

    Grain size aects the Si-migration

    Elongated grain structure ater brazing

    500 m

    500 m

    322.2 m

    8 AMAG | Brazing materials | 10.2012

    500 m

    322,2 m

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    Technical

    support,

    research and

    developmentHeat exchanger manuacturers are not let alone

    with their requests or ongoing process optimization.

    Together with its customers, AMAG makes intensive

    eorts to fnd well-designed solutions. Extensive material

    characterization equipment and tools or simulation and

    modelling provide a basis or the development o both

    products and additional expertise.

    AMAG R&D is also ocused on the ongoing improvement

    o production processes with regard to quality, processconsistency and cost-efciency. Highly qualifed sta and

    modern laboratories acilitate the acquisition o know-

    how in the brazing feld, while the equipment available

    in the laboratories allows the use o diering chemical

    analysis techniques and various optical, scanning and

    X-ray analyses.

    Upon customer request, analyses and material examina-

    tions can also be completed. On the basis o expertise

    relating to the demands o the brazing process, specifc as-

    signments can be dealt with and the appropriate solutions

    implemented. For example, these can include metallo-

    graphic and corrosion testing, as well as surace analyses.

    3D grain contours observed by Barkers etchingMorphology o a brazed assembly

    Liquidus projection and solidifcation simulationby thermodynamic calculation

    Expertise by highly qualifed sta

    500 m

    9AMAG | Brazing materials | 10.2012

    SuPPOrT

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    TECHNiCAl dATA

    dimensions an esign

    Strips Sheets

    Dimensions 1)

    thickness 0.3 4.0 mm 2) 0.3 8.0 mm

    width thickness 0.3 2.0 mm: 15 1530 mm

    thickness >2.0 4.0 mm: 55 1530 mm

    100 1530 mm

    length thickness 0.3 2.5 mm: max. 8000 mm

    thickness 1.5 6.35 mm: max. 10000 mm 3)

    thickness 2.5 4.0 mm: max. 4400 mm

    thickness 4.0 8.0 mm: max 7300 mm

    edge quality trimmed trimmed and slit; sawn

    inside diameter 300 mm; 400 mm; 508 mm; 600 mm

    outside diameter max. 1900 mm

    Cladding

    cladding one side; both sides 4)

    cladding thickness 1.5 20.0%

    cladding tolerance cladding thickness o 1.5 < 4.0%: 0.6

    cladding thickness o 4.0 < 6.0%: 1.0

    cladding thickness o 6.0 < 12.0%: 1.5

    cladding thickness o 12.0 20.0%: 2.0

    Surace

    quality mill fnish; or thickness 0.3 3.5 mm: chemically degreased

    marking zebra marking; ink marking

    1) Tolerances according to EN and ASME.2) Higher thickness on request.3) New cut to length line available in February 2013.4) Also with dierent thicknesses and alloys.

    Customer specifc dimensions and tolerances on request.

    The state-o-the-art slitting line also allows AMAG to

    meet the demand or ever-closer width tolerances o tubestock material. Depending on the material thickness width

    tolerances rom max. 0.05 mm up to max. 0.20 mm can

    be ensured.

    10 AMAG | Brazing materials | 10.2012

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    MATEriAl dATA CHEMiCAl COMPOSiTiON

    AMAG Cla Alloys

    others

    Designation Si Fe Cu Mn Mg Cr Zn Ti each total

    Clad alloys or VAC-brazing according to EN 573-3

    4004minmax.

    9.010.5

    -0.8

    -0.25

    -0.10

    1.02.0

    --

    -0.20

    --

    -0.05

    -0.15

    4104 1)min.max.

    9.010.5

    -0.8

    -0.25

    -0.10

    1.02.0

    --

    -0.20

    --

    -0.05

    -0.15

    Clad alloys or CAB-brazing according to EN 573-3

    4343min.max.

    6.88.2

    -0.8

    -0.25

    -0.10

    --

    --

    -0.20

    --

    -0.05

    -0.15

    4045min.max.

    9.011.0

    -0.8

    -0.30

    -0.05

    -0.05

    --

    -0.10

    -0.20

    -0.05

    -0.15

    4047A min.max.11.013.0

    -0.6

    -0.30

    -0.15

    -0.10

    --

    -0.20

    -0.15

    -0.05

    -0.15

    Zn-containing clad alloys or CAB-brazing

    4343.ZNmin.max.

