List of Supporting Documentation - · PDF fileADM Technical Services . 4666 Faries Parkway Decatur, IL 62526 . Phone: 800-637-5843 Fax: 217/451-2153 . . List of Supporting Documentation

ADM Technical Services

4666 Faries Parkway Decatur, IL 62526

Phone: 800-637-5843 Fax: 217/451-2153

www.adm.com

List of Supporting Documentation

1. Process and Product Protection Assurance Letter

2. C-TPAT certificate

3. Environmental Information and mission statement

4. Organizational Chart

5. GSSC 22000:GFSI Certificate

6. SOP Index

7. Product Data Sheet

8. Nutritional Information

9. Allergen Information

10. Lot Numbering System Information

11. Material Safety Data Sheets (MSDS)

12. BSE/TSE Statement

13. GMO Statement

14. Proposition 65 Statement

15. Residual Solvents Information

16. Certificate of Origin

17. Kosher/Halal Certificates

18. Example C of A

19. HACCP Flow Chart

20. Irradiation and Sewer Sludge statement (Organic Information)

21. The National List of Citric Products (Organic Information)

22. Product Guarantee

23. Ingredient Statement

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you

evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER

EXPRESS OR IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for

breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the

purchase price of material purchased from us. None of the statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for

obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland

Company ingredients. Rev. 02/11/2015

ADM SOUTHPORT

MASTER DOCUMENT MANUAL #2

LIST OF SOP

=================================================================

SOP100. . . . . . . WRITING PROCEDURES

SOP101. . . . . . . PURCHASING

SOP102. . . . . . . SUPPLIER APPROVAL

SOP103. . . . . . . LABELING CONTROL

SOP104. . . . . . . MATERIAL IDENTIFICATION

SOP105. . . . . . . MANUFACTURING PROCEDURES

SOP106. . . . . . . IN PROCESS CONTROLS

SOP107. . . . . . . PROCESS CHANGE PROCEDURE

SOP108. . . . . . . MASTER MFG. PLAN:CITRIC/CITRATES

SOP109. . . . . . . ISSUE OF PACKAGING SPECIFICATIONS

SOP110. . . . . . . VERIFICATION OF RAW MATERIALS

SOP111. . . . . . . RELEASE OF PACKAGING MATERIALS

SOP112. . . . . . . ISSUE OF RAW MATERIAL SPEC

SOP113. . . . . . . RETAINED SAMPLES OF RAW MATERIALS

SOP114. . . . . . . SHIPMENT OF SAMPLES

SOP115. . . . . . . PERFORMANCE/QUALITY TRENDS

SOP116. . . . . . . RECORDS REVIEW

SOP117. . . . . . . INSPECTION OF FINISHED GOODS

SOP118. . . . . . . RELEASE OF FINISHED GOODS

SOP119. . . . . . . ISSUES OF CERTIFICATES OF ANALYSIS

SOP120. . . . . . . RECORDS RETENTION

SOP121. . . . . . . APPARATUS IDENTIFICATION

SOP122. . . . . . . MAINTENANCE & CALIBRATION OF WEIGHT & MEASURING

SOP123. . . . . . . CALIBRATION OF LAB INSTRUMENTS

SOP124. . . . . . . EQUIPMENT IDENTIFICATION

SOP125. . . . . . . INSTRUMENT CALIBRATION - MAINT.

SOP126. . . . . . . ISOLATION OF REJECTED MATERIAL

SOP127. . . . . . . REWORK PROCEDURE

SOP128. . . . . . . PRODUCT WITHDRAWAL PROCEDURE

SOP129. . . . . . . CORRECTIVE-PREVENTATIVE ACTION

SOP130. . . . . . . COMPLAINT PROCEDURE

SOP131. . . . . . . CONTRACT REVIEW

SOP132. . . . . . . PURCHASER SUPPLIED PRODUCT

SOP133. . . . . . . DOCUMENT CONTROL

SOP134. . . . . . . STATISTICAL TECHNIQUES

SOP135. . . . . . . FINISHED GOODS HANDLING

SOP136. . . . . . . PEST CONTROL

SOP137. . . . . . . PACKAGING

SOP138. . . . . . . MATERIAL MOVEMENT PROCEDURE

SOP139. . . . . . . AUDITING

SOP140. . . . . . . PERSONNEL TRAINING

SOP141. . . . . . . PERSONNEL TRAINING - QC DEPT.