    6.88.2

    -0.8

    -0.25

    -0.10

    --

    --

    0.81.2

    --

    -0.05

    -0.15

    4045.ZNmin.max.

    9.011.0

    -0.8

    -0.30

    -0.05

    -0.05

    --

    0.81.2

    -0.20

    -0.05

    -0.15

    Clad alloys or corrosion protection according to EN 573-3

    1050Amin.max.

    -0.25

    -0.40

    -0.05

    -0.05

    -0.05

    --

    -0.07

    -0.05

    -0.03

    --

    7072min.max.

    -0.7 (Si + Fe)

    -0.10

    -0.10

    -0.10

    --

    0.81.3

    --

    -0.05

    -0.15

    1) Containing 0,02% 0,20% Bi

    All data in wt.-%.

    Customer specifc alloy compositions on request.

    High quality rolling products require premium rolling

    slabs. All heat exchanger alloys are cast in Ranshoen

    at AMAG Casting. In addition to command o casthouse

    processes customers demand comprehensive know-how

    in the material testing feld. This know-how is to be ound

    in the accredited AMAG testing laboratory.

    11AMAG | Brazing materials | 10.2012

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    MATEriAl dATA CHEMiCAl COMPOSiTiON

    AMAG Core Alloys

    others

    Designation Si Fe Cu Mn Mg Cr Zn Ti each total

    AMAG TopClad; 3xxx-non-heat-treatable alloys according to EN 573-3 and AA

    3003minmax.

    -0.6

    -0.7

    0.050.25

    1.01.5

    --

    --

    -0.10

    --

    -0.05

    -0.15

    3004min.max.

    -0.30

    -0.70

    -0.25

    1.01.5

    0.81.3

    --

    -0.25

    --

    -0.05

    -0.15

    3005minmax.

    -0.6

    -0.7

    -0.30

    1.01.5

    0.200.6

    -0.10

    -0.25

    -0.10

    -0.05

    -0.15

    3103 1)minmax.

    -0.50

    -0.7

    -0.10

    0.91.5

    -0.30

    -0.10

    -0.20

    --

    -0.05

    -0.15

    3105min

    max.

    -

    0.6

    -

    0.7

    -

    0.30

    0.30

    0.8

    0.20

    0.8

    -

    0.20

    -

    0.40

    -

    0.10

    -

    0.05

    -

    0.15

    AMAG TopClad LL (LongLie)

    LL-3503min.max.

    -0.2

    -0.25

    0.200.6

    0.71.2

    0.100.30

    -0.05

    -0.05

    0.100.25

    -0.05

    -0.15

    LL-3505min.max.

    -0.3

    -0.40

    0.200.40

    1.01.5

    0.200.45

    -0.05

    -0.15

    -0.15

    -0.05

    -0.15

    LL-3535min.max.

    -0.4

    -0.45

    0.500.70

    0.51.0

    0.100.30

    -0.05

    -0.15

    -0.15

    -0.05

    -0.15

    LL-93003min.max.

    -0.6

    -0.70

    0.300.70

    1.01.5

    -0.10

    --

    -0.15

    -0.15

    -0.05

    -0.15

    LL-93005

    min.

    max.

    -

    0.2

    -

    0.30

    0.30

    0.70

    0.8

    1.2

    0.15

    0.35

    -

    0.05

    -

    0.10

    0.05

    0.15

    -

    0.05

    -

    0.15

    AMAG 5xxx-non-heat-treatable alloys according to EN 573-3 and AA

    5049min.max.

    -0.40

    -0.50

    -0.10

    0.501.1

    1.62.5

    -0.30

    -0.20

    -0.10

    -0.05

    -0.15

    5052min.max.

    -0.25

    -0.40

    -0.10

    -0.10

    2.22.8

    0.150.35

    -0.10

    --

    -0.05

    -0.15

    5083min.max.

    -0.40

    -0.40

    -0.10

    0.401.0

    4.04.9

    0.050.25

    -0.25

    -0.15

    -0.05

    -0.15

    AMAG TopClad HS (High strength); 6xxx-heat treatable alloys according to EN 573-3 and AA

    6063 min.max. 0.200.6 -0.35 -0.10 -0.10 0.450.9 -0.10 -0.10 -- -0.05 -0.15

    6951min.max.

    0.200.50

    -0.08

    0.150.40

    -0.10

    0.400.8

    --

    -0.20

    --

    -0.05

    -0.15

    AMAG TopClad UHS (Ultra High Strength); 7xxx-heat treatable alloys according to EN 573-3 and AA

    7020 2)min.max.

    -0.35

    -0.40

    -0.20

    0.050.50

    1.01.4

    0.100.35

    4.05.0

    --

    -0.05

    -0.15

    1) Containing max. 0.10% (Zr+Ti)2) Containing 0.08% 0.25% (Zr+Ti) and 0.08% 0.20% Zr

    All data in wt.-%.

    Customer specifc alloy compositions on request.

    12 AMAG | Brazing materials | 10.2012

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    MATEriAl dATA MECHANiCAl PrOPErTiES

    Tensile ata in pre an post braze conition

    as delivered as brazed 1)

    Designation TemperGauge

    (mm)

    Rp0.2

    (Mpa)

    Rm

    (Mpa)

    A50

    (%)

    Rp0.2

    (Mpa)

    Rm

    (Mpa)

    A50

    (%)

    AMAG TopClad; 3xxx-non-heat-treatable alloys

    3003 min.max.

    0.34.0

    35-

    95135

    23-

    35-

    95-

    25-

    3004 min.max.

    0.34.0

    60-

    155200

    14-

    55-

    135-

    20-

    3005 min.max.

    0.34.0

    45-

    115165

    19-

    45-

    115-

    20-

    3103 min.max.

    0.34.0

    35-

    90130

    24-

    35-

    90-

    30-

    3105

    min.

    max.

    0.3

    4.0

    40

    -

    100

    155

    17

    -

    40

    -

    95

    -

    25

    -

    AMAG TopClad LL (LongLie)

    LL-3503 min.max.

    0.34.0

    45-

    120150

    20-

    50-

    135-

    18-

    LL-3505 min.max.

    0.34.0

    60-

    145175

    12-

    60-

    145-

    12-

    LL-3535 min.max.

    0.34.0

    40-

    120155

    18-

    40-

    130-

    25-

    LL-93003 min.max.

    0.34.0

    40-

    125150

    20-

    45-

    130-

    20-

    LL-93005 min.

    max.

    0.3

    4.0

    45

    -

    120

    150

    20

    -

    45

    -

    135

    -

    15

    -

    AMAG 5xxx-non-heat-treatable alloys

    5049 min.max.

    0.34.0

    80-

    190240

    18-

    --

    --

    --

    5052 min.max.

    0.34.0

    65-

    170215

    18-

    --

    --

    --

    5083 min.max.

    0.34.0

    125-

    275350

    15-

    --

    --

    --

    AMAG TopClad HS (High strength); 6xxx-heat-treatable alloys

    6063 2) min.max. 0.34.0 30- 80125 25- 70- 145- 12-

    6951 2) min.max.

    0.34.0

    35-

    -145

    23-

    65-

    140-

    18-

    AMAG TopClad wHS (High strength); 7xxx-heat-treatable alloys

    7020 2) H12min.max.

    2.05.0

    125-

    165205

    8-

    130-

    250-

    14-

    1) Post braze properties as typical value; 3 min on brazing temperature o 600C; tensile test at room temperature.2) Post braze properties ater 8 days room temperature aging.

    Customer specifc temper on request.

    13AMAG | Brazing materials | 10.2012

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    MATEriAl dATA ElEvATEd TEMPErATurE STrENGTH

    Typical tensile properties as a unction o temperature

    Tensile test at elevated temperatures of brazing sheet in post brazed condition

    14 AMAG | Brazing materials | 10.2012

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    MATEriAl dATA fOrMABiliTY