SOP142. . . . . . . QUALITY CONTROL OF WATER

SOP143. . . . . . . RECORDED LABORATORY WORK

SOP144. . . . . . . RESERVE SAMPLE OF FINISHED GOODS

SOP145. . . . . . . PREVENTION OF CONTAMINATION FROM ENGINEERING WORK

SOP146. . . . . . . PLANT COMPUTER CONTROL

SOP147. . . . . . . PRODUCT/PERSONAL PROTECTION PROCEDURE

ADM SOUTHPORT

MASTER DOCUMENT MANUAL #2

LIST OF SOP

=================================================================

SOP148. . . . . . . USE OF SAMPLING DEVICES

SOP149. . . . . . . MATERIAL DISPOSAL

SOP150. . . . . . . CLEANING OF PRODUCTION

SOP151. . . . . . . RETURNED GOODS PROCEDURE

SOP152. . . . . . . ASSEMBLY OF FINISHED GOODS LOT DOSSIER

SOP153. . . . . . . HANDLING OF SPECIAL CUSTOMER REQUIREMENTS

SOP154. . . . . . . FAILURE ANALYSIS

SOP155. . . . . . . DAILY PRODUCTION STATUS REPORT

SOP156. . . . . . . ISSUE OF PRODUCT SPECIFICATIONS

SOP157. . . . . . . HANDLING OF REGULATORY INSPECTIONS

SOP158. . . . . . . GOOD MANUFACTURING PRACTICES

SOP159. . . . . . . HAZARD ANALYSIS CRITICAL CONTROL POINT PLAN

SOP160. . . . . . . SEALING PROCEDURE

SOP161. . . . . . . PRODUCT DOWNGRADE

SOP162. . . . . . . NON-SOLUBILE RESIDUE, NSR SAMPLING PROTOCOL

SOP163. . . . . . . STABILITY TESTING PROGRAM

SOP164. . . . . . . ALLERGEN CONTROL SOP165. . . . . . . REWORK PROGRAM

SOP166. . . . . . . PRODUCT CONTACT AIR QUALITY PROGRAM SOP167. . . . . . . PRODUCT INFORMATION PROGRAM SOP168. . . . . . . FACILITY SECURITY/ACCESS CONTROL ASSESSMENT SOP169. . . . . . . GLASS BRITTLE PLASTIC POLICY SOP170. . . . . . . ENVIRONMENTAL MONITORING PROGRAM SOP172. . . . . . . CHEMICAL CONTROL PROGRAM SOP175. . . . . . . CONDITIONED AIR QUALITY AND VENTILATION IN FINISHED PACKAGING AND

WAREHOUSE SOP175. . . . . . . HACCP PLAN FOR CITRIC ACID SOP176. . . . . . . HACCP PLAN FOR CITROSOL 501 SOP177. . . . . . . HACCP PLAN FOR SODIUM AND POTASSIUM CITRATE SOP178. . . . . . . MANAGEMENT OF CHANGE (MOC) SOP179. . . . . . . SOFTWARE CHANGE REQUEST SOP180. . . . . . . ASSESSMENT OF FOOD SAFETY TRAINING EFFECTIVENESS SOP181. . . . . . . DAILY MEETING ACTION ITEM PROCEDURE ESOP600. . . . . . . SOUTHPORT- LEGAL ENVIRONMENTAL REQUIREMENTS (2) ESOP601. . . . . . . SOUTHPORT IDENTIFYING ENVIRONMENTAL ASPECTS

___________________________________________________________________________________________________

Citric Acid Anhydrous, USP/FCC (Excipient/Food Use)

020410, 020420, 020440 Acidulant

Archer Daniels Midland Co. Technical Services Phone: 800-637-5843

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to

change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY

DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach

of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall be

construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be

necessary to make, use, or sell products containing Archer Daniels Midland Company ingredients.

Description Citric acid anhydrous is widely used in the food, beverage, and pharmaceutical industries to impart a clean, refreshing tartness. Its prime use is as an acidulant, but it is also used as sequestrant of metal ions to give protection from the development of off-flavors and off-odors in certain foodstuffs.

A major industrial use of citric acid is in the manufacture of ecologically compatible detergents. It is also used in chemical cleaning, concrete admixtures, plasticizers, and a range of other applications.

General Characteristics

Formula H3C6H5O7 Molecular Weight 192.13 Solubility (g/100 ml at 25°C)

In Water 162 In Alcohol 59.1

Taste Tart

Standard Specifications

Appearance Free-flowing, colorless, translucent crystals or as a white granular to fine crystalline powder.

Odor None Identification Meets USP/FCC Clarity of Solution Meets USP Color of Solution Meets USP Assay (anhydrous basis) 99.5 to 100.5% Water Maximum 0.5% Residue on Ignition Maximum 0.05% Limit of Oxalic Acid Maximum 0.036% Sulfate Maximum 0.015% Heavy Metals (as lead) Maximum 5.0 ppm Lead Maximum 0.5 ppm Readily Carbonizable

Substances Not darker than matching fluid K. Tridodecylamine Not Applicable. ADM does not use

solvent extraction process. Oxalate Passes Test

Ingredients

Citric Acid

Storage & Shelf Life

Storage below 75°F and 55% relative humidity in tightly sealed container is recommended. This product is very stable and has been given a 3 year "best by" date. It is recommended to retest after 3 years.

Granulations USS Sieves (microns)

Granular On No. 16 (1180μ), maximum 2% Through No. 50 (300μ), maximum10%

Fine Granular On No. 30(600μ), maximum 3% Through No. 100 (150μ), maximum 5%

Powder On No. 60 (250μ), Maximum 2% Through No. 200 (75μ), minimum 50%

Packaging & Packaging Code Granular 50 lb. bags 020410-0H

25 kg bags 020410-2P 250 lb. drums 020410-5S 1000 kg totes 020410-9R

Fine Granular 50 lb. bags 020420-0H 25 kg bags 020420-2P 250 lb. drums 020420-5S 1000 kg totes 020420-9R

Powder 200 lb. drums 020440-2S

Regulatory Status

This Food Additive complies with all the compendial requirements of the U.S. Pharmacopeia, Food Chemical Codex, Code of Federal Regulations, European Pharmacopoeia, British Pharmacopoeia, Japanese Pharmacopeia, and W.H.O./F.A.O. Food Additive Specification.

CAS Number: 77-92-9

CA-001-130514

Citric Sodium Sodium Potassium Citrosol 501 Potassium GDL Potass sium GDL

Acid Citrate Citrate Citrate (50% Citric

Anhydrous Dihydrate Anhydrous Acid Solution,

Food Grade)

(Typical amount per 100 g)

Moisture (g) .5 12 1 5 50

Protein (g) 0 0 0 0 0

Fat (g) 0 0 0 0 0

Trans Fats (g) 0 0 0 0 0

Cholesterol (mg) 0 0 0 0 0

Carbohydrates (g) 99.45 64.5 72.3 58.8 49.73

Crude Fiber (g) 0 0 0 0 0

Soluble Fiber (g) 0 0 0 0 0

Calories 247 159 181 145 123.5

Sodium (mg) .3 23,450 26,700 30 .15

Potassium (mg) .3 24 27 36,200 .15

Calcium (mg) .2 .3 .31 .3 .1

Iron (mg) < .01 .1 .1 .04 < .01

Vitamin A (IU) 0 0 0 0 0

Vitamin C (mg) 0 0 0 0 0

Thiamine (mg) 0 0 0 0 0

Riboflavin (mg) 0 0 0 0 0

Niacin (mg) 0 0 0 0 0

Vitamin D (IU) 0 0 0 0 0

Vitamin E (IU) 0 0 0 0 0

Vitamin B6 (mg) 0 0 0 0 0

Folic Acid (mcg) 0 0 0 0 0

Vitamin B12 (mcg) 0 0 0 0 0

Alcohol (g) 0 0 0 0 0

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are

responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland Company ingredients. CA-028-130530

ARCHER DANIELS MIDLAND COMPANY BOX 1470 DECATUR, ILLINOIS 62525 TEL: 800/ 637-5843 or 217/ 451-3086 FAX: 217/ 451-2473

WWW.ADM.COM

NUTRITIONAL INFORMATION

FOR

CITRIC PRODUCTS



Phone: 217/451-7418 Fax: 217/451-2473

Allergen Statement

Ingredient: ________________CITRIC ACID_________________________________

Allergen Present in product Used in same equipment Present in plant

Cereals containing gluten,

such as wheat, rye, barley,

oats, spelt, buckwheat and

triticale

No No No

Peanut, and peanut

products

No No No

Soybean and soy products No No No

Tree nuts, such as almond,

brazil nut, cashew,

hazelnut (filbert),

macadamia, pecan, pine

nut, pistachio, and walnut

No No No

Milk and dairy products No No No

Crustacea and crustacea

products

No No No

Egg and egg products No No No

Fish and fish products No No No

Other allergens such as

cottonseed, sesame seed,

poppy seed, sunflower

seed, other legumes,

mollusks, celery, rice and

buckwheat

No No No

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without

guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE

DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach

of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us.

None of the statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels

Midland Company ingredients

CA-078-120723

- A Division of Archer Daniels Midland Company -

TO WHOM IT MAY CONCERN

CITRIC ACID LOT NUMBERING SYSTEM

For dry citric products, Citric Acid Anhydrous, USP/FCC, Sodium Citrate Dihydrate, USP/FCC, Sodium Citrate

Anhydrous, USP/FCC, and Potassium Citrate Anhydrous, USP/FCC:

S402161

Where S = production site (Southport, NC)

4 = last digit of year; 2004

02 = month; February 01 to 12 scale

16 = day of month

1 = packaging bin number

For Citrosol 501, 502 and 503, 50% Citric Acid Solutions:

04021601

Where 04 = last 2 digits of year; 2004

02 = month; February 01 to 12 scale

16 = day of month

01 = batch sequence identifier for that day

Sincerely,


The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall be construed as a grant, either express or implied, of any license under any patent held by

Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland Company ingredients.

ARCHER DANIELS MIDLAND COMPANY BOX 1470 DECATUR,ILLINOIS 62525 TEL: 800/637-5843 or 217/451-7418 FAX: 217-451-2473

www.adm.com

CA-025-121218

Original Preparation Date: 15-Apr-2009

WHMIS

Revision Date: 30-Apr-2013

(Material) Safety Data Sheet

Revision Number: 2

NFPA Personal Protective EquipmentTransport Symbol

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

OSHA / GHS Label Elements

2. HAZARDS IDENTIFICATION

Signal Word: Warning

GHS Hazard Pictogram(s):

Hazard Statement(s): H319 Causes serious eye irritationMay form combustible dust concentrations in air.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Precautionary Statements: Prevention Precautionary Statements:Wash hands and exposed skin thoroughly after handling. Wear eye protection.Response Precautionary Statement(s):If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice.

Classification according to 29 CFR 1910, amended to conform to the United Nations' Globally Harmonized System ofClassification and Labelling of Chemicals (GHS):Serious Eye Damage / Eye Irritation Category 2

Hazards Not Otherwise Classified Combustible Dust

Product Code:020410, 020420, 020440

Synonyms:2-hydroxy-1,2,3-propanetricarboxylic acid, or2-hydroxypropane-1,2,3-tricarboxylic acid

______________________________________________________________________________________________________________

Product Name:Citric Acid Anhydrous

Emergency response telephone number:Chemtrec 1-800-424-9300 (CCN 1635)

Contact Manufacturer:Archer Daniels Midland Company4666 Faries ParkwayDecatur, IL 62526, USATelephone Number: (+1) 217-424-5200

Use of the Substance / Preparation:Chemical intermediate Personal care productsCleaning/detergent products and other household productsPaper products Construction products Polymers and plasticsproducts Oil industry Textile industry Paints and coatingsPhotography products Laboratory reagents Water treatmentTreatment of metal surfaces Agricultural applications Medicaldevices Food additive

Emergency OverviewWarning. Irritating to eyes. Corrosive to metals (as aqueous solution). Product dust may cause mild, mechanical

irritation. May form combustible dust concentrations in air (during processing and handling).