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    0 0,05 0,1 0,15 0,2

    flow

    stresskf

    [MPa]

    deformation strain g

    1.2 mm EN AW-6063 brazing sheet in temper soft

    position to rolling direction:

    n4-6 = 0.27

    r8-12 = 0.73

    0

    n4-6 = 0.29

    r8-12 = 0.47

    45

    n4-6 = 0.28

    r8-12 = 0.68

    90

    0

    20

    40

    60

    80

    100

    120

    140

    160

    0 0,05 0,1 0,15 0,2

    flow

    stresskf

    [MPa]

    deformation strain g

    1.2 mm EN AW-3003 brazing sheet in temper soft

    position to rolling direction:

    n4-6 = 0.26

    r8-12 = 0.65

    0

    n4-6 = 0.25

    r8-12 = 0.72

    45

    n4-6 = 0.24

    r8-12 = 0.56

    90

    flow curves o brazing sheet in sot temper

    0

    20

    40

    60

    80

    100

    120

    140

    160

    0 0,05 0,1 0,15 0,2

    flow

    stresskf

    [MPa]

    deformation strain g

    1.6 mm EN AW-3103 brazing sheet in temper soft

    position to rolling direction:

    n4-6 = 0.24

    r8-12 = 0.67

    0

    n4-6 = 0.25

    r8-12 = 0.69

    45

    n4-6 = 0.24

    r8-12 = 0.69

    90

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    200220

    0 0,05 0,1 0,15 0,2

    flow

    stresskf

    [MPa]

    deformation strain g

    0.6 mm LL-3505 brazing sheet in temper soft

    position to rolling direction:

    n4-6 = 0.24

    r8-12 = 0.85

    0

    n4-6 = 0.25

    r8-12 = 1.15

    45

    n4-6 = 0.25

    r8-12 = 0.38

    90

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    0 0,05 0,1 0,15 0,2

    flow

    stresskf

    [MPa]

    deformation strain g

    1.2 mm LL-3503 brazing sheet in temper soft

    position to rolling direction:

    n4-6 = 0.29

    r8-12 = 0.71

    0

    n4-6 = 0.29

    r8-12 = 0.72

    45

    n4-6 = 0.28

    r8-12 = 0.68

    90

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    200220

    0 0,05 0,1 0,15 0,2

    flow

    stresskf

    [MPa]

    deformation strain g

    1.5 mm LL-3535 brazing sheet in temper soft

    position to rolling direction:

    n4-6 = 0.31

    r8-12 = 0.70

    0

    n4-6 = 0.32

    r8-12 = 0.85

    45

    n4-6 = 0.32

    r8-12 = 0.80

    90

    Elevated Temperature Strength

    A critical material requirement is sufcient strength at

    elevated temperatures; especially automotive oil cool-

    ers require aluminium heat exchanger material with high

    temperature tensile strengths.

    Formability Characteristics

    The ow curve can be calculated rom the region o

    uniorm elongation rom yield strength Rp0.2

    to uniorm

    elongation Ag

    in the stress-elongation curve. In order to

    determine the material characteristic values or orming

    the orce is related to the actual section area o the speci-

    men. The ow stress kis related to the region o plastic

    ow and depends on material, temperature, degree o

    strain and strain rate. The strain hardening exponent n can

    be calculated rom the ow curve; the higher the value o

    n and the higher the uniorm elongation, the lower is the

    tendency o the material to neck locally. Brazing sheets

    do not exhibit the same properties in all directions; the

    variation o material properties in dependence o the rolling

    direction is called anisotropy r.

    15AMAG | Brazing materials | 10.2012

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    GrOuP COMPANiES & lOCATiONS

    AMAG rolling GmbHP.O. Box 325282 RanshoenAUSTRIAT +43 7722 801 0F +43 7722 809 [email protected]

    AMAG metal GmbHP.O. Box 365282 RanshoenAUSTRIAT +43 7722 801 0F +43 7722 809 [email protected]

    Aluminium Austria Metall

    (Qubec) Inc.

    1010 Sherbrooke ouest# 2414, Montral, QC. H3A 2R7CANADAT +1 514 844 1079F +1 514 844 [email protected]

    AMAG casting GmbH

    P.O. Box 355282 RanshoenAUSTRIAT +43 7722 801 0F +43 7722 809 [email protected]

    AMAG service GmbHP.O. Box 395282 RanshoenAUSTRIAT +43 7722 801 0F +43 7722 809 [email protected]

    AMAG operative companies

    AMAG Deutschland GmbH

    Lustheide 8551427 Bergisch GladbachGERMANYT +49 2204 58654 0F +49 2204 58654 [email protected]

    AMAG FRANCE SARL

    65, Rue Jean Jacques Rousseau92150 SuresnesFRANCET +33 141 448 481F +33 141 380 [email protected]

    AMAG U.K. LTD.