Page 1 / 8

AppearanceWhite

North America (OSHA/GHS and WHMIS Compliant)

OdorOdorless

Physical StateSolid: Powder / Granular

______________________________________________________________________________________________________________

Revision Date: 30-Apr-2013020410, 020420, 020440 - Citric Acid Anhydrous

4. FIRST AID MEASURES

5. FIRE-FIGHTING MEASURES

Flammable PropertiesFine dust dispersed in air may ignite. Risk of ignition followed by flame propagation or secondary explosions should be preventedby avoiding accumulation of dust, e.g. on floors and ledges.

Extinguishing media Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO2). Water spray. Foam. Use extinguishing measures that areappropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media No information available.

77-92-9

Inhalation Move to fresh air.

99-100

Notes to Physician Treat symptomatically.

Hazardous Combustion Products Thermal decomposition can lead to release of irritating gases and vapors, Carbonmonoxide (CO), Carbon dioxide (CO2).

OSHA / GHS: Eye Irrit. 2;WHMIS: E

Skin According to GHS hazard classification criteria, the product is not considered as being a skin irritant. Product dust may causemild, mechanical irritation. Health injuries are not known or expected under normal use.

Description of first aid measures

3. COMPOSITION/INFORMATION ON INGREDIENTS

Specific Hazards Arising from theChemical

None known.

Ingestion Clean mouth with water and afterwards drink plenty of water.

Inhalation May cause irritation of respiratory tract. Based on the low pH, citric acid would be expected to cause irritation to therespiratory tract, resulting in a higher cough response as the inhalation exposure concentration was increased.

Sensitivity to mechanical impact No.

General Advice If symptoms persist, call a physician. Show this safety data sheet to the doctor in attendance. Use personalprotective equipment. For personal protection see section 8.

Chemical Family

Protection of First-aiders Use personal protective equipment. Avoid contact with skin, eyes and clothing.

Ingestion Oral exposure is not anticipated under normal working conditions. Health injuries are not known or expected undernormal use.

Acids

Sensitivity to static discharge Yes. (as dust).

The following component(s) in this product are considered hazardous under applicable OSHA (USA), WHMIS (Canada),and/or NOM-002-SCT-2003 (Mexico) regulations

Chemical nature of the preparation Substance

Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for atleast 15 minutes. If symptoms persist, call a physician.

Main Symptoms Itching. Redness. Burning sensation.

Further information Fine dust dispersed in air may ignite. Dust explosibility class = 1. Weak to moderatelyexplosible.

Chemical Name CAS-No Weight % North American Hazard Indicator

Most important symptoms and affects, both acute and delayed

______________________________________________________________________________________________________________

Molecular Formula

Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes.

C6H8O7

Indication of any immediate medical attention and special treatment needed

Page 2 / 8

Eyes Irritating to eyes. Contact with eyes may cause mechanical irritation.


Special hazards arising from the substance or mixture

Citric acid

______________________________________________________________________________________________________________

020410, 020420, 020440 - Citric Acid Anhydrous Revision Date: 30-Apr-2013

General Hygiene Considerations When using, do not eat, drink or smoke. Regular cleaning of equipment, work area andclothing.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal Protective Equipment Eye/face Protection. Safety glasses with side-shields. If airborne dust concentrations are excessive, wear

goggles.

Skin and Body Protection Impervious gloves. Long sleeved clothing. Boots.

Exposure LimitsAs an airborne dust, exposure limits pertaining to "particulates not otherwise regulated" have been provided below. Specificexposure limits have not been identified for this product. However, as an irritant, it is advisable to limit worker exposure to thegreatest extent possible.

Respiratory Protection Respirator with a dust filter. In case of insufficient ventilation wear suitable respiratoryequipment.

Personal PrecautionsAvoid contact with the skin and the eyes. Use personal protective equipment. For personal protection see section 8. Avoid dustformation.

Chemical Name ACGIH TLV OSHA PEL MEXICO NIOSH

Environmental PrecautionsPrevent further leakage or spillage if safe to do so. Prevent product from entering drains.

Particulates not otherwiseregulated

TWA: 10 mg/m3 inhalableparticles, recommended

TWA: 3 mg/m3 respirableparticles, recommended

TWA: 15 mg/m3 total dustTWA: 5 mg/m3 respirable

fraction

not listed not listed

6. ACCIDENTAL RELEASE MEASURES

Methods for Clean-upPick up and transfer to properly labelled containers. Avoid dust formation. Keep in suitable, closed containers for disposal.Aqueous spillage should be neutralized and treated prior to discharge. For disposal information see section 13.

Engineering Measures Local exhaust ventilation. Ensure adequate ventilation, especially in confined areas.

StorageKeep containers tightly closed in a cool, well-ventilated place. Keep in properly labelled containers. Keep at temperature notexceeding 23.9°C / 75°F. at 55% relative humidity. Keep away from metals. Corrosive to metals (as aqueous solution). Keep awayfrom oxidizing agents. Keep away from strong bases. Keep away from amines.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

7. HANDLING AND STORAGE

Advice for fire-fighters

HandlingWear personal protective equipment. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygieneand safety practice. Do not breathe vapours/dust. Use only in area provided with appropriate exhaust ventilation. Avoid dustformation in confined areas. Fine dust dispersed in air may ignite. Ensure adequate ventilation. Refer to NFPA 61, "Standard forthe Prevention of Fires and Dust Explosions in Agricultural and Food Processing Facilities".

NFPA

______________________________________________________________________________________________________________

Physical hazard None known

Stability and Reactivity 0

Page 3 / 8

Flammability 1


Health 1

______________________________________________________________________________________________________________


Skin corrosion/irritation Based on available data, not, or only slightly irritating.

Serious eye damage/eye irritation Irritant, causes serious eye irritation.

Acute toxicity Based on available data, the classification criteria are not met.

Chemical Name Weight % LD50 Oral LD50 Dermal LC50 Inhalation

Information on toxicological effects

Citric acid 99-100 5400 mg/kg Mouse11700 mg/kg Rat

>2000 mg/kg bw Rat

11. TOXICOLOGICAL INFORMATION

Incompatible Materials Amines. Heavy metals. Strong oxidizing agents. Strong bases.

Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapors, Carbonmonoxide (CO), Carbon dioxide (CO2).

Method OECD Guideline 405 (Acute Eye Irritation / Corrosion)

10. STABILITY AND REACTIVITY

Species Rabbit (New Zealand White)

9. PHYSICAL AND CHEMICAL PROPERTIES

Reactivity Reactions with metal nitrates may be potentially explosive. Aqueous form is corrosive to copper, zinc, aluminum andtheir alloys.

Stability Not applicable. Stable under normal conditions.

Possibility of Hazardous Reactions None under normal processing.

Conditions to Avoid Avoid dust formation. Heat, flames and sparks.

3.13, 4.76, and 6.4 at 25°C

Physical State

Autoignition Temperature

Vapor Density Not applicable

Decomposition temperature No information available

Not applicable (No obligation to report where the autoignition temperature is >400°C.)

Water Solubility 590g/l at 20°C

Density 1.665g/m3 at 20°C

Relative Density1.665g/m3 at 20°C

Solid: Powder / GranularWhite

pH 1 .8 @ 25°C at 5wt% conc

Oxidizing Properties

Bulk Density 500-950kg/m3 at 20°C

Solubility(ies)

Not oxidizing

Odor

Boiling point

Viscosity Not applicable (solid)

Not applicable (decomposes before boiling)

Odor Threshold

Surface Tension Not applicable. (no surface tension anticipated).

Not applicable

Partition Coefficient(n-octanol/water)

-0.2 to -1.8

Flammability Limits in Air Not flammable

Flash Point Not applicable (solid)

Evaporation Rate

Explosive Properties Not explosive

______________________________________________________________________________________________________________

Not applicable (solid)

Odorless

Melting/Freezing Point 153.000 °C / 307.000 °F (101.3 kPa)

Explosion Limits Not explosive

Vapor Pressure

Page 4 / 8

2.21E-6 Pa at 25°C Not applicable


Appearance

Dissociation Constants (pKa)

______________________________________________________________________________________________________________


Chemical Name Fresh Water Algae Acute Fish Toxicity Daphnia(Water flea)

Effects onmicro-organisms

Other

Skin

Citric acid NOEC(8d): 425mg/l(nominal)*

LC50(48h):440mg/L(Leuciscus

idus)(nominal)

EC50(24h): 1535mg/L(Daphnia

magna)(nominal)

According to GHS hazard classification criteria, the product is not considered as being askin irritant. Product dust may cause mild, mechanical irritation. Health injuries are notknown or expected under normal use.

Based on available data, no toxicity identified at highest exposure levels [NOAEL(rats)4000mg/kg bw/d].

*Determined by extrapolation (testing of intrinsic toxicity to algae impractical due to nutrient complexing behaviour of citric acid)

Based on available data, no evidence of carcinogenicity.

Inhalation May cause irritation of respiratory tract. Based on the low pH, citric acid would be expectedto cause irritation to the respiratory tract, resulting in a higher cough response as theinhalation exposure concentration was increased.

Predicted No Effect Concentrations (PNEC) - Determined by extrapolation

Respiratory or skin sensitisation

Aspiration hazard

Chemical Name Aqua(fresh water)

Aqua(marine)

SewageTreatment Plant

Sediment(fresh water)

Sediment(marine)

Soil

Ingestion

Citric acid 0.44mg/l 0.044mg/l >1000mg/l 34.6mg/kgsediment dw

3.46mg/kgsediment dw

33.1mg/kg

Oral exposure is not anticipated under normal working conditions. Health injuries are notknown or expected under normal use.

Based on available data, no known aspiration hazard.

Germ cell mutagenicity

Bioaccumulative Potential Bioaccumulation is unlikely. [Logkow < 0].

Reproductive toxicity

Chemical Name log Kow BCF

Main Symptoms

Citric acid -0.2 to -1.8 BCF ~ 3.2 (estimated)

Itching. Redness. Burning sensation.

Based on available data, no evidence of reproductive toxicity

Persistence/Degradability Readily biodegradable. Inherently biodegradable. 97% and 100% biodegradability in 28dand 19d, respectively (protocols OECD 301E and OECD 301A, respectively).

Based on available data, negative to test/non-mutagenic.

Mobility Soluble in water.

Based on available data, not expected to be a skin or respiratory sensitiser.

PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).

STOT - single exposure

12. ECOLOGICAL INFORMATION

Potential health effects

No evidence of toxicity.

______________________________________________________________________________________________________________

Ecotoxicity

Eyes Irritating to eyes. Contact with eyes may cause mechanical irritation.

Not classified for aquatic toxicity. Contains no substances known to be hazardous to the environment. Contains no substancesknown to be not degradable in waste water treatment plants.