    Beckley LodgeLeatherhead RoadGreat BookhamSurrey KT 23 4RNUNITED KINGDOMT +44 1372 450661F +44 1372 [email protected]

    Ofce Czech Republic

    David BicovskyMarie Podvalove 929/5196 00 Prag 9 - CakoviceCZECH REPUBLICT +42 0725 002 [email protected]

    AMAG BENELUX B.V.

    Burgwal 472611 GG DeltNETHERLANDST +31 15 21 33 222F +31 15 21 25 [email protected]

    AMAG ITALIA S.r.l.

    Via Pantano 220122 MilanoITALYT +39 02 720 016 63F +39 02 367 640 [email protected]

    AMAG USA Corp.

    600 East Crescent Ave, Suite 207Upper Saddle RiverNJ 07458-1827, USAT +1 201 9627105F +1 972 [email protected]

    Ofce China

    PH Tayc/o H&N Packaging (Suzhou) Co, Ltd.No: 18, Xingye Road, TaicangDevelopment Area JuangsuP.R. CHINAT +86 512 5344 [email protected]

    AMAG rolling GmbH sales subsidiaries

    Korea/Trading

    GST Corporation

    137-858, # Hanwha Obelisk,1327-27 Seocho 2 DongSeocho-Ku, SeoulKOREAT +82 2 597 7330F +82 2 597 [email protected]

    Mexico

    Intercontinental de Metales,

    S.A. de C.V.

    Cto. Historiadores No. 2ACd. Satelite, Naucalpan de JuarezEdo. Mex., ZC 53100MEXICO

    T +11 5255 5374 2272F +11 5255 5374 [email protected]

    Poland

    Nonerrometal

    ul. Kiliskiego 4/11432-600 OwicimPOLANDT +48 502 643 003F +48 33 8 433 [email protected]

    Sweden, Norway, Finland

    Danubia Metallkontor AB

    Linngatan 76115 23 StockholmSWEDENT +46 8 704 95 95F +46 8 704 28 [email protected]

    Switzerland

    R. Fischbacher AG

    Hagackerstrasse 108953 DietikonSWITZERLANDT +41 44 740 59 00F +41 44 740 00 [email protected]

    Spain/Trading

    Euromet Metales y

    Transormades, S.A.

    C/. Orense, 16-5oF28020 MadridSPAINT +34 639 770 672F +34 609 014 [email protected]

    Spain/OEM

    Glintek, ingeniera y

    aplicaciones del aluminio, SL

    C/Guillermo Tell, 27 Planta 108006 BarcelonaSPAINT +34 93 418 39 06

    F +34 93 418 39 [email protected]

    Taiwan

    De Pont Intern. Company

    No. 1, Lane 961Song Vun RoadTali City 41283, TaichungTAIWANT +886 (0) 4 240 69 421F +886 (0) 4 240 69 [email protected]

    Bulgaria/Cathode sheet

    Bulmet

    Blvd. Slivnitza 212, vh.D,et.6, ap.171202 SofaBULGARIAT +35 929 83 1936F +35 929 83 [email protected]

    Denmark

    P. Funder & Son ApS

    Nyhavn 47, 2. sal1051 Kobenhavn K.DENMARKT +45 39 63 89 83F +45 39 63 89 70

    [email protected]

    India

    Protos Engg Co PVT Ltd.

    173, Thakur NiwasJ tat a roadChurchgateMumbai - 400020INDIAT +91 22 66 28 7030F +91 22 22 02 [email protected]

    Israel

    Bino Trading

    Haziporen 1430500 BinyaminaISRAELT +972 4 6389992F +972 4 [email protected]

    Italy/Aircrat plate

    Aerospace Engineering

    Via Rimassa, 41/616129 GenovaITALYT +39 010 55 08 51F +39 010 574 [email protected]

    Representatives of AMAG rolling GmbH

    AMAG Austria Metall AG

    P.O. Box 3

    5282 RanshoenAUSTRIAT +43 7722 801 0F +43 7722 809 [email protected]

    10.2

    012