Carcinogenicity

STOT - repeated exposure

Page 5 / 8

Irritating: Overall irritation score for 10% solution: 9.3 of max. 110 (mean (of 3 animals))(Time point: at 1, 24, 48 or 72 h) (fully reversible within: 7 days) (score achieved at 1 h)Overall irritation score for 30% solution: 16 of max. 110 (mean (of 3 animals)) (Time point:at 1, 24, 48 or 72 h) (not fully reversible within: 14 days) (fully reversible in 14-21 days)(expert opinion) (score achieved at 1 h)


Results

______________________________________________________________________________________________________________


DOT Not regulated

Domestic transport regulations (Mexico)

15. REGULATORY INFORMATION

International Inventories

MEX Not regulated

The components of this product are reported in the following inventories:

Chemical Name TSCA DSL NDSL EINECS ELINCS AICS ENCSISHL

CHINA PICCS KECL NZIoC

Citric acid Yes Yes No Yes201-069-1

No Yes Yes(2)-1318

Yes Yes YesKE-20831

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 63)This product is not known to contain any HAPS.

No

Domestic transport regulations (Canada)

State Regulations

International transport regulations

Domestic transport regulations (USA)

ICAO Not regulated

TDG Not regulated

IATA Not regulated

14. TRANSPORT INFORMATION

IMDG/IMO Not regulated

CERCLA/SARA 103-302Sections 103-302 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product is not known tocontain any chemicals which are subject to the reporting requirements of the Act or regulations contained in 40 CFR 103-302.

Dispose of in compliance with the laws and regulations pertaining to this product in yourjurisdiction. Rinsewater resulting from cleanup should be collected for treatment beforedisposal. Solutions with low pH-value should be neutralized before discharge.

Ozone Depleting Substances:No Class I or Class II material is known to be used in the manufacture of, or contained in, this product.

Chronic Health Hazard No

USA

13. DISPOSAL CONSIDERATIONS

Contaminated Packaging Empty containers should be decontaminated and taken for local recycling, recovery orwaste disposal.

Fire Hazard No

SARA 311/312 Hazardous Categorization

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product is not known tocontain any chemicals which are subject to the reporting requirements of the Act or regulations contained in 40 CFR 372.

Federal Regulations

______________________________________________________________________________________________________________

Sudden Release of Pressure Hazard No

Whenever possible, as rules and regulations allow, please recycle or manage materials to minimize waste.

Acute Health Hazard Yes

Waste Disposal Methods

Page 6 / 8North America (OSHA/GHS and WHMIS Compliant)

Reactive Hazard No

______________________________________________________________________________________________________________


WHMIS Product ClassificationClass E: Corrosive Material.

Chemical Name

Prepared By: ADM Specialty Food, Corn

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) andthe SDS contains all the information required by the CPR.

Weight %

Original Preparation Date: 15-Apr-2009

WHMIS IDL

Revision Date: 30-Apr-2013

WHMIS Threshold limits

Revision Number: 2

Mexico

Reason for revision: New SDS format. This version replaces all previous versions.

State Right-to-KnowNo known components subject to "Right-To-Know" legislation in the following States:. Massachusetts. Minnesota. New Jersey.Pennsylvania.

Abbreviations and acronymsAICS - Australian Inventory of Chemical Substances (Australia)CAS - Chemical Abstract ServiceCHINA - Chinese Inventory of Existing Chemical Substances (China)DNEL - Derived No Effect LevelDOT - U.S. Department of TransportationDSL - Domestic Substance List (Canada)EC50 - Half maximal effective concentrationEINECS - European Inventory of Existing Commercial Chemical Substances (EU)ELINCS - European List of Notified Chemical Substances (EU)ENCS - Existing and New Chemical Substances (Japan) / ISHL - Industrial Health and Safety Law (Japan)GHS - Globally Harmonized System of Classification and Labelling of ChemicalsIATA - International Air Transport Association Dangerous Goods RegulationsICAO - International Civil Aviation OrganisationIMDG - International Maritime Dangerous Goods CodeIMO - International Maritime OrganizationKECL - Korean Existing and Evaluated Chemical Substances (Korea)LC50 - Lethal concentration that produces fatalities in 50% of a given test populationLD50 - Median lethal dose of a given test populationMEX - NOM-002-SCT/2003 List of Hazardous Substances and Materials Most Commonly TransportedMEXICO - Mexico Occupational Exposure LimitsNDSL - Non Domestic Substances List (Canada)NFPA - National Fire Protection AssociationNIOSH - National Institute of Occupational Safety and HealthNZIoC - New Zealand Inventory of Chemicals (New Zealand)OECD - Organisation for Economic Co-operation and DevelopmentOSHA - Occupational Safety & Health AdministrationOSHA PEL - Occupational Safety and Health Administration Permissible Exposure LimitsPICCS - Inventory of Chemicals and Chemical Substances (Philippines)PNEC - Predicted No-Effect ConcentrationSTOT - Specific Target Organ ToxicityTSCA - Toxic Substances Control Act, Section 8(b) Inventory (USA)TWA - Time Weighted Average: Average concentration that should not be exceeded during a work day (usually 8-hours)vPvB - Very Persistent and Very BioaccumulativeWGK - Wassergefährdungsklasse (German: Water Hazard Class)WHMIS - Workplace Hazardous Materials Information System

Citric acid

Mexico - Grade Moderate risk, Grade 2

______________________________________________________________________________________________________________

99-100 Listed 1%

WHMIS Ingredient Disclosure List IDLComponent Information

16. OTHER INFORMATION

Canada

Page 7 / 8

(NPRI) Canadian National Pollutant Release InventoryNo known component is listed on NPRI.


______________________________________________________________________________________________________________


______________________________________________________________________________________________________________

North America (OSHA/GHS and WHMIS Compliant) Page 8 / 8

The information provided on this (M)SDS is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the text.

End of sheet

Archer Daniels Midland Company Corn Business Unit

ADM Technical Services │ 4666 Faries Parkway, Decatur IL 62526 P: 800.238.9026 │ F: 217.451.2153 │ [email protected]

Animal Testing, BSE (Bovine Spongiform Encephalopathy) and TSE (Transmissible Spongiform Encephalopathy) Statements

Archer Daniels Midland Company (ADM) manufactures the products listed below. ADM does not conduct animal testing on these products for cosmetic purposes or for use in house hold cleaning agents. ADM would have no knowledge of animal testing performed on these products after they are sold into commercial or government markets.

As well, these products do not contain, and are not processed, with any animal products, by-products, or any animal derived products.

• CornSweet® High Fructose Corn Syrups • Clintose® Versadex Dextrose Greens • Corn Syrups • Fibersol®-2 Resistant Maltodextrin • Clintose® Dextrose • Fibersol®-HS

• Fibersol®-2AG • Fibersol®- LQ

• CornSweet® Crystalline Fructose • Food Grade Starch • Clintose® Maltodextrin • Liquid Invert Sugar • Clintose® Corn Syrup Solids • Sucrose • Sorbitol Solution, USP/FCC (Excipient/Food Use) • Sorbitol Solution Noncrystallizing, NF • Sorbitol Crystalline NF/FCC • Citric Anhydrous Acid USP/FCC • Citrosol® 501 • Sodium Citrate Anhydrous & Dihydrate USP/FCC • (Arlac S) Sodium Lactate FCC • (NovaXan™) Xanthan Gum, NF/FCC

• Un-modified and Modified Corn Starch • Ethyl Lactate • Potassium Citrate USP/FCC • Lactic Acid USP/FCC • (Arlac P) Potassium Lactate FCC • Glycerin USP/FCC • Propylene Glycol USP/FCC

If you have any questions, please do not hesitate to contact us.


Date Approved Version Document # June 16,2014 1.0 CBU.TS.MISC.003

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company ingredients.

www.adm.com

Archer Daniels Midland Company

Corn Business Unit

ADM Technical Services │ 4666 Faries Parkway, Decatur IL 62526

P: 800.238.9026 │ F: 217.451.7574 │ [email protected]

Date Approved Version Document #

04/16/2013 1.0 CBU.TS.MISC.102

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to

results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR

IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any

claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the

statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company ingredients.

www.adm.com

Genetically Modified Organisms (GMO) Statement

Archer Daniels Midland Company (ADM) contracts to procure its raw material corn from only European Union (EU)

approved varieties. Due to our large scale of operations, non-GM and GM corn cannot be segregated from one another.

Consequently, ADM’s products may or may not be produced from GM corn. The list of products can be seen at the end of

this document.

Current industry consensus is that GM DNA, or protein, in the raw material stream is denatured, degraded, or removed

through refining by successive processing which includes physical separation, heating, purification, and filtration. As a

result, GM DNA, or protein, most likely cannot be detected in measurable amounts in highly refined products.

While we do not expect to detect GM DNA or protein, ADM does periodically test for the presence of protein and DNA.

Previous samples tested for GM DNA were reported negative by a third party. We are unable to state a limit of detection

for DNA given the negative results. In addition, ADM Laboratory tests conducted for protein have tested below a

detection limit of 0.1%.

Clintose Dextrose

Clintose Maltodextrin

Clintose Corn Syrup Solids

CornSweet High Fructose Corn Syrup

CornSweet Crystalline Fructose

Corn Syrup

Clintose Versadex Dextrose Greens

Fibersol-2 Resistant Maltodextrins

Citric Acid and Citrates

Polyols

Lactic Acid

Xanthan Gum

Glycols

If you have any questions, please do not hesitate to contact us.

ADM Corn Technical Services



Phone: 217/451-4524 Fax: 217/451-2473

www.adm.com

USP <467> Residual Solvents in Citric Products

To Whom It May Concern:

ADM Citric products (Citric Acid; Sodium Citrate and Potassium Citrate) are produced by an

aqueous fermentation and recovery process. No USP <467> Class 1, Class 2, Class 3 solvents, or

other solvents are used in the manufacture of these products nor are they likely to be present in the

finished products.

If you need any additional information or if you have any questions, please, do not hesitate to contact

me.

Sincerely,

ADM Technical Service

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and

suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY

DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include

consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall

be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland

Company ingredients.

CA-029-131002

TO WHOM IT MAY CONCERN

CERTIFICATE OF ORIGIN

CITRIC ACID AND CITRATE PRODUCTS

This is to confirm that the following products are produced by the Archer Daniels Midland Company at our Southport, North Carolina, manufacturing facility located at 1730 E. Moore Street SE, Southport, NC USA:

Citric Acid Anhydrous, USP/FCC Sodium Citrate Dihydrate, USP/FCC Sodium Citrate Anhydrous, USP/FCC

Potassium Citrate, USP/FCC Sincerely, Technical Services

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland Company ingredients.

CA-076-130102

ARCHER DANIELS MIDLAND COMPANY BOX 1470 DECATUR, ILLINOIS 62525 TEL: 800/ 637-5843 or 217/ 451-7418 FAX: 217/ 451-2473

WWW.ADM.COM

Archer Daniels Midland


Phone: 217/451-3086 fax: 217/451-2473

website:www.adm.com

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and

suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SPECIFICALLY

DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include

consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements made here shall

be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland

Company ingredients.

HACCP FLOW SHEET - ADM SOUTHPORT

0.5 pH 80° C

SALTS ACA

CITROSOL 501

3.5 pHINCOMING MATERIAL FERMENTATION PURIFICATION

FILTRATION CRUDE CRYSTALLIZATION

WHITE LIQUOR TREATMENT oPRP1

FILTRATION

NEUTRALIZATION DRYING

FILTRATION

F.G. CRYSTALLIZATION

DRYING

MAGNETS

SIFTING

SCALPING SCREENS CCP1

PACKAGINGMETAL DETECTION CCP2

MAGNETS

SIFTING REDISSOLVE

FILTER oPRP2

LOADOUT

SCALPING SCREENS CCP1

PACKAGINGMETAL DETECTION CCP2

OPRP:Operational Prerequisite Program

CCP: Critical Control Point

ADM Technical Services 1001 N. Brush College Rd. Decatur, IL 62521

www.adm.com

May 22, 2013,


ADM Citric products (including citric acid, sodium citrate, and potassium citrate) have not been

irradiated nor have they been processed with sewer or industrial sludge. We are happy to

provide this information. Please feel free to contact us if we can be of further assistance.

Sincerely,

ADM Technical Service

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions

are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED,

AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE,

AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements

made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or

other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing Archer Daniels Midland Company ingredients.

Archer Daniels Midland Company

Corn Business Unit ADM Technical Services │ 4666 Faries Parkway, Decatur IL 62526

P: 800.238.9026 │ F: 217.451.2153 │ [email protected]

Date Approved Version Document #

02/12/2015 1.0 CBU.TS.MISC.021

The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to

results and are subject to change without notice. We suggest you evaluate any recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR

IMPLIED, AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any

claim for breach of warranty, negligence, or otherwise shall not include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the

statements made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company ingredients.

www.adm.com

Letter of Guarantee

ADM hereby warrants and guarantees that all of the following products sold to you have been approved by the U.S.

Food and Drug Administration for their use in foods or are Generally Recognized As Safe (GRAS), or exempt from the

provisions of the 1958 Additives Amendment to the Food, Drug and Cosmetic Act, and are allowed for sale in

Canada.

• CornSweet® High Fructose Corn Syrups • Clintose® Versadex Dextrose Greens

• Corn Syrups • Fibersol®-2 Resistant Maltodextrin

• Clintose® Dextrose • Fibersol®-2AG

• CornSweet® Crystalline Fructose • Fibersol®-LQTM

• Clintose® Maltodextrin • Fibersol®-HS

• Clintose® Corn Syrup Solids

• Food Grade Starch

• Liquid Invert Sugar* (sourced from sugarcane and sugar beets)

• Sucrose

• Sorbitol Solution, USP/FCC (Excipient/Food Use)

• Sorbitol Solution Noncrystallizing, NF

• Sorbitol Crystalline NF/FCC

• Citric Acid Anhydrous USP/FCC (Excipient/Food Use)

• Citrosol ® 501

• Sodium Citrate Anhydrous & Dihydrate USP/FCC

• (Arlac S) Sodium Lactate FCC

• (NovaXanTM

) Xanthan Gum, NF/FCC

• Un-Modified and Modified Corn Starch

• Ethyl Lactate

• Potassium Citrate USP/FCC (Excipient/Food Use)

• Lactic Acid USP/FCC (Excipient/Food Use)

• (Arlac P) Potassium Lactate FCC

• Glycerin USP/FCC (Excipient/Food Use)

• Propylene Glycol USP/FCC (Excipient/Food Use)

• VivaSweetTM

We further guarantee that none of the foregoing products comprising any shipment or other delivery now in transit

or hereafter made to you as is, as of the date of such shipment or delivery, adulterated or misbranded within the

meaning of the Federal Foods, Drug and Cosmetic Act or any practically similar state or municipal law, or is an article

which may not, under Section 404 or 505 of said Act, be introduced into Interstate Commerce.

All of the foregoing is a continuing guarantee, subject to revocation on written notice.

TECHNICAL SERVICES 4666 FARIES PARKWAY

DECATUR, IL 62526

TEL: 217-424-7418 FAX: 217-424-2473

August 24, 2012


In reply to your request for an ingredient statement for Citric Acid Anhydrous, the ingredient

listing is as follows: “citric acid".

The composition of citric acid anhydrous is 100 percent citric acid.

We are happy to provide this information to you. If we can be of further assistance, please call

our Technical Services office in Decatur, Illinois. Our toll free number is 800/637-5843.


The information contained herein is correct as of the date of this document to the best of our knowledge. Any recommendations or suggestions are made without guarantee or representation as to results and are subject to change without notice. We suggest you evaluate any

recommendations and suggestions independently. WE DISCLAIM ANY AND ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED,

AND SPECIFICALLY DISCLAIM THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, AND NON-INFRINGEMENT. Our responsibility for claims arising from any claim for breach of warranty, negligence, or otherwise shall not

include consequential, special, or incidental damages, and is limited to the purchase price of material purchased from us. None of the statements

made here shall be construed as a grant, either express or implied, of any license under any patent held by Archer Daniels Midland Company or other parties. Customers are responsible for obtaining any licenses or other rights that may be necessary to make, use, or sell products containing

Archer Daniels Midland Company ingredients.

Documents

List of Supporting Documentation - · PDF fileADM Technical Services . 4666 Faries Parkway Decatur, IL 62526 . Phone: 800-637-5843 Fax: 217/451-2153 . . List of Supporting Documentation